The formation of solid solution combined with tricalcium phosphate and dicalcium silicate could promote a considerable removal of phosphorus from liquid slag to solid during hot metal dephosphorization,and thus the de...The formation of solid solution combined with tricalcium phosphate and dicalcium silicate could promote a considerable removal of phosphorus from liquid slag to solid during hot metal dephosphorization,and thus the dephosphorization by using multi phase fluxes could significantly decrease the consumption of lime. However,the reaction mechanism of multi phase fluxes has not been understood clearly.In the present study,the phase diagram for the CaO-SiO_2-FeO-P_2O_5 system has been measured with certain oxygen partial pressure at hot metal pretreatment temperature.Comparing with the CaO-SiO_2-FeO system,shrinkage of liquid phase area at higher FeO contents was observed at 1 673 K with oxygen partial pressure of 9.2×10^(-11) atm.展开更多
Development of the efficient hot metal dephosphorization processes during steelmaking process is one of the most essential topics for the production of high grade clean steels. Since the formation of solid solution co...Development of the efficient hot metal dephosphorization processes during steelmaking process is one of the most essential topics for the production of high grade clean steels. Since the formation of solid solution composed of tricalcium phosphate and dicalcium silicate could obtain a considerable mass transfer of phosphorus from liquid slag into solid phase during hot metal dephosphorization, itcould obviously sustain a high phosphatecapacityof theliquid slag without huge consumption of lime or addition of fluxes, such as fluorite. The above outlines are the main idea of multi phase flux dephosphorization. For the last few decades, many studies have been done towards the scientific principles and the commercial utilization of this technique. However, the reaction mechanism by using multi phase fluxes remains unclear even by now due tolack of evidence. Based on those previous works, providing a reliable and available phase diagram for the fundamental understanding of the reaction mechanism of multi phase flux dephosphorization has become the main purpose of present research. As well known, the CaO-SiO2-FeO-P2O5 slag is the main component of current steelmaking process. Hence the CaO-SiO2-FeO-P2O5 system at equilibrium has been studied at 1673K with low oxygen partial pressure. The solid phase coexisting with liquid flux is approved to be the solid solution composed of CaO, SiO2 and P2O5. Phosphorus distributes mainly in solid solution rather than liquid phase.展开更多
The fluid of casting process is a typical kind of multi-phase flow. Actually, many casting phenomena have close relationship with the multi-phase flow, such as molten metal filling process, air entrapment, slag moveme...The fluid of casting process is a typical kind of multi-phase flow. Actually, many casting phenomena have close relationship with the multi-phase flow, such as molten metal filling process, air entrapment, slag movement, venting process of die casting, gas escaping of lost foam casting and so on. Obviously, in order to analyze these phenomena accurately, numerical simulation of the multi-phase fluid is necessary. Unfortunately, so far, most of the commercial casting simulation systems do not have the ability of multi-phase flow modeling due to the difficulty in the multi-phase flow calculation. In the paper, Finite Different Method (FDM) technique was adopt to solve the multi-phase fluid model. And a simple object of the muiti-phase fluid was analyzed to obtain the fluid rates of the liquid phase and the entrapped air phase.展开更多
In this paper, the design of a coarse-fine interpolation Time-to-Digital Converter (TDC) is implemented in an ALTERA’s Cyclone FPGA. The carry-select chain performs as the tapped delay line. The Logic Array Block (LA...In this paper, the design of a coarse-fine interpolation Time-to-Digital Converter (TDC) is implemented in an ALTERA’s Cyclone FPGA. The carry-select chain performs as the tapped delay line. The Logic Array Block (LAB) having a propagation delay of 165 ps in the chain is synthesized as delay cell. Coarse counters triggered by the global clock count the more significant bits of the time data. This clock is also fed through the delay line, and LABs create the copies. The replicas are latched by the tested event signal, and the less significant bits are encoded from the latched binary bits. Single-shot resolution of the TDC can be 60 ps. The worst Differential Nonlinearity (DNL) is about 0.2 Least Significant Bit (LSB, 165 ps in this TDC module), and the Integral Nonlinearity (INL) is 0.6 LSB. In comparison with other architectures using the synchronous global clock to sample the taps, this architecture consumed less electric power and logic cells, and is more stable.展开更多
Polyamide/acrylonitrile-butadiene-styrene copolymer(PA/ABS) blends have drawn considerable attention from both academia and industry for their important applications in automotive and electronic areas. Due to poor mis...Polyamide/acrylonitrile-butadiene-styrene copolymer(PA/ABS) blends have drawn considerable attention from both academia and industry for their important applications in automotive and electronic areas. Due to poor miscibility of PA and ABS, developing an effective compatibilization strategy has been an urgent challenge to achieve prominent mechanical properties. In this study, we create a set of mechanically enhanced PA6/ABS blends using two multi-monomer melt-grafted compatibilizers, SEBSg-(MAH-co-St) and ABS-g-(MAH-co-St). The dispersed domain size is significantly decreased and meanwhile the unique "soft shell-encapsulating-hard core" structures form in the presence of compatibilizers. The optimum mechanical performances manifest an increase of 36% in tensile strength and an increase of 1300% in impact strength, compared with the neat PA6/ABS binary blend.展开更多
A mechanical model of liquid crystals （LCs） is applied to study the polymorphism of homologous series of terphenyl compounds. With a senti-experimental molecular orbit method, we calculate the moment of inertia whic...A mechanical model of liquid crystals （LCs） is applied to study the polymorphism of homologous series of terphenyl compounds. With a senti-experimental molecular orbit method, we calculate the moment of inertia which represents the rotation state to describe the phase transition temperature obtained from experimental data. We propose a novel explanation of the phase sequence or polymorphism of LC materials using the two key parameters, the moment of inertia and critical rotational velocity. The effect of molecular polarity on the appearance of liquid crystalline is also discussed.展开更多
Based on the fundamental equations of the mechanics of solid continuum, the paper employs an analytical model for determination of elastic thermal stresses in isotropic continuum represented by periodically distribute...Based on the fundamental equations of the mechanics of solid continuum, the paper employs an analytical model for determination of elastic thermal stresses in isotropic continuum represented by periodically distributed spherical particles with different distributions in an infinite matrix, imaginarily divided into identical cells with dimensions equal to inter-particle distances, containing a central spherical particle with or without a spherical envelope on the particle surface. Consequently, the multi-particle-（envelope）- matrix system, as a model system regarding the analytical modelling, is applicable to four types of multi-phase materials. As functions of the particle volume fraction v, the inter-particle distances dl, d2, d3 along three mutually per- pendicular axes, and the particle and envelope radii, R1 and R2, respectively, the thermal stresses within the cell, are originated during a cooling process as a consequence of the difference in thermal expansion coefficients of phases rep- resented by the matrix, envelope and particle. Analytical-（experimental）-computational lifetime prediction methods for multi-phase materials are proposed, which can be used in engineering with appropriate values of parameters of real multi-phase materials.展开更多
A total of 80 weathering pits （gnammas）, located on granite surfaces of Qing Mountain （青山）, Hexigten （克什克腾） Global Geopark, Inner Mongolia, were identified and measured in terms of dimensional and orientat...A total of 80 weathering pits （gnammas）, located on granite surfaces of Qing Mountain （青山）, Hexigten （克什克腾） Global Geopark, Inner Mongolia, were identified and measured in terms of dimensional and orientational features. This article attempts to extract characteristics of the weathering pits by descriptive statistics and orientation rose diagrams, investigate the multi-phase evolution by the modified gnamma morphological analysis （GMA） method, and shed new light on the possible genesis and the influencing factors. Following the modified GMA method, weathering pits in Qing Mountain have been divided into six groups and compared with analogous sites to deduce their approximate age, which might be no older than 30 ka B.P., and explore the possibility that the multi-phase evolution of weathering pits may arise from responses to climate change. In consequence, we suggest that the combination of weathering, especially salt weathering, and wind erosion, both of which are closely related to climatic variation, take the main responsibility for the formation and development of weathering pits in Qing Mountain.展开更多
This work establishes a temperature-controlled sequence function, and a new multi-phase-field model, for liquid- solid-solid multi-phase transformation by coupling the liquid-solid phase transformation model with the ...This work establishes a temperature-controlled sequence function, and a new multi-phase-field model, for liquid- solid-solid multi-phase transformation by coupling the liquid-solid phase transformation model with the solid-solid phase transformation model. Taking an Fe-C alloy as an example, the continuous evolution of a multi-phase transformation is simulated by using this new model. In addition, the growth of grains affected by the grain orientation of the parent phase （generated in liquid-solid phase transformation） in the solid-solid phase transformation is studied. The results show that the morphology of ferrite grains which nucleate at the boundaries of the austenite grains is influenced by the orientation of the parent austenite grains. The growth rate of ferrite grains which nucleate at small-angle austenite grain boundaries is faster than those that nucleate at large-angle austenite grain boundaries. The difference of the growth rate of ferrites grains in different parent phase that nucleate at large-angle austenite grain boundaries, on both sides of the boundaries, is greater than that of ferrites nucleating at small-angle austenite grain boundaries.展开更多
By coupling the phase field model with the continuity equation of incompressible fluid, Navier–Stokes equation,electric field equation, and other governing equations, a multi-field coupling model for multi-bubble coa...By coupling the phase field model with the continuity equation of incompressible fluid, Navier–Stokes equation,electric field equation, and other governing equations, a multi-field coupling model for multi-bubble coalescence in a viscous fluids is established. The phase field method is used to capture the two-phase interface. The motion and coalescence of a pair of coaxial bubbles under an external uniform electric field and the effects of different electric field strengths on the interaction and coalescence of rising bubbles are studied. The results show that the uniform electric field accelerates the collision and coalescence process of double bubbles in the fluid, and increases the rising velocity of the coalesced bubble.The electric field with an intensity of E = 2 kV/mm is reduced about 2 times compared with that without electric field in coalescence time. When the electric field strength is strong(E ≥ 1 kV/mm), the coalesced bubble will rupture before it rises to the top of the calculation area, and the time of the bubble rupturing also decreases with the increase of the electric field strength. The phase field method is compared with the simulation results of Lattice Boltzmann Method(LBM), and the shape of bubble obtained by the two methods is in good agreement, which verifies the correctness of the calculation model.展开更多
Structure materials under severe irradiations in nuclear environments are known to degrade because of irradiation hardening and loss of ductility,resulting from irradiation-induced defects such as vacancies,interstiti...Structure materials under severe irradiations in nuclear environments are known to degrade because of irradiation hardening and loss of ductility,resulting from irradiation-induced defects such as vacancies,interstitials and dislocation loops,etc.In this paper,we develop an elastic-viscoplastic model for irradiated multi-phase polycrystalline BCC materials in which the mechanical behaviors of individual grains and polycrystalline aggregates are both explored.At the microscopic grain scale,we use the internal variable model and propose a new tensorial damage descriptor to represent the geometry character of the defect loop,which facilitates the analysis of the defect loop evolutions and dislocation-defect interactions.At the macroscopic polycrystal scale,the self-consistent scheme is extended to consider the multiphase problem and used to bridge the individual grain behavior to polycrystal properties.Based on the proposed model,we found that the work-hardening coefficient decreases with the increase of irradiation-induced defect loops,and the orientation/loading dependence of mechanical properties is mainly attributed to the different Schmid factors.At the polycrystalline scale,numerical results for pure Fe match well with the irradiation experiment data.The model is further extended to predict the hardening effect of dispersoids in oxide-dispersed strengthened steels by the considering the Orowan bowing.The influences of grain size and irradiation are found to compete to dominate the strengthening behaviors of materials.展开更多
To determine the time-independent constitutive modeling for porous and multi- phase nanocrystalline materials and understand the effects of grain size and porosity on their mechanical behavior, each phase was treated ...To determine the time-independent constitutive modeling for porous and multi- phase nanocrystalline materials and understand the effects of grain size and porosity on their mechanical behavior, each phase was treated as a mixture of grain interior and grain bound- ary, and pores were taken as a single phase, then Budiansky＇s self-consistent method was used to calculate the Young＇s modulus of porous, possible multi-phase, nanocrystalline materials, the prediction being in good agreement with the results in the literature. Further, the established method is extended to simulate the constitutive relations of porous and possible multi-phase nanocrystalline materials with small plastic deformation in conjunction with the secant-moduli approach and iso-strain assumption. Comparisons between the experimental grain size and porosity dependent mechanical data and the corresponding predictions using the established model show that it appears to be capable of describing the time-independent mechanical behaviors for porous and multi-phase nanocrystalline materials in a small plastic strain range. Further discussion on the modification factor, the advantages and limitations of the model developed were present.展开更多
In this article, principle and mathematical method of determining the phase fractions of multiphase flows by using a dual-energy γ -ray system have been described. The dual-energy γ -ray device is composed of radioa...In this article, principle and mathematical method of determining the phase fractions of multiphase flows by using a dual-energy γ -ray system have been described. The dual-energy γ -ray device is composed of radioactive isotopes of 241Am and 137Cs with γ -ray energies of 59.5 and 662 keV, respectively. A rational method to calibrate the absorption coefficient was introduced in detail. The modified arithmetic is beneficial to removing the extra Compton scattering from the measured value. The result shows that the dual-energy γ -ray technique can be used in three-phase flow with average accuracy greater than 95%, which enables us to determine phase fractions almost independent of the flow regime. Improvement has been achieved on measurement accuracy of phase fractions.展开更多
The deformation and micro-voids formation mechanisms in ferrite / bainite（ F / B） multi-phase steel with the volume fraction of bainite less than 50% were studied by numerical simulation and experimental observation...The deformation and micro-voids formation mechanisms in ferrite / bainite（ F / B） multi-phase steel with the volume fraction of bainite less than 50% were studied by numerical simulation and experimental observation. The results show that the micro-strain concentrates at the soft / hard phase（ F / B） interface in the multi-phase steel,which should be correlated with the mechanism of incoordinate deformation. During the necking of the steel,the micro-voids initially form around the F / B interface,which also form in ferrite and bainite with the severe strain. The micro-voids in bainite are more dense and finer than those in ferrite. The failure mechanism of bainite is the coalescence of micro-voids,and the failure mechanism of ferrite is the growth and tearing of micro-voids. Due to the different failure mechanisms of ferrite and bainite,a suitable part of soft phase would be beneficial to the capability of anti-failure of F / B multi-phase steel during the ductile fracture.展开更多
An advanced ceramic cutting tool material Al2O3/TiC/TiN （LTN） is developed by incorporation and dispersion of micro-scale TiC particle and nano-scale TiN particle in alumina matrix. With the optimal dispersing and f...An advanced ceramic cutting tool material Al2O3/TiC/TiN （LTN） is developed by incorporation and dispersion of micro-scale TiC particle and nano-scale TiN particle in alumina matrix. With the optimal dispersing and fabricating technology, this multi-scale and multi-phase nanocomposite ceramic tool material can get both higher flexural strength and fracture toughness than that of A1203/TiC （LZ） ceramic tool material without nano-scale TiN particle, especially the fracture toughness can reach to 7.8 MPa . m^0.5. The nano-scale TiN can lead to the grain fining effect and promote the sintering process to get a higher density. The coexisting transgranular and intergranular fracture mode induced by micro-scale TiC and nano-scale TiN, and the homogeneous and densified microstructure can result in a remarkable strengthening and toughening effect. The cutting performance and wear mechanisms of the advanced multi-scale and multi-phase nanocomposite ceramic cutting tool are researched.展开更多
In this paper, a finite element method （FEM）-based multi-phase problem based on a newly proposed thermal elastoplastic constitutive model for saturated/unsaturated geomaterial is discussed. A program of FEM named as...In this paper, a finite element method （FEM）-based multi-phase problem based on a newly proposed thermal elastoplastic constitutive model for saturated/unsaturated geomaterial is discussed. A program of FEM named as SOFT, adopting unified field equations for thermo-hydro-mechanical-air （THMA） behavior of geomaterial and using finite element-finite difference （FE-FD） scheme for so/l-water-air three-phase coupling problem, is used in the numerical simulation. As an application of the newly proposed numerical method, two engineering problems, one for slope failure in unsaturated model ground and another for in situ heating test related to deep geological repository of high-level radioactive waste （HLRW）, are simulated. The model tests on slope failure in unsaturated Shirasu ground, carried out by Kitamura et al. （2007）, is simulated in the framework of soil-water-air three-phase coupling under the condition of constant temperature. While the in situ heating test reported by Munoz （2006） is simulated in the same framework under the conditions of variable temperature hut constant air pressure.展开更多
A highly effective and mild protocol for ring opening of epoxides with NH4SCN in the presence of catalytic amount of a multi- site phase-transfer catalyst, α,α＇,α＂-N-hexakis（triethylammoniummethylene chloride）-...A highly effective and mild protocol for ring opening of epoxides with NH4SCN in the presence of catalytic amount of a multi- site phase-transfer catalyst, α,α＇,α＂-N-hexakis（triethylammoniummethylene chloride）-melamine, is developed. A variety of ^-hydroxy thiocyanates as important intermediates in agricultural and pharmaceutical chemistry were obtained in high yields with excellent regioselectivity and in short reaction times. 2009 Ali Reza Kiasat. Published by Elsevier B.V. on behalf of Chinese Chemical Society. All rights reserved.展开更多
In this article, a physics aware deep learning model is introduced for multiphase flow problems. The deep learning model is shown to be capable of capturing complex physics phenomena such as saturation front, which is...In this article, a physics aware deep learning model is introduced for multiphase flow problems. The deep learning model is shown to be capable of capturing complex physics phenomena such as saturation front, which is even challenging for numerical solvers due to the instability. We display the preciseness of the solution domain delivered by deep learning models and the low cost of deploying this model for complex physics problems, showing the versatile character of this method and bringing it to new areas. This will require more allocation points and more careful design of the deep learning model architectures and residual neural network can be a potential candidate.展开更多
This paper presents an enhanced multi-baseline phase unwrapping algorithm by combining an unscented Kalman filter with an enhanced joint phase gradient estimator based on the amended matrix pencil model, and an optima...This paper presents an enhanced multi-baseline phase unwrapping algorithm by combining an unscented Kalman filter with an enhanced joint phase gradient estimator based on the amended matrix pencil model, and an optimal path-following strategy based on phase quality estimate function. The enhanced joint phase gradient estimator can accurately and effectively extract the phase gradient information of wrapped pixels from noisy interferograms, which greatly increases the performances of the proposed method. The optimal path-following strategy ensures that the proposed algorithm simultaneously performs noise suppression and phase unwrapping along the pixels with high-reliance to the pixels with low-reliance. Accordingly, the proposed algorithm can be predicted to obtain better results, with respect to some other algorithms, as will be demonstrated by the results obtained from synthetic data.展开更多
Alloying greatly expands the amount of available materials beyond the naturally existing ones, and more importantly offers the material scientists opportunities to initiatively control the composition-structure-proper...Alloying greatly expands the amount of available materials beyond the naturally existing ones, and more importantly offers the material scientists opportunities to initiatively control the composition-structure-property relationship in materials. Since commonly used metallic materials are mostly multi-component alloys, the know-how of alloying through compositional control, certainly plays a critical role in designing materials with desired structure and properties. However, alloying in multi-component alloys is an extremely complicated issue, as the alloyed products could be the amorphous phase, various solid solutions and intermetallic compounds containing two or more alloy components. By narrowing down the scope of the multi-component alloys to those with equiatomic or close-to-equiatomic compositions only, and also aiming at framing out the rules that govern the phase selection upon alloying in multi-component alloys in a broad sense, we have identified here a simple and easily executable two-parameter scheme that can effectively predict the formation of the amorphous phase, solid solutions and intermetallic compounds, in multi-component alloys, simply from the given alloy compositions. We believe this scheme reveals a clear physical scenario governing the phase selection in multi-component alloys, helps to simplify the alloy design, and benefits the future development of advanced metallic alloys like bulk metallic glasses and high entropy alloys.展开更多
文摘The formation of solid solution combined with tricalcium phosphate and dicalcium silicate could promote a considerable removal of phosphorus from liquid slag to solid during hot metal dephosphorization,and thus the dephosphorization by using multi phase fluxes could significantly decrease the consumption of lime. However,the reaction mechanism of multi phase fluxes has not been understood clearly.In the present study,the phase diagram for the CaO-SiO_2-FeO-P_2O_5 system has been measured with certain oxygen partial pressure at hot metal pretreatment temperature.Comparing with the CaO-SiO_2-FeO system,shrinkage of liquid phase area at higher FeO contents was observed at 1 673 K with oxygen partial pressure of 9.2×10^(-11) atm.
文摘Development of the efficient hot metal dephosphorization processes during steelmaking process is one of the most essential topics for the production of high grade clean steels. Since the formation of solid solution composed of tricalcium phosphate and dicalcium silicate could obtain a considerable mass transfer of phosphorus from liquid slag into solid phase during hot metal dephosphorization, itcould obviously sustain a high phosphatecapacityof theliquid slag without huge consumption of lime or addition of fluxes, such as fluorite. The above outlines are the main idea of multi phase flux dephosphorization. For the last few decades, many studies have been done towards the scientific principles and the commercial utilization of this technique. However, the reaction mechanism by using multi phase fluxes remains unclear even by now due tolack of evidence. Based on those previous works, providing a reliable and available phase diagram for the fundamental understanding of the reaction mechanism of multi phase flux dephosphorization has become the main purpose of present research. As well known, the CaO-SiO2-FeO-P2O5 slag is the main component of current steelmaking process. Hence the CaO-SiO2-FeO-P2O5 system at equilibrium has been studied at 1673K with low oxygen partial pressure. The solid phase coexisting with liquid flux is approved to be the solid solution composed of CaO, SiO2 and P2O5. Phosphorus distributes mainly in solid solution rather than liquid phase.
文摘The fluid of casting process is a typical kind of multi-phase flow. Actually, many casting phenomena have close relationship with the multi-phase flow, such as molten metal filling process, air entrapment, slag movement, venting process of die casting, gas escaping of lost foam casting and so on. Obviously, in order to analyze these phenomena accurately, numerical simulation of the multi-phase fluid is necessary. Unfortunately, so far, most of the commercial casting simulation systems do not have the ability of multi-phase flow modeling due to the difficulty in the multi-phase flow calculation. In the paper, Finite Different Method (FDM) technique was adopt to solve the multi-phase fluid model. And a simple object of the muiti-phase fluid was analyzed to obtain the fluid rates of the liquid phase and the entrapped air phase.
基金Supported by National Natural Science Foundation of China (No. 10405023)Knowledge Innovation Program of The Chinese Academy of Sciences (KJCX2-YW-N27)
文摘In this paper, the design of a coarse-fine interpolation Time-to-Digital Converter (TDC) is implemented in an ALTERA’s Cyclone FPGA. The carry-select chain performs as the tapped delay line. The Logic Array Block (LAB) having a propagation delay of 165 ps in the chain is synthesized as delay cell. Coarse counters triggered by the global clock count the more significant bits of the time data. This clock is also fed through the delay line, and LABs create the copies. The replicas are latched by the tested event signal, and the less significant bits are encoded from the latched binary bits. Single-shot resolution of the TDC can be 60 ps. The worst Differential Nonlinearity (DNL) is about 0.2 Least Significant Bit (LSB, 165 ps in this TDC module), and the Integral Nonlinearity (INL) is 0.6 LSB. In comparison with other architectures using the synchronous global clock to sample the taps, this architecture consumed less electric power and logic cells, and is more stable.
基金the National Natural Science Foundation of China (No. 51633003) for the financial support
文摘Polyamide/acrylonitrile-butadiene-styrene copolymer(PA/ABS) blends have drawn considerable attention from both academia and industry for their important applications in automotive and electronic areas. Due to poor miscibility of PA and ABS, developing an effective compatibilization strategy has been an urgent challenge to achieve prominent mechanical properties. In this study, we create a set of mechanically enhanced PA6/ABS blends using two multi-monomer melt-grafted compatibilizers, SEBSg-(MAH-co-St) and ABS-g-(MAH-co-St). The dispersed domain size is significantly decreased and meanwhile the unique "soft shell-encapsulating-hard core" structures form in the presence of compatibilizers. The optimum mechanical performances manifest an increase of 36% in tensile strength and an increase of 1300% in impact strength, compared with the neat PA6/ABS binary blend.
文摘A mechanical model of liquid crystals （LCs） is applied to study the polymorphism of homologous series of terphenyl compounds. With a senti-experimental molecular orbit method, we calculate the moment of inertia which represents the rotation state to describe the phase transition temperature obtained from experimental data. We propose a novel explanation of the phase sequence or polymorphism of LC materials using the two key parameters, the moment of inertia and critical rotational velocity. The effect of molecular polarity on the appearance of liquid crystalline is also discussed.
基金the Slovak Research and Development Agency under the contract No.COST-0022-06,APVV-51-061505the 6th FP EU NESPA+5 种基金the Slovak Grant Agency VEGA (2/7197/27,2/7194/27,2/7195/27)NANOSMART,Centre of Excellence (1/1/2007-31/12/2010)Slovak Academy of Sciences,by KMM-NoE 502243-2 (10/2004-9/2008)NENAMAT INCO-CT-2003-510363COST Action 536 and COST Action 538János Bolyai Research Grant NSF-MTA-OTKA grant-MTA:96/OTKA:049953,OTKA 63609
文摘Based on the fundamental equations of the mechanics of solid continuum, the paper employs an analytical model for determination of elastic thermal stresses in isotropic continuum represented by periodically distributed spherical particles with different distributions in an infinite matrix, imaginarily divided into identical cells with dimensions equal to inter-particle distances, containing a central spherical particle with or without a spherical envelope on the particle surface. Consequently, the multi-particle-（envelope）- matrix system, as a model system regarding the analytical modelling, is applicable to four types of multi-phase materials. As functions of the particle volume fraction v, the inter-particle distances dl, d2, d3 along three mutually per- pendicular axes, and the particle and envelope radii, R1 and R2, respectively, the thermal stresses within the cell, are originated during a cooling process as a consequence of the difference in thermal expansion coefficients of phases rep- resented by the matrix, envelope and particle. Analytical-（experimental）-computational lifetime prediction methods for multi-phase materials are proposed, which can be used in engineering with appropriate values of parameters of real multi-phase materials.
基金supported by China Geological Survey(No.11212011120118)the Fundamental Research Projects of China University of Geosciences,Beijing,China(No.2011YYL016)
文摘A total of 80 weathering pits （gnammas）, located on granite surfaces of Qing Mountain （青山）, Hexigten （克什克腾） Global Geopark, Inner Mongolia, were identified and measured in terms of dimensional and orientational features. This article attempts to extract characteristics of the weathering pits by descriptive statistics and orientation rose diagrams, investigate the multi-phase evolution by the modified gnamma morphological analysis （GMA） method, and shed new light on the possible genesis and the influencing factors. Following the modified GMA method, weathering pits in Qing Mountain have been divided into six groups and compared with analogous sites to deduce their approximate age, which might be no older than 30 ka B.P., and explore the possibility that the multi-phase evolution of weathering pits may arise from responses to climate change. In consequence, we suggest that the combination of weathering, especially salt weathering, and wind erosion, both of which are closely related to climatic variation, take the main responsibility for the formation and development of weathering pits in Qing Mountain.
基金supported by the National Natural Science Foundation of China(Grant Nos.51661020,11504149,and 11364024)
文摘This work establishes a temperature-controlled sequence function, and a new multi-phase-field model, for liquid- solid-solid multi-phase transformation by coupling the liquid-solid phase transformation model with the solid-solid phase transformation model. Taking an Fe-C alloy as an example, the continuous evolution of a multi-phase transformation is simulated by using this new model. In addition, the growth of grains affected by the grain orientation of the parent phase （generated in liquid-solid phase transformation） in the solid-solid phase transformation is studied. The results show that the morphology of ferrite grains which nucleate at the boundaries of the austenite grains is influenced by the orientation of the parent austenite grains. The growth rate of ferrite grains which nucleate at small-angle austenite grain boundaries is faster than those that nucleate at large-angle austenite grain boundaries. The difference of the growth rate of ferrites grains in different parent phase that nucleate at large-angle austenite grain boundaries, on both sides of the boundaries, is greater than that of ferrites nucleating at small-angle austenite grain boundaries.
基金supported by the National Natural Science Foundation of China(Grant Nos.51661020,11504149,and 11364024)the Postdoctoral Science Foundation of China(Grant No.2014M560371)the Funds for Distinguished Young Scientists of Lanzhou University of Technology,China(Grant No.J201304)
文摘By coupling the phase field model with the continuity equation of incompressible fluid, Navier–Stokes equation,electric field equation, and other governing equations, a multi-field coupling model for multi-bubble coalescence in a viscous fluids is established. The phase field method is used to capture the two-phase interface. The motion and coalescence of a pair of coaxial bubbles under an external uniform electric field and the effects of different electric field strengths on the interaction and coalescence of rising bubbles are studied. The results show that the uniform electric field accelerates the collision and coalescence process of double bubbles in the fluid, and increases the rising velocity of the coalesced bubble.The electric field with an intensity of E = 2 kV/mm is reduced about 2 times compared with that without electric field in coalescence time. When the electric field strength is strong(E ≥ 1 kV/mm), the coalesced bubble will rupture before it rises to the top of the calculation area, and the time of the bubble rupturing also decreases with the increase of the electric field strength. The phase field method is compared with the simulation results of Lattice Boltzmann Method(LBM), and the shape of bubble obtained by the two methods is in good agreement, which verifies the correctness of the calculation model.
基金support provided by the Major State Basic Research Development Program of China(Grant 2011CB013101)the National Natural Science Foundation of China(NSFC)(Grants 11225208 and 91226202)+2 种基金support from the key subject "Computational Solid Mechanics" of the China Academy of Engineering Physicsthe support provided by the Shanghai Eastern-Scholar Planby the State Key Laboratory for Mechanical Behavior of Materials
文摘Structure materials under severe irradiations in nuclear environments are known to degrade because of irradiation hardening and loss of ductility,resulting from irradiation-induced defects such as vacancies,interstitials and dislocation loops,etc.In this paper,we develop an elastic-viscoplastic model for irradiated multi-phase polycrystalline BCC materials in which the mechanical behaviors of individual grains and polycrystalline aggregates are both explored.At the microscopic grain scale,we use the internal variable model and propose a new tensorial damage descriptor to represent the geometry character of the defect loop,which facilitates the analysis of the defect loop evolutions and dislocation-defect interactions.At the macroscopic polycrystal scale,the self-consistent scheme is extended to consider the multiphase problem and used to bridge the individual grain behavior to polycrystal properties.Based on the proposed model,we found that the work-hardening coefficient decreases with the increase of irradiation-induced defect loops,and the orientation/loading dependence of mechanical properties is mainly attributed to the different Schmid factors.At the polycrystalline scale,numerical results for pure Fe match well with the irradiation experiment data.The model is further extended to predict the hardening effect of dispersoids in oxide-dispersed strengthened steels by the considering the Orowan bowing.The influences of grain size and irradiation are found to compete to dominate the strengthening behaviors of materials.
基金Project supported by the National Natural Science Foundation of China (No. 10502025)Fok Ying Tong Education Foundation (No.101005)University Foundation of Jiangsu Province (No.05KJB1300421)
文摘To determine the time-independent constitutive modeling for porous and multi- phase nanocrystalline materials and understand the effects of grain size and porosity on their mechanical behavior, each phase was treated as a mixture of grain interior and grain bound- ary, and pores were taken as a single phase, then Budiansky＇s self-consistent method was used to calculate the Young＇s modulus of porous, possible multi-phase, nanocrystalline materials, the prediction being in good agreement with the results in the literature. Further, the established method is extended to simulate the constitutive relations of porous and possible multi-phase nanocrystalline materials with small plastic deformation in conjunction with the secant-moduli approach and iso-strain assumption. Comparisons between the experimental grain size and porosity dependent mechanical data and the corresponding predictions using the established model show that it appears to be capable of describing the time-independent mechanical behaviors for porous and multi-phase nanocrystalline materials in a small plastic strain range. Further discussion on the modification factor, the advantages and limitations of the model developed were present.
基金Supported by National Natural Science Foundation of China (No.10572143) and Joint Project between the Royal Society and the Chinese Academy of Sciences (No.15933).
文摘In this article, principle and mathematical method of determining the phase fractions of multiphase flows by using a dual-energy γ -ray system have been described. The dual-energy γ -ray device is composed of radioactive isotopes of 241Am and 137Cs with γ -ray energies of 59.5 and 662 keV, respectively. A rational method to calibrate the absorption coefficient was introduced in detail. The modified arithmetic is beneficial to removing the extra Compton scattering from the measured value. The result shows that the dual-energy γ -ray technique can be used in three-phase flow with average accuracy greater than 95%, which enables us to determine phase fractions almost independent of the flow regime. Improvement has been achieved on measurement accuracy of phase fractions.
基金Item Sponsored by National Basic Research Program of China(2010CB630801)
文摘The deformation and micro-voids formation mechanisms in ferrite / bainite（ F / B） multi-phase steel with the volume fraction of bainite less than 50% were studied by numerical simulation and experimental observation. The results show that the micro-strain concentrates at the soft / hard phase（ F / B） interface in the multi-phase steel,which should be correlated with the mechanism of incoordinate deformation. During the necking of the steel,the micro-voids initially form around the F / B interface,which also form in ferrite and bainite with the severe strain. The micro-voids in bainite are more dense and finer than those in ferrite. The failure mechanism of bainite is the coalescence of micro-voids,and the failure mechanism of ferrite is the growth and tearing of micro-voids. Due to the different failure mechanisms of ferrite and bainite,a suitable part of soft phase would be beneficial to the capability of anti-failure of F / B multi-phase steel during the ductile fracture.
基金Selected from Proceedings of the 7th International Conference on Frontiers of DesignManufacturing(ICFDM'2006)This project is supported by National Natural Science Foundation of China(No.50275086)the University of New South Wales Visiting Professorship Scheme,Australia.
文摘An advanced ceramic cutting tool material Al2O3/TiC/TiN （LTN） is developed by incorporation and dispersion of micro-scale TiC particle and nano-scale TiN particle in alumina matrix. With the optimal dispersing and fabricating technology, this multi-scale and multi-phase nanocomposite ceramic tool material can get both higher flexural strength and fracture toughness than that of A1203/TiC （LZ） ceramic tool material without nano-scale TiN particle, especially the fracture toughness can reach to 7.8 MPa . m^0.5. The nano-scale TiN can lead to the grain fining effect and promote the sintering process to get a higher density. The coexisting transgranular and intergranular fracture mode induced by micro-scale TiC and nano-scale TiN, and the homogeneous and densified microstructure can result in a remarkable strengthening and toughening effect. The cutting performance and wear mechanisms of the advanced multi-scale and multi-phase nanocomposite ceramic cutting tool are researched.
文摘In this paper, a finite element method （FEM）-based multi-phase problem based on a newly proposed thermal elastoplastic constitutive model for saturated/unsaturated geomaterial is discussed. A program of FEM named as SOFT, adopting unified field equations for thermo-hydro-mechanical-air （THMA） behavior of geomaterial and using finite element-finite difference （FE-FD） scheme for so/l-water-air three-phase coupling problem, is used in the numerical simulation. As an application of the newly proposed numerical method, two engineering problems, one for slope failure in unsaturated model ground and another for in situ heating test related to deep geological repository of high-level radioactive waste （HLRW）, are simulated. The model tests on slope failure in unsaturated Shirasu ground, carried out by Kitamura et al. （2007）, is simulated in the framework of soil-water-air three-phase coupling under the condition of constant temperature. While the in situ heating test reported by Munoz （2006） is simulated in the same framework under the conditions of variable temperature hut constant air pressure.
基金the partial support of this work by Shahid Chamran Research Council
文摘A highly effective and mild protocol for ring opening of epoxides with NH4SCN in the presence of catalytic amount of a multi- site phase-transfer catalyst, α,α＇,α＂-N-hexakis（triethylammoniummethylene chloride）-melamine, is developed. A variety of ^-hydroxy thiocyanates as important intermediates in agricultural and pharmaceutical chemistry were obtained in high yields with excellent regioselectivity and in short reaction times. 2009 Ali Reza Kiasat. Published by Elsevier B.V. on behalf of Chinese Chemical Society. All rights reserved.
文摘In this article, a physics aware deep learning model is introduced for multiphase flow problems. The deep learning model is shown to be capable of capturing complex physics phenomena such as saturation front, which is even challenging for numerical solvers due to the instability. We display the preciseness of the solution domain delivered by deep learning models and the low cost of deploying this model for complex physics problems, showing the versatile character of this method and bringing it to new areas. This will require more allocation points and more careful design of the deep learning model architectures and residual neural network can be a potential candidate.
基金supported by the National Natural Science Foundation of China(4120147961261033+2 种基金61461011)the Guangxi Natural Science Foundation(2014GXNSFBA118273)the Dean Project of Guangxi Key Laboratory of Wireless Broadband Communication and Signal Processing(GXKL061503)
文摘This paper presents an enhanced multi-baseline phase unwrapping algorithm by combining an unscented Kalman filter with an enhanced joint phase gradient estimator based on the amended matrix pencil model, and an optimal path-following strategy based on phase quality estimate function. The enhanced joint phase gradient estimator can accurately and effectively extract the phase gradient information of wrapped pixels from noisy interferograms, which greatly increases the performances of the proposed method. The optimal path-following strategy ensures that the proposed algorithm simultaneously performs noise suppression and phase unwrapping along the pixels with high-reliance to the pixels with low-reliance. Accordingly, the proposed algorithm can be predicted to obtain better results, with respect to some other algorithms, as will be demonstrated by the results obtained from synthetic data.
基金financially supported by the Research Grant Council(RGC),the Hong Kong Government,through the General Research Fund(GRF)under the project number CityU/521411,with City University ofHong Kong
文摘Alloying greatly expands the amount of available materials beyond the naturally existing ones, and more importantly offers the material scientists opportunities to initiatively control the composition-structure-property relationship in materials. Since commonly used metallic materials are mostly multi-component alloys, the know-how of alloying through compositional control, certainly plays a critical role in designing materials with desired structure and properties. However, alloying in multi-component alloys is an extremely complicated issue, as the alloyed products could be the amorphous phase, various solid solutions and intermetallic compounds containing two or more alloy components. By narrowing down the scope of the multi-component alloys to those with equiatomic or close-to-equiatomic compositions only, and also aiming at framing out the rules that govern the phase selection upon alloying in multi-component alloys in a broad sense, we have identified here a simple and easily executable two-parameter scheme that can effectively predict the formation of the amorphous phase, solid solutions and intermetallic compounds, in multi-component alloys, simply from the given alloy compositions. We believe this scheme reveals a clear physical scenario governing the phase selection in multi-component alloys, helps to simplify the alloy design, and benefits the future development of advanced metallic alloys like bulk metallic glasses and high entropy alloys.
