The electrochemical corrosion behavior of Ti（C,N）-based cermets with different Mo2C additions was investigated in freely aerated 10% H2SO4 and potentiodynamic polarization of all the materials was conducted from -0....The electrochemical corrosion behavior of Ti（C,N）-based cermets with different Mo2C additions was investigated in freely aerated 10% H2SO4 and potentiodynamic polarization of all the materials was conducted from -0.5 to 1.5 V. There are two passive regions for all polarization curves. The first should be attributed to passive film formation due to Ti（C,N）, while the second may be due to the presence of Ni. Corrosion current density increases with M02C content increasing, from 2.06×10^-3 to 6.70×10^-3 mA/cm2. It is indicated that the corrosion resistance of Ti（C,N）-based cermets decreases with the increase of Mo2C addition. A skeleton of Ti（C,N） gains is observed after dissolution of Ni. The inner rim of cermets, rich in Mo2C, is corroded along with Ni binder and is more serious with the increase of Mo2C content. The secondary carbide Mo2C can be oxidized and dissolved in sulphuric acid.展开更多
Effects of VC/Cr3C2 on the microstructure and mechanical properties of Ti（C,N）-based cermets were studied. The microstructure was investigated by means of optical microscopy, X-ray diffractometry as well as scanning...Effects of VC/Cr3C2 on the microstructure and mechanical properties of Ti（C,N）-based cermets were studied. The microstructure was investigated by means of optical microscopy, X-ray diffractometry as well as scanning electron microscopy in combination with energy dispersive spectrometry. Mechanical properties, such as transverse rupture strength, hardness and fracture toughness, were measured. The results show that there are black core-grey rim structure and white core-grey rim structure in the microstructure. The grains become fine due to the VC/Cr3C2, and the grains of cermet added with 0.75VC/0.25Cr3C2 are refined most remarkably. The black core becomes finer with the increase of VC addition and rim phase becomes thicker with the decrease of Cr3C2 addition. The porosity increases with the increase of VC addition in VC/Cr3C2. Compared with the cermet free of VC/Cr3C2, the transverse rupture strength and hardness of cermets with VC/Cr3C2 are both improved, and the maximum values are both found for the cermet with 0.25VC/0.75Cr3C2. The fracture toughness can be effectively promoted by adding VC/Cr3C2 with an appropriate ratio of VC to Cr3C2, and the maximum value is found for the cermet with 0.5VC/0.5Cr3C2.展开更多
A comparative study on the corrosion resistance of 17Ni/（NiFe2O4-10NiO） cermet inert anode prepared in differentsintering atmospheres was conducted in Na3AlF6-Al2O3 melt. The results indicate that the corrosion rate...A comparative study on the corrosion resistance of 17Ni/（NiFe2O4-10NiO） cermet inert anode prepared in differentsintering atmospheres was conducted in Na3AlF6-Al2O3 melt. The results indicate that the corrosion rates of NiFe2O4-based cermetanodes prepared in the vacuum and the atmosphere with oxygen content of 2×10^-3 （volume fraction） are 6.46 and 2.71 cm/a,respectively. Though there is a transition layer with lots of holes or pores, a densified layer is formed on the surface of anode due tosome reactions producing aluminates. For the anode prepared in the atmosphere with oxygen content of 2×10^-3, the thickness of thedensification layer （about 50 μm） is thicker than that （about 30 μm） formed on the surface of anode prepared in the vacuum. Thecontents of NiO and Fe（II） in NiFe2xO4-y-z increase with the decrease of oxygen content in sintering atmosphere, which reduces thecorrosion resistance of the material.展开更多
基金Project(51074110) supported by the National Natural Science Foundation of ChinaProject(10GGZD080GX-268) supported by Chengdu Science and Technology Program, China
文摘The electrochemical corrosion behavior of Ti（C,N）-based cermets with different Mo2C additions was investigated in freely aerated 10% H2SO4 and potentiodynamic polarization of all the materials was conducted from -0.5 to 1.5 V. There are two passive regions for all polarization curves. The first should be attributed to passive film formation due to Ti（C,N）, while the second may be due to the presence of Ni. Corrosion current density increases with M02C content increasing, from 2.06×10^-3 to 6.70×10^-3 mA/cm2. It is indicated that the corrosion resistance of Ti（C,N）-based cermets decreases with the increase of Mo2C addition. A skeleton of Ti（C,N） gains is observed after dissolution of Ni. The inner rim of cermets, rich in Mo2C, is corroded along with Ni binder and is more serious with the increase of Mo2C content. The secondary carbide Mo2C can be oxidized and dissolved in sulphuric acid.
基金Project (090414185) supported by the Natural Science Foundation of Anhui Province, China
文摘Effects of VC/Cr3C2 on the microstructure and mechanical properties of Ti（C,N）-based cermets were studied. The microstructure was investigated by means of optical microscopy, X-ray diffractometry as well as scanning electron microscopy in combination with energy dispersive spectrometry. Mechanical properties, such as transverse rupture strength, hardness and fracture toughness, were measured. The results show that there are black core-grey rim structure and white core-grey rim structure in the microstructure. The grains become fine due to the VC/Cr3C2, and the grains of cermet added with 0.75VC/0.25Cr3C2 are refined most remarkably. The black core becomes finer with the increase of VC addition and rim phase becomes thicker with the decrease of Cr3C2 addition. The porosity increases with the increase of VC addition in VC/Cr3C2. Compared with the cermet free of VC/Cr3C2, the transverse rupture strength and hardness of cermets with VC/Cr3C2 are both improved, and the maximum values are both found for the cermet with 0.25VC/0.75Cr3C2. The fracture toughness can be effectively promoted by adding VC/Cr3C2 with an appropriate ratio of VC to Cr3C2, and the maximum value is found for the cermet with 0.5VC/0.5Cr3C2.
基金Project(51474238)supported by the National Natural Science Foundation of China
文摘A comparative study on the corrosion resistance of 17Ni/（NiFe2O4-10NiO） cermet inert anode prepared in differentsintering atmospheres was conducted in Na3AlF6-Al2O3 melt. The results indicate that the corrosion rates of NiFe2O4-based cermetanodes prepared in the vacuum and the atmosphere with oxygen content of 2×10^-3 （volume fraction） are 6.46 and 2.71 cm/a,respectively. Though there is a transition layer with lots of holes or pores, a densified layer is formed on the surface of anode due tosome reactions producing aluminates. For the anode prepared in the atmosphere with oxygen content of 2×10^-3, the thickness of thedensification layer （about 50 μm） is thicker than that （about 30 μm） formed on the surface of anode prepared in the vacuum. Thecontents of NiO and Fe（II） in NiFe2xO4-y-z increase with the decrease of oxygen content in sintering atmosphere, which reduces thecorrosion resistance of the material.
