Aromatic nitro compounds present substantial health and environmental concerns due to their toxic nature and potential explosive properties.Consequently,the development of host–vip molecular recognition systems for...Aromatic nitro compounds present substantial health and environmental concerns due to their toxic nature and potential explosive properties.Consequently,the development of host–vip molecular recognition systems for these compounds serves a dual-purpose:enabling the fabrication of high-performance sensors for detection and guiding the design of efficient adsorbents for environmental remediation.This study investigated the host–vip recognition behavior of perethylated pillar[n]arenes toward two aromatic nitro molecules,1-chloro-2,4-dinitrobenzene and picric acid.Various techniques including^(1)H NMR,2D NOESY NMR,and UV-vis spectroscopy were employed to explore the binding behavior between pillararenes and aromatic nitro vips in solution.Moreover,valuable single crystal structures were obtained to elucidate the distinct solid-state assembly behaviors of these vips with different pillararenes.The assembled solid-state supramolecular structures observed encompassed a 1:1 host–vip inclusion complex,an external binding complex,and an exo-wall tessellation complex.Furthermore,based on the findings from these systems,a pillararene-based test paper was developed for efficient picric acid detection,and the removal of picric acid from solution was also achieved using pillararenes powder.This research provides novel insights into the development of diverse host–vip systems toward hazardous compounds,offering potential applications in environmental protection and explosive detection domains.展开更多
Soil denitrification,anammox,and Feammox are key for nitrogen(N)removal in agriculture.Despite potassium(K)fertilizer enhancing N efficiency,their role in regulation of these processes is unclear.A soil column incubat...Soil denitrification,anammox,and Feammox are key for nitrogen(N)removal in agriculture.Despite potassium(K)fertilizer enhancing N efficiency,their role in regulation of these processes is unclear.A soil column incubation with 15N isotope tracingwas conducted to explore millimeter-scale interactions of N and K on these pathways in soil fertilization zones.After 28 days,individual applications of N and K reduced denitrification-nitrogen removal rate(DNRR),anammox-nitrogen removal rate(ANRR),and feammox-nitrogen removal rate(FNRR)compared to a non-fertilizer control.N fertilizer had a greater effect than K,likely due to the high consumption of dissolved organic carbon by N fertilizer or the increased soil organic matter decomposition by K fertilizer.Combing of N and K increased DNRR,ANRR and FNRR rates by 31%,3090%and 244%compared to single N,and by-53.7%,885%and 222%compared to single K.These effects diminished with depth and distance from fertilizer sites.The effects of N fertilizer on these N removal processes might be regulate abundance of key microbes(e.g.,Limnobacter and Clostridium)and key gene(nirK,hzsB,ACM and Geo)by providing N substrates,while K enhances N metabolism efficiency through enzyme activation,indicated by the downregulation of certain genes(hzsB,ACM and Geo)and a negative correlation with N removal by simultaneously increasing gene expression and enzyme activity.These findings provide insights into how N and K together enhance N removal,emphasizing their importance for optimizing this process.展开更多
For a long time, it has been generally believed that spin-spin interactions can only exist in a theory where Lorentz symmetry is gauged, and a theory with spin-spin interactions is not perturbatively renormalizable. B...For a long time, it has been generally believed that spin-spin interactions can only exist in a theory where Lorentz symmetry is gauged, and a theory with spin-spin interactions is not perturbatively renormalizable. But this is not true. By studying the motion of a spinning particle in gravitational field, it is found that there exist spin-spin interactions in gauge theory of gravity. Its mechanism is that a spinning particle will generate gravitomagnetic field in space-time, and this gravitomagnetic field will interact with the spin of another particle, which will cause spin-spin interactions. So, spin-spin interactions are transmitted by gravitational field. The form of spin-spin interactions in post Newtonian approximations is deduced. This result can also be deduced from the Papapetrou equation. This kind of interaction will not affect the renormalizability of the theory. The spin-spin interactions will violate the weak equivalence principle, and the violation effects are detectable. An experiment is proposed to detect the effects of the violation of the weak equivalence principle.展开更多
In this work we present a model for the determination of the interaction energy for triplet and singlet states in atoms with incomplete filled shells. Our model includes the modification of the Coulomb’s law by the i...In this work we present a model for the determination of the interaction energy for triplet and singlet states in atoms with incomplete filled shells. Our model includes the modification of the Coulomb’s law by the interaction between the magnetic moments of the electrons. We find that the energy of the triplet state is lower than the energy of the singlet state. We calculate the interaction energy between the electrons from the adjacent atoms in fcc lattices and we find that the minimum interaction energy is attained for the triplet state. The result is presented for the interaction between the electrons of the first coordination group and those of the second coordination group. The interaction energy which aligns the spins is used to evaluate the Curie temperature in a mean field model.展开更多
Photocatalytic H2 evolution reactions on pristine graphitic carbon nitrides(g-C3N4),as a promising approach for converting solar energy to fuel,are attractive for tackling global energy concerns but still suffer from ...Photocatalytic H2 evolution reactions on pristine graphitic carbon nitrides(g-C3N4),as a promising approach for converting solar energy to fuel,are attractive for tackling global energy concerns but still suffer from low efficiencies.In this article,we report a tractable approach to modifying g-C3N4 with vanadyl phthalocyanine(VOPc/CN)for efficient visible-light-driven hydrogen production.A non-covalent VOPc/CN hybrid photocatalyst formed viaπ-πstacking interactions between the two components,as confirmed by analysis of UV-vis absorption spectra.The VOPc/CN hybrid photocatalyst shows excellent visible-light-driven photocatalytic performance and good stability.Under optimal conditions,the corresponding H2 evolution rate is nearly 6 times higher than that of pure g-C3N4.The role of VOPc in promoting hydrogen evolution activity was to extend the visible light absorption range and prevent the recombination of photoexcited electron-hole pairs effectively.It is expected that this facile modification method could be a new inspiration for the rational design and exploration of g-C3N4-based hybrid systems with strong light absorption and high-efficiency carrier separation.展开更多
Solvothermal reactions of 4,4＇-oxybis（benzoic acid） （H2oba） with 1,3-dipyridyl benzene （1,3-dpb） produced a two-dimensional （2D） cadmium（Ⅱ） coordination polymer {[Cd（oba）（dpb）]·H2O}n （1）. The co...Solvothermal reactions of 4,4＇-oxybis（benzoic acid） （H2oba） with 1,3-dipyridyl benzene （1,3-dpb） produced a two-dimensional （2D） cadmium（Ⅱ） coordination polymer {[Cd（oba）（dpb）]·H2O}n （1）. The complex was characterized by elemental analysis, IR spectroscopy, and X-ray single-crystal diffraction. It crystallizes in the monoclinic system, space group C2/c with a = 13.6692（9）, b = 25.9647（17）, c = 8.7912（6） , α = 125.0370（10）, γ = 2544.7（3）°, V = 2544.7（3） 3, C30H22N2O6Cd, Mr = 618.91, Dc =1.609 g/cm3, F（000） = 1248, μ = 0.904 mm-1 and Z = 4. The neighboring Cd（Ⅱ） ions are linked by oba2-anions and 1,3-dpb to form an infinitely 2D wavelike sheet, and two such 2D sheets are interlocked with each other by H-bonding to form a 2D → 2D structure. The adjacent two groups of interlocked structures are further linked to form a bilayer 2D supramolecular network by π-π interactions. In addition, the fluorescence property of 1 was also studied.展开更多
o understand the driving forces leading to mixed-ligand complexes in biologi-cal systenis.ternary complexes of M (ATP(L￣(2-) type, where M = Cu￣(2+), Ni￣(2+) orCo￣(2+) , and L= pyridine(Py) , 4-picoline, 3, 5-lut...o understand the driving forces leading to mixed-ligand complexes in biologi-cal systenis.ternary complexes of M (ATP(L￣(2-) type, where M = Cu￣(2+), Ni￣(2+) orCo￣(2+) , and L= pyridine(Py) , 4-picoline, 3, 5-lutidine, isoquinoline (lq) or benzimi-dazole(Bi) in aqueous solution were studied by spectropliotometry, some of them(M=Cu￣(2+), L = isoquinoline or benzimidazole) were also separately studied hy po-tentiometric pH titration. The results show that an intramolecular stacking interac-tion exists between the heteroaromatic ring of the ligands and the purine moiety ofATP.展开更多
Two series of lanthanide compounds, namely, chlorides containing different numbers of both 1,10-phenanthroline （Phen） molecules and chloride anions in the first coordination sphere, and Schiff Bases （SBs） derived ...Two series of lanthanide compounds, namely, chlorides containing different numbers of both 1,10-phenanthroline （Phen） molecules and chloride anions in the first coordination sphere, and Schiff Bases （SBs） derived from Pyridoxal （PL） and amino acids, were characterized by single crystal X-ray diffraction and luminescence techniques. The combined use of these techniques for the analysis of long-distance europium non-covalent interactions was performed for the first time. As a result, the correlation between supramolecular organization and the features of the Eum electronic transitions was found for the compounds of the first series. Strong non-covalent interactions between pyridoxal tings of SBs （the second series of compotmd） led to the formation of 1：2 species and four-dentate coordination function of these SBs in aqueous solution.展开更多
Driven by safety issues,environmental concerns,and high costs,rechargeable aqueous zinc-ion batteries(ZIBs)have received increasing attention in recent years owing to their unique advantages.However,the sluggish kinet...Driven by safety issues,environmental concerns,and high costs,rechargeable aqueous zinc-ion batteries(ZIBs)have received increasing attention in recent years owing to their unique advantages.However,the sluggish kinetics of divalent charge Zn^(2+)in the cathode materials caused by the strong electrostatic interaction and their unsatisfactory cycle life hinder the development of ZIBs.Herein,organic cations and Zn^(2+)ions co-pre-inserted vanadium oxide([N(CH_(3))_(4)]_(0.77),Zn_(0.23))V_(8)O_(20)·3.8H_(2)O are reported as the cathode for ultra-stable aqueous ZIBs,in which the weaker electrostatic interactions between Zn^(2+)and organic ion-pinned vanadium oxide can induce the high reversibility of Zn^(2+)insertion and extraction,thereby improving the cycle life.It is demonstrated that([N(CH_(3))_(4)]_(0.77),Zn_(0.23))V_(8)O_(20)·3.8H_(2)O cathodes deliver a discharge capacity of 181 mA h g^(-1)at8 A g^(-1)and ultra-long life span(99.5%capacity retention after 2000 cycles).A reversible Zn^(2+)/H^(+)ions(de)intercalation storage process and pseudocapacitive charge storage are characterized.The weaker interactions between organic ion and Zn^(2+)open a novel avenue for the design of highly reversible cathode materials with long-term cycling stability.展开更多
RNA modification has recently been proposed to play important roles in biological regulation. The detection and quantification of RNA modifications generally are challenging tasks since most of the modifications exist...RNA modification has recently been proposed to play important roles in biological regulation. The detection and quantification of RNA modifications generally are challenging tasks since most of the modifications exist in low abundance in vivo. Here we developed an on-line trapping/capillary hydrophilic-interaction liquid chromatography/electrospray ionization-mass spectrometry(on-line trapping/cHILIC/MS) method for sensitive and simultaneous quantification of RNA modifications of N^6-methyladenosine(m^6A) and 5-methylcytosine(5-mC) from human blood. The hydrophilic organic-silica hybrid monolith was prepared using sol-gel combined with "thiol-ene" click reaction for the separation of nucleosides. A poly(MAA-co-EGDMA) monolithic capillary was used as the on-line trapping column.With the developed on-line trapping/cHILIC/MS analytical platform, the detection limits of m^6A and 5-mC can reach to 0.06 fmol and 0.10 fmol. We then investigated the contents of m^6A and 5-mC in human blood RNA from healthy persons at the age of 6-14 and 60-68 years. Our results showed that both m^6A and 5-mC contents were significantly decreased in elder persons, suggesting the RNA modifications of m^6A and 5-mC are correlated to aging.展开更多
In this paper, by using harmonic-oscillator wave functions of different interaction models, i.e. OPE (onepion-exchange model), OPsE (only pseudoscalar meson exchange model), the extended GBE (Goldstone-boson-exchange ...In this paper, by using harmonic-oscillator wave functions of different interaction models, i.e. OPE (onepion-exchange model), OPsE (only pseudoscalar meson exchange model), the extended GBE (Goldstone-boson-exchange model including vector and scalar mesons), and OGE (one-gluon-exchange model), we calculate and compare the strong decays of negative parity N* resonances under 2 GeV. We find that the conventional mixing angles are correct, and GBE and OGE are obviously superior to OPE and OPsE.展开更多
With excellent biocompatibility and biodegradability,natural polysaccharides and their derivative s have exhibited great potential in constructing drug delivery ve hicles for tissue engineering and therapeutics.Cucurb...With excellent biocompatibility and biodegradability,natural polysaccharides and their derivative s have exhibited great potential in constructing drug delivery ve hicles for tissue engineering and therapeutics.Cucurbit[n]uril(CB[n])-mediated reversible crosslinking of polysaccharides possess intrinsic stimuliresponsiveness towards competitive vips and have been extensively investigated to fabricate various particles and hydrogels for multiple stimuli-re sponsive drug release by incorpo ration with other stimuli including photo,redox,and enzyme.Through host-vip interactions between CB[6]and aliphatic diamines,functional tags covalently connected with CB[6]can be readily anchored into polysaccharidebased hydrogels,realizing multiple functionalization.The rheological prope rty and drug release profile of polysaccharide-based supramolecular hydrogels can be facilely tuned through CB[8]-mediated dyna mic homo or hetero crosslinking of polysaccharides and/or other polymers.In this review,we introduce and summarize recent progress regarding polysaccharide-based supramolecular drug delivery systems mediated via host-vip interactions of CB[6]and CB[8],covering both bulk hydrogels and particular systems.At the end,possible utilization of CB[7]-based host-vip interactions in constructing polysaccharide-based drug delivery systems and future perspectives of this research direction are also discussed.展开更多
Based on the crystal structures of two cucurbit[6]uril/calix[n]arene-based supramolecular frameworks reported by Long and co-workers,we further investigated the interactions of cucurbit[6]uril with 4-sulfocalix[4]aren...Based on the crystal structures of two cucurbit[6]uril/calix[n]arene-based supramolecular frameworks reported by Long and co-workers,we further investigated the interactions of cucurbit[6]uril with 4-sulfocalix[4]arene and 4-sulfocalix[6]arene using ^(1)H NMR spectroscopy and isothermal titration calorimetry(ITC),respectively.Moreover,solid fluorescent materials were prepared via the adsorption of fluorescent dyes by these porous supramolecular frameworks,which exhibit a selective response to certain volatile organic compounds.展开更多
We study the lattice QCDΛ_(c)N phase shifts for the^(3)S_(1)-^(3)D_(1)coupled channel using both the leading order covariant chiral effective theory and the next-to-leading order non-relativistic chiral effective fie...We study the lattice QCDΛ_(c)N phase shifts for the^(3)S_(1)-^(3)D_(1)coupled channel using both the leading order covariant chiral effective theory and the next-to-leading order non-relativistic chiral effective field theory(ChEFT).We show that although it is possible to describe simultaneously the^(3)S_(1)and^(3)D_(1)phase shifts and the inelasticityη_(1),the fitted energy range is quite small,only up to E_(c.m.)=5 MeV.This raises concerns regarding the consistency between leading/next-to-leading order ChEFT and the lattice QCD simulations.展开更多
A series of novel cis poly(phenylacetylene)s(PPAs)substituted at meta-position(s)by two alkoxycarbonyl pendants,Le.,sP-Me-C8/rP-Me-C8,P-Me-C12,sP-Et-C4,sP-2C4 and sP-Oct-C4,were synthesized under the catalysis of[Rh(n...A series of novel cis poly(phenylacetylene)s(PPAs)substituted at meta-position(s)by two alkoxycarbonyl pendants,Le.,sP-Me-C8/rP-Me-C8,P-Me-C12,sP-Et-C4,sP-2C4 and sP-Oct-C4,were synthesized under the catalysis of[Rh(nbd)Cl]2(nbd=norbornadiene).The dependence of elongation,screw sense,and stimuli response of helical polyene backbone on the structure of pendant,solvent,and temperature was systematically investigated in both solution and solid states.Because of n→π*interaction between vicinal carbonyl groups,sP-Me-C8/rP-Me-C8 could adopt contracted cis-cisoid helix in THF,toluene,CH2Cl2,and CHCl3.Such an intramolecular interaction was sensitive to the hydrogen bond donating ability of solvent and temperature,but insensitive to the dielectric constant and polarity of solvent.In poly(3-methoxycarbonyl-5-alkoxycarbonylphenylacetylene),the longer the chiral alkyl chain was,the easier the stable cis-cisoid helix could be achieved.However,when the methoxycarbonyl was changed to ethoxycarbonyl,sec-butyloxycarbonyl,and octyloxycarbonyl pendant groups,only cistransoid helix was obtained at room temperature due to the increased steric hindrance.Moreover,lowering temperature was found to facilitate the stabilization of n→π*interactions,and reversible temperature-dependent stereomutations were achieved in sP-Me-C8 and sP-Et-C4depending on the solvent where they were dissolved.These results suggested that the long alkyl chain,small pendant size,and lower temperature favored the stabilization of intramolecular n→π*interactions and the formation of contracted,cis-cisoid helices for poly(3,5-diestersubstituted phenylacetylene)s.展开更多
Five optimized geometries of F-?(H2O)n (n = 1, 2) were obtained with ab initio calculation at the B3LYP/6-311++G** level. The accurate intermonomer interaction energy was calculated using the MP2 electron correlation ...Five optimized geometries of F-?(H2O)n (n = 1, 2) were obtained with ab initio calculation at the B3LYP/6-311++G** level. The accurate intermonomer interaction energy was calculated using the MP2 electron correlation correction as well as the basis set superposition error correction by the Boys-Bernardi “counterpoise” protocol. Natural bond orbital (NBO) theory was applied to quantify the relative strength of these interactions and account for their effects on the stability, structural and vibrational parameters of Fˉ?(H2O)n (n = 1, 2). It is shown that the charge transferring from the lone pair of F-1 to the σ?OH(…F) antibonding orbital is important. The results indicate the occupancy of σ?OH(…F) is increased (denoted ?σ?OH(…F)) and the σOH(…F) bond is leng- thened (denoted ?ROH(…F)), leading to the red-shift and the red-shift values have linear correlation with both ?σ?OH(…F) and ?ROH(…F).展开更多
In this paper, a nonlocal two-wave interaction system from the Manakov hierarchy is investigated via the Riemann–Hilbert approach. Based on the spectral analysis of the Lax pair, a Riemann–Hilbert problem for the no...In this paper, a nonlocal two-wave interaction system from the Manakov hierarchy is investigated via the Riemann–Hilbert approach. Based on the spectral analysis of the Lax pair, a Riemann–Hilbert problem for the nonlocal two-wave interaction system is constructed. By discussing the solutions of this Riemann–Hilbert problem in both the regular and nonregular cases, we explicitly present the N-soliton solution formula of the nonlocal two-wave interaction system. Moreover,the dynamical behaviour of the single-soliton solution is shown graphically.展开更多
The N-N <sup>1</sup>S<sub>0</sub> scattering length differences Δα<sub>CSB</sub> and Δα<sub>CIH</sub> of the charge symmetrybreaking and charge independence breaking...The N-N <sup>1</sup>S<sub>0</sub> scattering length differences Δα<sub>CSB</sub> and Δα<sub>CIH</sub> of the charge symmetrybreaking and charge independence breaking are calculated by a resonating group method with aquark cluster model.By adding the QED-QCD interference effect to the quark mass differenceand the electromagnetic interaction,the Δα<sub>CSH</sub> and Δα<sub>CIH</sub> can be reproduced with modelparameters constrained by the hadron isomultiplet masses.展开更多
[Objective] The paper was to obtain host proteins interacting with porcine epidemic diarrhea virus （PEDV） N protein. [Method] The re-combinant vector pGBKT7-N of PEDV N gene was constructed and used as the bait plas...[Objective] The paper was to obtain host proteins interacting with porcine epidemic diarrhea virus （PEDV） N protein. [Method] The re-combinant vector pGBKT7-N of PEDV N gene was constructed and used as the bait plasmid to screen the proteins interacting with N protein ofPEDV from the cDNA library of porcine alveolar macrophage （PAM） by yeast two-hybrid method. [Result] There was no toxicity and self activationof bait protein in yeast hybridization system, and six proteins （FTH1, LGALS3, CORO1C, SNRPG, KRTAP5-3, ZNF598） interacting with N proteinwere indentified. It was confirmed that LGALS3 and SNRPG had specific interaction with N protein by return experiment and co-immunoprecipitation（CoIP） test. [Conclusion] The study lays a foundation for further studying the function of PEDV N protein and the pathogenic mechanism of PEDV.展开更多
基金supported by the fundamental research funds of Zhejiang Sci-Tech University(No.22212286-Y)the Natural Science Foundation of Zhejiang Province(No.LQ24B040003)。
文摘Aromatic nitro compounds present substantial health and environmental concerns due to their toxic nature and potential explosive properties.Consequently,the development of host–vip molecular recognition systems for these compounds serves a dual-purpose:enabling the fabrication of high-performance sensors for detection and guiding the design of efficient adsorbents for environmental remediation.This study investigated the host–vip recognition behavior of perethylated pillar[n]arenes toward two aromatic nitro molecules,1-chloro-2,4-dinitrobenzene and picric acid.Various techniques including^(1)H NMR,2D NOESY NMR,and UV-vis spectroscopy were employed to explore the binding behavior between pillararenes and aromatic nitro vips in solution.Moreover,valuable single crystal structures were obtained to elucidate the distinct solid-state assembly behaviors of these vips with different pillararenes.The assembled solid-state supramolecular structures observed encompassed a 1:1 host–vip inclusion complex,an external binding complex,and an exo-wall tessellation complex.Furthermore,based on the findings from these systems,a pillararene-based test paper was developed for efficient picric acid detection,and the removal of picric acid from solution was also achieved using pillararenes powder.This research provides novel insights into the development of diverse host–vip systems toward hazardous compounds,offering potential applications in environmental protection and explosive detection domains.
基金supported by the National Natural Science Foundation of China(Nos.32271726 and 32171648)the Natural Science Foundation of Hubei Province of China(No.2022CFB030)。
文摘Soil denitrification,anammox,and Feammox are key for nitrogen(N)removal in agriculture.Despite potassium(K)fertilizer enhancing N efficiency,their role in regulation of these processes is unclear.A soil column incubation with 15N isotope tracingwas conducted to explore millimeter-scale interactions of N and K on these pathways in soil fertilization zones.After 28 days,individual applications of N and K reduced denitrification-nitrogen removal rate(DNRR),anammox-nitrogen removal rate(ANRR),and feammox-nitrogen removal rate(FNRR)compared to a non-fertilizer control.N fertilizer had a greater effect than K,likely due to the high consumption of dissolved organic carbon by N fertilizer or the increased soil organic matter decomposition by K fertilizer.Combing of N and K increased DNRR,ANRR and FNRR rates by 31%,3090%and 244%compared to single N,and by-53.7%,885%and 222%compared to single K.These effects diminished with depth and distance from fertilizer sites.The effects of N fertilizer on these N removal processes might be regulate abundance of key microbes(e.g.,Limnobacter and Clostridium)and key gene(nirK,hzsB,ACM and Geo)by providing N substrates,while K enhances N metabolism efficiency through enzyme activation,indicated by the downregulation of certain genes(hzsB,ACM and Geo)and a negative correlation with N removal by simultaneously increasing gene expression and enzyme activity.These findings provide insights into how N and K together enhance N removal,emphasizing their importance for optimizing this process.
文摘For a long time, it has been generally believed that spin-spin interactions can only exist in a theory where Lorentz symmetry is gauged, and a theory with spin-spin interactions is not perturbatively renormalizable. But this is not true. By studying the motion of a spinning particle in gravitational field, it is found that there exist spin-spin interactions in gauge theory of gravity. Its mechanism is that a spinning particle will generate gravitomagnetic field in space-time, and this gravitomagnetic field will interact with the spin of another particle, which will cause spin-spin interactions. So, spin-spin interactions are transmitted by gravitational field. The form of spin-spin interactions in post Newtonian approximations is deduced. This result can also be deduced from the Papapetrou equation. This kind of interaction will not affect the renormalizability of the theory. The spin-spin interactions will violate the weak equivalence principle, and the violation effects are detectable. An experiment is proposed to detect the effects of the violation of the weak equivalence principle.
文摘In this work we present a model for the determination of the interaction energy for triplet and singlet states in atoms with incomplete filled shells. Our model includes the modification of the Coulomb’s law by the interaction between the magnetic moments of the electrons. We find that the energy of the triplet state is lower than the energy of the singlet state. We calculate the interaction energy between the electrons from the adjacent atoms in fcc lattices and we find that the minimum interaction energy is attained for the triplet state. The result is presented for the interaction between the electrons of the first coordination group and those of the second coordination group. The interaction energy which aligns the spins is used to evaluate the Curie temperature in a mean field model.
基金supported by the National Natural Science Foundation of China(51572253,21771171)Scientific Research Grant of Hefei National Synchrotron Radiation Laboratory(UN2017LHJJ)+1 种基金the Fundamental Research Funds for the Central Universitiescooperation between NSFC and Netherlands Organization for Scientific Research(51561135011)~~
文摘Photocatalytic H2 evolution reactions on pristine graphitic carbon nitrides(g-C3N4),as a promising approach for converting solar energy to fuel,are attractive for tackling global energy concerns but still suffer from low efficiencies.In this article,we report a tractable approach to modifying g-C3N4 with vanadyl phthalocyanine(VOPc/CN)for efficient visible-light-driven hydrogen production.A non-covalent VOPc/CN hybrid photocatalyst formed viaπ-πstacking interactions between the two components,as confirmed by analysis of UV-vis absorption spectra.The VOPc/CN hybrid photocatalyst shows excellent visible-light-driven photocatalytic performance and good stability.Under optimal conditions,the corresponding H2 evolution rate is nearly 6 times higher than that of pure g-C3N4.The role of VOPc in promoting hydrogen evolution activity was to extend the visible light absorption range and prevent the recombination of photoexcited electron-hole pairs effectively.It is expected that this facile modification method could be a new inspiration for the rational design and exploration of g-C3N4-based hybrid systems with strong light absorption and high-efficiency carrier separation.
基金supported by the National Natural Science Foundation of China (21071004, 51173002)the Start-up Foundation and the young teacher’s research foundation of Anhui University of Science and Technology (11227, 2012QNZ08)the Research fund of Key Laboratory for Advanced Technology in Environmental Protection of Jiangsu Province (AE 201107)
文摘Solvothermal reactions of 4,4＇-oxybis（benzoic acid） （H2oba） with 1,3-dipyridyl benzene （1,3-dpb） produced a two-dimensional （2D） cadmium（Ⅱ） coordination polymer {[Cd（oba）（dpb）]·H2O}n （1）. The complex was characterized by elemental analysis, IR spectroscopy, and X-ray single-crystal diffraction. It crystallizes in the monoclinic system, space group C2/c with a = 13.6692（9）, b = 25.9647（17）, c = 8.7912（6） , α = 125.0370（10）, γ = 2544.7（3）°, V = 2544.7（3） 3, C30H22N2O6Cd, Mr = 618.91, Dc =1.609 g/cm3, F（000） = 1248, μ = 0.904 mm-1 and Z = 4. The neighboring Cd（Ⅱ） ions are linked by oba2-anions and 1,3-dpb to form an infinitely 2D wavelike sheet, and two such 2D sheets are interlocked with each other by H-bonding to form a 2D → 2D structure. The adjacent two groups of interlocked structures are further linked to form a bilayer 2D supramolecular network by π-π interactions. In addition, the fluorescence property of 1 was also studied.
文摘o understand the driving forces leading to mixed-ligand complexes in biologi-cal systenis.ternary complexes of M (ATP(L￣(2-) type, where M = Cu￣(2+), Ni￣(2+) orCo￣(2+) , and L= pyridine(Py) , 4-picoline, 3, 5-lutidine, isoquinoline (lq) or benzimi-dazole(Bi) in aqueous solution were studied by spectropliotometry, some of them(M=Cu￣(2+), L = isoquinoline or benzimidazole) were also separately studied hy po-tentiometric pH titration. The results show that an intramolecular stacking interac-tion exists between the heteroaromatic ring of the ligands and the purine moiety ofATP.
基金Russian Science Support Foundation, Russian Foundation of Basic Research (07-03-12196 and grant MK-6026.2008.9)
文摘Two series of lanthanide compounds, namely, chlorides containing different numbers of both 1,10-phenanthroline （Phen） molecules and chloride anions in the first coordination sphere, and Schiff Bases （SBs） derived from Pyridoxal （PL） and amino acids, were characterized by single crystal X-ray diffraction and luminescence techniques. The combined use of these techniques for the analysis of long-distance europium non-covalent interactions was performed for the first time. As a result, the correlation between supramolecular organization and the features of the Eum electronic transitions was found for the compounds of the first series. Strong non-covalent interactions between pyridoxal tings of SBs （the second series of compotmd） led to the formation of 1：2 species and four-dentate coordination function of these SBs in aqueous solution.
基金supported by the funding from the National Natural Science Foundation of China(grant nos.51902187,52072224,and 51732007)the Natural Science Foundation of Shandong Province(ZR2018BEM010)+3 种基金the Science Fund for Distinguished Young Scholars of Shandong Province(ZR2019JQ16)the Fundamental Research Funds of Shandong UniversityYoung Elite Scientist Sponsorship Program by CAST(YESS)the support from Collaborative Innovation Center of Technology and Equipment for Biological Diagnosis and Therapy in Universities of Shandong
文摘Driven by safety issues,environmental concerns,and high costs,rechargeable aqueous zinc-ion batteries(ZIBs)have received increasing attention in recent years owing to their unique advantages.However,the sluggish kinetics of divalent charge Zn^(2+)in the cathode materials caused by the strong electrostatic interaction and their unsatisfactory cycle life hinder the development of ZIBs.Herein,organic cations and Zn^(2+)ions co-pre-inserted vanadium oxide([N(CH_(3))_(4)]_(0.77),Zn_(0.23))V_(8)O_(20)·3.8H_(2)O are reported as the cathode for ultra-stable aqueous ZIBs,in which the weaker electrostatic interactions between Zn^(2+)and organic ion-pinned vanadium oxide can induce the high reversibility of Zn^(2+)insertion and extraction,thereby improving the cycle life.It is demonstrated that([N(CH_(3))_(4)]_(0.77),Zn_(0.23))V_(8)O_(20)·3.8H_(2)O cathodes deliver a discharge capacity of 181 mA h g^(-1)at8 A g^(-1)and ultra-long life span(99.5%capacity retention after 2000 cycles).A reversible Zn^(2+)/H^(+)ions(de)intercalation storage process and pseudocapacitive charge storage are characterized.The weaker interactions between organic ion and Zn^(2+)open a novel avenue for the design of highly reversible cathode materials with long-term cycling stability.
基金financially supported by the National Natural Science Foundation of China (Nos. 21522507, 21672166, 21728802, 21721005)
文摘RNA modification has recently been proposed to play important roles in biological regulation. The detection and quantification of RNA modifications generally are challenging tasks since most of the modifications exist in low abundance in vivo. Here we developed an on-line trapping/capillary hydrophilic-interaction liquid chromatography/electrospray ionization-mass spectrometry(on-line trapping/cHILIC/MS) method for sensitive and simultaneous quantification of RNA modifications of N^6-methyladenosine(m^6A) and 5-methylcytosine(5-mC) from human blood. The hydrophilic organic-silica hybrid monolith was prepared using sol-gel combined with "thiol-ene" click reaction for the separation of nucleosides. A poly(MAA-co-EGDMA) monolithic capillary was used as the on-line trapping column.With the developed on-line trapping/cHILIC/MS analytical platform, the detection limits of m^6A and 5-mC can reach to 0.06 fmol and 0.10 fmol. We then investigated the contents of m^6A and 5-mC in human blood RNA from healthy persons at the age of 6-14 and 60-68 years. Our results showed that both m^6A and 5-mC contents were significantly decreased in elder persons, suggesting the RNA modifications of m^6A and 5-mC are correlated to aging.
文摘In this paper, by using harmonic-oscillator wave functions of different interaction models, i.e. OPE (onepion-exchange model), OPsE (only pseudoscalar meson exchange model), the extended GBE (Goldstone-boson-exchange model including vector and scalar mesons), and OGE (one-gluon-exchange model), we calculate and compare the strong decays of negative parity N* resonances under 2 GeV. We find that the conventional mixing angles are correct, and GBE and OGE are obviously superior to OPE and OPsE.
基金supported by the National Natural Science Foundation of China(No.201872051)National Key Research and Development Plan(No.2017YFD0200306)Startup Research Fund of Nanjing University of Science and Technology(No.AE89991/163)。
文摘With excellent biocompatibility and biodegradability,natural polysaccharides and their derivative s have exhibited great potential in constructing drug delivery ve hicles for tissue engineering and therapeutics.Cucurbit[n]uril(CB[n])-mediated reversible crosslinking of polysaccharides possess intrinsic stimuliresponsiveness towards competitive vips and have been extensively investigated to fabricate various particles and hydrogels for multiple stimuli-re sponsive drug release by incorpo ration with other stimuli including photo,redox,and enzyme.Through host-vip interactions between CB[6]and aliphatic diamines,functional tags covalently connected with CB[6]can be readily anchored into polysaccharidebased hydrogels,realizing multiple functionalization.The rheological prope rty and drug release profile of polysaccharide-based supramolecular hydrogels can be facilely tuned through CB[8]-mediated dyna mic homo or hetero crosslinking of polysaccharides and/or other polymers.In this review,we introduce and summarize recent progress regarding polysaccharide-based supramolecular drug delivery systems mediated via host-vip interactions of CB[6]and CB[8],covering both bulk hydrogels and particular systems.At the end,possible utilization of CB[7]-based host-vip interactions in constructing polysaccharide-based drug delivery systems and future perspectives of this research direction are also discussed.
基金the financial support of National Natural Science Foundation of China(Nos.51663005,21761007 and21871064)Science and Technology Plan Project of Guizhou Province(Nos.20175788 and 20185781)+2 种基金the Creative Research Groups of Guizhou Provincial Education Department(No.2017028)the Innovation Program for High-level Talents of Guizhou Province(No.20165657)“Chun-Hui” Fund of Chinese Ministry of Education(No.Z2017005)。
文摘Based on the crystal structures of two cucurbit[6]uril/calix[n]arene-based supramolecular frameworks reported by Long and co-workers,we further investigated the interactions of cucurbit[6]uril with 4-sulfocalix[4]arene and 4-sulfocalix[6]arene using ^(1)H NMR spectroscopy and isothermal titration calorimetry(ITC),respectively.Moreover,solid fluorescent materials were prepared via the adsorption of fluorescent dyes by these porous supramolecular frameworks,which exhibit a selective response to certain volatile organic compounds.
基金partly supported by the National Natural Science Foundation of China(NSFC)under Grants No.11975041,No.11735003,and No.11961141004Yang Xiao acknowledges the support from China Scholarship Council
文摘We study the lattice QCDΛ_(c)N phase shifts for the^(3)S_(1)-^(3)D_(1)coupled channel using both the leading order covariant chiral effective theory and the next-to-leading order non-relativistic chiral effective field theory(ChEFT).We show that although it is possible to describe simultaneously the^(3)S_(1)and^(3)D_(1)phase shifts and the inelasticityη_(1),the fitted energy range is quite small,only up to E_(c.m.)=5 MeV.This raises concerns regarding the consistency between leading/next-to-leading order ChEFT and the lattice QCD simulations.
基金This work was financially supported by the National Natural Science Foundation of China(Nos.51833001 and 21674002).
文摘A series of novel cis poly(phenylacetylene)s(PPAs)substituted at meta-position(s)by two alkoxycarbonyl pendants,Le.,sP-Me-C8/rP-Me-C8,P-Me-C12,sP-Et-C4,sP-2C4 and sP-Oct-C4,were synthesized under the catalysis of[Rh(nbd)Cl]2(nbd=norbornadiene).The dependence of elongation,screw sense,and stimuli response of helical polyene backbone on the structure of pendant,solvent,and temperature was systematically investigated in both solution and solid states.Because of n→π*interaction between vicinal carbonyl groups,sP-Me-C8/rP-Me-C8 could adopt contracted cis-cisoid helix in THF,toluene,CH2Cl2,and CHCl3.Such an intramolecular interaction was sensitive to the hydrogen bond donating ability of solvent and temperature,but insensitive to the dielectric constant and polarity of solvent.In poly(3-methoxycarbonyl-5-alkoxycarbonylphenylacetylene),the longer the chiral alkyl chain was,the easier the stable cis-cisoid helix could be achieved.However,when the methoxycarbonyl was changed to ethoxycarbonyl,sec-butyloxycarbonyl,and octyloxycarbonyl pendant groups,only cistransoid helix was obtained at room temperature due to the increased steric hindrance.Moreover,lowering temperature was found to facilitate the stabilization of n→π*interactions,and reversible temperature-dependent stereomutations were achieved in sP-Me-C8 and sP-Et-C4depending on the solvent where they were dissolved.These results suggested that the long alkyl chain,small pendant size,and lower temperature favored the stabilization of intramolecular n→π*interactions and the formation of contracted,cis-cisoid helices for poly(3,5-diestersubstituted phenylacetylene)s.
基金This work was supported by the Foundation of Education Committee of Gansu Province (021-227).
文摘Five optimized geometries of F-?(H2O)n (n = 1, 2) were obtained with ab initio calculation at the B3LYP/6-311++G** level. The accurate intermonomer interaction energy was calculated using the MP2 electron correlation correction as well as the basis set superposition error correction by the Boys-Bernardi “counterpoise” protocol. Natural bond orbital (NBO) theory was applied to quantify the relative strength of these interactions and account for their effects on the stability, structural and vibrational parameters of Fˉ?(H2O)n (n = 1, 2). It is shown that the charge transferring from the lone pair of F-1 to the σ?OH(…F) antibonding orbital is important. The results indicate the occupancy of σ?OH(…F) is increased (denoted ?σ?OH(…F)) and the σOH(…F) bond is leng- thened (denoted ?ROH(…F)), leading to the red-shift and the red-shift values have linear correlation with both ?σ?OH(…F) and ?ROH(…F).
基金Project supported by the National Natural Science Foundation of China(Grant Nos.11331008 and 11522112)
文摘In this paper, a nonlocal two-wave interaction system from the Manakov hierarchy is investigated via the Riemann–Hilbert approach. Based on the spectral analysis of the Lax pair, a Riemann–Hilbert problem for the nonlocal two-wave interaction system is constructed. By discussing the solutions of this Riemann–Hilbert problem in both the regular and nonregular cases, we explicitly present the N-soliton solution formula of the nonlocal two-wave interaction system. Moreover,the dynamical behaviour of the single-soliton solution is shown graphically.
基金The project supported by the NSF(19675018)SEDC of ChinaSSTC of China
文摘The N-N <sup>1</sup>S<sub>0</sub> scattering length differences Δα<sub>CSB</sub> and Δα<sub>CIH</sub> of the charge symmetrybreaking and charge independence breaking are calculated by a resonating group method with aquark cluster model.By adding the QED-QCD interference effect to the quark mass differenceand the electromagnetic interaction,the Δα<sub>CSH</sub> and Δα<sub>CIH</sub> can be reproduced with modelparameters constrained by the hadron isomultiplet masses.
基金Supported by National Natural Science Foundation of China(31201915,31502071)Key Project of Science and Technology Promoting Agriculture in Shanghai City[HNKGZ(2013)No.3-6,No.5-5]
文摘[Objective] The paper was to obtain host proteins interacting with porcine epidemic diarrhea virus （PEDV） N protein. [Method] The re-combinant vector pGBKT7-N of PEDV N gene was constructed and used as the bait plasmid to screen the proteins interacting with N protein ofPEDV from the cDNA library of porcine alveolar macrophage （PAM） by yeast two-hybrid method. [Result] There was no toxicity and self activationof bait protein in yeast hybridization system, and six proteins （FTH1, LGALS3, CORO1C, SNRPG, KRTAP5-3, ZNF598） interacting with N proteinwere indentified. It was confirmed that LGALS3 and SNRPG had specific interaction with N protein by return experiment and co-immunoprecipitation（CoIP） test. [Conclusion] The study lays a foundation for further studying the function of PEDV N protein and the pathogenic mechanism of PEDV.
