Rechargeable magnesium batteries(RMBs)hold promise for offering higher volumetric energy density and safety features,attracting increasing research interest as the next post lithium-ion batteries.Developing high perfo...Rechargeable magnesium batteries(RMBs)hold promise for offering higher volumetric energy density and safety features,attracting increasing research interest as the next post lithium-ion batteries.Developing high performance cathode material by inducing multi-electron reaction process as well as maintaining structural stability is the key to the development and application of RMBs.Herein,multielectron reaction occurred in VS_(4)by simple W doping strategy.W doping induces valence of partial V as V^(2+)and V^(3+)in VS_(4)structure,and then stimulates electrochemical reaction involving multi-electrons in 0.5%W-V-S.The flower-like microsphere morphology as well as rich S vacancies is also modulated by W doping to neutralize structure change in such multi-electron reaction process.The fabricated 0.5%W-V-S delivers higher specific capacity(149.3 m A h g^(-1)at 50 m A g^(-1),which is 1.6 times higher than that of VS_(4)),superior rate capability(76 mA h g^(-1)at 1000 mA g^(-1)),and stable cycling performance(1500cycles with capacity retention ratio of 93.8%).Besides that,pesudocapaticance-like contribution analysis as well as galvanostatic intermittent titration technique(GITT)further confirms the enhanced Mg^(2+)storage kinetics during such multi-electron involved electrochemical reaction process.Such discovery provides new insights into the designing of multi-electron reaction process in cathode as well as neutralizing structural change during such reaction for realizing superior electrochemical performance in energy storage devices.展开更多
Rechargeable aluminum batteries with multi-electron reaction have a high theoretical capacity for next generation of energy storage devices. However, the diffusion mechanism and intrinsic property of Al insertion into...Rechargeable aluminum batteries with multi-electron reaction have a high theoretical capacity for next generation of energy storage devices. However, the diffusion mechanism and intrinsic property of Al insertion into MnO_(2) are not clear. Hence, based on the first-principles calculations, key influencing factors of slow Al-ions diffusion are narrow pathways, unstable Al-O bonds and Mn^(3+) type polaron have been identified by investigating four types of δ-MnO_(2)(O3, O'3, P2 and T1). Although Al insert into δ-MnO_(2) leads to a decrease in the spacing of the Mn-Mn layer, P2 type MnO_(2) keeps the long(spacious pathways)and stable(2.007–2.030 A) Al-O bonds resulting in the lower energy barrier of Al diffusion of 0.56 e V. By eliminated the influence of Mn^(3+)(low concentration of Al insertion), the energy barrier of Al migration achieves 0.19 e V in P2 type, confirming the obviously effect of Mn^(3+) polaron. On the contrary, although the T1 type MnO_(2) has the sluggish of Al-ions diffusion, the larger interlayer spacing of Mn-Mn layer,causing by H_(2)O could assist Al-ions diffusion. Furthermore, it is worth to notice that the multilayer δ-MnO_(2) achieves multi-electron reaction of 3|e|. Considering the requirement of high energy density, the average voltage of P2(1.76 V) is not an obstacle for application as cathode in RABs. These discover suggest that layered MnO_(2) should keep more P2-type structure in the synthesis of materials and increase the interlayer spacing of Mn-Mn layer for providing technical support of RABs in large-scale energy storage.展开更多
Our previous work on the classical over-barrier ionization model for helium double ionization is extended to the complex multi-electron system of Ne. The total and q-fold ionization cross sections are calculated at en...Our previous work on the classical over-barrier ionization model for helium double ionization is extended to the complex multi-electron system of Ne. The total and q-fold ionization cross sections are calculated at energies ranging from a few tens to several hundred keV/u. The calculation results are in good agreement with the experimental data, and the energy dependence of the cross sections suggests that the multi-ionization of a strong perturbated complex atom is probably the sequential over-barrier ionization process.展开更多
Since the electrochemical energy storage was invented, mobile has brought us a new world without wires for more electronic devices [1–4]. Aluminum ion batteries(AIBs) were born with the requirements of electrochemica...Since the electrochemical energy storage was invented, mobile has brought us a new world without wires for more electronic devices [1–4]. Aluminum ion batteries(AIBs) were born with the requirements of electrochemical energy storage towards high capacity, safe and low cost.展开更多
Using the fully propagated time-dependent Hartree–Fock method, we identify that both the dynamic core polarization and multiorbital contributions are important in the attosecond transient absorption of CO molecules.T...Using the fully propagated time-dependent Hartree–Fock method, we identify that both the dynamic core polarization and multiorbital contributions are important in the attosecond transient absorption of CO molecules.The dynamics of core electrons effectively modifies the behaviors of electrons in the highest occupied molecular orbital, resulting in the modulation of intensity and position of the absorption peaks. Depending on the alignment angles, different inner orbitals are identified to contribute, and even dominate the total absorption spectra. As a result, multi-electron fingerprints are encoded in the absorption spectra, which shed light on future applications of attosecond transient absorption in complex systems.展开更多
Electrochemical batteries define the contraption stores electricity in the direct form of chemical energy with high efficiency. If the energy conversion process can be reversed, namely the input and output of electric...Electrochemical batteries define the contraption stores electricity in the direct form of chemical energy with high efficiency. If the energy conversion process can be reversed, namely the input and output of electricity both being permitted, the batteries are termed rechargeable batteries or also secondary batteries accordingly [1]. These decades have witnessed the rapid development of batteries because of the demands for transportation of information and mass in the mobile area, and stationary storage for the implementation of renewable energy technologies.展开更多
The oxidative polymerization of aryl sulfoxides provides a novel polysulfo-nium compound, poly(methylsulfonio-1,4-phenylenethio-1,4-phenylene cation) in quantita-tive yield. The polymerization proceeds efficiently in ...The oxidative polymerization of aryl sulfoxides provides a novel polysulfo-nium compound, poly(methylsulfonio-1,4-phenylenethio-1,4-phenylene cation) in quantita-tive yield. The polymerization proceeds efficiently in an acidic solution under atmosphericconditions. Oxygen, chemical and electrochemical oxidations are available. Vanadyl acety-lacetonate and cerium ammonium nitrate act as an effective catalyst for the oxygen ox-idative polymerization. The polymerization mechanism involves multielectron oxidation ofthe sulfides followed by successive electrophilic substitution. The resulting polyarylenesul-fonium cations are useful as a soluble precursor for the synthesis of high molecular weight(M_w>10~5) poly(thio arylne)s.展开更多
Influence of core property on multi-electron process in the collisions of q = 6-9 and 11 isocharged sequence ions with Ne is investigated in the keV/u region. The cross-section ratios of double-, triple-, quadruple- a...Influence of core property on multi-electron process in the collisions of q = 6-9 and 11 isocharged sequence ions with Ne is investigated in the keV/u region. The cross-section ratios of double-, triple-, quadruple- and total multielectron processes to the single electron capture process as well as the partial ratios of different reaction channels to the relevant multi-electron process are measured by using position-sensitive and time-of-flight techniques. The experimental data are compared with the theoretical predictions including the extended classical over-barrier model, the molecular Columbic barrier model and the semi-empirical scaling law. Results show a core effect on multi-electron process of isocharge ions colliding with Neon, which is consistent with the results of Helium we obtained previously.展开更多
We derive a new differential formula about a kind of product of polynomials and then apply it to analyze some properties of multi-electron state ＂related to Laughlin wave function＂. The entangled state representatio...We derive a new differential formula about a kind of product of polynomials and then apply it to analyze some properties of multi-electron state ＂related to Laughlin wave function＂. The entangled state representation for describing electrons in uniform magnetic field is used.展开更多
Defect engineering acts as an efficiency method to modulate the microstructure and electronic structure of cathode for rechargeable magnesium batteries(RMBs).Owing to rich sulfur(S)vacancies tunes the electronic struc...Defect engineering acts as an efficiency method to modulate the microstructure and electronic structure of cathode for rechargeable magnesium batteries(RMBs).Owing to rich sulfur(S)vacancies tunes the electronic structure of VS4 with rich S vacancies(V_(S)-VS_(4)),the lower oxidation state of V^(3+)is induced for achieving the V^(3+)/V^(4+)and V^(4+)/V^(5+)multi-electrons reaction for Mg^(2+)storage.Amorphous structure is also constructed in VS-VS4 by chemical vapor deposition(CVD)method under the high temperature for providing fast magnesium ions(Mg^(2+))diffusion channels and expanding inner stress release space to balance the structural stability of multi-electrons reaction process.The simple defect engineering realizes the stable multi-electrons reaction in V_(S)-VS_(4) for enhancing its Mg^(2+)storage performance with higher specific capacity(158.6 mAh·g^(-1) at 50 mA·g^(-1)),stable cycling performance(capacity retention ratio of 72.7% after 3600 cycles)and the superior rate capability.This work provides electrode designing guidance for achieving stable multi-electrons to fully utilize the bivalent property of multivalence metal batteries.展开更多
Sodium superionic conductors(NASICONs)have attracted enormous attention owing to their excellent ionic diffusion and structural stability.However,the high cost of vanadium,limited capacity due to fewer redox reactions...Sodium superionic conductors(NASICONs)have attracted enormous attention owing to their excellent ionic diffusion and structural stability.However,the high cost of vanadium,limited capacity due to fewer redox reactions,and low electronic conductivity restrict their practical application.Herein,we designed Na_(3.5)V_(0.5)Mn_(0.5)Fe_(0.5)Ti_(0.5)(PO_(4))3 (NVMFTP)medium entropy NASICON with multi-electron reactions as a fast sodium storage cathode for sodium-ion batteries(SIBs).The incorporation of Fe,Mn and Ti not only reduces the cost but also activates multi-redox reactions of V^(2+)/V^(3+),Ti^(3+)/Ti^(4+),Fe^(2+)/Fe^(3+),V^(3+)/V^(4+),Mn^(2+)/Mn^(3+),V^(4+)/V^(5+).Owing to distinctive structural design with medium entropy,the NVMFTP delivered 168 mAh·g^(−1) at 0.5C with a remarkable rate capability of 93.51 mAh·g^(−1) at 60C and steady long-term cycling performance till 5000 cycles.More importantly,NVMFTP takes only 11 min to achieve 80%SOC at 5C.The in-situ and ex-situ X-ray diffraction(XRD)further demonstrate reversible multi-electron reaction mechanisms of slow charging and fast charging.NVMFTP/HC full cell shows 110 mAh·g^(−1) capacity and 208 Wh·kg^(−1) energy density.This study will provide comprehensive insight into developing low-cost,cutting-edge materials for SIBs.展开更多
基金supported by the National Natural Science Foundation of China under Grant No.52072196,52002200,52102106,52202262,22379081,and 22379080Major Basic Research Program of the Natural Science Foundation of Shandong Province under Grant No.ZR2020ZD09+1 种基金the Natural Science Foundation of Shandong Province under Grant No.ZR2020QE063,ZR202108180009,ZR2023QE059the Postdoctoral Program in Qingdao under No.QDBSH20220202019。
文摘Rechargeable magnesium batteries(RMBs)hold promise for offering higher volumetric energy density and safety features,attracting increasing research interest as the next post lithium-ion batteries.Developing high performance cathode material by inducing multi-electron reaction process as well as maintaining structural stability is the key to the development and application of RMBs.Herein,multielectron reaction occurred in VS_(4)by simple W doping strategy.W doping induces valence of partial V as V^(2+)and V^(3+)in VS_(4)structure,and then stimulates electrochemical reaction involving multi-electrons in 0.5%W-V-S.The flower-like microsphere morphology as well as rich S vacancies is also modulated by W doping to neutralize structure change in such multi-electron reaction process.The fabricated 0.5%W-V-S delivers higher specific capacity(149.3 m A h g^(-1)at 50 m A g^(-1),which is 1.6 times higher than that of VS_(4)),superior rate capability(76 mA h g^(-1)at 1000 mA g^(-1)),and stable cycling performance(1500cycles with capacity retention ratio of 93.8%).Besides that,pesudocapaticance-like contribution analysis as well as galvanostatic intermittent titration technique(GITT)further confirms the enhanced Mg^(2+)storage kinetics during such multi-electron involved electrochemical reaction process.Such discovery provides new insights into the designing of multi-electron reaction process in cathode as well as neutralizing structural change during such reaction for realizing superior electrochemical performance in energy storage devices.
基金supported financially by the National Natural Science Foundation of China (No.22075028)。
文摘Rechargeable aluminum batteries with multi-electron reaction have a high theoretical capacity for next generation of energy storage devices. However, the diffusion mechanism and intrinsic property of Al insertion into MnO_(2) are not clear. Hence, based on the first-principles calculations, key influencing factors of slow Al-ions diffusion are narrow pathways, unstable Al-O bonds and Mn^(3+) type polaron have been identified by investigating four types of δ-MnO_(2)(O3, O'3, P2 and T1). Although Al insert into δ-MnO_(2) leads to a decrease in the spacing of the Mn-Mn layer, P2 type MnO_(2) keeps the long(spacious pathways)and stable(2.007–2.030 A) Al-O bonds resulting in the lower energy barrier of Al diffusion of 0.56 e V. By eliminated the influence of Mn^(3+)(low concentration of Al insertion), the energy barrier of Al migration achieves 0.19 e V in P2 type, confirming the obviously effect of Mn^(3+) polaron. On the contrary, although the T1 type MnO_(2) has the sluggish of Al-ions diffusion, the larger interlayer spacing of Mn-Mn layer,causing by H_(2)O could assist Al-ions diffusion. Furthermore, it is worth to notice that the multilayer δ-MnO_(2) achieves multi-electron reaction of 3|e|. Considering the requirement of high energy density, the average voltage of P2(1.76 V) is not an obstacle for application as cathode in RABs. These discover suggest that layered MnO_(2) should keep more P2-type structure in the synthesis of materials and increase the interlayer spacing of Mn-Mn layer for providing technical support of RABs in large-scale energy storage.
基金Project supported the by the National Natural Science Foundation of China (Grant No. 10804039)the Fundamental Research Funds for the Central Universities,China (Grant No. lzujbky-2009-24)
文摘Our previous work on the classical over-barrier ionization model for helium double ionization is extended to the complex multi-electron system of Ne. The total and q-fold ionization cross sections are calculated at energies ranging from a few tens to several hundred keV/u. The calculation results are in good agreement with the experimental data, and the energy dependence of the cross sections suggests that the multi-ionization of a strong perturbated complex atom is probably the sequential over-barrier ionization process.
基金supported by the National Natural Science Foundation of China (Grant No. 22075028)。
文摘Since the electrochemical energy storage was invented, mobile has brought us a new world without wires for more electronic devices [1–4]. Aluminum ion batteries(AIBs) were born with the requirements of electrochemical energy storage towards high capacity, safe and low cost.
基金Supported by the National Basic Research Program of China under Grant No 2013CB922203the National Natural Science Foundation of China under Grant No 11374366+1 种基金the Innovation Foundation of National University of Defense Technology under Grant No B110204the Hunan Provincial Innovation Foundation for Postgraduate under Grant No CX2011B010
文摘Using the fully propagated time-dependent Hartree–Fock method, we identify that both the dynamic core polarization and multiorbital contributions are important in the attosecond transient absorption of CO molecules.The dynamics of core electrons effectively modifies the behaviors of electrons in the highest occupied molecular orbital, resulting in the modulation of intensity and position of the absorption peaks. Depending on the alignment angles, different inner orbitals are identified to contribute, and even dominate the total absorption spectra. As a result, multi-electron fingerprints are encoded in the absorption spectra, which shed light on future applications of attosecond transient absorption in complex systems.
基金the National Basic Research Program of China (Grant Nos. 2015CB251100, 2009CB220100, 2002CB211800) for financial support。
文摘Electrochemical batteries define the contraption stores electricity in the direct form of chemical energy with high efficiency. If the energy conversion process can be reversed, namely the input and output of electricity both being permitted, the batteries are termed rechargeable batteries or also secondary batteries accordingly [1]. These decades have witnessed the rapid development of batteries because of the demands for transportation of information and mass in the mobile area, and stationary storage for the implementation of renewable energy technologies.
基金This work was partially supported by a Grant-in-Aid for Research Fellow of the Japan Society for the Promotion of Science(No.085410)and International Scientific Research(Joint Research No.08044174)from the Ministry of Education,Science,Sports and Culture
文摘The oxidative polymerization of aryl sulfoxides provides a novel polysulfo-nium compound, poly(methylsulfonio-1,4-phenylenethio-1,4-phenylene cation) in quantita-tive yield. The polymerization proceeds efficiently in an acidic solution under atmosphericconditions. Oxygen, chemical and electrochemical oxidations are available. Vanadyl acety-lacetonate and cerium ammonium nitrate act as an effective catalyst for the oxygen ox-idative polymerization. The polymerization mechanism involves multielectron oxidation ofthe sulfides followed by successive electrophilic substitution. The resulting polyarylenesul-fonium cations are useful as a soluble precursor for the synthesis of high molecular weight(M_w>10~5) poly(thio arylne)s.
基金Project supported by the National Natural Science Foundation of China (Grant Nos. 10874188 and 10775160)
文摘Influence of core property on multi-electron process in the collisions of q = 6-9 and 11 isocharged sequence ions with Ne is investigated in the keV/u region. The cross-section ratios of double-, triple-, quadruple- and total multielectron processes to the single electron capture process as well as the partial ratios of different reaction channels to the relevant multi-electron process are measured by using position-sensitive and time-of-flight techniques. The experimental data are compared with the theoretical predictions including the extended classical over-barrier model, the molecular Columbic barrier model and the semi-empirical scaling law. Results show a core effect on multi-electron process of isocharge ions colliding with Neon, which is consistent with the results of Helium we obtained previously.
基金The project supported by National Natural Science Foundation of China under Grant No. 10475056
文摘We derive a new differential formula about a kind of product of polynomials and then apply it to analyze some properties of multi-electron state ＂related to Laughlin wave function＂. The entangled state representation for describing electrons in uniform magnetic field is used.
基金supported by the National Natural Science Foundation of China(Nos.52072196,52002200,52102106,52202262,22379081,and 22379080)Major Basic Research Program of Natural Science Foundation of Shandong Province(No.ZR2020ZD09)+1 种基金the Natural Science Foundation of Shandong Province(Nos.ZR2020QE063,ZR202108180009,and ZR2023QE059)the Postdoctoral Program of Qingdao(No.QDBSH20220202019).
文摘Defect engineering acts as an efficiency method to modulate the microstructure and electronic structure of cathode for rechargeable magnesium batteries(RMBs).Owing to rich sulfur(S)vacancies tunes the electronic structure of VS4 with rich S vacancies(V_(S)-VS_(4)),the lower oxidation state of V^(3+)is induced for achieving the V^(3+)/V^(4+)and V^(4+)/V^(5+)multi-electrons reaction for Mg^(2+)storage.Amorphous structure is also constructed in VS-VS4 by chemical vapor deposition(CVD)method under the high temperature for providing fast magnesium ions(Mg^(2+))diffusion channels and expanding inner stress release space to balance the structural stability of multi-electrons reaction process.The simple defect engineering realizes the stable multi-electrons reaction in V_(S)-VS_(4) for enhancing its Mg^(2+)storage performance with higher specific capacity(158.6 mAh·g^(-1) at 50 mA·g^(-1)),stable cycling performance(capacity retention ratio of 72.7% after 3600 cycles)and the superior rate capability.This work provides electrode designing guidance for achieving stable multi-electrons to fully utilize the bivalent property of multivalence metal batteries.
基金supported by the National Natural Science Foundation of China(Nos.52027801 and 92263203)the National Key R&D Program of China(Nos.2022YFA1203902 and 2022YFA1200093)and the China-Germany Collaboration Project(No.M-0199)。
文摘Sodium superionic conductors(NASICONs)have attracted enormous attention owing to their excellent ionic diffusion and structural stability.However,the high cost of vanadium,limited capacity due to fewer redox reactions,and low electronic conductivity restrict their practical application.Herein,we designed Na_(3.5)V_(0.5)Mn_(0.5)Fe_(0.5)Ti_(0.5)(PO_(4))3 (NVMFTP)medium entropy NASICON with multi-electron reactions as a fast sodium storage cathode for sodium-ion batteries(SIBs).The incorporation of Fe,Mn and Ti not only reduces the cost but also activates multi-redox reactions of V^(2+)/V^(3+),Ti^(3+)/Ti^(4+),Fe^(2+)/Fe^(3+),V^(3+)/V^(4+),Mn^(2+)/Mn^(3+),V^(4+)/V^(5+).Owing to distinctive structural design with medium entropy,the NVMFTP delivered 168 mAh·g^(−1) at 0.5C with a remarkable rate capability of 93.51 mAh·g^(−1) at 60C and steady long-term cycling performance till 5000 cycles.More importantly,NVMFTP takes only 11 min to achieve 80%SOC at 5C.The in-situ and ex-situ X-ray diffraction(XRD)further demonstrate reversible multi-electron reaction mechanisms of slow charging and fast charging.NVMFTP/HC full cell shows 110 mAh·g^(−1) capacity and 208 Wh·kg^(−1) energy density.This study will provide comprehensive insight into developing low-cost,cutting-edge materials for SIBs.
