The effect of Mo on nano-scaled particles,prior austenite grains and impact toughness of coarse-grained heat-affected zone(CGHAZ)in offshore engineering steels with Ca deoxidation was studied.The heat-affected zone(HA...The effect of Mo on nano-scaled particles,prior austenite grains and impact toughness of coarse-grained heat-affected zone(CGHAZ)in offshore engineering steels with Ca deoxidation was studied.The heat-affected zone(HAZ)toughness of Mo16 steel is obviously higher than that of Mo8 steel at all the heat inputs of 50,100,150 and 200 kJ/cm,with HAZ toughness of both steels decreased with increasing the welding heat input.When the Mo content is increased from 0.08 to 0.16%,the size of nano-scaled particles in HAZ is decreased from 18 to 15 nm,and their number density is increased from 0.7 to 0.9μm^(−2).Thus,the Zener pinning force is increased,and the prior austenite grain size(PAGS)is decreased,leading to the improved HAZ toughness.Microstructural characterizations show that the nano-scaled particles in both steels are Ti(C,N)with the solute elements of Nb and Mo.The calculated critical particle size of TiN is 10.2 and 8.4 nm in Mo8 and Mo16 steels at 1350℃,and the particles larger than the critical size are stable during the welding process.From the Zener pinning force calculation,Ti(C,N)particles play the more important role in the pinning effect on the prior austenite grain growth.Based on the regression analysis by the MATLAB results,the predicted values of PAGS at different heat inputs are well fitted with the experimental data.展开更多
Mo/ZSM 5 catalysts with different Mo content were prepared by impregnation method. The effect of Mo content on the property of Mo/ZSM 5 catalysts and their performance for selective catalytic reduction(SCR) of NO with...Mo/ZSM 5 catalysts with different Mo content were prepared by impregnation method. The effect of Mo content on the property of Mo/ZSM 5 catalysts and their performance for selective catalytic reduction(SCR) of NO with ammonia was investigated by XRD, ICP, XPS and NO TPD respectively. The results showed that the catalytic activity of Mo/ZSM 5 for SCR of NO is strongly influenced by the Mo loading in HZSM 5 zeolites. The NOx conversion reached the highest value of 64.2% at 375℃ when Mo content is about 10 9%, and the temperatures at which the maximum of NOx conversion obtained were declined with the increase of Mo content. From XRD results, it can be seen that it exhibits the distinct interaction between Mo and HZSM 5 when Mo content is about 10 9%. This may result in a suitable phase structure in Mo/ZSM 5 catalyst, which is advantageous for NO reduction. XPS and NO TPD results also showed that the catalytic activity of Mo/ZSM 5 may be related to the Mo percent on the surface.展开更多
The substantial influences of Mo contents varying from 0 to 0.26 and 0.50 wt.%on the microstructural evolution and MX(M=Nb,V and Mo;X=C and N)precipitation characteristics of Nb–V–N microalloyed steels processed by ...The substantial influences of Mo contents varying from 0 to 0.26 and 0.50 wt.%on the microstructural evolution and MX(M=Nb,V and Mo;X=C and N)precipitation characteristics of Nb–V–N microalloyed steels processed by hot deformation and continuous cooling were studied using a Gleeble 3800 thermomechanical simulator.Metallographic analysis showed that the ferrite microstructure transformed from polygonal ferrite(PF)in 0Mo steel to both acicular ferrite(AF)and PF in 0.26Mo and 0.50Mo steels,and AF content first increased and then decreased.The thermodynamic calculations and the experimental results proved that the quantity of solid solution of Mo in austenite obviously increased,which reduced the austenite(γ)to ferrite(α)transformation temperature,consequently promoting AF formation in 0.26Mo steel and bainite transformation in 0.50Mo steel.Moreover,the submicron Nb-rich MX particles that precipitated at the temperature of the austenite region further induced AF heterogeneous nucleation with an orientation relationship of(100)_(MX)//(100)_(Ferrite)and[■][001]Ferrite.The interphase precipitation of the nanosized V-rich MX particles with Mo partitioning that precipitated duringγ→αtransformation exhibited a Baker–Nutting orientation relationship of(100)_(MX)//(100)Ferrite and[001]_(MX)//[■]_(Ferrite)with respect to the ferrite matrix.With increasing Mo content from 0 to 0.26 and 0.50 wt.%,the sheet spacing decreased from 46.9–49.0 to 34.6–38.6 and 25.7–28.0 nm,respectively,which evidently hindered dislocation movement and greatly enhanced precipitation strengthening.Furthermore,facilitating AF formation and interphase precipitation was beneficial to improving steel properties,and the optimal Mo content was 0.26 wt.%.展开更多
基金supported by the National Natural Science Foundation of China(U1960202).
文摘The effect of Mo on nano-scaled particles,prior austenite grains and impact toughness of coarse-grained heat-affected zone(CGHAZ)in offshore engineering steels with Ca deoxidation was studied.The heat-affected zone(HAZ)toughness of Mo16 steel is obviously higher than that of Mo8 steel at all the heat inputs of 50,100,150 and 200 kJ/cm,with HAZ toughness of both steels decreased with increasing the welding heat input.When the Mo content is increased from 0.08 to 0.16%,the size of nano-scaled particles in HAZ is decreased from 18 to 15 nm,and their number density is increased from 0.7 to 0.9μm^(−2).Thus,the Zener pinning force is increased,and the prior austenite grain size(PAGS)is decreased,leading to the improved HAZ toughness.Microstructural characterizations show that the nano-scaled particles in both steels are Ti(C,N)with the solute elements of Nb and Mo.The calculated critical particle size of TiN is 10.2 and 8.4 nm in Mo8 and Mo16 steels at 1350℃,and the particles larger than the critical size are stable during the welding process.From the Zener pinning force calculation,Ti(C,N)particles play the more important role in the pinning effect on the prior austenite grain growth.Based on the regression analysis by the MATLAB results,the predicted values of PAGS at different heat inputs are well fitted with the experimental data.
文摘Mo/ZSM 5 catalysts with different Mo content were prepared by impregnation method. The effect of Mo content on the property of Mo/ZSM 5 catalysts and their performance for selective catalytic reduction(SCR) of NO with ammonia was investigated by XRD, ICP, XPS and NO TPD respectively. The results showed that the catalytic activity of Mo/ZSM 5 for SCR of NO is strongly influenced by the Mo loading in HZSM 5 zeolites. The NOx conversion reached the highest value of 64.2% at 375℃ when Mo content is about 10 9%, and the temperatures at which the maximum of NOx conversion obtained were declined with the increase of Mo content. From XRD results, it can be seen that it exhibits the distinct interaction between Mo and HZSM 5 when Mo content is about 10 9%. This may result in a suitable phase structure in Mo/ZSM 5 catalyst, which is advantageous for NO reduction. XPS and NO TPD results also showed that the catalytic activity of Mo/ZSM 5 may be related to the Mo percent on the surface.
基金supported by the National Natural Science Foundation of China(Grant No.52104333)the Program for Young Talents of Science and Technology in Universities of Inner Mongolia Autonomous Region(Grant No.NJYT24070)+1 种基金the Natural Science Foundation of Inner Mongolia(Grant No.2024MS05029)the Research Project of Carbon Peak and Carbon Neutrality in Universities of Inner Mongolia Autonomous Region(Grant No.STZX202316).
文摘The substantial influences of Mo contents varying from 0 to 0.26 and 0.50 wt.%on the microstructural evolution and MX(M=Nb,V and Mo;X=C and N)precipitation characteristics of Nb–V–N microalloyed steels processed by hot deformation and continuous cooling were studied using a Gleeble 3800 thermomechanical simulator.Metallographic analysis showed that the ferrite microstructure transformed from polygonal ferrite(PF)in 0Mo steel to both acicular ferrite(AF)and PF in 0.26Mo and 0.50Mo steels,and AF content first increased and then decreased.The thermodynamic calculations and the experimental results proved that the quantity of solid solution of Mo in austenite obviously increased,which reduced the austenite(γ)to ferrite(α)transformation temperature,consequently promoting AF formation in 0.26Mo steel and bainite transformation in 0.50Mo steel.Moreover,the submicron Nb-rich MX particles that precipitated at the temperature of the austenite region further induced AF heterogeneous nucleation with an orientation relationship of(100)_(MX)//(100)_(Ferrite)and[■][001]Ferrite.The interphase precipitation of the nanosized V-rich MX particles with Mo partitioning that precipitated duringγ→αtransformation exhibited a Baker–Nutting orientation relationship of(100)_(MX)//(100)Ferrite and[001]_(MX)//[■]_(Ferrite)with respect to the ferrite matrix.With increasing Mo content from 0 to 0.26 and 0.50 wt.%,the sheet spacing decreased from 46.9–49.0 to 34.6–38.6 and 25.7–28.0 nm,respectively,which evidently hindered dislocation movement and greatly enhanced precipitation strengthening.Furthermore,facilitating AF formation and interphase precipitation was beneficial to improving steel properties,and the optimal Mo content was 0.26 wt.%.
