In this study,we established a simple colorimetric method for visual detection of chromium(Ⅲ)ions using aggregated silver nanoprisms induced by monohydrogen phosphate.The detection strategy had two steps,selective ag...In this study,we established a simple colorimetric method for visual detection of chromium(Ⅲ)ions using aggregated silver nanoprisms induced by monohydrogen phosphate.The detection strategy had two steps,selective aggregation of silver nanoprisms with monohydrogen phosphate at high temperature,and anti aggregation of silver nanoprisms in the presence of chromium(Ⅲ)ions.In this strategy,significant spectral shift of the localized surface plasmon resonance(LSPR)absorption peak of silver nanoprisms could be visualized with the color changed from yellow to blue.The spectral peak shift of silver nanoprisms in the anti-aggregation process was linear with the concentrations of the added chromium(Ⅲ)ions in the range of 20.0-800.0 nM.Thus,a colorimetric method for chromium(Ⅲ)ions detection was established with the detection limit of 3.6 nM.The experimental results of real water samples indicated that the colorimetric sensor was potential in environmental monitoring.展开更多
基金financially supported by the National Natural Science Foundation of China(21565030 and 21465025)Program for Excellent Young Talents of Yunnan UniversityFoundation of National Demonstration Center for Experimental Chemistry and Chemical Engineering Education(Yunnan University)
文摘In this study,we established a simple colorimetric method for visual detection of chromium(Ⅲ)ions using aggregated silver nanoprisms induced by monohydrogen phosphate.The detection strategy had two steps,selective aggregation of silver nanoprisms with monohydrogen phosphate at high temperature,and anti aggregation of silver nanoprisms in the presence of chromium(Ⅲ)ions.In this strategy,significant spectral shift of the localized surface plasmon resonance(LSPR)absorption peak of silver nanoprisms could be visualized with the color changed from yellow to blue.The spectral peak shift of silver nanoprisms in the anti-aggregation process was linear with the concentrations of the added chromium(Ⅲ)ions in the range of 20.0-800.0 nM.Thus,a colorimetric method for chromium(Ⅲ)ions detection was established with the detection limit of 3.6 nM.The experimental results of real water samples indicated that the colorimetric sensor was potential in environmental monitoring.
