In the study of the catalytic active center of nitrogen fixation in nitrogenase, structural models containing MoFe3S3 or MoFe3S4 cubane-like skeleton have been proposed. The syntheses of these model compounds have sin...In the study of the catalytic active center of nitrogen fixation in nitrogenase, structural models containing MoFe3S3 or MoFe3S4 cubane-like skeleton have been proposed. The syntheses of these model compounds have since attracted the attention of many chemists. Up to the present time, however, only Holm’s research group has obtained MoFe3S4 single cubane cluster compounds by multi-step cleavage reaction of Mo—Fe—S展开更多
文摘In the study of the catalytic active center of nitrogen fixation in nitrogenase, structural models containing MoFe3S3 or MoFe3S4 cubane-like skeleton have been proposed. The syntheses of these model compounds have since attracted the attention of many chemists. Up to the present time, however, only Holm’s research group has obtained MoFe3S4 single cubane cluster compounds by multi-step cleavage reaction of Mo—Fe—S
