Brazing filler metals are widely applied,which serve as an industrial adhesive in the joining of dissimilar structures.With the continuous emergence of new structures and materials,the demand for novel brazing filler ...Brazing filler metals are widely applied,which serve as an industrial adhesive in the joining of dissimilar structures.With the continuous emergence of new structures and materials,the demand for novel brazing filler metals is ever-increasing.It is of great significance to investigate the optimized composition design methods and to establish systematic design guidelines for brazing filler metals.This study elucidated the fundamental rules for the composition design of brazing filler metals from a three-dimensional perspective encompassing the basic properties of applied brazing filler metals,formability and processability,and overall cost.The basic properties of brazing filler metals refer to their mechanical properties,physicochemical properties,electromagnetic properties,corrosion resistance,and the wettability and fluidity during brazing.The formability and processability of brazing filler metals include the processes of smelting and casting,extrusion,rolling,drawing and ring-making,as well as the processes of granulation,powder production,and the molding of amorphous and microcrystalline structures.The cost of brazing filler metals corresponds to the sum of materials value and manufacturing cost.Improving the comprehensive properties of brazing filler metals requires a comprehensive and systematic consideration of design indicators.Highlighting the unique characteristics of brazing filler metals should focus on relevant technical indicators.Binary or ternary eutectic structures can effectively enhance the flow spreading ability of brazing filler metals,and solid solution structures contribute to the formability.By employing the proposed design guidelines,typical Ag based,Cu based,Zn based brazing filler metals,and Sn based solders were designed and successfully applied in major scientific and engineering projects.展开更多
Proton exchange membrane water electrolyzer(PEMWE)is crucial for the storage and conversion of renewable energy.However,the harsh anode environment and the oxygen evolution reaction(OER),which involves a four-electron...Proton exchange membrane water electrolyzer(PEMWE)is crucial for the storage and conversion of renewable energy.However,the harsh anode environment and the oxygen evolution reaction(OER),which involves a four-electron transfer,result in a significant overpotential that limits the overall efficiency of hydrogen production.Identifying active sites in the OER is crucial for understanding the reaction mechanism and guiding the development of novel electrocatalysts with high activity,cost-effectiveness,and durability.Herein,we summarize the widely accepted OER mechanism in acidic media,in situ characterization and monitoring of active sites during the reaction,and provide a general understanding of the active sites on various catalysts in the OER,including Ir-based metals,Ir-based oxides,carbon/oxide-supported Ir,Ir-based perovskite oxides,and Ir-based pyrochlore oxides.For each type of electrocatalysts,reaction pathways and actual active sites are proposed based on in situ characterization techniques and theoretical calculations.Finally,the challenges and strategic research directions associated with the design of highly efficient Ir-based electrocatalysts are discussed,offering new insights for the further scientific advancement and practical application of acidic OER.展开更多
The study of the oxygen evolution reaction(OER)mechanism is vital for advancing our understanding of this pivotal energy conversion process.This review synthesizes recent advancements in OER mechanism,emphasizing the ...The study of the oxygen evolution reaction(OER)mechanism is vital for advancing our understanding of this pivotal energy conversion process.This review synthesizes recent advancements in OER mechanism,emphasizing the intricate relationship between catalytic mechanisms and catalyst design.This review discusses the connotation and cutting-edge progress of traditional mechanisms such as adsorbate evolution mechanism(AEM)and lattice oxygen mechanism(LOM)as well as emerging pathways including oxide path mechanism(OPM),oxo-oxo coupling mechanism(OCM),and intramolecular oxygen coupling mechanism(IMOC)etc.Innovative research progress on the coexistence and transformation of multiple mechanisms is highlighted,and the intrinsic factors that influence these dynamic processes are summarized.Advanced characterization techniques and theoretical modeling are underscored as indispensable tools for revealing these complex interactions.This review provides guiding principles for mechanism-based catalyst design.Finally,in view of the multidimensional challenges currently faced by OER mechanisms,prospects for future research are given to bridge the gap between mechanism innovation and experimental verification and application.This comprehensive review provides valuable perspectives for advancing clean energy technologies and achieving sustainable development.展开更多
The path to searching for sustainable energy has never stopped since thedepletion of fossil fuels can lead to serious environmental pollution andenergy shortages.Using water electrolysis to produce hydrogen has beenpr...The path to searching for sustainable energy has never stopped since thedepletion of fossil fuels can lead to serious environmental pollution andenergy shortages.Using water electrolysis to produce hydrogen has beenproven to be a prioritized approach for green resource production.It is highlycrucial to explore inexpensive and high-performance electrocatalysts foraccelerating hydrogen evolution reaction(HER)and apply them to industrialcases on a large scale.Here,we summarize the different mechanisms of HERin different pH settings and review recent advances in non-noble-metal-basedelectrocatalysts.Then,based on the previous efforts,we discuss severaluniversal strategies for designing pH-independent catalysts and showdirections for the future design of pH-universal catalysts.展开更多
Every river basin is characterised by an evolutionary history,which may be analysed at different time scales.This study provides a geological and geomorphic history of different river basins of India at different time...Every river basin is characterised by an evolutionary history,which may be analysed at different time scales.This study provides a geological and geomorphic history of different river basins of India at different time scales ranging from millions of years to millennial time scales.The river basins in India are divided into six different groups on the basis of different tectono-climatic settings and geomorphic characteristics.The evolutionary trajectories in the past strongly govern the modern day geomorphic characteristics and processes in a river basin.The basin scale data compiled in this paper highlights the role of geological inheritance and‘landscape memory’in the evolution of river systems of India.展开更多
Differential evolution (DE) algorithm has been shown to be a simple and efficient evolutionary algorithm for global optimization over continuous spaces, and has been widely used in both benchmark test functions and re...Differential evolution (DE) algorithm has been shown to be a simple and efficient evolutionary algorithm for global optimization over continuous spaces, and has been widely used in both benchmark test functions and real-world applications. This paper introduces a novel mutation operator, without using the scaling factor F, a conventional control parameter, and this mutation can generate multiple trial vectors by incorporating different weighted values at each generation, which can make the best of the selected multiple parents to improve the probability of generating a better offspring. In addition, in order to enhance the capacity of adaptation, a new and adaptive control parameter, i.e. the crossover rate CR, is presented and when one variable is beyond its boundary, a repair rule is also applied in this paper. The proposed algorithm ADE is validated on several constrained engineering design optimization problems reported in the specialized literature. Compared with respect to algorithms representative of the state-of-the-art in the area, the experimental results show that ADE can obtain good solutions on a test set of constrained optimization problems in engineering design.展开更多
Product innovation can be achieved by analyzing leading products patents in the market.Different methods have been proposed for design around patent,commonly using the elimination or replacement of a single patent ele...Product innovation can be achieved by analyzing leading products patents in the market.Different methods have been proposed for design around patent,commonly using the elimination or replacement of a single patent element However,the existing research fails to restore the position and function of the design around object in the original patent portfolio of enterprises,which often leads to the phenomenon of evading one patent and violating another.This paper proposes a method for design around patent through using the fusion of technologies of the evolution theory and bundle-type patent portfolio analysis in the initial stage of product development.The object system is analyzed to select technical opportunities through the evolutionary path of technologies and functional trimming methods to achieve circumvent barriers of bundle-type patents.The bundle patent portfolio is analyzed for the product evolution with a radar map.The technological evolution path is combined with the TRIZ innovation method to identify and solve the design problem.Patentability of the new design is evaluated using the patent system rules for innovative scheme difference from the original patent portfolio.The method is verified in a case study for the design of a glass-wiping robot.The design solution has been patented.展开更多
Taking social statistic data as basic data,this paper extended the meaning of urban land uses,highlighted the meaning of urban land uses in modern urbanization,which includes direct,indirect and induced land uses,quan...Taking social statistic data as basic data,this paper extended the meaning of urban land uses,highlighted the meaning of urban land uses in modern urbanization,which includes direct,indirect and induced land uses,quantitatively simulated the indirect and induced land uses by the substitution method of agricultural consumption and urban carbon emission and then,analyzed the spatiotemporal evolution of urban land uses in China during 1952–2005 by spatial analysis tool of Geographic Information System. The results indicate that the area of urban land use in China had been increasing since 1952,showing an inversed pyramid structure,i.e.,the direct<the indirect<the induced. Specifically,Chinese urban land use has changed from concentrated distribution in Northwest China to balanced spatial distribution,and the eastern coastal area is under great pressure. Moreover,the northeastern region has moved into the induced dominant stage,while the western region remains at the indirect dominant stage. Finally,it is proposed that in order to guarantee the future demand of urban land use in China,ensuring the induced land use in the eastern region should be taken as a priority goal of Chinese developing policy.展开更多
The agricultural regional type and function are the key theoretical issues in agricultural geography research.Gully agriculture in the Loess Plateau is a new regional type of agricultural system with the coupling deve...The agricultural regional type and function are the key theoretical issues in agricultural geography research.Gully agriculture in the Loess Plateau is a new regional type of agricultural system with the coupling development of the modern gully human-earth relationship.The study of its functional changes is of great practical significance for food security,rural revitalization and sustainable development of regional agriculture in the region of interest.This paper analyses the multifunctional change of gully agriculture in the Loess Plateau and its dynamic mechanism by using large-scale remote sensing data,topographic relief amplitude model,and spatial econometric model to understand internal implications for evolution differentiation at the basin level.The results show that:(1)The spatial concentration of production and supply function of agricultural products(APF)in the gully of the Loess Plateau gully is high,while the ecological conservation and maintenance function(ECF),employment and social security function(ESF),cultural heritage and leisure function(CRF)are relatively low.The four functions’spatial distribution has revealed an apparent regularity.(2)APF has been significantly enhanced,which is mainly distributed in point clusters and strips in the farming and pastoral areas in northern Shaanxi to the Yanhe river basin.The high-value areas of ESF are clustered around the urbanized metropolitan circles and urban-rural staggered areas along the Great Wall.ECF is concentrated in areas with significant natural endowments and excellent ecological conditions.CRF is significantly higher in the municipal districts and the surrounding regional central cities.(3)There are noticeable differences in the gully agriculture regional function(GARF)evolution process due to the geographical environment and socio-economic development stages.In this regard,natural factors have tremendously affected APF,ESF,and ECF,while socio-economic factors greatly differ in the four functions.There are still differences in the driving mechanisms of modern gully agriculture evolution types;hence many critical policies in the Loess Plateau can directly affect the function evolution paths.The dynamic evolution of GARF can reflect the general law of rural human-earth system transition in gully areas,thereby providing policy ideas for high-quality development of agriculture in the Loess Plateau.展开更多
Photocatalysis is considered a prospective way to alleviate the energy crisis and environmental pollution.It is therefore extremely important to design highly efficient photocatalysts for catalytic systems.In recent y...Photocatalysis is considered a prospective way to alleviate the energy crisis and environmental pollution.It is therefore extremely important to design highly efficient photocatalysts for catalytic systems.In recent years,hollow‐structured materials have attracted considerable interest for application in energy conversion fields owing to their large specific surface areas,improved light absorption,and shortened charge carrier transfer path.Because they contain inner and outer surfaces,hollow‐structured materials can provide a superior platform for the deposition of other components.A number of hollow‐structured hierarchical systems have been designed and fabricated in recent decades.It is important to rationally design and construct complex hierarchical structures.In this review,general preparation approaches for hollow‐structured materials are presented,followed by a summary of the recent synthesis methods and mechanisms of typical hollow‐structured materials for applications in the photocatalytic field.Complex hollow‐structured hierarchical photocatalysts are classified into two types,hollow cocatalyst‐based and hollow host photocatalyst‐based,and the design principle and analysis of the photocatalytic reaction mechanism for photocatalytic H2 evolution and CO_(2)reduction are also introduced.The effects of hollow‐structured materials have also been investigated.This review provides a reference for the rational construction of advanced,highly efficient photocatalytic materials.展开更多
Because of their superior problem-solving ability,nature-inspired optimization algorithms are being regularly used in solving complex real-world optimization problems.Engineering academics have recently focused on met...Because of their superior problem-solving ability,nature-inspired optimization algorithms are being regularly used in solving complex real-world optimization problems.Engineering academics have recently focused on meta-heuristic algorithms to solve various optimization challenges.Among the state-of-the-art algorithms,Differential Evolution(DE)is one of the most successful algorithms and is frequently used to solve various industrial problems.Over the previous 2 decades,DE has been heavily modified to improve its capabilities.Several DE variations secured positions in IEEE CEC competitions,establishing their efficacy.However,to our knowledge,there has never been a comparison of performance across various CEC-winning DE versions,which could aid in determining which is the most successful.In this study,the performance of DE and its eight other IEEE CEC competition-winning variants are compared.First,the algorithms have evaluated IEEE CEC 2019 and 2020 bound-constrained functions,and the performances have been compared.One unconstrained problem from IEEE CEC 2011 problem suite and five other constrained mechanical engineering design problems,out of which four issues have been taken from IEEE CEC 2020 non-convex constrained optimization suite,have been solved to compare the performances.Statistical analyses like Friedman's test and Wilcoxon's test are executed to verify the algorithm’s ability statistically.Performance analysis exposes that none of the DE variants can solve all the problems efficiently.Performance of SHADE and ELSHADE-SPACMA are considerable among the methods used for comparison to solve such mechanical design problems.展开更多
Paleoenvironmental reconstruction is fundamental to understand the modern environmental changes and to predict future environment, which is especially critical to understand the evolution of land and sea during geolog...Paleoenvironmental reconstruction is fundamental to understand the modern environmental changes and to predict future environment, which is especially critical to understand the evolution of land and sea during geological periods. However, the basic geological research on China＇s muddy coastal zone is not enough to provide quantitative data to compare with global changes. Therefore, in 2011, China Geological Survey deployed the ＂Late Quaternary geo-environmental evolution and modern process of China＂ project, and focused on the muddy coastal zones of the Liaodong Bay, Bohai Bay, the Yellow River Delta, Yangtze River Delta and Pearl River Delta （Fig. 1）. Next we will briefly introduce our latest results in the Bohai Bay.展开更多
Compression is an intuitive way to boost the performance of a database system. However, compared with other physical database design techniques, compression consumes large amount of CPU power. There is a trade-off bet...Compression is an intuitive way to boost the performance of a database system. However, compared with other physical database design techniques, compression consumes large amount of CPU power. There is a trade-off between the re- duction of disk access and the overhead of CPU processing. Automatic design and adaptive administration of database systems are widely demanded, and the automatic selection of compression schema to compromise the trade-off is very important. In this paper, we present a model with novel techniques to integrate a rapidly convergent agent-based evolution framework, i.e. the SWAF (SWarm Algorithm Framework), into adaptive attribute compression for relational database. The model evolutionally consults statistics of CPU load and IO bandwidth to select compression schemas considering both aspects of the trade-off. We have im- plemented a prototype model on Oscar RDBMS with experiments highlighting the correctness and efficiency of our techniques.展开更多
Rational design of high-performance electrocatalysts for hydrogen evolution reaction(HER)is vital for future renewable energy systems.The incorporation of foreign metal ions into catalysts can be an effective approach...Rational design of high-performance electrocatalysts for hydrogen evolution reaction(HER)is vital for future renewable energy systems.The incorporation of foreign metal ions into catalysts can be an effective approach to optimize its performance.However,there is a lack of systematic theoretical studies to reveal the quantitative relationships at the electronic level.Here,we develop a multi-level screening methodology to search for highly stable and active dopants for CoP catalysts.The density functional theory(DFT)calculations and symbolic regression(SR)were performed to investigate the relationship between the adsorption free energy(ΔG_(H^(*)))and 10 electronic parameters.The mathematic formulas derived from SR indicate that the difference of work function(ΔΦ)between doped metal and the acceptor plays the most important role in regulatingΔG_(H^(*)),followed by the d-band center(d-BC)of doped system.The descriptor of HER can be expressed asΔG_(H^(*))=1.59×√|0.188ΔΦ+d BC+0.120|1/2-0.166 with a high determination coefficient(R^(2)=0.807).Consistent with the theoretical prediction,experimental results show that the Al-CoP delivers superior electrocatalytic HER activity with a low overpotential of75 m V to drive a current density of 10 mA cm^(-2),while the overpotentials for undoped CoP,Mo-CoP,and V-CoP are 206,134,and 83 m V,respectively.The current work proves that theΔΦis the most significant regulatory parameter ofΔG_(H^(*))for ion-doped electrocatalysts.This finding can drive the discovery of high-performance ion-doped electrocatalysts,which is crucial for electrocatalytic water splitting.展开更多
The self-organized evolution technology of the mechanism kinetic scheme based on axiomatic design is presented. This technology tries to express the constraints between kinetic mechanisms briefly in a semantic form wh...The self-organized evolution technology of the mechanism kinetic scheme based on axiomatic design is presented. This technology tries to express the constraints between kinetic mechanisms briefly in a semantic form which is more familiar to the designers. Through the mapping process between the kinetic chain unit and the unit instance, the evolution from abstract unit to concrete engineering instance is achieved. The subdivision of unit coupling semantics is studied, and the evolution of semantics is finished. Also, the semantic constraints evolution of unit coupling semantics is described. The product structure models with function and assembly meanings are constructed based on the kinematic chain unit and unit coupling. It provides a basis to realize the inheritance and transfer of constraint information from conceptual design to design for assembly （DFA）. As the engineering practice result shows, the method can help the engineers express their And the automation, recursion and design intension more clearly and naturally in a high semantic level. visualization of the mechanism kinetic scheme design are realized展开更多
Within the framework of Appraisal theory,this thesis attempts to do the discourse analysis of modern evolution of fe males'non-prototype characteristics through six versions of biographies of Wu Zetian(included Li...Within the framework of Appraisal theory,this thesis attempts to do the discourse analysis of modern evolution of fe males'non-prototype characteristics through six versions of biographies of Wu Zetian(included Lin Yutang's Lady Wu,and Yuan Baidai's Wu Zetian) in modern times,which aims to uncover the implicit relationship of language and ideology of these different Wu Zetian's biographical versions composed by different authors with different genders and nationalities,which can evoke the readers resonance and affection towards them and reflect the interpersonal function between them by means of excavat ing the regularity of Attitude,Engagement and Graduation resources distribution.展开更多
Based on the field survey of dwellings in Tieqiong Village of Waerma Town in Aba County, northwest Tibetan area of Sichuan Province, this paper firstly introduced main characteristics of the construction system in the...Based on the field survey of dwellings in Tieqiong Village of Waerma Town in Aba County, northwest Tibetan area of Sichuan Province, this paper firstly introduced main characteristics of the construction system in the structure, materials and structural system, and analyzed changes in construction practices of various dwellings from traditional to modern time. Finally, it summarized characteristics of spontaneous evolution and research value of the construction system of dwellings in the northwest Tibetan area of Sichuan Province, with rammed earth wooden dwellings in upper and middle Aba areas as representatives.展开更多
This paper divided the evolution of modern Chinese vernacular architecture(1949–2010) into 3 stages: early exploration,confine and confusion,and modern development,by taking time line as the clue,vernacular character...This paper divided the evolution of modern Chinese vernacular architecture(1949–2010) into 3 stages: early exploration,confine and confusion,and modern development,by taking time line as the clue,vernacular characteristics of modern architecture in Xi'an during different phases as the support,and combining literature research and field investigation. On this basis,it reviewed historical background,relevant context and typical features of modern vernacular architecture in Xi'an during different phases,and further concluded the evolution laws and research level of modern Chinese vernacular architecture.展开更多
A multi-world mechanism is developed for modeling evolutionary design process from conceptual design to detailed design. In this mechanism, the evolutionary design database is represented by a sequence of worlds corre...A multi-world mechanism is developed for modeling evolutionary design process from conceptual design to detailed design. In this mechanism, the evolutionary design database is represented by a sequence of worlds corresponding to the design descriptions at different design stages. In each world, only the differences with its ancestor world are recorded. When the design descriptions in one world are changed, these changes are then propagated to its descendant worlds automatically. Case study is conducted to show the effectiveness of this evolutionary design database model.展开更多
This paper deals with the development and evolution of modern Yellow River delta and the erosion or deposition rates of its different sections. In June, 1996, Yellow Rivers terminal course was artificially turned east...This paper deals with the development and evolution of modern Yellow River delta and the erosion or deposition rates of its different sections. In June, 1996, Yellow Rivers terminal course was artificially turned eastwards to empty into the sea and then the 11th lobe of the modern Yellow River delta began to form. This course change may mark the beginning of the 3rd subdelta formation. As a result of that, the Yellow River delta advances towards east by north with the 1st, 2nd and 3rd subdeltas arranged in succession. Coast zone in the deltaic area is divided into 7 different sections according to their different erosion or deposition rates: the relatively stable section from Dakou River to Shunjiang Stream, the weakly retreating section from Shunjiang Stream to the Tiaohe River mouth, the strongly retreating section from the Tiaohe River mouth to the station 106, the artificially stable section due to stone dam protection from the station 106 to Gudong Oilfield, the strong deposition section from Gudong Oilfield to Dawenliu Haipu, the weakly deposition section from Dawenliu Haipu to the Zimai Stream mouth, and the stable section from the Zimai Stream mouth to the Jiaolai River mouth. It is predicted that the erosion and deposition situations of the sections will nearly remain the same in 10 years, but the retreating and silting-up rates will tend to become slower gradually. Human activities have an evident influence on the changes of the coastline.展开更多
基金National Natural Science Foundation of China(U22A20191)。
文摘Brazing filler metals are widely applied,which serve as an industrial adhesive in the joining of dissimilar structures.With the continuous emergence of new structures and materials,the demand for novel brazing filler metals is ever-increasing.It is of great significance to investigate the optimized composition design methods and to establish systematic design guidelines for brazing filler metals.This study elucidated the fundamental rules for the composition design of brazing filler metals from a three-dimensional perspective encompassing the basic properties of applied brazing filler metals,formability and processability,and overall cost.The basic properties of brazing filler metals refer to their mechanical properties,physicochemical properties,electromagnetic properties,corrosion resistance,and the wettability and fluidity during brazing.The formability and processability of brazing filler metals include the processes of smelting and casting,extrusion,rolling,drawing and ring-making,as well as the processes of granulation,powder production,and the molding of amorphous and microcrystalline structures.The cost of brazing filler metals corresponds to the sum of materials value and manufacturing cost.Improving the comprehensive properties of brazing filler metals requires a comprehensive and systematic consideration of design indicators.Highlighting the unique characteristics of brazing filler metals should focus on relevant technical indicators.Binary or ternary eutectic structures can effectively enhance the flow spreading ability of brazing filler metals,and solid solution structures contribute to the formability.By employing the proposed design guidelines,typical Ag based,Cu based,Zn based brazing filler metals,and Sn based solders were designed and successfully applied in major scientific and engineering projects.
基金supported by Henan Province Science and Technology Research Project(Grant No.242103810058)Natural Science Foundation of Henan(Grant No.252300421104)+3 种基金National Natural Science Foundation of China(Grant No.52102346)Henan Key Research and Development Project(Grant No.231111230100)Heluo Youth Talent Project(Grant No.2024HLTJ14)Henan Postdoctoral Research Initiation Project(Grant No.HN2022040 and HN2022048).
文摘Proton exchange membrane water electrolyzer(PEMWE)is crucial for the storage and conversion of renewable energy.However,the harsh anode environment and the oxygen evolution reaction(OER),which involves a four-electron transfer,result in a significant overpotential that limits the overall efficiency of hydrogen production.Identifying active sites in the OER is crucial for understanding the reaction mechanism and guiding the development of novel electrocatalysts with high activity,cost-effectiveness,and durability.Herein,we summarize the widely accepted OER mechanism in acidic media,in situ characterization and monitoring of active sites during the reaction,and provide a general understanding of the active sites on various catalysts in the OER,including Ir-based metals,Ir-based oxides,carbon/oxide-supported Ir,Ir-based perovskite oxides,and Ir-based pyrochlore oxides.For each type of electrocatalysts,reaction pathways and actual active sites are proposed based on in situ characterization techniques and theoretical calculations.Finally,the challenges and strategic research directions associated with the design of highly efficient Ir-based electrocatalysts are discussed,offering new insights for the further scientific advancement and practical application of acidic OER.
文摘The study of the oxygen evolution reaction(OER)mechanism is vital for advancing our understanding of this pivotal energy conversion process.This review synthesizes recent advancements in OER mechanism,emphasizing the intricate relationship between catalytic mechanisms and catalyst design.This review discusses the connotation and cutting-edge progress of traditional mechanisms such as adsorbate evolution mechanism(AEM)and lattice oxygen mechanism(LOM)as well as emerging pathways including oxide path mechanism(OPM),oxo-oxo coupling mechanism(OCM),and intramolecular oxygen coupling mechanism(IMOC)etc.Innovative research progress on the coexistence and transformation of multiple mechanisms is highlighted,and the intrinsic factors that influence these dynamic processes are summarized.Advanced characterization techniques and theoretical modeling are underscored as indispensable tools for revealing these complex interactions.This review provides guiding principles for mechanism-based catalyst design.Finally,in view of the multidimensional challenges currently faced by OER mechanisms,prospects for future research are given to bridge the gap between mechanism innovation and experimental verification and application.This comprehensive review provides valuable perspectives for advancing clean energy technologies and achieving sustainable development.
基金“Pioneer” and “Leading Goose” R&D Program of Zhejiang Province,Grant/Award Numbers:2021C01SA301612, 2023C01235Zhejiang Provincial Key Research and Development Program,Grant/Award Number:2020C01030
文摘The path to searching for sustainable energy has never stopped since thedepletion of fossil fuels can lead to serious environmental pollution andenergy shortages.Using water electrolysis to produce hydrogen has beenproven to be a prioritized approach for green resource production.It is highlycrucial to explore inexpensive and high-performance electrocatalysts foraccelerating hydrogen evolution reaction(HER)and apply them to industrialcases on a large scale.Here,we summarize the different mechanisms of HERin different pH settings and review recent advances in non-noble-metal-basedelectrocatalysts.Then,based on the previous efforts,we discuss severaluniversal strategies for designing pH-independent catalysts and showdirections for the future design of pH-universal catalysts.
基金supported by COFUND fellowship at Durham University,UKSonam was supported by PhD fellowship provided by CSIR-UGC,India(Fellowship No.061320507-23/06/2013(i)EU-V).
文摘Every river basin is characterised by an evolutionary history,which may be analysed at different time scales.This study provides a geological and geomorphic history of different river basins of India at different time scales ranging from millions of years to millennial time scales.The river basins in India are divided into six different groups on the basis of different tectono-climatic settings and geomorphic characteristics.The evolutionary trajectories in the past strongly govern the modern day geomorphic characteristics and processes in a river basin.The basin scale data compiled in this paper highlights the role of geological inheritance and‘landscape memory’in the evolution of river systems of India.
文摘Differential evolution (DE) algorithm has been shown to be a simple and efficient evolutionary algorithm for global optimization over continuous spaces, and has been widely used in both benchmark test functions and real-world applications. This paper introduces a novel mutation operator, without using the scaling factor F, a conventional control parameter, and this mutation can generate multiple trial vectors by incorporating different weighted values at each generation, which can make the best of the selected multiple parents to improve the probability of generating a better offspring. In addition, in order to enhance the capacity of adaptation, a new and adaptive control parameter, i.e. the crossover rate CR, is presented and when one variable is beyond its boundary, a repair rule is also applied in this paper. The proposed algorithm ADE is validated on several constrained engineering design optimization problems reported in the specialized literature. Compared with respect to algorithms representative of the state-of-the-art in the area, the experimental results show that ADE can obtain good solutions on a test set of constrained optimization problems in engineering design.
基金Supported by National Natural Science Foundation of China(Grant Nos.51675159,51605135)Central Guided Local Science and Technology Development Project(Grant No.1824-1837G)Ministry of Science and Technology(Grant No.2017IM040100)
文摘Product innovation can be achieved by analyzing leading products patents in the market.Different methods have been proposed for design around patent,commonly using the elimination or replacement of a single patent element However,the existing research fails to restore the position and function of the design around object in the original patent portfolio of enterprises,which often leads to the phenomenon of evading one patent and violating another.This paper proposes a method for design around patent through using the fusion of technologies of the evolution theory and bundle-type patent portfolio analysis in the initial stage of product development.The object system is analyzed to select technical opportunities through the evolutionary path of technologies and functional trimming methods to achieve circumvent barriers of bundle-type patents.The bundle patent portfolio is analyzed for the product evolution with a radar map.The technological evolution path is combined with the TRIZ innovation method to identify and solve the design problem.Patentability of the new design is evaluated using the patent system rules for innovative scheme difference from the original patent portfolio.The method is verified in a case study for the design of a glass-wiping robot.The design solution has been patented.
基金Under the auspices of Key Program of National Natural Science Foundation of China (No. 40535026)
文摘Taking social statistic data as basic data,this paper extended the meaning of urban land uses,highlighted the meaning of urban land uses in modern urbanization,which includes direct,indirect and induced land uses,quantitatively simulated the indirect and induced land uses by the substitution method of agricultural consumption and urban carbon emission and then,analyzed the spatiotemporal evolution of urban land uses in China during 1952–2005 by spatial analysis tool of Geographic Information System. The results indicate that the area of urban land use in China had been increasing since 1952,showing an inversed pyramid structure,i.e.,the direct<the indirect<the induced. Specifically,Chinese urban land use has changed from concentrated distribution in Northwest China to balanced spatial distribution,and the eastern coastal area is under great pressure. Moreover,the northeastern region has moved into the induced dominant stage,while the western region remains at the indirect dominant stage. Finally,it is proposed that in order to guarantee the future demand of urban land use in China,ensuring the induced land use in the eastern region should be taken as a priority goal of Chinese developing policy.
基金National Natural Science Foundation of China,No.42101202,No.42061037National Natural Science Foundation of China and National Science Foundation of the United States Sustainable Regional System Cooperation Research Project,No.T221101034+1 种基金China Postdoctoral Science,No.2022M710015Fundamental Research Funds for the Central Universities,No.2022CDJSKJC29。
文摘The agricultural regional type and function are the key theoretical issues in agricultural geography research.Gully agriculture in the Loess Plateau is a new regional type of agricultural system with the coupling development of the modern gully human-earth relationship.The study of its functional changes is of great practical significance for food security,rural revitalization and sustainable development of regional agriculture in the region of interest.This paper analyses the multifunctional change of gully agriculture in the Loess Plateau and its dynamic mechanism by using large-scale remote sensing data,topographic relief amplitude model,and spatial econometric model to understand internal implications for evolution differentiation at the basin level.The results show that:(1)The spatial concentration of production and supply function of agricultural products(APF)in the gully of the Loess Plateau gully is high,while the ecological conservation and maintenance function(ECF),employment and social security function(ESF),cultural heritage and leisure function(CRF)are relatively low.The four functions’spatial distribution has revealed an apparent regularity.(2)APF has been significantly enhanced,which is mainly distributed in point clusters and strips in the farming and pastoral areas in northern Shaanxi to the Yanhe river basin.The high-value areas of ESF are clustered around the urbanized metropolitan circles and urban-rural staggered areas along the Great Wall.ECF is concentrated in areas with significant natural endowments and excellent ecological conditions.CRF is significantly higher in the municipal districts and the surrounding regional central cities.(3)There are noticeable differences in the gully agriculture regional function(GARF)evolution process due to the geographical environment and socio-economic development stages.In this regard,natural factors have tremendously affected APF,ESF,and ECF,while socio-economic factors greatly differ in the four functions.There are still differences in the driving mechanisms of modern gully agriculture evolution types;hence many critical policies in the Loess Plateau can directly affect the function evolution paths.The dynamic evolution of GARF can reflect the general law of rural human-earth system transition in gully areas,thereby providing policy ideas for high-quality development of agriculture in the Loess Plateau.
文摘Photocatalysis is considered a prospective way to alleviate the energy crisis and environmental pollution.It is therefore extremely important to design highly efficient photocatalysts for catalytic systems.In recent years,hollow‐structured materials have attracted considerable interest for application in energy conversion fields owing to their large specific surface areas,improved light absorption,and shortened charge carrier transfer path.Because they contain inner and outer surfaces,hollow‐structured materials can provide a superior platform for the deposition of other components.A number of hollow‐structured hierarchical systems have been designed and fabricated in recent decades.It is important to rationally design and construct complex hierarchical structures.In this review,general preparation approaches for hollow‐structured materials are presented,followed by a summary of the recent synthesis methods and mechanisms of typical hollow‐structured materials for applications in the photocatalytic field.Complex hollow‐structured hierarchical photocatalysts are classified into two types,hollow cocatalyst‐based and hollow host photocatalyst‐based,and the design principle and analysis of the photocatalytic reaction mechanism for photocatalytic H2 evolution and CO_(2)reduction are also introduced.The effects of hollow‐structured materials have also been investigated.This review provides a reference for the rational construction of advanced,highly efficient photocatalytic materials.
文摘Because of their superior problem-solving ability,nature-inspired optimization algorithms are being regularly used in solving complex real-world optimization problems.Engineering academics have recently focused on meta-heuristic algorithms to solve various optimization challenges.Among the state-of-the-art algorithms,Differential Evolution(DE)is one of the most successful algorithms and is frequently used to solve various industrial problems.Over the previous 2 decades,DE has been heavily modified to improve its capabilities.Several DE variations secured positions in IEEE CEC competitions,establishing their efficacy.However,to our knowledge,there has never been a comparison of performance across various CEC-winning DE versions,which could aid in determining which is the most successful.In this study,the performance of DE and its eight other IEEE CEC competition-winning variants are compared.First,the algorithms have evaluated IEEE CEC 2019 and 2020 bound-constrained functions,and the performances have been compared.One unconstrained problem from IEEE CEC 2011 problem suite and five other constrained mechanical engineering design problems,out of which four issues have been taken from IEEE CEC 2020 non-convex constrained optimization suite,have been solved to compare the performances.Statistical analyses like Friedman's test and Wilcoxon's test are executed to verify the algorithm’s ability statistically.Performance analysis exposes that none of the DE variants can solve all the problems efficiently.Performance of SHADE and ELSHADE-SPACMA are considerable among the methods used for comparison to solve such mechanical design problems.
基金funded by China Geological Survey(Grants No.1212011120169 and 12120113005800)the National Natural Science Foundation of China(Grants No.41206069,41476074 and 41372173)
文摘Paleoenvironmental reconstruction is fundamental to understand the modern environmental changes and to predict future environment, which is especially critical to understand the evolution of land and sea during geological periods. However, the basic geological research on China＇s muddy coastal zone is not enough to provide quantitative data to compare with global changes. Therefore, in 2011, China Geological Survey deployed the ＂Late Quaternary geo-environmental evolution and modern process of China＂ project, and focused on the muddy coastal zones of the Liaodong Bay, Bohai Bay, the Yellow River Delta, Yangtze River Delta and Pearl River Delta （Fig. 1）. Next we will briefly introduce our latest results in the Bohai Bay.
基金Project (No. 2004AA4Z3010) supported by the National Hi-Tech Research and Development Program (863) of China
文摘Compression is an intuitive way to boost the performance of a database system. However, compared with other physical database design techniques, compression consumes large amount of CPU power. There is a trade-off between the re- duction of disk access and the overhead of CPU processing. Automatic design and adaptive administration of database systems are widely demanded, and the automatic selection of compression schema to compromise the trade-off is very important. In this paper, we present a model with novel techniques to integrate a rapidly convergent agent-based evolution framework, i.e. the SWAF (SWarm Algorithm Framework), into adaptive attribute compression for relational database. The model evolutionally consults statistics of CPU load and IO bandwidth to select compression schemas considering both aspects of the trade-off. We have im- plemented a prototype model on Oscar RDBMS with experiments highlighting the correctness and efficiency of our techniques.
基金Financial support from the National Natural Science Foundation of China(21676216)the Special project of Shaanxi Provincial Education Department(20JC034)+1 种基金GHfund B(202202022563)Hefei Advanced Computing Center。
文摘Rational design of high-performance electrocatalysts for hydrogen evolution reaction(HER)is vital for future renewable energy systems.The incorporation of foreign metal ions into catalysts can be an effective approach to optimize its performance.However,there is a lack of systematic theoretical studies to reveal the quantitative relationships at the electronic level.Here,we develop a multi-level screening methodology to search for highly stable and active dopants for CoP catalysts.The density functional theory(DFT)calculations and symbolic regression(SR)were performed to investigate the relationship between the adsorption free energy(ΔG_(H^(*)))and 10 electronic parameters.The mathematic formulas derived from SR indicate that the difference of work function(ΔΦ)between doped metal and the acceptor plays the most important role in regulatingΔG_(H^(*)),followed by the d-band center(d-BC)of doped system.The descriptor of HER can be expressed asΔG_(H^(*))=1.59×√|0.188ΔΦ+d BC+0.120|1/2-0.166 with a high determination coefficient(R^(2)=0.807).Consistent with the theoretical prediction,experimental results show that the Al-CoP delivers superior electrocatalytic HER activity with a low overpotential of75 m V to drive a current density of 10 mA cm^(-2),while the overpotentials for undoped CoP,Mo-CoP,and V-CoP are 206,134,and 83 m V,respectively.The current work proves that theΔΦis the most significant regulatory parameter ofΔG_(H^(*))for ion-doped electrocatalysts.This finding can drive the discovery of high-performance ion-doped electrocatalysts,which is crucial for electrocatalytic water splitting.
文摘The self-organized evolution technology of the mechanism kinetic scheme based on axiomatic design is presented. This technology tries to express the constraints between kinetic mechanisms briefly in a semantic form which is more familiar to the designers. Through the mapping process between the kinetic chain unit and the unit instance, the evolution from abstract unit to concrete engineering instance is achieved. The subdivision of unit coupling semantics is studied, and the evolution of semantics is finished. Also, the semantic constraints evolution of unit coupling semantics is described. The product structure models with function and assembly meanings are constructed based on the kinematic chain unit and unit coupling. It provides a basis to realize the inheritance and transfer of constraint information from conceptual design to design for assembly （DFA）. As the engineering practice result shows, the method can help the engineers express their And the automation, recursion and design intension more clearly and naturally in a high semantic level. visualization of the mechanism kinetic scheme design are realized
文摘Within the framework of Appraisal theory,this thesis attempts to do the discourse analysis of modern evolution of fe males'non-prototype characteristics through six versions of biographies of Wu Zetian(included Lin Yutang's Lady Wu,and Yuan Baidai's Wu Zetian) in modern times,which aims to uncover the implicit relationship of language and ideology of these different Wu Zetian's biographical versions composed by different authors with different genders and nationalities,which can evoke the readers resonance and affection towards them and reflect the interpersonal function between them by means of excavat ing the regularity of Attitude,Engagement and Graduation resources distribution.
基金Supported by the Open Research Subject of Research Base of Local Culture Protection and Development Research Center(15DFWH016)Research Base of Sichuan Rural Development Research Center(CR1512)Research Base of Sichuan Province Multi-cultural Research Center(DYWH1507)
文摘Based on the field survey of dwellings in Tieqiong Village of Waerma Town in Aba County, northwest Tibetan area of Sichuan Province, this paper firstly introduced main characteristics of the construction system in the structure, materials and structural system, and analyzed changes in construction practices of various dwellings from traditional to modern time. Finally, it summarized characteristics of spontaneous evolution and research value of the construction system of dwellings in the northwest Tibetan area of Sichuan Province, with rammed earth wooden dwellings in upper and middle Aba areas as representatives.
基金Sponsored by Cultivation Foundation of Xi’an University of Science and Technology(201640)
文摘This paper divided the evolution of modern Chinese vernacular architecture(1949–2010) into 3 stages: early exploration,confine and confusion,and modern development,by taking time line as the clue,vernacular characteristics of modern architecture in Xi'an during different phases as the support,and combining literature research and field investigation. On this basis,it reviewed historical background,relevant context and typical features of modern vernacular architecture in Xi'an during different phases,and further concluded the evolution laws and research level of modern Chinese vernacular architecture.
基金Selected from Proceedings of the 7th Intemational Conference on Frontiers of Design and Manufacturing (ICFDM'2006).
文摘A multi-world mechanism is developed for modeling evolutionary design process from conceptual design to detailed design. In this mechanism, the evolutionary design database is represented by a sequence of worlds corresponding to the design descriptions at different design stages. In each world, only the differences with its ancestor world are recorded. When the design descriptions in one world are changed, these changes are then propagated to its descendant worlds automatically. Case study is conducted to show the effectiveness of this evolutionary design database model.
基金The study is supported by the China National Natural Science Foundation (project No. 49476282)by the Shandong Province Natural Science Foundation (project No. 98E04075).
文摘This paper deals with the development and evolution of modern Yellow River delta and the erosion or deposition rates of its different sections. In June, 1996, Yellow Rivers terminal course was artificially turned eastwards to empty into the sea and then the 11th lobe of the modern Yellow River delta began to form. This course change may mark the beginning of the 3rd subdelta formation. As a result of that, the Yellow River delta advances towards east by north with the 1st, 2nd and 3rd subdeltas arranged in succession. Coast zone in the deltaic area is divided into 7 different sections according to their different erosion or deposition rates: the relatively stable section from Dakou River to Shunjiang Stream, the weakly retreating section from Shunjiang Stream to the Tiaohe River mouth, the strongly retreating section from the Tiaohe River mouth to the station 106, the artificially stable section due to stone dam protection from the station 106 to Gudong Oilfield, the strong deposition section from Gudong Oilfield to Dawenliu Haipu, the weakly deposition section from Dawenliu Haipu to the Zimai Stream mouth, and the stable section from the Zimai Stream mouth to the Jiaolai River mouth. It is predicted that the erosion and deposition situations of the sections will nearly remain the same in 10 years, but the retreating and silting-up rates will tend to become slower gradually. Human activities have an evident influence on the changes of the coastline.
