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Robust Hyper-Polarization Protocol of Nuclear Spins via Magic Sequence
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作者 Haiyang Li Yongju Li +1 位作者 Hao Liao Ping Wang 《Chinese Physics Letters》 2026年第1期105-128,共24页
Hyperpolarization of nuclear spins is crucial for advancing nuclear magnetic resonance and quantum information technologies,as nuclear spins typically exhibit extremely low polarization at room temperature due to thei... Hyperpolarization of nuclear spins is crucial for advancing nuclear magnetic resonance and quantum information technologies,as nuclear spins typically exhibit extremely low polarization at room temperature due to their small gyromagnetic ratios.A promising approach to achieving high nuclear spin polarization is transferring the polarization of electrons to nuclear spins.The nitrogen-vacancy(NV)center in diamond has emerged as a highly effective medium for this purpose,and various hyperpolarization protocols have been developed.Among these,the pulsed polarization(PulsePol)method has been extensively studied due to its robustness against static energy shifts of the electron spin.In this work,we present a novel polarization protocol and uncover a family of magic sequences for hyperpolarizing nuclear spins,with PulsePol emerging as a special case of our general approach.Notably,we demonstrate that some of these magic sequences exhibit significantly greater robustness compared to the PulsePol protocol in the presence of finite half𝜋pulse duration of the protocol,Rabi and detuning errors.This enhanced robustness positions our protocol as a more suitable candidate for hyper-polarizing nuclear spins species with large gyromagnetic ratios and also ensures better compatibility with high-efficiency readout techniques at high magnetic fields.Additionally,the generality of our protocol allows for its direct application to other solid-state quantum systems beyond the NV center. 展开更多
关键词 transferring polarization electrons hyperpolarization protocols quantum information technologiesas nuclear spins pulse polarization nuclear spin polarization magic sequences nuclear magnetic resonance
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FAAD:an unsupervised fast and accurate anomaly detection method for a multi-dimensional sequence over data stream 被引量:1
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作者 Bin LI Yi-jie WANG +2 位作者 Dong-sheng YANG Yong-mou LI Xing-kong MA 《Frontiers of Information Technology & Electronic Engineering》 SCIE EI CSCD 2019年第3期388-404,共17页
Recently, sequence anomaly detection has been widely used in many fields. Sequence data in these fields are usually multi-dimensional over the data stream. It is a challenge to design an anomaly detection method for a... Recently, sequence anomaly detection has been widely used in many fields. Sequence data in these fields are usually multi-dimensional over the data stream. It is a challenge to design an anomaly detection method for a multi-dimensional sequence over the data stream to satisfy the requirements of accuracy and high speed. It is because:(1) Redundant dimensions in sequence data and large state space lead to a poor ability for sequence modeling;(2) Anomaly detection cannot adapt to the high-speed nature of the data stream, especially when concept drift occurs, and it will reduce the detection rate. On one hand, most existing methods of sequence anomaly detection focus on the single-dimension sequence. On the other hand, some studies concerning multi-dimensional sequence concentrate mainly on the static database rather than the data stream. To improve the performance of anomaly detection for a multi-dimensional sequence over the data stream, we propose a novel unsupervised fast and accurate anomaly detection(FAAD) method which includes three algorithms. First, a method called "information calculation and minimum spanning tree cluster" is adopted to reduce redundant dimensions. Second, to speed up model construction and ensure the detection rate for the sequence over the data stream, we propose a method called"random sampling and subsequence partitioning based on the index probabilistic suffix tree." Last, the method called "anomaly buffer based on model dynamic adjustment" dramatically reduces the effects of concept drift in the data stream. FAAD is implemented on the streaming platform Storm to detect multi-dimensional log audit data.Compared with the existing anomaly detection methods, FAAD has a good performance in detection rate and speed without being affected by concept drift. 展开更多
关键词 Data STREAM multi-dimensional sequence ANOMALY detection Concept DRIFT Feature selection
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Composite anti-disturbance predictive control of unmanned systems with time-delay using multi-dimensional Taylor network 被引量:1
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作者 Chenlong LI Wenshuo LI Zejun ZHANG 《Chinese Journal of Aeronautics》 2025年第7期589-600,共12页
A composite anti-disturbance predictive control strategy employing a Multi-dimensional Taylor Network(MTN)is presented for unmanned systems subject to time-delay and multi-source disturbances.First,the multi-source di... A composite anti-disturbance predictive control strategy employing a Multi-dimensional Taylor Network(MTN)is presented for unmanned systems subject to time-delay and multi-source disturbances.First,the multi-source disturbances are addressed according to their specific characteristics as follows:(A)an MTN data-driven model,which is used for uncertainty description,is designed accompanied with the mechanism model to represent the unmanned systems;(B)an adaptive MTN filter is used to remove the influence of the internal disturbance;(C)an MTN disturbance observer is constructed to estimate and compensate for the influence of the external disturbance;(D)the Extended Kalman Filter(EKF)algorithm is utilized as the learning mechanism for MTNs.Second,to address the time-delay effect,a recursiveτstep-ahead MTN predictive model is designed utilizing recursive technology,aiming to mitigate the impact of time-delay,and the EKF algorithm is employed as its learning mechanism.Then,the MTN predictive control law is designed based on the quadratic performance index.By implementing the proposed composite controller to unmanned systems,simultaneous feedforward compensation and feedback suppression to the multi-source disturbances are conducted.Finally,the convergence of the MTN and the stability of the closed-loop system are established utilizing the Lyapunov theorem.Two exemplary applications of unmanned systems involving unmanned vehicle and rigid spacecraft are presented to validate the effectiveness of the proposed approach. 展开更多
关键词 multi-dimensional Taylor network Composite anti-disturbance Predictive control Unmanned systems Multi-source disturbances TIME-DELAY
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Detailed oil-source correlation within the sequence and sedimentary framework in the Fushan Depression,Beibuwan Basin,South China Sea 被引量:1
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作者 Xin Wang Mei-Jun Li +3 位作者 Yang Shi Hao Guo Bang Zeng Xi He 《Petroleum Science》 2025年第1期90-109,共20页
The Fushan Depression is one of the petroliferous depressions in the Beibuwan Basin,South China Sea.Previous studies have preliminarily explored the origin and source of crude oils in some areas of this depression.Nev... The Fushan Depression is one of the petroliferous depressions in the Beibuwan Basin,South China Sea.Previous studies have preliminarily explored the origin and source of crude oils in some areas of this depression.Nevertheless,no systematic investigations on the classification and origin of oils and hy-drocarbon migration processes have been made for the entire petroleum system in this depression,which has significantly hindered the hydrocarbon exploration in the region.A total of 32 mudstone and 58 oil samples from the Fushan Depression were analyzed to definite the detailed oil-source correlation within the sequence and sedimentary framework.The organic matter of third member of Paleogene Liushagang Formation(Els(3))source rocks,both deltaic and lacustrine mudstone,are algal-dominated with high abundance of C_(23)tricyclic terpane and C_(30)4-methylsteranes.The deltaic source rocks occur-ring in the first member(Els_(1))and second member(Els_(2))of the Paleogene Liushagang Formation are characterized by high abundance of C_(19+20)tricyclic terpane and oleanane,reflecting a more terrestrial plants contribution.While lacustrine source rocks of Els_(1)and Els_(2)display the reduced input of terrige-nous organic matter with relatively low abundance of C 19+20 tricyclic terpane and oleanane.Three types of oils were identified by their biomarker compositions in this study.Most of the oils discovered in the Huachang and Bailian Els_(1)reservoir belong to group A and were derived from lacustrine source rocks of Els_(1)and Els_(2).Group B oils are found within the Els_(1)and Els_(2)reservoirs,showing a close relation to the deltaic source rocks of Els_(1)and Els_(2),respectively.Group C oils,occurring in the Els3 reservoirs,have a good affinity with the Els3 source rocks.The spatial distribution and accumulation of different groups of oils are mainly controlled by the sedimentary facies and specific structural conditions.The Els_(2)reservoir in the Yong'an area belonging to Group B oil,are adjacent to the source kitchen and could be considered as the favorable exploration area in the future. 展开更多
关键词 Oil-source correlation sequence stratigraphic framework Biomarkers Fushan depression South China Sea
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Relationship between pore throat structure and crude oil mobility of full particle sequence reservoirs in Permian Fengcheng Formation,Mahu Sag,Junggar Basin,NW China 被引量:2
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作者 TANG Yong JIA Chengzao +8 位作者 CHEN Fangwen HE Wenjun ZHI Dongming SHAN Xiang YOU Xincai JIANG Lin ZOU Yang WU Tao XIE An 《Petroleum Exploration and Development》 2025年第1期112-124,共13页
Based on the experimental results of casting thin section,low temperature nitrogen adsorption,high pressure mercury injection,nuclear magnetic resonance T2 spectrum,contact angle and oil-water interfacial tension,the ... Based on the experimental results of casting thin section,low temperature nitrogen adsorption,high pressure mercury injection,nuclear magnetic resonance T2 spectrum,contact angle and oil-water interfacial tension,the relationship between pore throat structure and crude oil mobility characteristics of full particle sequence reservoirs in the Lower Permian Fengcheng Formation of Mahu Sag,Junggar Basin,are revealed.(1)With the decrease of reservoir particle size,the volume of pores connected by large throats and the volume of large pores show a decreasing trend,and the distribution and peak ranges of throat and pore radius shift to smaller size in an orderly manner.The upper limits of throat radius,porosity and permeability of unconventional reservoirs in Fengcheng Formation are approximately 0.7μm,8%and 0.1×10^(−3)μm^(2),respectively.(2)As the reservoir particle size decreases,the distribution and peak ranges of pores hosting retained oil and movable oil are shifted to a smaller size in an orderly manner.With the increase of driving pressure,the amount of retained and movable oil of the larger particle reservoir samples shows a more obvious trend of decreasing and increasing,respectively.(3)With the increase of throat radius,the driving pressure of reservoir with different particle levels presents three stages,namely rapid decrease,slow decrease and stabilization.The oil driving pressures of various reservoirs and the differences of them decrease with the increase of temperature and obviously decrease with the increase of throat radius.According to the above experimental analysis,it is concluded that the deep shale oil of Fengcheng Formation in Mahu Sag has great potential for production under geological conditions. 展开更多
关键词 Junggar Basin Mahu Sag Lower Permian Fengcheng Formation full particle sequence reservoir pore throat structure crude oil mobility whole petroleum system
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Progradational sequence stratigraphic architecture of the Triassic Yanchang Formation and a case study of Qingcheng Oilfield,Ordos Basin,NW China 被引量:1
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作者 HUI Xiao HOU Yunchao +2 位作者 QU Tong ZHANG Jie YANG Zhi 《Petroleum Exploration and Development》 2025年第5期1164-1178,共15页
To address the discrepancies between well and seismic data in stratigraphic correlation of the Triassic Yanchang Formation in the Ordos Basin,NW China,traditional stratigraphic classification schemes,the latest 3D sei... To address the discrepancies between well and seismic data in stratigraphic correlation of the Triassic Yanchang Formation in the Ordos Basin,NW China,traditional stratigraphic classification schemes,the latest 3D seismic and drilling data,and reservoir sections are thoroughly investigated.Guided by the theory of sequence stratigraphy,the progradational sequence stratigraphic framework of the Yanchang Formation is systematically constructed to elucidate new deposition mechanisms in the depressed lacustrine basin,and it has been successfully applied to the exploration and development practices in the Qingcheng Oilfield.Key findings are obtained in three aspects.First,the seismic progradational reflections,marker tuff beds,and condensed sections of flooding surfaces in the Yanchang Formation are consistent and isochronous.Using flooding surface markers as a reference,a progradational sequence stratigraphic architecture is reconstructed for the middle-upper part of Yanchang Formation,and divided into seven clinoform units(CF1-CF7).Second,progradation predominantly occurs in semi-deep to deep lake environments,with the depositional center not always coinciding with the thickest strata.The lacustrine basin underwent an evolution of“oscillatory regression-progradational infilling-multi-phase superimposition”.Third,the case study of Qingcheng Oilfield reveals that the major pay zones consist of“isochronous but heterochronous”gravity-flow sandstone complexes.Guided by the progradational sequence stratigraphic architecture,horizontal well oil-layer penetration rates remain above 82%.The progradational sequence stratigraphic architecture and associated geological insights are more consistent with the sedimentary infilling mechanisms of large-scale continental depressed lacustrine basins and actual drilling results.The research results provide crucial theoretical and technical support for subsequent refined exploration and development of the Yanchang Formation,and are expected to offer a reference for research and production practice in similar continental lacustrine basins. 展开更多
关键词 progradational sequence stratigraphic architecture CLINOFORM flooding surface continental depression lacustrine basin Ordos Basin TRIASSIC Yanchang Formation
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The Supplementary Motor Area as a Flexible Hub Mediating Behavioral and Neuroplastic Changes in Motor Sequence Learning:A TMS and TMS-EEG Study 被引量:1
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作者 Jing Chen Yanzi Fan +6 位作者 Xize Jia Fengmei Fan Jinhui Wang Qihong Zou Bing Chen Xianwei Che Yating Lv 《Neuroscience Bulletin》 2025年第5期837-852,共16页
Attempts have been made to modulate motor sequence learning(MSL)through repetitive transcranial magnetic stimulation,targeting different sites within the sensorimotor network.However,the target with the optimum modula... Attempts have been made to modulate motor sequence learning(MSL)through repetitive transcranial magnetic stimulation,targeting different sites within the sensorimotor network.However,the target with the optimum modulatory effect on neural plasticity associated with MSL remains unclarified.This study was therefore designed to compare the role of the left primary motor cortex and the left supplementary motor area proper(SMAp)in modulating MSL across different complexity levels and for both hands,as well as the associated neuroplasticity by applying intermittent theta burst stimulation together with the electroencephalogram and concurrent transcranial magnetic stimulation.Our data demonstrated the role of SMAp stimulation in modulating neural communication to support MSL,which is achieved by facilitating regional activation and orchestrating neural coupling across distributed brain regions,particularly in interhemispheric connections.These findings may have important clinical implications,particularly for motor rehabilitation in populations such as post-stroke patients. 展开更多
关键词 Motor sequence learning Intermittent theta burst stimulation Concurrent transcranial magnetic stimulation and electroencephalogram NEUROPLASTICITY Functional connectivity
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Molecular Identification of Echinococcus spp. and Other Taeniid Tapeworms Using Next-Generation Sequence Analysis of PCR Amplified 18s rRNA Gene
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作者 Rasmi Abu-Helu George Kokaly +3 位作者 Sajeda Nojoum Imad Matouk Murad Ibrahim Ibrahim Abbasi 《American Journal of Molecular Biology》 2025年第1期75-87,共13页
Cystic echinococcosis (CE) is a prevalent zoonotic disease caused by Echinococcus granulosus, with a cosmopolitan distribution. The parasite is transmitted cyclically between canines and numerous intermediate herbivor... Cystic echinococcosis (CE) is a prevalent zoonotic disease caused by Echinococcus granulosus, with a cosmopolitan distribution. The parasite is transmitted cyclically between canines and numerous intermediate herbivorous livestock animals. Also, other Taeniid tapeworms could infect domestic dogs and they pose significant veterinary and public health concerns worldwide. This study aimed to develop a sensitive molecular method for detecting Echinococcus spp. DNA in dog fecal samples using next-generation sequencing (NGS). A set of PCR primers targeting conserved regions of Taeniid tapeworms’ 18s rRNA genes was designed and tested for amplifying genomic DNA from various tapeworm species. The PCR system demonstrated high sensitivity, amplifying DNA from all tested tapeworm species, with differences observed in amplified band sizes. The primers were adapted for NGS analysis by adding forward and reverse adapters, enabling the sequencing of amplified DNA fragments. Application of the developed PCR system to dog fecal samples collected from Yatta town, Palestine, revealed the presence of E. granulosus DNA in five out of 50 samples. NGS analysis confirmed the specificity of the amplified DNA fragments, showing 98% - 99% similarity with the 18s rDNA gene of E. granulosus. This study demonstrates the utility of NGS-based molecular methods for accurate and sensitive detection of Echinococcus spp. in dog fecal samples, providing valuable insights for epidemiological surveillance and control programs of echinococcosis in endemic regions. 展开更多
关键词 Cystic Echinococcosis Taeniid Tapeworms Next-Generation sequencing Molecular Detection Dog Fecal Samples
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Retraced Multi-dimensional Chinese Logic System behind Chinese Medicine
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作者 Edwin C.L.Yu 《Chinese Medicine and Culture》 2025年第1期1-12,共12页
The ancient tacit knowledge behind the logic system permeated the culture and promoted numerous impactful inventions throughout the history. Traditional Chinese medicine with its effectiveness should also have stemmed... The ancient tacit knowledge behind the logic system permeated the culture and promoted numerous impactful inventions throughout the history. Traditional Chinese medicine with its effectiveness should also have stemmed out from such logic system. This article aims to rearticulate the underlying lucid multi-dimensional logic system, which faded in obscurity only because of time-out loss of the mid-right concept. Retracing this past tacit but important concept could uncover a multi-dimensional system over a point relating to all matters while capturing the central core of the matter. The seemingly unmanageable multidimensional logic was strengthened by verification processes which affirmed its further extensions, and made up the language of the people, the concepts of yin-yang(阴阳), and the development of extensions of Ba Gua(八卦) derivatives, which furthered the interpretation of the space-time properties and Chinese medicine. 展开更多
关键词 multi-dimensional logic system Traditional Chinese medicine YIN-YANG
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Effective stress dissipation by multi-dimensional architecture engineering for ultrafast and ultralong sodium storage
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作者 Man Zhang Jing Zhu +7 位作者 Qianqian Li Fenghua Zheng Sijiang Hu Youguo Huang Hongqiang Wang Xing Ou Qichang Pan Qingyu Li 《Journal of Energy Chemistry》 2025年第2期619-629,I0013,共12页
Stress accumulation is a key factor leading to sodium storage performance deterioration for NiSe_(2)-based anodes.Therefore,inhibiting the concentrated local stress during the sodiataion/desodiation process is crucial... Stress accumulation is a key factor leading to sodium storage performance deterioration for NiSe_(2)-based anodes.Therefore,inhibiting the concentrated local stress during the sodiataion/desodiation process is crucial for acquiring stable NiSe2-based materials for sodium-ion batteries(SIBs),Herein,a stress dissipation strategy driven by architecture engineering is proposed,which can achieve ultrafast and ultralong sodium storage properties.Different from the conventional sphere-like or rod-like architecture,the three-dimensional(3D)flower-like NiSe_(2)@C composite is delicately designed and assembled with onedimensional nanorods and carbon framework.More importantly,the fundamental mechanism of improved structure stability is unveiled by simulations and experimental results simultaneously.It demonstrates that this designed multidimensional flower-like architecture with dispersed nanorods can balance the structural mismatch,avoid concentrated local strain,and relax the internal stress,mainly induced by the unavoidable volume variation during the repeated conversion processes.Moreover,it can provide more Na^(+)-storage sites and multi-directional migration pathways,leading to a fast Na^(+)-migration channel with boosted reaction kinetic.As expected,it delivers superior rate performance(441 mA h g^(-1)at 5.0 A g^(-1))and long cycling stability(563 mA h g^(-1)at 1.0 A g^(-1)over 1000 cycles)for SIBs.This work provides useful insights for designing high-performance conversion-based anode materials for SIBs. 展开更多
关键词 Stress dissipation multi-dimensional architecture Structure engineering Conversion-based anodes Sodium-ion batteries
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The 2-adic complexity of sum sequences of Legendre sequences
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作者 JING Xiaoyan XU Zhefeng FENG Keqin 《纯粹数学与应用数学》 2025年第2期191-199,共9页
Binary sequences constructed by Legendre symbols are widely used in communication and cryptography since they have many good pseudo-random properties.In this paper,we determine the 2-adic complexity of the sum sequenc... Binary sequences constructed by Legendre symbols are widely used in communication and cryptography since they have many good pseudo-random properties.In this paper,we determine the 2-adic complexity of the sum sequence of any k many Legendre sequences and show that the 2-adic complexity of the sum sequences of any k many Legendre sequences reaches the maximum by proving the case of k=2 and 3,which implies that the sum sequences can resist the attack of rational approximation algorithm. 展开更多
关键词 2-adic complexity binary sequences Legendre symbol Legendre sequences
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Research on Multi-Dimensional Collaborative Strategies in Design Management,Investment Management,and Beyond from the Perspective of Whole-Process Engineering Consulting
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作者 Zexin Chen 《Journal of Architectural Research and Development》 2025年第5期21-28,共8页
This paper explores whole-process engineering consulting,including its application models in public buildings and elderly-friendly projects,such as service integration and whole lifecycle management.It also addresses ... This paper explores whole-process engineering consulting,including its application models in public buildings and elderly-friendly projects,such as service integration and whole lifecycle management.It also addresses the construction of multi-dimensional collaborative theoretical models,public space streamline organization,and other aspects,emphasizing the importance of multi-dimensional collaboration.Additionally,it highlights the role of talent cultivation and digital transformation in enhancing project efficiency. 展开更多
关键词 Whole-process engineering consulting multi-dimensional collaboration Project efficiency
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Practical Application of the Multi-Dimensional Interactive Teaching Model in College English
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作者 Bo Sun 《Journal of Contemporary Educational Research》 2025年第10期106-111,共6页
The multi-dimensional interactive teaching model significantly enhances the effectiveness of college English instruction by emphasizing dynamic engagement between teachers and students,as well as among students themse... The multi-dimensional interactive teaching model significantly enhances the effectiveness of college English instruction by emphasizing dynamic engagement between teachers and students,as well as among students themselves.This paper explores practical strategies for implementing this model,focusing on four key aspects:deepening teachers’understanding of the model through continuous learning,innovating interactive methods such as questioning techniques and practical activities,leveraging modern technology to integrate resources and track learning progress,and establishing a communication platform that centers on student participation.By adopting these approaches,the model fosters a student-centered classroom environment,improves comprehensive English application skills,and optimizes overall teaching quality. 展开更多
关键词 multi-dimensional interactive teaching model Student-centered approach Teacher-student interaction
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Construction of the Practice System of Landscape Architecture Major Based on“Multi-dimensional Integration”
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作者 LI Yinan DING Juan +4 位作者 ZHU Yan WU Jing ZHAO Zhiyan LI Jie XIANG Cheng 《Journal of Landscape Research》 2025年第3期89-92,共4页
During the critical transformation period of landscape architecture major after the adjustment of disciplinary structure and the changes in market demand,private colleges and universities,as important places for culti... During the critical transformation period of landscape architecture major after the adjustment of disciplinary structure and the changes in market demand,private colleges and universities,as important places for cultivating local talents,have pain points such as uneven quality of teachers and students and weak innovation and practice.The practice system with“multi-dimensional Integration”integrates four dimensions:interdisciplinary integration,spatial and temporal intersection,historical inheritance,and behavioral activity,deepens the disciplinary connotation,and integrates the three elements of nature,humanity,and technology,aiming to provide a new path for private colleges and universities to cultivate application-oriented and compound talents with innovative capabilities.In terms of optimizing talent cultivation and adapting to industry changes,this system provides thinking and reference for landscape architecture major,helping the major reshape its core competitiveness and promoting educational innovation and industry development. 展开更多
关键词 Landscape architecture Practice system multi-dimensional integration”model Talent cultivation Teaching reform
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Reliability of multi-dimensional network systems with nodes having stochastic connection ranges
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作者 FU Yuqiang MA Xiaoyang ZHAO Fei 《Journal of Systems Engineering and Electronics》 2025年第4期1017-1023,共7页
This paper proposes a reliability evaluation model for a multi-dimensional network system,which has potential to be applied to the internet of things or other practical networks.A multi-dimensional network system with... This paper proposes a reliability evaluation model for a multi-dimensional network system,which has potential to be applied to the internet of things or other practical networks.A multi-dimensional network system with one source element and multiple sink elements is considered first.Each element can con-nect with other elements within a stochastic connection ranges.The system is regarded as successful as long as the source ele-ment remains connected with all sink elements.An importance measure is proposed to evaluate the performance of non-source elements.Furthermore,to calculate the system reliability and the element importance measure,a multi-valued decision diagram based approach is structured and its complexity is analyzed.Finally,a numerical example about the signal transfer station system is illustrated to analyze the system reliability and the ele-ment importance measure. 展开更多
关键词 multi-dimensional network multi-valued decision diagram stochastic connection range reliability analysis impor-tance measure.
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Multi-dimensional hydrogen bonds regulated emissions of single-molecule system enabling surficial hydrophobicity/hydrophilicity mapping
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作者 Hao Gu Rui Li +6 位作者 Qiuying Li Sheng Lu Yahui Chen Xiaoning Yang Huili Ma Zhijun Xu Xiaoqiang Chen 《Chinese Chemical Letters》 2025年第5期515-520,共6页
Constructing multi-dimensional hydrogen bond(H-bond)regulated single-molecule systems with multiemission remains a challenge.Herein,we report the design of a new excited-state intramolecular proton transfer(ESIPT)feat... Constructing multi-dimensional hydrogen bond(H-bond)regulated single-molecule systems with multiemission remains a challenge.Herein,we report the design of a new excited-state intramolecular proton transfer(ESIPT)featured chromophore(HBT-DPI)that shows flexible emission tunability via the multidimensional regulation of intra-and intermolecular H-bonds.The feature of switchable intramolecular Hbonds is induced via incorporating several hydrogen bond acceptors and donors into one single HBT-DPI molecule,allowing the“turn on/off”of ESIPT process by forming isomers with distinct intramolecular Hbonds configurations.In response to different external H-bonding environments,the obtained four types of crystal/cocrystals vary in the contents of isomers and the molecular packing modes,which are mainly guided by the intermolecular H-bonds,exhibiting non-emissive features or emissions ranging from green to orange.Utilizing the feature of intermolecular H-bond guided molecular packing,we demonstrate the utility of this fluorescent material for visualizing hydrophobic/hydrophilic areas on large-scale heterogeneous surfaces of modified poly(1,1-difluoroethylene)(PVDF)membranes and quantitatively estimating the surface hydrophobicity,providing a new approach for hydrophobicity/hydrophilicity monitoring and measurement.Overall,this study represents a new design strategy for constructing multi-dimensional hydrogen bond regulated ESIPT-based fluorescent materials that enable multiple emissions and unique applications. 展开更多
关键词 multi-dimensional hydrogen bonds Emission regulation Hydrophobicity/hydrophilicity Surficial mapping Excited-state intramolecular proton transfer
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PLC transition sequence identification based on logical reduction
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作者 Yue Luo Jianhong Ye +2 位作者 Jiazhong Zhou Jia Liu Linping Jiang 《Control Theory and Technology》 2025年第4期672-687,共16页
In industrial control systems,such as power transmission facilities and water treatment plants,Programmable Logic Controllers(PLCs)can work consistently and stably over long periods if there are no faults.Black-box id... In industrial control systems,such as power transmission facilities and water treatment plants,Programmable Logic Controllers(PLCs)can work consistently and stably over long periods if there are no faults.Black-box identification aims to automatically construct Petri net models with the help of I/O signals from PLC devices only.The main challenge is how to convert the infinitely long PLC signals into an event sequence,which is the foundation for subsequent modeling.The current algorithms are confronted with a number of challenges,including an exponential increase in the number of transitions,high time complexity,and susceptibility to noisy signals.To solve these problems,this paper proposes a new method for converting PLC signals into a transition sequence.The method is based on the principles of Boolean absorption law,which filters out noise information in the I/O signals.Then firing functions representing input–output causality are constructed from the filtered signals.Finally,the original signal sequence is traversed to generate a transition sequence.The experimental results show that these methods can rapidly identify a transition sequence.Compared to traditional methods,the proposed algorithms have polynomial time complexity. 展开更多
关键词 PLC Boolean logic Transition sequence Petri net
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Unsupervised hierarchical sequence stratigraphy framework of carbonate successions
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作者 Márcio Vinicius Santana Dantas Kaio Henrique Masse Vieira +9 位作者 Thomás Jung Spier JoséArthur Oliveira Santos Alan Cabral Trindade Prado Danilo Vomlel Mariana Leite Felipe Alves Farias Daniel Galvão Carnier Fragoso Humberto Reis Gabriel Coutinho Douglas G.Macharet 《Artificial Intelligence in Geosciences》 2025年第2期306-319,共14页
Performing the high-resolution stratigraphic analysis may be challenging and time-consuming if one has to work with large datasets.Moreover,sedimentary records have signals of different frequencies and intrinsic noise... Performing the high-resolution stratigraphic analysis may be challenging and time-consuming if one has to work with large datasets.Moreover,sedimentary records have signals of different frequencies and intrinsic noise,resulting in a complex signature that is difficult to identify only through eyes-based analysis.This work proposes identifying transgressive-regressive(T-R)sequences from carbonate facies successions of three South American basins:(i)São Francisco Basin-Brazil,(ii)Santos Basin-Brazil,and(iii)Salta Basin-Argentina.We applied a hidden Markov model in an unsupervised approach followed by a Score-Based Recommender System that automatically finds medium or low-frequency sedimentary cycles from high-frequency ones.Our method is applied to facies identified using Fullbore Formation Microimager(FMI)logs,outcrop description,and composite logs from carbonate intervals.The automatic recommendation results showed better long-distance correlations between medium-to low-frequency sedimentary cycles,whereas the hidden Markov model method successfully identified high-resolution(high-frequency)transgressive and regressive systems tracts from the given facies successions.Our workflow offers advances in the automated analyses and construction of to lower-higher-rank stratigraphic framework and short to long-distance stratigraphic correlation,allowing for scale large-automated processing of the basin dataset.Our approach in this work fits the unsupervised learning framework,as we require no previous input of stratigraphical analysis in the basin.The results provide solutions for prospecting any sediment-hosted mineral resource,especially for the oil and gas industry,offering support for subsurface geological characterization,whether at the exploration scale or for reservoir zoning during production development. 展开更多
关键词 sequence stratigraphy High-frequency cycles Markov chain Unsupervised learning
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Optimization of Linear Sequence-controlled Copolymers for Maximizing Adsorption Capacity
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作者 Sheng-Da Zhao Qiu-Ju Chen +2 位作者 Zhi-Xin Liu Quan-Xiao Dong Xing-Hua Zhang 《Chinese Journal of Polymer Science》 2025年第10期1739-1748,共10页
The optimization of polymer structures aims to determine an optimal sequence or topology that achieves a given target property or structural performance.This inverse design problem involves searching within a vast com... The optimization of polymer structures aims to determine an optimal sequence or topology that achieves a given target property or structural performance.This inverse design problem involves searching within a vast combinatorial phase space defined by components,se-quences,and topologies,and is often computationally intractable due to its NP-hard nature.At the core of this challenge lies the need to evalu-ate complex correlations among structural variables,a classical problem in both statistical physics and combinatorial optimization.To address this,we adopt a mean-field approach that decouples direct variable-variable interactions into effective interactions between each variable and an auxiliary field.The simulated bifurcation(SB)algorithm is employed as a mean-field-based optimization framework.It constructs a Hamiltonian dynamical system by introducing generalized momentum fields,enabling efficient decoupling and dynamic evolution of strongly coupled struc-tural variables.Using the sequence optimization of a linear copolymer adsorbing on a solid surface as a case study,we demonstrate the applica-bility of the SB algorithm to high-dimensional,non-differentiable combinatorial optimization problems.Our results show that SB can efficiently discover polymer sequences with excellent adsorption performance within a reasonable computational time.Furthermore,it exhibits robust con-vergence and high parallel scalability across large design spaces.The approach developed in this work offers a new computational pathway for polymer structure optimization.It also lays a theoretical foundation for future extensions to topological design problems,such as optimizing the number and placement of side chains,as well as the co-optimization of sequence and topology. 展开更多
关键词 Combinatorial optimization Optimal design sequence design COPOLYMER Adsorption problem
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Bayesian-based analysis of sequence activity characteristics in the Bohai Rim region
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作者 Bi Jin-Meng Song Cheng Cao Fu-Yang 《Applied Geophysics》 2025年第2期237-251,554,共16页
Disaster mitigation necessitates scientifi c and accurate aftershock forecasting during the critical 2 h after an earthquake. However, this action faces immense challenges due to the lack of early postearthquake data ... Disaster mitigation necessitates scientifi c and accurate aftershock forecasting during the critical 2 h after an earthquake. However, this action faces immense challenges due to the lack of early postearthquake data and the unreliability of forecasts. To obtain foundational data for sequence parameters of the land-sea adjacent zone and establish a reliable and operational aftershock forecasting framework, we combined the initial sequence parameters extracted from envelope functions and incorporated small-earthquake information into our model to construct a Bayesian algorithm for the early postearthquake stage. We performed parameter fitting and early postearthquake aftershock occurrence rate forecasting and effectiveness evaluation for 36 earthquake sequences with M ≥ 4.0 in the Bohai Rim region since 2010. According to the results, during the early stage after the mainshock, earthquake sequence parameters exhibited relatively drastic fl uctuations with signifi cant errors. The integration of prior information can mitigate the intensity of these changes and reduce errors. The initial and stable sequence parameters generally display advantageous distribution characteristics, with each parameter’s distribution being relatively concentrated and showing good symmetry and remarkable consistency. The sequence parameter p-values were relatively small, which indicates the comparatively slow attenuation of signifi cant earthquake events in the Bohai Rim region. A certain positive correlation was observed between earthquake sequence parameters b and p. However, sequence parameters are unrelated to the mainshock magnitude, which implies that their statistical characteristics and trends are universal. The Bayesian algorithm revealed a good forecasting capability for aftershocks in the early postearthquake period (2 h) in the Bohai Rim region, with an overall forecasting effi cacy rate of 76.39%. The proportion of “too low” failures exceeded that of “too high” failures, and the number of forecasting failures for the next three days was greater than that for the next day. 展开更多
关键词 earthquake sequences Bayesian algorithm model parameters correlation analysis effectiveness evaluation
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