Grain boundary engineering plays a significant role in the improvement of strength and plasticity of alloys. However, in refractory high-entropy alloys, the susceptibility of grain boundaries to oxygen presents a bott...Grain boundary engineering plays a significant role in the improvement of strength and plasticity of alloys. However, in refractory high-entropy alloys, the susceptibility of grain boundaries to oxygen presents a bottleneck in achieving high mechanical performance. Creating a large number of clean grain boundaries in refractory high-entropy alloys is a challenge. In this study, an ultrafine-grained (UFG) NbMoTaW alloy with high grain-boundary cohesion was prepared by powder metallurgy, taking advantages of rapid hot-pressing sintering and full-process inert atmosphere protection from powder synthesis to sintering. By oxygen control and an increase in the proportion of grain boundaries, the segregation of oxygen and formation of oxides at grain boundaries were strongly mitigated, thus the intrinsic high cohesion of the interfaces was preserved. Compared to the coarse-grained alloys prepared by arc-melting and those sintered by traditional powder metallurgy methods, the UFG NbMoTaW alloy demonstrated simultaneously increased strength and plasticity at ambient temperature. The highly cohesive grain boundaries not only reduce brittle fractures effectively but also promote intragranular deformation. Consequently, the UFG NbMoTaW alloy achieved a high yield strength even at elevated temperatures, with a remarkable performance of 1117 MPa at 1200 ℃. This work provides a feasible solution for producing refractory high-entropy alloys with low impurity content, refined microstructure, and excellent mechanical performance.展开更多
This article investigated the factors and mechanisms that affected the workability and mechanical properties of cement paste incorporating nano-TiO_(2).The findings indicated that,for nano-TiO_(2)aqueous solution conc...This article investigated the factors and mechanisms that affected the workability and mechanical properties of cement paste incorporating nano-TiO_(2).The findings indicated that,for nano-TiO_(2)aqueous solution concentrations of 3%,6%,9%,and 12%,the optimal dispersion effect was achieved with an ultrasonic dispersion time of 20 minutes.Specifically,at a 6%nano-TiO_(2)content,both the workability and mechanical performance of the cement paste were enhanced.Furthermore,while nano-TiO_(2)did not alter the types of hydration products present in the cement paste,it did increase the amount of C-S-H gels.This enhancement was attributed to a higher number of nucleation sites for hydration products,which promoted hydration and reduced the porosity of the cement paste.展开更多
The unbreakable doll performance at Tang Dynasty Night City has become extremely popular,sparking a wave of enthusiasm online.In the performance,actors dressed in elegant Tang Dynasty attire appear as if they have ste...The unbreakable doll performance at Tang Dynasty Night City has become extremely popular,sparking a wave of enthusiasm online.In the performance,actors dressed in elegant Tang Dynasty attire appear as if they have stepped out of a historical painting,gracefully dancing on the unbreakable doll apparatus.Every gesture and expression exudes the unparalleled elegance of the Tang Dynasty.This paper primarily analyzes the mechanical principles behind the Tang Dynasty Night City’s Unbreakable Doll Performance,starting with structural design to examine its mechanical principles and summarize its dynamic mechanical control mechanisms.展开更多
A steel-concrete composite cable-stayed bridge features integrated steel girders and concrete decks linked by shear connectors to support loads,but stress concentration in wet joints can lead to cracking.In-situ tests...A steel-concrete composite cable-stayed bridge features integrated steel girders and concrete decks linked by shear connectors to support loads,but stress concentration in wet joints can lead to cracking.In-situ tests were conducted on key sections of steel-concrete composite cable-stayed bridges to analyze the stress-strain evolution of wet joints under environmental factors,constraints,and complex construction processes.The coordinated working performance of the bridge decks was also analyzed.The results indicate that temperature is the key factor affecting the stresses and strains in wet joint concrete.Approximately 7 days after casting the wet joint concrete,the strains at each measurement point of the wet joint are approximately negatively correlated with the temperature change at the measurement point.Different locations within the wet joints have respective impacts,presenting potential weak points.Construction conditions have a certain impact on the stress and strain of the wet joint.The top deck of the steel box girder is not fully bonded to the bottom surface of the wet joints,resulting in a certain strain difference after loading.To further analyze the cooperative working performance of steel box girders and concrete wet joint bridge deck systems,finite element analysis was conducted on composite girder structures.A stiffness calculation method for shear connectors based on numerical simulation was proposed.The results indicate that strain differences can cause interface slip in composite girders.This slip leads to increased deflection of the composite girders and increased tensile stress in the bottom plate of the steel box girders.This study clarifies the stress conditions and factors affecting wet joints during construction,preventing early cracking,and offers precise data for a full bridge finite element model.展开更多
The waterproof performance,mechanical properties,chemical composition,microstructure,and pore structure of hydrophobically-modified geopolymer concrete are investigated before and after dry-wet cycles,to determine the...The waterproof performance,mechanical properties,chemical composition,microstructure,and pore structure of hydrophobically-modified geopolymer concrete are investigated before and after dry-wet cycles,to determine the long-term feasibility of using hydrophobically-modified geopolymer concrete in wet environments.We use two types of organic modifying agents:polydimethylsiloxane(PDMS)and sodium methyl siliconate(SMS).The experimental results show that incorporating 2%–6%PDMS or 5%–15%SMS can make the concrete hydrophobic,with water absorption and chloride transport rates decreasing by up to 94.3%.We also analyze the bonding modes of organic molecules and geopolymer gels,as well as their evolution mechanisms during dry-wet cycles.PDMS-modified geopolymer concrete is found to exhibit long-term waterproof performance that is not weakened by dry-wet cycles.This is attributed to the robust combination of organic components and the geopolymer gel skeleton formed through phase cross-linking.Meanwhile,PDMS-modified geopolymer concrete’s hydrophobicity,strength,and microstructure are essentially unaffected.In contrast,SMS-modified geopolymer concrete shows higher water sensitivity,although it does maintain efficient waterproof performance.Due to relatively low binding energy,the dry-wet cycles may lead to the detachment of some SMS molecules from the gel network,which results in a decrease of 18.6%in compressive strength and an increase of 37.6%in total porosity.This work confirms the utility of hydrophobically-modified geopolymer concrete as a building material for long-term service in wet environments,for instance,areas with frequent precipitation,or splash and tidal zones.展开更多
Floating photovoltaic(FPV)technology is emerging as a highly promising approach to accelerate decarbonization of the global economy,due to its higher power generation efficiency and lower land occupation.With the rapi...Floating photovoltaic(FPV)technology is emerging as a highly promising approach to accelerate decarbonization of the global economy,due to its higher power generation efficiency and lower land occupation.With the rapid development of FPV technology,the mechanical performance degradation of key components caused by the harsh marine environment has become a pressing issue,as it significantly contributes to failure behavior observed in FPV systems.A comprehensive compilation of the mechanical performance of key components in FPV systems is also currently unavailable.Here,the mechanical behavior of each structural component in FPV systems under harsh marine environments is systematically reviewed.It further emphasizes the synergistic effects of mechanical performance degradation among different components on the overall system.The drop-off rate(v)of normalized elongation at break(EAB)of polymer under the synergistic effect of various environmental factors increases from 7.5×10^(−4)h^(−1)to 21.8×10^(−4)h^(−1)compared with the single environmental stress.Moreover,the development of novel materials and innovative mechanical structures applied in FPV systems to enhance mechanical performance is discussed.The novel flexible PV modules applied in FPV systems minimize the loads acting on the mooring lines by 80%and increase power generation by 5%.Notably,this paper provides a theoretical foundation for developing standards of FPV systems,especially the establishment of standards related to the synergistic effects of the mechanical performance degradation of different key components on FPV systems.展开更多
AZ31B magnesium alloy is widely used in transportation and aerospace fields due to its light weight and high strength,but it often causes structural failure due to fatigue fracture during service.Fatigue fracture is u...AZ31B magnesium alloy is widely used in transportation and aerospace fields due to its light weight and high strength,but it often causes structural failure due to fatigue fracture during service.Fatigue fracture is usually caused by the initiation of cracks on the surface of structural parts and the propagation of cracks to the interior of the specimen in the form of intergranular fracture.In order to improve the fatigue performance,this study proposes a method of pre-tension deformation and surface mechanical rolling treatment of AZ31B magnesium alloy,thereby changing the crack initiation area and increasing the crack propagation resistance.The experimental results show that:As the pre-tension deformation increases,the fatigue limit shows a trend of first rising and then decreasing.The 5PT specimen exhibits the optimal strengthening effect,with a fatigue limit of 115 MPa,which is a 27.78% improvement.Under surface mechanical rolling treatment,the fatigue limit reaches 140 MPa,which is a 55.56% improvement.When pre-tension deformation and surface mechanical rolling treatment are combined,the fatigue limit is further improved compared to individual strengthening methods.Among these,the 2PT+SMRT specimen shows the most significant strengthening effect,with a fatigue limit of 150 MPa,which is a 66.67% improvement.This study proposes a new strategy for improving the fatigue performance of AZ31B magnesium alloy,and reveals the synergistic strengthening mechanism of pre-tension deformation and surface mechanical rolling treatment of AZ31B magnesium alloy,which is of great significance for improving the fatigue performance of metal materials.展开更多
This paper aims to find the relationship between the structural parameters and the radial stiffness of the braided stent and to understand the stress distribution law of the wires. According to the equation of the spa...This paper aims to find the relationship between the structural parameters and the radial stiffness of the braided stent and to understand the stress distribution law of the wires. According to the equation of the space spiral curve, a three-dimensional parametrical geometrical model is constructed. The finite element model is built by using the beam-beam contact elements and 3D beam elements. The constituent nitinol wires are assumed to be linear elastic material. The finite element analysis figures out that the radial stiffness of the stent and the stress distribution of the wires are influenced by all the structural parameters. The helix pitch of the wires is the most important factor. Under the condition of the same load and other structural parameters remaining unchanged, when the number of wires is 24, the stress of the wire crosssection is at the minimum. A comparison between the vitro experimental results and the analytical results is conducted, and the data is consistent, which proves that the current finite element model can be used to appropriately predict the mechanical performance of the braided esophageal stents.展开更多
Neuromorphic devices have shown great potential in simulating the function of biological neurons due to their efficient parallel information processing and low energy consumption.MXene-Ti_(3)C_(2)T_(x),an emerging two...Neuromorphic devices have shown great potential in simulating the function of biological neurons due to their efficient parallel information processing and low energy consumption.MXene-Ti_(3)C_(2)T_(x),an emerging twodimensional material,stands out as an ideal candidate for fabricating neuromorphic devices.Its exceptional electrical performance and robust mechanical properties make it an ideal choice for this purpose.This review aims to uncover the advantages and properties of MXene-Ti_(3)C_(2)T_(x)in neuromorphic devices and to promote its further development.Firstly,we categorize several core physical mechanisms present in MXene-Ti_(3)C_(2)T_(x)neuromorphic devices and summarize in detail the reasons for their formation.Then,this work systematically summarizes and classifies advanced techniques for the three main optimization pathways of MXene-Ti_(3)C_(2)T_(x),such as doping engineering,interface engineering,and structural engineering.Significantly,this work highlights innovative applications of MXene-Ti_(3)C_(2)T_(x)neuromorphic devices in cutting-edge computing paradigms,particularly near-sensor computing and in-sensor computing.Finally,this review carefully compiles a table that integrates almost all research results involving MXene-Ti_(3)C_(2)T_(x)neuromorphic devices and discusses the challenges,development prospects,and feasibility of MXene-Ti_(3)C_(2)T_(x)-based neuromorphic devices in practical applications,aiming to lay a solid theoretical foundation and provide technical support for further exploration and application of MXene-Ti_(3)C_(2)T_(x)in the field of neuromorphic devices.展开更多
To study the influence of rolling on the interfaces and mechanical performance of graphene-reinforced Al-matrix composites,a rolling method was used to process them.Using scanning electron microscopy(SEM),transmission...To study the influence of rolling on the interfaces and mechanical performance of graphene-reinforced Al-matrix composites,a rolling method was used to process them.Using scanning electron microscopy(SEM),transmission electron microscopy(TEM),X-ray diffraction(XRD),Raman spectroscopy,and tensile testing,this study analyzed the micromorphology,interfaces,and mechanical performance of the composites before and after rolling.The experimental results demonstrates that the composites after hot rolling has uniform structures with strong interfacial bonding.With an increase in rolling temperature,the tensile strength and elastic modulus of the composites gradually increase.However,when the rolling temperature is higher than 500°C,granular and rod-like Al4C3 phases are observed at the interfaces and the mechanical performance of the composites is degraded.When the rolling temperature is 480°C,the composites show the optimal comprehensive mechanical performance,with a tensile strength and elastic modulus of 403.3 MPa and 77.6 GPa,respectively,which represent increases of 31.6%and 36.9%,respectively,compared with the corresponding values prior to rolling.展开更多
To understand the enhancing effect and fiber-reinforced mechanism of composite fibers reinforced cement concrete, the influences of composite fibers on micro-cracks and the distribution of composite fibers were evalua...To understand the enhancing effect and fiber-reinforced mechanism of composite fibers reinforced cement concrete, the influences of composite fibers on micro-cracks and the distribution of composite fibers were evaluated by optical electron micrometer(OEM) and scanning electron microscope(SEM). Three kinds of fiber, such as polyacrylonitrile-based carbon fiber, basalt fiber, and glass fiber, were used in the composite fibers reinforced cement concrete. The composite fibers could form a stable structure in concrete after the liquid-phase coupling treatment, gas-liquid double-effect treatment, and inert atmosphere drying. The mechanical properties of composite fibers reinforced concrete(CFRC) were studied by universal test machine(UTM). Moreover, the effect of composite fibers on concrete was analyzed based on the toughness index and residual strength index. The results demonstrated that the composite fibers could improve the mechanical properties of concrete, while the excessive amount of composite fibers had an adverse effect on the mechanical properties of concrete. The composite fibers could significantly improve the toughness index of CFRC, and the increment rate is more than 30%. The composite fibers could form a mesh structure, which could promote the stability of concrete and guarantee the excellent mechanical properties.展开更多
The effect of rare earth element Ce on mechanical performance and electrical conductivity of aluminum rod for electrical purpose were studied under industrial production condition. Using optical microscope, SEM, TEM, ...The effect of rare earth element Ce on mechanical performance and electrical conductivity of aluminum rod for electrical purpose were studied under industrial production condition. Using optical microscope, SEM, TEM, EDS and X-ray diffractometer, the microstructure and phase composition of aluminum rod were measured and analyzed. The results indicate that the content of rare earth element Ce is between 0.05% -0.16% in the aluminum rod for electrical purpose. Its tensile strength is enhanced to some extent. The research also discovers that the tensile strength is enhanced remarkably with impurity element Si content increases. Because influence of Si is big to the conductivity, the Si content should be controlled continuously strictly in the aluminum for electrical purpose. Adding rare earth element Ce reduces the solid solubility of Si in the aluminum matrix, and the negative effect of Si on the aluminum conductor reduces effectively. So the limit of in Si content in aluminum rod for electrical purpose can be relaxed moderately.展开更多
The average stiffness performance indices throughout the workspace are commonly used as global stiffness performance indices to evaluate the overall stiffness performance of parallel mechanisms,which involves an analy...The average stiffness performance indices throughout the workspace are commonly used as global stiffness performance indices to evaluate the overall stiffness performance of parallel mechanisms,which involves an analysis of the stiffness performance of numerous discrete points in the workspace.This necessitates time-consuming and inefficient calculation,which is particularly pronounced in the optimization design stage of the mechanism,where the variations in the global stiffness performance indices versus various dimensional and structural parameters need to be analyzed.This paper presents a semi-analytical approach for stiffness modeling of the novel(R(RPS&RP))&2-UPS parallel mechanism(referred to as the Trifree mechanism)and proposes“local”stiffness performance indices as alternatives to global indices.Drawing on the screw theory,the Cartesian stiffness matrix of the Trifree mechanism is formulated explicitly by considering the compliances of all elastic elements and the over-constraint characteristics inherent in the mechanism.Based on the spherical motion pattern of the Trifree mechanism,four special reference configurations are extracted within the workspace.This yields“local”stiffness performance indices capable of accurately evaluating the overall stiffness performance of the mechanism and effectively improving the computational efficiency.The variations in global and“local”stiffness performance indices versus key design parameters are investigated.Furthermore,the proposed indices are applied to the Tricept and Trimule mechanisms.The results demonstrate that the proposed indices exhibit excellent computational accuracy and efficiency in evaluating the overall stiffness performance of these spherical parallel mechanisms.Moreover,the stiffness performance of the novel parallel mechanism investigated in this study closely resembles that of the well-known Tricept and Trimule mechanisms.This research proposes a semi-analytic stiffness model of the Trifree mechanism and“local”stiffness performance indices to evaluate the overall stiffness performance,thereby substantially improving the computational efficiency without sacrificing accuracy.展开更多
High entropy materials(HEMs)are the promising electrocatalysts for anion exchange membrane electrolyser(AEMs)and proton exchange membrane fuel cells(PEMFCs)due to the intriguing cocktail effect,wide design space,tailo...High entropy materials(HEMs)are the promising electrocatalysts for anion exchange membrane electrolyser(AEMs)and proton exchange membrane fuel cells(PEMFCs)due to the intriguing cocktail effect,wide design space,tailorable electronic structure,and entropy stabilization effect.The precise fabrication of HEMs with functional nanostructures provides a crucial avenue to optimize the adsorption strength and catalytic activity for electrocatalysis.This review comprehensively summarizes the development of HEMs,focusing on the principles and strategies of structural design,and the catalytic mechanism towards hydrogen evolution reaction,oxygen evolution reaction and oxygen reduction reaction for the development of high-performance electrocatalysts.The complexity inherent in the interactions between different elements,the changes in the d-band center and the Gibbs free energies during the catalytic progress,as well as the coordination environment of the active sites associated with the unique crystal structure to improve the catalytic performance are discussed.We also provide a perspective on the challenges and future development direction of HEMs in electrocatalysis.This review will contribute to the design and development of HEMs-based catalysts for the next generation of electrochemical applications.展开更多
Rare earth -containing PSBR sheet was prepared by reaction of rare earth alkoxide with quaternary ammonium salt of pyridine modified SBR (PSBR) latex, and then it was blended with natural rubber (NR) to produce rare e...Rare earth -containing PSBR sheet was prepared by reaction of rare earth alkoxide with quaternary ammonium salt of pyridine modified SBR (PSBR) latex, and then it was blended with natural rubber (NR) to produce rare earth - containing composite elastomer. It is found that mechanical performance can be improved remarkably. Analyzed by infrared spectrometry (IR), differential scanning calorimetry (DSC) and cross-linking densitometry, the relationship between structure and performance was discussed.展开更多
In petroleum extraction,the sealing surfaces of bolted joints are susceptible to damage due to the high-temperature and high-pressure conditions in wellbores.This damage adversely affects sealing performance,consequen...In petroleum extraction,the sealing surfaces of bolted joints are susceptible to damage due to the high-temperature and high-pressure conditions in wellbores.This damage adversely affects sealing performance,consequently leading to the failure and damage of threaded connections.In severe cases,it can result in considerable economic losses and trigger safety accidents.The sealing performance of special bolted joints holds crucial importance for production efficiency,output,equipment lifespan,and cost control.Enhancing the sealing perfor-mance of threaded connections can have a positive impact on industrial production and environmental protection.The existing research on American Petroleum Institute threaded joints has been thorough and has obtained a series of excellent results.However,the research on the sealing damage mechanism of threaded connections under complex well conditions lacks sufficient depth and that on new sealing technology is scarce.This study proposes a half-size evaluation test to address the abovementioned problem.Based on this test,an investigation into the sealing performance of threaded connections under high-temperature,cyclic loading,and high-temperature creep conditions is conducted.This study uses a combined approach of finite element methods and experiments to investigate the impact of different makeup torques on the sealing performance of premium threaded connections(PTCs).The results of the half-size evaluation test indicate that temperature notably influences the sealing performance of threaded connections.The continuous action of high temperatures causes contact pressure and sealing performance to decrease,and sealing contact pressure increases after cooling.Finite element and test results show that for a certain joint A,the greater the torque,the higher the critical sealing pressure of the thread,and the better the sealing performance.The research on the sealing damage mechanism of PTCs provides a scientific basis and theoretical guidance for the further optimization and development of PTCs.展开更多
To quantify the nonuniform micromechanical performance of welded joint,the load-displacement curves by nanoindentation test were introduced to examine different zones including base metal,coarse grained heat affected ...To quantify the nonuniform micromechanical performance of welded joint,the load-displacement curves by nanoindentation test were introduced to examine different zones including base metal,coarse grained heat affected zone,partially melted zone,weld metal near the fusion boundary and weld metal center.The results showed that the strengthening effect of weld metal was more obvious than that of heat affected zone for nickel based welded joint and especially in coarse grained heat affected zone,the hardening resulted from overheating was not apparent.Nickel based weld metal with high content of alloying elements which were often segregated at interdendritic regions or precipitated in grain interior under nonequilibrium solidification contributed to the characteristics that differ from conventional low alloy steel welded joint.展开更多
Thermal barrier coatings(TBCs)are extensively utilized in aero-engines and heavy-duty gas turbines due to their outstanding properties,including low thermal conductivity,corrosion,high-temperature oxidation,and wear r...Thermal barrier coatings(TBCs)are extensively utilized in aero-engines and heavy-duty gas turbines due to their outstanding properties,including low thermal conductivity,corrosion,high-temperature oxidation,and wear resistance.The rising thrust-to-weight ratio and service temperature in engine hot sections have presented a significant challenge in TBC's materials,structure,and preparation process;it is one of the current research hotspots in the aviation field.This paper reviews the recent advancement in turbine blade TBCs.It focuses on the TBC's structure,deposition mechanism and the key performance evaluation indexes for TBCs applied to turbine blades.Finally,the future research field of TBCs for turbine blades is also be prospected.展开更多
Water-induced disasters in long-distance pipelines are prevalent geological hazards,characterized by their frequency and widespread distribution.The complexity of factors contributing to pipeline damage in practical e...Water-induced disasters in long-distance pipelines are prevalent geological hazards,characterized by their frequency and widespread distribution.The complexity of factors contributing to pipeline damage in practical engineering poses a significant challenge for analysis using solely theoretical models.This study systematically reveals the cross-scale failure mechanism of long-distance pipelines under hydrodynamic impact through the combination of multi-scale experimental representation and theoretical modeling.Employing a combination of macroscopic measurements,advanced material testing of residual samples from failed pipelines,and consideration of operational conditions and environmental factors,the failure modes is systematically analyzed.The findings reveal that under the vibrations induced by water impulses,the pipe material exhibits a pronounced ratchet effect,leading to an 8.92%reduction in elongation at break.Furthermore,the Bauschinger effect is observed,resulting in a 2.95%decrease in yield strength.Cyclic hardening significantly diminishes the impact toughness of the weld by 22.2%.Notably,at high vibration frequencies of approximately 18.98 Hz,the stress concentration in the girth weld near the axial midpoint of the pipe section initiates cracking,ultimately leading to failure under the alternating load generated by the oscillation.This study provides valuable insights into the scientific understanding of pipeline failure mechanisms under water impact,contributing to the development ofmore robust and resilient pipeline systems.展开更多
A near-equiatomic NiTi shape memory alloy was fabricated by rapid solidification process through vacuum arc melting followed by vacuum suction casting in water-cooled thick copper mold. The rapidly solidified （or suc...A near-equiatomic NiTi shape memory alloy was fabricated by rapid solidification process through vacuum arc melting followed by vacuum suction casting in water-cooled thick copper mold. The rapidly solidified （or suction cast） NiTi alloy shows much finer grains and homogenous microstructure, in particular a uniform distribution of various fine precipitates, compared to the conventional cast one. The resultant alloy also exhibits the homogenous Ni distribution in the matrix of the alloy, allowing the martensitic transformation to take place throughout the NiTi alloy matrix simultaneously and resulting in sharper transformation peaks compared to the conventional cast alloy. Moreover, the suction cast NiTJ alloy shows a significant improvement over the conventional cast one, in terms of possessing higher deformation recovery rates and displaying the increased compressive strength and damping capacity by 4% and 20%, respectively.展开更多
基金supported by the National Natural Science Foundation of China(Nos.52371128,52304378,52101031 and 92163107).
文摘Grain boundary engineering plays a significant role in the improvement of strength and plasticity of alloys. However, in refractory high-entropy alloys, the susceptibility of grain boundaries to oxygen presents a bottleneck in achieving high mechanical performance. Creating a large number of clean grain boundaries in refractory high-entropy alloys is a challenge. In this study, an ultrafine-grained (UFG) NbMoTaW alloy with high grain-boundary cohesion was prepared by powder metallurgy, taking advantages of rapid hot-pressing sintering and full-process inert atmosphere protection from powder synthesis to sintering. By oxygen control and an increase in the proportion of grain boundaries, the segregation of oxygen and formation of oxides at grain boundaries were strongly mitigated, thus the intrinsic high cohesion of the interfaces was preserved. Compared to the coarse-grained alloys prepared by arc-melting and those sintered by traditional powder metallurgy methods, the UFG NbMoTaW alloy demonstrated simultaneously increased strength and plasticity at ambient temperature. The highly cohesive grain boundaries not only reduce brittle fractures effectively but also promote intragranular deformation. Consequently, the UFG NbMoTaW alloy achieved a high yield strength even at elevated temperatures, with a remarkable performance of 1117 MPa at 1200 ℃. This work provides a feasible solution for producing refractory high-entropy alloys with low impurity content, refined microstructure, and excellent mechanical performance.
基金Funded by National Natural Science Foundation of China(No.52108188)State Key Laboratory of Silicate Materials for Architectures(Wuhan University of Technology)(No.SYSJJ2024-15)+3 种基金State Key Laboratory of Mountain Bridge and Tunnel Engineering,Chongqing Jiaotong University(No.SKLBT-2301)Opening Project of State Key Laboratory of Green Building Materials(No.2022GBM10)Open Research Fund of Key Laboratory of Engineering Materials of Ministry of Water Resources,China Institute of Water Resources and Hydropower Research(No.EMF202407)General Project of Science and Technology Plan of Beijing Municipal Commission of Education(No.KM202110005018)。
文摘This article investigated the factors and mechanisms that affected the workability and mechanical properties of cement paste incorporating nano-TiO_(2).The findings indicated that,for nano-TiO_(2)aqueous solution concentrations of 3%,6%,9%,and 12%,the optimal dispersion effect was achieved with an ultrasonic dispersion time of 20 minutes.Specifically,at a 6%nano-TiO_(2)content,both the workability and mechanical performance of the cement paste were enhanced.Furthermore,while nano-TiO_(2)did not alter the types of hydration products present in the cement paste,it did increase the amount of C-S-H gels.This enhancement was attributed to a higher number of nucleation sites for hydration products,which promoted hydration and reduced the porosity of the cement paste.
文摘The unbreakable doll performance at Tang Dynasty Night City has become extremely popular,sparking a wave of enthusiasm online.In the performance,actors dressed in elegant Tang Dynasty attire appear as if they have stepped out of a historical painting,gracefully dancing on the unbreakable doll apparatus.Every gesture and expression exudes the unparalleled elegance of the Tang Dynasty.This paper primarily analyzes the mechanical principles behind the Tang Dynasty Night City’s Unbreakable Doll Performance,starting with structural design to examine its mechanical principles and summarize its dynamic mechanical control mechanisms.
文摘A steel-concrete composite cable-stayed bridge features integrated steel girders and concrete decks linked by shear connectors to support loads,but stress concentration in wet joints can lead to cracking.In-situ tests were conducted on key sections of steel-concrete composite cable-stayed bridges to analyze the stress-strain evolution of wet joints under environmental factors,constraints,and complex construction processes.The coordinated working performance of the bridge decks was also analyzed.The results indicate that temperature is the key factor affecting the stresses and strains in wet joint concrete.Approximately 7 days after casting the wet joint concrete,the strains at each measurement point of the wet joint are approximately negatively correlated with the temperature change at the measurement point.Different locations within the wet joints have respective impacts,presenting potential weak points.Construction conditions have a certain impact on the stress and strain of the wet joint.The top deck of the steel box girder is not fully bonded to the bottom surface of the wet joints,resulting in a certain strain difference after loading.To further analyze the cooperative working performance of steel box girders and concrete wet joint bridge deck systems,finite element analysis was conducted on composite girder structures.A stiffness calculation method for shear connectors based on numerical simulation was proposed.The results indicate that strain differences can cause interface slip in composite girders.This slip leads to increased deflection of the composite girders and increased tensile stress in the bottom plate of the steel box girders.This study clarifies the stress conditions and factors affecting wet joints during construction,preventing early cracking,and offers precise data for a full bridge finite element model.
基金supported by the National Natural Science Foundation of China(Nos.52101328 and 52171277)the National Key Research and Development Program of China(No.2022YFE0109200)+1 种基金the Foundation of the Shanxi-Zheda Institute of Advanced Materials and Chemical Engineering(No.2022SZ-TD006)the Postdoctoral Fellowship Program of China Postdoctoral Science Foundation(CPSF)(No.GZB20230653)。
文摘The waterproof performance,mechanical properties,chemical composition,microstructure,and pore structure of hydrophobically-modified geopolymer concrete are investigated before and after dry-wet cycles,to determine the long-term feasibility of using hydrophobically-modified geopolymer concrete in wet environments.We use two types of organic modifying agents:polydimethylsiloxane(PDMS)and sodium methyl siliconate(SMS).The experimental results show that incorporating 2%–6%PDMS or 5%–15%SMS can make the concrete hydrophobic,with water absorption and chloride transport rates decreasing by up to 94.3%.We also analyze the bonding modes of organic molecules and geopolymer gels,as well as their evolution mechanisms during dry-wet cycles.PDMS-modified geopolymer concrete is found to exhibit long-term waterproof performance that is not weakened by dry-wet cycles.This is attributed to the robust combination of organic components and the geopolymer gel skeleton formed through phase cross-linking.Meanwhile,PDMS-modified geopolymer concrete’s hydrophobicity,strength,and microstructure are essentially unaffected.In contrast,SMS-modified geopolymer concrete shows higher water sensitivity,although it does maintain efficient waterproof performance.Due to relatively low binding energy,the dry-wet cycles may lead to the detachment of some SMS molecules from the gel network,which results in a decrease of 18.6%in compressive strength and an increase of 37.6%in total porosity.This work confirms the utility of hydrophobically-modified geopolymer concrete as a building material for long-term service in wet environments,for instance,areas with frequent precipitation,or splash and tidal zones.
基金supported by the National Key R&D Pro-gram of China(Grant No.2023YFE0114600)The National Natural Science Foundation of China(NSFC)(Grant No.52477029)Joint Laboratory of China-Morocco Green Energy and Advanced Materials,The Youth Innovation Team of Shaanxi Universities and The Xi’an City Science and Technology Project(No.23GXFW0070)。
文摘Floating photovoltaic(FPV)technology is emerging as a highly promising approach to accelerate decarbonization of the global economy,due to its higher power generation efficiency and lower land occupation.With the rapid development of FPV technology,the mechanical performance degradation of key components caused by the harsh marine environment has become a pressing issue,as it significantly contributes to failure behavior observed in FPV systems.A comprehensive compilation of the mechanical performance of key components in FPV systems is also currently unavailable.Here,the mechanical behavior of each structural component in FPV systems under harsh marine environments is systematically reviewed.It further emphasizes the synergistic effects of mechanical performance degradation among different components on the overall system.The drop-off rate(v)of normalized elongation at break(EAB)of polymer under the synergistic effect of various environmental factors increases from 7.5×10^(−4)h^(−1)to 21.8×10^(−4)h^(−1)compared with the single environmental stress.Moreover,the development of novel materials and innovative mechanical structures applied in FPV systems to enhance mechanical performance is discussed.The novel flexible PV modules applied in FPV systems minimize the loads acting on the mooring lines by 80%and increase power generation by 5%.Notably,this paper provides a theoretical foundation for developing standards of FPV systems,especially the establishment of standards related to the synergistic effects of the mechanical performance degradation of different key components on FPV systems.
基金the generous support from natural Science Foundation of Shanxi Province(No.202203021221040 and No.201901D111106).
文摘AZ31B magnesium alloy is widely used in transportation and aerospace fields due to its light weight and high strength,but it often causes structural failure due to fatigue fracture during service.Fatigue fracture is usually caused by the initiation of cracks on the surface of structural parts and the propagation of cracks to the interior of the specimen in the form of intergranular fracture.In order to improve the fatigue performance,this study proposes a method of pre-tension deformation and surface mechanical rolling treatment of AZ31B magnesium alloy,thereby changing the crack initiation area and increasing the crack propagation resistance.The experimental results show that:As the pre-tension deformation increases,the fatigue limit shows a trend of first rising and then decreasing.The 5PT specimen exhibits the optimal strengthening effect,with a fatigue limit of 115 MPa,which is a 27.78% improvement.Under surface mechanical rolling treatment,the fatigue limit reaches 140 MPa,which is a 55.56% improvement.When pre-tension deformation and surface mechanical rolling treatment are combined,the fatigue limit is further improved compared to individual strengthening methods.Among these,the 2PT+SMRT specimen shows the most significant strengthening effect,with a fatigue limit of 150 MPa,which is a 66.67% improvement.This study proposes a new strategy for improving the fatigue performance of AZ31B magnesium alloy,and reveals the synergistic strengthening mechanism of pre-tension deformation and surface mechanical rolling treatment of AZ31B magnesium alloy,which is of great significance for improving the fatigue performance of metal materials.
基金The National Natural Science Foundation of China(No.51005124)the Opening Foundation of Jiangsu Key Laboratory for Design and Manufacture of Micro-Nano Biomedical Instruments(No.JS-NB-2009-1-1)
文摘This paper aims to find the relationship between the structural parameters and the radial stiffness of the braided stent and to understand the stress distribution law of the wires. According to the equation of the space spiral curve, a three-dimensional parametrical geometrical model is constructed. The finite element model is built by using the beam-beam contact elements and 3D beam elements. The constituent nitinol wires are assumed to be linear elastic material. The finite element analysis figures out that the radial stiffness of the stent and the stress distribution of the wires are influenced by all the structural parameters. The helix pitch of the wires is the most important factor. Under the condition of the same load and other structural parameters remaining unchanged, when the number of wires is 24, the stress of the wire crosssection is at the minimum. A comparison between the vitro experimental results and the analytical results is conducted, and the data is consistent, which proves that the current finite element model can be used to appropriately predict the mechanical performance of the braided esophageal stents.
基金supported by the National Science Foundation for Distinguished Young Scholars of China(Grant No.12425209)the National Natural Science Foundation of China(Grant No.U20A20390,11827803,12172034,11822201,62004056,62104058,62271269).
文摘Neuromorphic devices have shown great potential in simulating the function of biological neurons due to their efficient parallel information processing and low energy consumption.MXene-Ti_(3)C_(2)T_(x),an emerging twodimensional material,stands out as an ideal candidate for fabricating neuromorphic devices.Its exceptional electrical performance and robust mechanical properties make it an ideal choice for this purpose.This review aims to uncover the advantages and properties of MXene-Ti_(3)C_(2)T_(x)in neuromorphic devices and to promote its further development.Firstly,we categorize several core physical mechanisms present in MXene-Ti_(3)C_(2)T_(x)neuromorphic devices and summarize in detail the reasons for their formation.Then,this work systematically summarizes and classifies advanced techniques for the three main optimization pathways of MXene-Ti_(3)C_(2)T_(x),such as doping engineering,interface engineering,and structural engineering.Significantly,this work highlights innovative applications of MXene-Ti_(3)C_(2)T_(x)neuromorphic devices in cutting-edge computing paradigms,particularly near-sensor computing and in-sensor computing.Finally,this review carefully compiles a table that integrates almost all research results involving MXene-Ti_(3)C_(2)T_(x)neuromorphic devices and discusses the challenges,development prospects,and feasibility of MXene-Ti_(3)C_(2)T_(x)-based neuromorphic devices in practical applications,aiming to lay a solid theoretical foundation and provide technical support for further exploration and application of MXene-Ti_(3)C_(2)T_(x)in the field of neuromorphic devices.
基金financially supported by the National Key Development Program of China for the “13th Five-Year Plan”(No.2016YFB0700300)
文摘To study the influence of rolling on the interfaces and mechanical performance of graphene-reinforced Al-matrix composites,a rolling method was used to process them.Using scanning electron microscopy(SEM),transmission electron microscopy(TEM),X-ray diffraction(XRD),Raman spectroscopy,and tensile testing,this study analyzed the micromorphology,interfaces,and mechanical performance of the composites before and after rolling.The experimental results demonstrates that the composites after hot rolling has uniform structures with strong interfacial bonding.With an increase in rolling temperature,the tensile strength and elastic modulus of the composites gradually increase.However,when the rolling temperature is higher than 500°C,granular and rod-like Al4C3 phases are observed at the interfaces and the mechanical performance of the composites is degraded.When the rolling temperature is 480°C,the composites show the optimal comprehensive mechanical performance,with a tensile strength and elastic modulus of 403.3 MPa and 77.6 GPa,respectively,which represent increases of 31.6%and 36.9%,respectively,compared with the corresponding values prior to rolling.
基金Funded by the National Natural Science Foundation of China(No.51778479).
文摘To understand the enhancing effect and fiber-reinforced mechanism of composite fibers reinforced cement concrete, the influences of composite fibers on micro-cracks and the distribution of composite fibers were evaluated by optical electron micrometer(OEM) and scanning electron microscope(SEM). Three kinds of fiber, such as polyacrylonitrile-based carbon fiber, basalt fiber, and glass fiber, were used in the composite fibers reinforced cement concrete. The composite fibers could form a stable structure in concrete after the liquid-phase coupling treatment, gas-liquid double-effect treatment, and inert atmosphere drying. The mechanical properties of composite fibers reinforced concrete(CFRC) were studied by universal test machine(UTM). Moreover, the effect of composite fibers on concrete was analyzed based on the toughness index and residual strength index. The results demonstrated that the composite fibers could improve the mechanical properties of concrete, while the excessive amount of composite fibers had an adverse effect on the mechanical properties of concrete. The composite fibers could significantly improve the toughness index of CFRC, and the increment rate is more than 30%. The composite fibers could form a mesh structure, which could promote the stability of concrete and guarantee the excellent mechanical properties.
基金Project supported by the Baotou Aluminum Co. Ltd.
文摘The effect of rare earth element Ce on mechanical performance and electrical conductivity of aluminum rod for electrical purpose were studied under industrial production condition. Using optical microscope, SEM, TEM, EDS and X-ray diffractometer, the microstructure and phase composition of aluminum rod were measured and analyzed. The results indicate that the content of rare earth element Ce is between 0.05% -0.16% in the aluminum rod for electrical purpose. Its tensile strength is enhanced to some extent. The research also discovers that the tensile strength is enhanced remarkably with impurity element Si content increases. Because influence of Si is big to the conductivity, the Si content should be controlled continuously strictly in the aluminum for electrical purpose. Adding rare earth element Ce reduces the solid solubility of Si in the aluminum matrix, and the negative effect of Si on the aluminum conductor reduces effectively. So the limit of in Si content in aluminum rod for electrical purpose can be relaxed moderately.
基金Supported by National High-quality Development Project of China(Grant No.2340STCZB193).
文摘The average stiffness performance indices throughout the workspace are commonly used as global stiffness performance indices to evaluate the overall stiffness performance of parallel mechanisms,which involves an analysis of the stiffness performance of numerous discrete points in the workspace.This necessitates time-consuming and inefficient calculation,which is particularly pronounced in the optimization design stage of the mechanism,where the variations in the global stiffness performance indices versus various dimensional and structural parameters need to be analyzed.This paper presents a semi-analytical approach for stiffness modeling of the novel(R(RPS&RP))&2-UPS parallel mechanism(referred to as the Trifree mechanism)and proposes“local”stiffness performance indices as alternatives to global indices.Drawing on the screw theory,the Cartesian stiffness matrix of the Trifree mechanism is formulated explicitly by considering the compliances of all elastic elements and the over-constraint characteristics inherent in the mechanism.Based on the spherical motion pattern of the Trifree mechanism,four special reference configurations are extracted within the workspace.This yields“local”stiffness performance indices capable of accurately evaluating the overall stiffness performance of the mechanism and effectively improving the computational efficiency.The variations in global and“local”stiffness performance indices versus key design parameters are investigated.Furthermore,the proposed indices are applied to the Tricept and Trimule mechanisms.The results demonstrate that the proposed indices exhibit excellent computational accuracy and efficiency in evaluating the overall stiffness performance of these spherical parallel mechanisms.Moreover,the stiffness performance of the novel parallel mechanism investigated in this study closely resembles that of the well-known Tricept and Trimule mechanisms.This research proposes a semi-analytic stiffness model of the Trifree mechanism and“local”stiffness performance indices to evaluate the overall stiffness performance,thereby substantially improving the computational efficiency without sacrificing accuracy.
基金supported by the Guangdong Basic and Applied Basic Research Fund Project(2022A1515140061,No.11000-2344014)Startup Foundation for Postdoctor by Dongguan University of Technology(No.11000-221110149)the High-level Talents Program(contract number 2023JC10L014)of the Department of Science and Technology of Guangdong Province。
文摘High entropy materials(HEMs)are the promising electrocatalysts for anion exchange membrane electrolyser(AEMs)and proton exchange membrane fuel cells(PEMFCs)due to the intriguing cocktail effect,wide design space,tailorable electronic structure,and entropy stabilization effect.The precise fabrication of HEMs with functional nanostructures provides a crucial avenue to optimize the adsorption strength and catalytic activity for electrocatalysis.This review comprehensively summarizes the development of HEMs,focusing on the principles and strategies of structural design,and the catalytic mechanism towards hydrogen evolution reaction,oxygen evolution reaction and oxygen reduction reaction for the development of high-performance electrocatalysts.The complexity inherent in the interactions between different elements,the changes in the d-band center and the Gibbs free energies during the catalytic progress,as well as the coordination environment of the active sites associated with the unique crystal structure to improve the catalytic performance are discussed.We also provide a perspective on the challenges and future development direction of HEMs in electrocatalysis.This review will contribute to the design and development of HEMs-based catalysts for the next generation of electrochemical applications.
文摘Rare earth -containing PSBR sheet was prepared by reaction of rare earth alkoxide with quaternary ammonium salt of pyridine modified SBR (PSBR) latex, and then it was blended with natural rubber (NR) to produce rare earth - containing composite elastomer. It is found that mechanical performance can be improved remarkably. Analyzed by infrared spectrometry (IR), differential scanning calorimetry (DSC) and cross-linking densitometry, the relationship between structure and performance was discussed.
文摘In petroleum extraction,the sealing surfaces of bolted joints are susceptible to damage due to the high-temperature and high-pressure conditions in wellbores.This damage adversely affects sealing performance,consequently leading to the failure and damage of threaded connections.In severe cases,it can result in considerable economic losses and trigger safety accidents.The sealing performance of special bolted joints holds crucial importance for production efficiency,output,equipment lifespan,and cost control.Enhancing the sealing perfor-mance of threaded connections can have a positive impact on industrial production and environmental protection.The existing research on American Petroleum Institute threaded joints has been thorough and has obtained a series of excellent results.However,the research on the sealing damage mechanism of threaded connections under complex well conditions lacks sufficient depth and that on new sealing technology is scarce.This study proposes a half-size evaluation test to address the abovementioned problem.Based on this test,an investigation into the sealing performance of threaded connections under high-temperature,cyclic loading,and high-temperature creep conditions is conducted.This study uses a combined approach of finite element methods and experiments to investigate the impact of different makeup torques on the sealing performance of premium threaded connections(PTCs).The results of the half-size evaluation test indicate that temperature notably influences the sealing performance of threaded connections.The continuous action of high temperatures causes contact pressure and sealing performance to decrease,and sealing contact pressure increases after cooling.Finite element and test results show that for a certain joint A,the greater the torque,the higher the critical sealing pressure of the thread,and the better the sealing performance.The research on the sealing damage mechanism of PTCs provides a scientific basis and theoretical guidance for the further optimization and development of PTCs.
基金supported by the Primary Research&Developement Plan of Jiangsu Province(BE2017168)
文摘To quantify the nonuniform micromechanical performance of welded joint,the load-displacement curves by nanoindentation test were introduced to examine different zones including base metal,coarse grained heat affected zone,partially melted zone,weld metal near the fusion boundary and weld metal center.The results showed that the strengthening effect of weld metal was more obvious than that of heat affected zone for nickel based welded joint and especially in coarse grained heat affected zone,the hardening resulted from overheating was not apparent.Nickel based weld metal with high content of alloying elements which were often segregated at interdendritic regions or precipitated in grain interior under nonequilibrium solidification contributed to the characteristics that differ from conventional low alloy steel welded joint.
基金supported by the National Natural Science Foundation of China(Grant No.52271087).
文摘Thermal barrier coatings(TBCs)are extensively utilized in aero-engines and heavy-duty gas turbines due to their outstanding properties,including low thermal conductivity,corrosion,high-temperature oxidation,and wear resistance.The rising thrust-to-weight ratio and service temperature in engine hot sections have presented a significant challenge in TBC's materials,structure,and preparation process;it is one of the current research hotspots in the aviation field.This paper reviews the recent advancement in turbine blade TBCs.It focuses on the TBC's structure,deposition mechanism and the key performance evaluation indexes for TBCs applied to turbine blades.Finally,the future research field of TBCs for turbine blades is also be prospected.
基金supported by the Youth Science and Technology New Star Project of Shaanxi Province(grants Nos.2024ZC-KjXX-002,2021KJXX65 and 2023KJXX-092)the Natural Science Foundation of Shaanxi Province(grant No.2021JQ-947)the Basic Research and Strategic Reserve Technology Research Fund of the China National Petroleum Corporation(projects Nos.2022DQ03-05 and 2023DQ03-07).
文摘Water-induced disasters in long-distance pipelines are prevalent geological hazards,characterized by their frequency and widespread distribution.The complexity of factors contributing to pipeline damage in practical engineering poses a significant challenge for analysis using solely theoretical models.This study systematically reveals the cross-scale failure mechanism of long-distance pipelines under hydrodynamic impact through the combination of multi-scale experimental representation and theoretical modeling.Employing a combination of macroscopic measurements,advanced material testing of residual samples from failed pipelines,and consideration of operational conditions and environmental factors,the failure modes is systematically analyzed.The findings reveal that under the vibrations induced by water impulses,the pipe material exhibits a pronounced ratchet effect,leading to an 8.92%reduction in elongation at break.Furthermore,the Bauschinger effect is observed,resulting in a 2.95%decrease in yield strength.Cyclic hardening significantly diminishes the impact toughness of the weld by 22.2%.Notably,at high vibration frequencies of approximately 18.98 Hz,the stress concentration in the girth weld near the axial midpoint of the pipe section initiates cracking,ultimately leading to failure under the alternating load generated by the oscillation.This study provides valuable insights into the scientific understanding of pipeline failure mechanisms under water impact,contributing to the development ofmore robust and resilient pipeline systems.
基金supported by the National Natural Science Foundation of China under grant Nos. 50871039 and 51205135Guangdong Provincial Natural Science Foundation under grant Nos. 10151064101000017 and S2011040001436the Fundamental Research Funds for Central Universities (SCUT2011ZM0001)
文摘A near-equiatomic NiTi shape memory alloy was fabricated by rapid solidification process through vacuum arc melting followed by vacuum suction casting in water-cooled thick copper mold. The rapidly solidified （or suction cast） NiTi alloy shows much finer grains and homogenous microstructure, in particular a uniform distribution of various fine precipitates, compared to the conventional cast one. The resultant alloy also exhibits the homogenous Ni distribution in the matrix of the alloy, allowing the martensitic transformation to take place throughout the NiTi alloy matrix simultaneously and resulting in sharper transformation peaks compared to the conventional cast alloy. Moreover, the suction cast NiTJ alloy shows a significant improvement over the conventional cast one, in terms of possessing higher deformation recovery rates and displaying the increased compressive strength and damping capacity by 4% and 20%, respectively.
