This study numerically examines the heat and mass transfer characteristics of two ternary nanofluids via converging and diverg-ing channels.Furthermore,the study aims to assess two ternary nanofluids combinations to d...This study numerically examines the heat and mass transfer characteristics of two ternary nanofluids via converging and diverg-ing channels.Furthermore,the study aims to assess two ternary nanofluids combinations to determine which configuration can provide better heat and mass transfer and lower entropy production,while ensuring cost efficiency.This work bridges the gap be-tween academic research and industrial feasibility by incorporating cost analysis,entropy generation,and thermal efficiency.To compare the velocity,temperature,and concentration profiles,we examine two ternary nanofluids,i.e.,TiO_(2)+SiO_(2)+Al_(2)O_(3)/H_(2)O and TiO_(2)+SiO_(2)+Cu/H_(2)O,while considering the shape of nanoparticles.The velocity slip and Soret/Dufour effects are taken into consideration.Furthermore,regression analysis for Nusselt and Sherwood numbers of the model is carried out.The Runge-Kutta fourth-order method with shooting technique is employed to acquire the numerical solution of the governed system of ordinary differential equations.The flow pattern attributes of ternary nanofluids are meticulously examined and simulated with the fluc-tuation of flow-dominating parameters.Additionally,the influence of these parameters is demonstrated in the flow,temperature,and concentration fields.For variation in Eckert and Dufour numbers,TiO_(2)+SiO_(2)+Al_(2)O_(3)/H_(2)O has a higher temperature than TiO_(2)+SiO_(2)+Cu/H_(2)O.The results obtained indicate that the ternary nanofluid TiO_(2)+SiO_(2)+Al_(2)O_(3)/H_(2)O has a higher heat transfer rate,lesser entropy generation,greater mass transfer rate,and lower cost than that of TiO_(2)+SiO_(2)+Cu/H_(2)O ternary nanofluid.展开更多
The present study introduces a screw-pressing charging method to tackle deficiencies in automation and charge uniformity during the melt-casting of polymer-based energetic materials.To ensure the safety of the experim...The present study introduces a screw-pressing charging method to tackle deficiencies in automation and charge uniformity during the melt-casting of polymer-based energetic materials.To ensure the safety of the experiments,this study used inert materials with similar physical properties to partially substitute for the actual energetic components in the preparation of simulant materials.By thoroughly analyzing slurry physical properties,a simulation framework and an extensive performance evaluation method were developed.Such tools guide the design of the structure and configuration of process parameters.Results demonstrate that employing the Pin element significantly enhances radial mixing within the screw,minimizes temperature variations in the slurry,and improves both efficiency and safety in the mixing process.Further,adjustments such as widening the cone angle of the barrel,modifying the solid content of the slurry,and varying the speed of the screw can optimize the mechanical and thermal coupling in the flow field.These adjustments promote higher-quality slurry and create a safer production environment for the extrusion process.展开更多
The implementation of ultrahigh-Ni cathodes in high-energy lithium-ion batteries(LIBs)is constrained by significant structural and interfacial degradation during cycling.In this study,doping-induced surface restructur...The implementation of ultrahigh-Ni cathodes in high-energy lithium-ion batteries(LIBs)is constrained by significant structural and interfacial degradation during cycling.In this study,doping-induced surface restructuring in ultrahigh-nickel cathode materials is rapidly facilitated through an ultrafast Joule heating method.Density functional theory(DFT)calculations,synchrotron X-ray absorption spectroscopy(XAS),and single-particle force test confirmed the establishment of a stable crystal framework and lattice oxygen,which mitigated H2-H3 phase transitions and improved structural reversibility.Additionally,the Sc doping process exhibits a pinning effect on the grain boundaries,as shown by scanning transmission electron microscopy(STEM),enhancing Li~+diffusion kinetics and decreasing mechanical strain during cycling.The in situ development of a cation-mixing layer at grain boundaries also creates a robust cathode/electrolyte interphase,effectively reducing interfacial parasitic reactions and transition metal dissolution,as validated by STEM and time-of-flight secondary ion mass spectrometry(TOF-SIMS).These synergistic modifications reduce particle cracking and surface/interface degradation,leading to enhanced rate capability,structural integrity,and thermal stability.Consequently,the optimized Sc-modified ultrahigh-Ni cathode(Sc-1)exhibits 93.99%capacity retention after 100 cycles at 1 C(25℃)and87.06%capacity retention after 100 cycles at 1 C(50℃),indicating excellent cycling and thermal stability.By presenting a one-step multifunctional modification approach,this research delivers an extensive analysis of the mechanisms governing the structure,microstructure,and interface properties of nickel-rich layered cathode materials(NCMs).These results underscore the potential of ultrahigh-Ni cathodes as viable candidates for advanced lithium-ion batteries(LIBs)in next-generation electric vehicles(EVs).展开更多
In this study,we examine the problem of sliced inverse regression(SIR),a widely used method for sufficient dimension reduction(SDR).It was designed to find reduced-dimensional versions of multivariate predictors by re...In this study,we examine the problem of sliced inverse regression(SIR),a widely used method for sufficient dimension reduction(SDR).It was designed to find reduced-dimensional versions of multivariate predictors by replacing them with a minimally adequate collection of their linear combinations without loss of information.Recently,regularization methods have been proposed in SIR to incorporate a sparse structure of predictors for better interpretability.However,existing methods consider convex relaxation to bypass the sparsity constraint,which may not lead to the best subset,and particularly tends to include irrelevant variables when predictors are correlated.In this study,we approach sparse SIR as a nonconvex optimization problem and directly tackle the sparsity constraint by establishing the optimal conditions and iteratively solving them by means of the splicing technique.Without employing convex relaxation on the sparsity constraint and the orthogonal constraint,our algorithm exhibits superior empirical merits,as evidenced by extensive numerical studies.Computationally,our algorithm is much faster than the relaxed approach for the natural sparse SIR estimator.Statistically,our algorithm surpasses existing methods in terms of accuracy for central subspace estimation and best subset selection and sustains high performance even with correlated predictors.展开更多
The impact of different global and local variables in urban development processes requires a systematic study to fully comprehend the underlying complexities in them.The interplay between such variables is crucial for...The impact of different global and local variables in urban development processes requires a systematic study to fully comprehend the underlying complexities in them.The interplay between such variables is crucial for modelling urban growth to closely reflects reality.Despite extensive research,ambiguity remains about how variations in these input variables influence urban densification.In this study,we conduct a global sensitivity analysis(SA)using a multinomial logistic regression(MNL)model to assess the model’s explanatory and predictive power.We examine the influence of global variables,including spatial resolution,neighborhood size,and density classes,under different input combinations at a provincial scale to understand their impact on densification.Additionally,we perform a stepwise regression to identify the significant explanatory variables that are important for understanding densification in the Brussels Metropolitan Area(BMA).Our results indicate that a finer spatial resolution of 50 m and 100 m,smaller neighborhood size of 5×5 and 3×3,and specific density classes—namely 3(non-built-up,low and high built-up)and 4(non-built-up,low,medium and high built-up)—optimally explain and predict urban densification.In line with the same,the stepwise regression reveals that models with a coarser resolution of 300 m lack significant variables,reflecting a lower explanatory power for densification.This approach aids in identifying optimal and significant global variables with higher explanatory power for understanding and predicting urban densification.Furthermore,these findings are reproducible in a global urban context,offering valuable insights for planners,modelers and geographers in managing future urban growth and minimizing modelling.展开更多
Triaxial tests,a staple in rock engineering,are labor-intensive,sample-demanding,and costly,making their optimization highly advantageous.These tests are essential for characterizing rock strength,and by adopting a fa...Triaxial tests,a staple in rock engineering,are labor-intensive,sample-demanding,and costly,making their optimization highly advantageous.These tests are essential for characterizing rock strength,and by adopting a failure criterion,they allow for the derivation of criterion parameters through regression,facilitating their integration into modeling programs.In this study,we introduce the application of an underutilized statistical technique—orthogonal regression—well-suited for analyzing triaxial test data.Additionally,we present an innovation in this technique by minimizing the Euclidean distance while incorporating orthogonality between vectors as a constraint,for the case of orthogonal linear regression.Also,we consider the Modified Least Squares method.We exemplify this approach by developing the necessary equations to apply the Mohr-Coulomb,Murrell,Hoek-Brown,andÚcar criteria,and implement these equations in both spreadsheet calculations and R scripts.Finally,we demonstrate the technique's application using five datasets of varied lithologies from specialized literature,showcasing its versatility and effectiveness.展开更多
Gastric cancer is the third leading cause of cancer-related mortality and remains a major global health issue^([1]).Annually,approximately 479,000individuals in China are diagnosed with gastric cancer,accounting for a...Gastric cancer is the third leading cause of cancer-related mortality and remains a major global health issue^([1]).Annually,approximately 479,000individuals in China are diagnosed with gastric cancer,accounting for almost 45%of all new cases worldwide^([2]).展开更多
In recent years,machine learning(ML)techniques have been shown to be effective in accelerating the development process of optoelectronic devices.However,as"black box"models,they have limited theoretical inte...In recent years,machine learning(ML)techniques have been shown to be effective in accelerating the development process of optoelectronic devices.However,as"black box"models,they have limited theoretical interpretability.In this work,we leverage symbolic regression(SR)technique for discovering the explicit symbolic relationship between the structure of the optoelectronic Fabry-Perot(FP)laser and its optical field distribution,which greatly improves model transparency compared to ML.We demonstrated that the expressions explored through SR exhibit lower errors on the test set compared to ML models,which suggests that the expressions have better fitting and generalization capabilities.展开更多
Developing cost-effective single-crystalline Ni-rich Co-poor cathodes operating at high-voltage is one of the most important ways to achieve higher energy Li-ion batteries. However, the Li/O loss and Li/Ni mixing unde...Developing cost-effective single-crystalline Ni-rich Co-poor cathodes operating at high-voltage is one of the most important ways to achieve higher energy Li-ion batteries. However, the Li/O loss and Li/Ni mixing under high-temperature lithiation result in electrochemical kinetic hysteresis and structural instability. Herein, we report a highly-ordered single-crystalline LiNi0.85Co0.05Mn0.10O2(NCM85) cathode by doping K+and F-ions. To be specific, the K-ion as a fluxing agent can remarkably decrease the solid-state lithiation temperature by ~30°C, leading to less Li/Ni mixing and oxygen vacancy. Meanwhile, the strong transitional metal(TM)-F bonds are helpful for enhancing de-/lithiation kinetics and limiting the lattice oxygen escape even at 4.5 V high-voltage. Their advantages synergistically endow the single-crystalline NCM85 cathode with a very high reversible capacity of 222.3 mAh g-1. A superior capacity retention of 91.3% is obtained after 500 times at 1 C in pouch-type full cells, and a prediction value of 75.3% is given after cycling for 5000 h. These findings are reckoned to expedite the exploitation and application of high-voltage single-crystalline Ni-rich cathodes for next-generation Li-ion batteries.展开更多
Background:The COVID-1’s impact on influenza activity is of interest to inform future flu prevention and control strategies.Our study aim to examine COVID-19’s effects on influenza in Fujian Province,China,using a r...Background:The COVID-1’s impact on influenza activity is of interest to inform future flu prevention and control strategies.Our study aim to examine COVID-19’s effects on influenza in Fujian Province,China,using a regression discontinuity design.Methods:We utilized influenza-like illness(ILI)percentage as an indicator of influenza activity,with data from all sentinel hospitals between Week 4,2020,and Week 51,2023.The data is divided into two groups:the COVID-19 epidemic period and the post-epidemic period.Statistical analysis was performed with R software using robust RD design methods to account for potential confounders including seasonality,temperature,and influenza vaccination rates.Results:There was a discernible increase in the ILI percentage during the post-epidemic period.The robustness of the findings was confirmed with various RD design bandwidth selection methods and placebo tests,with certwo bandwidth providing the largest estimated effect size:a 14.6-percentage-point increase in the ILI percentage(β=0.146;95%CI:0.096–0.196).Sensitivity analyses and adjustments for confounders consistently pointed to an increased ILI percentage during the post-epidemic period compared to the epidemic period.Conclusion:The 14.6 percentage-point increase in the ILI percentage in Fujian Province,China,after the end of the COVID-19 pandemic suggests that there may be a need to re-evaluate and possibly enhance public health measures to control influenza transmission.Further research is needed to fully understand the factors contributing to this rise and to assess the ongoing impacts of post-pandemic behavioral changes.展开更多
In petroleum,mercaptan impurities generate malodorous fumes that pose risks to both human health and the environment,and leading to substandard oil quality.Lye desulfurization is a widely employed technique for elimin...In petroleum,mercaptan impurities generate malodorous fumes that pose risks to both human health and the environment,and leading to substandard oil quality.Lye desulfurization is a widely employed technique for eliminating mercaptans from oil.In traditional scrubber towers,lye and oil are poorly mixed,the desulfurization efficiency is low,and the lye consumption is high.To enhance washing efficiency,a droplet micromixer and corresponding fiber coalescence separator were developed.By optimizing the structure and operating parameters,more effective mixing and separation were achieved,and both caustic washing and desulfurization were enhanced.The proposed mixer/separator outperforms the industry standard by reducing the caustic loading by 30%and offers superior economic and engineering performances.The results of this study offer a direction for designing and optimizing a mercaptan removal unit to enhance the scrubbing effectiveness and decrease expenses to achieve more efficient and green production process.展开更多
The mixing process plays a pivotal role in the design,optimization,and scale-up of chemical reactors.For most chemical reactions,achieving uniform and rapid contact between reactants at the molecular level is crucial....The mixing process plays a pivotal role in the design,optimization,and scale-up of chemical reactors.For most chemical reactions,achieving uniform and rapid contact between reactants at the molecular level is crucial.Mixing intensification encompasses innovative methods and tools that address the limitations of inadequate mixing within reactors,enabling efficient reaction scaling and boosting the productivity of industrial processes.This review provides a concise introduction to the fundamentals of multiphase mixing,followed by case studies highlighting the application of mixing intensification in the production of energy-storage materials,advanced optical materials,and nanopesticides.These examples illustrate the significance of theoretical analysis in informing and advancing engineering practices within the chemical industry.We also explore the challenges and opportunities in this field,offering insights based on our current understanding.展开更多
Open channel confluences,where two streams or rivers converge,play a crucial role in hydraulic engineering and river dynamics.These confluences are characterized by complex hydrodynamics influenced by the discharge ra...Open channel confluences,where two streams or rivers converge,play a crucial role in hydraulic engineering and river dynamics.These confluences are characterized by complex hydrodynamics influenced by the discharge ratios of merging water bodies.This study investigated the mixing structure at open channel confluences using three-dimensional numerical modeling.A comprehensive three-dimensional numerical model was developed and validated against a dataset obtained from controlled laboratory experiments.This dataset incorporated three-dimensional time-averaged velocity measurements.The skew-induced and stress-induced equation systems were adopted as the core governing equations,providing a framework for simulating various scenarios.A total of ten different cases were analyzed.The results highlighted the effect of discharge ratios on turbulence,lateral and vertical vorticities,and the distribution of mixing,which intensified with higher magnitudes of discharge ratios.The mixing structure,driven by velocity gradients and vorticity,revealed the significant role of lateral and vertical vorticities in determining hydrodynamic behaviors and mixing distributions at confluences.Specifically,the momentum ratio of incoming flows governed the spatial evolution of mixing processes.This study revealed that the distribution of mixing served as a key indicator for identifying the formation of mid-channel scours.High normalized velocities induced toward the left bank led to the superelevation of the water surface,enhancing the potential for bed material and the formation of significant scour holes beneath the elevated water surface.This novel approach provides a deeper understanding of the mixing patterns at confluences,particularly in scenarios with equilibrated discharge ratios but in different magnitudes.展开更多
This opinion article discusses the original research work of Yünkül et al.(the Authors)published in the Journal of Mountain Science 21(9):3108–3122.Employing non-linear regression,fuzzy logic and artificial...This opinion article discusses the original research work of Yünkül et al.(the Authors)published in the Journal of Mountain Science 21(9):3108–3122.Employing non-linear regression,fuzzy logic and artificial neural network modeling techniques,the Authors interrogated a large database assembled from the existing research literature to assess the performance of twelve equation rules in predicting the undrained shear strength(s_(u))mobilized for remolded fine-grained soils at different values of liquidity index(I_(L))and water content ratio.Based on their analyses,the Authors proposed a simple and reportedly reliable correlation(i.e.,Eq.9 in their paper)for predicting s_(u) over the I_(L) range of 0.15 to 3.00.This article describes various shortcomings in the Authors’assembled database(including potentially anomalous data and covering an excessively wide I_(L) range in relation to routine geotechnical and transportation engineering applications)and their proposed s_(u)=f(I_(L))correlation.Contrary to the Authors’assertions,their proposed correlation is not reliable for fine-grained soils with consistencies in the general firm to stiff range(i.e.,for 0.15<I_(L)<0.40),increasingly overestimating s_(u) for reducing I_(L),and eventually predicting s_(u)→+∞for I_(L)→0.15+(while producing mathematically undefined s_(u) for I_(L)<0.15),thus rendering their correlation unconservative and potentially leading to unsafe geotechnical designs.Exponential or regular-power type s_(u)=f(I_(L))models are more s_(u)itable when developing correlations that are applicable over the full plastic range(of 0<I_(L)<1),thereby providing reasonably conservative s_(u) predictions for use in the preliminary design for routine geotechnical engineering applications.展开更多
Frequency conversion is pivotal in nonlinear optics and quantum optics for manipulating and translating light signals across different wavelength regimes.Achieving frequency conversion between two light beams with a s...Frequency conversion is pivotal in nonlinear optics and quantum optics for manipulating and translating light signals across different wavelength regimes.Achieving frequency conversion between two light beams with a small frequency interval is a central challenge.In this work,we design a pair of coupled silicon microrings wherein coupled-induced modesplitting exists to achieve a small frequency shift by the process of four-wave mixing Bragg scattering.As an example,the signal can be up or down converted to the idler which is 15.5 GHz spaced when two pumps align with another pair of split resonances.The results unveil the potential of coupled microring resonators for small interval frequency conversion in a high-fidelity,all-optical,and signal processing quantum frequency interface.展开更多
This paper focuses on the technical management of concrete mixing plants.It introduces the whole-process engineering consulting model and elaborates on multifaceted aspects of technical management,including a matrix-b...This paper focuses on the technical management of concrete mixing plants.It introduces the whole-process engineering consulting model and elaborates on multifaceted aspects of technical management,including a matrix-based management framework,standardized design management pathways,cost early-warning systems,approval strategies,regulatory databases,etc.This paper also emphasizes the importance of innovations in collaborative management mechanisms for improving quality and efficiency.展开更多
In clinical research,subgroup analysis can help identify patient groups that respond better or worse to specific treatments,improve therapeutic effect and safety,and is of great significance in precision medicine.This...In clinical research,subgroup analysis can help identify patient groups that respond better or worse to specific treatments,improve therapeutic effect and safety,and is of great significance in precision medicine.This article considers subgroup analysis methods for longitudinal data containing multiple covariates and biomarkers.We divide subgroups based on whether a linear combination of these biomarkers exceeds a predetermined threshold,and assess the heterogeneity of treatment effects across subgroups using the interaction between subgroups and exposure variables.Quantile regression is used to better characterize the global distribution of the response variable and sparsity penalties are imposed to achieve variable selection of covariates and biomarkers.The effectiveness of our proposed methodology for both variable selection and parameter estimation is verified through random simulations.Finally,we demonstrate the application of this method by analyzing data from the PA.3 trial,further illustrating the practicality of the method proposed in this paper.展开更多
High-dimensional heterogeneous data have acquired increasing attention and discussion in the past decade.In the context of heterogeneity,semiparametric regression emerges as a popular method to model this type of data...High-dimensional heterogeneous data have acquired increasing attention and discussion in the past decade.In the context of heterogeneity,semiparametric regression emerges as a popular method to model this type of data in statistics.In this paper,we leverage the benefits of expectile regression for computational efficiency and analytical robustness in heterogeneity,and propose a regularized partially linear additive expectile regression model with a nonconvex penalty,such as SCAD or MCP,for high-dimensional heterogeneous data.We focus on a more realistic scenario where the regression error exhibits a heavy-tailed distribution with only finite moments.This scenario challenges the classical sub-gaussian distribution assumption and is more prevalent in practical applications.Under certain regular conditions,we demonstrate that with probability tending to one,the oracle estimator is one of the local minima of the induced optimization problem.Our theoretical analysis suggests that the dimensionality of linear covariates that our estimation procedure can handle is fundamentally limited by the moment condition of the regression error.Computationally,given the nonconvex and nonsmooth nature of the induced optimization problem,we have developed a two-step algorithm.Finally,our method’s effectiveness is demonstrated through its high estimation accuracy and effective model selection,as evidenced by Monte Carlo simulation studies and a real-data application.Furthermore,by taking various expectile weights,our method effectively detects heterogeneity and explores the complete conditional distribution of the response variable,underscoring its utility in analyzing high-dimensional heterogeneous data.展开更多
Branch size is a crucial characteristic,closely linked to both tree growth and wood quality.A review of existing branch size models reveals various approaches,but the ability to estimate branch diameter and length wit...Branch size is a crucial characteristic,closely linked to both tree growth and wood quality.A review of existing branch size models reveals various approaches,but the ability to estimate branch diameter and length within the same whorl remains underexplored.In this study,a total of 77 trees were sampled from Northeast China to model the vertical distribution of branch diameter and length within each whorl along the crown.Several commonly used functions were taken as the alternative model forms,and the quantile regression method was employed and compared with the classical two-step modeling approach.The analysis incorporated stand,tree,and competition factors,with a particular focus on how these factors influence branches of varying sizes.The modified Weibull function was chosen as the optimal model,due to its excellent performance across all quantiles.Eight quantile regression curves(ranging from 0.20 to 0.85)were combined to predict branch diameter,while seven curves(ranging from 0.20 to 0.80)were used for branch length.The results showed that the quantile regression method outperformed the classical approach at model fitting and validation,likely due to its ability to estimate different rates of change across the entire branch size distribution.Lager branches in each whorl were more sensitive to changes in DBH,crown length(CL),crown ratio(CR)and dominant tree height(H_(dom)),while slenderness(HDR)more effectively influenced small and medium-sized branches.The effect of stand basal area(BAS)was relatively consistent across different branch sizes.The findings indicate that quantile regression is a good way not only a more accurate method for predicting branch size but also a valuable tool for understanding how branch growth responds to stand and tree factors.The models developed in this study are prepared to be further integrated into tree growth and yield simulation system,contributing to the assessment and promotion of wood quality.展开更多
Global Navigation Satellite System(GNSS)imaging method(GIM)has been successfully applied to global regions to investigate vertical land motion(VLM)of the Earth's surface.GNSS images derived from conventional GIM m...Global Navigation Satellite System(GNSS)imaging method(GIM)has been successfully applied to global regions to investigate vertical land motion(VLM)of the Earth's surface.GNSS images derived from conventional GIM method may present fragmented patches and encounter problems caused by excessive smoothing of velocity peaks,leading to difficulty in short-wavelength deformation detection and improper geophysical interpretation.Therefore,we propose a novel GNSS imaging method based on Gaussian process regression with velocity uncertainty considered(GPR-VU).Gaussian processing regression is introduced to describe the spatial relationship between neighboring site pairs as a priori weights and then reweight velocities by known station uncertainties,converting the discrete velocity field to a continuous one.The GPR-VU method is applied to reconstruct VLM images in the southwestern United States and the eastern Qinghai-Xizang Plateau,China,using the GNSS position time series in vertical direction.Compared to the traditional GIM method,the root-mean-square(RMS)and overall accuracy of the confusion matrix of the GPR-VU method increase by 5.0%and 14.0%from the 1°×1°checkerboard test in the southwestern United States.Similarly,the RMS and overall accuracy increase by 33.7%and 15.8%from the 6°×6°checkerboard test in the eastern Qinghai-Xizang Plateau.These checkerboard tests validate the capability to effectively capture the spatiotemporal variations characteristics of VLM and show that this algorithm outperforms the sparsely distributed network in the Qinghai-Xizang Plateau.The images from the GPR-VU method using real data in both regions show significant subsidence around Lassen Volcanic in northern California within a 30 km radius,slight uplift in the northern Sichuan Basin,and subsidence in its central and southern sections.These results further qualitatively illustrate consistency with previous findings.The GPR-VU method outperforms in diminishing the effect by fragmented patches,excessive smoothing of velocity peaks,and detecting potential short-wavelength deformations.展开更多
基金supported by DST-FIST(Government of India)(Grant No.SR/FIST/MS-1/2017/13)and Seed Money Project(Grant No.DoRDC/733).
文摘This study numerically examines the heat and mass transfer characteristics of two ternary nanofluids via converging and diverg-ing channels.Furthermore,the study aims to assess two ternary nanofluids combinations to determine which configuration can provide better heat and mass transfer and lower entropy production,while ensuring cost efficiency.This work bridges the gap be-tween academic research and industrial feasibility by incorporating cost analysis,entropy generation,and thermal efficiency.To compare the velocity,temperature,and concentration profiles,we examine two ternary nanofluids,i.e.,TiO_(2)+SiO_(2)+Al_(2)O_(3)/H_(2)O and TiO_(2)+SiO_(2)+Cu/H_(2)O,while considering the shape of nanoparticles.The velocity slip and Soret/Dufour effects are taken into consideration.Furthermore,regression analysis for Nusselt and Sherwood numbers of the model is carried out.The Runge-Kutta fourth-order method with shooting technique is employed to acquire the numerical solution of the governed system of ordinary differential equations.The flow pattern attributes of ternary nanofluids are meticulously examined and simulated with the fluc-tuation of flow-dominating parameters.Additionally,the influence of these parameters is demonstrated in the flow,temperature,and concentration fields.For variation in Eckert and Dufour numbers,TiO_(2)+SiO_(2)+Al_(2)O_(3)/H_(2)O has a higher temperature than TiO_(2)+SiO_(2)+Cu/H_(2)O.The results obtained indicate that the ternary nanofluid TiO_(2)+SiO_(2)+Al_(2)O_(3)/H_(2)O has a higher heat transfer rate,lesser entropy generation,greater mass transfer rate,and lower cost than that of TiO_(2)+SiO_(2)+Cu/H_(2)O ternary nanofluid.
基金financially supported by the Fundamental Research Funds for the Central Universities(Grant No.30923011018)。
文摘The present study introduces a screw-pressing charging method to tackle deficiencies in automation and charge uniformity during the melt-casting of polymer-based energetic materials.To ensure the safety of the experiments,this study used inert materials with similar physical properties to partially substitute for the actual energetic components in the preparation of simulant materials.By thoroughly analyzing slurry physical properties,a simulation framework and an extensive performance evaluation method were developed.Such tools guide the design of the structure and configuration of process parameters.Results demonstrate that employing the Pin element significantly enhances radial mixing within the screw,minimizes temperature variations in the slurry,and improves both efficiency and safety in the mixing process.Further,adjustments such as widening the cone angle of the barrel,modifying the solid content of the slurry,and varying the speed of the screw can optimize the mechanical and thermal coupling in the flow field.These adjustments promote higher-quality slurry and create a safer production environment for the extrusion process.
基金supported by the National Key R&D Program of China(2022YFB3803501)the National Natural Science Foundation of China(22179008,22209156)+5 种基金support from the Beijing Nova Program(20230484241)support from the China Postdoctoral Science Foundation(2024M754084)the Postdoctoral Fellowship Program of CPSF(GZB20230931)support from beamline BL08U1A of Shanghai Synchrotron Radiation Facility(2024-SSRF-PT-506950)beamline 1W1B of the Beijing Synchrotron Radiation Facility(2021-BEPC-PT-006276)support from Initial Energy Science&Technology Co.,Ltd(IEST)。
文摘The implementation of ultrahigh-Ni cathodes in high-energy lithium-ion batteries(LIBs)is constrained by significant structural and interfacial degradation during cycling.In this study,doping-induced surface restructuring in ultrahigh-nickel cathode materials is rapidly facilitated through an ultrafast Joule heating method.Density functional theory(DFT)calculations,synchrotron X-ray absorption spectroscopy(XAS),and single-particle force test confirmed the establishment of a stable crystal framework and lattice oxygen,which mitigated H2-H3 phase transitions and improved structural reversibility.Additionally,the Sc doping process exhibits a pinning effect on the grain boundaries,as shown by scanning transmission electron microscopy(STEM),enhancing Li~+diffusion kinetics and decreasing mechanical strain during cycling.The in situ development of a cation-mixing layer at grain boundaries also creates a robust cathode/electrolyte interphase,effectively reducing interfacial parasitic reactions and transition metal dissolution,as validated by STEM and time-of-flight secondary ion mass spectrometry(TOF-SIMS).These synergistic modifications reduce particle cracking and surface/interface degradation,leading to enhanced rate capability,structural integrity,and thermal stability.Consequently,the optimized Sc-modified ultrahigh-Ni cathode(Sc-1)exhibits 93.99%capacity retention after 100 cycles at 1 C(25℃)and87.06%capacity retention after 100 cycles at 1 C(50℃),indicating excellent cycling and thermal stability.By presenting a one-step multifunctional modification approach,this research delivers an extensive analysis of the mechanisms governing the structure,microstructure,and interface properties of nickel-rich layered cathode materials(NCMs).These results underscore the potential of ultrahigh-Ni cathodes as viable candidates for advanced lithium-ion batteries(LIBs)in next-generation electric vehicles(EVs).
文摘In this study,we examine the problem of sliced inverse regression(SIR),a widely used method for sufficient dimension reduction(SDR).It was designed to find reduced-dimensional versions of multivariate predictors by replacing them with a minimally adequate collection of their linear combinations without loss of information.Recently,regularization methods have been proposed in SIR to incorporate a sparse structure of predictors for better interpretability.However,existing methods consider convex relaxation to bypass the sparsity constraint,which may not lead to the best subset,and particularly tends to include irrelevant variables when predictors are correlated.In this study,we approach sparse SIR as a nonconvex optimization problem and directly tackle the sparsity constraint by establishing the optimal conditions and iteratively solving them by means of the splicing technique.Without employing convex relaxation on the sparsity constraint and the orthogonal constraint,our algorithm exhibits superior empirical merits,as evidenced by extensive numerical studies.Computationally,our algorithm is much faster than the relaxed approach for the natural sparse SIR estimator.Statistically,our algorithm surpasses existing methods in terms of accuracy for central subspace estimation and best subset selection and sustains high performance even with correlated predictors.
基金funded by the INTER program and cofunded by the Fond National de la Recherche,Luxembourg(FNR)and the Fund for Scientific Research-FNRS,Belgium(F.R.S-FNRS),T.0233.20-‘Sustainable Residential Densification’project(SusDens,2020–2024).
文摘The impact of different global and local variables in urban development processes requires a systematic study to fully comprehend the underlying complexities in them.The interplay between such variables is crucial for modelling urban growth to closely reflects reality.Despite extensive research,ambiguity remains about how variations in these input variables influence urban densification.In this study,we conduct a global sensitivity analysis(SA)using a multinomial logistic regression(MNL)model to assess the model’s explanatory and predictive power.We examine the influence of global variables,including spatial resolution,neighborhood size,and density classes,under different input combinations at a provincial scale to understand their impact on densification.Additionally,we perform a stepwise regression to identify the significant explanatory variables that are important for understanding densification in the Brussels Metropolitan Area(BMA).Our results indicate that a finer spatial resolution of 50 m and 100 m,smaller neighborhood size of 5×5 and 3×3,and specific density classes—namely 3(non-built-up,low and high built-up)and 4(non-built-up,low,medium and high built-up)—optimally explain and predict urban densification.In line with the same,the stepwise regression reveals that models with a coarser resolution of 300 m lack significant variables,reflecting a lower explanatory power for densification.This approach aids in identifying optimal and significant global variables with higher explanatory power for understanding and predicting urban densification.Furthermore,these findings are reproducible in a global urban context,offering valuable insights for planners,modelers and geographers in managing future urban growth and minimizing modelling.
文摘Triaxial tests,a staple in rock engineering,are labor-intensive,sample-demanding,and costly,making their optimization highly advantageous.These tests are essential for characterizing rock strength,and by adopting a failure criterion,they allow for the derivation of criterion parameters through regression,facilitating their integration into modeling programs.In this study,we introduce the application of an underutilized statistical technique—orthogonal regression—well-suited for analyzing triaxial test data.Additionally,we present an innovation in this technique by minimizing the Euclidean distance while incorporating orthogonality between vectors as a constraint,for the case of orthogonal linear regression.Also,we consider the Modified Least Squares method.We exemplify this approach by developing the necessary equations to apply the Mohr-Coulomb,Murrell,Hoek-Brown,andÚcar criteria,and implement these equations in both spreadsheet calculations and R scripts.Finally,we demonstrate the technique's application using five datasets of varied lithologies from specialized literature,showcasing its versatility and effectiveness.
基金supported by the Natural Science Foundation of Shanghai(23ZR1463600)Shanghai Pudong New Area Health Commission Research Project(PW2021A-69)Research Project of Clinical Research Center of Shanghai Health Medical University(22MC2022002)。
文摘Gastric cancer is the third leading cause of cancer-related mortality and remains a major global health issue^([1]).Annually,approximately 479,000individuals in China are diagnosed with gastric cancer,accounting for almost 45%of all new cases worldwide^([2]).
基金supported by the National Natural Science Foundation of China(No.92370117)the CAS Project for Young Scientists in Basic Research(No.YSBR-090)。
文摘In recent years,machine learning(ML)techniques have been shown to be effective in accelerating the development process of optoelectronic devices.However,as"black box"models,they have limited theoretical interpretability.In this work,we leverage symbolic regression(SR)technique for discovering the explicit symbolic relationship between the structure of the optoelectronic Fabry-Perot(FP)laser and its optical field distribution,which greatly improves model transparency compared to ML.We demonstrated that the expressions explored through SR exhibit lower errors on the test set compared to ML models,which suggests that the expressions have better fitting and generalization capabilities.
基金supported by the National Natural Science Foundation of China(U22A20429 and 22308103)Shanghai Pilot Program for Basic Research(22TQ1400100-13)+2 种基金Postdoctoral Fellowship Program of CPSF(GZB20230214)China Postdoctoral Science Foundation(2023M731083)the Fundamental Research Funds for the Central Universities.
文摘Developing cost-effective single-crystalline Ni-rich Co-poor cathodes operating at high-voltage is one of the most important ways to achieve higher energy Li-ion batteries. However, the Li/O loss and Li/Ni mixing under high-temperature lithiation result in electrochemical kinetic hysteresis and structural instability. Herein, we report a highly-ordered single-crystalline LiNi0.85Co0.05Mn0.10O2(NCM85) cathode by doping K+and F-ions. To be specific, the K-ion as a fluxing agent can remarkably decrease the solid-state lithiation temperature by ~30°C, leading to less Li/Ni mixing and oxygen vacancy. Meanwhile, the strong transitional metal(TM)-F bonds are helpful for enhancing de-/lithiation kinetics and limiting the lattice oxygen escape even at 4.5 V high-voltage. Their advantages synergistically endow the single-crystalline NCM85 cathode with a very high reversible capacity of 222.3 mAh g-1. A superior capacity retention of 91.3% is obtained after 500 times at 1 C in pouch-type full cells, and a prediction value of 75.3% is given after cycling for 5000 h. These findings are reckoned to expedite the exploitation and application of high-voltage single-crystalline Ni-rich cathodes for next-generation Li-ion batteries.
基金supported by the Youth Scientific Research Project of Fujian Provincial Center for Disease Control and Prevention(2022QN02)the Fujian Provincial Health Youth Scientific Research Project(2023QNA040).
文摘Background:The COVID-1’s impact on influenza activity is of interest to inform future flu prevention and control strategies.Our study aim to examine COVID-19’s effects on influenza in Fujian Province,China,using a regression discontinuity design.Methods:We utilized influenza-like illness(ILI)percentage as an indicator of influenza activity,with data from all sentinel hospitals between Week 4,2020,and Week 51,2023.The data is divided into two groups:the COVID-19 epidemic period and the post-epidemic period.Statistical analysis was performed with R software using robust RD design methods to account for potential confounders including seasonality,temperature,and influenza vaccination rates.Results:There was a discernible increase in the ILI percentage during the post-epidemic period.The robustness of the findings was confirmed with various RD design bandwidth selection methods and placebo tests,with certwo bandwidth providing the largest estimated effect size:a 14.6-percentage-point increase in the ILI percentage(β=0.146;95%CI:0.096–0.196).Sensitivity analyses and adjustments for confounders consistently pointed to an increased ILI percentage during the post-epidemic period compared to the epidemic period.Conclusion:The 14.6 percentage-point increase in the ILI percentage in Fujian Province,China,after the end of the COVID-19 pandemic suggests that there may be a need to re-evaluate and possibly enhance public health measures to control influenza transmission.Further research is needed to fully understand the factors contributing to this rise and to assess the ongoing impacts of post-pandemic behavioral changes.
基金supported by the National Natural Science Foundation of China(52025103)the Xplorer Prize(XPLORER-2022-1034).
文摘In petroleum,mercaptan impurities generate malodorous fumes that pose risks to both human health and the environment,and leading to substandard oil quality.Lye desulfurization is a widely employed technique for eliminating mercaptans from oil.In traditional scrubber towers,lye and oil are poorly mixed,the desulfurization efficiency is low,and the lye consumption is high.To enhance washing efficiency,a droplet micromixer and corresponding fiber coalescence separator were developed.By optimizing the structure and operating parameters,more effective mixing and separation were achieved,and both caustic washing and desulfurization were enhanced.The proposed mixer/separator outperforms the industry standard by reducing the caustic loading by 30%and offers superior economic and engineering performances.The results of this study offer a direction for designing and optimizing a mercaptan removal unit to enhance the scrubbing effectiveness and decrease expenses to achieve more efficient and green production process.
基金supported by the National Natural Science Foundation of China(22288102,22035007,and 22122815)。
文摘The mixing process plays a pivotal role in the design,optimization,and scale-up of chemical reactors.For most chemical reactions,achieving uniform and rapid contact between reactants at the molecular level is crucial.Mixing intensification encompasses innovative methods and tools that address the limitations of inadequate mixing within reactors,enabling efficient reaction scaling and boosting the productivity of industrial processes.This review provides a concise introduction to the fundamentals of multiphase mixing,followed by case studies highlighting the application of mixing intensification in the production of energy-storage materials,advanced optical materials,and nanopesticides.These examples illustrate the significance of theoretical analysis in informing and advancing engineering practices within the chemical industry.We also explore the challenges and opportunities in this field,offering insights based on our current understanding.
文摘Open channel confluences,where two streams or rivers converge,play a crucial role in hydraulic engineering and river dynamics.These confluences are characterized by complex hydrodynamics influenced by the discharge ratios of merging water bodies.This study investigated the mixing structure at open channel confluences using three-dimensional numerical modeling.A comprehensive three-dimensional numerical model was developed and validated against a dataset obtained from controlled laboratory experiments.This dataset incorporated three-dimensional time-averaged velocity measurements.The skew-induced and stress-induced equation systems were adopted as the core governing equations,providing a framework for simulating various scenarios.A total of ten different cases were analyzed.The results highlighted the effect of discharge ratios on turbulence,lateral and vertical vorticities,and the distribution of mixing,which intensified with higher magnitudes of discharge ratios.The mixing structure,driven by velocity gradients and vorticity,revealed the significant role of lateral and vertical vorticities in determining hydrodynamic behaviors and mixing distributions at confluences.Specifically,the momentum ratio of incoming flows governed the spatial evolution of mixing processes.This study revealed that the distribution of mixing served as a key indicator for identifying the formation of mid-channel scours.High normalized velocities induced toward the left bank led to the superelevation of the water surface,enhancing the potential for bed material and the formation of significant scour holes beneath the elevated water surface.This novel approach provides a deeper understanding of the mixing patterns at confluences,particularly in scenarios with equilibrated discharge ratios but in different magnitudes.
文摘This opinion article discusses the original research work of Yünkül et al.(the Authors)published in the Journal of Mountain Science 21(9):3108–3122.Employing non-linear regression,fuzzy logic and artificial neural network modeling techniques,the Authors interrogated a large database assembled from the existing research literature to assess the performance of twelve equation rules in predicting the undrained shear strength(s_(u))mobilized for remolded fine-grained soils at different values of liquidity index(I_(L))and water content ratio.Based on their analyses,the Authors proposed a simple and reportedly reliable correlation(i.e.,Eq.9 in their paper)for predicting s_(u) over the I_(L) range of 0.15 to 3.00.This article describes various shortcomings in the Authors’assembled database(including potentially anomalous data and covering an excessively wide I_(L) range in relation to routine geotechnical and transportation engineering applications)and their proposed s_(u)=f(I_(L))correlation.Contrary to the Authors’assertions,their proposed correlation is not reliable for fine-grained soils with consistencies in the general firm to stiff range(i.e.,for 0.15<I_(L)<0.40),increasingly overestimating s_(u) for reducing I_(L),and eventually predicting s_(u)→+∞for I_(L)→0.15+(while producing mathematically undefined s_(u) for I_(L)<0.15),thus rendering their correlation unconservative and potentially leading to unsafe geotechnical designs.Exponential or regular-power type s_(u)=f(I_(L))models are more s_(u)itable when developing correlations that are applicable over the full plastic range(of 0<I_(L)<1),thereby providing reasonably conservative s_(u) predictions for use in the preliminary design for routine geotechnical engineering applications.
基金Project supported by the National Key Research and Development Program of China(Grant No.2022YFF0712800)。
文摘Frequency conversion is pivotal in nonlinear optics and quantum optics for manipulating and translating light signals across different wavelength regimes.Achieving frequency conversion between two light beams with a small frequency interval is a central challenge.In this work,we design a pair of coupled silicon microrings wherein coupled-induced modesplitting exists to achieve a small frequency shift by the process of four-wave mixing Bragg scattering.As an example,the signal can be up or down converted to the idler which is 15.5 GHz spaced when two pumps align with another pair of split resonances.The results unveil the potential of coupled microring resonators for small interval frequency conversion in a high-fidelity,all-optical,and signal processing quantum frequency interface.
文摘This paper focuses on the technical management of concrete mixing plants.It introduces the whole-process engineering consulting model and elaborates on multifaceted aspects of technical management,including a matrix-based management framework,standardized design management pathways,cost early-warning systems,approval strategies,regulatory databases,etc.This paper also emphasizes the importance of innovations in collaborative management mechanisms for improving quality and efficiency.
基金Supported by the Natural Science Foundation of Fujian Province(2022J011177,2024J01903)the Key Project of Fujian Provincial Education Department(JZ230054)。
文摘In clinical research,subgroup analysis can help identify patient groups that respond better or worse to specific treatments,improve therapeutic effect and safety,and is of great significance in precision medicine.This article considers subgroup analysis methods for longitudinal data containing multiple covariates and biomarkers.We divide subgroups based on whether a linear combination of these biomarkers exceeds a predetermined threshold,and assess the heterogeneity of treatment effects across subgroups using the interaction between subgroups and exposure variables.Quantile regression is used to better characterize the global distribution of the response variable and sparsity penalties are imposed to achieve variable selection of covariates and biomarkers.The effectiveness of our proposed methodology for both variable selection and parameter estimation is verified through random simulations.Finally,we demonstrate the application of this method by analyzing data from the PA.3 trial,further illustrating the practicality of the method proposed in this paper.
基金Supported by the Hangzhou Joint Fund of the Zhejiang Provincial Natural Science Foundation of Chi-na(LHZY24A010002)the MOE Project of Humanities and Social Sciences(21YJCZH235).
文摘High-dimensional heterogeneous data have acquired increasing attention and discussion in the past decade.In the context of heterogeneity,semiparametric regression emerges as a popular method to model this type of data in statistics.In this paper,we leverage the benefits of expectile regression for computational efficiency and analytical robustness in heterogeneity,and propose a regularized partially linear additive expectile regression model with a nonconvex penalty,such as SCAD or MCP,for high-dimensional heterogeneous data.We focus on a more realistic scenario where the regression error exhibits a heavy-tailed distribution with only finite moments.This scenario challenges the classical sub-gaussian distribution assumption and is more prevalent in practical applications.Under certain regular conditions,we demonstrate that with probability tending to one,the oracle estimator is one of the local minima of the induced optimization problem.Our theoretical analysis suggests that the dimensionality of linear covariates that our estimation procedure can handle is fundamentally limited by the moment condition of the regression error.Computationally,given the nonconvex and nonsmooth nature of the induced optimization problem,we have developed a two-step algorithm.Finally,our method’s effectiveness is demonstrated through its high estimation accuracy and effective model selection,as evidenced by Monte Carlo simulation studies and a real-data application.Furthermore,by taking various expectile weights,our method effectively detects heterogeneity and explores the complete conditional distribution of the response variable,underscoring its utility in analyzing high-dimensional heterogeneous data.
基金supported by the Young Scientists Fund of the National Key R&D Program of China(No.2022YFD2201800)the Youth Science Fund Program of National Natural Science Foundation of China(No.32301581)+2 种基金the Joint Funds for Regional Innovation and Development of the National Natural Science Foundation of China(No.U21A20244)the China Postdoctoral Science Foundation(No.2024M750383)the Heilongjiang Touyan Innovation Team Program(Technology Development Team for High-Efficiency Silviculture of Forest Resources).
文摘Branch size is a crucial characteristic,closely linked to both tree growth and wood quality.A review of existing branch size models reveals various approaches,but the ability to estimate branch diameter and length within the same whorl remains underexplored.In this study,a total of 77 trees were sampled from Northeast China to model the vertical distribution of branch diameter and length within each whorl along the crown.Several commonly used functions were taken as the alternative model forms,and the quantile regression method was employed and compared with the classical two-step modeling approach.The analysis incorporated stand,tree,and competition factors,with a particular focus on how these factors influence branches of varying sizes.The modified Weibull function was chosen as the optimal model,due to its excellent performance across all quantiles.Eight quantile regression curves(ranging from 0.20 to 0.85)were combined to predict branch diameter,while seven curves(ranging from 0.20 to 0.80)were used for branch length.The results showed that the quantile regression method outperformed the classical approach at model fitting and validation,likely due to its ability to estimate different rates of change across the entire branch size distribution.Lager branches in each whorl were more sensitive to changes in DBH,crown length(CL),crown ratio(CR)and dominant tree height(H_(dom)),while slenderness(HDR)more effectively influenced small and medium-sized branches.The effect of stand basal area(BAS)was relatively consistent across different branch sizes.The findings indicate that quantile regression is a good way not only a more accurate method for predicting branch size but also a valuable tool for understanding how branch growth responds to stand and tree factors.The models developed in this study are prepared to be further integrated into tree growth and yield simulation system,contributing to the assessment and promotion of wood quality.
基金supported by the National Natural Science Foundation of China(Grant No.42274035)the Major Science and Technology Program for Hubei Province(No.2022AAA002)the Hunan Provincial Land Surveying and Mapping Project(HNGTCH-2023-05)。
文摘Global Navigation Satellite System(GNSS)imaging method(GIM)has been successfully applied to global regions to investigate vertical land motion(VLM)of the Earth's surface.GNSS images derived from conventional GIM method may present fragmented patches and encounter problems caused by excessive smoothing of velocity peaks,leading to difficulty in short-wavelength deformation detection and improper geophysical interpretation.Therefore,we propose a novel GNSS imaging method based on Gaussian process regression with velocity uncertainty considered(GPR-VU).Gaussian processing regression is introduced to describe the spatial relationship between neighboring site pairs as a priori weights and then reweight velocities by known station uncertainties,converting the discrete velocity field to a continuous one.The GPR-VU method is applied to reconstruct VLM images in the southwestern United States and the eastern Qinghai-Xizang Plateau,China,using the GNSS position time series in vertical direction.Compared to the traditional GIM method,the root-mean-square(RMS)and overall accuracy of the confusion matrix of the GPR-VU method increase by 5.0%and 14.0%from the 1°×1°checkerboard test in the southwestern United States.Similarly,the RMS and overall accuracy increase by 33.7%and 15.8%from the 6°×6°checkerboard test in the eastern Qinghai-Xizang Plateau.These checkerboard tests validate the capability to effectively capture the spatiotemporal variations characteristics of VLM and show that this algorithm outperforms the sparsely distributed network in the Qinghai-Xizang Plateau.The images from the GPR-VU method using real data in both regions show significant subsidence around Lassen Volcanic in northern California within a 30 km radius,slight uplift in the northern Sichuan Basin,and subsidence in its central and southern sections.These results further qualitatively illustrate consistency with previous findings.The GPR-VU method outperforms in diminishing the effect by fragmented patches,excessive smoothing of velocity peaks,and detecting potential short-wavelength deformations.
