Active Fe-and Mn-loaded MCM-41(Fe–Mn/MCM-41),which was synthesized via a hydrothermal reaction followed by impregnation,is used in the heterogeneous Fenton reaction to degrade methyl orange(MO) in aqueous solution. T...Active Fe-and Mn-loaded MCM-41(Fe–Mn/MCM-41),which was synthesized via a hydrothermal reaction followed by impregnation,is used in the heterogeneous Fenton reaction to degrade methyl orange(MO) in aqueous solution. The synthesized samples were characterized by X-ray diffraction,scanning electron microscopy,transmission electron microscopy,N_2 adsorption–desorption isotherm analysis,Fourier transform infrared spectroscopy,and X-ray photoelectron spectroscopy. Compared with Fe/MCM-41 and Mn/MCM-41,Fe–Mn/MCM-41 showed higher activity for MO degradation and mineralization. Effects of various operating parameters,such as pH,Mn content,and H_2O_2 dosage,on the degradation process were subsequently investigated. Results of experiments on the effect of radical scavengers revealed that the degradation of MO could be attributed to oxidation by HO_·. The synergy of Fe and Mn species in the Fenton oxidation process was also explained.展开更多
We have investigated the magnetic transition and magnetocaloric effects of Mn1＋xCo1-xGe alloys by tuning the ratio of Mn/Co. With increasing Mn content, a series of first-order magnetostructural transitions from ferr...We have investigated the magnetic transition and magnetocaloric effects of Mn1＋xCo1-xGe alloys by tuning the ratio of Mn/Co. With increasing Mn content, a series of first-order magnetostructural transitions from ferromagnetic to paramagnetic states with large changes of magnetization are observed at room temperature. Further increasing the content of Mn （x = 0.11） gives rise to a single second-order magnetic transition. Interestingly, large low-field magnetic entropy changes with almost zero magnetic hysteresis are observed in these alloys. The effects of Mn/Co ratio on magnetic transition and magnetocaloric effects are discussed in this paper.展开更多
Lake Aha in Guizhou Province, China is a medium-sized artificial reservoir with seasonally anoxic hypolimnion. Long-term sedimentary accumulation of iron and manganese resulted in their enrichment in the upper sedimen...Lake Aha in Guizhou Province, China is a medium-sized artificial reservoir with seasonally anoxic hypolimnion. Long-term sedimentary accumulation of iron and manganese resulted in their enrichment in the upper sediments. In anoxic season, Fe2+ and Mn2+ formed from bioledcal oxidation, would diffuse upto upper water from sediments. However, the concentration of Fe2+ incrlater and decreased earlier than that of Mn2+. Generally, Sulfate reduction occUrred at 6cm below the sediment-water interface. Whereas, in anoxic season, the reduction reached sediment top, inhibiting the release of Fe2+. As the oxidation of Mn2+ required molecular oxygen as catalyst, Serious anoxia caused the violent diffusion of Mn2+. Based on the bio-effects on the accumulation of Mn in natural fresh water, it’s necessary to seek a way to control manganese rerelease through accumulated manganese bacteria action.Keywrods: petdeopitional migration of Fe and Mn, biogaxhemical effect, Lake展开更多
Due to traffic and wave actions, cast steel joints are subjected to variable-amplitude fatigue loading, which may cause fatigue problems. The ratio of the minimum strain to the maximum strain(strain ratio)can be emplo...Due to traffic and wave actions, cast steel joints are subjected to variable-amplitude fatigue loading, which may cause fatigue problems. The ratio of the minimum strain to the maximum strain(strain ratio)can be employed to analyze the influence of variable-amplitude fatigue both in the elastic and plastic ranges. To evaluate the effect of the strain ratio on G20Mn5 QT cast steel, the fatigue tests of smooth specimens were carried out at the strain ratio of 0.1. The cyclic deformation and the relationships between the strain amplitude, the stress amplitude, the Smith, Watson and Topper(SWT)parameter and fatigue life were studied and compared with those at the strain ratio of-1. Compared with other methods, Basquin formula and Solonberg formula provide reliable and appropriate ranges of S-N curve and fatigue limit at different strain ratios respectively. The SWT parameter can be used to predict the fatigue life at other strain ratios accurately.展开更多
基金supported by the National Basic Research Program of China ("973" Program, No. 2012CB720302)Program for Changjiang Scholars and the Innovative Research Team in Universities (No. IRT0936)
文摘Active Fe-and Mn-loaded MCM-41(Fe–Mn/MCM-41),which was synthesized via a hydrothermal reaction followed by impregnation,is used in the heterogeneous Fenton reaction to degrade methyl orange(MO) in aqueous solution. The synthesized samples were characterized by X-ray diffraction,scanning electron microscopy,transmission electron microscopy,N_2 adsorption–desorption isotherm analysis,Fourier transform infrared spectroscopy,and X-ray photoelectron spectroscopy. Compared with Fe/MCM-41 and Mn/MCM-41,Fe–Mn/MCM-41 showed higher activity for MO degradation and mineralization. Effects of various operating parameters,such as pH,Mn content,and H_2O_2 dosage,on the degradation process were subsequently investigated. Results of experiments on the effect of radical scavengers revealed that the degradation of MO could be attributed to oxidation by HO_·. The synergy of Fe and Mn species in the Fenton oxidation process was also explained.
基金Project supported by the National Natural Science Foundation of China (Grant Nos. 50701022,51001019,and 50831006)the Program for New Century Excellent Talents of China (Grant No. NCET-08-0278)
文摘We have investigated the magnetic transition and magnetocaloric effects of Mn1＋xCo1-xGe alloys by tuning the ratio of Mn/Co. With increasing Mn content, a series of first-order magnetostructural transitions from ferromagnetic to paramagnetic states with large changes of magnetization are observed at room temperature. Further increasing the content of Mn （x = 0.11） gives rise to a single second-order magnetic transition. Interestingly, large low-field magnetic entropy changes with almost zero magnetic hysteresis are observed in these alloys. The effects of Mn/Co ratio on magnetic transition and magnetocaloric effects are discussed in this paper.
文摘Lake Aha in Guizhou Province, China is a medium-sized artificial reservoir with seasonally anoxic hypolimnion. Long-term sedimentary accumulation of iron and manganese resulted in their enrichment in the upper sediments. In anoxic season, Fe2+ and Mn2+ formed from bioledcal oxidation, would diffuse upto upper water from sediments. However, the concentration of Fe2+ incrlater and decreased earlier than that of Mn2+. Generally, Sulfate reduction occUrred at 6cm below the sediment-water interface. Whereas, in anoxic season, the reduction reached sediment top, inhibiting the release of Fe2+. As the oxidation of Mn2+ required molecular oxygen as catalyst, Serious anoxia caused the violent diffusion of Mn2+. Based on the bio-effects on the accumulation of Mn in natural fresh water, it’s necessary to seek a way to control manganese rerelease through accumulated manganese bacteria action.Keywrods: petdeopitional migration of Fe and Mn, biogaxhemical effect, Lake
基金Supported by the National Natural Science Foundation of China(No.51178307 and No.51525803)
文摘Due to traffic and wave actions, cast steel joints are subjected to variable-amplitude fatigue loading, which may cause fatigue problems. The ratio of the minimum strain to the maximum strain(strain ratio)can be employed to analyze the influence of variable-amplitude fatigue both in the elastic and plastic ranges. To evaluate the effect of the strain ratio on G20Mn5 QT cast steel, the fatigue tests of smooth specimens were carried out at the strain ratio of 0.1. The cyclic deformation and the relationships between the strain amplitude, the stress amplitude, the Smith, Watson and Topper(SWT)parameter and fatigue life were studied and compared with those at the strain ratio of-1. Compared with other methods, Basquin formula and Solonberg formula provide reliable and appropriate ranges of S-N curve and fatigue limit at different strain ratios respectively. The SWT parameter can be used to predict the fatigue life at other strain ratios accurately.
