Four metallogenic epochs occurred in different tectonic environments during theevolution of the Northern Qilian metallogenic province through the geological time. The Mid-dle Proterozoic metallogenic epoch witnessed t...Four metallogenic epochs occurred in different tectonic environments during theevolution of the Northern Qilian metallogenic province through the geological time. The Mid-dle Proterozoic metallogenic epoch witnessed the tectonic environment of crustal breakupcaused by mantle diapirism, in which ultramafic-mafic rocks were intruded along beep faultbelts and the superlarge Jinchuan magmatic Cu-Ni sulphide deposit was formed. In theMiddle-Late Proterozoic metallogenic epoch the crust was further broken to form anintracontinental rift, in which the Chenjiamiao style massive Cu-Fe sulphide deposits hosted bybasic volcanic tuff were formed in the lower volcano-sedimentary sequence, while the largesedex type Jingtieshan style Fe-Cu deposits were formed within the upper abyssal carbon-richargillaceous sedimentary sequence. The Early Palaeozoic saw the aulacogen environment, with-in which the Baiyinchang style superlarge massive base and precious metal sulphide depositshosted by quartz keratophyric tuff were formed in the Middle-Late Cambrian rifted island arcand the massive Cu-Zn sulphide deposits and magmatic chromite deposits associated with theophiolite suite were formed in the Early-Middle Ordovician, and the Honggou style massiveCu-Fe sulphide deposits hosted by spilite were formed in the Late Ordovician back-arc basinenvironment. In the Late Palaeozoic-Meso-Cenozoic, the metallogenic province went into anintracontinental orogenic stage characterized by compressive tectonic environment, in whichthere occurred carbonate-quartz vein type and tectono-alteration gold deposits associated withductile-shear structures.展开更多
Rare metal ore reserves are an important strategic resource, and their metallogenic mechanism and mineralization studies have also been received widespread international attention.
The Bangong Lake-Nujiang River metallogenic belt is located between the Qiangtang Block and Lhasa Block, and the Duolong ore concentration area is located in the western section of the Bangong Lake-Nujiang River metal...The Bangong Lake-Nujiang River metallogenic belt is located between the Qiangtang Block and Lhasa Block, and the Duolong ore concentration area is located in the western section of the Bangong Lake-Nujiang River metallogenic belt. Till now, several large and super large copper-gold deposits, such as Duobuza, Bolong, Dibaonamugang, Naruo and Rongna deposits have been discovered in this area, mainly porphyry copper-gold ones.展开更多
Uranium is a typical lithophile element, having outstanding geo-chemical characteristics of association whith high SiO<sub>2</sub>, peraluminousand marginally peralkalic rocks. In evolution process of all ...Uranium is a typical lithophile element, having outstanding geo-chemical characteristics of association whith high SiO<sub>2</sub>, peraluminousand marginally peralkalic rocks. In evolution process of all geologicalhistory, uranium gathers without interruption in upper crust. Urani-um mineralization is closely realted with evolution characteristics of thecontinent crust.1. It was not until the continent crust evolved to certain maturedegree that uranium began metallization. The oldest uranium depositon the earth occurred in the Delanshiwa （Kapuwaer） district,展开更多
This study developed a direct reduction route to smelt refractory high-phosphorus iron ores by using hydrogen rich gas.The effects of temperature,gas composition,and gangue on the reduction behavior of iron ore pellet...This study developed a direct reduction route to smelt refractory high-phosphorus iron ores by using hydrogen rich gas.The effects of temperature,gas composition,and gangue on the reduction behavior of iron ore pellets were investigated.Additionally,the migration behavior of phosphorus throughout the reduction-smelting process was examined.The apparent activation energy of the reduction process increased from 64.2 to 194.2 kJ/mol.Increasing the basicity from 0.5 to 0.9 increased the metallization rate from 85.9%to 89.2%.During the reduction process,phosphorus remained in the gangue phase.Carbon deposition and phosphorus removal behaviors of the pellets were investigated and correlated with the gas composition,temperature,pressure,metallization rate,and basicity.Increasing the FeO and CaO contents led to an increase in the liquidus temperature.A high metallization rate of the pellets reduced the phosphorus removal rate but increased the carbon content of the final iron product.Increasing basicity restricted the migration of phosphorus and improved the rate of phosphorus removal.The optimum dephosphorization parameters were separation temperature of 1823 K,basicity of 2.0,and metallization rate of 82.3%.This study presents a high-efficiency and low carbon method for smelting high-phosphorus iron ores.展开更多
Multi-scale chemo-mechanical effects and microscopic failure modes are explored in the evolution of strength change of slip surface. Direct shear equipments, scanning electro-microscope and X-ray diffraction are used ...Multi-scale chemo-mechanical effects and microscopic failure modes are explored in the evolution of strength change of slip surface. Direct shear equipments, scanning electro-microscope and X-ray diffraction are used to trace the change in strength of remodeled soils of slip surfaces in the Three Gorges area. Results show that there is a release of alkali metals and concentration of clay minerals on the surface. During the tests, potassium ions were released, the cementation was reduced, and the ratio of interlayer minerals varied associated with strength change. Accordingly, illites or montmorillonite-illite mixtures turned into montmorillonite. So the strength change originates from the release of alkali metal ions on molecular scale that leads to the concentration and transition of clay minerals on meso-scale. The evolution of slip surface and soil strength is a typical process involving multi-scale processes of structure changes and chemo-mechanical coupling.展开更多
Co-gasification of industrial sludge(IS)and coal was an effective approach to achieve harmless and sustainable utilization of IS.The long-term and stable operation of a co-gasification largely depends on fluidity of c...Co-gasification of industrial sludge(IS)and coal was an effective approach to achieve harmless and sustainable utilization of IS.The long-term and stable operation of a co-gasification largely depends on fluidity of coal-ash slag.Herein,the effects of IS addition on the crystallization and viscosity of Shuangmazao(SMZ)coal were investigated by means of high temperature stage coupled with an optical microscope(HTSOM),a scanning electron microscopy coupled with an energy dispersive Xray spectrometry(SEM-EDS),X-ray diffraction(XRD),a Fourier transform infrared spectrometer(FTIR),and FactSage software.The results showed that when the proportion of IS was less than 60%,with the addition of IS,the slag existed in an amorphous form.This was due to the high content of SiO_(2) and Al_(2)O_(3) in SMZ ash and blended ash,which had a high glass-forming ability(GFA).The slag formed at a high temperature had a higher polymerization degree and viscosity,which led to a decrease in the migration ability between ions,and ultimately made the slag difficult to crystallize during the cooling.When the proportion of IS was higher than 60%,the addition of IS increased the CaO and FeO content in the system.As network modifiers,CaO and FeO could provide O^(2−)at a high temperature,which reacted with silicate network structure and continuously destroyed the complexity of network structure,thus reducing the polymerization degree and viscosity of slag.At this time,the migration ability between ions was enhanced,and needle-shaped/rod-shaped crystals were precipitated during the cooling process.Finally,the viscosity calculated by simulation and Einstein-Roscoe empirical formula demonstrated that the addition of IS could significantly improve the fluidity of coal ash and meet the requirements of the liquid slag-tapping gasifier.The purpose of this work was to provide theoretical support for slag flow mechanisms during the gasifier slagging-tapping process and the resource treatment of industrial solid waste.展开更多
基金This paper presents part of the result of the project supported by the National Natural Science Foundation of China(No.49272109)and the Foundation for Development of Geological Science and Technology of the Ministry of Geology and Mineral Resources(No.89
文摘Four metallogenic epochs occurred in different tectonic environments during theevolution of the Northern Qilian metallogenic province through the geological time. The Mid-dle Proterozoic metallogenic epoch witnessed the tectonic environment of crustal breakupcaused by mantle diapirism, in which ultramafic-mafic rocks were intruded along beep faultbelts and the superlarge Jinchuan magmatic Cu-Ni sulphide deposit was formed. In theMiddle-Late Proterozoic metallogenic epoch the crust was further broken to form anintracontinental rift, in which the Chenjiamiao style massive Cu-Fe sulphide deposits hosted bybasic volcanic tuff were formed in the lower volcano-sedimentary sequence, while the largesedex type Jingtieshan style Fe-Cu deposits were formed within the upper abyssal carbon-richargillaceous sedimentary sequence. The Early Palaeozoic saw the aulacogen environment, with-in which the Baiyinchang style superlarge massive base and precious metal sulphide depositshosted by quartz keratophyric tuff were formed in the Middle-Late Cambrian rifted island arcand the massive Cu-Zn sulphide deposits and magmatic chromite deposits associated with theophiolite suite were formed in the Early-Middle Ordovician, and the Honggou style massiveCu-Fe sulphide deposits hosted by spilite were formed in the Late Ordovician back-arc basinenvironment. In the Late Palaeozoic-Meso-Cenozoic, the metallogenic province went into anintracontinental orogenic stage characterized by compressive tectonic environment, in whichthere occurred carbonate-quartz vein type and tectono-alteration gold deposits associated withductile-shear structures.
基金financially supported by the National Natural Science Foundation of China(grant No.41302061)
文摘Rare metal ore reserves are an important strategic resource, and their metallogenic mechanism and mineralization studies have also been received widespread international attention.
基金granted by the Geological Survey Program of China Geological Survey (Grant No.1212011086074 and 12120113036500)
文摘The Bangong Lake-Nujiang River metallogenic belt is located between the Qiangtang Block and Lhasa Block, and the Duolong ore concentration area is located in the western section of the Bangong Lake-Nujiang River metallogenic belt. Till now, several large and super large copper-gold deposits, such as Duobuza, Bolong, Dibaonamugang, Naruo and Rongna deposits have been discovered in this area, mainly porphyry copper-gold ones.
文摘Uranium is a typical lithophile element, having outstanding geo-chemical characteristics of association whith high SiO<sub>2</sub>, peraluminousand marginally peralkalic rocks. In evolution process of all geologicalhistory, uranium gathers without interruption in upper crust. Urani-um mineralization is closely realted with evolution characteristics of thecontinent crust.1. It was not until the continent crust evolved to certain maturedegree that uranium began metallization. The oldest uranium depositon the earth occurred in the Delanshiwa （Kapuwaer） district,
基金Project(U1960205)supported by the National Natural Science Foundation of ChinaProject(2020ZXA01)supported by China Minmetals Science and Technology Special Plan Foundation。
文摘This study developed a direct reduction route to smelt refractory high-phosphorus iron ores by using hydrogen rich gas.The effects of temperature,gas composition,and gangue on the reduction behavior of iron ore pellets were investigated.Additionally,the migration behavior of phosphorus throughout the reduction-smelting process was examined.The apparent activation energy of the reduction process increased from 64.2 to 194.2 kJ/mol.Increasing the basicity from 0.5 to 0.9 increased the metallization rate from 85.9%to 89.2%.During the reduction process,phosphorus remained in the gangue phase.Carbon deposition and phosphorus removal behaviors of the pellets were investigated and correlated with the gas composition,temperature,pressure,metallization rate,and basicity.Increasing the FeO and CaO contents led to an increase in the liquidus temperature.A high metallization rate of the pellets reduced the phosphorus removal rate but increased the carbon content of the final iron product.Increasing basicity restricted the migration of phosphorus and improved the rate of phosphorus removal.The optimum dephosphorization parameters were separation temperature of 1823 K,basicity of 2.0,and metallization rate of 82.3%.This study presents a high-efficiency and low carbon method for smelting high-phosphorus iron ores.
基金supported by the National Natural Science Foundation of China (Grant No. 40171005)the Key Project of National Natural Science Foundation of China (Grant No. 41030742)+1 种基金Foundation of Key Laboratory of Mountain Hazards and Earth Surface Process of Chinese Academy of Sciencesthe Natural Science Foundation of U.S.A. (Grant No. 0324543)
文摘Multi-scale chemo-mechanical effects and microscopic failure modes are explored in the evolution of strength change of slip surface. Direct shear equipments, scanning electro-microscope and X-ray diffraction are used to trace the change in strength of remodeled soils of slip surfaces in the Three Gorges area. Results show that there is a release of alkali metals and concentration of clay minerals on the surface. During the tests, potassium ions were released, the cementation was reduced, and the ratio of interlayer minerals varied associated with strength change. Accordingly, illites or montmorillonite-illite mixtures turned into montmorillonite. So the strength change originates from the release of alkali metal ions on molecular scale that leads to the concentration and transition of clay minerals on meso-scale. The evolution of slip surface and soil strength is a typical process involving multi-scale processes of structure changes and chemo-mechanical coupling.
基金supported by the project of Key Research Plan of Ningxia(2019BEB04030 and 2019BCH01001)the project of CHN Energy Ningxia Coal Industry Co.,Ltd.(NXMY2112).
文摘Co-gasification of industrial sludge(IS)and coal was an effective approach to achieve harmless and sustainable utilization of IS.The long-term and stable operation of a co-gasification largely depends on fluidity of coal-ash slag.Herein,the effects of IS addition on the crystallization and viscosity of Shuangmazao(SMZ)coal were investigated by means of high temperature stage coupled with an optical microscope(HTSOM),a scanning electron microscopy coupled with an energy dispersive Xray spectrometry(SEM-EDS),X-ray diffraction(XRD),a Fourier transform infrared spectrometer(FTIR),and FactSage software.The results showed that when the proportion of IS was less than 60%,with the addition of IS,the slag existed in an amorphous form.This was due to the high content of SiO_(2) and Al_(2)O_(3) in SMZ ash and blended ash,which had a high glass-forming ability(GFA).The slag formed at a high temperature had a higher polymerization degree and viscosity,which led to a decrease in the migration ability between ions,and ultimately made the slag difficult to crystallize during the cooling.When the proportion of IS was higher than 60%,the addition of IS increased the CaO and FeO content in the system.As network modifiers,CaO and FeO could provide O^(2−)at a high temperature,which reacted with silicate network structure and continuously destroyed the complexity of network structure,thus reducing the polymerization degree and viscosity of slag.At this time,the migration ability between ions was enhanced,and needle-shaped/rod-shaped crystals were precipitated during the cooling process.Finally,the viscosity calculated by simulation and Einstein-Roscoe empirical formula demonstrated that the addition of IS could significantly improve the fluidity of coal ash and meet the requirements of the liquid slag-tapping gasifier.The purpose of this work was to provide theoretical support for slag flow mechanisms during the gasifier slagging-tapping process and the resource treatment of industrial solid waste.
