The leaching process of magnesiothermic self-propagating product generated during the multistage deep reduction process was investigated.The influence of magnesiothermic self-propagating product particle size,HCl solu...The leaching process of magnesiothermic self-propagating product generated during the multistage deep reduction process was investigated.The influence of magnesiothermic self-propagating product particle size,HCl solution concentration,and leaching solution temperature on the leaching behavior of elements Al and V was investigated.Results demonstrate that the leaching rate of Al and V is increased with the rise in leaching solution temperature,the increase in HCl solution concentration,and the enlargement of magnesiothermic self-propagating product particle size.The leaching processes of Al and V are consistent with the chemical reaction control model.When the magnesiothermic self-propagation product with D_(50) of 59.4μm is selected as the raw material,the leaching temperature is 40℃,and 1 mol/L HCl solution is employed,after leaching for 180 min,the leaching rates of Al and V are 24.8%and 12.6%,respectively.The acid-leached product exhibits a porous structure with a specific surface area of 3.5633 m^(2)/g.展开更多
This study reconstructed the paleo-uplift and depression pattern within the sequence stratigraphic framework of the Mid-Permian Maokou Formation,Sichuan Basin,investigated its tectono-sedimentary mechanisms and its co...This study reconstructed the paleo-uplift and depression pattern within the sequence stratigraphic framework of the Mid-Permian Maokou Formation,Sichuan Basin,investigated its tectono-sedimentary mechanisms and its control on paleogeomorphology and large-sale shoals based on analysis of outcrops,loggings and seismic data.The results show that the Maokou Formation comprises two third-order sequences,six fourth-order sequences(SSQ1-SSQ6),and four distinct slope-break zones developing progressively from north to south.Slope-break zones I-III in the northern basin,controlled by synsedimentary extensional faults,exhibited a NE-trending linear distribution with gradual southeastward migration.In contrast,slope-break zone IV in the southern basin displayed an arcuate distribution along the Emeishan Large Igneous Province(ELIP).The evolutions of these multistage slope-break zones governed the Mid-Permian paleogeomorphy in the Sichuan Basin transformations from a giant,north-dipping gentle slope(higher in the southwest than in the northeast)in the early-stage(SSQ1-SSQ2)to a platform(south)-basin(north)pattern in the middle-stage(SSQ3-SSQ5).Ultimately,a further depression zone developed in the southwestern basin during the late-stage(SSQ6),forming a paleo-uplift bounded by two depressions.The developments of the Mid-Permian paleogeomorphic configuration reflected the combined control by the rapid subduction of the Mianlüe Ocean and the episodic eruptions of the Emeishan mantle plume(or hot spots),which jointly facilitated the formation of extensive high-energy shoal facies belts along slope-break zones and around paleo-volcanic uplifts.展开更多
To investigate the relationship between grain sizes, seepage capacity, and oil-displacement efficiency in the Liushagang Formation of the Beibuwan Basin, this study identifies the multistage pore-throat structure as a...To investigate the relationship between grain sizes, seepage capacity, and oil-displacement efficiency in the Liushagang Formation of the Beibuwan Basin, this study identifies the multistage pore-throat structure as a crucial factor through a comparison of oil displacement in microscopic pore-throat experiments. The two-phase flow evaluation method based on the Li-Horne model is utilized to effectively characterize and quantify the seepage characteristics of different reservoirs, closely relating them to the distribution of microscopic pores and throats. It is observed that conglomerate sandstones at different stages exhibit significant heterogeneity and noticeable differences in seepage capacity, highlighting the crucial role played by certain large pore throats in determining seepage capacity and oil displacement efficiency. Furthermore, it was found that the displacement effects of conglomeratic sandstones with strong heterogeneity were inferior to those of conventional homogeneous sandstone, as evidenced by multiple displacement experiments conducted on core samples with varying granularities and flooding systems. Subsequently, core-based experiments on associated gas flooding after water flooding were conducted to address the challenge of achieving satisfactory results in a single displacement mode for reservoirs with significant heterogeneity. The results indicate that the oil recovery rates for associated gas flooding after water flooding increased by 7.3%-16.4% compared with water flooding alone at a gas-oil ratio of approximately 7000 m^(3)/m^(3). Therefore, considering the advantages of gas flooding in terms of seepage capacity, oil exchange ratio, and the potential for two-phase production, gas flooding is recommended as an energy supplement mode for homogeneous reservoirs in the presence of sufficient gas source and appropriate tectonic angle. On the other hand, associated gas flooding after water flooding is suggested to achieve a more favorable development effect compared to a single mode of energy supplementation for strongly heterogeneous sandstone reservoirs.展开更多
Objective:To reveal the distribution characteristics and demographic factors of traditional Chinese medicine(TCM)constitution among elderly individuals in China.Methods: Elderly individuals from seven regions in China...Objective:To reveal the distribution characteristics and demographic factors of traditional Chinese medicine(TCM)constitution among elderly individuals in China.Methods: Elderly individuals from seven regions in China were selected as samples in this study using a multistage cluster random sampling method.The basic information questionnaire and Constitution in Chinese Medicine Questionnaire(Elderly Edition)were used.Descriptive statistical analysis,chi-squared tests,and binary logistic regression analysis were used.Results: The single balanced constitution(BC)accounted for 23.9%.The results of the major TCM constitution types showed that BC(43.2%)accounted for the largest proportion and unbalanced constitutions ranged from 0.9%to 15.7%.East China region(odds ratio[OR]=2.097;95%confidence interval[CI],1.912 to 2.301),married status(OR=1.341;95%CI,1.235 to 1.457),and managers(OR=1.254;95%CI,1.044 to 1.505)were significantly associated with BC.Age>70 years was associated with qi-deficiency constitution and blood stasis constitution(BSC).Female sex was significantly associated with yang-deficiency constitution(OR=1.646;95%CI,1.52 to 1.782).Southwest region was significantly associated with phlegm-dampness constitution(OR=1.809;95%CI,1.569 to 2.086).North China region was significantly associated with inherited special constitution(OR=2.521;95%CI,1.569 to 4.05).South China region(OR=2.741;95%CI,1.997 to 1.3.763),Central China region(OR=8.889;95%CI,6.676 to 11.835),senior middle school education(OR=2.442;95%CI,1.932 to 3.088),and managers(OR=1.804;95%CI,1.21 to 2.69)were significantly associated with BSC.Conclusions: This study defined the distribution characteristics and demographic factors of TCM constitution in the elderly population.Adjusting and improving unbalanced constitutions,which are correlated with diseases,can help promote healthy aging through the scientific management of these demographic factors.展开更多
Multistage hydraulic fracturing of horizontal wells(MFHW)is a promising technology for controlling coal burst caused by thick and hard roofs in China.However,challenges remain regarding the MFHW control mechanism of c...Multistage hydraulic fracturing of horizontal wells(MFHW)is a promising technology for controlling coal burst caused by thick and hard roofs in China.However,challenges remain regarding the MFHW control mechanism of coal burst and assessment of the associated fracturing effects.In this study,these challenges were investigated through numerical modelling and field applications,based on the actual operating parameters of MFHW for hard roofs in a Chinese coal mine.A damage parameter(D)is proposed to assess the degree of hydraulic fracturing in the roof.The mechanisms and effects of MFHW for controlling coal burst are analyzed using microseismic(MS)data and front-abutment stress distribution.Results show that the degree of fracturing can be categorized into lightly-fractured(D≤0.3),moderately fractured(0.3<D≤0.6),well-fractured(0.6<D≤0.9),and over-fractured(0.9<D≤0.95).A response stage in the fracturing process,characterized by a slowdown in crack development,indicates the transition to a wellfractured condition.After MFHW,the zone range and peak value of the front-abutment stress decrease.Additionally,MS events shift from near the coal seam to the fractured roof layers,with the number of MS events increases while the average MS energy decreases.The MFHW control mechanisms of coal bursts involve mitigating mining-induced stress and reducing seismic activity during longwall retreat,ensuring stresses remain below the ultimate stress level.These findings provide a reference for evaluating MFHW fracturing effects and controlling coal burst disasters in engineering.展开更多
Blasting operations,which are crucial to open-pit mine production due to their simplicity and efficiency,require precise control through accurate vibration velocity calculations.The conventional Sadowski formula mainl...Blasting operations,which are crucial to open-pit mine production due to their simplicity and efficiency,require precise control through accurate vibration velocity calculations.The conventional Sadowski formula mainly focuses on blast center distance but neglects the amplification effect of blasting vibration waves by terraced terrain,from which the calculated blasting vibration velocities are smaller than the actual values,affecting the safety of the project.To address this issue,our model introduces the influences of slope and time into Sadowski formula to measure safety through blast vibration displacement.In the northern section of the open-pit quartz mine in Jinchang City,Gansu Province,China,the data of a continuous blasting slope project are referred to.Our findings reveal a noticeable vibration amplification effect during blasting when a multi-stage slope platform undergoes a sudden cross-sectional change near the upper overhanging surface.The amplification vibration coefficient increases with height,while vibration waves within rocks decrease from bottom to top.Conversely,platforms without distinct crosssectional changes exhibit no pronounced amplification during blasting.In addition,the vibration intensity decreases with distance as the rock height difference change propagates.The results obtained by the proposed blast vibration displacement equation incorporating slope shape influence closely agree with real-world scenarios.According to Pearson correlation coefficient(PPMCC)analysis,the average accuracy rate of our model is 88.84%,which exceeds the conventional Sadowski formula(46.92%).展开更多
The current portfolio model for property-liability insurance company is only single period that can not meet the practical demands of portfolio management, and the purpose of this paper is to develop a multiperiod mod...The current portfolio model for property-liability insurance company is only single period that can not meet the practical demands of portfolio management, and the purpose of this paper is to develop a multiperiod model for its portfolio problem. The model is a multistage stochastic programming which considers transaction costs, cash flow between time periods, and the matching of asset and liability; it does not depend on the assumption for normality of return distribution. Additionally, an investment constraint is added. The numerical example manifests that the multiperiod model can more effectively assist the property-liability insurer to determine the optimal composition of insurance and investment portfolio and outperforms the single period one.展开更多
High ferrotitanium is used as a deoxidizer and alloying agent in steelmaking processes and is mainly produced using high-cost remelting processes.The thermite method is a simple and low-cost method for preparing low f...High ferrotitanium is used as a deoxidizer and alloying agent in steelmaking processes and is mainly produced using high-cost remelting processes.The thermite method is a simple and low-cost method for preparing low ferrotitanium.However,the high levels of S,Al,and O residues in the product severely restrict its applicability in the low-cost preparation of good-quality high ferrotitanium.In this study,a novel multistage deep reduction method for preparing high-quality high ferrotitanium is proposed,and the multistage desulfurization mechanism is systematically investigated.The results indicate that multistage desulfurization is an effective method for reducing the S content of high ferrotitanium prepared via the thermite method.During the strong desulfurization stage,Ti_(2)S reacts with CaO at the slag-metal interface and produces CaS.The S content decreases,while the O content increases,with the increase of CaO in the CaO-Al_(2)O_(3)-based slag.During the deep desulfurization,Ti_(2)S is deeply reduced by the Ca and produces CaS,thus further reducing the S content.The S content decreases with the incremental addition of Ca and can be reduced to 0.035 wt%after multistage desulfurization.展开更多
Abstract There are two extensional systems in the Xiaoqinling metamorphic core complex (XMCC). One is the detachment fault system developed along the peripheries of the XMCC, which extended in an ESE-WNW direction and...Abstract There are two extensional systems in the Xiaoqinling metamorphic core complex (XMCC). One is the detachment fault system developed along the peripheries of the XMCC, which extended in an ESE-WNW direction and whose upper plate moved towards the WNW. The other extensional system includes the retrograde shear zones and normal faults developed within the XMCC, which represent the collapse of the XMCC. Ar-Ar and K-Ar dating shows that the extension of the detachment fault system continued from 135 to 123 Ma, i.e. in the late stage of its evolution at about 127 Ma. The collapse represented by the extensional system within the XMCC was operative during 120–106 Ma, and its main activity occurred about 116 Ma ago. These suggest that the XMCC experienced two extensional stages in its evolution, i.e., the syn-orogenic regional extension and post-orogenic collapse extension.展开更多
Rotor blades fault of aeroengine compressor is mostly caused by mechanical and aerodynamic excitation.And the excitation factor of high intensity sound wave to rotor blades should not be ignored.Experimental researche...Rotor blades fault of aeroengine compressor is mostly caused by mechanical and aerodynamic excitation.And the excitation factor of high intensity sound wave to rotor blades should not be ignored.Experimental researches are conducted on a multistage high pressure compressor.When high level vibration occurs on the first stage of rotor blades, the noise spectrum presents typical characteristic for discrete multi-tone in the compressor.The amplitude of blade vibration displacement and the sound pressure level of characteristic frequency noise increases and decreases simultaneously and reaches the maximum value at the same time.This frequency merely occur on a certain speed range and is locked in a specific range which presents no variation with the rotating speed.When high level vibration occurs on the first stage of rotor blades, the noise spectrum presents a sharp peak and the propagation state of the characteristic frequency is a helix structure in the compressor.It can be confirmed that acoustic resonance occurs in the multistage compressor.The acoustic resonance frequency and its side band frequencies are generated by modulation of a rotating noise source at the rotor speed which is the excitation source of the rotor blades vibration.展开更多
Developing megahertz(MHz)electromagnetic wave(EMW)absorption materials with broadband absorption,multi-temperature adaptability,and facile preparation method remains a challenge.Herein,nanocrystalline FeCoNiCr_(0.4)Cu...Developing megahertz(MHz)electromagnetic wave(EMW)absorption materials with broadband absorption,multi-temperature adaptability,and facile preparation method remains a challenge.Herein,nanocrystalline FeCoNiCr_(0.4)Cu_(0.2) high-entropy alloy powders(HEAs)with both large aspect ratios and thin intergranular amorphous layers are constructed by a multistage mechanical alloying strategy,aiming to achieve excellent and temperature-stable permeability and EMW absorption.A single-phase face-centered cubic structure with good ductility and high crystallinity is obtained as wet milling precursors,via precisely controlling dry milling time.Then,HEAs are flattened to improve aspect ratios by synergistically regulating wet milling time.FeCoNiCr_(0.4)Cu_(0.2) HEAs with dry milling 20 h and wet milling 5 h(D20)exhibit higher and more stable permeability because of larger aspect ratios and thinner intergranular amorphous layers.The maximum reflection loss(RL)of D20/SiO_(2) composites is greater than-7 dB with 5 mm thickness,and EMW absorption bandwidth(RL<-7 dB)can maintain between 523 and 600 MHz from-50 to 150℃.Furthermore,relying on the“cocktail effect”of HEAs,D20 sample also exhibits excellent corrosion resistance and high Curie temperature.This work provides a facile and tunable strategy to design MHz electromagnetic absorbers with temperature stability,broadband,and resistance to harsh environments.展开更多
In the multistage reliability growth tests with instant and delayed fix modes, the failure data can be assumed to follow Weibull processes with different parameters at different stages. For the Weibull process within ...In the multistage reliability growth tests with instant and delayed fix modes, the failure data can be assumed to follow Weibull processes with different parameters at different stages. For the Weibull process within a stage, by the proper selection of prior distribution form and the parameters, a concise posterior distribution form is obtained, thus simplifying the Bayesian analysis. In the multistage tests, the improvement factor is used to convert the posterior of one stage to the prior of the subsequent stage. The conversion criterion is carefully analyzed to determine the distribution parameters of the subsequent stage's variable reasonably. Based on the mentioned results, a new synthetic Bayesian evaluation program and algorithm framework is put forward to evaluate the multistage reliability growth tests with instant and delayed fix modes. The example shows the effectiveness and flexibility of this method.展开更多
Interests in charcoal usage have recently been re-ignited because it is believed that charcoal is a muchbetter fuel than wood. The conventional charcoal production consumes a large amount of energy due to the prolonge...Interests in charcoal usage have recently been re-ignited because it is believed that charcoal is a muchbetter fuel than wood. The conventional charcoal production consumes a large amount of energy due to the prolonged heating time and cooling time which contribute to the process completing in one to several days. Wood py-rolysis consists of both endothermic and exothermic reactions as well as the decomposition of the different components at different temperature range (hemicellulose: 200-260℃; cellulose: 240-350℃ and lignin: 280-500℃). Inthis study we propose a multistagepyrolysis which is an approach to carry out pyrolysis with multiple heating stages so as to gain certain processing benefits. We propose a three-stage approach which includes rapid stepwise heating stage to a variable target temperatures of 250 ℃, 300℃, 350 ℃ and 400 ℃, slow and gradual heatingstage to a tinal temperature of 400℃ and adiabatic with cooling stage. The multi-stage pyrolysis process can save 30% energy and the processing time by using a first temperature target of 300 ℃and heating rate of 5℃.min-1 to produce a fixed-carbon yield of 25.73% as opposed to the base case with a fixed-carbon yield of23.18%.展开更多
Large quadruped mammals,such as ruminants,have outstanding motion ability,including running and bounding.These advanced motion abilities are related to the buffer effect of their complicated musculoskeletal systems.Ho...Large quadruped mammals,such as ruminants,have outstanding motion ability,including running and bounding.These advanced motion abilities are related to the buffer effect of their complicated musculoskeletal systems.However,the buffer effect of most bio-robots is not satisfactory owing to the simple design of their buffer systems.In this paper,a physiological analysis of the ruminant musculoskeletal system is presented to explain the intrinsic buffer mechanism of motion.Based on the physical buffer parts of the ruminant limbs,the corresponding bionic mappings were determined.These mappings were used to guide the mechanism design of the robot multistage buffer system.The multistage buffer system includes two main buffer mechanisms:the first stage and the second stage.The buffer mechanism analysis of the first stage and multiple stages is discussed in theory to compare the effects between the normal single buffer system and the novel multistage buffer system.Then,the detailed mechanical structure of the limbs was designed based on the limb mechanism design.To further verify the superior efficacy of the multistage buffer system,the corresponding walking simulation experiments were conducted after the virtual prototype of a quadruped robot with a novel limb was built completely.Both theoretical analysis and simulation experiments prove that the bionic robot design with the novel multistage buffer system achieves better motion performance than the traditional robot buffer design and can be regarded as the design template of the robot limb.展开更多
The volumetric overall mass transfer coefficients in a multistage column have been measured using axial dispersion model for toluene–acetone–water system. The effect of operating parameters on the volumetric overall...The volumetric overall mass transfer coefficients in a multistage column have been measured using axial dispersion model for toluene–acetone–water system. The effect of operating parameters on the volumetric overall mass transfer coefficients has been investigated for both mass transfer directions. The results show that the mass transfer performance is strongly dependent on rotor speed and mass transfer direction, although only slightly dependent on phase flow rates. In addition, empirical correlations to predict the overall mass transfer coefficients have been developed. The proposed correlations based on dimensionless numbers can be considered as a useful tool for the possible scale up of the multistage column extractor.展开更多
In previous studies,a theoretical model was developed after Acoustic Resonance(AR)was experimentally detected in a four-stage compressor,and AR inception was proposed to be triggered by an unknown sound source,which i...In previous studies,a theoretical model was developed after Acoustic Resonance(AR)was experimentally detected in a four-stage compressor,and AR inception was proposed to be triggered by an unknown sound source,which is a pressure perturbation of a specific frequency with a suitable circumferential propagation speed.The present paper,which is not dedicated to the simulation of acoustic field,aims to identify the specific sound source generated by the unsteady tip leakage flow using the unsteady Computational Fluid Mechanics(CFD)approach.After a comprehensive analysis of an Unsteady Reynolds Averaged Navier-Stokes(URANS)simulation,a pressure perturbation of non-integer multiple of rotor frequency is found at the blade tip.Since the essence of the tip leakage flow is a jet flow driven by the pressure difference between two sides of blade,a simplified tip leakage flow model is adopted using Large Eddy Simulation(LES)in order to simulate the jet flow through a tip clearance.It is found that the convection velocity of shedding vortices fits the expected propagation speed of the sound source,the frequency is also close to one of the dominating frequencies in the URANS simulation,and the resultant combination frequency coincides with the experimentally measured AR frequency.Since such a simplified model successfully captures the key physical mechanisms,it is concluded that this paper provides a piece of unambiguous evidence on the role of unsteady tip leakage vortex in triggering the AR inception of the multistage compressor.展开更多
A pilot-scale multistage constructed wetland-pond(MCWP)system with a"pre-ecological oxidation pond,two-stage horizontal subsurface flow constructed wetland(HSCW)and surface flow constructed wetland(SFCW)as the co...A pilot-scale multistage constructed wetland-pond(MCWP)system with a"pre-ecological oxidation pond,two-stage horizontal subsurface flow constructed wetland(HSCW)and surface flow constructed wetland(SFCW)as the core and postsubmerged plant pond"as the process was used to treat actual polluted river water in the field,and the variation in nitrogen removal from summer to winter was investigated.The results showed that the average total nitrogen(TN)removal efficiency in the MCWP was approximately 40.74%.The significant positive correlation between the daily highest temperature and the TN removal efficiency of the whole system was fitted with a nonlinear curve(R^(2)=0.7192).The TN removal load rate in the HSCWs was 2.7–3.7 times that in the SFCW.The SFCW,which had high-density plants(35 plants/m^(2)),increased the proportion of nitrogen removed by plant harvesting and microbial function.The TN transformed by Iris pseudacorus L.accounted for 54.53%in the SFCW.Furthermore,bacteria completed the nitrogen cycle in the SFCW through a variety of nitrogen removal pathways.This research not only investigated the TN removal performance in an MCWP system but also made it possible to predict the TN removal efficiency according to the daily highest temperature from summer to winter in the field.展开更多
Meso-Cenozoic intracontinental orogenic processes in the Tian Shan orogenic belt have significant effect on the sandstone-hosted uranium deposits in the intramontane basins and those adjacent to the orogen. The Sawafu...Meso-Cenozoic intracontinental orogenic processes in the Tian Shan orogenic belt have significant effect on the sandstone-hosted uranium deposits in the intramontane basins and those adjacent to the orogen. The Sawafuqi uranium deposit, which is located in the South Tian Shan orogenic belt, is investigated to reveal the relationships between uranium mineralization and orogenies. Recent exploration results show that the Sawafuqi uranium deposit has tabular, stratiform, quasi-stratiform, and lens-like orebodies and various geological characteristics different from typical interlayer oxidation zone sandstone-hosted uranium deposits. Systematic studies of ore samples from the Sawafuqi uranium deposit using a variety of techniques, including thin section observation, a-track radiograph, electron microprobe and scanning electron microscope, suggest that uranium mineralization is closely related to pyrite and organic matter. Mineralization-related alterations in the host rocks are mainly silicification and argillation including kaolinite, illite (and illite-smectite mixed layer) and chlorite. Tree stages of mineralization were identified in the Sawafuqi uranium deposit: (i) uranium-bearing detritus and synsedimentary initial pre-enrichment; (ii) interlayer oxidization zone uranium mineralization; and (iii) vein-type uranium mineralization. The synsedimentary uranium pre-enrichment represents an early uranium enrichment in the Sawafuqi uranium deposit, and interlayer oxidation zone uranium mineralization formed the main orebodies, which are superimposed by the vein-type uranium mineralization. Combining the results of this study with previous studies on the Meso-Cenozoic orogenies of South Tian Shan, it is proposed that the synsedimentary uranium pre-enrichment of the Sawafuqi uranium deposit was caused by Triassic Tian Shan uplift, and the interlayer oxidation zone uranium mineralization occurred during the Eocence-Oligocene period, when tectonism was relatively quiet, whereas the vein-type uranium mineralization took place in relation to the strong orogeny of South Tian Shan since Miocene.展开更多
To achieve the secondary production in multistage fracturing wells of tight oil,milling tools are usually used to remove the multistage fracturing ball seats to achieve production with a large diameter in later.In thi...To achieve the secondary production in multistage fracturing wells of tight oil,milling tools are usually used to remove the multistage fracturing ball seats to achieve production with a large diameter in later.In this paper,first of all,the working mechanism of milling tools for multistage fracturing ball seats was studied and a mechanical analysis model of single abrasive grain was established.Then,an experimental system for milling tools was developed,and the experimental tests of the flat,the blade,and the slope milling tool were conducted in order.Besides,the morphology of chips and the surface morphology of the workpiece after the experiment were analyzed.Also,the working performance of milling tools was evaluated from the perspectives of working safety,working efficiency,and wear resistance of the milling tool.The results show that the torque of the milling tool increases nonlinearly with the increase in the cutting depth of the abrasive grain and increases linearly with the increase in the cutting width.Also,the chips are irregular particles and the size is mainly from 10 to 50μm.So,the chips should be pumped up with a small pump pressure and a large displacement.Besides this,the cutting depths of the abrasive grains are from 216.20 to 635.47μm and the bottom surface of the milling tool should be eccentric to avoid the zero point of cutting speed.Furthermore,the torque of the slope milling tool is 23.8%larger than that of the flat milling tool,which is also 30.4%smaller than that of the blade milling tool.Compared with the flat milling tool,the working efficiency of the blade milling tool improves by 79.9%and the slope milling tool improves by 111.1%.Also,the wear resistance of the blade milling tool decreases by 102.7%,while the slope milling tool declines by 32.6%when compared with the flat milling tool.Therefore,the slope milling tool has the characteristics of moderate torque,stable working conditions,the highest working efficiency,and fine wear resistance,which is preferably used to mill multistage fracturing ball seats.This study provides a theoretical basis and guidance for milling multistage fracturing ball seats on-site and realizing production with a large diameter in later stages of multistage fracturing wells.展开更多
The Central Asian Orogenic Belt,as one of world-class gold economic belts,preserves a number of giant,large black shale-hosted gold deposits,while it is still debated for origin of sulfides and gold mainly due to lack...The Central Asian Orogenic Belt,as one of world-class gold economic belts,preserves a number of giant,large black shale-hosted gold deposits,while it is still debated for origin of sulfides and gold mainly due to lack of identification for multiple stages of sulfides.The Haoyaoerhudong gold deposit is hosted in a sequence of Mesoproterozoic carbonaceous and pyritic slate,phyllite,and schist that form a tight syncline along the north margin of the North China Craton.Detailed petrography of the host rocks and mineralization have defined five stages of pyrites.The earliest form of pyrite(Py_(1))occurs as fine-grained dispersed pyrite in black carbonaceous slate and medium-to coarse-grained disseminated pyrite in pyrite-rich layers,contains relative low gold and high arsenic content,indicating a syn-sedimentary or diagenetic in origin.Stage Ⅱ pyrite(Py_(2))occurs with garnet and quartz inclusions and Py_(3) occurs as pyrite veins,contains higher gold and lower As content,and are interpreted to have formed from the dissolution-reprecipitation of Py_(1) during the peak metamorphism or post-peak metamorphism.Stage Ⅳ pyrite(Py_(4))from the pyrite-quartz veins crosscut the metamorphic garnet,contains the highest gold concentrations and other trace elements,and is considered to have formed post-peak metamorphism.Abundant native gold,electrum,and maldonite occur as inclusions within Py_(4) and monazite and in fractures that crosscut garnet.While,Py_(5) with typical remobilized feature is thought to be a product of melting of former pyrites(Py_(1) to Py_(4))triggered by the large-scale Hercynian magmatism.The sedimentary/diagenetic Py_(1) have δ^(34)S values that range from +12.4‰to +16.2‰.Later generations of sulfides,including Py_(2) to Py_(5),and Ccp_(2) to Ccp_(3),have δ^(34)S values from +9.5‰to +12.7‰.Monazite with maldonite inclusions from quartz-pyrite veins yielded an intercept age of 341.3±6.6 Ma,while coarse grained monazite associated biotite along fractures in the reefs yielded an intercept age of 254.6±8.2 Ma.The paragenetic,textural,chemical,and isotopic data suggest three distinct gold producing episodes at Haoyaoerhudong gold deposit.Gold and arsenic were clearly initially concentrated in organic muds,and enriched along the structures of diagenetic arsenic-rich pyrite.Subsequently,accompanying metamorphism and deformation,gold was liberated from the dissolution of diagenetic pyrites to form the pyrite veins.Finally,accompanying transformation of pyrite into pyrrhotite,gold was released into the metamorphic fluids to become concentrated as native gold,electrum,and maldonite in pyrite-quart veins.Monazite with age of 341 Ma from quartz-pyrite veins suggests that the third major gold mineralizing event in Haoyaoerhudong occurred before the Hercynian magmatism,suggesting that the Haoyaoerhudong deposit is a typical orogenic gold deposit rather than intrusion-related deposit.展开更多
基金Scientific and Technological Project of Nanyang(23KJGG017)Key Specialized Research&Development and Promotion Project(Scientific and Technological Project)of Henan Province(232102221022)+1 种基金College Students and Technology Innovation Fund Project of Nanyang Institute of Technology(2023139)Project of Doctoral Scientific Research Startup Fund of Nanyang Institute of Technology(NGBJ-2023-25)。
文摘The leaching process of magnesiothermic self-propagating product generated during the multistage deep reduction process was investigated.The influence of magnesiothermic self-propagating product particle size,HCl solution concentration,and leaching solution temperature on the leaching behavior of elements Al and V was investigated.Results demonstrate that the leaching rate of Al and V is increased with the rise in leaching solution temperature,the increase in HCl solution concentration,and the enlargement of magnesiothermic self-propagating product particle size.The leaching processes of Al and V are consistent with the chemical reaction control model.When the magnesiothermic self-propagation product with D_(50) of 59.4μm is selected as the raw material,the leaching temperature is 40℃,and 1 mol/L HCl solution is employed,after leaching for 180 min,the leaching rates of Al and V are 24.8%and 12.6%,respectively.The acid-leached product exhibits a porous structure with a specific surface area of 3.5633 m^(2)/g.
基金Supported by the Key projects of the PetroChina Joint Fund Under the National Natural Science Foundation of China(U23B20154,92255302)Science and Technology Cooperation Project of the Innovation Consortium between PetroChina and Southwest Petroleum University(2020CX010000)Open Fund of the Key Laboratory of Carbonate Reservoirs,China National Petroleum Corporation(RIPED-2024-JS-1804).
文摘This study reconstructed the paleo-uplift and depression pattern within the sequence stratigraphic framework of the Mid-Permian Maokou Formation,Sichuan Basin,investigated its tectono-sedimentary mechanisms and its control on paleogeomorphology and large-sale shoals based on analysis of outcrops,loggings and seismic data.The results show that the Maokou Formation comprises two third-order sequences,six fourth-order sequences(SSQ1-SSQ6),and four distinct slope-break zones developing progressively from north to south.Slope-break zones I-III in the northern basin,controlled by synsedimentary extensional faults,exhibited a NE-trending linear distribution with gradual southeastward migration.In contrast,slope-break zone IV in the southern basin displayed an arcuate distribution along the Emeishan Large Igneous Province(ELIP).The evolutions of these multistage slope-break zones governed the Mid-Permian paleogeomorphy in the Sichuan Basin transformations from a giant,north-dipping gentle slope(higher in the southwest than in the northeast)in the early-stage(SSQ1-SSQ2)to a platform(south)-basin(north)pattern in the middle-stage(SSQ3-SSQ5).Ultimately,a further depression zone developed in the southwestern basin during the late-stage(SSQ6),forming a paleo-uplift bounded by two depressions.The developments of the Mid-Permian paleogeomorphic configuration reflected the combined control by the rapid subduction of the Mianlüe Ocean and the episodic eruptions of the Emeishan mantle plume(or hot spots),which jointly facilitated the formation of extensive high-energy shoal facies belts along slope-break zones and around paleo-volcanic uplifts.
基金supported by the Major Science and Technology Project(Nos.CNOOC-KJ 135 ZDXM 38 ZJ 01 ZJ,KJGG2021-0505) of CNOOC Co.,Ltd.of Chinathe National Natural Science Foundation of China(No.42002171)+2 种基金China Postdoctoral Science Foundation(Nos.2020TQ0299,2020M682520)Postdoctoral Innovation Science Foundation of Hubei Province of ChinaScientific Research Project of Zhanjiang Branch of CNOOC(No.ZYKY-2022-ZJ-02)。
文摘To investigate the relationship between grain sizes, seepage capacity, and oil-displacement efficiency in the Liushagang Formation of the Beibuwan Basin, this study identifies the multistage pore-throat structure as a crucial factor through a comparison of oil displacement in microscopic pore-throat experiments. The two-phase flow evaluation method based on the Li-Horne model is utilized to effectively characterize and quantify the seepage characteristics of different reservoirs, closely relating them to the distribution of microscopic pores and throats. It is observed that conglomerate sandstones at different stages exhibit significant heterogeneity and noticeable differences in seepage capacity, highlighting the crucial role played by certain large pore throats in determining seepage capacity and oil displacement efficiency. Furthermore, it was found that the displacement effects of conglomeratic sandstones with strong heterogeneity were inferior to those of conventional homogeneous sandstone, as evidenced by multiple displacement experiments conducted on core samples with varying granularities and flooding systems. Subsequently, core-based experiments on associated gas flooding after water flooding were conducted to address the challenge of achieving satisfactory results in a single displacement mode for reservoirs with significant heterogeneity. The results indicate that the oil recovery rates for associated gas flooding after water flooding increased by 7.3%-16.4% compared with water flooding alone at a gas-oil ratio of approximately 7000 m^(3)/m^(3). Therefore, considering the advantages of gas flooding in terms of seepage capacity, oil exchange ratio, and the potential for two-phase production, gas flooding is recommended as an energy supplement mode for homogeneous reservoirs in the presence of sufficient gas source and appropriate tectonic angle. On the other hand, associated gas flooding after water flooding is suggested to achieve a more favorable development effect compared to a single mode of energy supplementation for strongly heterogeneous sandstone reservoirs.
基金supported by the National Key R&D Program of China(2020YFC2003102).
文摘Objective:To reveal the distribution characteristics and demographic factors of traditional Chinese medicine(TCM)constitution among elderly individuals in China.Methods: Elderly individuals from seven regions in China were selected as samples in this study using a multistage cluster random sampling method.The basic information questionnaire and Constitution in Chinese Medicine Questionnaire(Elderly Edition)were used.Descriptive statistical analysis,chi-squared tests,and binary logistic regression analysis were used.Results: The single balanced constitution(BC)accounted for 23.9%.The results of the major TCM constitution types showed that BC(43.2%)accounted for the largest proportion and unbalanced constitutions ranged from 0.9%to 15.7%.East China region(odds ratio[OR]=2.097;95%confidence interval[CI],1.912 to 2.301),married status(OR=1.341;95%CI,1.235 to 1.457),and managers(OR=1.254;95%CI,1.044 to 1.505)were significantly associated with BC.Age>70 years was associated with qi-deficiency constitution and blood stasis constitution(BSC).Female sex was significantly associated with yang-deficiency constitution(OR=1.646;95%CI,1.52 to 1.782).Southwest region was significantly associated with phlegm-dampness constitution(OR=1.809;95%CI,1.569 to 2.086).North China region was significantly associated with inherited special constitution(OR=2.521;95%CI,1.569 to 4.05).South China region(OR=2.741;95%CI,1.997 to 1.3.763),Central China region(OR=8.889;95%CI,6.676 to 11.835),senior middle school education(OR=2.442;95%CI,1.932 to 3.088),and managers(OR=1.804;95%CI,1.21 to 2.69)were significantly associated with BSC.Conclusions: This study defined the distribution characteristics and demographic factors of TCM constitution in the elderly population.Adjusting and improving unbalanced constitutions,which are correlated with diseases,can help promote healthy aging through the scientific management of these demographic factors.
基金financial support for this work provided by the National Natural Science Foundation of China(Nos.52274147,52374101,and 32111530138)the Jiangsu Province Basic Research Special Fund-Soft Science Research(No.BZ2024024)the State Key Research Development Program of China(No.2022YFC3004603).
文摘Multistage hydraulic fracturing of horizontal wells(MFHW)is a promising technology for controlling coal burst caused by thick and hard roofs in China.However,challenges remain regarding the MFHW control mechanism of coal burst and assessment of the associated fracturing effects.In this study,these challenges were investigated through numerical modelling and field applications,based on the actual operating parameters of MFHW for hard roofs in a Chinese coal mine.A damage parameter(D)is proposed to assess the degree of hydraulic fracturing in the roof.The mechanisms and effects of MFHW for controlling coal burst are analyzed using microseismic(MS)data and front-abutment stress distribution.Results show that the degree of fracturing can be categorized into lightly-fractured(D≤0.3),moderately fractured(0.3<D≤0.6),well-fractured(0.6<D≤0.9),and over-fractured(0.9<D≤0.95).A response stage in the fracturing process,characterized by a slowdown in crack development,indicates the transition to a wellfractured condition.After MFHW,the zone range and peak value of the front-abutment stress decrease.Additionally,MS events shift from near the coal seam to the fractured roof layers,with the number of MS events increases while the average MS energy decreases.The MFHW control mechanisms of coal bursts involve mitigating mining-induced stress and reducing seismic activity during longwall retreat,ensuring stresses remain below the ultimate stress level.These findings provide a reference for evaluating MFHW fracturing effects and controlling coal burst disasters in engineering.
文摘Blasting operations,which are crucial to open-pit mine production due to their simplicity and efficiency,require precise control through accurate vibration velocity calculations.The conventional Sadowski formula mainly focuses on blast center distance but neglects the amplification effect of blasting vibration waves by terraced terrain,from which the calculated blasting vibration velocities are smaller than the actual values,affecting the safety of the project.To address this issue,our model introduces the influences of slope and time into Sadowski formula to measure safety through blast vibration displacement.In the northern section of the open-pit quartz mine in Jinchang City,Gansu Province,China,the data of a continuous blasting slope project are referred to.Our findings reveal a noticeable vibration amplification effect during blasting when a multi-stage slope platform undergoes a sudden cross-sectional change near the upper overhanging surface.The amplification vibration coefficient increases with height,while vibration waves within rocks decrease from bottom to top.Conversely,platforms without distinct crosssectional changes exhibit no pronounced amplification during blasting.In addition,the vibration intensity decreases with distance as the rock height difference change propagates.The results obtained by the proposed blast vibration displacement equation incorporating slope shape influence closely agree with real-world scenarios.According to Pearson correlation coefficient(PPMCC)analysis,the average accuracy rate of our model is 88.84%,which exceeds the conventional Sadowski formula(46.92%).
文摘The current portfolio model for property-liability insurance company is only single period that can not meet the practical demands of portfolio management, and the purpose of this paper is to develop a multiperiod model for its portfolio problem. The model is a multistage stochastic programming which considers transaction costs, cash flow between time periods, and the matching of asset and liability; it does not depend on the assumption for normality of return distribution. Additionally, an investment constraint is added. The numerical example manifests that the multiperiod model can more effectively assist the property-liability insurer to determine the optimal composition of insurance and investment portfolio and outperforms the single period one.
基金financially supported by the Technology Program of Henan Province(No.202102210207)the National Key Research and Development Plan(No.2017YFB0305401)+2 种基金the National Natural Science Foundation of China(Nos.51422403 and 51774078)the Fundamental Research Funds for the Central Universities(Nos.N162505002,N172506009 and N170908001)the Key Science and Shenyang Science and Technology Project(No.17-500-8-01)。
文摘High ferrotitanium is used as a deoxidizer and alloying agent in steelmaking processes and is mainly produced using high-cost remelting processes.The thermite method is a simple and low-cost method for preparing low ferrotitanium.However,the high levels of S,Al,and O residues in the product severely restrict its applicability in the low-cost preparation of good-quality high ferrotitanium.In this study,a novel multistage deep reduction method for preparing high-quality high ferrotitanium is proposed,and the multistage desulfurization mechanism is systematically investigated.The results indicate that multistage desulfurization is an effective method for reducing the S content of high ferrotitanium prepared via the thermite method.During the strong desulfurization stage,Ti_(2)S reacts with CaO at the slag-metal interface and produces CaS.The S content decreases,while the O content increases,with the increase of CaO in the CaO-Al_(2)O_(3)-based slag.During the deep desulfurization,Ti_(2)S is deeply reduced by the Ca and produces CaS,thus further reducing the S content.The S content decreases with the incremental addition of Ca and can be reduced to 0.035 wt%after multistage desulfurization.
文摘Abstract There are two extensional systems in the Xiaoqinling metamorphic core complex (XMCC). One is the detachment fault system developed along the peripheries of the XMCC, which extended in an ESE-WNW direction and whose upper plate moved towards the WNW. The other extensional system includes the retrograde shear zones and normal faults developed within the XMCC, which represent the collapse of the XMCC. Ar-Ar and K-Ar dating shows that the extension of the detachment fault system continued from 135 to 123 Ma, i.e. in the late stage of its evolution at about 127 Ma. The collapse represented by the extensional system within the XMCC was operative during 120–106 Ma, and its main activity occurred about 116 Ma ago. These suggest that the XMCC experienced two extensional stages in its evolution, i.e., the syn-orogenic regional extension and post-orogenic collapse extension.
基金co-supported by the National Natural Science Foundation of China(Nos.51576009,11661141020 and 51711530036)the Aeronautical Science Foundation of China(No.20151554002)。
文摘Rotor blades fault of aeroengine compressor is mostly caused by mechanical and aerodynamic excitation.And the excitation factor of high intensity sound wave to rotor blades should not be ignored.Experimental researches are conducted on a multistage high pressure compressor.When high level vibration occurs on the first stage of rotor blades, the noise spectrum presents typical characteristic for discrete multi-tone in the compressor.The amplitude of blade vibration displacement and the sound pressure level of characteristic frequency noise increases and decreases simultaneously and reaches the maximum value at the same time.This frequency merely occur on a certain speed range and is locked in a specific range which presents no variation with the rotating speed.When high level vibration occurs on the first stage of rotor blades, the noise spectrum presents a sharp peak and the propagation state of the characteristic frequency is a helix structure in the compressor.It can be confirmed that acoustic resonance occurs in the multistage compressor.The acoustic resonance frequency and its side band frequencies are generated by modulation of a rotating noise source at the rotor speed which is the excitation source of the rotor blades vibration.
基金the Supported by Program for the National Natural Science Foundation of China(No.52071053,U1704253,52103334)China Postdoctoral Science Foundation(2020M670748,2020M680946)the Fundamental Research Funds for the Central Universities(DUT20GF111).
文摘Developing megahertz(MHz)electromagnetic wave(EMW)absorption materials with broadband absorption,multi-temperature adaptability,and facile preparation method remains a challenge.Herein,nanocrystalline FeCoNiCr_(0.4)Cu_(0.2) high-entropy alloy powders(HEAs)with both large aspect ratios and thin intergranular amorphous layers are constructed by a multistage mechanical alloying strategy,aiming to achieve excellent and temperature-stable permeability and EMW absorption.A single-phase face-centered cubic structure with good ductility and high crystallinity is obtained as wet milling precursors,via precisely controlling dry milling time.Then,HEAs are flattened to improve aspect ratios by synergistically regulating wet milling time.FeCoNiCr_(0.4)Cu_(0.2) HEAs with dry milling 20 h and wet milling 5 h(D20)exhibit higher and more stable permeability because of larger aspect ratios and thinner intergranular amorphous layers.The maximum reflection loss(RL)of D20/SiO_(2) composites is greater than-7 dB with 5 mm thickness,and EMW absorption bandwidth(RL<-7 dB)can maintain between 523 and 600 MHz from-50 to 150℃.Furthermore,relying on the“cocktail effect”of HEAs,D20 sample also exhibits excellent corrosion resistance and high Curie temperature.This work provides a facile and tunable strategy to design MHz electromagnetic absorbers with temperature stability,broadband,and resistance to harsh environments.
基金supported by Pre-research Foundation of General Armament Department of China(xxxxxxxxxxxx06KG0164)and the National Doctoral Foundation of China (2005999807).
文摘In the multistage reliability growth tests with instant and delayed fix modes, the failure data can be assumed to follow Weibull processes with different parameters at different stages. For the Weibull process within a stage, by the proper selection of prior distribution form and the parameters, a concise posterior distribution form is obtained, thus simplifying the Bayesian analysis. In the multistage tests, the improvement factor is used to convert the posterior of one stage to the prior of the subsequent stage. The conversion criterion is carefully analyzed to determine the distribution parameters of the subsequent stage's variable reasonably. Based on the mentioned results, a new synthetic Bayesian evaluation program and algorithm framework is put forward to evaluate the multistage reliability growth tests with instant and delayed fix modes. The example shows the effectiveness and flexibility of this method.
基金Supported by the Hong Kong RGC in form of PhD Fellowship to Adetoyese Olajire Oyedun(PF09-05997)
文摘Interests in charcoal usage have recently been re-ignited because it is believed that charcoal is a muchbetter fuel than wood. The conventional charcoal production consumes a large amount of energy due to the prolonged heating time and cooling time which contribute to the process completing in one to several days. Wood py-rolysis consists of both endothermic and exothermic reactions as well as the decomposition of the different components at different temperature range (hemicellulose: 200-260℃; cellulose: 240-350℃ and lignin: 280-500℃). Inthis study we propose a multistagepyrolysis which is an approach to carry out pyrolysis with multiple heating stages so as to gain certain processing benefits. We propose a three-stage approach which includes rapid stepwise heating stage to a variable target temperatures of 250 ℃, 300℃, 350 ℃ and 400 ℃, slow and gradual heatingstage to a tinal temperature of 400℃ and adiabatic with cooling stage. The multi-stage pyrolysis process can save 30% energy and the processing time by using a first temperature target of 300 ℃and heating rate of 5℃.min-1 to produce a fixed-carbon yield of 25.73% as opposed to the base case with a fixed-carbon yield of23.18%.
基金Supported by the National Key Research and Development Program of China(Grant No.2019YFB1309600)the National Natural Science Foundation of China(Grant Nos.51775011&91748201).
文摘Large quadruped mammals,such as ruminants,have outstanding motion ability,including running and bounding.These advanced motion abilities are related to the buffer effect of their complicated musculoskeletal systems.However,the buffer effect of most bio-robots is not satisfactory owing to the simple design of their buffer systems.In this paper,a physiological analysis of the ruminant musculoskeletal system is presented to explain the intrinsic buffer mechanism of motion.Based on the physical buffer parts of the ruminant limbs,the corresponding bionic mappings were determined.These mappings were used to guide the mechanism design of the robot multistage buffer system.The multistage buffer system includes two main buffer mechanisms:the first stage and the second stage.The buffer mechanism analysis of the first stage and multiple stages is discussed in theory to compare the effects between the normal single buffer system and the novel multistage buffer system.Then,the detailed mechanical structure of the limbs was designed based on the limb mechanism design.To further verify the superior efficacy of the multistage buffer system,the corresponding walking simulation experiments were conducted after the virtual prototype of a quadruped robot with a novel limb was built completely.Both theoretical analysis and simulation experiments prove that the bionic robot design with the novel multistage buffer system achieves better motion performance than the traditional robot buffer design and can be regarded as the design template of the robot limb.
文摘The volumetric overall mass transfer coefficients in a multistage column have been measured using axial dispersion model for toluene–acetone–water system. The effect of operating parameters on the volumetric overall mass transfer coefficients has been investigated for both mass transfer directions. The results show that the mass transfer performance is strongly dependent on rotor speed and mass transfer direction, although only slightly dependent on phase flow rates. In addition, empirical correlations to predict the overall mass transfer coefficients have been developed. The proposed correlations based on dimensionless numbers can be considered as a useful tool for the possible scale up of the multistage column extractor.
基金the National Natural Science Foundation of China(Nos.51976116 and 51976125)the Natural Science Fund of Shanghai,China(No.19ZR1425900)+1 种基金the Open Research Subject of Key Laboratory(Fluid Machinery and Engineering Research Base)of Sichuan Province,China(No.szjj2019-022)Alexander von Humboldt Foundation.
文摘In previous studies,a theoretical model was developed after Acoustic Resonance(AR)was experimentally detected in a four-stage compressor,and AR inception was proposed to be triggered by an unknown sound source,which is a pressure perturbation of a specific frequency with a suitable circumferential propagation speed.The present paper,which is not dedicated to the simulation of acoustic field,aims to identify the specific sound source generated by the unsteady tip leakage flow using the unsteady Computational Fluid Mechanics(CFD)approach.After a comprehensive analysis of an Unsteady Reynolds Averaged Navier-Stokes(URANS)simulation,a pressure perturbation of non-integer multiple of rotor frequency is found at the blade tip.Since the essence of the tip leakage flow is a jet flow driven by the pressure difference between two sides of blade,a simplified tip leakage flow model is adopted using Large Eddy Simulation(LES)in order to simulate the jet flow through a tip clearance.It is found that the convection velocity of shedding vortices fits the expected propagation speed of the sound source,the frequency is also close to one of the dominating frequencies in the URANS simulation,and the resultant combination frequency coincides with the experimentally measured AR frequency.Since such a simplified model successfully captures the key physical mechanisms,it is concluded that this paper provides a piece of unambiguous evidence on the role of unsteady tip leakage vortex in triggering the AR inception of the multistage compressor.
基金supported bythe Ministry of Science and Technology of China(No.2015FY110900)the National Natural Science Foundation of China(No.41877409)the Major Science and Technology Program for Water Pollution Control and Treatment of China(No.2018ZX07208008)。
文摘A pilot-scale multistage constructed wetland-pond(MCWP)system with a"pre-ecological oxidation pond,two-stage horizontal subsurface flow constructed wetland(HSCW)and surface flow constructed wetland(SFCW)as the core and postsubmerged plant pond"as the process was used to treat actual polluted river water in the field,and the variation in nitrogen removal from summer to winter was investigated.The results showed that the average total nitrogen(TN)removal efficiency in the MCWP was approximately 40.74%.The significant positive correlation between the daily highest temperature and the TN removal efficiency of the whole system was fitted with a nonlinear curve(R^(2)=0.7192).The TN removal load rate in the HSCWs was 2.7–3.7 times that in the SFCW.The SFCW,which had high-density plants(35 plants/m^(2)),increased the proportion of nitrogen removed by plant harvesting and microbial function.The TN transformed by Iris pseudacorus L.accounted for 54.53%in the SFCW.Furthermore,bacteria completed the nitrogen cycle in the SFCW through a variety of nitrogen removal pathways.This research not only investigated the TN removal performance in an MCWP system but also made it possible to predict the TN removal efficiency according to the daily highest temperature from summer to winter in the field.
基金supported by the National Key Basic Research Program of China (No.2015CB453004)National Pre-research Project (No.3210402)
文摘Meso-Cenozoic intracontinental orogenic processes in the Tian Shan orogenic belt have significant effect on the sandstone-hosted uranium deposits in the intramontane basins and those adjacent to the orogen. The Sawafuqi uranium deposit, which is located in the South Tian Shan orogenic belt, is investigated to reveal the relationships between uranium mineralization and orogenies. Recent exploration results show that the Sawafuqi uranium deposit has tabular, stratiform, quasi-stratiform, and lens-like orebodies and various geological characteristics different from typical interlayer oxidation zone sandstone-hosted uranium deposits. Systematic studies of ore samples from the Sawafuqi uranium deposit using a variety of techniques, including thin section observation, a-track radiograph, electron microprobe and scanning electron microscope, suggest that uranium mineralization is closely related to pyrite and organic matter. Mineralization-related alterations in the host rocks are mainly silicification and argillation including kaolinite, illite (and illite-smectite mixed layer) and chlorite. Tree stages of mineralization were identified in the Sawafuqi uranium deposit: (i) uranium-bearing detritus and synsedimentary initial pre-enrichment; (ii) interlayer oxidization zone uranium mineralization; and (iii) vein-type uranium mineralization. The synsedimentary uranium pre-enrichment represents an early uranium enrichment in the Sawafuqi uranium deposit, and interlayer oxidation zone uranium mineralization formed the main orebodies, which are superimposed by the vein-type uranium mineralization. Combining the results of this study with previous studies on the Meso-Cenozoic orogenies of South Tian Shan, it is proposed that the synsedimentary uranium pre-enrichment of the Sawafuqi uranium deposit was caused by Triassic Tian Shan uplift, and the interlayer oxidation zone uranium mineralization occurred during the Eocence-Oligocene period, when tectonism was relatively quiet, whereas the vein-type uranium mineralization took place in relation to the strong orogeny of South Tian Shan since Miocene.
基金supported by the National Science and Technology Major Project under Grant Nos.2016ZX05042004 and 2017ZX05072the Joint Funds of the National Natural Science Foundation of China under Grant No.U1762104+2 种基金the Postgraduate Innovation Project Foundation under Grant No.YCX2019054the Fundamental Research Funds for the Central Universities under Grant No.20CX02306Athe Opening Fund of National Engineering Laboratory of Offshore Geophysical and Exploration Equipment。
文摘To achieve the secondary production in multistage fracturing wells of tight oil,milling tools are usually used to remove the multistage fracturing ball seats to achieve production with a large diameter in later.In this paper,first of all,the working mechanism of milling tools for multistage fracturing ball seats was studied and a mechanical analysis model of single abrasive grain was established.Then,an experimental system for milling tools was developed,and the experimental tests of the flat,the blade,and the slope milling tool were conducted in order.Besides,the morphology of chips and the surface morphology of the workpiece after the experiment were analyzed.Also,the working performance of milling tools was evaluated from the perspectives of working safety,working efficiency,and wear resistance of the milling tool.The results show that the torque of the milling tool increases nonlinearly with the increase in the cutting depth of the abrasive grain and increases linearly with the increase in the cutting width.Also,the chips are irregular particles and the size is mainly from 10 to 50μm.So,the chips should be pumped up with a small pump pressure and a large displacement.Besides this,the cutting depths of the abrasive grains are from 216.20 to 635.47μm and the bottom surface of the milling tool should be eccentric to avoid the zero point of cutting speed.Furthermore,the torque of the slope milling tool is 23.8%larger than that of the flat milling tool,which is also 30.4%smaller than that of the blade milling tool.Compared with the flat milling tool,the working efficiency of the blade milling tool improves by 79.9%and the slope milling tool improves by 111.1%.Also,the wear resistance of the blade milling tool decreases by 102.7%,while the slope milling tool declines by 32.6%when compared with the flat milling tool.Therefore,the slope milling tool has the characteristics of moderate torque,stable working conditions,the highest working efficiency,and fine wear resistance,which is preferably used to mill multistage fracturing ball seats.This study provides a theoretical basis and guidance for milling multistage fracturing ball seats on-site and realizing production with a large diameter in later stages of multistage fracturing wells.
基金the National Natural Science Foundation of China(Nos.41402042,41002064)Natural Sciences and Engineering Research Council of Canada Discovery Grant+1 种基金Fundamental Research Funds for the Central Universities(310827172006,300102278402)Geological Investigation Work Project of China Geological Survey(12120115069701).
文摘The Central Asian Orogenic Belt,as one of world-class gold economic belts,preserves a number of giant,large black shale-hosted gold deposits,while it is still debated for origin of sulfides and gold mainly due to lack of identification for multiple stages of sulfides.The Haoyaoerhudong gold deposit is hosted in a sequence of Mesoproterozoic carbonaceous and pyritic slate,phyllite,and schist that form a tight syncline along the north margin of the North China Craton.Detailed petrography of the host rocks and mineralization have defined five stages of pyrites.The earliest form of pyrite(Py_(1))occurs as fine-grained dispersed pyrite in black carbonaceous slate and medium-to coarse-grained disseminated pyrite in pyrite-rich layers,contains relative low gold and high arsenic content,indicating a syn-sedimentary or diagenetic in origin.Stage Ⅱ pyrite(Py_(2))occurs with garnet and quartz inclusions and Py_(3) occurs as pyrite veins,contains higher gold and lower As content,and are interpreted to have formed from the dissolution-reprecipitation of Py_(1) during the peak metamorphism or post-peak metamorphism.Stage Ⅳ pyrite(Py_(4))from the pyrite-quartz veins crosscut the metamorphic garnet,contains the highest gold concentrations and other trace elements,and is considered to have formed post-peak metamorphism.Abundant native gold,electrum,and maldonite occur as inclusions within Py_(4) and monazite and in fractures that crosscut garnet.While,Py_(5) with typical remobilized feature is thought to be a product of melting of former pyrites(Py_(1) to Py_(4))triggered by the large-scale Hercynian magmatism.The sedimentary/diagenetic Py_(1) have δ^(34)S values that range from +12.4‰to +16.2‰.Later generations of sulfides,including Py_(2) to Py_(5),and Ccp_(2) to Ccp_(3),have δ^(34)S values from +9.5‰to +12.7‰.Monazite with maldonite inclusions from quartz-pyrite veins yielded an intercept age of 341.3±6.6 Ma,while coarse grained monazite associated biotite along fractures in the reefs yielded an intercept age of 254.6±8.2 Ma.The paragenetic,textural,chemical,and isotopic data suggest three distinct gold producing episodes at Haoyaoerhudong gold deposit.Gold and arsenic were clearly initially concentrated in organic muds,and enriched along the structures of diagenetic arsenic-rich pyrite.Subsequently,accompanying metamorphism and deformation,gold was liberated from the dissolution of diagenetic pyrites to form the pyrite veins.Finally,accompanying transformation of pyrite into pyrrhotite,gold was released into the metamorphic fluids to become concentrated as native gold,electrum,and maldonite in pyrite-quart veins.Monazite with age of 341 Ma from quartz-pyrite veins suggests that the third major gold mineralizing event in Haoyaoerhudong occurred before the Hercynian magmatism,suggesting that the Haoyaoerhudong deposit is a typical orogenic gold deposit rather than intrusion-related deposit.