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Multiphasic characterization of a plant growth promoting bacterial strain, Burkholderia sp.7016 and its effect on tomato growth in the field 被引量:13
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作者 GAO Miao ZHOU Jian-jiao +3 位作者 WANG En-tao CHEN Qian XU Jing SUN Jian-guang 《Journal of Integrative Agriculture》 SCIE CAS CSCD 2015年第9期1855-1863,共9页
Aiming at searching for plant growth promoting rhizobacteria (PGPR), a bacterium strain coded as 7016 was isolated from soybean rhizosphere and was characterized in the present study. It was identiifed as Burkholderia... Aiming at searching for plant growth promoting rhizobacteria (PGPR), a bacterium strain coded as 7016 was isolated from soybean rhizosphere and was characterized in the present study. It was identiifed as Burkholderia sp. based on 16S rDNA sequence analysis, as wel as phenotypic and biochemical characterizations. This bacterium presented nitrogenase activity, 1-aminocyclopropane-1-carboxylic acid (ACC) deaminase activity and phosphate solubilizing ability;inhibited the growth of Sclerotinia sclerotiorum, Gibberel a zeae and Verticil ium dahliae;and produced smal quantities of indole acetic acid (IAA). In green house experiments, signiifcant increases in shoot height and weight, root length and weight, and stem diameter were observed on tomato plants in 30 d after inoculation with strain 7016. Result of 16S rDNA PCR-DGGE showed that 7016 survived in the rhizosphere of tomato seedlings. In the ifeld experiments, Burkholderia sp. 7016 enhanced the tomato yield and signiifcantly promoted activities of soil urease, phosphatase, sucrase, and catalase. Al these results demonstrated Burkholderia sp. 7016 as a valuable PGPR and a candidate of biofertilizer. 展开更多
关键词 PGPR Burkholderia sp. multiphasic characterization promoting growth BIOFERTILIZER
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Computed tomography pulmonary angiography using a 20% reduction in contrast medium dose delivered in a multiphasic injection 被引量:3
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作者 Mitchell Chen Gaith Mattar Jamal A Abdulkarim 《World Journal of Radiology》 CAS 2017年第3期143-147,共5页
AIM To evaluate the feasibility of reducing the dose of iodinated contrast agent in computed tomography pulmonary angiography(CTPA). METHODS One hundred and twenty-seven patients clinically suspected of having pulmona... AIM To evaluate the feasibility of reducing the dose of iodinated contrast agent in computed tomography pulmonary angiography(CTPA). METHODS One hundred and twenty-seven patients clinically suspected of having pulmonary embolism underwent spiral CTPA, out of whom fifty-seven received 75 mL and the remaining seventy a lower dose of 60 mL of contrast agent. Both doses were administered in a multiphasic injection. A minimum opacification threshold of 250 Hounsfield units(HU) in the main pulmonary artery is used for assessing the technical adequacy of the scans. RESULTS Mean opacification was found to be positively correlated to patient age(Pearson's correlation 0.4255, P < 0.0001) and independent of gender(male:female, 425.6 vs 450.4,P = 0.34). When age is accounted for, the study and control groups did not differ significantly in their mean opacification in the main(436.8 vs 437.9, P = 0.48),left(416.6 vs 419.8, P = 0.45) or the right pulmonary arteries(417.3 vs 423.5, P = 0.40). The number of sub-optimally opacified scans(the mean opacification in the main pulmonary artery < 250 HU) did not differ significantly between the study and control groups(7 vs 10).CONCLUSION A lower dose of iodine contrast at 60 mL can be feasibly used in CTPA without resulting in a higher number of sub-optimally opacified scans. 展开更多
关键词 Computed tomography pulmonary angiography Contrast dose Contrast induced nephropathy Acute kidney disease Contrast safety Contrast dose reduction multiphasic injection
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Booting the electrochemical properties of Fe-based anode by the formation multiphasic nanocomposite for lithium-ion batteries 被引量:2
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作者 Guotao Xiang Jiangmei Yin +2 位作者 Xixi Zhang Peiyu Houa Xijin Xu 《Chinese Chemical Letters》 SCIE CAS CSCD 2021年第7期2169-2173,共5页
Fe-based compounds with good environmental friendliness and high reversible capacity have attracted considerable attention as anode for lithium-ion batteries.But,similar to other transition metal oxides(TMOs),it is al... Fe-based compounds with good environmental friendliness and high reversible capacity have attracted considerable attention as anode for lithium-ion batteries.But,similar to other transition metal oxides(TMOs),it is also affected by large volume changes and inferior kinetics during redox reactions,resulting in the destruction of the crystal structure and poor electrochemical performance.Here,Fe_(3)O_(4)/C nanospheres anchored on the two-dimensional graphene oxide as precursors are phosphated and sintered to build the multiphasic nanocomposite.XRD results confirmed the multiphasic nanocomposite composed of Fe2O3,Fe_(3)O_(4) and Fe_(3)PO_(7),which will facilitate the Li+diffusion.And the carbonaceous matrix will buffer the volume changes and enhance electron conduction.Consequently,the multiphasic Febased anode delivers a large specific capacity of 1086 mAh/g with a high initial Coulombic efficiency of 87%at 0.1 C.It also has excellent cycling stability and rate property,maintaining a capacity retention of~87%after 300 cycles and a high reversible capacity of 632 mAh/g at 10 C.The proposed multiphasic structure offers a new insight into improving the electrochemical properties of TMO-based anodes for advanced alkali-ion batteries. 展开更多
关键词 Lithium-ion batteries Fe-based anode multiphasic structure Electrochemical properties Phosphated
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Neuronal degeneration in the hippocampus and dorsolateral prefrontal cortex in depressive disorder Correlation between ~1H-MRS and Minnesota Multiphasic Personality Inventory
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作者 Jun Xia Minjie Yang +1 位作者 Yi Lei Yicheng Zhou 《Neural Regeneration Research》 SCIE CAS CSCD 2010年第20期1587-1591,共5页
Previous studies using magnetic resonance imaging(MRI)and functional MRI to study depression have primarily focused on proton magnetic resonance spectroscopy(1H-MRS)appearance in various areas of the brain and vol... Previous studies using magnetic resonance imaging(MRI)and functional MRI to study depression have primarily focused on proton magnetic resonance spectroscopy(1H-MRS)appearance in various areas of the brain and volume measurements in the limbic system.However,results have not been consistent.To the best of our knowledge,very little is known about the relationship between 1H-MRS appearance and depression inventory.In the present study,the relationship between 1H-MRS appearance in depressive patients and Minnesota Multiphasic Personality Inventory-2 scale was analyzed.MRI and 1H-MRS exhibited widened sulci and cisterns,as well as an absence of abnormal signals in depressive patients.In addition,N-acetyl aspartate/total creatine ratios in bilateral hippocampi and dorsolateral prefrontal cortex were significantly less in depressive patients than in control subjects(P 〈 0.01).In contrast,choline-containing compounds/total creatine ratios in the dorsolateral prefrontal cortex were significantly greater in depressive patients than in control subjects(P 〈 0.01).These ratios significantly and positively correlated with patient total depression scores as assessed using the Minnesota Multiphasic Personality Inventory-2 scale(r=0.934 7,0.878 7,P 〈 0.01).These results suggested that 1H-MRS could be used to reveal a reduced number of neurons in the hippocampus and dorsolateral prefrontal cortex,as well as altered membrane phospholipid metabolism in the dorsolateral prefrontal cortex,in patients with depressive disorder.Abnormal mechanisms partially reflected severity of depressive disorder. 展开更多
关键词 depressive disorder proton magnetic resonance spectroscopy HIPPOCAMPUS dorsolateral prefrontal cortex Minnesota multiphasic Personality Inventory
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Multiphasic scaffolds for the repair of osteochondral defects:Outcomes of preclinical studies 被引量:11
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作者 Rouyan Chen Jasmine Sarah Pye +2 位作者 Jiarong Li Christopher B.Little Jiao Jiao Li 《Bioactive Materials》 SCIE CSCD 2023年第9期505-545,共41页
Osteochondral defects are caused by injury to both the articular cartilage and subchondral bone within skeletal joints. They can lead to irreversible joint damage and increase the risk of progression to osteoarthritis... Osteochondral defects are caused by injury to both the articular cartilage and subchondral bone within skeletal joints. They can lead to irreversible joint damage and increase the risk of progression to osteoarthritis. Current treatments for osteochondral injuries are not curative and only target symptoms, highlighting the need for a tissue engineering solution. Scaffold-based approaches can be used to assist osteochondral tissue regeneration, where biomaterials tailored to the properties of cartilage and bone are used to restore the defect and minimise the risk of further joint degeneration. This review captures original research studies published since 2015, on multiphasic scaffolds used to treat osteochondral defects in animal models. These studies used an extensive range of biomaterials for scaffold fabrication, consisting mainly of natural and synthetic polymers. Different methods were used to create multiphasic scaffold designs, including by integrating or fabricating multiple layers, creating gradients, or through the addition of factors such as minerals, growth factors, and cells. The studies used a variety of animals to model osteochondral defects, where rabbits were the most commonly chosen and the vast majority of studies reported small rather than large animal models. The few available clinical studies reporting cell-free scaffolds have shown promising early-stage results in osteochondral repair, but long-term follow-up is necessary to demonstrate consistency in defect restoration. Overall, preclinical studies of multiphasic scaffolds show favourable results in simultaneously regenerating cartilage and bone in animal models of osteochondral defects, suggesting that biomaterials-based tissue engineering strategies may be a promising solution. 展开更多
关键词 Osteochondral defects Tissue engineering multiphasic scaffolds BIOMATERIALS Animal models
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Interscale analysis of sediment clusters amid turbulence 被引量:1
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作者 Wai Hong Ronald Chan Ahmed Elnahhas +3 位作者 Hanul Hwang Lucy J.Brown Andrew J.Banko S.Balachandar 《Acta Mechanica Sinica》 2026年第1期73-80,共8页
Noncohesive particle clusters are identified and tracked in turbulent flows to determine the breakdown and time evolution of cluster statistics and their implications for interscale mass transfer,which has connections... Noncohesive particle clusters are identified and tracked in turbulent flows to determine the breakdown and time evolution of cluster statistics and their implications for interscale mass transfer,which has connections to the classical turbulent energy cascade and its mass cascade counterpart running in parallel.In particular,the formation and dynamics of sediment and larvae clusters are of interest to coral larvae settlement in coastal regions and particularly the resilience of green-gray coastal protection solutions.Analogous cluster behavior is relevant to cloud microphysics and precipitation initiation,radiation transport and light transmission through colloids and suspensions,heat and mass transfer in particle-laden flows,and viral and pollutant transmission.Following a comparison between various clustering techniques,we adopt a density-based cluster identification algorithm based on its simplicity and efficiency,where particles are clustered based on the number of neighboring particles in their individual spheres of influence.We establish parallels with lattice-based percolation theory,as evident in the power-law scaling of the cluster size distribution near the percolation threshold.The degree of discontinuity of the phase transition associated with this percolation threshold is observed to broaden with larger Stokes numbers and thereby large-scale clustering.The sensitivity of our findings to the employed clustering algorithm is discussed.A novel cluster tracking algorithm is deployed to determine the interscale transfer rate along the particle-number phase-space dimension via accounting of cluster breakup and merger events,extending previous work on the bubble breakup cascade beneath surface breaking waves.Our findings shed light on the interaction between particle clusters and their carrier turbulent flows,with an eye toward transport models incorporating cluster characteristics and dynamics. 展开更多
关键词 Particle-laden flows Particle-laden turbulence Sediment transport Computational fluid dynamics Multiphase turbulence Particle clustering Percolation theory
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Transforming layered 2D mats into multiphasic 3D nanofiber scaffolds with tailored gradient features for tissue regeneration
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作者 S.M.Shatil Shahriar Navatha Shree Polavoram +5 位作者 Syed Muntazir Andrabi Yajuan Su Donghee Lee Huy Quang Tran Samantha J.Schindler Jingwei Xie 《BMEMat(BioMedical Engineering Materials)》 2024年第1期160-179,共20页
Multiphasic scaffolds with tailored gradient features hold significant promise for tissue regeneration applications. Herein, this work reports the transformation of two-dimensional (2D) layered fiber mats into three-d... Multiphasic scaffolds with tailored gradient features hold significant promise for tissue regeneration applications. Herein, this work reports the transformation of two-dimensional (2D) layered fiber mats into three-dimensional (3D) multiphasic scaffolds using a ‘solids-of-revolution’ inspired gas-foaming expansion technology. These scaffolds feature precise control over fiber alignment, pore size, and regional structure. Manipulating nanofiber mat layers and Pluronic F127 concentrations allows further customization of pore size and fiber alignment within different scaffold regions. The cellular response to multiphasic scaffolds demonstrates that the number of cells migrated and proliferated onto the scaffolds is mainly dependent on the pore size rather than fiber alignment. In vivo subcutaneous implantation of multiphasic scaffolds to rats reveals substantial cell infiltration, neo tissue formation, collagen deposition, and new vessel formation within scaffolds, greatly surpassing the capabilities of traditional nanofiber mats. Histological examination indicates the importance of optimizing pore size and fiber alignment for the promotion of cell infiltration and tissue regeneration. Overall, these scaffolds have potential applications in tissue modeling, studying tissue-tissue interactions, interface tissue engineering, and highthroughput screening for optimized tissue regeneration. 展开更多
关键词 EXPANSION gradients multiphasic scaffolds nanofiber mats tissue regeneration
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Experimental and numerical investigation on the deformation and breakup of water droplets in shear airflow
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作者 Jingxin WANG Yuan WANG +3 位作者 Ning ZHAO Chengxiang ZHU Hao DAI Chunling ZHU 《Science China(Technological Sciences)》 2026年第2期28-43,共16页
The dynamic behaviors of supercooled large water droplets(SLDs)in airflow involving deformation,breakup,and splash affect the local water collection coefficient,leading to an increase in the complexity of aircraft ici... The dynamic behaviors of supercooled large water droplets(SLDs)in airflow involving deformation,breakup,and splash affect the local water collection coefficient,leading to an increase in the complexity of aircraft icing.A parametric study on the influence of deformed water droplets in shear flow is investigated experimentally and numerically.A horizontal refrigerated wind tunnel is used to create the background shear airflow.A high-speed camera records the evolution of cross-stream/streamwise diameters and the breakup process.The level set method is employed to capture the deformation of micrometer-sized supercooled water droplets in continuous airflow.The deformation modes are categorized into five regimes:stabilization,vibration,transition,bag breakup,and bag-stamen breakup.A dimensionless deformation factor L is defined to describe the droplet deformation,which increases with airflow speed,droplet volume,and temperature.Applying the scaling expression Oh~(4.39)We~(0.85),a normalized acceleration model of water droplets in shear airflow is established.Based on the experimental results,a drag coefficient model for disc-shaped droplets within the transient Reynolds number range of 420-10000 is obtained.As the initial Weber number exceeds 9.5 and the maximum deformation factor exceeds 3.5,the droplet enters the breakup regime.Furthermore,bag-stamen breakup occurs when the initial Weber number exceeds 17.5. 展开更多
关键词 multiphase fluid dynamics deformation factor drag coefficient breakup regime level set
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Study on Numerical Simulation about Motion Trajectory of Ice Crystal Particles under Different Injection Conditions in Wind Tunnel
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作者 Zhaokun Ren Yue Zhang +2 位作者 Yunxiang Wang Zhanyuan Ma Chen Bu 《Journal of Harbin Institute of Technology(New Series)》 2026年第1期51-68,共18页
Ice crystal icing is an important cause of accidents in aircraft engines.Ice formation in aircraft engines can cause internal blades to freeze,affecting the quality of the air flow field and blocking the flow path.On ... Ice crystal icing is an important cause of accidents in aircraft engines.Ice formation in aircraft engines can cause internal blades to freeze,affecting the quality of the air flow field and blocking the flow path.On the other hand,the entry of ice crystal particles into the combustion chamber can cause a decrease in temperature or even flameout,leading to engine surge or shutdown.Therefore,it is necessary to conduct multiphase flow tests on ice crystals for aircraft components such as aircraft engines.Conducting ice crystal multiphase flow tests on aircraft is an effective research method,but it requires the construction of an ice crystal multiphase flow test platform that meets relevant technical requirements.The paper focuses on the relevant experimental requirements and combines wind tunnel test structures to conduct multiphase flow numerical simulations on various forms of jet pipelines,obtaining particle motion distribution results.After comparison,the optimal form of jet structure is obtained,providing the best selection scheme for the design of relevant wind tunnel structures. 展开更多
关键词 ice crystal wind tunnel numerical simulation multiphase flow jet pipelines
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Thermodynamic performance calculation and test verification of gas-liquid two-phase water ramjet engine
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作者 Pingan LIU Dianlong SUN +4 位作者 Xile QIAN Shang LIU Tao WANG Jingtao CHENG Kejing XU 《Chinese Journal of Aeronautics》 2026年第1期1-17,共17页
Underwater gas-liquid two-phase propulsion technology is an emerging propulsion method that offers high efficiency and unrestricted navigation speed.The integration of this technology into water ramjet engines can sig... Underwater gas-liquid two-phase propulsion technology is an emerging propulsion method that offers high efficiency and unrestricted navigation speed.The integration of this technology into water ramjet engines can significantly enhance propulsion efficiency and holds substantial potential for broad applications.However,forming a gas-liquid two-phase flow within the nozzle requires introducing a large amount of rammed seawater.At this time,there is a complex phase transition problem of combustion products in the combustion chamber,which makes the thermodynamic calculation for gas-liquid two-phase water ramjet engines particularly challenging.This paper proposes a thermodynamic calculation method for gas-liquid two-phase water ramjet engines,based on the energy equation for gas-liquid two-phase flow and traditional thermodynamic principles,enabling thermodynamic calculations under conditions of ultra-high water-fuel ratios.Additionally,ground ignition tests of the gas-liquid two-phase engine were conducted,yielding critical engine test parameters.The results demonstrate that the gas-liquid two-phase water ramjet engine achieves a high specific impulse,with a theoretical maximum specific impulse of up to 7000(N s)/kg.The multiphase flow effects significantly impact engine performance,with specific impulse losses reaching up to 25.86%.The error between the thrust and specific impulse in the ground test and the theoretical values is within 10%,validating the proposed thermodynamic calculation method as a reliable reference for further research on gas-liquid two-phase water ramjet engines. 展开更多
关键词 Gas-liquid two-phase flow Ignition test Multiphase flow Thermal calculation Water ramjet engine
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Strong yet ductile low-density steel via multiphase heterogeneous microstructure
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作者 Jiahe YAN Zhinan YANG +4 位作者 Jinliang DU Yunli FENG Minghe ZHANG Xiaoyong FENG Fucheng ZHANG 《Chinese Journal of Aeronautics》 2026年第1期656-673,共18页
Under equivalent stiffness conditions,material substitution based on a thin-walled design is crucial for the lightweight of components.Developing high-performance steels with both high-yield strength and excellent duc... Under equivalent stiffness conditions,material substitution based on a thin-walled design is crucial for the lightweight of components.Developing high-performance steels with both high-yield strength and excellent ductility has become a key focus in fields like aerospace and lowaltitude flight.The novel low-density steel presented here exhibits a yield strength of 1000 MPa,which is 2-3 times higher than conventional low-alloy high-strength steels,while maintaining an elongation of about 18.7%.By combining ex-situ experimental characterization with a phase mechanical response model based on the iso-work theory and the von Mises equivalent method,the role of heterogeneous deformation-induced strengthening was revealed.The calculated values align closely with experimental results.This exceptional performance is attributed to a multiphase heterogeneous microstructure,where fresh martensite,bainite/tempered martensite,and deformation-induced martensite act as hard regions.These regions release micro-stresses through inhomogeneous cooperative deformation with soft ferrite,enabling multiple plastic deformation mechanisms and stress concentration relief.This research offers new insights into optimizing microstructures through mechanical metallurgy,which is crucial for producing high-performance,lightweight components. 展开更多
关键词 Constitutive model Low-density steel Multiphase heterogeneous microstructure Strength and ductility Stress concentration relieving
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Numerical investigation of mixed-phase turbulence in flow past a partially merged plate
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作者 Junqi Tong Rong Li Zixuan Yang 《Acta Mechanica Sinica》 2026年第1期3-14,共12页
Large-eddy simulation(LES)is conducted to study the statistical properties of mixed-phase turbulence induced by the breaking of bow waves in flow past a partially submerged plate.The simulation is performed using a fi... Large-eddy simulation(LES)is conducted to study the statistical properties of mixed-phase turbulence induced by the breaking of bow waves in flow past a partially submerged plate.The simulation is performed using a finite difference method,with the air-water interface captured by a coupled level-set and volume-of-fluid method.Four cases are conducted to investigate the effects of Froude number on turbulent statistics,including the mean velocity,turbulence kinetic energy,and turbulence mass flux(TMF),which is an additional unclosed term in the Reynolds-averaged momentum equation.The TMF,especially its vertical component,shows a complex behaviour with respect to the Froude number.This property of the TMF imposes high demands on the robustness of the closure model of TMF.The present LES data is further used to examine a closure model of the TMF production term,which shows a high correlation with the data obtained from LES. 展开更多
关键词 Turbulent flows Multiphase flows Wave breaking
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A numerical study on wind-driven runback characteristics of a thin water film flow over a solid surface
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作者 Jincheng Wang Ping He Hui Hu 《Acta Mechanica Sinica》 2026年第1期64-72,共9页
An unsteady numerical simulation is conducted to examine the dynamic runback characteristics of a water film flow driven by a boundary layer airflow over a solid surface pertinent to the dynamic glaze ice accretion pr... An unsteady numerical simulation is conducted to examine the dynamic runback characteristics of a water film flow driven by a boundary layer airflow over a solid surface pertinent to the dynamic glaze ice accretion process over aircraft wing surfaces.The multiphase flow simulation results of the wind-driven water runback(WDWR)flow are compared quantitatively with the experimental results in terms of the time-dependent variations of the water film thickness profiles and evolution of the front contact point of the runback water film flow.The underlying mechanism of the intermittent water runback behavior is elucidated by analyzing the time evolution of the airflow velocity and vorticity fields above the runback water film flow over the solid surface.To the best knowledge of the authors,the work presented here is the first successful attempt to numerically examine the transient runback characteristics of WDWR flows.It serves as an excellent benchmark case for the development of best practices to model the important micro-physical processes responsible for the transient water transport over aircraft wing surfaces. 展开更多
关键词 Multiphase flow simulation Water transport over wing surfaces Glaze ice accretion process Volume of fluid method
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Transformation of monolayer MoS2 into multiphasic MoTe2: Chalcogen atom-exchange synthesis route 被引量:1
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作者 Qiyi Fang Zhepeng Zhang +8 位作者 Qingqing Ji Siya Zhu Yue Gong Yu Zhang Jianping Shi Xiebo Zhou Lin Gu Qian Wang Yanfeng Zhang 《Nano Research》 SCIE EI CAS CSCD 2017年第8期2761-2771,共11页
Molybdenum ditelluride (MoTe2), which is an important transition-metal dichalcogenide, has attracted considerable interest owing to its unique properties, such as its small bandgap and large Seebeck coefficient. How... Molybdenum ditelluride (MoTe2), which is an important transition-metal dichalcogenide, has attracted considerable interest owing to its unique properties, such as its small bandgap and large Seebeck coefficient. However, the batch production of monolayer MoTe2 has been rarely reported. In this study, we demonstrate the synthesis of large-domain (edge length exceeding 30 μm), monolayer MoTe2 from chemical vapor deposition-grown monolayer MoS2 using a chalcogen atom-exchange synthesis route. An in-depth investigation of the tellurization process reveals that the substitution of S atoms by Te is prevalently initiated at the edges and grain boundaries of the monolayer MoS2, which differs from the homogeneous selenization of MoS2 flakes with the formation of alloyed Mo-S-Se hybrids. Moreover, we detect a large compressive strain (approximately -10%) in the transformed MoTe2 lattice, which possibly drives the phase transition from 2H to 1T' at the reaction temperature of 500 ℃. This phase change is substantiated by experimental facts and first-principles calculations. This work introduces a novel route for the templated synthesis of two-dimensional layered materials through atom substitutional chemistry and provides a new pathway for engineering the strain and thus the intriguing physics and chemistry. 展开更多
关键词 transition-metal dichacogenide MoTe2 atom exchange MULTIPHASE phase transformation
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TiCrNb hydride fabricated by melt spinning as the efficient catalyst for enhancing the hydrogen storage properties of MgH_(2)
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作者 Houqun Xiao Luocai Yi +6 位作者 Huxu Lei Yu Xu Xiaoxuan Zhang Huazhou Hu Ruizhu Tang Qian Li Qingjun Chen 《Journal of Magnesium and Alloys》 2025年第9期4206-4218,共13页
Magnesium hydride(MgH_(2))has garnered significant attention as a promising material for high-capacity hydrogen storage.However,its commercial application remains challenging due to the high operating temperature and ... Magnesium hydride(MgH_(2))has garnered significant attention as a promising material for high-capacity hydrogen storage.However,its commercial application remains challenging due to the high operating temperature and slow reaction kinetics.In this study,melt-spun Ti_(45)Cr_(40)Nb_(15)(with a BCC phase)hydride(designated as TiCrNbH_(x-)MS)was synthesized and used to form a nano-multiphase composite to improve the de-/rehydrogenation properties of MgH_(2) through ball milling.The incorporation of TiCrNbH_(x-)MS was shown to significantly enhance the hydrogen de-/rehydrogenation properties of MgH_(2).The MgH_(2)+20 wt%TiCrNbH_(x-)MS composite exhibits an appealing initial dehydrogenation temperature of 163℃ and can absorb hydrogen at room temperature.Notably,it releases 5.8 wt% hydrogen in 700 s at 230℃ and recharges 4.3 wt%hydrogen in just 2 mins at 150℃.Even after 100 cycles,it retains a reversible hydrogen capacity of 4.98 wt%.Kinetic analysis revealed that the dehydrogenation rate follows the Chou surface penetration model.Microstructural analysis showed that the FCC phase of the melt-spun TiCrNbH_(x-)MS hydride reversibly transformed into the BCC phase during the de-/rehydrogenation process in the composite.Numerous phase interfaces were generated and uniformly dispersed on the MgH_(2) surface,providing additional hydrogen diffusion pathways and heterogeneous nucleation sites for Mg/MgH_(2),thereby further improving the hydrogen de-/rehydrogenation kinetics of the system.This study offers valuable insights into the use of multiphase composites to enhance MgH_(2) performance. 展开更多
关键词 MgH_(2) BCC Hydrogen storage Structural evolution multiphasic composite
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Research progress on the copper-based catalyst design for dimethyl oxalate hydrogenation to ethylene glycol
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作者 Hansheng Wang Xintian Luo +6 位作者 Kaixuan Chen Benduan Xiao Xu Zhang Qingjun Meng Huibing He Jing Xu Yong Jin 《Chinese Journal of Chemical Engineering》 2025年第9期189-205,共17页
In this paper,the research progress of Cu-based catalyst and the activity enhancement strategies in the hydrogenation of dimethyl oxalate(DMO)to ethylene glycol(EG)was reviewed.As a green and economical ethylene glyco... In this paper,the research progress of Cu-based catalyst and the activity enhancement strategies in the hydrogenation of dimethyl oxalate(DMO)to ethylene glycol(EG)was reviewed.As a green and economical ethylene glycol production path,the core of DMO hydrogenation of EG lies in the rational design and optimization of catalysts.This paper first introduces the background of the DMO hydrogenation system EG significance and the important effect of Cu-based catalyst in the reaction,particularly emphasizing the coordination with the Cu^(+)-Cu^(0) species catalytic effect.Then,many factors affecting the activity of Cu-based catalysts were analyzed in detail,including the equilibrium effect between Cu^(0) and Cu+species,the surface dispersion of Cu species,the interaction between metal and support,and the morphology effect of the catalyst.Regarding strategies for improving catalyst performance,this paper summarized effective measures such as optimizing support structure,adding promoters and optimizing preparation methods,and demonstrated the practical application effects of these strategies through representative catalyst examples.In addition,this paper also discusses the complex relationship between the influencing factors and catalyst performance.It points out the key directions for future research,with in-depth exploration of the correlation between catalyst structure and performance,the development of new catalysts,and the application of machine learning and big data technology in the catalyst research and development.In summary,this paper provides comprehensive theoretical guidance and practical reference for the performance optimization of Cu-based catalysts for DMO hydrogenation to EG. 展开更多
关键词 Copper-based catalyst Dimethyl oxalate HYDROGENATION CATALYSIS Multiphase reaction
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Numerical analysis of dispersion,attenuation,and seismic effects in a porous rock saturated with three-phase immiscible fluids
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作者 Xin Luo Xue-Hua Chen +2 位作者 Tong Li Gui-Rong Luo Peng Wang 《Petroleum Science》 2025年第7期2828-2850,共23页
Multiphase flow in porous rock is of great importance in the application of many industrial processes,including reservoir delineation,enhanced oil recovery,and CO_(2) sequestration.However,previous research typically ... Multiphase flow in porous rock is of great importance in the application of many industrial processes,including reservoir delineation,enhanced oil recovery,and CO_(2) sequestration.However,previous research typically investigated the dispersive behaviors when rock saturated with single or two-phase fluids and conducted limited studies on three-phase immiscible fluids.This study investigated the seismic dispersion,attenuation,and reflection features of seismic waves in three-phase immiscible fluidsaturated porous rocks.First,we proposed the calculation formulas of effective fluid modulus and effective fluid viscosity of multiphase immiscible fluids by taking into account the capillary pressure,reservoir wettability,and relative permeability simultaneously.Then,we analysed the frequencydependent behaviors of three-phase immiscible fluid-saturated porous rock under different fluid proportion cases using the Chapman multi-scale model.Next,the seismic responses are analysed using a four-layer model.The results indicate that the relative permeability,capillary pressure parameter,and fluid proportions are all significantly affect dispersion and attenuation.Comparative analyses demonstrate that dispersion and attenuation can be observed within the frequency range of seismic exploration for a lower capillary parameter a3 and higher oil content.Seismic responses reveal that the reflection features,such as travel time,seismic amplitude,and waveform of the bottom reflections of saturated rock and their underlying reflections are significantly dependent on fluid proportions and capillary parameters.For validation,the numerical results are further verified using the log data and real seismic data.This numerical analysis helps to further understand the wave propagation characteristics for a porous rock saturated with multiphase immiscible fluids. 展开更多
关键词 Multiphase immiscible fluids DISPERSION ATTENUATION Relative permeability Capillary parameter Seismic responses
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A granular thermodynamic framework-based coupled multiphasesubstance flow model considering temperature driving effect
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作者 Bing Bai Haiyan Wu +2 位作者 Rui Zhou Nan Wu Bixia Zhang 《Journal of Rock Mechanics and Geotechnical Engineering》 2025年第9期5816-5828,共13页
Based on the energy dissipation caused by consolidation deformation of the porous media under external force and migration of the internal suspended substances,a coupled multiphase-substance flow(CMF)model was establi... Based on the energy dissipation caused by consolidation deformation of the porous media under external force and migration of the internal suspended substances,a coupled multiphase-substance flow(CMF)model was established.This model introduced the new concepts,such as particle temperature and particle entropy,to describe energy dissipation at meso-level.This model used a potential energy density function and migration coefficients to establish the corresponding connection between the dissipative force and dissipative flow.This viewpoint unifies the deformation,seepage,and suspended substance migration of geotechnical materials under the framework of granular thermodynamics.It can reflect the evolution of effective stress in the solid matrix of multi-components in a particle-reorganized state,and considers the temperature driving effect.The proposed CMF model is validated using the experimental results under coupled migration of heavy metal ions(HMs)and suspended particles(SPs).The calculation results demonstrated that the CMF model can describe the flow process under the conditions of arbitrary changes in different suspended substance types,injection concentrations,and injection velocities. 展开更多
关键词 GROUNDWATER Granular thermodynamics Multiphase substance Coupled migration Consolidation deformation
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Mechanistic insights and practical applications of impinging-jet dynamics and atomization
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作者 Yongze An Bo Wang +2 位作者 Zhili Peng Xiaodong Chen Vigor Yang 《Acta Mechanica Sinica》 2025年第7期21-37,共17页
This review summarizes recent progress in the study of impinging-jet dynamics and atomization,with a focus on liquid sheet formation,instability mechanisms,and the influence of key parameters such as fluid properties,... This review summarizes recent progress in the study of impinging-jet dynamics and atomization,with a focus on liquid sheet formation,instability mechanisms,and the influence of key parameters such as fluid properties,Weber number,and Reynolds number.Special attention is given to atomization behaviors under high pressure and external perturbations.Representative experimental and numerical approaches are introduced,and critical findings under complex conditions are highlighted.In addition,practical applications of impinging-jet technology in aerospace propulsion,biomedical devices,and energy science are discussed.This review aims to serve as a concise reference for researchers interested in multiphase flow dynamics and engineering applications of impinging jets. 展开更多
关键词 Impinging jets Liquid sheet breakup ATOMIZATION Interfacial instability Spray dynamics Multiphase flow
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Unified mixed conductivity model
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作者 X.T.Li Z.J.Zhang +8 位作者 R.J.Dai R.Liu Z.Qu S.G.Wang H.T.Li W.J.Hu Q.Z.Wang Z.Y.Ma Z.F.Zhang 《Journal of Materials Science & Technology》 2025年第10期80-89,共10页
Matter conductivities are crucial physical properties that directly determine the engineering application value of materials.In reality,the majority of materials are multiphase composites.However,there is currently a ... Matter conductivities are crucial physical properties that directly determine the engineering application value of materials.In reality,the majority of materials are multiphase composites.However,there is currently a lack of theoretical models to accurately predict the conductivities of composite materials.In this study,we develop a unified mixed conductivity(UMC)model,achieving unity in three aspects:(1)a unified description and prediction for different conductivities,including elastic modulus,thermal conductivity,electrical conductivity,magnetic permeability,liquid permeability coefficient,and gas diffusion coefficient;(2)a unified-form governing equation for mixed conductivities of various composite structures,conforming to the Riccati equation;(3)a unified-form composite structure,i.e.,a three-dimensional multiphase interpenetrating cuboid structure,encompassing over a dozen of typical composite structures as its specific cases.The UMC model is applicable for predicting the conductivity across six different types of physical fields and over a dozen different composite structures,providing a broad range of applications.Therefore,the current study deepens our understanding of the conduction phenomena and offers a powerful theoretical tool for predicting the conductivities of composite materials and optimizing their structures,which holds significant scientific and engineering implications. 展开更多
关键词 Composite materials CONDUCTIVITY Elastic modulus Permeability coefficient Diffusion coefficient Multiphase interpenetrating structure
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