Direct ethanol fuel cells have attracted attention as an alternative energy technology due to several advantages such as high theoretical energy density and abundant supply of ethanol.In spite of the advantages,commer...Direct ethanol fuel cells have attracted attention as an alternative energy technology due to several advantages such as high theoretical energy density and abundant supply of ethanol.In spite of the advantages,commercialization of direct ethanol fuel cells is hampered by the relatively low performance caused by its slow oxidation kinetics and difficulty of complete oxidation.In this study,formate,which has relatively faster oxidation kinetics,was mixed with ethanol to compensate the latter’s sluggish kinetics.Effects of p H,concentration,scan rate,and temperature on the mixed reactants oxidation on Pd were investigated by electrochemical experiments such as potential sweep and potentiostatic methods.Furthermore,the potential of the mixed reactants as fuel was evaluated by single cell experiments.As a result,we demonstrate that mixing formate with ethanol results in enhanced power performance in a single cell system.展开更多
Micro-mixing is an important mechanism, which works simultaneously with macro-mixing in chemical reactors in process industries, for achieving the best selectivity with respect to desired products. In about a half cen...Micro-mixing is an important mechanism, which works simultaneously with macro-mixing in chemical reactors in process industries, for achieving the best selectivity with respect to desired products. In about a half century, a huge amount of data and knowledge has been accumulated from theoretical and experimental studies on micromixing. Nevertheless, those results are mostly composites of simplified theoretical and empirical models, and the true nature of interactions of flow inhomogeneity and micro-mixing with chemical reaction has not been fully unveiled. This article reviews the progress in micro-mixing study in chemical reactors to date. A few important topics related to the nature, experimental evaluation, and numerical simulation of micro-mixing are addressed.Some suggestions are given hopefully to motivate more chemical engineers to devote their efforts to better understanding of micro-mixing in chemical reactors.展开更多
基金supported by the New & Renewable Energy Core Technology Program of the Korea Institute of Energy Technology Evaluation and Planning(KETEP)granted financial resource from the Ministry of Trade,Industry & Energy,Republic of Korea(20153030031720)
文摘Direct ethanol fuel cells have attracted attention as an alternative energy technology due to several advantages such as high theoretical energy density and abundant supply of ethanol.In spite of the advantages,commercialization of direct ethanol fuel cells is hampered by the relatively low performance caused by its slow oxidation kinetics and difficulty of complete oxidation.In this study,formate,which has relatively faster oxidation kinetics,was mixed with ethanol to compensate the latter’s sluggish kinetics.Effects of p H,concentration,scan rate,and temperature on the mixed reactants oxidation on Pd were investigated by electrochemical experiments such as potential sweep and potentiostatic methods.Furthermore,the potential of the mixed reactants as fuel was evaluated by single cell experiments.As a result,we demonstrate that mixing formate with ethanol results in enhanced power performance in a single cell system.
基金Supported by the National Natural Science Foundation of China(21376243,91434126)National Key Research and Development Program(2016YFB0301702)+1 种基金the State Key Development Program for Basic Research of China(2012CB224806)Jiangsu National Synergetic Innovation Center for Advanced Materials
文摘Micro-mixing is an important mechanism, which works simultaneously with macro-mixing in chemical reactors in process industries, for achieving the best selectivity with respect to desired products. In about a half century, a huge amount of data and knowledge has been accumulated from theoretical and experimental studies on micromixing. Nevertheless, those results are mostly composites of simplified theoretical and empirical models, and the true nature of interactions of flow inhomogeneity and micro-mixing with chemical reaction has not been fully unveiled. This article reviews the progress in micro-mixing study in chemical reactors to date. A few important topics related to the nature, experimental evaluation, and numerical simulation of micro-mixing are addressed.Some suggestions are given hopefully to motivate more chemical engineers to devote their efforts to better understanding of micro-mixing in chemical reactors.
