An essential technology of carbon capture, utilization and storage-enhanced oil recovery (CCUS-EOR) for tight oil reservoirs is CO_(2) huff-puff followed by associated produced gas reinjection. In this paper, the effe...An essential technology of carbon capture, utilization and storage-enhanced oil recovery (CCUS-EOR) for tight oil reservoirs is CO_(2) huff-puff followed by associated produced gas reinjection. In this paper, the effects of multi-component gas on the properties and components of tight oil are studied. First, the core displacement experiments using the CH_(4)/CO_(2) multi-component gas are conducted to determine the oil displacement efficiency under different CO_(2) and CH_(4) ratios. Then, a viscometer and a liquid density balance are used to investigate the change characteristics of oil viscosity and density after multi-component gas displacement with different CO_(2) and CH_(4) ratios. In addition, a laboratory scale numerical model is established to validate the experimental results. Finally, a composition model of multi-stage fractured horizontal well in tight oil reservoir considering nano-confinement effects is established to investigate the effects of multi-component gas on the components of produced dead oil and formation crude oil. The experimental results show that the oil displacement efficiency of multi-component gas displacement is greater than that of single-component gas displacement. The CH_(4) decreases the viscosity and density of light oil, while CO_(2) decreases the viscosity but increases the density. And the numerical simulation results show that CO_(2) extracts more heavy components from the liquid phase into the vapor phase, while CH_(4) extracts more light components from the liquid phase into the vapor phase during cyclic gas injection. The multi-component gas can extract both the light components and the heavy components from oil, and the balanced production of each component can be achieved by using multi-component gas huff-puff.展开更多
Carbenes as one of the most important class of intermediates have been widely utilized in various organic synthetic transformations.Carbene insertion-initiated ring-opening reactions of cyclic ethers offer a valuable ...Carbenes as one of the most important class of intermediates have been widely utilized in various organic synthetic transformations.Carbene insertion-initiated ring-opening reactions of cyclic ethers offer a valuable strategy for constructing new carbon-oxygen bonds.In comparison with traditional thermal or metal-mediated carbene transfer reactions,visible-light-promoted multi-component reaction strategy provides a mild and eco-friendly approach to access densely functionalized molecules.Recently,visible-light-induced multi-component carbene transfer reactions of diazo compounds have been rapidly developed and attracted a great deal of research interest of chemists owing to their advantages of simple operation,mild condition,high atom economy and rich structural diversity.This paper summarizes the recent research progress on the visible-light-promoted multi-component carbene transfer reactions of diazo compounds via ring-opening of cyclic ethers with various nucleophiles.The reaction patterns of different nucleophiles and their corresponding mechanism are described in this review.The future research direction and challenges in this area are also discussed.展开更多
The introduction of surface engineering is expected to be an effective strategy against fretting damage.A large number of studies show that the low gas multi-component(such as carbon,nitrogen,sulphur and oxygen,etc)th...The introduction of surface engineering is expected to be an effective strategy against fretting damage.A large number of studies show that the low gas multi-component(such as carbon,nitrogen,sulphur and oxygen,etc)thermo-chemical treatment(LTGMTT)can overcome the brittleness of nitriding process,and upgrade the surface hardness and improve the wear resistance and fatigue properties of the work-pieces significantly.However,there are few reports on the anti-fretting properties of the LTGMTT modified layer up to now,which limits the applications of fretting.So this paper discusses the fretting wear behavior of modified layer on the surface of LZ50(0.48%C)steel prepared by low temperature gas multi-component thermo-chemical treatment(LTGMTT)technology.The fretting wear tests of the modified layer flat specimens and its substrate(LZ50 steel)against 52100 steel balls with diameter of 40 mm are carried out under normal load of 150 N and displacement amplitudes varied from 2μm to 40μm.Characterization of the modified layer and dynamic analyses in combination with microscopic examinations were performed through the means of scanning electron microscope(SEM),optical microscope(OM),X-ray diffraction(XRD)and surface profilometer.The experimental results showed that the modified layer with a total thickness of 60μm was consisted of three parts,i.e.,loose layer,compound layer and diffusion layer.Compared with the substrate,the range of the mixed fretting regime(MFR)of the LTGMTT modified layer diminished,and the slip regime(SR)of the modified layer shifted to the direction of smaller displacement amplitude.The coefficient of friction(COF)of the modified layer was lower than that of the substrate in the initial stage.For the modified layer,the damage in partial slip regime(PSR)was very slight.The fretting wear mechanism of the modified layer both in MFR and SR was abrasive wear and delamination.The modified layer presented better wear resistance than the substrate in PSR and MFR;however,in SR,the wear resistance of the modified layer decreased with the increase of the displacement amplitudes.The experimental results can provide some experimental bases for promoting industrial application of LTGMTT modified layer in anti-fretting wear.展开更多
The tight-fractured gas reservoir of the Upper Triassic Xujiahe Formation in the Western Sichuan Depression has low porosity and permeability. This study presents a DNN-based method for identifying gas-bearing strata ...The tight-fractured gas reservoir of the Upper Triassic Xujiahe Formation in the Western Sichuan Depression has low porosity and permeability. This study presents a DNN-based method for identifying gas-bearing strata in tight sandstone. First, multi-component composite seismic attributes are obtained.The strong nonlinear relationships between multi-component composite attributes and gas-bearing reservoirs can be constrained through a DNN. Therefore, we identify and predict the gas-bearing strata using a DNN. Then, sample data are fed into the DNN for training and testing. After optimized network parameters are determined by the performance curves and empirical formulas, the best deep learning gas-bearing prediction model is determined. The composite seismic attributes can then be fed into the model to extrapolate the hydrocarbon-bearing characteristics from known drilling areas to the entire region for predicting the gas reservoir distribution. Finally, we assess the proposed method in terms of the structure and fracture characteristics and predict favorable exploration areas for identifying gas reservoirs.展开更多
The segregation modes and characteristics of 1-6 mm multi-component lignite were studied in a microporous, vibrated, gas-fluidized bed of Φ110 mm ×400 mm. The effects of particle density and size, vibration freq...The segregation modes and characteristics of 1-6 mm multi-component lignite were studied in a microporous, vibrated, gas-fluidized bed of Φ110 mm ×400 mm. The effects of particle density and size, vibration frequency and amplitude, and gas velocity on these characteristics were considered. The average size, average density, size deviation coefficient, and density deviation coefficient were used to identify lignite size and density. The separation efficiency was adopted to evaluate the segregation performance,and the segregation mechanisms were explored. The results show that ε(size,max) of heterogeneous multisize-component lignite with K_(size) = 65% reaches 80% at f= 20 Hz, A = 5 mm, and N =(1,3). ε_(density,max) Of heterogeneous multi-density-component lignite with K_(density)= 25% reaches 50% at f = 15 Hz, A = 5 mm,and N =(1,1.5). The density segregations of 1-3 and 3-6 mm multi-component mixtures are remarkable,ε_(density,max)= 42% and 31% at f= 14 and 16 Hz, and A = 3 and 5 mm, respectively. The size segregation of 1-6 mm multi-component mixture is prominent and ε_(size,max)= 55% at f= 15 Hz, A = 5 mm. The mediumsized mixture with a narrow size distribution at low frequency is favorable for density segregation,and a mixture with a wider size distribution at high frequency is most favorable for size segregation.Precise control of gas flow and vibration as well as optimal design of the fluidized bed can improve the performance of segregation in the vibrated gas-fluidized bed.展开更多
Studied on multi-component combustible gas,methane mainly,explosion char- acteristics of high gas mine,obtained the rules of gas explosive limit that influenced by environment temperature,pressure,concentration of oxy...Studied on multi-component combustible gas,methane mainly,explosion char- acteristics of high gas mine,obtained the rules of gas explosive limit that influenced by environment temperature,pressure,concentration of oxygen,other combustible gas,coal dust,energy of fire source,and the inert gas,proposed a new method of divide gas explo- sive triangle partition,and gave new partition linear equations.The gas explosive triangle and its new partition has important directive significance in distinguishing if the fire area has a gas explosion when sealing or opening fire area,or fire extinguishing in sealed fire area,and judging if there will be a gas explosion or other trend while fire extinguishing with inert gas.展开更多
An optical multi-component gas detection system based on the conjugated interferometer （CI） is proposed and experimentally demonstrated. It can realize the concentration detection of mixture gas in the environment. ...An optical multi-component gas detection system based on the conjugated interferometer （CI） is proposed and experimentally demonstrated. It can realize the concentration detection of mixture gas in the environment. The CI can transform the absorption spectrum of the target gases to a conjugated emission spectrum, when combining the CI with the broadband light source, the spectrum of output light matches well with the absorption spectrum of target gases. The CI design for different target gases can be achieved by replacing the kind of target absorbing gas in the CI filter. The traditional fiber gas sensor system requires multiple light sources for detection when there are several kinds of gases, and this problem has been solved by using the CI filter combined with the broadband light source. The experimental results show that the system can detect the concentration of multi-component gases, which are mixed with C2H2 and NH3. Experimental results also show a good concentration sensing linearity.展开更多
Multi-component seismic exploration is an important technique in the utilization of P-waves and converted S-waves for oil and gas exploration.It has unique advantages in the structural imaging of gas zones,reservoir p...Multi-component seismic exploration is an important technique in the utilization of P-waves and converted S-waves for oil and gas exploration.It has unique advantages in the structural imaging of gas zones,reservoir prediction,lithology,and gas-water identifi cation,and the development direction and degree of fractures.Multi-component joint inversion is one of the most important steps in multi-component exploration.In this paper,starting from the basic principle of multi-component joint inversion,the diff erences between the method and single P-wave inversion are introduced.Next,the technique is applied to the PLN area of the Sichuan Basin,and the P-wave impedance,S-wave impedance,and density are obtained based on multi-component joint inversion.Through the velocity and lithology,porosity,and gas saturation fi tting formulas,prediction results are calculated,and the results are analyzed.Finally,multi-component joint inversion and single P-wave inversion are compared in eff ective reservoir prediction.The results show that multi-component joint inversion increases the constraints on the inversion conditions,reduces the multi-solution of a single P-wave inversion,and is more objective and reliable for the identification of reservoirs,effectively improving the accuracy of oil and gas reservoir prediction and development.展开更多
In the realm of nonlinear integrable systems,the presence of decompositions facilitates the establishment of linear superposition solutions and the derivation of novel coupled systems exhibiting nonlinear integrabilit...In the realm of nonlinear integrable systems,the presence of decompositions facilitates the establishment of linear superposition solutions and the derivation of novel coupled systems exhibiting nonlinear integrability.By focusing on single-component decompositions within the potential BKP hierarchy,it has been observed that specific linear superpositions of decomposition solutions remain consistent with the underlying equations.Moreover,through the implementation of multi-component decompositions within the potential BKP hierarchy,successful endeavors have been undertaken to formulate linear superposition solutions and novel coupled Kd V-type systems that resist decoupling via alterations in dependent variables.展开更多
Multi-component transition group metal borides(MMB_(2))have become a research hotspot due to their new composition design concepts and superior properties compared with conventional ceramics.Most of the current method...Multi-component transition group metal borides(MMB_(2))have become a research hotspot due to their new composition design concepts and superior properties compared with conventional ceramics.Most of the current methods,however,are complicated and time-consuming,the mass production remains a chal-lenge.Herein,we proposed a new high-efficiency strategy for synthesis of MMB_(2)using molten aluminum as the medium for the first time.The prepared Al-containing multi-component borides(TiZrHfNbTa)B_(2)microcrystals had a homogeneous composition with a hexagonal AlB_(2)structure and ultra-high hardness value of∼35.3 GPa,which was much higher than data reported in the literature and the rule of mix-ture estimations.Furthermore,combined with the First-principles calculation results,we found that the Poisson’s ratio(v)values exhibit a clearly ascending trend from 0.17 at VEC=3.5 to 0.18 at VEC=3.4,then to 0.201 at VEC=3.2 with the increasing of Al content.This indicates that the intrinsic toughness of multi-component boride microcrystals is obviously enhanced by the trace-doped Al elements.Besides,the fabricated Al-containing multi-component boride microcrystals have superior oxidation activation en-ergy and structural stability.The enhanced oxidation resistance is mainly attributed to the formation of a protective Al2 O3 oxide layer and the lattice distortion,both of which lead to sluggish diffusion of O_(2).These findings propose a new unexplored avenue for the fabrication of MMB_(2)materials with supe-rior comprehensive performance including ultra-hardness and intrinsically improved thermo-mechanical properties.展开更多
The hardening mechanism of multi-component carbide ceramic has been investigated in detail through a combination of experiments,first-principles calculations,and ab initio molecular dynamics(AIMD).Eight dense carbide ...The hardening mechanism of multi-component carbide ceramic has been investigated in detail through a combination of experiments,first-principles calculations,and ab initio molecular dynamics(AIMD).Eight dense carbide ceramics were prepared by spark plasma sintering.Compulsorily,all the multi-component carbide samples have similar carbon content,grain size,and uniform compositional distribution by optimizing the sintering process and adjusting the initial raw materials.Hence the interference of other factors on the hardness of multi-component carbide ceramics is minimized.The effects of changes in the elemental species on the lattice distortion,bond strength,bonding properties,and electronic structure of multi-component carbide ceramics were thoroughly analyzed.These results show that the hardening of multi-component carbide ceramic can be attributed to the coupling of solid solution strengthening caused by lattice distortion and covalent bond strengthening.Besides,the“host lattice”of multi-component carbide ceramics is defined based on the concept of supporting lattice.The present work is of great significance for a deeper understanding of the hardening mechanism of multi-component carbide ceramics and the design of superhard multi-component carbides.展开更多
A convenient photocatalytic multi-component reaction of alkenes,quinoxalin-2(1H)-ones,and diazo compounds has been developed in the presence of water.A number of ester-containing quinoxalin-2(1H)-ones could be efficie...A convenient photocatalytic multi-component reaction of alkenes,quinoxalin-2(1H)-ones,and diazo compounds has been developed in the presence of water.A number of ester-containing quinoxalin-2(1H)-ones could be efficiently obtained in moderate to good yields at room temperature.This metal-free visiblelight-driven tandem reaction was conducted through proton-coupled electron transfer(PCET)process using water as the hydrogen donor and 1,2,3,5-tetrakis(carbazol-9-yl)-4,6-dicyanobenzene(4CzIPN)as the photocatalyst.展开更多
The construction of a borehole correction library for the multi-component array induction tool in deviated boreholes involves extensive 3D forward modeling and typically requires significant computational resources.To...The construction of a borehole correction library for the multi-component array induction tool in deviated boreholes involves extensive 3D forward modeling and typically requires significant computational resources.To address this challenge,this paper proposes an efficient algorithm for the library construction based on the 3D finite volume method(FVM)and contraction high-order Born approximation(CHBA).First,the electromagnetic(EM)field solution region is divided into two symmetric subregions based on the symmetry of the correction library model and the EM field.Numerical solution on a single subregion,combined with the symmetry boundary extension technique,enhances the efficiency of the 3D numerical simulation.Second,three reference mud conductivities are selected based on the mud conductivity range,and the CHBA is applied to calculate the EM responses at all mud conductivity nodes rapidly.Third,the number of forward simulation operations is further reduced by exploiting the principle that models with different frequencies and different formation conductivities have equivalent EM responses.Numerical experiments demonstrate the correctness and feasibility of the proposed algorithm.Compared to conventional 3D modeling,the proposed algorithm achieves approximately a 20-fold speedup in library construction,effectively reducing computational resources and time consumption.展开更多
It is crucial to develop arsenic removal adsorbents with strong sulfur resistance under middle-low-temperature flue gas conditions(<400℃).In this work,five Fe-Ce-La oxides were prepared by co-precipitation method,...It is crucial to develop arsenic removal adsorbents with strong sulfur resistance under middle-low-temperature flue gas conditions(<400℃).In this work,five Fe-Ce-La oxides were prepared by co-precipitation method,and FeCeLaO/SiO_(2)-Al_(2)O_(3) composite adsorbents were prepared by coupling fly ash-based Si-Al carriers.The active components Fe-Ce-La oxides and Si-Al carriers were characterized by TPD,TG,XRF,BET and XPS,respectively.The effects of temperature,Si/Al ratio and FeCeLaO loading rate on the sulfur resistance were investigated.Results show that the SO_(2) promotes the arsenic removal of Fe_(2)O_(3),CeLaO and FeCeLaO.At 400℃,the arsenic removal efficiencies of the three oxides increase from 45.3%,72.5% and 81.3% without SO_(2) to 62.6%,80.5%and 91.0%,respectively.The SO_(2) inhibits the arsenic removal of La_(2)O_(2)CO_(3) and FeLaO,and the inhibition effect is pronounced at high temperatures.The sulfur poisoning resistance of Si-Al carriers increases with the increase of Si/Al ratio.When the Si/Al ratio is increased to 9.74,the arsenic removal efficiency in the SO_(2) environment is 13.9% higher than that in the absence of SO_(2).Introducing FeCeLaO active components is beneficial for enhancing the SO_(2) poisoning resistance of Si-Al carriers.The strong sulfur resistance of the FeCeLaO/SiO_(2)-Al_(2)O_(3) composite adsorbent results from multiple factors:protective effects of Ce on Fe,La and Al;sulfation-induced generation of Ce^(3+)and surface-adsorbed oxygen;and strong surface acidity of SiO_(2).展开更多
The Savitzky-Golay(SG)filter,which employs polynomial least-squares approximations to smooth data and estimate derivatives,is widely used for processing noisy data.However,noise suppression by the SG filter is recogni...The Savitzky-Golay(SG)filter,which employs polynomial least-squares approximations to smooth data and estimate derivatives,is widely used for processing noisy data.However,noise suppression by the SG filter is recognized to be limited at data boundaries and high frequencies,which can significantly reduce the signal-to-noise ratio(SNR).To solve this problem,a novel method synergistically integrating Principal Component Analysis(PCA)with SG filtering is proposed in this paper.This approach avoids the is-sue of excessive smoothing associated with larger window sizes.The proposed PCA-SG filtering algorithm was applied to a CO gas sensing system based on Cavity Ring-Down Spectroscopy(CRDS).The perform-ance of the PCA-SG filtering algorithm is demonstrated through comparison with Moving Average Filtering(MAF),Wavelet Transformation(WT),Kalman Filtering(KF),and the SG filter.The results demonstrate that the proposed algorithm exhibits superior noise reduction capabilities compared to the other algorithms evaluated.The SNR of the ring-down signal was improved from 11.8612 dB to 29.0913 dB,and the stand-ard deviation of the extracted ring-down time constant was reduced from 0.037μs to 0.018μs.These results confirm that the proposed PCA-SG filtering algorithm effectively improves the smoothness of the ring-down curve data,demonstrating its feasibility.展开更多
Natural Gas Industry B创刊于2014年,是天然气工业杂志社与KeAi公司合作出版的国际OA期刊,在爱思唯尔旗下的Science Direct平台上双月出版。论文聚焦天然气、氢气、氦气、地热等地质能源,涵盖地质勘探、气藏开发、工程技术、储运利用...Natural Gas Industry B创刊于2014年,是天然气工业杂志社与KeAi公司合作出版的国际OA期刊,在爱思唯尔旗下的Science Direct平台上双月出版。论文聚焦天然气、氢气、氦气、地热等地质能源,涵盖地质勘探、气藏开发、工程技术、储运利用、净化化工、产业趋势等专业方向。期刊服务全球天然气产业,并积极推动能源行业碳减排和低碳转型的发展。展开更多
基金supported by the National Natural Science Foundation of China(No.52174038 and No.52004307)China Petroleum Science and Technology Project-major project-Research on tight oil-shale oil reservoir engineering methods and key technologies in Ordos Basin(ZLZX2020-02-04)Science Foundation of China University of Petroleum,Beijing(No.2462018YJRC015).
文摘An essential technology of carbon capture, utilization and storage-enhanced oil recovery (CCUS-EOR) for tight oil reservoirs is CO_(2) huff-puff followed by associated produced gas reinjection. In this paper, the effects of multi-component gas on the properties and components of tight oil are studied. First, the core displacement experiments using the CH_(4)/CO_(2) multi-component gas are conducted to determine the oil displacement efficiency under different CO_(2) and CH_(4) ratios. Then, a viscometer and a liquid density balance are used to investigate the change characteristics of oil viscosity and density after multi-component gas displacement with different CO_(2) and CH_(4) ratios. In addition, a laboratory scale numerical model is established to validate the experimental results. Finally, a composition model of multi-stage fractured horizontal well in tight oil reservoir considering nano-confinement effects is established to investigate the effects of multi-component gas on the components of produced dead oil and formation crude oil. The experimental results show that the oil displacement efficiency of multi-component gas displacement is greater than that of single-component gas displacement. The CH_(4) decreases the viscosity and density of light oil, while CO_(2) decreases the viscosity but increases the density. And the numerical simulation results show that CO_(2) extracts more heavy components from the liquid phase into the vapor phase, while CH_(4) extracts more light components from the liquid phase into the vapor phase during cyclic gas injection. The multi-component gas can extract both the light components and the heavy components from oil, and the balanced production of each component can be achieved by using multi-component gas huff-puff.
基金Science and Technology Foundation of Guizhou Province(No.QKHJC-ZK[2024]654)Guizhou Provincial University Key Laboratory of Advanced Functional Electronic Materials(No.QJJ[2023]021).
文摘Carbenes as one of the most important class of intermediates have been widely utilized in various organic synthetic transformations.Carbene insertion-initiated ring-opening reactions of cyclic ethers offer a valuable strategy for constructing new carbon-oxygen bonds.In comparison with traditional thermal or metal-mediated carbene transfer reactions,visible-light-promoted multi-component reaction strategy provides a mild and eco-friendly approach to access densely functionalized molecules.Recently,visible-light-induced multi-component carbene transfer reactions of diazo compounds have been rapidly developed and attracted a great deal of research interest of chemists owing to their advantages of simple operation,mild condition,high atom economy and rich structural diversity.This paper summarizes the recent research progress on the visible-light-promoted multi-component carbene transfer reactions of diazo compounds via ring-opening of cyclic ethers with various nucleophiles.The reaction patterns of different nucleophiles and their corresponding mechanism are described in this review.The future research direction and challenges in this area are also discussed.
基金supported by National Natural Science Foundation of China(Grant No.50521503)National Basic Research Program of China(973 Program,Grant No.2007CB714704)National Hi-tech Research and Development Program of China(863 Program,Grant No.2006AA04Z406)
文摘The introduction of surface engineering is expected to be an effective strategy against fretting damage.A large number of studies show that the low gas multi-component(such as carbon,nitrogen,sulphur and oxygen,etc)thermo-chemical treatment(LTGMTT)can overcome the brittleness of nitriding process,and upgrade the surface hardness and improve the wear resistance and fatigue properties of the work-pieces significantly.However,there are few reports on the anti-fretting properties of the LTGMTT modified layer up to now,which limits the applications of fretting.So this paper discusses the fretting wear behavior of modified layer on the surface of LZ50(0.48%C)steel prepared by low temperature gas multi-component thermo-chemical treatment(LTGMTT)technology.The fretting wear tests of the modified layer flat specimens and its substrate(LZ50 steel)against 52100 steel balls with diameter of 40 mm are carried out under normal load of 150 N and displacement amplitudes varied from 2μm to 40μm.Characterization of the modified layer and dynamic analyses in combination with microscopic examinations were performed through the means of scanning electron microscope(SEM),optical microscope(OM),X-ray diffraction(XRD)and surface profilometer.The experimental results showed that the modified layer with a total thickness of 60μm was consisted of three parts,i.e.,loose layer,compound layer and diffusion layer.Compared with the substrate,the range of the mixed fretting regime(MFR)of the LTGMTT modified layer diminished,and the slip regime(SR)of the modified layer shifted to the direction of smaller displacement amplitude.The coefficient of friction(COF)of the modified layer was lower than that of the substrate in the initial stage.For the modified layer,the damage in partial slip regime(PSR)was very slight.The fretting wear mechanism of the modified layer both in MFR and SR was abrasive wear and delamination.The modified layer presented better wear resistance than the substrate in PSR and MFR;however,in SR,the wear resistance of the modified layer decreased with the increase of the displacement amplitudes.The experimental results can provide some experimental bases for promoting industrial application of LTGMTT modified layer in anti-fretting wear.
基金funded by the Natural Science Foundation of Shandong Province (ZR202103050722)National Natural Science Foundation of China (41174098)。
文摘The tight-fractured gas reservoir of the Upper Triassic Xujiahe Formation in the Western Sichuan Depression has low porosity and permeability. This study presents a DNN-based method for identifying gas-bearing strata in tight sandstone. First, multi-component composite seismic attributes are obtained.The strong nonlinear relationships between multi-component composite attributes and gas-bearing reservoirs can be constrained through a DNN. Therefore, we identify and predict the gas-bearing strata using a DNN. Then, sample data are fed into the DNN for training and testing. After optimized network parameters are determined by the performance curves and empirical formulas, the best deep learning gas-bearing prediction model is determined. The composite seismic attributes can then be fed into the model to extrapolate the hydrocarbon-bearing characteristics from known drilling areas to the entire region for predicting the gas reservoir distribution. Finally, we assess the proposed method in terms of the structure and fracture characteristics and predict favorable exploration areas for identifying gas reservoirs.
基金the National Natural Science Foundation of China (Nos. 51774283, 51174203)the Major International (Regional) Joint Research Project of NSFC (No. 51620105001) for the financial supports
文摘The segregation modes and characteristics of 1-6 mm multi-component lignite were studied in a microporous, vibrated, gas-fluidized bed of Φ110 mm ×400 mm. The effects of particle density and size, vibration frequency and amplitude, and gas velocity on these characteristics were considered. The average size, average density, size deviation coefficient, and density deviation coefficient were used to identify lignite size and density. The separation efficiency was adopted to evaluate the segregation performance,and the segregation mechanisms were explored. The results show that ε(size,max) of heterogeneous multisize-component lignite with K_(size) = 65% reaches 80% at f= 20 Hz, A = 5 mm, and N =(1,3). ε_(density,max) Of heterogeneous multi-density-component lignite with K_(density)= 25% reaches 50% at f = 15 Hz, A = 5 mm,and N =(1,1.5). The density segregations of 1-3 and 3-6 mm multi-component mixtures are remarkable,ε_(density,max)= 42% and 31% at f= 14 and 16 Hz, and A = 3 and 5 mm, respectively. The size segregation of 1-6 mm multi-component mixture is prominent and ε_(size,max)= 55% at f= 15 Hz, A = 5 mm. The mediumsized mixture with a narrow size distribution at low frequency is favorable for density segregation,and a mixture with a wider size distribution at high frequency is most favorable for size segregation.Precise control of gas flow and vibration as well as optimal design of the fluidized bed can improve the performance of segregation in the vibrated gas-fluidized bed.
基金the National Natural Science Fund of China(50474010)the National"Eleventh Five-year Plan"Science and Technology Support Plan of China(2006BAK03B0503)+1 种基金the Fund of Education Department Liaoning Province(05L-174)the Fund of Education Department Liaoning Province(20060389)
文摘Studied on multi-component combustible gas,methane mainly,explosion char- acteristics of high gas mine,obtained the rules of gas explosive limit that influenced by environment temperature,pressure,concentration of oxygen,other combustible gas,coal dust,energy of fire source,and the inert gas,proposed a new method of divide gas explo- sive triangle partition,and gave new partition linear equations.The gas explosive triangle and its new partition has important directive significance in distinguishing if the fire area has a gas explosion when sealing or opening fire area,or fire extinguishing in sealed fire area,and judging if there will be a gas explosion or other trend while fire extinguishing with inert gas.
基金Acknowledgment This research was supported by the Natural National Science Foundation of China, NSFC （Grant No. 61575149, 61290311）, and the Major Project of Hubei Technological Innovation Special Fund （2016AAA008）.
文摘An optical multi-component gas detection system based on the conjugated interferometer （CI） is proposed and experimentally demonstrated. It can realize the concentration detection of mixture gas in the environment. The CI can transform the absorption spectrum of the target gases to a conjugated emission spectrum, when combining the CI with the broadband light source, the spectrum of output light matches well with the absorption spectrum of target gases. The CI design for different target gases can be achieved by replacing the kind of target absorbing gas in the CI filter. The traditional fiber gas sensor system requires multiple light sources for detection when there are several kinds of gases, and this problem has been solved by using the CI filter combined with the broadband light source. The experimental results show that the system can detect the concentration of multi-component gases, which are mixed with C2H2 and NH3. Experimental results also show a good concentration sensing linearity.
基金This work was supported by“Thirteenth Five-Year”national science and technology major Project(No.2017ZX05018005-004)CNPC fundamental research project(No.2016E-0604)National Natural Science Foundation of China(No.41374111).
文摘Multi-component seismic exploration is an important technique in the utilization of P-waves and converted S-waves for oil and gas exploration.It has unique advantages in the structural imaging of gas zones,reservoir prediction,lithology,and gas-water identifi cation,and the development direction and degree of fractures.Multi-component joint inversion is one of the most important steps in multi-component exploration.In this paper,starting from the basic principle of multi-component joint inversion,the diff erences between the method and single P-wave inversion are introduced.Next,the technique is applied to the PLN area of the Sichuan Basin,and the P-wave impedance,S-wave impedance,and density are obtained based on multi-component joint inversion.Through the velocity and lithology,porosity,and gas saturation fi tting formulas,prediction results are calculated,and the results are analyzed.Finally,multi-component joint inversion and single P-wave inversion are compared in eff ective reservoir prediction.The results show that multi-component joint inversion increases the constraints on the inversion conditions,reduces the multi-solution of a single P-wave inversion,and is more objective and reliable for the identification of reservoirs,effectively improving the accuracy of oil and gas reservoir prediction and development.
基金sponsored by the National Natural Science Foundations of China under Grant Nos.12301315,12235007,11975131the Zhejiang Provincial Natural Science Foundation of China under Grant No.LQ20A010009。
文摘In the realm of nonlinear integrable systems,the presence of decompositions facilitates the establishment of linear superposition solutions and the derivation of novel coupled systems exhibiting nonlinear integrability.By focusing on single-component decompositions within the potential BKP hierarchy,it has been observed that specific linear superpositions of decomposition solutions remain consistent with the underlying equations.Moreover,through the implementation of multi-component decompositions within the potential BKP hierarchy,successful endeavors have been undertaken to formulate linear superposition solutions and novel coupled Kd V-type systems that resist decoupling via alterations in dependent variables.
基金financially supported by the National Natural Science Foundation of China(Nos.52271033 and 52071179)the Key program of National Natural Science Foundation of China(No.51931003)+2 种基金Natural Science Foundation of Jiangsu Province,China(No.BK20221493)Jiangsu Province Leading Edge Technology Basic Research Major Project(No.BK20222014)Foundation of“Qinglan Project”for Colleges and Universities in Jiangsu Province.
文摘Multi-component transition group metal borides(MMB_(2))have become a research hotspot due to their new composition design concepts and superior properties compared with conventional ceramics.Most of the current methods,however,are complicated and time-consuming,the mass production remains a chal-lenge.Herein,we proposed a new high-efficiency strategy for synthesis of MMB_(2)using molten aluminum as the medium for the first time.The prepared Al-containing multi-component borides(TiZrHfNbTa)B_(2)microcrystals had a homogeneous composition with a hexagonal AlB_(2)structure and ultra-high hardness value of∼35.3 GPa,which was much higher than data reported in the literature and the rule of mix-ture estimations.Furthermore,combined with the First-principles calculation results,we found that the Poisson’s ratio(v)values exhibit a clearly ascending trend from 0.17 at VEC=3.5 to 0.18 at VEC=3.4,then to 0.201 at VEC=3.2 with the increasing of Al content.This indicates that the intrinsic toughness of multi-component boride microcrystals is obviously enhanced by the trace-doped Al elements.Besides,the fabricated Al-containing multi-component boride microcrystals have superior oxidation activation en-ergy and structural stability.The enhanced oxidation resistance is mainly attributed to the formation of a protective Al2 O3 oxide layer and the lattice distortion,both of which lead to sluggish diffusion of O_(2).These findings propose a new unexplored avenue for the fabrication of MMB_(2)materials with supe-rior comprehensive performance including ultra-hardness and intrinsically improved thermo-mechanical properties.
基金financially supported by the National Natural Science Foundation of China(Nos.52032002,52372060,51972081,and U22A20128)the National Safety Academic Foundation(No.U2130103)+1 种基金the National Key Laboratory of Precision Hot Processing of Metals(No.61429092300305)Heilongjiang Touyan Team Program are gratefully acknowledged.
文摘The hardening mechanism of multi-component carbide ceramic has been investigated in detail through a combination of experiments,first-principles calculations,and ab initio molecular dynamics(AIMD).Eight dense carbide ceramics were prepared by spark plasma sintering.Compulsorily,all the multi-component carbide samples have similar carbon content,grain size,and uniform compositional distribution by optimizing the sintering process and adjusting the initial raw materials.Hence the interference of other factors on the hardness of multi-component carbide ceramics is minimized.The effects of changes in the elemental species on the lattice distortion,bond strength,bonding properties,and electronic structure of multi-component carbide ceramics were thoroughly analyzed.These results show that the hardening of multi-component carbide ceramic can be attributed to the coupling of solid solution strengthening caused by lattice distortion and covalent bond strengthening.Besides,the“host lattice”of multi-component carbide ceramics is defined based on the concept of supporting lattice.The present work is of great significance for a deeper understanding of the hardening mechanism of multi-component carbide ceramics and the design of superhard multi-component carbides.
基金supported by Sichuan Science and Technology Program(No.2023NSFSC0101)the 2024 Provincial platform project of Chengdu Normal University(No.GNFZ202404)+1 种基金Natural Science Foundation of Shandong Province(No.ZR2021MB065)National Natural Science Foundation of China(No.22101237)。
文摘A convenient photocatalytic multi-component reaction of alkenes,quinoxalin-2(1H)-ones,and diazo compounds has been developed in the presence of water.A number of ester-containing quinoxalin-2(1H)-ones could be efficiently obtained in moderate to good yields at room temperature.This metal-free visiblelight-driven tandem reaction was conducted through proton-coupled electron transfer(PCET)process using water as the hydrogen donor and 1,2,3,5-tetrakis(carbazol-9-yl)-4,6-dicyanobenzene(4CzIPN)as the photocatalyst.
基金funded by the Forward-looking Basic Science and Technology Research Project of PetroChina Company Limited(2025DJ104)the National Natural Science Foundation of China(42174150)the National Science and Technology Major Project for Deep Earth Probe and Mineral Resources Exploration(2024ZD1003005).
文摘The construction of a borehole correction library for the multi-component array induction tool in deviated boreholes involves extensive 3D forward modeling and typically requires significant computational resources.To address this challenge,this paper proposes an efficient algorithm for the library construction based on the 3D finite volume method(FVM)and contraction high-order Born approximation(CHBA).First,the electromagnetic(EM)field solution region is divided into two symmetric subregions based on the symmetry of the correction library model and the EM field.Numerical solution on a single subregion,combined with the symmetry boundary extension technique,enhances the efficiency of the 3D numerical simulation.Second,three reference mud conductivities are selected based on the mud conductivity range,and the CHBA is applied to calculate the EM responses at all mud conductivity nodes rapidly.Third,the number of forward simulation operations is further reduced by exploiting the principle that models with different frequencies and different formation conductivities have equivalent EM responses.Numerical experiments demonstrate the correctness and feasibility of the proposed algorithm.Compared to conventional 3D modeling,the proposed algorithm achieves approximately a 20-fold speedup in library construction,effectively reducing computational resources and time consumption.
文摘It is crucial to develop arsenic removal adsorbents with strong sulfur resistance under middle-low-temperature flue gas conditions(<400℃).In this work,five Fe-Ce-La oxides were prepared by co-precipitation method,and FeCeLaO/SiO_(2)-Al_(2)O_(3) composite adsorbents were prepared by coupling fly ash-based Si-Al carriers.The active components Fe-Ce-La oxides and Si-Al carriers were characterized by TPD,TG,XRF,BET and XPS,respectively.The effects of temperature,Si/Al ratio and FeCeLaO loading rate on the sulfur resistance were investigated.Results show that the SO_(2) promotes the arsenic removal of Fe_(2)O_(3),CeLaO and FeCeLaO.At 400℃,the arsenic removal efficiencies of the three oxides increase from 45.3%,72.5% and 81.3% without SO_(2) to 62.6%,80.5%and 91.0%,respectively.The SO_(2) inhibits the arsenic removal of La_(2)O_(2)CO_(3) and FeLaO,and the inhibition effect is pronounced at high temperatures.The sulfur poisoning resistance of Si-Al carriers increases with the increase of Si/Al ratio.When the Si/Al ratio is increased to 9.74,the arsenic removal efficiency in the SO_(2) environment is 13.9% higher than that in the absence of SO_(2).Introducing FeCeLaO active components is beneficial for enhancing the SO_(2) poisoning resistance of Si-Al carriers.The strong sulfur resistance of the FeCeLaO/SiO_(2)-Al_(2)O_(3) composite adsorbent results from multiple factors:protective effects of Ce on Fe,La and Al;sulfation-induced generation of Ce^(3+)and surface-adsorbed oxygen;and strong surface acidity of SiO_(2).
文摘The Savitzky-Golay(SG)filter,which employs polynomial least-squares approximations to smooth data and estimate derivatives,is widely used for processing noisy data.However,noise suppression by the SG filter is recognized to be limited at data boundaries and high frequencies,which can significantly reduce the signal-to-noise ratio(SNR).To solve this problem,a novel method synergistically integrating Principal Component Analysis(PCA)with SG filtering is proposed in this paper.This approach avoids the is-sue of excessive smoothing associated with larger window sizes.The proposed PCA-SG filtering algorithm was applied to a CO gas sensing system based on Cavity Ring-Down Spectroscopy(CRDS).The perform-ance of the PCA-SG filtering algorithm is demonstrated through comparison with Moving Average Filtering(MAF),Wavelet Transformation(WT),Kalman Filtering(KF),and the SG filter.The results demonstrate that the proposed algorithm exhibits superior noise reduction capabilities compared to the other algorithms evaluated.The SNR of the ring-down signal was improved from 11.8612 dB to 29.0913 dB,and the stand-ard deviation of the extracted ring-down time constant was reduced from 0.037μs to 0.018μs.These results confirm that the proposed PCA-SG filtering algorithm effectively improves the smoothness of the ring-down curve data,demonstrating its feasibility.
文摘Natural Gas Industry B创刊于2014年,是天然气工业杂志社与KeAi公司合作出版的国际OA期刊,在爱思唯尔旗下的Science Direct平台上双月出版。论文聚焦天然气、氢气、氦气、地热等地质能源,涵盖地质勘探、气藏开发、工程技术、储运利用、净化化工、产业趋势等专业方向。期刊服务全球天然气产业,并积极推动能源行业碳减排和低碳转型的发展。
