A two-dimensional electromagnetic particle-in-cell simulation model is proposed to study the density evolution and collective stopping of electron beams in background plasmas.We show here the formation of the multi-la...A two-dimensional electromagnetic particle-in-cell simulation model is proposed to study the density evolution and collective stopping of electron beams in background plasmas.We show here the formation of the multi-layer structure of the relativistic electron beam in the plasma due to the different betatron frequency from the beam front to the beam tail.Meanwhile,the nonuniformity of the longitudinal wakefield is the essential reason for the multi-layer structure formation in beam phase space.The influences of beam parameters(beam radius and transverse density profile)on the formation of the multi-layer structure and collective stopping in background plasmas are also considered.展开更多
Commercial3D reticular nickel foam and its composite structure were investigated on the sound absorption at200-2000Hz.The absorption performance of foam plates1?5layers(1-layer thickness:2.3mm;porosity:89%;average por...Commercial3D reticular nickel foam and its composite structure were investigated on the sound absorption at200-2000Hz.The absorption performance of foam plates1?5layers(1-layer thickness:2.3mm;porosity:89%;average pore-diameter:0.57mm)was found to be poor,and could be improved by adding backed cavum or front perforated thin sheet.The absorption coefficient could reach about0.4at1000-1600Hz for the composite structure of5-layer foam with a backed5mm-thick cavum,and even0.68at about1000Hz for that of2-layer foam with the same cavum and a perforated plate closely in front of the foam.展开更多
Multi-layer riveted structures are widely applied to aircraft.During the service,cracks may appear within these structures due to stress concentration of the riveted holes.The guided wave monitoring has been proved to...Multi-layer riveted structures are widely applied to aircraft.During the service,cracks may appear within these structures due to stress concentration of the riveted holes.The guided wave monitoring has been proved to be an effective tool to deal with this problem.However,there is a lack of understanding of the wave propagation process across such kinds of structures.This study proposes a piezoelectric guided wave simulation method to reveal the propagation of guided waves in multi-layer riveted structures.Effects of pretension force,friction coefficient,and cracks that might influence wave characteristics are studied.The guided wave simulation data is compared with the experimental results and the results verify the simulation model.Then the guided wave propagation in a more complex long-beam butt joint structure is further simulated.展开更多
The key parameters that characterize the morphological quality of multi-layer and multi-pass metal laser deposited parts are the surface roughness and the error between the actual printing height and the theoretical m...The key parameters that characterize the morphological quality of multi-layer and multi-pass metal laser deposited parts are the surface roughness and the error between the actual printing height and the theoretical model height.The Taguchi method was employed to establish the correlations between process parameter combinations and multi-objective characterization of metal deposition morphology(height error and roughness).Results show that using the signal-to-noise ratio and grey relational analysis,the optimal parameter combination for multi-layer and multi-pass deposition is determined as follows:laser power of 800 W,powder feeding rate of 0.3 r/min,step distance of 1.6 mm,and scanning speed of 20 mm/s.Subsequently,a Genetic Bayesian-back propagation(GB-BP)network is constructed to predict multi-objective responses.Compared with the traditional back propagation network,the GB-back propagation network improves the prediction accuracy of height error and surface roughness by 43.14%and 71.43%,respectively.This network can accurately predict the multi-objective characterization of morphological quality of multi-layer and multi-pass metal deposited parts.展开更多
Six new lanthanide complexes:[Ln(3,4-DEOBA)3(4,4'-DM-2,2'-bipy)]2·2C_(2)H_(5)OH,[Ln=Dy(1),Eu(2),Tb(3),Sm(4),Ho(5),Gd(6);3,4-DEOBA-=3,4-diethoxybenzoate,4,4'-DM-2,2'-bipy=4,4'-dimethyl-2,2'...Six new lanthanide complexes:[Ln(3,4-DEOBA)3(4,4'-DM-2,2'-bipy)]2·2C_(2)H_(5)OH,[Ln=Dy(1),Eu(2),Tb(3),Sm(4),Ho(5),Gd(6);3,4-DEOBA-=3,4-diethoxybenzoate,4,4'-DM-2,2'-bipy=4,4'-dimethyl-2,2'-bipyridine]were successfully synthesized by the volatilization of the solution at room temperature.The crystal structures of six complexes were determined by single-crystal X-ray diffraction technology.The results showed that the complexes all have a binuclear structure,and the structures contain free ethanol molecules.Moreover,the coordination number of the central metal of each structural unit is eight.Adjacent structural units interact with each other through hydrogen bonds and further expand to form 1D chain-like and 2D planar structures.After conducting a systematic study on the luminescence properties of complexes 1-4,their emission and excitation spectra were obtained.Experimental results indicated that the fluorescence lifetimes of complexes 2 and 3 were 0.807 and 0.845 ms,respectively.The emission spectral data of complexes 1-4 were imported into the CIE chromaticity coordinate system,and their corre sponding luminescent regions cover the yellow light,red light,green light,and orange-red light bands,respectively.Within the temperature range of 299.15-1300 K,the thermal decomposition processes of the six complexes were comprehensively analyzed by using TG-DSC/FTIR/MS technology.The hypothesis of the gradual loss of ligand groups during the decomposition process was verified by detecting the escaped gas,3D infrared spectroscopy,and ion fragment information detected by mass spectrometry.The specific decomposition path is as follows:firstly,free ethanol molecules and neutral ligands are removed,and finally,acidic ligands are released;the final product is the corresponding metal oxide.CCDC:2430420,1;2430422,2;2430419,3;2430424,4;2430421,5;2430423,6.展开更多
To elucidate the effect of calcite-regulated activated carbon(AC)structure on low-temperature denitrification performance of SCR catalysts,this work prepared a series of Mn-Ce/De-AC-xCaCO_(3)(x is the calcite content ...To elucidate the effect of calcite-regulated activated carbon(AC)structure on low-temperature denitrification performance of SCR catalysts,this work prepared a series of Mn-Ce/De-AC-xCaCO_(3)(x is the calcite content in coal)catalysts were prepared by the incipient wetness impregnation method,followed by acid washing to remove calcium-containing minerals.Comprehensive characterization and low-temperature denitrification tests revealed that calcite-induced structural modulation of coal-derived AC significantly enhances catalytic activity.Specifically,NO conversion increased from 88.3%of Mn-Ce/De-AC to 91.7%of Mn-Ce/De-AC-1CaCO_(3)(210℃).The improved SCR denitrification activity results from the enhancement of physicochemical properties including higher Mn^(4+)content and Ce^(4+)/Ce^(3+)ratio,an abundance of chemisorbed oxygen and acidic sites,which could strengthen the SCR reaction pathways(richer NH_(3)activated species and bidentate nitrate active species).Therefore,NO removal is enhanced.展开更多
Alkali-free SiO_(2)-Al_(2)O_(3)-CaO-MgO with different SiO_(2)/Al_(2)O_(3)mass ratios was prepared by conventional melt quenching method.The glass network structure,thermodynamic properties and elastic modulus changes...Alkali-free SiO_(2)-Al_(2)O_(3)-CaO-MgO with different SiO_(2)/Al_(2)O_(3)mass ratios was prepared by conventional melt quenching method.The glass network structure,thermodynamic properties and elastic modulus changes with SiO_(2)and Al_(2)O_(3)ratios were investigated using various techniques.It is found that when SiO_(2)is replaced by Al_(2)O_(3),the Q^(4) to Q^(3) transition of silicon-oxygen network decreases while the aluminum-oxygen network increases,which result in the transformation of Si-O-Si bonds to Si-O-Al bonds and an increase in glass network connectivity even though the intermolecular bond strength decreases.The glass transition temperature(T_(g))increases continuously,while the thermal expansion coefficient increases and high-temperature viscosity first decreases and then increases.Meanwhile,the elastic modulus values increase from 93 to 102 GPa.This indicates that the elastic modulus is mainly affected by packing factor and dissociation energy,and elements with higher packing factors and dissociation energies supplant those with lower values,resulting in increased rigidity within the glass.展开更多
To investigate the pore structure of graphene oxide modified polymer cement mortar(GOPM)under salt-freeze-thaw(SFT)coupling effects and its impact on deterioration,this study modifies polymer cement mortar(EMCM)with g...To investigate the pore structure of graphene oxide modified polymer cement mortar(GOPM)under salt-freeze-thaw(SFT)coupling effects and its impact on deterioration,this study modifies polymer cement mortar(EMCM)with graphene oxide(GO).The micro-pore structure of GOPM is characterized using LF-NMR and SEM.Fractal theory is applied to calculate the fractal dimension of pore volume,and the deterioration patterns are analyzed based on the evolution characteristics of capillary pores.The experimental results indicate that,after 25 salt-freeze-thaw cycles(SFTc),SO2-4 ions penetrate the matrix,generating corrosion products that fill existing pores and enhance the compactness of the specimen.As the number of cycles increases,the ongoing formation and expansion of corrosion products within the matrix,combined with persistent freezing forces,and result in the degradation of the pore structure.Therefore,the mass loss rate(MLR)of the specimens shows a trend of first decreasing and then increasing,while the relative dynamic elastic modulus(RDEM)initially increases and then decreases.Compared to the PC group specimens,the G3PM group specimens show a 28.71% reduction in MLR and a 31.42% increase in RDEM after 150 SFTc.The fractal dimensions of the transition pores,capillary pores,and macropores in the G3PM specimens first increase and then decrease as the number of SFTc increases.Among them,the capillary pores show the highest correlation with MLR and RDEM,with correlation coefficients of 0.97438 and 0.98555,respectively.展开更多
Tilted metasurface nanostructures,with excellent physical properties and enormous application potential,pose an urgent need for manufacturing methods.Here,electric-field-driven generative-nanoimprinting technique is p...Tilted metasurface nanostructures,with excellent physical properties and enormous application potential,pose an urgent need for manufacturing methods.Here,electric-field-driven generative-nanoimprinting technique is proposed.The electric field applied between the template and the substrate drives the contact,tilting,filling,and holding processes.By accurately controlling the introduced included angle between the flexible template and the substrate,tilted nanostructures with a controllable angle are imprinted onto the substrate,although they are vertical on the template.By flexibly adjusting the electric field intensity and the included angle,large-area uniform-tilted,gradient-tilted,and high-angle-tilted nanostructures are fabricated.In contrast to traditional replication,the morphology of the nanoimprinting structure is extended to customized control.This work provides a cost-effective,efficient,and versatile technology for the fabrication of various large-area tilted metasurface structures.As an illustration,a tilted nanograting with a high coupling efficiency is fabricated and integrated into augmented reality displays,demonstrating superior imaging quality.展开更多
AIM:To investigate the effects of shortening the duration of silicone oil tamponade on retinal structure and function in patients undergoing silicone oil removal(SOR)after surgery for primary rhegmatogenous retinal de...AIM:To investigate the effects of shortening the duration of silicone oil tamponade on retinal structure and function in patients undergoing silicone oil removal(SOR)after surgery for primary rhegmatogenous retinal detachment(RRD).METHODS:A total of 58 eligible patients were enrolled and randomly assigned to two groups based on tamponade duration:the short-term group(30-45d)and the conventional group(≥90d).Comprehensive evaluations were performed before and after SOR,including slitlamp examination,best-corrected visual acuity(BCVA)measurement,intraocular pressure(IOP)testing,optical coherence tomography(OCT),optical coherence tomography angiography(OCTA),microperimetry,electroretinography(ERG),and visual evoked potential(VEP)assessment.RESULTS:A total of 33 patients(23 males and 10 females;33 eyes)were enrolled in the short-term SO tamponade group with mean age of 52.45±9.35y,and 25 patients(15 males and 10 females;25 eyes)were enrolled in the conventional SO tamponade group with mean age of 50.80±12.06y.Compared with the conventional group,the short-term silicone oil tamponade group had a significantly lower incidence of silicone oil emulsification and cataract progression,with no significant difference in retinal reattachment success rate.Structurally,short-term tamponade was associated with increased thickness of the retinal ganglion cell layer(RGCL)in the nasal and superior macular regions and improved recovery of superficial retinal vascular density in these areas.Functionally,the shortterm group showed better BCVA and retinal sensitivity both before and 1mo after SOR;additionally,the P100 amplitude in VEP tests was significantly increased in this group.CONCLUSION:Shortening the duration of silicone oil tamponade effectively reduces damage to retinal structure and function without compromising the success rate of retinal reattachment in patients with primary RRD.展开更多
Si-based multilayer structures are widely used in current microelectronics. During their preparation, some inhomogeneous residual stress is induced, resulting in competition between interface mismatching and surface e...Si-based multilayer structures are widely used in current microelectronics. During their preparation, some inhomogeneous residual stress is induced, resulting in competition between interface mismatching and surface energy and even leading to structure failure. This work presents a methodological study on the measurement of residual stress in a multi-layer semiconductor heterostructure. Scanning electron microscopy（SEM）, micro-Raman spectroscopy（MRS）, and transmission electron microscopy（TEM） were applied to measure the geometric parameters of the multilayer structure. The relationship between the Raman spectrum and the stress/strain on the [100] and [110] crystal orientations was determined to enable surface and crosssection residual stress analyses, respectively. Based on the Raman mapping results, the distribution of residual stress along the depth of the multi-layer heterostructure was successfully obtained.展开更多
In this paper,we report the study of the process of fabricating a multi-layermetal micro-structure using UV-LIGA overlay technology,includingmask fabrication,substrate treatment,and UV-LIGA overlay processes.To solve ...In this paper,we report the study of the process of fabricating a multi-layermetal micro-structure using UV-LIGA overlay technology,includingmask fabrication,substrate treatment,and UV-LIGA overlay processes.To solve the process problems in the masking procedure,the swelling problemof the first layer of SU-8 thick photoresist was studied experimentally.The 5μmline-width compensation and closed 20μmand 30μmisolation strips were designed and fabricated around the micro-structure pattern.The pore problemin the Ni micro-electroforming layer was analyzed and the electroforming parameters were improved.The pH value of the electroforming solution should be controlled between 3.8 and 4.4 and the current density should be below 3 A/dm^2.To solve the problems of high inner stress and incomplete development of the micro-cylinder hole array with a diameter of 30μm,the lithography process was optimized.The pre-baking temperature was increased via gradient heating and rose every 5℃ from 65℃ to 85℃ and then remained at 85℃ for 50 min–1 h.In addition,the full contact exposure was used.Finally,a multi-layer metal micro-structure with high precision and good quality of microelectroforming layer was fabricated using UV-LIGA overlay technology.展开更多
The microstructure and mechanical properties of multi-layer multi-pass TIG welded joints of Al-Zn-Mg alloy plates were studied.The phase constituent and microstructure of different regions of the welded joints were ch...The microstructure and mechanical properties of multi-layer multi-pass TIG welded joints of Al-Zn-Mg alloy plates were studied.The phase constituent and microstructure of different regions of the welded joints were characterized by scanning electron microscopy(SEM),X-ray diffraction(XRD),transmission electron microscopy(TEM)and energy disperse spectrum(EDS),while the mechanical properties were evaluated according to the impact test.A dispersively distributed spherical and needle-likeη(MgZn2)phase was obtained in the welding seam.The phase composition of the heat-affected zone(HAZ)wasα(Al)+η(MgZn2)+Al6Mn,and there were a large number of dispersively precipitated nanoscale particles.The welded joint zone had the highest impact toughness as compared with the other parts of the joint.The MgZn2 phase in the weld zone contributed to the improved toughness of the joint.Al2 MgCu phase in HAZ was proven to act as a crack source during fracture.展开更多
Laser multi\|layer cladding experiments were performed on the substrate of DD3 single crystal with FGH95 powder as cladding material.The solidification microstructure in the sample was investigated.It was found that t...Laser multi\|layer cladding experiments were performed on the substrate of DD3 single crystal with FGH95 powder as cladding material.The solidification microstructure in the sample was investigated.It was found that the solidification microstructure was greatly influenced by the crystallography orientation of the substrate and the local solidification conditions.When the angle between the preferred orientation of the single crystal and the direction of heat flow in the cladding layer is less than 30°,single crystal cladding layers were acquired.Otherwise the crystallography orientation of the cladding layer will deviate from the orientation of the substrate and the microstructure with polycrystalline appears.Meanwhile,even when the experiments were performed on the same preferred crystal surface,the solidification microstructures will be different distinctly resulting from the variation of the local solidification conditions.The secondary arms were degenerated and the primary arm spacing was about 10\|20μm.Further investigation shows that the phases of the cladding layer are mainly made up ofγ,γ′,the flower\|likeγ/γ′eutectic and carbide.The morphology ofγ′was cubical and the size is less than 0.1μm.展开更多
Inspired that the neck structure can stabilize the head from body movements and external dynamic vibration by the role of intervertebral disc and surrounding muscles,a novel multi-layer structure with nonlinear elasti...Inspired that the neck structure can stabilize the head from body movements and external dynamic vibration by the role of intervertebral disc and surrounding muscles,a novel multi-layer structure with nonlinear elastic components is proposed in this paper.The proposed structure is expected for loading the weight of the end effector and isolating bending vibration with lowfrequency in the range of 0.1 Hz to 1 Hz.First,considering the loading,the potential energy,restoring force,and structural configuration in axial direction are defined.Then,the dynamical restoring force and stiffness for bending are modelled for different structural parameters and configurations after the axial weight.According to the functions of the proposed structure required in applications including loading capacity and bending vibration isolation effectiveness,design criteria are carried out.Due to the realization of high-order quasi-zero stiffness property,the effective isolation band for bending vibration can be extended from about 0.08 Hz.In addition,based on the proposed design criteria,the constructed multi-layer structure displays remarkable dynamical stabilization effectiveness in ultralow frequency band.The proposed structure not only provides the biological explanations for car sickness,nausea,and airsickness of humans,but also solves the bottleneck techniques in bioinspired nonlinear isolation structural design for transverse dynamical stabilization,which has remarkable potential applications in the fields of mechanical arm,sensors in satellite etc.展开更多
Poly（ethylene oxide） multi-layer crystals were obtained and the re-crystallization behavior was studied to give insight into how melt thickness and temperature affect the lamellar orientation. For a special re-cryst...Poly（ethylene oxide） multi-layer crystals were obtained and the re-crystallization behavior was studied to give insight into how melt thickness and temperature affect the lamellar orientation. For a special re-crystallization temperature, there exists a critical transition thickness range for the occurrence of edge-on lamellar orientation. Below the critical thickness, only flat-on lamellae were observed. While above the critical thickness, both flat-on and edge-on lamellae were found and the proportion of the edge-on lamellae increases with thickness. At low re-crystallization temperatures （below 30 ℃）, the critical transition thickness gradually increases from about 15 nm to 35 nm when the re-crystallization temperature was increased from 20 ℃ to 30 ℃. However, when the re-crystallization temperature is above 30 ℃, the critical transition thickness becomes constant. Our results demonstrated that the lamellar orientation could be specially modified by changing the melt thickness and re-crystallization temperature.展开更多
The explosive reaction degree and protection from explosions are concerns in the military field.In this work,the reaction degree of the composition B explosive was investigated experimentally.Multi-layered compound st...The explosive reaction degree and protection from explosions are concerns in the military field.In this work,the reaction degree of the composition B explosive was investigated experimentally.Multi-layered compound structures were used as barriers to weaken the blast loads.A comprehensive experiment using a high-speed camera and image processing techniques,side witness plates,and bottom witness plates was presented.Using the experimental fragment velocities,fragment piercing patterns,and damage characteristics,the reaction degree of the explosive impeded by different multi-layered compound structures could be precisely differentiated.Reaction parameters of the explosive obstructed by compound structures were obtained by theoretical analysis and numerical simulations.Unlike the common method in which the explosive reaction degree is only distinguished based on the initial pressure amplitude transmitted into the explosive,a following shock wave reflected from the side steel casing was also considered.Different detonation growth paths in the explosive formed.Therefore,all these shock wave propagation characteristics must be considered to analyze the explosive response impeded by compound structures.展开更多
Sentiment analysis,commonly called opinion mining or emotion artificial intelligence(AI),employs biometrics,computational linguistics,nat-ural language processing,and text analysis to systematically identify,extract,m...Sentiment analysis,commonly called opinion mining or emotion artificial intelligence(AI),employs biometrics,computational linguistics,nat-ural language processing,and text analysis to systematically identify,extract,measure,and investigate affective states and subjective data.Sentiment analy-sis algorithms include emotion lexicon,traditional machine learning,and deep learning.In the text sentiment analysis algorithm based on a neural network,multi-layer Bi-directional long short-term memory(LSTM)is widely used,but the parameter amount of this model is too huge.Hence,this paper proposes a Bi-directional LSTM with a trapezoidal structure model.The design of the trapezoidal structure is derived from classic neural networks,such as LeNet-5 and AlexNet.These classic models have trapezoidal-like structures,and these structures have achieved success in the field of deep learning.There are two benefits to using the Bi-directional LSTM with a trapezoidal structure.One is that compared with the single-layer configuration,using the of the multi-layer structure can better extract the high-dimensional features of the text.Another is that using the trapezoidal structure can reduce the model’s parameters.This paper introduces the Bi-directional LSTM with a trapezoidal structure model in detail and uses Stanford sentiment treebank 2(STS-2)for experiments.It can be seen from the experimental results that the trapezoidal structure model and the normal structure model have similar performances.However,the trapezoidal structure model parameters are 35.75%less than the normal structure model.展开更多
A meshless radial basis function （RBF） collocation method based on the Eringen nonlocal elasticity theory is developed to calculate the band structures of ternary and quaternary nanoscale multi-layered phononic crys...A meshless radial basis function （RBF） collocation method based on the Eringen nonlocal elasticity theory is developed to calculate the band structures of ternary and quaternary nanoscale multi-layered phononic crystals （PNCs） with functionally graded （FG） interlayers. Detailed calculations are performed for anti-plane transverse waves propagating in such PNCs. The influences of FG and homogeneous interlayers, component number, nonlocal interface imperfections and nanoscale size on cut-off frequency and band structures are investigated in detail. Numerical results show that these factors have significant effects on band structures at the macroscopic and microscopic scales.展开更多
Luquire et al. ' s impedance change model of a rectangular cross section probe coil above a structure with an arbitrary number of parallel layers was used to study the principle of measuring thicknesses of multi-l...Luquire et al. ' s impedance change model of a rectangular cross section probe coil above a structure with an arbitrary number of parallel layers was used to study the principle of measuring thicknesses of multi-layered structures in terms of eddy current testing voltage measurements. An experimental system for multi-layered thickness measurement was developed and several fitting models to formulate the relationships between detected impedance/voltage measurements and thickness are put forward using least square method. The determination of multi-layered thicknesses was investigated after inversing the voltage outputs of the detecting system. The best fitting and inversion models are presented.展开更多
基金supported by National Natural Science Foundation of China(Nos.12075046 and 11775042)。
文摘A two-dimensional electromagnetic particle-in-cell simulation model is proposed to study the density evolution and collective stopping of electron beams in background plasmas.We show here the formation of the multi-layer structure of the relativistic electron beam in the plasma due to the different betatron frequency from the beam front to the beam tail.Meanwhile,the nonuniformity of the longitudinal wakefield is the essential reason for the multi-layer structure formation in beam phase space.The influences of beam parameters(beam radius and transverse density profile)on the formation of the multi-layer structure and collective stopping in background plasmas are also considered.
基金Project (C16) supported by the Testing Foundation of Beijing Normal University,China
文摘Commercial3D reticular nickel foam and its composite structure were investigated on the sound absorption at200-2000Hz.The absorption performance of foam plates1?5layers(1-layer thickness:2.3mm;porosity:89%;average pore-diameter:0.57mm)was found to be poor,and could be improved by adding backed cavum or front perforated thin sheet.The absorption coefficient could reach about0.4at1000-1600Hz for the composite structure of5-layer foam with a backed5mm-thick cavum,and even0.68at about1000Hz for that of2-layer foam with the same cavum and a perforated plate closely in front of the foam.
文摘Multi-layer riveted structures are widely applied to aircraft.During the service,cracks may appear within these structures due to stress concentration of the riveted holes.The guided wave monitoring has been proved to be an effective tool to deal with this problem.However,there is a lack of understanding of the wave propagation process across such kinds of structures.This study proposes a piezoelectric guided wave simulation method to reveal the propagation of guided waves in multi-layer riveted structures.Effects of pretension force,friction coefficient,and cracks that might influence wave characteristics are studied.The guided wave simulation data is compared with the experimental results and the results verify the simulation model.Then the guided wave propagation in a more complex long-beam butt joint structure is further simulated.
基金National Natural Science Foundation of China(52175237)。
文摘The key parameters that characterize the morphological quality of multi-layer and multi-pass metal laser deposited parts are the surface roughness and the error between the actual printing height and the theoretical model height.The Taguchi method was employed to establish the correlations between process parameter combinations and multi-objective characterization of metal deposition morphology(height error and roughness).Results show that using the signal-to-noise ratio and grey relational analysis,the optimal parameter combination for multi-layer and multi-pass deposition is determined as follows:laser power of 800 W,powder feeding rate of 0.3 r/min,step distance of 1.6 mm,and scanning speed of 20 mm/s.Subsequently,a Genetic Bayesian-back propagation(GB-BP)network is constructed to predict multi-objective responses.Compared with the traditional back propagation network,the GB-back propagation network improves the prediction accuracy of height error and surface roughness by 43.14%and 71.43%,respectively.This network can accurately predict the multi-objective characterization of morphological quality of multi-layer and multi-pass metal deposited parts.
文摘Six new lanthanide complexes:[Ln(3,4-DEOBA)3(4,4'-DM-2,2'-bipy)]2·2C_(2)H_(5)OH,[Ln=Dy(1),Eu(2),Tb(3),Sm(4),Ho(5),Gd(6);3,4-DEOBA-=3,4-diethoxybenzoate,4,4'-DM-2,2'-bipy=4,4'-dimethyl-2,2'-bipyridine]were successfully synthesized by the volatilization of the solution at room temperature.The crystal structures of six complexes were determined by single-crystal X-ray diffraction technology.The results showed that the complexes all have a binuclear structure,and the structures contain free ethanol molecules.Moreover,the coordination number of the central metal of each structural unit is eight.Adjacent structural units interact with each other through hydrogen bonds and further expand to form 1D chain-like and 2D planar structures.After conducting a systematic study on the luminescence properties of complexes 1-4,their emission and excitation spectra were obtained.Experimental results indicated that the fluorescence lifetimes of complexes 2 and 3 were 0.807 and 0.845 ms,respectively.The emission spectral data of complexes 1-4 were imported into the CIE chromaticity coordinate system,and their corre sponding luminescent regions cover the yellow light,red light,green light,and orange-red light bands,respectively.Within the temperature range of 299.15-1300 K,the thermal decomposition processes of the six complexes were comprehensively analyzed by using TG-DSC/FTIR/MS technology.The hypothesis of the gradual loss of ligand groups during the decomposition process was verified by detecting the escaped gas,3D infrared spectroscopy,and ion fragment information detected by mass spectrometry.The specific decomposition path is as follows:firstly,free ethanol molecules and neutral ligands are removed,and finally,acidic ligands are released;the final product is the corresponding metal oxide.CCDC:2430420,1;2430422,2;2430419,3;2430424,4;2430421,5;2430423,6.
基金Supported by the Science and Technology Cooperation and Exchange special project of Cooperation of Shanxi Province(202404041101014)the Fundamental Research Program of Shanxi Province(202403021212333)+3 种基金the Joint Funds of the National Natural Science Foundation of China(U24A20555)the Lvliang Key R&D of University-Local Cooperation(2023XDHZ10)the Initiation Fund for Doctoral Research of Taiyuan University of Science and Technology(20242026)the Outstanding Doctor Funding Award of Shanxi Province(20242080).
文摘To elucidate the effect of calcite-regulated activated carbon(AC)structure on low-temperature denitrification performance of SCR catalysts,this work prepared a series of Mn-Ce/De-AC-xCaCO_(3)(x is the calcite content in coal)catalysts were prepared by the incipient wetness impregnation method,followed by acid washing to remove calcium-containing minerals.Comprehensive characterization and low-temperature denitrification tests revealed that calcite-induced structural modulation of coal-derived AC significantly enhances catalytic activity.Specifically,NO conversion increased from 88.3%of Mn-Ce/De-AC to 91.7%of Mn-Ce/De-AC-1CaCO_(3)(210℃).The improved SCR denitrification activity results from the enhancement of physicochemical properties including higher Mn^(4+)content and Ce^(4+)/Ce^(3+)ratio,an abundance of chemisorbed oxygen and acidic sites,which could strengthen the SCR reaction pathways(richer NH_(3)activated species and bidentate nitrate active species).Therefore,NO removal is enhanced.
基金Supported by the National Key Research Program(No.2024-1129-954-112)National Natural Science Foundation of China(No.52372033)Guangxi Science and Technology Major Program(No.AA24263054)。
文摘Alkali-free SiO_(2)-Al_(2)O_(3)-CaO-MgO with different SiO_(2)/Al_(2)O_(3)mass ratios was prepared by conventional melt quenching method.The glass network structure,thermodynamic properties and elastic modulus changes with SiO_(2)and Al_(2)O_(3)ratios were investigated using various techniques.It is found that when SiO_(2)is replaced by Al_(2)O_(3),the Q^(4) to Q^(3) transition of silicon-oxygen network decreases while the aluminum-oxygen network increases,which result in the transformation of Si-O-Si bonds to Si-O-Al bonds and an increase in glass network connectivity even though the intermolecular bond strength decreases.The glass transition temperature(T_(g))increases continuously,while the thermal expansion coefficient increases and high-temperature viscosity first decreases and then increases.Meanwhile,the elastic modulus values increase from 93 to 102 GPa.This indicates that the elastic modulus is mainly affected by packing factor and dissociation energy,and elements with higher packing factors and dissociation energies supplant those with lower values,resulting in increased rigidity within the glass.
基金Funded by the National Natural Science Foundation of China(Nos.5226804252468035)。
文摘To investigate the pore structure of graphene oxide modified polymer cement mortar(GOPM)under salt-freeze-thaw(SFT)coupling effects and its impact on deterioration,this study modifies polymer cement mortar(EMCM)with graphene oxide(GO).The micro-pore structure of GOPM is characterized using LF-NMR and SEM.Fractal theory is applied to calculate the fractal dimension of pore volume,and the deterioration patterns are analyzed based on the evolution characteristics of capillary pores.The experimental results indicate that,after 25 salt-freeze-thaw cycles(SFTc),SO2-4 ions penetrate the matrix,generating corrosion products that fill existing pores and enhance the compactness of the specimen.As the number of cycles increases,the ongoing formation and expansion of corrosion products within the matrix,combined with persistent freezing forces,and result in the degradation of the pore structure.Therefore,the mass loss rate(MLR)of the specimens shows a trend of first decreasing and then increasing,while the relative dynamic elastic modulus(RDEM)initially increases and then decreases.Compared to the PC group specimens,the G3PM group specimens show a 28.71% reduction in MLR and a 31.42% increase in RDEM after 150 SFTc.The fractal dimensions of the transition pores,capillary pores,and macropores in the G3PM specimens first increase and then decrease as the number of SFTc increases.Among them,the capillary pores show the highest correlation with MLR and RDEM,with correlation coefficients of 0.97438 and 0.98555,respectively.
基金supported by National Natural Science Foundation of China(No.52025055 and 52275571)Basic Research Operation Fund of China(No.xzy012024024).
文摘Tilted metasurface nanostructures,with excellent physical properties and enormous application potential,pose an urgent need for manufacturing methods.Here,electric-field-driven generative-nanoimprinting technique is proposed.The electric field applied between the template and the substrate drives the contact,tilting,filling,and holding processes.By accurately controlling the introduced included angle between the flexible template and the substrate,tilted nanostructures with a controllable angle are imprinted onto the substrate,although they are vertical on the template.By flexibly adjusting the electric field intensity and the included angle,large-area uniform-tilted,gradient-tilted,and high-angle-tilted nanostructures are fabricated.In contrast to traditional replication,the morphology of the nanoimprinting structure is extended to customized control.This work provides a cost-effective,efficient,and versatile technology for the fabrication of various large-area tilted metasurface structures.As an illustration,a tilted nanograting with a high coupling efficiency is fabricated and integrated into augmented reality displays,demonstrating superior imaging quality.
基金Supported by the Key Science&Technology Project of Guangzhou(No.202103000045)the National Natural Science Foundation of China(No.82070972,No.82271093).
文摘AIM:To investigate the effects of shortening the duration of silicone oil tamponade on retinal structure and function in patients undergoing silicone oil removal(SOR)after surgery for primary rhegmatogenous retinal detachment(RRD).METHODS:A total of 58 eligible patients were enrolled and randomly assigned to two groups based on tamponade duration:the short-term group(30-45d)and the conventional group(≥90d).Comprehensive evaluations were performed before and after SOR,including slitlamp examination,best-corrected visual acuity(BCVA)measurement,intraocular pressure(IOP)testing,optical coherence tomography(OCT),optical coherence tomography angiography(OCTA),microperimetry,electroretinography(ERG),and visual evoked potential(VEP)assessment.RESULTS:A total of 33 patients(23 males and 10 females;33 eyes)were enrolled in the short-term SO tamponade group with mean age of 52.45±9.35y,and 25 patients(15 males and 10 females;25 eyes)were enrolled in the conventional SO tamponade group with mean age of 50.80±12.06y.Compared with the conventional group,the short-term silicone oil tamponade group had a significantly lower incidence of silicone oil emulsification and cataract progression,with no significant difference in retinal reattachment success rate.Structurally,short-term tamponade was associated with increased thickness of the retinal ganglion cell layer(RGCL)in the nasal and superior macular regions and improved recovery of superficial retinal vascular density in these areas.Functionally,the shortterm group showed better BCVA and retinal sensitivity both before and 1mo after SOR;additionally,the P100 amplitude in VEP tests was significantly increased in this group.CONCLUSION:Shortening the duration of silicone oil tamponade effectively reduces damage to retinal structure and function without compromising the success rate of retinal reattachment in patients with primary RRD.
基金supported by the National Basic Research Program of China (Grant 2012CB937500)the National Natural Science Foundation of China (Grants 11422219, 11227202, 11372217, 11272232)+1 种基金the Program for New Century Excellent Talents in University (Grant NCET-13)China Scholarship Council (201308120092)
文摘Si-based multilayer structures are widely used in current microelectronics. During their preparation, some inhomogeneous residual stress is induced, resulting in competition between interface mismatching and surface energy and even leading to structure failure. This work presents a methodological study on the measurement of residual stress in a multi-layer semiconductor heterostructure. Scanning electron microscopy（SEM）, micro-Raman spectroscopy（MRS）, and transmission electron microscopy（TEM） were applied to measure the geometric parameters of the multilayer structure. The relationship between the Raman spectrum and the stress/strain on the [100] and [110] crystal orientations was determined to enable surface and crosssection residual stress analyses, respectively. Based on the Raman mapping results, the distribution of residual stress along the depth of the multi-layer heterostructure was successfully obtained.
文摘In this paper,we report the study of the process of fabricating a multi-layermetal micro-structure using UV-LIGA overlay technology,includingmask fabrication,substrate treatment,and UV-LIGA overlay processes.To solve the process problems in the masking procedure,the swelling problemof the first layer of SU-8 thick photoresist was studied experimentally.The 5μmline-width compensation and closed 20μmand 30μmisolation strips were designed and fabricated around the micro-structure pattern.The pore problemin the Ni micro-electroforming layer was analyzed and the electroforming parameters were improved.The pH value of the electroforming solution should be controlled between 3.8 and 4.4 and the current density should be below 3 A/dm^2.To solve the problems of high inner stress and incomplete development of the micro-cylinder hole array with a diameter of 30μm,the lithography process was optimized.The pre-baking temperature was increased via gradient heating and rose every 5℃ from 65℃ to 85℃ and then remained at 85℃ for 50 min–1 h.In addition,the full contact exposure was used.Finally,a multi-layer metal micro-structure with high precision and good quality of microelectroforming layer was fabricated using UV-LIGA overlay technology.
基金Project(ZR2016EEQ03) supported by the Shandong Province Natural Science Foundation,ChinaProject(2018M641822) supported by the China Postdoctoral Science Foundation-General ProgramProject(HIT.NSRIF.201703) supported by the Natural Scientific Research Innovation Foundation in HIT,China
文摘The microstructure and mechanical properties of multi-layer multi-pass TIG welded joints of Al-Zn-Mg alloy plates were studied.The phase constituent and microstructure of different regions of the welded joints were characterized by scanning electron microscopy(SEM),X-ray diffraction(XRD),transmission electron microscopy(TEM)and energy disperse spectrum(EDS),while the mechanical properties were evaluated according to the impact test.A dispersively distributed spherical and needle-likeη(MgZn2)phase was obtained in the welding seam.The phase composition of the heat-affected zone(HAZ)wasα(Al)+η(MgZn2)+Al6Mn,and there were a large number of dispersively precipitated nanoscale particles.The welded joint zone had the highest impact toughness as compared with the other parts of the joint.The MgZn2 phase in the weld zone contributed to the improved toughness of the joint.Al2 MgCu phase in HAZ was proven to act as a crack source during fracture.
基金National Key Basic Research Development Program me of china(No.G2000067205-3)
文摘Laser multi\|layer cladding experiments were performed on the substrate of DD3 single crystal with FGH95 powder as cladding material.The solidification microstructure in the sample was investigated.It was found that the solidification microstructure was greatly influenced by the crystallography orientation of the substrate and the local solidification conditions.When the angle between the preferred orientation of the single crystal and the direction of heat flow in the cladding layer is less than 30°,single crystal cladding layers were acquired.Otherwise the crystallography orientation of the cladding layer will deviate from the orientation of the substrate and the microstructure with polycrystalline appears.Meanwhile,even when the experiments were performed on the same preferred crystal surface,the solidification microstructures will be different distinctly resulting from the variation of the local solidification conditions.The secondary arms were degenerated and the primary arm spacing was about 10\|20μm.Further investigation shows that the phases of the cladding layer are mainly made up ofγ,γ′,the flower\|likeγ/γ′eutectic and carbide.The morphology ofγ′was cubical and the size is less than 0.1μm.
基金This work was supported by the National Natural Science Foundation of China(Grant Nos.12122208 and 11972254)。
文摘Inspired that the neck structure can stabilize the head from body movements and external dynamic vibration by the role of intervertebral disc and surrounding muscles,a novel multi-layer structure with nonlinear elastic components is proposed in this paper.The proposed structure is expected for loading the weight of the end effector and isolating bending vibration with lowfrequency in the range of 0.1 Hz to 1 Hz.First,considering the loading,the potential energy,restoring force,and structural configuration in axial direction are defined.Then,the dynamical restoring force and stiffness for bending are modelled for different structural parameters and configurations after the axial weight.According to the functions of the proposed structure required in applications including loading capacity and bending vibration isolation effectiveness,design criteria are carried out.Due to the realization of high-order quasi-zero stiffness property,the effective isolation band for bending vibration can be extended from about 0.08 Hz.In addition,based on the proposed design criteria,the constructed multi-layer structure displays remarkable dynamical stabilization effectiveness in ultralow frequency band.The proposed structure not only provides the biological explanations for car sickness,nausea,and airsickness of humans,but also solves the bottleneck techniques in bioinspired nonlinear isolation structural design for transverse dynamical stabilization,which has remarkable potential applications in the fields of mechanical arm,sensors in satellite etc.
基金financially supported by the Natural Science Foundation of China(Nos.20634050,20804053 and 21074015)the Science Foundation of Beijing(No.212030)+1 种基金the National Basic Research Program of China(973 Project No.2011CB605605)the Fundamental Research Funds for the Central Universities
文摘Poly（ethylene oxide） multi-layer crystals were obtained and the re-crystallization behavior was studied to give insight into how melt thickness and temperature affect the lamellar orientation. For a special re-crystallization temperature, there exists a critical transition thickness range for the occurrence of edge-on lamellar orientation. Below the critical thickness, only flat-on lamellae were observed. While above the critical thickness, both flat-on and edge-on lamellae were found and the proportion of the edge-on lamellae increases with thickness. At low re-crystallization temperatures （below 30 ℃）, the critical transition thickness gradually increases from about 15 nm to 35 nm when the re-crystallization temperature was increased from 20 ℃ to 30 ℃. However, when the re-crystallization temperature is above 30 ℃, the critical transition thickness becomes constant. Our results demonstrated that the lamellar orientation could be specially modified by changing the melt thickness and re-crystallization temperature.
基金The authors are very grateful for the support received from the National Natural Science Foundation of China(No.11872121).
文摘The explosive reaction degree and protection from explosions are concerns in the military field.In this work,the reaction degree of the composition B explosive was investigated experimentally.Multi-layered compound structures were used as barriers to weaken the blast loads.A comprehensive experiment using a high-speed camera and image processing techniques,side witness plates,and bottom witness plates was presented.Using the experimental fragment velocities,fragment piercing patterns,and damage characteristics,the reaction degree of the explosive impeded by different multi-layered compound structures could be precisely differentiated.Reaction parameters of the explosive obstructed by compound structures were obtained by theoretical analysis and numerical simulations.Unlike the common method in which the explosive reaction degree is only distinguished based on the initial pressure amplitude transmitted into the explosive,a following shock wave reflected from the side steel casing was also considered.Different detonation growth paths in the explosive formed.Therefore,all these shock wave propagation characteristics must be considered to analyze the explosive response impeded by compound structures.
基金supported by Yunnan Provincial Education Department Science Foundation of China under Grant construction of the seventh batch of key engineering research centers in colleges and universities(Grant Project:Yunnan College and University Edge Computing Network Engineering Research Center).
文摘Sentiment analysis,commonly called opinion mining or emotion artificial intelligence(AI),employs biometrics,computational linguistics,nat-ural language processing,and text analysis to systematically identify,extract,measure,and investigate affective states and subjective data.Sentiment analy-sis algorithms include emotion lexicon,traditional machine learning,and deep learning.In the text sentiment analysis algorithm based on a neural network,multi-layer Bi-directional long short-term memory(LSTM)is widely used,but the parameter amount of this model is too huge.Hence,this paper proposes a Bi-directional LSTM with a trapezoidal structure model.The design of the trapezoidal structure is derived from classic neural networks,such as LeNet-5 and AlexNet.These classic models have trapezoidal-like structures,and these structures have achieved success in the field of deep learning.There are two benefits to using the Bi-directional LSTM with a trapezoidal structure.One is that compared with the single-layer configuration,using the of the multi-layer structure can better extract the high-dimensional features of the text.Another is that using the trapezoidal structure can reduce the model’s parameters.This paper introduces the Bi-directional LSTM with a trapezoidal structure model in detail and uses Stanford sentiment treebank 2(STS-2)for experiments.It can be seen from the experimental results that the trapezoidal structure model and the normal structure model have similar performances.However,the trapezoidal structure model parameters are 35.75%less than the normal structure model.
基金the supports by the National Natural Science Foundation of China (nos.11002026,11372039)Beijing Natural Science Foundation (no.3133039)the Scientific Research Foundation for the Returned (no.20121832001)
文摘A meshless radial basis function （RBF） collocation method based on the Eringen nonlocal elasticity theory is developed to calculate the band structures of ternary and quaternary nanoscale multi-layered phononic crystals （PNCs） with functionally graded （FG） interlayers. Detailed calculations are performed for anti-plane transverse waves propagating in such PNCs. The influences of FG and homogeneous interlayers, component number, nonlocal interface imperfections and nanoscale size on cut-off frequency and band structures are investigated in detail. Numerical results show that these factors have significant effects on band structures at the macroscopic and microscopic scales.
文摘Luquire et al. ' s impedance change model of a rectangular cross section probe coil above a structure with an arbitrary number of parallel layers was used to study the principle of measuring thicknesses of multi-layered structures in terms of eddy current testing voltage measurements. An experimental system for multi-layered thickness measurement was developed and several fitting models to formulate the relationships between detected impedance/voltage measurements and thickness are put forward using least square method. The determination of multi-layered thicknesses was investigated after inversing the voltage outputs of the detecting system. The best fitting and inversion models are presented.
