The cobalt-free Mn-based Li-rich layered oxide material has the advantages of low cost,high energy density,and good performance at low temperatures,and is the promising choice for energy storage batteries.However,the ...The cobalt-free Mn-based Li-rich layered oxide material has the advantages of low cost,high energy density,and good performance at low temperatures,and is the promising choice for energy storage batteries.However,the long-cycling stability of batteries needs to be improved.Herein,the Mn-based Li-rich cathode materials with small amounts of Li2 MnO3 crystal domains and gradient doping of Al and Ti elements from the surface to the bulk have been developed to improve the structure and interface stability.Then the batteries with a high energy density of 600 Wh kg^(-1),excellent capacity retention of 99.7%with low voltage decay of 0.03 mV cycle^(-1) after 800 cycles,and good rates performances can be achieved.Therefore,the structure and cycling stability of low voltage Mn-based Li-rich cathode materials can be significantly improved by the bulk structure design and interface regulation,and this work has paved the way for developing low-cost and high-energy Mn-based energy storage batteries with long lifetime.展开更多
Li_(1.3)Al_(0.3)Ti_(1.7)(PO_(4))_(3)(LATP),of much interest owing to its high ionic conductivity,superior air stability,and low cost,has been regarded as one of the most promising solid-state electrolytes for next-gen...Li_(1.3)Al_(0.3)Ti_(1.7)(PO_(4))_(3)(LATP),of much interest owing to its high ionic conductivity,superior air stability,and low cost,has been regarded as one of the most promising solid-state electrolytes for next-generation solid-state lithium batteries(SSLBs).Unfortunately,the commercialization of SSLBs is still impeded by severe interfacial issues,such as high interfacial impedance and poor chemical stability.Herein,we proposed a simple and convenient in-situ approach to constructing a tight and robust interface between the Li anode and LATP electrolyte via a SnO_(2)gradient buffer layer.It is firmly attached to the surface of LATP pellets due to the volume expansion of SnO_(2)when in-situ reacting with Li metal,and thus effectively alleviates the physical contact loosening during cycling,as confirmed by the mitigated impedance rising.Meanwhile,the as-formed SnO_(2)/Sn/LixSn gradient buffer layer with low electronic conductivity successfully protects the LATP electrolyte surface from erosion by the Li metal anode.Additionally,the LixSn alloy formed at the Li surface can effectively regulate uniform lithium deposition and suppress Li dendrite growth.Therefore,this work paves a new way to simultaneously address the chemical instability and poor physical contact of LATP with Li metal in developing low-cost and highly stable SSLBs.展开更多
The basic terrain-following(BTF)coordinate simplifies the lower boundary conditions of a numerical model but leads to numerical error and instability on steep terrain.Hybrid terrain-following(HTF)coordinates with smoo...The basic terrain-following(BTF)coordinate simplifies the lower boundary conditions of a numerical model but leads to numerical error and instability on steep terrain.Hybrid terrain-following(HTF)coordinates with smooth slopes of vertical layers(slopeVL)generally overcome this difficulty.Therefore,the HTF coordinate becomes very desirable for atmospheric and oceanic numerical models.However,improper vertical layering in HTF coordinates may also increase the incidence of error.Except for the slopeVL of an HTF coordinate,this study further optimizes the HTF coordinate focusing on the thickness of vertical layers(thickVL).Four HTF coordinates(HTF1–HTF4)with similar slopeVL but different vertical transition methods of thickVL are designed,and the relationship between thickVL and numerical errors in each coordinate is compared in the classic idealized thermal convection[two-dimensional(2D)rising bubble]experiment over steep terrain.The errors of potential temperatureθand vertical velocity w are reduced most,by approximately 70%and 40%,respectively,in the HTF1 coordinate,with a monotonic increase in thickVL according to the increasing height;however,the errors ofθincreased in all the other HTF coordinates,with nonmonotonic thickVLs.Furthermore,analyses of the errors of vertical pressure gradient force(VPGF)show that due to the interpolation errors of thickVL,the inflection points in the vertical transition of thickVL induce the initial VPGF errors;therefore,the HTF1 coordinate with a monotonic increase in thickVL has the smallest errors among all the coordinates.More importantly,the temporal evolution of VPGF errors manifests top-type VPGF errors that propagate upward gradually during the time integration.Only the HTF1 and HTF4 coordinates with a monotonic increase in thickVL near the top of the terrain can suppress this propagation.This optimized HTF coordinate(i.e.,HTF1)can be a reference for designing a vertical thickVL in a numerical model.展开更多
基金supported by the National Key R&D Program of China(No.2022YFB2404400)the National Natural Science Foundation of China(Nos.U23A20577,52372168,92263206 and 21975006)+1 种基金the“The Youth Beijing Scholars program”(No.PXM2021_014204_000023)the Beijing Natural Science Foundation(Nos.2222001 and KM202110005009).
文摘The cobalt-free Mn-based Li-rich layered oxide material has the advantages of low cost,high energy density,and good performance at low temperatures,and is the promising choice for energy storage batteries.However,the long-cycling stability of batteries needs to be improved.Herein,the Mn-based Li-rich cathode materials with small amounts of Li2 MnO3 crystal domains and gradient doping of Al and Ti elements from the surface to the bulk have been developed to improve the structure and interface stability.Then the batteries with a high energy density of 600 Wh kg^(-1),excellent capacity retention of 99.7%with low voltage decay of 0.03 mV cycle^(-1) after 800 cycles,and good rates performances can be achieved.Therefore,the structure and cycling stability of low voltage Mn-based Li-rich cathode materials can be significantly improved by the bulk structure design and interface regulation,and this work has paved the way for developing low-cost and high-energy Mn-based energy storage batteries with long lifetime.
基金financially supported by the China Postdoctoral Science Foundation(2021M700396)the National Natural Science Foundation of China(52102206)the research grants from the National Research Foundation(2022K1A3A1A20014496 and 2022R1F1A1074707)funded by the government of the Republic of Korea。
文摘Li_(1.3)Al_(0.3)Ti_(1.7)(PO_(4))_(3)(LATP),of much interest owing to its high ionic conductivity,superior air stability,and low cost,has been regarded as one of the most promising solid-state electrolytes for next-generation solid-state lithium batteries(SSLBs).Unfortunately,the commercialization of SSLBs is still impeded by severe interfacial issues,such as high interfacial impedance and poor chemical stability.Herein,we proposed a simple and convenient in-situ approach to constructing a tight and robust interface between the Li anode and LATP electrolyte via a SnO_(2)gradient buffer layer.It is firmly attached to the surface of LATP pellets due to the volume expansion of SnO_(2)when in-situ reacting with Li metal,and thus effectively alleviates the physical contact loosening during cycling,as confirmed by the mitigated impedance rising.Meanwhile,the as-formed SnO_(2)/Sn/LixSn gradient buffer layer with low electronic conductivity successfully protects the LATP electrolyte surface from erosion by the Li metal anode.Additionally,the LixSn alloy formed at the Li surface can effectively regulate uniform lithium deposition and suppress Li dendrite growth.Therefore,this work paves a new way to simultaneously address the chemical instability and poor physical contact of LATP with Li metal in developing low-cost and highly stable SSLBs.
基金Supported by the National Natural Science Foundation of China(42230606)14th Five-Year Plan Basic Research Program of Institute of Atmospheric Physics,Chinese Academy of Sciences(E268081801)National Key Research and Development Program of China(2017YFA0603901)。
文摘The basic terrain-following(BTF)coordinate simplifies the lower boundary conditions of a numerical model but leads to numerical error and instability on steep terrain.Hybrid terrain-following(HTF)coordinates with smooth slopes of vertical layers(slopeVL)generally overcome this difficulty.Therefore,the HTF coordinate becomes very desirable for atmospheric and oceanic numerical models.However,improper vertical layering in HTF coordinates may also increase the incidence of error.Except for the slopeVL of an HTF coordinate,this study further optimizes the HTF coordinate focusing on the thickness of vertical layers(thickVL).Four HTF coordinates(HTF1–HTF4)with similar slopeVL but different vertical transition methods of thickVL are designed,and the relationship between thickVL and numerical errors in each coordinate is compared in the classic idealized thermal convection[two-dimensional(2D)rising bubble]experiment over steep terrain.The errors of potential temperatureθand vertical velocity w are reduced most,by approximately 70%and 40%,respectively,in the HTF1 coordinate,with a monotonic increase in thickVL according to the increasing height;however,the errors ofθincreased in all the other HTF coordinates,with nonmonotonic thickVLs.Furthermore,analyses of the errors of vertical pressure gradient force(VPGF)show that due to the interpolation errors of thickVL,the inflection points in the vertical transition of thickVL induce the initial VPGF errors;therefore,the HTF1 coordinate with a monotonic increase in thickVL has the smallest errors among all the coordinates.More importantly,the temporal evolution of VPGF errors manifests top-type VPGF errors that propagate upward gradually during the time integration.Only the HTF1 and HTF4 coordinates with a monotonic increase in thickVL near the top of the terrain can suppress this propagation.This optimized HTF coordinate(i.e.,HTF1)can be a reference for designing a vertical thickVL in a numerical model.
