The effects of liquid-solid ratio and reaction time on the leaching rate of magnesium at room temperature were investigated,as well as the effects of the molar ratio of MgO/MgCl_(2),the amount of water added,and the a...The effects of liquid-solid ratio and reaction time on the leaching rate of magnesium at room temperature were investigated,as well as the effects of the molar ratio of MgO/MgCl_(2),the amount of water added,and the amount of acid-impregnated slag dosed on the compressive strength and water resistance of LR-MOC.The results showed that the magnesium element in the boron mud could be maximally leached under the conditions of 1:1 concentration of hydrochloric acid at room temperature,liquid-solid ratio of 2.5 mL·g^(-1),and reaction time of 5 h,and the main products were amorphous SiO_(2) as well as a small amount of magnesium olivine which had not been completely reacted.The LR-MOC prepared using the acid-soaked mixture could reach a softening coefficient of 0.85 for 28 d of water immersion when the molar ratio of MgO/MgCl_(2) was 2.2,the amount of water added was 0 g,and the acid-soaked slag dosing was 40 wt%,which also led to an appreciable late-strength,with an increase of 19.4%in compressive strength at 28 d compared to that at 7 d.Unlike previous studies,LR-MOC prepared in this way has a final strength phase that is not the more easily hydrolysed 3-phase but the lath-like 5-phase.For this phenomenon,we analyzed the mechanism and found that,during the acid leaching process,a part of amorphous SiO_(2) dissolved in the acid leaching solution formed a silica sol,in which Mg^(2+)played a bridging role to make the silica sol more stable.With the addition and hydrolysis of MgO,the silica sol gel coagulation slows down,providing a capping layer to inhibit the hydrolysis of the 5-phase crystals and providing some strength after coagulation.The amorphous SiO_(2) in the other part of the acid-impregnated slag generated M-S-H gel with Mg^(2+)and OH-,which synergised with the dense structure composed of interlocking crystals to improve the water resistance of LR-MOC.展开更多
Mercury removal from coal combustion flue gas remains a significant challenge for environmental protection due to the lack of cost-effective sorbents.In this study,a series of red mud(RM)-based sorbents impregnated wi...Mercury removal from coal combustion flue gas remains a significant challenge for environmental protection due to the lack of cost-effective sorbents.In this study,a series of red mud(RM)-based sorbents impregnated with sodium halides(NaBr and NaI)are presented to capture elemental mercury(Hg^(0))from flue gas.The modified RM underwent comprehensive characterization,including analysis of its textural qualities,crystal structure,chemical composition,and thermal properties.The results indicate that the halide impregnation substantially impacts the surface area and pore size of the RM.Hg^(0) removal performance was evaluated on a fixed-bed reactor in simulated flue gas(consisting of N_(2),O_(2),CO_(2),NO and SO_(2),etc.)on a modified RM.At an optimal adsorption temperature of 160℃,NaI-modified sorbent(RMI5)offers a removal efficiency of 98%in a mixture of gas,including O_(2),NO and HCl.Furthermore,pseudo-second-order model fitting results demonstrate the chemisorption mechanism for the adsorption of Hg^(0) in kinetic investigations.展开更多
The evaluation of permeability in reservoir assessment is a complex problem. Thus, it is difficult to perform direct evaluation permeability with conventional well-logging methods. Considering that reservoir permeabil...The evaluation of permeability in reservoir assessment is a complex problem. Thus, it is difficult to perform direct evaluation permeability with conventional well-logging methods. Considering that reservoir permeability significantly affects mud invasion during drilling, we derive a mathematical model to assess the reservoir permeability based on mud invasion. A numerical model is first used to simulate the process of mud invasion and mud cake growth. Then, based on Darcy＇s law, an approximation is derived to associate the depth of mud invasion with reservoir permeability. A mathematical model is constructed to evaluate the reservoir permeability as a function of the mud invasion depth in time-lapse logging. Sensitivity analyses of the reservoir porosity, permeability, and water saturation are performed, and the results suggest that the proposed model and method are well suited for oil layers or oil-water layers of low porosity and low permeability. Numerical simulations using field logging and coring data suggest that the evaluated and assumed permeability data agree, validating the proposed model and method.展开更多
Reclamation of tidal flat is one of the main ways to get a dynamic balance of the total amount of plowland. With the development of social economy and the increasing demand for plowland, the contradiction between tida...Reclamation of tidal flat is one of the main ways to get a dynamic balance of the total amount of plowland. With the development of social economy and the increasing demand for plowland, the contradiction between tidal flat reclamation and environment protection becomes more and more outstanding. However, tidal flat reclamation should also follow the dynamic balance of total amount of tidal flat amount. The paper analyzed the history of reclamation and development of Jiangsu mud coast, and calculated the feasible rates of tidal flat reclamation on different stretches respectively, and pointed out that both the economic social benefits of reclamation and the natural erosion-accretion conditions of the coasts should be taken into consideration in deciding the intensity of tidal flat reclamation, so as to satisfy demands on both reclamation and protection of tidal flat resource.展开更多
The phenomenon of mud volcanism has a connection with the processes of hydrocarbon generation.However,the genesis of sediments is not often taken into consideration.The study of mud volcanoes in the West Kuban margina...The phenomenon of mud volcanism has a connection with the processes of hydrocarbon generation.However,the genesis of sediments is not often taken into consideration.The study of mud volcanoes in the West Kuban marginal marine basin and the Junggar freshwater basin revealed significant isotope-geochemical differences due to various types of sedimentation.The waters from both basins exhibit three principal geochemical facies:Na-HCO_(3),Na-Cl-HCO_(3),and Na-Cl,of which the latter type of water is the dominant.The analysis of genetic coefficients(Cl/Br,Na/Br,and B/Cl)allowed us to distinguish different pathways of mud volcanic water evolution:evaporite dissolution,formation(sedimentation)waters,and waters formed by active water-rock interaction.Through statistical research,we were able to determine that noticeable variations in the behavior of chemical elements in waters from different areas can reflect discrepancies in the geological environment and the evolutionary stage of the diagenetic water transformation.Using thermodynamic modeling,the main directions of mass transfer were shown.It was established that the waters of the Junggar Basin were at a relatively early stage of evolution and had reached equilibrium only with carbonates,while in the formation waters of the West Kuban Basin,element concentrations were also controlled by silicate minerals.The correlations betweenδ^(18)O andδ~2H values and saturation indices of halides,aluminosilicates,sulfates,and borates confirm the enrichment of water with heavy isotopes during interactions with rocks without evaporation or thermal water partition.These reactions are characterized by clay dehydration and water enrichment with^(18)O and B.The data obtained made it possible to clarify the depths of formation of mud-volcanic fluids and their possible stratigraphic sources.展开更多
Red mud(RM) is an industrial solid waste produced during the extraction of alumina from bauxite.The strong alkaline and heavy metal leaching issues are the primary factors limiting its utilization.This paper proposes ...Red mud(RM) is an industrial solid waste produced during the extraction of alumina from bauxite.The strong alkaline and heavy metal leaching issues are the primary factors limiting its utilization.This paper proposes a method for dealkalization and chromium(Cr) removal by repeated freeze and thaw to enhance the comprehensive utilization rate of RM.This study focused on the Bayer RM and investigated the effects of freeze-thaw(FT)-acid washing(AW) for dealkalization and Cr removal.The variables were the eluent concentration and FT cycles.The results showed that the synergistic action of FT-AW significantly improved the efficiency of dealkalization and Cr removal.After five FT cycles with 0.5 mol/L oxalic acid,the dealkalization and Cr removal rates reached 97.5% and 65.38%,respectively,16.1% and 7.40% higher than those achieved at room temperature.The repeated FT disrupted the structure of the RM particles,leading to an increase in the pore space between the soil particles.This enables complete eluent contact and reaction with Cr and alkali,thereby enhancing the removal rate.The FT-AW process is suitable for practical engineering applications.It offers a novel method for RM dealkalization and Cr removal by using the FT alternation phenomena in seasonally frozen regions.展开更多
Red mud(RM)is a solid waste generated in the aluminum industry after the extraction of alumina oxide;its multiple elements and higher pH value likely pose a severe threat to the environment after treatment.However,RM&...Red mud(RM)is a solid waste generated in the aluminum industry after the extraction of alumina oxide;its multiple elements and higher pH value likely pose a severe threat to the environment after treatment.However,RM's higher concentrations of metal components,particularly Fe_(2)O_(3)and rare earth elements(REEs),render RM promising for catalytic application.Hence,this work showed an efficient high-speed RM to catalyze electrocatalytic nitrate-to-ammonia reduction reaction(NARR).RM calcined at 500℃(RM-500)exhibited excellent catalytic performance.Faradaic efficiency of ammonia(FENH_(3))in an electrolyte solution containing 1 mol·L^(-1)NO_(3)-achieved a maximum value of 92.3%at-0.8 V(vs.RHE).Additionally,24-h cycle testing and post-reaction PXRD and SEM indicated that the RM-500 electrocatalyst is stable during NARR.The RM-500 demonstrated a high FE of NH_(3)-to-NO_(3)-of 89.7%at 1.85 V(vs.RHE),showing great potential in the ammonia fuel cells technology and achieving the nitrogen cycle.展开更多
The large-scale accumulation of industrial solid waste,including red mud and coal gangue,coupled with goafs left by under-ground mining activities,poses significant challenges to sustainable human development.In this ...The large-scale accumulation of industrial solid waste,including red mud and coal gangue,coupled with goafs left by under-ground mining activities,poses significant challenges to sustainable human development.In this study,red mud,coal gangue,and othersolid wastes were used to prepare underground backfilling materials.The utilization rate of the total solid waste reached 95%,with redmud accounting for approximately 40wt% of the total.The unconfined compressive strength,setting time,and slump tests were conduc-ted to evaluate the mechanical properties of the material.At the optimal ratio,the 7-and 28-d strengths reach 4.4 and 6.9 MPa,respect-ively.The initial and final setting times were 200 and 250 min,respectively,whereas the initial and 1-h slump exceed 250 and 210 mm,respectively.X-ray diffraction(XRD),Fourier-transform infrared spectroscopy(FTIR),and scanning electron microscopy(SEM)wereemployed to explore the microstructure,phase composition,and chemical bonding within the material.Needle-like,clustered,and granu-lar hydration products were observed,and the primary crystalline structures were identified as ettringite,gmelinite,C-A-S-H,andC-S-H.In addition,a thorough environmental risk assessment was conducted,complemented by detailed economic cost and carbonemission calculations.During the creation of backfill material,hazardous elements from solid waste are immobilized through adsorption,precipitation,and incorporation into the crystal lattice.The immobilization efficiencies for Ni,Al,Cr^(6+),and As were 97.03%,94.32%,86.43%,and 84.22%,respectively,at a pH of 8.49.Moreover,the use of solid waste as a raw material results in considerable cost savingsand marked reduction in carbon emissions.This study innovatively promotes the green cycle of alumina production in the bauxite miningindustry.展开更多
The release of accumulated stress through earthquakes is known to devote to the mud volcanism occurrence,which may in turn affect subsequent regional seismicity.Mud volcanoes have been observed on the northeast contin...The release of accumulated stress through earthquakes is known to devote to the mud volcanism occurrence,which may in turn affect subsequent regional seismicity.Mud volcanoes have been observed on the northeast continental margin of the South China Sea as well.Based on the mud volcanoes and earthquakes catalogue,we measured the spatial and temporal distribution of z and b values,to explore the geodynamic process of the repeated eruptions of mud volcanoes influence on the regional seismicity.The results suggest a close correlation between the b-z values and mud volcanism occurrence in the SW Taiwan.Generally,the z-value anomalies in where the mud volcanoes eruptions show unchanged negative values and indicate seismic quiescence before a big earthquake,whereas the b-values often show periodicity fluctuations around the value of 0.5.This may indicate a mutual triggering relationship between the mud volcanoes and earthquakes.We infer that mud volcano eruptions help to partition and release part of the regional stress accumulation from the seismogenic structures,thus balancing the local stress and mitigating large-magnitude seismicity occurring probability.展开更多
The oil-based mud(OBM) borehole measurement environment presents significant limitations on the application of existing electrical logging instruments in high-resistance formations. In this paper, we propose a novel l...The oil-based mud(OBM) borehole measurement environment presents significant limitations on the application of existing electrical logging instruments in high-resistance formations. In this paper, we propose a novel logging method for detection of high-resistance formations in OBM using highfrequency electrodes. The method addresses the issue of shallow depth of investigation(DOI) in existing electrical logging instruments, while simultaneously ensuring the vertical resolution. Based on the principle of current continuity, the total impedance of the loop is obtained by equating the measurement loop to the series form of a capacitively coupled circuit. and its validity is verified in a homogeneous formation model and a radial two-layer formation model with a mud standoff. Then, the instrument operating frequency and electrode system parameters were preferentially determined by numerical simulation, and the effect of mud gap on impedance measurement was investigated. Subsequently, the DOI of the instrument was investigated utilizing the pseudo-geometric factor defined by the real part of impedance. It was determined that the detection depth of the instrument is 8.74 cm, while the effective vertical resolution was not less than 2 cm. Finally, a focused high-frequency electrode-type instrument was designed by introducing a pair of focused electrodes, which effectively enhanced the DOI of the instrument and was successfully deployed in the Oklahoma formation model. The simulation results demonstrate that the novel method can achieve a detection depth of 17.40 cm in highly-resistive formations drilling with OBM, which is approximately twice the depth of detection of the existing oil-based mud microimager instruments. Furthermore, its effective vertical resolution remains at or above 2 cm,which is comparable to the resolution of the existing OBM electrical logging instrument.展开更多
Red mud is a kind of industrial waste residue produced in the process of alumina production,which has strong suspension and is difficult to precipitate and filter.This study compared the effects of 4 kinds of filter a...Red mud is a kind of industrial waste residue produced in the process of alumina production,which has strong suspension and is difficult to precipitate and filter.This study compared the effects of 4 kinds of filter aids,including CaCl2,polymerized ferrous sulfate(PFS),steel slag(SS),and Portland cement(PC),on the filtration rate,filter cake moisture content,and Na2O content of red mud slurry.At a dosage of 10 g·L^(-1),the filtration effects were in the following order:PFS>CaCl_(2)>SS>PC.Under the combination of 5 g·L^(-1) SS and 5 g·L^(-1) PC,the better filtration effect was achieved with a filtration time of 205.17 s,which was reduced by 58.52%compared to the original red mud.The combined use of SS and PC exhibits better advantages in terms of cost and filtration effect.This study provides a data foundation for the rapid filtration of red mud slurry.The use of SS and PC as filter aids for red mud holds broad application pro-spects.展开更多
Red mud is a solid waste discharged in the process of alumina production,and how to realize the efficient recovery of its iron is an urgent problem to be solved.In this study,the iron extraction test and mechanism stu...Red mud is a solid waste discharged in the process of alumina production,and how to realize the efficient recovery of its iron is an urgent problem to be solved.In this study,the iron extraction test and mechanism study of high iron red mud were carried out under the coupling conditions of multiple physical field(microwave field,gas-solid flow field and temperature field)with biomass as the reducing agent.The test results showed that under the optimal conditions,an iron concentrate with a yield of 78.4%,an iron grade of 59.23%,and a recovery rate of 86.65%was obtained.The analyses of XRD,XPS,TEM,and SEM-EDS showed that during the roasting process,the hematite in the high-iron red mud was completely converted to magnetite,and the biomass produced the reductant that provided the magnetization reaction;A large number of cracks and pores appeared in the surface of the hematite reduction product particles,which helped to induce iron minerals to undergo effective mineral phase transformation.The above study provides ideas for the phase transformation and efficient recovery of iron minerals in red mud.展开更多
This paper addresses the accuracy and timeliness limitations of traditional comprehensive prediction methods by proposing an approach of decision-level fusion of multisource data.A risk prediction indicator system was...This paper addresses the accuracy and timeliness limitations of traditional comprehensive prediction methods by proposing an approach of decision-level fusion of multisource data.A risk prediction indicator system was established for water and mud inrush in tunnels by analyzing advanced prediction data for specifi c tunnel segments.Additionally,the indicator weights were determined using the analytic hierarchy process combined with the Huber weighting method.Subsequently,a multisource data decision-layer fusion algorithm was utilized to generate fused imaging results for tunnel water and mud inrush risk predictions.Meanwhile,risk analysis was performed for different tunnel sections to achieve spatial and temporal complementarity within the indicator system and optimize redundant information.Finally,model feasibility was validated using the CZ Project Sejila Mountain Tunnel segment as a case study,yielding favorable risk prediction results and enabling effi cient information fusion and support for construction decision-making.展开更多
β-hemihydrate phosphogypsum(HPG)was used to replace a part of cement to prepare hemihydrate phosphogypsum-red mud concrete,effectively increasing the comprehensive use of red mud(RM)and HPG in the concrete.The effect...β-hemihydrate phosphogypsum(HPG)was used to replace a part of cement to prepare hemihydrate phosphogypsum-red mud concrete,effectively increasing the comprehensive use of red mud(RM)and HPG in the concrete.The effects of different RM and HPG contents on the flow properties,water absorption and strengths of HPG-RM concretes were investigated.The appropriate content of HPG reduces the water resistance of red mud concrete,enhances the cohesion and water retention,and effectively filled the pores to decrease the degree of free water erosion.The optimal HPG content was 5%,10%,and 10%for red mud concretes with 30%,40%,and 50%RM,respectively.HPG content has more significant effects on the 28 d strengths of HPG-RM concretes.This consequence is accordant with the effect of HPG content on the pore size and pore size distribution from MIP results.The SEM and XRD results show that a large amount of SO_(4)^(2-)and Ca^(2+)from HPG promote the volcanic ash effect of RM generating more favorable hydration products.However,excessive HPG generates more Ettringite to inhibit the generation of calcium silicate and albite,causing cracks in the concrete and deteriorating performance.展开更多
Subduction zones are critical interfaces for lithospheric volatile fluxes,where complex tectonic and geochemical interactions facilitate the release of gases and fluids from deep-seated reservoirs within the Earth’s ...Subduction zones are critical interfaces for lithospheric volatile fluxes,where complex tectonic and geochemical interactions facilitate the release of gases and fluids from deep-seated reservoirs within the Earth’s crust.Mud volcanism,as a dynamic manifestation of these processes,contributes CH_(4)emissions that influence the global methane budget and impact marine ecosystems.Although∼2000 CH_(4)-rich mud extrusions have been documented in subduction zones globally,the geological origins and subduction-related geochemical and tectonic mechanisms driving these emissions remain poorly understood.This research examines the Makran subduction zone which hosts one of the world’s largest accretionary wedge and extensive CH_(4)-rich mud extrusions,as a model system.Integrated geochemical,geophysical,and geological observations reveal that thermogenic CH_(4)and clay-rich fluidized muds originate from deeply buried Himalayan turbidites(underthrusted sediments),driven by organic-rich sediment maturation and high fluid overpressure.Key tectonic features,including thrust faults,overburden pressure of wedge-top sediments,normal faults,brittle fractures,and seismicity,facilitate CH_(4)-rich mud extrusions into the hydrosphere and atmosphere.The extruded gases are predominantly CH_(4),with minor C_(2)H_(6),C_(3)H_(8),i-C_(4)H_(10),and n-C_(4)H_(10)while the mud breccia exhibits a chemical composition dominated by SiO_(2),Al_(2)O_(3),and Fe_(2)O_(3),enriched with trace elements(Rb,Zr,and V)and clay minerals,quartz,and carbonates.Geochemical indicators suggest intense chemical weathering and mature sediments classifying the mud breccia as litharenite and sub-litharenite,indicative of deep burial and compaction.These findings model the evolution of CH_(4)-rich mud extrusions through three geological stages:(i)Eocene to Early Miocene pre-thermogenic formation of the CH_(4)-rich source,(ii)Middle Miocene to Pliocene syn-thermogenic CH_(4)and fluidized mud generation,and(iii)Pleistocene to Recent post-thermogenic CH_(4)-rich fluidized mud migration.These findings underscore the critical yet often overlooked role of subduction-related geochemical and tectonic processes in CH_(4)generation and emission,with significant implications for the global CH_(4)budget and marine ecosystems.展开更多
In deep drilling applications,such as those for geothermal energy,there are many challenges,such as those related to efficient operation of the drilling fluid(mud)pumping system.Legacy drilling rigs often use paired,p...In deep drilling applications,such as those for geothermal energy,there are many challenges,such as those related to efficient operation of the drilling fluid(mud)pumping system.Legacy drilling rigs often use paired,parallel-connected independent-excitation direct-current(DC)motors for mud pumps,that are supplied by a single power converter.This configuration results in electrical power imbalance,thus reducing its efficiency.This paper investigates this power imbalance issue in such legacy DC mud pump drive systems and offers an innovative solution in the form of a closed-loop control system for electrical load balancing.The paper first analyzes the drilling fluid circulation and electrical drive layout to develop an analytical model that can be used for electrical load balancing and related energy efficiency improvements.Based on this analysis,a feedback control system(so-called“current mirror”control system)is designed to balance the electrical load(i.e.,armature currents)of parallel-connected DC machines by adjusting the excitation current of one of the DC machines,thus mitigating the power imbalance of the electrical drive.Theproposed control systemeffectiveness has been validated,first through simulations,followed by experimental testing on a deep drilling rig during commissioning and field tests.The results demonstrate the practical viability of the proposed“current mirror”control system that can effectively and rather quickly equalize the armature currents of both DC machines in a parallel-connected electrical drive,and thus balance both the electrical and mechanical load of individual DC machines under realistic operating conditions of the mud pump electrical drive.展开更多
A novel adsorbent was prepared from granular red mud mixed with cement and its potential to be a suitable adsorbent for the removal of cadmium ions from aqueous solutions was evaluated. The wet red mud was directly mi...A novel adsorbent was prepared from granular red mud mixed with cement and its potential to be a suitable adsorbent for the removal of cadmium ions from aqueous solutions was evaluated. The wet red mud was directly mixed up with cement at different mass fractions of 2%-8% and their properties were investigated. Based on the textural characteristics and strength, the granular red mud with 2% addition of cement maintaining for 6 d is identified to have better properties. The batch adsorption experiments for adsorption of Cd2+ ions from solution were performed at 30, 40 and 50 °C at different initial concentrations under the condition of constant pH of 6.5. The equilibrium adsorption was found to increase with the increase of temperature during the adsorption process. Langmuir adsorption isotherm model was found to match the experimental adsorption isotherm better. The kinetics of adsorption was modeled using a pseudo second order kinetic model and the model parameters were estimated.展开更多
The recovery of titanium with citric acid in sulfuric acid from red mud was put forward to strengthen acid leaching efficiency.The main factors on the recovery of titanium such as citric acid addition,sulfuric acid co...The recovery of titanium with citric acid in sulfuric acid from red mud was put forward to strengthen acid leaching efficiency.The main factors on the recovery of titanium such as citric acid addition,sulfuric acid concentration,leaching temperature,time and liquid-to-solid ratio were studied.The kinetics analysis of titanium leaching from red mud was deeply investigated.The results show that the citric acid could increase the recovery of titanium and decrease the consumption of sulfuric acid.The recovery of titanium was increased from 65% to 82% and the consumption of sulfuric acid was decreased by about 30% with using 5% citric acid.The dissolution of perovskite,brookite,and hematite in red mud could easily be dissolved using citric acid.The acid leaching process was controlled by internal diffusion of shrinking core model（SCM） and the correlation coefficient was above 0.98.The apparent rate constant was increased from 0.0012 to 0.0019 with 5% citric acid at 90 °C.The apparent activation energy of titanium leaching decreased from 39.77 k J/mol to 34.61 k J/mol with 5% citric acid.展开更多
[Objective] The research aimed to provide basic files and theoretical guidance for constructing sluicing-siltation dam using soil with high clay content soil.[Method] The soils of Dagou basin near Xiwu Village of Bais...[Objective] The research aimed to provide basic files and theoretical guidance for constructing sluicing-siltation dam using soil with high clay content soil.[Method] The soils of Dagou basin near Xiwu Village of Baishui County,Shaanxi Province were taken as experimental materials.pvc pipes with same height and diameter were used to construct testing model for dynamically determining settlement,shear strength,wet density of grouting bulk under 2 different grouting speeds(15 cm/d and 25 cm/d).[Result] Under different grouting speeds,general change trend was similar during grouting course.The subsidence,deformation,shear strength and wet density increased with the increase of grouting speed.Five or six days after grouting,daily displacement under 25 cm/d grouting speed was fewer than that under 15 cm/d grouting speed.[Conclusion] The increase of grouting speed could shorten the time for reaching the same subsidence,deformation,shear strength and wet density and increased displacement at the initial stage of grouting,however,with the increase of grouting time,lower grouting bulk was bad for displacement at later grouting period because it was near impermeable layer.展开更多
基金Funded by Provincial Basic Research Projects(No.LJKMZ20220947)。
文摘The effects of liquid-solid ratio and reaction time on the leaching rate of magnesium at room temperature were investigated,as well as the effects of the molar ratio of MgO/MgCl_(2),the amount of water added,and the amount of acid-impregnated slag dosed on the compressive strength and water resistance of LR-MOC.The results showed that the magnesium element in the boron mud could be maximally leached under the conditions of 1:1 concentration of hydrochloric acid at room temperature,liquid-solid ratio of 2.5 mL·g^(-1),and reaction time of 5 h,and the main products were amorphous SiO_(2) as well as a small amount of magnesium olivine which had not been completely reacted.The LR-MOC prepared using the acid-soaked mixture could reach a softening coefficient of 0.85 for 28 d of water immersion when the molar ratio of MgO/MgCl_(2) was 2.2,the amount of water added was 0 g,and the acid-soaked slag dosing was 40 wt%,which also led to an appreciable late-strength,with an increase of 19.4%in compressive strength at 28 d compared to that at 7 d.Unlike previous studies,LR-MOC prepared in this way has a final strength phase that is not the more easily hydrolysed 3-phase but the lath-like 5-phase.For this phenomenon,we analyzed the mechanism and found that,during the acid leaching process,a part of amorphous SiO_(2) dissolved in the acid leaching solution formed a silica sol,in which Mg^(2+)played a bridging role to make the silica sol more stable.With the addition and hydrolysis of MgO,the silica sol gel coagulation slows down,providing a capping layer to inhibit the hydrolysis of the 5-phase crystals and providing some strength after coagulation.The amorphous SiO_(2) in the other part of the acid-impregnated slag generated M-S-H gel with Mg^(2+)and OH-,which synergised with the dense structure composed of interlocking crystals to improve the water resistance of LR-MOC.
基金supported by the National Natural Science Foundation of China(22278066,21776039)the National Key R&D Program of China(2023YFB4103001)The Fundamental Research Funds for the Central Universities(DUT2021TB03).
文摘Mercury removal from coal combustion flue gas remains a significant challenge for environmental protection due to the lack of cost-effective sorbents.In this study,a series of red mud(RM)-based sorbents impregnated with sodium halides(NaBr and NaI)are presented to capture elemental mercury(Hg^(0))from flue gas.The modified RM underwent comprehensive characterization,including analysis of its textural qualities,crystal structure,chemical composition,and thermal properties.The results indicate that the halide impregnation substantially impacts the surface area and pore size of the RM.Hg^(0) removal performance was evaluated on a fixed-bed reactor in simulated flue gas(consisting of N_(2),O_(2),CO_(2),NO and SO_(2),etc.)on a modified RM.At an optimal adsorption temperature of 160℃,NaI-modified sorbent(RMI5)offers a removal efficiency of 98%in a mixture of gas,including O_(2),NO and HCl.Furthermore,pseudo-second-order model fitting results demonstrate the chemisorption mechanism for the adsorption of Hg^(0) in kinetic investigations.
基金financially supported by the Open Fund(No.PLC201103) of the State Key Laboratory of Oil and Gas Reservoir Geology and Exploration(Chengdu University of Technology)Open Fund(No.PRP/OPEN-1302) of the State Key Laboratory of Petroleum Resources and Prospecting(China University of Petroleum,Beijing)+2 种基金PetroChina Innovation Foundation(No.2015D-5006-0304)National Natural Science Foundation of China(No.41304078)Sinopec Foundation(No.P14136)
文摘The evaluation of permeability in reservoir assessment is a complex problem. Thus, it is difficult to perform direct evaluation permeability with conventional well-logging methods. Considering that reservoir permeability significantly affects mud invasion during drilling, we derive a mathematical model to assess the reservoir permeability based on mud invasion. A numerical model is first used to simulate the process of mud invasion and mud cake growth. Then, based on Darcy＇s law, an approximation is derived to associate the depth of mud invasion with reservoir permeability. A mathematical model is constructed to evaluate the reservoir permeability as a function of the mud invasion depth in time-lapse logging. Sensitivity analyses of the reservoir porosity, permeability, and water saturation are performed, and the results suggest that the proposed model and method are well suited for oil layers or oil-water layers of low porosity and low permeability. Numerical simulations using field logging and coring data suggest that the evaluated and assumed permeability data agree, validating the proposed model and method.
文摘Reclamation of tidal flat is one of the main ways to get a dynamic balance of the total amount of plowland. With the development of social economy and the increasing demand for plowland, the contradiction between tidal flat reclamation and environment protection becomes more and more outstanding. However, tidal flat reclamation should also follow the dynamic balance of total amount of tidal flat amount. The paper analyzed the history of reclamation and development of Jiangsu mud coast, and calculated the feasible rates of tidal flat reclamation on different stretches respectively, and pointed out that both the economic social benefits of reclamation and the natural erosion-accretion conditions of the coasts should be taken into consideration in deciding the intensity of tidal flat reclamation, so as to satisfy demands on both reclamation and protection of tidal flat resource.
基金partly supported by the NSFC-RSF Joint Research project(Nos.42261134534,23-47-00035)funded by the Chinese Academy of Sciences President’s International Fellowship Initiative(Nos.2024VCA0006,2024VCB0013)the National Natural Science Foundation of China(No.42442006)。
文摘The phenomenon of mud volcanism has a connection with the processes of hydrocarbon generation.However,the genesis of sediments is not often taken into consideration.The study of mud volcanoes in the West Kuban marginal marine basin and the Junggar freshwater basin revealed significant isotope-geochemical differences due to various types of sedimentation.The waters from both basins exhibit three principal geochemical facies:Na-HCO_(3),Na-Cl-HCO_(3),and Na-Cl,of which the latter type of water is the dominant.The analysis of genetic coefficients(Cl/Br,Na/Br,and B/Cl)allowed us to distinguish different pathways of mud volcanic water evolution:evaporite dissolution,formation(sedimentation)waters,and waters formed by active water-rock interaction.Through statistical research,we were able to determine that noticeable variations in the behavior of chemical elements in waters from different areas can reflect discrepancies in the geological environment and the evolutionary stage of the diagenetic water transformation.Using thermodynamic modeling,the main directions of mass transfer were shown.It was established that the waters of the Junggar Basin were at a relatively early stage of evolution and had reached equilibrium only with carbonates,while in the formation waters of the West Kuban Basin,element concentrations were also controlled by silicate minerals.The correlations betweenδ^(18)O andδ~2H values and saturation indices of halides,aluminosilicates,sulfates,and borates confirm the enrichment of water with heavy isotopes during interactions with rocks without evaporation or thermal water partition.These reactions are characterized by clay dehydration and water enrichment with^(18)O and B.The data obtained made it possible to clarify the depths of formation of mud-volcanic fluids and their possible stratigraphic sources.
基金supported by the National Natural Science Foundation of China (No. U2004181)State Key Laboratory of Frozen Soil Engineering (No. SKLFSE20191702)+2 种基金the key scientific and technological project of Henan Province (222102320226)Basic research expenses of Henan Polytechnic University (NSFRF230424)the Natural Science Foundation of Henan Province (242300421650)。
文摘Red mud(RM) is an industrial solid waste produced during the extraction of alumina from bauxite.The strong alkaline and heavy metal leaching issues are the primary factors limiting its utilization.This paper proposes a method for dealkalization and chromium(Cr) removal by repeated freeze and thaw to enhance the comprehensive utilization rate of RM.This study focused on the Bayer RM and investigated the effects of freeze-thaw(FT)-acid washing(AW) for dealkalization and Cr removal.The variables were the eluent concentration and FT cycles.The results showed that the synergistic action of FT-AW significantly improved the efficiency of dealkalization and Cr removal.After five FT cycles with 0.5 mol/L oxalic acid,the dealkalization and Cr removal rates reached 97.5% and 65.38%,respectively,16.1% and 7.40% higher than those achieved at room temperature.The repeated FT disrupted the structure of the RM particles,leading to an increase in the pore space between the soil particles.This enables complete eluent contact and reaction with Cr and alkali,thereby enhancing the removal rate.The FT-AW process is suitable for practical engineering applications.It offers a novel method for RM dealkalization and Cr removal by using the FT alternation phenomena in seasonally frozen regions.
基金supported by grants from the National Natural Science Foundation of China (22178339)2023 Innovation-driven Development Special Foundation of Guangxi(AA23023021)the Hundred Talents Program (A) of the Chinese Academy of Sciences
文摘Red mud(RM)is a solid waste generated in the aluminum industry after the extraction of alumina oxide;its multiple elements and higher pH value likely pose a severe threat to the environment after treatment.However,RM's higher concentrations of metal components,particularly Fe_(2)O_(3)and rare earth elements(REEs),render RM promising for catalytic application.Hence,this work showed an efficient high-speed RM to catalyze electrocatalytic nitrate-to-ammonia reduction reaction(NARR).RM calcined at 500℃(RM-500)exhibited excellent catalytic performance.Faradaic efficiency of ammonia(FENH_(3))in an electrolyte solution containing 1 mol·L^(-1)NO_(3)-achieved a maximum value of 92.3%at-0.8 V(vs.RHE).Additionally,24-h cycle testing and post-reaction PXRD and SEM indicated that the RM-500 electrocatalyst is stable during NARR.The RM-500 demonstrated a high FE of NH_(3)-to-NO_(3)-of 89.7%at 1.85 V(vs.RHE),showing great potential in the ammonia fuel cells technology and achieving the nitrogen cycle.
基金financially supported by the National Nature Science Foundation of China(No.U23A20557)the Young Elite Scientists Sponsorship Program by China Association for Science and Technology(No.2022QNRC001)Fundamental Research Funds for the Central Universities,China(No.00007720)。
文摘The large-scale accumulation of industrial solid waste,including red mud and coal gangue,coupled with goafs left by under-ground mining activities,poses significant challenges to sustainable human development.In this study,red mud,coal gangue,and othersolid wastes were used to prepare underground backfilling materials.The utilization rate of the total solid waste reached 95%,with redmud accounting for approximately 40wt% of the total.The unconfined compressive strength,setting time,and slump tests were conduc-ted to evaluate the mechanical properties of the material.At the optimal ratio,the 7-and 28-d strengths reach 4.4 and 6.9 MPa,respect-ively.The initial and final setting times were 200 and 250 min,respectively,whereas the initial and 1-h slump exceed 250 and 210 mm,respectively.X-ray diffraction(XRD),Fourier-transform infrared spectroscopy(FTIR),and scanning electron microscopy(SEM)wereemployed to explore the microstructure,phase composition,and chemical bonding within the material.Needle-like,clustered,and granu-lar hydration products were observed,and the primary crystalline structures were identified as ettringite,gmelinite,C-A-S-H,andC-S-H.In addition,a thorough environmental risk assessment was conducted,complemented by detailed economic cost and carbonemission calculations.During the creation of backfill material,hazardous elements from solid waste are immobilized through adsorption,precipitation,and incorporation into the crystal lattice.The immobilization efficiencies for Ni,Al,Cr^(6+),and As were 97.03%,94.32%,86.43%,and 84.22%,respectively,at a pH of 8.49.Moreover,the use of solid waste as a raw material results in considerable cost savingsand marked reduction in carbon emissions.This study innovatively promotes the green cycle of alumina production in the bauxite miningindustry.
基金supported by the Southern Marine Science and Engineering Guangdong Laboratory(Zhuhai)(No.SML2021SP318)the National Postdoctoral Program for Innovative Talents(No.BX20190391)+1 种基金the Guangdong Province Introduced Innovative R&D Team of Geological Processes and Natural Disasters around the South China Sea founded by the Science and Technology Department of Guangdong Province(No.2016ZT06N331)the Guangdong Basic and Applied Basic Research Foundation(Nos.2019A1515110305,2021A1515011130,2021A1515110288)。
文摘The release of accumulated stress through earthquakes is known to devote to the mud volcanism occurrence,which may in turn affect subsequent regional seismicity.Mud volcanoes have been observed on the northeast continental margin of the South China Sea as well.Based on the mud volcanoes and earthquakes catalogue,we measured the spatial and temporal distribution of z and b values,to explore the geodynamic process of the repeated eruptions of mud volcanoes influence on the regional seismicity.The results suggest a close correlation between the b-z values and mud volcanism occurrence in the SW Taiwan.Generally,the z-value anomalies in where the mud volcanoes eruptions show unchanged negative values and indicate seismic quiescence before a big earthquake,whereas the b-values often show periodicity fluctuations around the value of 0.5.This may indicate a mutual triggering relationship between the mud volcanoes and earthquakes.We infer that mud volcano eruptions help to partition and release part of the regional stress accumulation from the seismogenic structures,thus balancing the local stress and mitigating large-magnitude seismicity occurring probability.
基金the National Natural Science Foundation of China(42074134,42474152,42374150)CNPC Innovation Found(2024DQ02-0152).
文摘The oil-based mud(OBM) borehole measurement environment presents significant limitations on the application of existing electrical logging instruments in high-resistance formations. In this paper, we propose a novel logging method for detection of high-resistance formations in OBM using highfrequency electrodes. The method addresses the issue of shallow depth of investigation(DOI) in existing electrical logging instruments, while simultaneously ensuring the vertical resolution. Based on the principle of current continuity, the total impedance of the loop is obtained by equating the measurement loop to the series form of a capacitively coupled circuit. and its validity is verified in a homogeneous formation model and a radial two-layer formation model with a mud standoff. Then, the instrument operating frequency and electrode system parameters were preferentially determined by numerical simulation, and the effect of mud gap on impedance measurement was investigated. Subsequently, the DOI of the instrument was investigated utilizing the pseudo-geometric factor defined by the real part of impedance. It was determined that the detection depth of the instrument is 8.74 cm, while the effective vertical resolution was not less than 2 cm. Finally, a focused high-frequency electrode-type instrument was designed by introducing a pair of focused electrodes, which effectively enhanced the DOI of the instrument and was successfully deployed in the Oklahoma formation model. The simulation results demonstrate that the novel method can achieve a detection depth of 17.40 cm in highly-resistive formations drilling with OBM, which is approximately twice the depth of detection of the existing oil-based mud microimager instruments. Furthermore, its effective vertical resolution remains at or above 2 cm,which is comparable to the resolution of the existing OBM electrical logging instrument.
基金supported by the Science and Technology Innovation Program of Hunan Province,China(No.2023RC3053)the National Key Research and Development Program of China(No.2023YFC3904201)the National Natural Science Foundation of China(No.52004343).
文摘Red mud is a kind of industrial waste residue produced in the process of alumina production,which has strong suspension and is difficult to precipitate and filter.This study compared the effects of 4 kinds of filter aids,including CaCl2,polymerized ferrous sulfate(PFS),steel slag(SS),and Portland cement(PC),on the filtration rate,filter cake moisture content,and Na2O content of red mud slurry.At a dosage of 10 g·L^(-1),the filtration effects were in the following order:PFS>CaCl_(2)>SS>PC.Under the combination of 5 g·L^(-1) SS and 5 g·L^(-1) PC,the better filtration effect was achieved with a filtration time of 205.17 s,which was reduced by 58.52%compared to the original red mud.The combined use of SS and PC exhibits better advantages in terms of cost and filtration effect.This study provides a data foundation for the rapid filtration of red mud slurry.The use of SS and PC as filter aids for red mud holds broad application pro-spects.
基金Project(MMCS2023OF02)supported by the Open Foundation of State Key Laboratory of Featured Metal Materials and Life-cycle Safety for Composite Structures,ChinaProject(AA23073018)supported by the Guangxi Science and Technology,ChinaProject(2024M751861)supported by the China Postdoctoral Science Foundation。
文摘Red mud is a solid waste discharged in the process of alumina production,and how to realize the efficient recovery of its iron is an urgent problem to be solved.In this study,the iron extraction test and mechanism study of high iron red mud were carried out under the coupling conditions of multiple physical field(microwave field,gas-solid flow field and temperature field)with biomass as the reducing agent.The test results showed that under the optimal conditions,an iron concentrate with a yield of 78.4%,an iron grade of 59.23%,and a recovery rate of 86.65%was obtained.The analyses of XRD,XPS,TEM,and SEM-EDS showed that during the roasting process,the hematite in the high-iron red mud was completely converted to magnetite,and the biomass produced the reductant that provided the magnetization reaction;A large number of cracks and pores appeared in the surface of the hematite reduction product particles,which helped to induce iron minerals to undergo effective mineral phase transformation.The above study provides ideas for the phase transformation and efficient recovery of iron minerals in red mud.
基金supported by the National Natural Science Foundation of China (grant numbers 42293351, and U2468221)。
文摘This paper addresses the accuracy and timeliness limitations of traditional comprehensive prediction methods by proposing an approach of decision-level fusion of multisource data.A risk prediction indicator system was established for water and mud inrush in tunnels by analyzing advanced prediction data for specifi c tunnel segments.Additionally,the indicator weights were determined using the analytic hierarchy process combined with the Huber weighting method.Subsequently,a multisource data decision-layer fusion algorithm was utilized to generate fused imaging results for tunnel water and mud inrush risk predictions.Meanwhile,risk analysis was performed for different tunnel sections to achieve spatial and temporal complementarity within the indicator system and optimize redundant information.Finally,model feasibility was validated using the CZ Project Sejila Mountain Tunnel segment as a case study,yielding favorable risk prediction results and enabling effi cient information fusion and support for construction decision-making.
基金Funded by the National Natural Science Foundation of China(Nos.52168027 and 12362011)the Guizhou Province Science and Technology Innovation Talent Team Project(No.CXTD[2023]022)the Guizhou Province Science and Technology Support Project(No.[2022]027)。
文摘β-hemihydrate phosphogypsum(HPG)was used to replace a part of cement to prepare hemihydrate phosphogypsum-red mud concrete,effectively increasing the comprehensive use of red mud(RM)and HPG in the concrete.The effects of different RM and HPG contents on the flow properties,water absorption and strengths of HPG-RM concretes were investigated.The appropriate content of HPG reduces the water resistance of red mud concrete,enhances the cohesion and water retention,and effectively filled the pores to decrease the degree of free water erosion.The optimal HPG content was 5%,10%,and 10%for red mud concretes with 30%,40%,and 50%RM,respectively.HPG content has more significant effects on the 28 d strengths of HPG-RM concretes.This consequence is accordant with the effect of HPG content on the pore size and pore size distribution from MIP results.The SEM and XRD results show that a large amount of SO_(4)^(2-)and Ca^(2+)from HPG promote the volcanic ash effect of RM generating more favorable hydration products.However,excessive HPG generates more Ettringite to inhibit the generation of calcium silicate and albite,causing cracks in the concrete and deteriorating performance.
基金funded by the National Natural Science Foundation of China(Grants No.92058213 and No.U22A20581)the Specific Research Fund of the Innovation Platform for Academicians of Hainan Province(Grant No.YSPTZX202204)key R&D projects of Hainan Province(ZDYF2024GXJS022).
文摘Subduction zones are critical interfaces for lithospheric volatile fluxes,where complex tectonic and geochemical interactions facilitate the release of gases and fluids from deep-seated reservoirs within the Earth’s crust.Mud volcanism,as a dynamic manifestation of these processes,contributes CH_(4)emissions that influence the global methane budget and impact marine ecosystems.Although∼2000 CH_(4)-rich mud extrusions have been documented in subduction zones globally,the geological origins and subduction-related geochemical and tectonic mechanisms driving these emissions remain poorly understood.This research examines the Makran subduction zone which hosts one of the world’s largest accretionary wedge and extensive CH_(4)-rich mud extrusions,as a model system.Integrated geochemical,geophysical,and geological observations reveal that thermogenic CH_(4)and clay-rich fluidized muds originate from deeply buried Himalayan turbidites(underthrusted sediments),driven by organic-rich sediment maturation and high fluid overpressure.Key tectonic features,including thrust faults,overburden pressure of wedge-top sediments,normal faults,brittle fractures,and seismicity,facilitate CH_(4)-rich mud extrusions into the hydrosphere and atmosphere.The extruded gases are predominantly CH_(4),with minor C_(2)H_(6),C_(3)H_(8),i-C_(4)H_(10),and n-C_(4)H_(10)while the mud breccia exhibits a chemical composition dominated by SiO_(2),Al_(2)O_(3),and Fe_(2)O_(3),enriched with trace elements(Rb,Zr,and V)and clay minerals,quartz,and carbonates.Geochemical indicators suggest intense chemical weathering and mature sediments classifying the mud breccia as litharenite and sub-litharenite,indicative of deep burial and compaction.These findings model the evolution of CH_(4)-rich mud extrusions through three geological stages:(i)Eocene to Early Miocene pre-thermogenic formation of the CH_(4)-rich source,(ii)Middle Miocene to Pliocene syn-thermogenic CH_(4)and fluidized mud generation,and(iii)Pleistocene to Recent post-thermogenic CH_(4)-rich fluidized mud migration.These findings underscore the critical yet often overlooked role of subduction-related geochemical and tectonic processes in CH_(4)generation and emission,with significant implications for the global CH_(4)budget and marine ecosystems.
文摘In deep drilling applications,such as those for geothermal energy,there are many challenges,such as those related to efficient operation of the drilling fluid(mud)pumping system.Legacy drilling rigs often use paired,parallel-connected independent-excitation direct-current(DC)motors for mud pumps,that are supplied by a single power converter.This configuration results in electrical power imbalance,thus reducing its efficiency.This paper investigates this power imbalance issue in such legacy DC mud pump drive systems and offers an innovative solution in the form of a closed-loop control system for electrical load balancing.The paper first analyzes the drilling fluid circulation and electrical drive layout to develop an analytical model that can be used for electrical load balancing and related energy efficiency improvements.Based on this analysis,a feedback control system(so-called“current mirror”control system)is designed to balance the electrical load(i.e.,armature currents)of parallel-connected DC machines by adjusting the excitation current of one of the DC machines,thus mitigating the power imbalance of the electrical drive.Theproposed control systemeffectiveness has been validated,first through simulations,followed by experimental testing on a deep drilling rig during commissioning and field tests.The results demonstrate the practical viability of the proposed“current mirror”control system that can effectively and rather quickly equalize the armature currents of both DC machines in a parallel-connected electrical drive,and thus balance both the electrical and mechanical load of individual DC machines under realistic operating conditions of the mud pump electrical drive.
基金Project (51264022) supported by the National Natural Science Foundation of China
文摘A novel adsorbent was prepared from granular red mud mixed with cement and its potential to be a suitable adsorbent for the removal of cadmium ions from aqueous solutions was evaluated. The wet red mud was directly mixed up with cement at different mass fractions of 2%-8% and their properties were investigated. Based on the textural characteristics and strength, the granular red mud with 2% addition of cement maintaining for 6 d is identified to have better properties. The batch adsorption experiments for adsorption of Cd2+ ions from solution were performed at 30, 40 and 50 °C at different initial concentrations under the condition of constant pH of 6.5. The equilibrium adsorption was found to increase with the increase of temperature during the adsorption process. Langmuir adsorption isotherm model was found to match the experimental adsorption isotherm better. The kinetics of adsorption was modeled using a pseudo second order kinetic model and the model parameters were estimated.
基金Project(B2014-012)supported by the Doctoral Foundation from Henan Polytechnic University,China
文摘The recovery of titanium with citric acid in sulfuric acid from red mud was put forward to strengthen acid leaching efficiency.The main factors on the recovery of titanium such as citric acid addition,sulfuric acid concentration,leaching temperature,time and liquid-to-solid ratio were studied.The kinetics analysis of titanium leaching from red mud was deeply investigated.The results show that the citric acid could increase the recovery of titanium and decrease the consumption of sulfuric acid.The recovery of titanium was increased from 65% to 82% and the consumption of sulfuric acid was decreased by about 30% with using 5% citric acid.The dissolution of perovskite,brookite,and hematite in red mud could easily be dissolved using citric acid.The acid leaching process was controlled by internal diffusion of shrinking core model（SCM） and the correlation coefficient was above 0.98.The apparent rate constant was increased from 0.0012 to 0.0019 with 5% citric acid at 90 °C.The apparent activation energy of titanium leaching decreased from 39.77 k J/mol to 34.61 k J/mol with 5% citric acid.
基金Supported by National Key Technology R&D Program(2006BAD09)Program for Science and Technology Innovative of Northwest A&F UniversityWarping Dam Management Fund of Department of Water and Soil Conservation~~
文摘[Objective] The research aimed to provide basic files and theoretical guidance for constructing sluicing-siltation dam using soil with high clay content soil.[Method] The soils of Dagou basin near Xiwu Village of Baishui County,Shaanxi Province were taken as experimental materials.pvc pipes with same height and diameter were used to construct testing model for dynamically determining settlement,shear strength,wet density of grouting bulk under 2 different grouting speeds(15 cm/d and 25 cm/d).[Result] Under different grouting speeds,general change trend was similar during grouting course.The subsidence,deformation,shear strength and wet density increased with the increase of grouting speed.Five or six days after grouting,daily displacement under 25 cm/d grouting speed was fewer than that under 15 cm/d grouting speed.[Conclusion] The increase of grouting speed could shorten the time for reaching the same subsidence,deformation,shear strength and wet density and increased displacement at the initial stage of grouting,however,with the increase of grouting time,lower grouting bulk was bad for displacement at later grouting period because it was near impermeable layer.
