Nanostructured MnO2/CNT composite was synthesized by a soft template approach in the presence of Pluronic P123 surfactant. The product was characterized by X-ray diffraction, thermogravimetric and differential thermal...Nanostructured MnO2/CNT composite was synthesized by a soft template approach in the presence of Pluronic P123 surfactant. The product was characterized by X-ray diffraction, thermogravimetric and differential thermal analyses, Fourier transformed infrared spectroscopy and high-resolution transmission electron microscopy. The results show that the sample consists of poor crystalline α-MnO2 nanorods with a diameter of about 10 nm and a length of 30-50 nm, which absorb on the carbon nanotubes. The electrochemical properties of the product as cathode material for Li-MnO2 cell are evaluated by galvanostatic charge-discharge and electrochemical impedance spectroscopy （EIS）. Compared with pure MnO2 electrode, the MnO2/CNT composite delivers a much larger initial capacity of 275.3 mA-h/g and better rate and cycling performance.展开更多
MnO_(2)作为超级电容器电极材料具有理论比电容高、成本低、环境友好等优点,但其低导电性和低利用率阻碍了其潜在应用.本研究首先在柔性碳布上电化学生长ZnO纳米棒阵列作为电极衬底,然后通过阳极电沉积法在ZnO纳米棒阵列表面外延生长了M...MnO_(2)作为超级电容器电极材料具有理论比电容高、成本低、环境友好等优点,但其低导电性和低利用率阻碍了其潜在应用.本研究首先在柔性碳布上电化学生长ZnO纳米棒阵列作为电极衬底,然后通过阳极电沉积法在ZnO纳米棒阵列表面外延生长了Mo和碳纳米管(CNTs)共掺杂的MnO_(2)薄膜,可控构筑了有效、高导电性的MnO_(2)纳米阵列电极(定义为ZnO@Mo-CNT-MnO_(2)NA).柔性ZnO@Mo-CNTMnO_(2)NA电极在100 A g^(-1)的大电流充放电密度下比电容可达237.5 F g^(-1),10,000次循环后电容保留率高达86%.采用ZnO@Mo-CNTMnO_(2)NA电极组装成水系非对称超级电容器,弯曲状态下在132.35 mW cm^(-3)(5mA cm^(-2))高功率密度下获得了1.13 mW h cm^(-3)的高能量密度,5mA cm^(-2)充放电倍率下循环7600次后电容保留率高达88%.本研究构筑的MnO_(2)基纳米阵列电极结构可提高其电导率和利用率,为柔性金属氧化物超级电容器电极的设计与制备提供新途径.展开更多
基金Projects(21071153,20976198)supported by the National Natural Science Foundation of China
文摘Nanostructured MnO2/CNT composite was synthesized by a soft template approach in the presence of Pluronic P123 surfactant. The product was characterized by X-ray diffraction, thermogravimetric and differential thermal analyses, Fourier transformed infrared spectroscopy and high-resolution transmission electron microscopy. The results show that the sample consists of poor crystalline α-MnO2 nanorods with a diameter of about 10 nm and a length of 30-50 nm, which absorb on the carbon nanotubes. The electrochemical properties of the product as cathode material for Li-MnO2 cell are evaluated by galvanostatic charge-discharge and electrochemical impedance spectroscopy （EIS）. Compared with pure MnO2 electrode, the MnO2/CNT composite delivers a much larger initial capacity of 275.3 mA-h/g and better rate and cycling performance.
基金supported by the National Key R&D Program of China(2017YFA0208200)the National Natural Science Foundation of China(51862026,22022505 and 21872069)+4 种基金the Aeronautical Science Foundation of China(2017ZF56027)the Natural Science Foundation of Jiangxi Province(20192ACBL21048)the Key Research and Development Program of Jiangxi Province(20203BBE53069)the Fundamental Research Funds for the Central Universities(020514380266,020514380272 and 020514380274)the Scientific and Technological Innovation Special Fund for Carbon Peak and Carbon Neutrality of Jiangsu Province(BK20220008)。
文摘MnO_(2)作为超级电容器电极材料具有理论比电容高、成本低、环境友好等优点,但其低导电性和低利用率阻碍了其潜在应用.本研究首先在柔性碳布上电化学生长ZnO纳米棒阵列作为电极衬底,然后通过阳极电沉积法在ZnO纳米棒阵列表面外延生长了Mo和碳纳米管(CNTs)共掺杂的MnO_(2)薄膜,可控构筑了有效、高导电性的MnO_(2)纳米阵列电极(定义为ZnO@Mo-CNT-MnO_(2)NA).柔性ZnO@Mo-CNTMnO_(2)NA电极在100 A g^(-1)的大电流充放电密度下比电容可达237.5 F g^(-1),10,000次循环后电容保留率高达86%.采用ZnO@Mo-CNTMnO_(2)NA电极组装成水系非对称超级电容器,弯曲状态下在132.35 mW cm^(-3)(5mA cm^(-2))高功率密度下获得了1.13 mW h cm^(-3)的高能量密度,5mA cm^(-2)充放电倍率下循环7600次后电容保留率高达88%.本研究构筑的MnO_(2)基纳米阵列电极结构可提高其电导率和利用率,为柔性金属氧化物超级电容器电极的设计与制备提供新途径.
