The tight-fractured gas reservoir of the Upper Triassic Xujiahe Formation in the Western Sichuan Depression has low porosity and permeability. This study presents a DNN-based method for identifying gas-bearing strata ...The tight-fractured gas reservoir of the Upper Triassic Xujiahe Formation in the Western Sichuan Depression has low porosity and permeability. This study presents a DNN-based method for identifying gas-bearing strata in tight sandstone. First, multi-component composite seismic attributes are obtained.The strong nonlinear relationships between multi-component composite attributes and gas-bearing reservoirs can be constrained through a DNN. Therefore, we identify and predict the gas-bearing strata using a DNN. Then, sample data are fed into the DNN for training and testing. After optimized network parameters are determined by the performance curves and empirical formulas, the best deep learning gas-bearing prediction model is determined. The composite seismic attributes can then be fed into the model to extrapolate the hydrocarbon-bearing characteristics from known drilling areas to the entire region for predicting the gas reservoir distribution. Finally, we assess the proposed method in terms of the structure and fracture characteristics and predict favorable exploration areas for identifying gas reservoirs.展开更多
Carbenes as one of the most important class of intermediates have been widely utilized in various organic synthetic transformations.Carbene insertion-initiated ring-opening reactions of cyclic ethers offer a valuable ...Carbenes as one of the most important class of intermediates have been widely utilized in various organic synthetic transformations.Carbene insertion-initiated ring-opening reactions of cyclic ethers offer a valuable strategy for constructing new carbon-oxygen bonds.In comparison with traditional thermal or metal-mediated carbene transfer reactions,visible-light-promoted multi-component reaction strategy provides a mild and eco-friendly approach to access densely functionalized molecules.Recently,visible-light-induced multi-component carbene transfer reactions of diazo compounds have been rapidly developed and attracted a great deal of research interest of chemists owing to their advantages of simple operation,mild condition,high atom economy and rich structural diversity.This paper summarizes the recent research progress on the visible-light-promoted multi-component carbene transfer reactions of diazo compounds via ring-opening of cyclic ethers with various nucleophiles.The reaction patterns of different nucleophiles and their corresponding mechanism are described in this review.The future research direction and challenges in this area are also discussed.展开更多
In the realm of nonlinear integrable systems,the presence of decompositions facilitates the establishment of linear superposition solutions and the derivation of novel coupled systems exhibiting nonlinear integrabilit...In the realm of nonlinear integrable systems,the presence of decompositions facilitates the establishment of linear superposition solutions and the derivation of novel coupled systems exhibiting nonlinear integrability.By focusing on single-component decompositions within the potential BKP hierarchy,it has been observed that specific linear superpositions of decomposition solutions remain consistent with the underlying equations.Moreover,through the implementation of multi-component decompositions within the potential BKP hierarchy,successful endeavors have been undertaken to formulate linear superposition solutions and novel coupled Kd V-type systems that resist decoupling via alterations in dependent variables.展开更多
Multi-component transition group metal borides(MMB_(2))have become a research hotspot due to their new composition design concepts and superior properties compared with conventional ceramics.Most of the current method...Multi-component transition group metal borides(MMB_(2))have become a research hotspot due to their new composition design concepts and superior properties compared with conventional ceramics.Most of the current methods,however,are complicated and time-consuming,the mass production remains a chal-lenge.Herein,we proposed a new high-efficiency strategy for synthesis of MMB_(2)using molten aluminum as the medium for the first time.The prepared Al-containing multi-component borides(TiZrHfNbTa)B_(2)microcrystals had a homogeneous composition with a hexagonal AlB_(2)structure and ultra-high hardness value of∼35.3 GPa,which was much higher than data reported in the literature and the rule of mix-ture estimations.Furthermore,combined with the First-principles calculation results,we found that the Poisson’s ratio(v)values exhibit a clearly ascending trend from 0.17 at VEC=3.5 to 0.18 at VEC=3.4,then to 0.201 at VEC=3.2 with the increasing of Al content.This indicates that the intrinsic toughness of multi-component boride microcrystals is obviously enhanced by the trace-doped Al elements.Besides,the fabricated Al-containing multi-component boride microcrystals have superior oxidation activation en-ergy and structural stability.The enhanced oxidation resistance is mainly attributed to the formation of a protective Al2 O3 oxide layer and the lattice distortion,both of which lead to sluggish diffusion of O_(2).These findings propose a new unexplored avenue for the fabrication of MMB_(2)materials with supe-rior comprehensive performance including ultra-hardness and intrinsically improved thermo-mechanical properties.展开更多
The hardening mechanism of multi-component carbide ceramic has been investigated in detail through a combination of experiments,first-principles calculations,and ab initio molecular dynamics(AIMD).Eight dense carbide ...The hardening mechanism of multi-component carbide ceramic has been investigated in detail through a combination of experiments,first-principles calculations,and ab initio molecular dynamics(AIMD).Eight dense carbide ceramics were prepared by spark plasma sintering.Compulsorily,all the multi-component carbide samples have similar carbon content,grain size,and uniform compositional distribution by optimizing the sintering process and adjusting the initial raw materials.Hence the interference of other factors on the hardness of multi-component carbide ceramics is minimized.The effects of changes in the elemental species on the lattice distortion,bond strength,bonding properties,and electronic structure of multi-component carbide ceramics were thoroughly analyzed.These results show that the hardening of multi-component carbide ceramic can be attributed to the coupling of solid solution strengthening caused by lattice distortion and covalent bond strengthening.Besides,the“host lattice”of multi-component carbide ceramics is defined based on the concept of supporting lattice.The present work is of great significance for a deeper understanding of the hardening mechanism of multi-component carbide ceramics and the design of superhard multi-component carbides.展开更多
A convenient photocatalytic multi-component reaction of alkenes,quinoxalin-2(1H)-ones,and diazo compounds has been developed in the presence of water.A number of ester-containing quinoxalin-2(1H)-ones could be efficie...A convenient photocatalytic multi-component reaction of alkenes,quinoxalin-2(1H)-ones,and diazo compounds has been developed in the presence of water.A number of ester-containing quinoxalin-2(1H)-ones could be efficiently obtained in moderate to good yields at room temperature.This metal-free visiblelight-driven tandem reaction was conducted through proton-coupled electron transfer(PCET)process using water as the hydrogen donor and 1,2,3,5-tetrakis(carbazol-9-yl)-4,6-dicyanobenzene(4CzIPN)as the photocatalyst.展开更多
The construction of a borehole correction library for the multi-component array induction tool in deviated boreholes involves extensive 3D forward modeling and typically requires significant computational resources.To...The construction of a borehole correction library for the multi-component array induction tool in deviated boreholes involves extensive 3D forward modeling and typically requires significant computational resources.To address this challenge,this paper proposes an efficient algorithm for the library construction based on the 3D finite volume method(FVM)and contraction high-order Born approximation(CHBA).First,the electromagnetic(EM)field solution region is divided into two symmetric subregions based on the symmetry of the correction library model and the EM field.Numerical solution on a single subregion,combined with the symmetry boundary extension technique,enhances the efficiency of the 3D numerical simulation.Second,three reference mud conductivities are selected based on the mud conductivity range,and the CHBA is applied to calculate the EM responses at all mud conductivity nodes rapidly.Third,the number of forward simulation operations is further reduced by exploiting the principle that models with different frequencies and different formation conductivities have equivalent EM responses.Numerical experiments demonstrate the correctness and feasibility of the proposed algorithm.Compared to conventional 3D modeling,the proposed algorithm achieves approximately a 20-fold speedup in library construction,effectively reducing computational resources and time consumption.展开更多
An analysis of a base-isolated structure for multi-component random ground motion is presented. The mean square respond of the system is Obtained under different parametric variations. The effectiveness of main param...An analysis of a base-isolated structure for multi-component random ground motion is presented. The mean square respond of the system is Obtained under different parametric variations. The effectiveness of main parameters and the torsional component during an earthquake is quantified with the help of the response ratio and the root mean square response with and without base isolation. It is observed that the base isolation has considerable influence on the response and the effect of the torsional component is not ignored.展开更多
This study employed tri-component continuous monitoring data from 10 measurement points on both sides of a base isolation layer in the basement of a large-span high-rise building in Beijing,as well as from a free-fiel...This study employed tri-component continuous monitoring data from 10 measurement points on both sides of a base isolation layer in the basement of a large-span high-rise building in Beijing,as well as from a free-field station and roof frame,during a Mw 5.5 magnitude earthquake in Pingyuan,Shandong,in 2023.The H/V spectral ratio method was used to evaluate the structural dynamic response characteristics of the building and analyze the regulatory effect of the base-isolation layer on seismic waves.The results indicate that during the earthquake,the peak frequency of the free-field and the measurement points below the base-isolation layer was stable at 0.17 Hz,whereas the main frequency of the measurement points above the base-isolation layer increased to 0.75–1.18 Hz,which is 4–6 times greater than that of the points below.The amplitude was suppressed by more than 70%,confirming that the base isolation layer effectively isolated the low-frequency energy from the ground and increased the response frequency of the building.When the building was excited by an earthquake,a three-tier frequency gradient was formed throughout the building:“base-isolation layer(0.17 Hz)-main body(1.18 Hz)-roof frame(3.83 Hz)”,which can effectively avoid resonance of the entire building.In addition,the composite base-isolation device changed the dynamic characteristics of the structure.The resonance period was extended from 0.74 s(theoretical value without base isolation)to 5.9 s(calculated value),and the resonance frequency was reduced from 1.35 to 0.17 Hz.This finding indicates that the base-isolation layer can enhance seismic performance by increasing flexibility and damping.展开更多
To address the neglect of seismic performance in conventional double-girder bridge crane optimization,this paper introduces a time-history analysis-based seismic optimization methodology for crane structures.Using a 2...To address the neglect of seismic performance in conventional double-girder bridge crane optimization,this paper introduces a time-history analysis-based seismic optimization methodology for crane structures.Using a 25-t nuclear power crane as a case study,a bridge frame finite element model is established and validated through static analysis,confirming its accurate representation of the physical entity’s mechanical behavior.Furthermore,with bridge mass reduction as the objective and structural strength,stiffness,stability,and seismic mechanical performance as constraints,an optimization model is developed employing the Whale Optimization Algorithm(WOA).展开更多
Strong seismic excitation and fault dislocation are likely to occur simultaneously in high-intensity seismic zones,causing severe damage to tunnels crossing active fault zones.This paper aims to develop a novel analyt...Strong seismic excitation and fault dislocation are likely to occur simultaneously in high-intensity seismic zones,causing severe damage to tunnels crossing active fault zones.This paper aims to develop a novel analytical solution to determine the longitudinal mechanical responses of tunnels subjected to the combined effects of seismic waves and strike-slip faulting.Adopting the elastic springbeam model,the seismic waves are modelled as shear horizontal(SH)waves and the fault dislocation follows an S-shaped pattern;the superposition principle for free-fielddisplacements caused by both effects is assumed.In addition,the transmission and reflectionof seismic waves at the fault-rock geological interface and the tangential contact conditions at the tunnel-rock interface are considered.The analytical model is validated against numerical simulations,confirmingits accuracy in calculating tunnel responses.Moreover,a parametric study is conducted to evaluate the impact of key factors,including fault displacement,fault zone width,fault dip angle,earthquake frequency,rock conditions,tunnel lining stiffness,and tangential contact conditions,on tunnel responses.Compared with each effect alone,the combined effects of seismic waves and strike-slip faulting significantlychange the tunnel deformation and internal forces,leading to increased tunnel responses,especially within the fault zone and near the fault-rock interfaces.Depending on specificparameters,tunnel responses can be classifiedinto seismic-dominated,faulting-dominated,and seismic-faulting coupled responses on the basis of the relative contributions of each effect.The proposed analytical solution can be applied to quickly predict the longitudinal mechanical behaviour of tunnels under such combined effects in engineering applications.展开更多
The northern segment of the North-South Seismic Belt is characterized by intense crustal deformation,well-developed active tectonics,and frequent occurrences of strong earthquakes.Therefore,conducting a Probabilistic ...The northern segment of the North-South Seismic Belt is characterized by intense crustal deformation,well-developed active tectonics,and frequent occurrences of strong earthquakes.Therefore,conducting a Probabilistic Seismic Hazard Analysis(PSHA)for this region is of significant importance for supporting seismic fortification in major engineering projects and formulating disaster prevention and mitigation policies.In this study,a composite seismic source model was constructed by integrating data on historical earthquakes,active faults,and paleoseismicity.Furthermore,a logic tree framework was employed to quantify epistemic uncertainties,enabling a systematic seismic hazard assessment of the region.To more accurately characterize the spatial heterogeneity of seismic activity,improvements were made to both the Circular Spatial Smoothing Model(CSSM)with a fixed radius and the Adaptive Spatial Smoothing Model(ASSM),with full consideration given to the spatiotemporal completeness of historical earthquake magnitudes.Regarding the CSSM,for scenarios involving small sample sizes in earthquake catalogs,the cross-validation method proposed in this study demonstrated higher robustness than the maximum likelihood method in determining the optimal correlation distance.Performance evaluation results indicate that while both models effectively characterize seismic activity,the ASSM exhibits superior overall predictive performance compared to the CSSM,owing to its ability to adaptively adjust the smoothing radius according to seismic density.Significant discrepancies were observed in the Peak Ground Acceleration(PGA)results calculated with a 10%probability of exceedance in 50 years across different combinations of seismic source models.The single spatially smoothed point-source model yielded a maximum PGA of approximately 0.52 g,with high-value areas concentrated near historical epicenters,thereby significantly underestimating the hazard associated with major fault zones.When combined with the simple fault-source model,the maximum PGA increased to 0.8 g,with high-value zones exhibiting a zonal distribution along faults;however,the risk remained underestimated for faults with low slip rates that are nevertheless approaching their recurrence cycles.Following the introduction of the time-dependent characteristic fault-source model,local PGA values for faults in the middle-to-late stages of their recurrence cycles increased by a factor of 2 to 7 compared to the single model.These results demonstrate that the characteristic fault-source model reasonably delineates the time-dependence of large earthquake recurrence,thereby providing a more accurate assessment of imminent seismic risks.By comprehensively applying the improved spatially smoothed pointsource model,the simple fault-source model,and the characteristic fault-source model,the following faults within the region were identified as having high seismic hazard:the Huangxianggou,Zhangxian,and Tianshui segments of the Xiqinling northern edge fault;the Maqin-Maqu segment of the Dongkunlun fault;the Longriqu fault;the Maoergai fault;the Elashan fault;the Riyueshan fault;the eastern segment of the Lenglongling fault;the Maxianshan segment of the Maxianshan northern Margin fault;and the Maomaoshan-Jinqianghe segment of the Laohushan-Maomaoshan fault.As these faults are located within seismic gaps or are approaching the recurrence periods of large earthquakes,they should be prioritized for current and future seismic monitoring as well as disaster prevention and mitigation efforts.展开更多
Following a magnitude M 7.9 earthquake that struck near Mandalay,Myanmar in March 2025,this study investigates the seismic damage inflicted upon the city’s municipal water supply system.The analysis focuses on the fa...Following a magnitude M 7.9 earthquake that struck near Mandalay,Myanmar in March 2025,this study investigates the seismic damage inflicted upon the city’s municipal water supply system.The analysis focuses on the failure characteristics of water facilities and pipelines,examines cross-system cascading effects,and proposes corresponding recovery strategies.The main findings are as follows:(1)The damage to water plant facilities,concentrated in ancillary structures and connections due to insufficient seismic measures,demonstrated significant intensity-dependence.Increased seismic intensity not only aggravated structural damage but also compromised core treatment processes,leading to deteriorated water quality.(2)Within the same seismic intensity zone,high-density polyethylene(HDPE)pipes exhibited a significantly lower damage occurrence rate than ductile iron(DI)pipes,highlighting the material’s substantial influence on seismic performance.Moreover,a strong positive correlation was observed between the overall pipeline network damage and the seismic intensity.The average damage rate in IntensityⅨzones was 6.84 times that of IntensityⅧzones.(3)A cascading failure,initiated by a power outage,led to water supply disruption,loss of emergency response capability,and elevated secondary risks.This strongly coupled cross-system effect resulted in significant spatiotemporal propagation of disaster impacts.(4)The post-earthquake recovery adopted a phased strategy that prioritized critical facilities.Actions involved rapidly restoring the core supply zone with temporary points,reinstating the water plant’s power supply,and deploying targeted technologies for efficient pipeline repair.The outcomes of this study are expected to provide critical support and a valuable reference for developing earthquake-resilient urban water supply systems.展开更多
The widely distributed loess deposits in the Yellow River Basin exhibit unique engineering geological characteristics.The variations in their thickness and stratigraphic structure significantly amplify ground motion p...The widely distributed loess deposits in the Yellow River Basin exhibit unique engineering geological characteristics.The variations in their thickness and stratigraphic structure significantly amplify ground motion parameters,directly influencing the regional seismic hazard risk level.This study methodically conducted on-site studies and observations of building collapses and damages resulting from seismic amplification effects,using the Wenchuan M_(S)8.0 earthquake as a case study.Comprehensive experimental and numerical simulation studies were carried out.A large-scale shaking table test was performed,and numerical models for 14 different loess sites types were established.Various types of seismic waves were incorporated into these models for systematic numerical simulation calculations.The research reveals the mechanisms by which loess deposit thickness and stratigraphic structure in the Yellow River Basin affect seismic ground motion amplification.The results indicate that as the epicentral distance increases,the peak ground motion shows a marked attenuation trend,with the horizontal component attenuating substantially faster than the vertical component.As the overlying loess layer thickness increases from 50 to 100 m,the seismic intensity may escalate by 3−4 degrees,and the peak acceleration may amplify by 1.5−2.2 times.With the augmentation of loess deposit thickness and the proliferation of soil layers,both the peak acceleration response spectrum and the characteristic period demonstrate an upward tendency,exhibiting slight fluctuations contingent upon the seismic wave type.展开更多
In multi-component seismic exploration, the horizontal and vertical components both contain P- and SV-waves. The P- and SV-wavefields in a seismic record can be separated by their horizontal and vertical displacements...In multi-component seismic exploration, the horizontal and vertical components both contain P- and SV-waves. The P- and SV-wavefields in a seismic record can be separated by their horizontal and vertical displacements when upgoing P- and SV-waves arrive at the sea floor. If the sea floor P wave velocity, S wave velocity, and density are known, the separation can be achieved in ther-p domain. The separated wavefields are then transformed to the time domain. A method of separating P- and SV-wavefields is presented in this paper and used to effectively separate P- and SV-wavefields in synthetic and real data. The application to real data shows that this method is feasible and effective. It also can be used for free surface data.展开更多
To enhance the deformation capacity of vertical support columns of underground structures and improve their overall seismic performance,a new truncated column connected by unbonded prestressed tendons is proposed,insp...To enhance the deformation capacity of vertical support columns of underground structures and improve their overall seismic performance,a new truncated column connected by unbonded prestressed tendons is proposed,inspired by the concepts of the toughness seismic resistance and rocking design.Although many experimental and numerical studies have focused on underground structures,research on the behavior of truncated columns remains limited.This paper develops threedimensional(3D)finite element(FE)models for various columns,including cast-in-place column(CIPC)and prestressed tendon truncated column(PTTC),to evaluate the effects of three parameters,including axial compression ratio(ACR),initial tendon stress,and the effect of hole diameter on mechanical performance—specifically deformation capacity,strength,residual deformation and gap width.The results indicate that the deformability and self-centering ability of the prestressed tendon truncated column is obviously superior to the cast-in-place column,but its strength was comparatively lower.The axial compression ratio has obvious effects on seismic performance,especially deformation and residual deformation,while initial tendon stress and hole diameter influence performance only in the case of a small axial compression ratio.This study systematically identifies the influence of various factors on seismic performance.Additionally,this study proposes a method to evaluate the self-centering capability of structures and establishes an empirical relationship between maximum recoverable deformation and the axial compression ratio.The developed numerical model can serve as a tool for future studies to predict the seismic responses of overall subway stations that feature truncated columns.展开更多
A multi-component system has the long fixed maintenance time, so the opportunistic maintenance policy is adopted to put preventive replacement and corrective replacement together, so that the long fixed maintenance ti...A multi-component system has the long fixed maintenance time, so the opportunistic maintenance policy is adopted to put preventive replacement and corrective replacement together, so that the long fixed maintenance time can be shared by more than one component, and the system availability can be improved. Then, the generation characteristics of the random failure time are researched based on the replacement maintenance and the minima[ maintenance. Furthermore, by choosing the opportunistic replacement ages of each component as opti- mized variables, a simulation algorithm based on an opportunistic maintenance policy is designed to maximize the total availability. Finally, the simulation result shows the validity of the algorithm by an example.展开更多
This review focuses on the recent research progress in the multi-component assembly of luminescent rare earth hybrid materials, which is based on the luminescent rare earth compounds and two or more other building uni...This review focuses on the recent research progress in the multi-component assembly of luminescent rare earth hybrid materials, which is based on the luminescent rare earth compounds and two or more other building units, including the other photoactive species. It covers the multi-component luminescent rare earth hybrids which was assembled with different(a) organic-inorganic polymeric units,(b)nanoporous units,(c) nanoparticle composites or(d) other developing special units. Finally, future challenges and opportunities in this field are discussed. Herein it mainly focuses on the work of Yan's group in recent years.展开更多
A general scheme for generating a multi-component integrable equation hierarchy is proposed. A simple 3M- dimensional loop algebra ~X is produced. By taking advantage of ~X a new isospectral problem is established and...A general scheme for generating a multi-component integrable equation hierarchy is proposed. A simple 3M- dimensional loop algebra ~X is produced. By taking advantage of ~X a new isospectral problem is established and then by making use of the Tu scheme the multi-component Dirac equation hierarchy is obtained. Finally, an expanding loop algebra ~FM of the loop algebra ~X is presented. Based on the ~FM, the multi-component integrable coupling system of the multi-component Dirac equation hierarchy is investigated. The method in this paper can be applied to other nonlinear evolution equation hierarchies.展开更多
Seismic AVO analysis now is one of the major criteria for recognizing potential hydrocarbon reservoirs. Volume scattering information that carries information of stratigraphic structure, lithology, and pore fluid is m...Seismic AVO analysis now is one of the major criteria for recognizing potential hydrocarbon reservoirs. Volume scattering information that carries information of stratigraphic structure, lithology, and pore fluid is more useful for seismic exploration. However, traditional AVO analysis is based on the Zoeppritz equation, which only contains single-interface information. Quantitative interpretation of the thin bed thickness is essential to thin bed structure interpretation, reservoir description, and lateral reservoir prediction. The reflectance spectrum equation based on the elastic wave propagation matrix in the frequency domain derived in this paper shows that both interfaces and intervals have an effect on amplitude. The equation includes information about both single interfaces and volume scattering. Since the reflectance spectrum equation is a continuous function of thin bed thickness and frequency, it is convenient to analyze the effects of a single frequency and bed thickness on the reflectance spectrum. Bed thickness is analyzable until the bed thickness is vanishingly small. These characteristics can＇t be achieved by Fourier transform. The propagation of seismic waves is complex and various wave modes exist simultaneously. The reflectance spectrum includes various propagating wave modes and multiples and is better for simulating multi-component thin bed AVO responses than the ray tracing method.展开更多
基金funded by the Natural Science Foundation of Shandong Province (ZR202103050722)National Natural Science Foundation of China (41174098)。
文摘The tight-fractured gas reservoir of the Upper Triassic Xujiahe Formation in the Western Sichuan Depression has low porosity and permeability. This study presents a DNN-based method for identifying gas-bearing strata in tight sandstone. First, multi-component composite seismic attributes are obtained.The strong nonlinear relationships between multi-component composite attributes and gas-bearing reservoirs can be constrained through a DNN. Therefore, we identify and predict the gas-bearing strata using a DNN. Then, sample data are fed into the DNN for training and testing. After optimized network parameters are determined by the performance curves and empirical formulas, the best deep learning gas-bearing prediction model is determined. The composite seismic attributes can then be fed into the model to extrapolate the hydrocarbon-bearing characteristics from known drilling areas to the entire region for predicting the gas reservoir distribution. Finally, we assess the proposed method in terms of the structure and fracture characteristics and predict favorable exploration areas for identifying gas reservoirs.
基金Science and Technology Foundation of Guizhou Province(No.QKHJC-ZK[2024]654)Guizhou Provincial University Key Laboratory of Advanced Functional Electronic Materials(No.QJ[2023]021).
文摘Carbenes as one of the most important class of intermediates have been widely utilized in various organic synthetic transformations.Carbene insertion-initiated ring-opening reactions of cyclic ethers offer a valuable strategy for constructing new carbon-oxygen bonds.In comparison with traditional thermal or metal-mediated carbene transfer reactions,visible-light-promoted multi-component reaction strategy provides a mild and eco-friendly approach to access densely functionalized molecules.Recently,visible-light-induced multi-component carbene transfer reactions of diazo compounds have been rapidly developed and attracted a great deal of research interest of chemists owing to their advantages of simple operation,mild condition,high atom economy and rich structural diversity.This paper summarizes the recent research progress on the visible-light-promoted multi-component carbene transfer reactions of diazo compounds via ring-opening of cyclic ethers with various nucleophiles.The reaction patterns of different nucleophiles and their corresponding mechanism are described in this review.The future research direction and challenges in this area are also discussed.
基金sponsored by the National Natural Science Foundations of China under Grant Nos.12301315,12235007,11975131the Zhejiang Provincial Natural Science Foundation of China under Grant No.LQ20A010009。
文摘In the realm of nonlinear integrable systems,the presence of decompositions facilitates the establishment of linear superposition solutions and the derivation of novel coupled systems exhibiting nonlinear integrability.By focusing on single-component decompositions within the potential BKP hierarchy,it has been observed that specific linear superpositions of decomposition solutions remain consistent with the underlying equations.Moreover,through the implementation of multi-component decompositions within the potential BKP hierarchy,successful endeavors have been undertaken to formulate linear superposition solutions and novel coupled Kd V-type systems that resist decoupling via alterations in dependent variables.
基金financially supported by the National Natural Science Foundation of China(Nos.52271033 and 52071179)the Key program of National Natural Science Foundation of China(No.51931003)+2 种基金Natural Science Foundation of Jiangsu Province,China(No.BK20221493)Jiangsu Province Leading Edge Technology Basic Research Major Project(No.BK20222014)Foundation of“Qinglan Project”for Colleges and Universities in Jiangsu Province.
文摘Multi-component transition group metal borides(MMB_(2))have become a research hotspot due to their new composition design concepts and superior properties compared with conventional ceramics.Most of the current methods,however,are complicated and time-consuming,the mass production remains a chal-lenge.Herein,we proposed a new high-efficiency strategy for synthesis of MMB_(2)using molten aluminum as the medium for the first time.The prepared Al-containing multi-component borides(TiZrHfNbTa)B_(2)microcrystals had a homogeneous composition with a hexagonal AlB_(2)structure and ultra-high hardness value of∼35.3 GPa,which was much higher than data reported in the literature and the rule of mix-ture estimations.Furthermore,combined with the First-principles calculation results,we found that the Poisson’s ratio(v)values exhibit a clearly ascending trend from 0.17 at VEC=3.5 to 0.18 at VEC=3.4,then to 0.201 at VEC=3.2 with the increasing of Al content.This indicates that the intrinsic toughness of multi-component boride microcrystals is obviously enhanced by the trace-doped Al elements.Besides,the fabricated Al-containing multi-component boride microcrystals have superior oxidation activation en-ergy and structural stability.The enhanced oxidation resistance is mainly attributed to the formation of a protective Al2 O3 oxide layer and the lattice distortion,both of which lead to sluggish diffusion of O_(2).These findings propose a new unexplored avenue for the fabrication of MMB_(2)materials with supe-rior comprehensive performance including ultra-hardness and intrinsically improved thermo-mechanical properties.
基金financially supported by the National Natural Science Foundation of China(Nos.52032002,52372060,51972081,and U22A20128)the National Safety Academic Foundation(No.U2130103)+1 种基金the National Key Laboratory of Precision Hot Processing of Metals(No.61429092300305)Heilongjiang Touyan Team Program are gratefully acknowledged.
文摘The hardening mechanism of multi-component carbide ceramic has been investigated in detail through a combination of experiments,first-principles calculations,and ab initio molecular dynamics(AIMD).Eight dense carbide ceramics were prepared by spark plasma sintering.Compulsorily,all the multi-component carbide samples have similar carbon content,grain size,and uniform compositional distribution by optimizing the sintering process and adjusting the initial raw materials.Hence the interference of other factors on the hardness of multi-component carbide ceramics is minimized.The effects of changes in the elemental species on the lattice distortion,bond strength,bonding properties,and electronic structure of multi-component carbide ceramics were thoroughly analyzed.These results show that the hardening of multi-component carbide ceramic can be attributed to the coupling of solid solution strengthening caused by lattice distortion and covalent bond strengthening.Besides,the“host lattice”of multi-component carbide ceramics is defined based on the concept of supporting lattice.The present work is of great significance for a deeper understanding of the hardening mechanism of multi-component carbide ceramics and the design of superhard multi-component carbides.
基金supported by Sichuan Science and Technology Program(No.2023NSFSC0101)the 2024 Provincial platform project of Chengdu Normal University(No.GNFZ202404)+1 种基金Natural Science Foundation of Shandong Province(No.ZR2021MB065)National Natural Science Foundation of China(No.22101237)。
文摘A convenient photocatalytic multi-component reaction of alkenes,quinoxalin-2(1H)-ones,and diazo compounds has been developed in the presence of water.A number of ester-containing quinoxalin-2(1H)-ones could be efficiently obtained in moderate to good yields at room temperature.This metal-free visiblelight-driven tandem reaction was conducted through proton-coupled electron transfer(PCET)process using water as the hydrogen donor and 1,2,3,5-tetrakis(carbazol-9-yl)-4,6-dicyanobenzene(4CzIPN)as the photocatalyst.
基金funded by the Forward-looking Basic Science and Technology Research Project of PetroChina Company Limited(2025DJ104)the National Natural Science Foundation of China(42174150)the National Science and Technology Major Project for Deep Earth Probe and Mineral Resources Exploration(2024ZD1003005).
文摘The construction of a borehole correction library for the multi-component array induction tool in deviated boreholes involves extensive 3D forward modeling and typically requires significant computational resources.To address this challenge,this paper proposes an efficient algorithm for the library construction based on the 3D finite volume method(FVM)and contraction high-order Born approximation(CHBA).First,the electromagnetic(EM)field solution region is divided into two symmetric subregions based on the symmetry of the correction library model and the EM field.Numerical solution on a single subregion,combined with the symmetry boundary extension technique,enhances the efficiency of the 3D numerical simulation.Second,three reference mud conductivities are selected based on the mud conductivity range,and the CHBA is applied to calculate the EM responses at all mud conductivity nodes rapidly.Third,the number of forward simulation operations is further reduced by exploiting the principle that models with different frequencies and different formation conductivities have equivalent EM responses.Numerical experiments demonstrate the correctness and feasibility of the proposed algorithm.Compared to conventional 3D modeling,the proposed algorithm achieves approximately a 20-fold speedup in library construction,effectively reducing computational resources and time consumption.
文摘An analysis of a base-isolated structure for multi-component random ground motion is presented. The mean square respond of the system is Obtained under different parametric variations. The effectiveness of main parameters and the torsional component during an earthquake is quantified with the help of the response ratio and the root mean square response with and without base isolation. It is observed that the base isolation has considerable influence on the response and the effect of the torsional component is not ignored.
基金supported by the Deep Earth Probe and Mineral Resources Exploration-National Science and Technology Major Project(Grant No.2025ZD005100)by Beijing Geolight Technology Co.,Ltd.under the project“The Impact of Strong Ground Motion on Buildings”(YF-202520).
文摘This study employed tri-component continuous monitoring data from 10 measurement points on both sides of a base isolation layer in the basement of a large-span high-rise building in Beijing,as well as from a free-field station and roof frame,during a Mw 5.5 magnitude earthquake in Pingyuan,Shandong,in 2023.The H/V spectral ratio method was used to evaluate the structural dynamic response characteristics of the building and analyze the regulatory effect of the base-isolation layer on seismic waves.The results indicate that during the earthquake,the peak frequency of the free-field and the measurement points below the base-isolation layer was stable at 0.17 Hz,whereas the main frequency of the measurement points above the base-isolation layer increased to 0.75–1.18 Hz,which is 4–6 times greater than that of the points below.The amplitude was suppressed by more than 70%,confirming that the base isolation layer effectively isolated the low-frequency energy from the ground and increased the response frequency of the building.When the building was excited by an earthquake,a three-tier frequency gradient was formed throughout the building:“base-isolation layer(0.17 Hz)-main body(1.18 Hz)-roof frame(3.83 Hz)”,which can effectively avoid resonance of the entire building.In addition,the composite base-isolation device changed the dynamic characteristics of the structure.The resonance period was extended from 0.74 s(theoretical value without base isolation)to 5.9 s(calculated value),and the resonance frequency was reduced from 1.35 to 0.17 Hz.This finding indicates that the base-isolation layer can enhance seismic performance by increasing flexibility and damping.
文摘To address the neglect of seismic performance in conventional double-girder bridge crane optimization,this paper introduces a time-history analysis-based seismic optimization methodology for crane structures.Using a 25-t nuclear power crane as a case study,a bridge frame finite element model is established and validated through static analysis,confirming its accurate representation of the physical entity’s mechanical behavior.Furthermore,with bridge mass reduction as the objective and structural strength,stiffness,stability,and seismic mechanical performance as constraints,an optimization model is developed employing the Whale Optimization Algorithm(WOA).
基金supported by the National Natural Science Foundation of China(No.41941018)Shanghai Gaofeng Discipline Construction Funding.
文摘Strong seismic excitation and fault dislocation are likely to occur simultaneously in high-intensity seismic zones,causing severe damage to tunnels crossing active fault zones.This paper aims to develop a novel analytical solution to determine the longitudinal mechanical responses of tunnels subjected to the combined effects of seismic waves and strike-slip faulting.Adopting the elastic springbeam model,the seismic waves are modelled as shear horizontal(SH)waves and the fault dislocation follows an S-shaped pattern;the superposition principle for free-fielddisplacements caused by both effects is assumed.In addition,the transmission and reflectionof seismic waves at the fault-rock geological interface and the tangential contact conditions at the tunnel-rock interface are considered.The analytical model is validated against numerical simulations,confirmingits accuracy in calculating tunnel responses.Moreover,a parametric study is conducted to evaluate the impact of key factors,including fault displacement,fault zone width,fault dip angle,earthquake frequency,rock conditions,tunnel lining stiffness,and tangential contact conditions,on tunnel responses.Compared with each effect alone,the combined effects of seismic waves and strike-slip faulting significantlychange the tunnel deformation and internal forces,leading to increased tunnel responses,especially within the fault zone and near the fault-rock interfaces.Depending on specificparameters,tunnel responses can be classifiedinto seismic-dominated,faulting-dominated,and seismic-faulting coupled responses on the basis of the relative contributions of each effect.The proposed analytical solution can be applied to quickly predict the longitudinal mechanical behaviour of tunnels under such combined effects in engineering applications.
基金supported by the National Key R&D Program of China(No.2022YFC3003502).
文摘The northern segment of the North-South Seismic Belt is characterized by intense crustal deformation,well-developed active tectonics,and frequent occurrences of strong earthquakes.Therefore,conducting a Probabilistic Seismic Hazard Analysis(PSHA)for this region is of significant importance for supporting seismic fortification in major engineering projects and formulating disaster prevention and mitigation policies.In this study,a composite seismic source model was constructed by integrating data on historical earthquakes,active faults,and paleoseismicity.Furthermore,a logic tree framework was employed to quantify epistemic uncertainties,enabling a systematic seismic hazard assessment of the region.To more accurately characterize the spatial heterogeneity of seismic activity,improvements were made to both the Circular Spatial Smoothing Model(CSSM)with a fixed radius and the Adaptive Spatial Smoothing Model(ASSM),with full consideration given to the spatiotemporal completeness of historical earthquake magnitudes.Regarding the CSSM,for scenarios involving small sample sizes in earthquake catalogs,the cross-validation method proposed in this study demonstrated higher robustness than the maximum likelihood method in determining the optimal correlation distance.Performance evaluation results indicate that while both models effectively characterize seismic activity,the ASSM exhibits superior overall predictive performance compared to the CSSM,owing to its ability to adaptively adjust the smoothing radius according to seismic density.Significant discrepancies were observed in the Peak Ground Acceleration(PGA)results calculated with a 10%probability of exceedance in 50 years across different combinations of seismic source models.The single spatially smoothed point-source model yielded a maximum PGA of approximately 0.52 g,with high-value areas concentrated near historical epicenters,thereby significantly underestimating the hazard associated with major fault zones.When combined with the simple fault-source model,the maximum PGA increased to 0.8 g,with high-value zones exhibiting a zonal distribution along faults;however,the risk remained underestimated for faults with low slip rates that are nevertheless approaching their recurrence cycles.Following the introduction of the time-dependent characteristic fault-source model,local PGA values for faults in the middle-to-late stages of their recurrence cycles increased by a factor of 2 to 7 compared to the single model.These results demonstrate that the characteristic fault-source model reasonably delineates the time-dependence of large earthquake recurrence,thereby providing a more accurate assessment of imminent seismic risks.By comprehensively applying the improved spatially smoothed pointsource model,the simple fault-source model,and the characteristic fault-source model,the following faults within the region were identified as having high seismic hazard:the Huangxianggou,Zhangxian,and Tianshui segments of the Xiqinling northern edge fault;the Maqin-Maqu segment of the Dongkunlun fault;the Longriqu fault;the Maoergai fault;the Elashan fault;the Riyueshan fault;the eastern segment of the Lenglongling fault;the Maxianshan segment of the Maxianshan northern Margin fault;and the Maomaoshan-Jinqianghe segment of the Laohushan-Maomaoshan fault.As these faults are located within seismic gaps or are approaching the recurrence periods of large earthquakes,they should be prioritized for current and future seismic monitoring as well as disaster prevention and mitigation efforts.
基金National Key Research and Development Program of China under Grant No.2023YFC3805201Scientific Research Fund of Institute of Engineering Mechanics,China Earthquake Administration under Grant Nos.2024B29 and 2024B25。
文摘Following a magnitude M 7.9 earthquake that struck near Mandalay,Myanmar in March 2025,this study investigates the seismic damage inflicted upon the city’s municipal water supply system.The analysis focuses on the failure characteristics of water facilities and pipelines,examines cross-system cascading effects,and proposes corresponding recovery strategies.The main findings are as follows:(1)The damage to water plant facilities,concentrated in ancillary structures and connections due to insufficient seismic measures,demonstrated significant intensity-dependence.Increased seismic intensity not only aggravated structural damage but also compromised core treatment processes,leading to deteriorated water quality.(2)Within the same seismic intensity zone,high-density polyethylene(HDPE)pipes exhibited a significantly lower damage occurrence rate than ductile iron(DI)pipes,highlighting the material’s substantial influence on seismic performance.Moreover,a strong positive correlation was observed between the overall pipeline network damage and the seismic intensity.The average damage rate in IntensityⅨzones was 6.84 times that of IntensityⅧzones.(3)A cascading failure,initiated by a power outage,led to water supply disruption,loss of emergency response capability,and elevated secondary risks.This strongly coupled cross-system effect resulted in significant spatiotemporal propagation of disaster impacts.(4)The post-earthquake recovery adopted a phased strategy that prioritized critical facilities.Actions involved rapidly restoring the core supply zone with temporary points,reinstating the water plant’s power supply,and deploying targeted technologies for efficient pipeline repair.The outcomes of this study are expected to provide critical support and a valuable reference for developing earthquake-resilient urban water supply systems.
基金supported by the Earthquake Science and Technology Spark Plan Project(No.XH23041C)The Natural Science Foundation of Gansu Province(No.22JR11RA090)Gansu Lanzhou Geophysics National Observation and Research Station(No.2021Y14).
文摘The widely distributed loess deposits in the Yellow River Basin exhibit unique engineering geological characteristics.The variations in their thickness and stratigraphic structure significantly amplify ground motion parameters,directly influencing the regional seismic hazard risk level.This study methodically conducted on-site studies and observations of building collapses and damages resulting from seismic amplification effects,using the Wenchuan M_(S)8.0 earthquake as a case study.Comprehensive experimental and numerical simulation studies were carried out.A large-scale shaking table test was performed,and numerical models for 14 different loess sites types were established.Various types of seismic waves were incorporated into these models for systematic numerical simulation calculations.The research reveals the mechanisms by which loess deposit thickness and stratigraphic structure in the Yellow River Basin affect seismic ground motion amplification.The results indicate that as the epicentral distance increases,the peak ground motion shows a marked attenuation trend,with the horizontal component attenuating substantially faster than the vertical component.As the overlying loess layer thickness increases from 50 to 100 m,the seismic intensity may escalate by 3−4 degrees,and the peak acceleration may amplify by 1.5−2.2 times.With the augmentation of loess deposit thickness and the proliferation of soil layers,both the peak acceleration response spectrum and the characteristic period demonstrate an upward tendency,exhibiting slight fluctuations contingent upon the seismic wave type.
基金This research is sponsored by National Natural Science Foundation of China （No. 40272041） and Innovative Foundation of CNPC （N0. 04E702）.
文摘In multi-component seismic exploration, the horizontal and vertical components both contain P- and SV-waves. The P- and SV-wavefields in a seismic record can be separated by their horizontal and vertical displacements when upgoing P- and SV-waves arrive at the sea floor. If the sea floor P wave velocity, S wave velocity, and density are known, the separation can be achieved in ther-p domain. The separated wavefields are then transformed to the time domain. A method of separating P- and SV-wavefields is presented in this paper and used to effectively separate P- and SV-wavefields in synthetic and real data. The application to real data shows that this method is feasible and effective. It also can be used for free surface data.
基金National Natural Science Foundation of China under Grant Nos.52478488 and 51908013the National Key Basic Research and Development Program of China under Grant No.2018YFC1504305。
文摘To enhance the deformation capacity of vertical support columns of underground structures and improve their overall seismic performance,a new truncated column connected by unbonded prestressed tendons is proposed,inspired by the concepts of the toughness seismic resistance and rocking design.Although many experimental and numerical studies have focused on underground structures,research on the behavior of truncated columns remains limited.This paper develops threedimensional(3D)finite element(FE)models for various columns,including cast-in-place column(CIPC)and prestressed tendon truncated column(PTTC),to evaluate the effects of three parameters,including axial compression ratio(ACR),initial tendon stress,and the effect of hole diameter on mechanical performance—specifically deformation capacity,strength,residual deformation and gap width.The results indicate that the deformability and self-centering ability of the prestressed tendon truncated column is obviously superior to the cast-in-place column,but its strength was comparatively lower.The axial compression ratio has obvious effects on seismic performance,especially deformation and residual deformation,while initial tendon stress and hole diameter influence performance only in the case of a small axial compression ratio.This study systematically identifies the influence of various factors on seismic performance.Additionally,this study proposes a method to evaluate the self-centering capability of structures and establishes an empirical relationship between maximum recoverable deformation and the axial compression ratio.The developed numerical model can serve as a tool for future studies to predict the seismic responses of overall subway stations that feature truncated columns.
文摘A multi-component system has the long fixed maintenance time, so the opportunistic maintenance policy is adopted to put preventive replacement and corrective replacement together, so that the long fixed maintenance time can be shared by more than one component, and the system availability can be improved. Then, the generation characteristics of the random failure time are researched based on the replacement maintenance and the minima[ maintenance. Furthermore, by choosing the opportunistic replacement ages of each component as opti- mized variables, a simulation algorithm based on an opportunistic maintenance policy is designed to maximize the total availability. Finally, the simulation result shows the validity of the algorithm by an example.
基金Project supported by the National Natural Science Foundation of China(21571142)the Developing Science Fund of Tongji University,the Natural Science Foundation of Zhejiang Province(LQ14B010001)the Natural Science Foundation of Ningbo,China(2016A610105)
文摘This review focuses on the recent research progress in the multi-component assembly of luminescent rare earth hybrid materials, which is based on the luminescent rare earth compounds and two or more other building units, including the other photoactive species. It covers the multi-component luminescent rare earth hybrids which was assembled with different(a) organic-inorganic polymeric units,(b)nanoporous units,(c) nanoparticle composites or(d) other developing special units. Finally, future challenges and opportunities in this field are discussed. Herein it mainly focuses on the work of Yan's group in recent years.
文摘A general scheme for generating a multi-component integrable equation hierarchy is proposed. A simple 3M- dimensional loop algebra ~X is produced. By taking advantage of ~X a new isospectral problem is established and then by making use of the Tu scheme the multi-component Dirac equation hierarchy is obtained. Finally, an expanding loop algebra ~FM of the loop algebra ~X is presented. Based on the ~FM, the multi-component integrable coupling system of the multi-component Dirac equation hierarchy is investigated. The method in this paper can be applied to other nonlinear evolution equation hierarchies.
基金The research was supported by the Notion's Fifteenth Scientific and Technological Breakthrough Project: Research of Vector and Mountain Seismic Exploration (No.2001BA605A-12).
文摘Seismic AVO analysis now is one of the major criteria for recognizing potential hydrocarbon reservoirs. Volume scattering information that carries information of stratigraphic structure, lithology, and pore fluid is more useful for seismic exploration. However, traditional AVO analysis is based on the Zoeppritz equation, which only contains single-interface information. Quantitative interpretation of the thin bed thickness is essential to thin bed structure interpretation, reservoir description, and lateral reservoir prediction. The reflectance spectrum equation based on the elastic wave propagation matrix in the frequency domain derived in this paper shows that both interfaces and intervals have an effect on amplitude. The equation includes information about both single interfaces and volume scattering. Since the reflectance spectrum equation is a continuous function of thin bed thickness and frequency, it is convenient to analyze the effects of a single frequency and bed thickness on the reflectance spectrum. Bed thickness is analyzable until the bed thickness is vanishingly small. These characteristics can＇t be achieved by Fourier transform. The propagation of seismic waves is complex and various wave modes exist simultaneously. The reflectance spectrum includes various propagating wave modes and multiples and is better for simulating multi-component thin bed AVO responses than the ray tracing method.
