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ANALYSIS OF MULTI-TONE INTERFERENCE SUPPKESSION IN HF SERIAL DATA TRANSMISSION SYSTEM
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作者 唐军 李振邦 李乐民 《Journal of Electronics(China)》 1993年第1期15-24,共10页
The multi-tone interference suppression in HF serial data transmission systemsis analyzed.Analytic expression for the tap weights and minimum mean square errors of theadaptive equalizer in HF serial systems are obtain... The multi-tone interference suppression in HF serial data transmission systemsis analyzed.Analytic expression for the tap weights and minimum mean square errors of theadaptive equalizer in HF serial systems are obtained.The rate of convergence of equalizer indicatethat the equalizer in HF serial system can not only track the rapid variation of HF channel butalso suppress the multi-tone interferences perfectly. 展开更多
关键词 HF serial data transmission systems multi-tone interferences Adaptive EQUALIZER
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Beyond the surface:Advancing neurorehabilitation with transcranial temporal interference stimulation——clinical applications and future prospects
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作者 Camille E.Proulx Friedhelm C.Hummel 《Neural Regeneration Research》 2026年第5期1987-1988,共2页
Brain lesions,such as those caused by stroke or traumatic brain injury(TBI),frequently result in persistent motor and cognitive impairments that significantly affect the individual patient's quality of life.Despit... Brain lesions,such as those caused by stroke or traumatic brain injury(TBI),frequently result in persistent motor and cognitive impairments that significantly affect the individual patient's quality of life.Despite differences in the mechanisms of injury,both conditions share a high prevalence of motor and cognitive impairments.These deficits show only limited natural recovery. 展开更多
关键词 NEUROREHABILITATION STIMULATION TRANSCRANIAL TEMPORAL interferENCE motor cognitive impairments brain lesionssuch motor cognitive impairmentsthese
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A Robust Face Recognition Method Combining LBP with Multi-mirror Symmetry for Images with Various Face Interferences 被引量:8
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作者 Shui-Guang Tong Yuan-Yuan Huang Zhe-Ming Tong 《International Journal of Automation and computing》 EI CSCD 2019年第5期671-682,共12页
Face recognition(FR) is a practical application of pattern recognition(PR) and remains a compelling topic in the study of computer vision. However, in real-world FR systems, interferences in images, including illumina... Face recognition(FR) is a practical application of pattern recognition(PR) and remains a compelling topic in the study of computer vision. However, in real-world FR systems, interferences in images, including illumination condition, occlusion, facial expression and pose variation, make the recognition task challenging. This study explored the impact of those interferences on FR performance and attempted to alleviate it by taking face symmetry into account. A novel and robust FR method was proposed by combining multi-mirror symmetry with local binary pattern(LBP), namely multi-mirror local binary pattern(MMLBP). To enhance FR performance with various interferences, the MMLBP can 1) adaptively compensate lighting under heterogeneous lighting conditions, and 2) generate extracted image features that are much closer to those under well-controlled conditions(i.e., frontal facial images without expression). Therefore, in contrast with the later variations of LBP, the symmetrical singular value decomposition representation(SSVDR) algorithm utilizing the facial symmetry and a state-of-art non-LBP method, the MMLBP method is shown to successfully handle various image interferences that are common in FR applications without preprocessing operation and a large number of training images. The proposed method was validated with four public data sets. According to our analysis, the MMLBP method was demonstrated to achieve robust performance regardless of image interferences. 展开更多
关键词 FACE recognition(FR) local binary pattern(LBP) FACIAL SYMMETRY image interferences multi-mirror average
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CERTAIN NATIVE LANGUAGE INTERFERENCES IN SECOND LANGUAGE ACQUISITION 被引量:14
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作者 Zhao Dianxue (Department of Euglish, Sanning Teachers College) 《三明学院学报》 1999年第3期64-66,共3页
Here we refer the native language to Chinese and the second language to English especially college English. According to linguistic study, there are certain native language interferences in secondlanguage acquisition... Here we refer the native language to Chinese and the second language to English especially college English. According to linguistic study, there are certain native language interferences in secondlanguage acquisition when one is learning the second language,i. e. when a Chinese is learningEnglish, due to the influence of mother tongue which is habitually applied in learning the second language, his pronounciation, his grammar and his vocabulary are quite likely influencedor interfered by his native language or his dialect. Unfortunately, we did find certain first language interferences in our English teaching and learning processes on various items or subjects. 展开更多
关键词 NATIVE LANGUAGE interferences. SECOND LANGUAGE ACQUISI TION
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GNSS array receiver faced with overloaded interferences:anti-jamming performance and the incident directions of interferences 被引量:7
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作者 WANG Jie LIU Wenxiang +2 位作者 CHEN Feiqiang LU Zukun OU Gang 《Journal of Systems Engineering and Electronics》 SCIE EI CSCD 2023年第2期335-341,共7页
Anti-jamming solutions based on antenna arrays enhance the anti-jamming ability and the robustness of global navigation satellite system(GNSS)receiver remarkably.However,the performance of the receiver will deteriorat... Anti-jamming solutions based on antenna arrays enhance the anti-jamming ability and the robustness of global navigation satellite system(GNSS)receiver remarkably.However,the performance of the receiver will deteriorate significantly in the overloaded interferences scenario.We define the overloaded interferences scenario as where the number of interferences is more than or equal to the number of antenna arrays elements.In this paper,the effect mechanism of interferences with different incident directions is found by studying the anti-jamming performance of the adaptive space filter.The theoretical analysis and conclusions,which are first validated through numerical examples,reveal the relationships between the optimal weight vector and the eigenvectors of the input signal autocorrelation matrix,the relationships between the interference cancellation ratio(ICR),the signal to interference and noise power ratio(SINR)of the adaptive space filter output and the number of interferences,the eigenvalues of the input signal autocorrelation matrix.In addition,two simulation experiments are utilized to further corroborate the theoretical findings through soft anti-jamming receiver.The simulation results match well with the theoretical analysis results,thus validating the effect mechanism of overloaded interferences.The simulation results show that,for a four elements circular array,the performance difference is up to 19 dB with different incident directions of interferences.Anti-jamming performance evaluation and jamming deployment optimization can obtain more accurate and efficient results by using the conclusions. 展开更多
关键词 antenna arrays ANTI-JAMMING overloaded interferences incident direction
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Investigation of potential interferences on the measurement of dissolved reactive phosphate using zirconium oxide-based DGT technique 被引量:4
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作者 Qin Sun Yifei Chen +2 位作者 Di Xu Yan Wang Shiming Ding 《Journal of Environmental Sciences》 SCIE EI CAS CSCD 2013年第8期1592-1600,共9页
A diffusive gradients in thin films (DGT) technique based on hydrous zirconium oxide (Zr-oxide) has been recently developed for the measurement of dissolved reactive phosphate (DRP). In this study, the detailed ... A diffusive gradients in thin films (DGT) technique based on hydrous zirconium oxide (Zr-oxide) has been recently developed for the measurement of dissolved reactive phosphate (DRP). In this study, the detailed performance of the DGT technique is reported. Spiking experiments revealed that several orthophosphate monoester compounds contributed to the Zr-oxide DGT measurements of DRP. However, such a phenomenon is unlikely to occur during field conditions due to the low concentration of organic P in typical natural waters. The presence of Cl- (up to 106 g/L), SO42- (up to 16 g/L), HCO3- (up to 817 g/L), and AsO2- and AsO 3 4 (both up to 1 mg As/L) in solutions had negligible effects on the measurement of DRP. The threshold concentrations of Cl-, SO42- and HCO3- have been increased from previous reports for the measurements of DRP using other adsorbent-based DGT techniques. The capacity for DGT measurements of DRP decreased with increasing solution pH (4.2-9.2). The lowest capacity (95 μg P/m2 at pH 9.2) was still greater than that of other DGT techniques that are usually used for the measurement of DRP (2-12 μg P/cm2 ). The Zr-oxide binding gel could be stored for up to 2 years without any aging effect. This period of validity was considerably longer than the ferrihydrite binding gel that is commonly used in present DGT devices (6 months). The field application revealed that the concentrations of DRP measured in three fresh water samples using the Zr-oxide DGT technique were in agreement with those of the traditional colorimetric method. 展开更多
关键词 diffusive gradients in thin films (DGT) technique zirconium oxide (Zr-oxide) dissolved reactive phosphate (DRP) interference soil water
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Multiple interferences suppression with space-polarization null-decoupling for polarimetric array 被引量:13
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作者 LU Yawei MA Jiazhi +1 位作者 SHI Longfei QUAN Yuan 《Journal of Systems Engineering and Electronics》 SCIE EI CSCD 2021年第1期44-52,共9页
The adaptive digital beamforming technique in the space-polarization domain suppresses the interference with forming the coupling nulls of space and polarization domain.When there is the interference in mainlobe,it wi... The adaptive digital beamforming technique in the space-polarization domain suppresses the interference with forming the coupling nulls of space and polarization domain.When there is the interference in mainlobe,it will cause serious mainlobe distortion,that the target detection suffers from.To overcome this problem and make radar cope with the complex multiple interferences scenarios,we propose a multiple mainlobe and/or sidelobe interferences suppression method for dual polarization array radar.Specifically,the proposed method consists of a signal preprocessing based on the proposed angle estimation with degree of polarization(DoP),and a filtering criterion based on the proposed linear constraint.The signal preprocessing provides the accurate estimated parameters of the interference,which contributes to the criterion for null-decoupling in the space-polarization domain of mainlobe.The proposed method can reduce the mainlobe distortion in the space-polarization domain while suppressing the multiple mainlobe and/or sidelobe interferences.The effectiveness of the proposed method is verified by simulations. 展开更多
关键词 multiple interferences suppression dual polarization array radar null-decoupling
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Digital Demodulation Algorithm for Multi-Tone FM Signal in New Type Track Circuit 被引量:1
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作者 祝林啸 吴嗣亮 《Journal of Beijing Institute of Technology》 EI CAS 2006年第3期331-335,共5页
The multi-tone frequency modulation (FM) signal transferred through track circuit in automatic train control (ATC) system is analyzed. A digital filter with ideal sloping shape in frequency domain is designed for ... The multi-tone frequency modulation (FM) signal transferred through track circuit in automatic train control (ATC) system is analyzed. A digital filter with ideal sloping shape in frequency domain is designed for frequency discrimination. With this filter, the FM signal is converted into AM-FM signal by frequency-to-amplitude conversion. The modulating signal is finally extracted from the envelope of the AM-FM signal. Simulations show that the digital demodulation method could accurately recover the modulating signal in low signal noise ratio (SNR) circumstance, and has good performance in suppressing interference of harmonies of traction current frequency. The feasibility of the proposed method is proved in a hardware system based on SHARC DSP. 展开更多
关键词 track circuit multi-tone frequency modulation frequency discrimination
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A 330-W single-frequency retrievable multi-tone monolithic fiber amplifier 被引量:1
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作者 王小林 周朴 +2 位作者 冷进勇 杜文博 许晓军 《Chinese Physics B》 SCIE EI CAS CSCD 2013年第4期274-280,共7页
A single-frequency retrievable phase modulated multi-tone fiber amplifier is presented in theory and demonstrated in experiment. A multi-tone seed laser generated by a sine wave phase modulated single-frequency laser ... A single-frequency retrievable phase modulated multi-tone fiber amplifier is presented in theory and demonstrated in experiment. A multi-tone seed laser generated by a sine wave phase modulated single-frequency laser is employed for stimulated Brillouin scattering suppression in an all-fiber amplifier. A demodulation signal which is π phase shifted with respect to the modulation signal is used to retrieve the single-frequency laser from the multi-tone laser. In experiment, we first optimize the all-fiber master-oscillator power-amplifier. With this amplifier, we demonstrate a single-frequency retrievable multi-tone laser with 330-W output when driven by the multi-tone seed, while the ultimate output power is only 130 W when driven by the single-frequency laser. Then, we carry out an experiment for retrieving the single-frequency laser from the amplified multi-tone laser. Results indicate that the single-frequency laser can be retrieved with a sideband suppression of more than 20 dB. Retrieving an even higher power single-frequency laser is possible if a high power demodulator is available. 展开更多
关键词 single-frequency laser multi-tone amplifier phase modulation and demodulation
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Application of pseudo-random frequency domain electromagnetic method in mining areas with strong interferences 被引量:8
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作者 Yan-fang HU Di-quan LI +2 位作者 Bo YUAN Guang-yun SUO Zi-jie LIU 《Transactions of Nonferrous Metals Society of China》 SCIE EI CAS CSCD 2020年第3期774-788,共15页
Due to the strong electromagnetic interferences and human interference,traditional electromagnetic methods cannot obtain high quality resistivity data of mineral deposits in Chinese mines.The wide field electromagneti... Due to the strong electromagnetic interferences and human interference,traditional electromagnetic methods cannot obtain high quality resistivity data of mineral deposits in Chinese mines.The wide field electromagnetic method(WFEM),in which the pseudo-random signal is taken as the transmitter source,can extract high quality resistivity data in areas with sever interference by only measuring the electric field component.We use the WFEM to extract the resistivity information of the Dongguashan mine in southeast China.Compared with the audio magnetotelluric(AMT)method,and the controlled source audio-frequency magnetotelluric(CSAMT) method,the WFEM can obtain data with higher quality and simpler operations.The inversion results indicate that the WFEM can accurately identify the location of the main ore-body,which can be used for deep mine exploration in areas with strong interference. 展开更多
关键词 pseudo-random signal frequency domain electromagnetic method wide field electromagnetic method(WFEM) strong interference anti-interference capability Dongguashan copper deposit
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Interferences in Photodetachment of a Negative Molecular Ion Model 被引量:1
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作者 A. Afaq DU Meng-Li 《Communications in Theoretical Physics》 SCIE CAS CSCD 2008年第12期1401-1406,共6页
By employing a two-center model, the total and differential cross sections in the photodetachment of "a negative molecular ion" are studied theoreticedly and obtained for the case of light polarization paredlel to t... By employing a two-center model, the total and differential cross sections in the photodetachment of "a negative molecular ion" are studied theoreticedly and obtained for the case of light polarization paredlel to the molecular axis. We find that in contrast to the smooth behavior of the total cross section for perpendicular polarized light, the cross section for parallel polarized light shows an interesting oscillatory structure. The oscillations in the toted cross section may provide a method to determine the distance between the two centers. We explain the oscillation in the toted cross section as an interference effect using closed-orbit theory. We also cedculated the detached-electron flux distributions on a screen placed at a large distance from the negative molecular ion. The distributions display multiple-ring-like interference patterns. Such interference patterns are similar to those in the photodetachment microscopy experiments. 展开更多
关键词 quantum interference two-center model PHOTODETACHMENT
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Interferences in Photodetachment of a Negative Molecular Ion 被引量:1
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作者 Ahmad Afaq DU Meng-Li 《Communications in Theoretical Physics》 SCIE CAS CSCD 2006年第1X期119-122,共4页
The photodetachment of a negative molecular ion is studied theoretically using a two-center model. The detached electron wave function is obtained as a superposition of two coherent waves originating from each center.... The photodetachment of a negative molecular ion is studied theoretically using a two-center model. The detached electron wave function is obtained as a superposition of two coherent waves originating from each center. The photo-detached electron flux is evaluated on a screen placed at a large distance from the negative molecular ion. The electron flux on the screen displays strong interferences, the peak positions are related to the distance between the two centers in the negative molecular ion. We a/so obtained a simple analytical formula for the total photodetachment cross section. It approaches one and two times of the cross section for the one-center system in the high and lowphoton energy limits respectively. 展开更多
关键词 PHOTODETACHMENT quantum interference
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Measurement of tropospheric HO_(2) radical using fluorescence assay by gas expansion with low interferences 被引量:1
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作者 Yihui Wang Renzhi Hu +5 位作者 Pinhua Xie Hao Chen Fengyang Wang Xiaoyan Liu JianGuo Liu Wenqing Liu 《Journal of Environmental Sciences》 SCIE EI CAS CSCD 2021年第1期40-50,共11页
An instrument to detect atmospheric HO_(2) radicals using fluorescence assay by gas expansion(FAGE)technique has been developed.HO_(2) is measured by reaction with NO to form OH and subsequent detection of OH by laser... An instrument to detect atmospheric HO_(2) radicals using fluorescence assay by gas expansion(FAGE)technique has been developed.HO_(2) is measured by reaction with NO to form OH and subsequent detection of OH by laser-induced fluorescence at low pressure.The system performance has been improved by optimizing the expansion distance and pressure,the influence factors of HO_(2) conversion efficiency are also studied.The interferences of RO_(2) radicals were investigated by determining the conversion efficiency of RO_(2) to OH during the measurement of HO_(2).The dependence of the conversion of HO_(2) on NO concentration was investigated,and low HO_(2) conversion efficiency was selected to realize the ambient HO_(2) measurement,where the conversion efficiency of RO_(2) derived by propane,ethene,isoprene and methanol to OH has been reduced to less than 6%in the atmosphere.Furthermore,no significant interferences from PM_(2.5) and NO were found in the ambient HO_(2) measurement.The detection limits for HO_(2)(S/N=2)are estimated to 4.8×10^5 cm^-3 and 1.1×10^6 cm^-3(ρHO_(2)=20%)under night and noon conditions,with 60 sec signal integration time.The instrument was successfully deployed during STORM-2018 field campaign at Shenzhen graduate school of Peking University.The concentration of atmospheric HOx radical and the good correlation of OH with j(O1D)was obtained here.The diurnal variation of HOx concentration shows that the OH maximum concentration of those days is about 5.3×10^6 cm^-3 appearing around 12:00,while the HO_(2) maximum concentration is about 4.2×10^8 cm^-3 appearing around 13:30. 展开更多
关键词 HO_(2) radical FAGE interferENCE Environmental measurement
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Inter-well interferences and their influencing factors during water flooding in fractured-vuggy carbonate reservoirs 被引量:1
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作者 WANG Jing ZHAO Wei +5 位作者 LIU Huiqing LIU Fangna ZHANG Tuozheng DOU Liangbin YANG Xinling LI Bo 《Petroleum Exploration and Development》 2020年第5期1062-1073,共12页
Based on the characteristics of injection-production units in fractured-vuggy carbonate reservoirs,nine groups of experiments were designed and performed to analyze the interference characteristics and their influenci... Based on the characteristics of injection-production units in fractured-vuggy carbonate reservoirs,nine groups of experiments were designed and performed to analyze the interference characteristics and their influencing factors during water flooding.Based on percolation theory,an inversion model for simulating waterflooding interferences was proposed to study the influence laws of different factors on interference characteristics.The results show that well spacing,permeability ratio,cave size,and cave location all affect the interference characteristics of water flooding.When the cave is located in high permeability fractures,or in the small well spacing direction,or close to the producer in an injection-production unit,the effects of water flooding are much better.When the large cave is located in the high-permeability or small well spacing direction,the well in the direction with lower permeability or smaller well spacing will see water breakthrough earlier.When the cave is in the higher permeability direction and the reserves between the water injector and producer differ greatly,the conductivity differences in different injection-production directions are favorable for water flooding.When the injection-production well pattern is constructed or recombined,it’s better to make the reserves of caves in different injection-production directions proportional to permeability,and inversely proportional to the well spacing.The well close to the cave should be a producer,and the well far from the cave should be an injector.Different ratios of cave reserves to fracture reserves correspond to different optimal well spacings and optimal permeability ratios.Moreover,both optimal well spacing and optimal permeability ratio increase as the ratio of cave reserves to fracture reserves increases. 展开更多
关键词 fractured-vuggy carbonate reservoir water flooding inter-well interference physical modeling experiment numerical inversion
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RESEARCH ON REAL-TIME CORRECTOR OF SPECTRAL INTERFERENCES
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作者 王金成 宇正武 +1 位作者 白梅 沈兰荪 《Journal of Electronics(China)》 1992年第3期278-282,共5页
Further advancement of ICP-AES analytical technique is hindered by complex spec-tral interferences.The correction algorithms recently proposed need too much computation andtime to run in real time on general microcomp... Further advancement of ICP-AES analytical technique is hindered by complex spec-tral interferences.The correction algorithms recently proposed need too much computation andtime to run in real time on general microcomputers.In this paper,a new kind of spectral interfer-ence fast correcting system(SIFCS)was developed,in which the hardware is a TMS32020 digitalsignal processing board in IBM-PC I/O channel and the software is composed of a correctingprogram based on a new effective algorithm and a master program on IBM-PC.Experimentsshow that the processing speed on SIFCS is 50-100 times faster than that on IBM-PC/AT.Thismakes real-time correction of spectral interferences feasible. 展开更多
关键词 ICP-AES SPECTRAL interferENCE Digital SIGNAL PROCESSOR
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On Broadband Adaptive Beamforming in the Presence of Correlated Interferences 被引量:1
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作者 Jing-Ran Lin Qi-Cong Peng Huai-Zong Shao Tai-Liang Ju 《Journal of Electronic Science and Technology of China》 2007年第2期175-179,共5页
A novel approach of unitarily interpolated array MVDR (UIA-MVDR) is proposed, aiming at avoiding the signal cancellation caused by broadband signal-correlated interferences. UIA-MVDR belongs to the classic approache... A novel approach of unitarily interpolated array MVDR (UIA-MVDR) is proposed, aiming at avoiding the signal cancellation caused by broadband signal-correlated interferences. UIA-MVDR belongs to the classic approaches of spectral averaging. However, it is distinguished from the conventional interpolated array MVDR (IA-MVDR) by two points: 1) It imposes a unitary constraint on the transform matrices. 2) It only optimizes the worst-case performance of array manifold approximation. As a result, the restriction on the order of Bessel function expansion is released, so that very accurate approximation can be achieved even in the case of small or middle arrays. Compared with many related approaches, UIA-MVDR destroys the correlation more completely and then achieves better performance. Its excellent performance in both correlated and uncorrelated broadband interferences suppression is confirmed via a n umber of numerical examples. 展开更多
关键词 Broadband adaptive beamforming correlated interferences spectral averaging unitary constraint worst-case performance optimization.
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Interferences in photo-detached electron spectra from a non-collinear tri-atomic anion
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作者 A.Afaq K.Farooq +1 位作者 M.A.Khan 衣学喜 《Chinese Physics B》 SCIE EI CAS CSCD 2014年第10期114-117,共4页
The electron flux oscillations in photo-detachment of a non-collinear tri-atomic anion have been studied by taking each atom of the system as a coherent source of detached-electron wave. These electron waves traversin... The electron flux oscillations in photo-detachment of a non-collinear tri-atomic anion have been studied by taking each atom of the system as a coherent source of detached-electron wave. These electron waves traversing along three different trajectories result in a quantum interference. An analytical expression of detached-electron flux is evaluated for various detached-electron energies and for different geometrical shapes of the system. The results show that the electron flux distributions exhibit molecular shape-induced oscillatory structures. These oscillations are explained using the semi- classical closed-orbit theory; the outgoing electron waves produced from one center are propagated in the vicinity of the sources at other centers. It is also observed that in a particular case our non-collinear tri-atomic system reduces to the collinear tri-atomic system recently published. 展开更多
关键词 electron flux collinear tri-atomic system quantum interference
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Quantum interferences in four-wave mixing processes inside a cavity driven by quantized fields
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作者 李蓬勃 《Chinese Physics B》 SCIE EI CAS CSCD 2011年第5期250-254,共5页
Interferences in the quantum fluctuations of the output fields are demonstrated in four-wave mixing processes inside a cavity, which is driven by two quantized fields at the signal and the idler frequencies. These int... Interferences in the quantum fluctuations of the output fields are demonstrated in four-wave mixing processes inside a cavity, which is driven by two quantized fields at the signal and the idler frequencies. These interferences depend on the phase fluctuations of the input fields and induce mode splitting in the transmission spectra. 展开更多
关键词 quantum interferences and coherence four-wave mixing
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Factors affecting the performance of a multi-tone carrier source based re-circulating frequency shifter
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作者 席丽霞 李建平 +2 位作者 张晓光 田凤 张文博 《Chinese Physics B》 SCIE EI CAS CSCD 2011年第8期210-215,共6页
Generation of single-sideband (SSB) multi-carrier source based on a recirculating frequency shifter (RFS) is anal- ysed theoretically and realized experimentally. The effects of affecting factors originating from ... Generation of single-sideband (SSB) multi-carrier source based on a recirculating frequency shifter (RFS) is anal- ysed theoretically and realized experimentally. The effects of affecting factors originating from the deviation from the right operation bias voltage and unbalanced amplitude, and the phase of the radio frequency (RF) drive signals on the performance of the multi-tone source are discussed in detail. Based on the theoretical analysis, high-quality 50-tone out- put is successfully realized. Experiments under some implementation imperfections are also carried out. The imperfect and low-quality output results are in good agreement with theoretical analysis. 展开更多
关键词 multi-tone carrier source recirculating frequency shifter affecting factors
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A Pragmatic Approach to Coping with Matrix Effects during ICP-MS Analysis of Trace Elements in Silicate Rocks and Calibration of REE Interferences
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作者 C. Michael B. Henderson Paul R. Lythgoe Karen J. Theis 《Journal of Geoscience and Environment Protection》 2019年第3期82-125,共44页
Operating an Agilent 7700X ICP-MS spectrometer under robust plasma conditions (1550 W) with a He-filled octopole collision cell and analysing solutions (?1 total dissolved solids) still suffered analyte peak suppressi... Operating an Agilent 7700X ICP-MS spectrometer under robust plasma conditions (1550 W) with a He-filled octopole collision cell and analysing solutions (?1 total dissolved solids) still suffered analyte peak suppression due to matrix effects. International reference rocks BCR-1, BHVO-1, AGV-1, G-2 and BCR-2 all showed count rate reductions for 36 elements (mass range 7Li to 238U) averaging ~10% but with no dependence on isotope mass. Use of an internal standard (103Rh) and/or using a ten-fold dilution of sample solutions reduced these effects but problems with reduced count rates combined with larger errors for some elements introduced other problems. The best approach was to normalise the count rates for each element in the other samples against those for BCR-1 as an external standard;thus the count suppression due to the matrix effect is corrected for each individual element. This approach provides standardization “traceability” in line with the ERM ISO/IEC requirement. Experiments are also reported on quantifying the proportions of Ba and selected REE oxide/hydroxide components versus parent isotopes (XO/X and XOH/X). This information is essential for correcting peak interferences on higher mass number REE for the rock samples, and equations are developed to use measured CeO/Ce and CeOH/Ce ratios to predict such values for any other member of the REE suite. Concentrations obtained show excellent agreement with recommended values for the international reference materials especially for the REE. Robust data are also provided for two other standard rocks: nepheline syenite STM-1 and quartz syenite CAAS-1;the latter shows exceptional enrichments of Zr, REE, Th, and U. 展开更多
关键词 ICP-MS Dilution Minimises Matrix Effects BCR-1 as an External Standard New Analyses for STM-1 and CAAS-1 CALIBRATION of X-O/OH interferences on REE Elements
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