Shale of the MiddleeUpper Permian Dalong Formation and Gufeng Formation in the Lower Yangtze region is characterized by large thickness,high total organic carbon(TOC),wide distribution and moderate organic thermal evo...Shale of the MiddleeUpper Permian Dalong Formation and Gufeng Formation in the Lower Yangtze region is characterized by large thickness,high total organic carbon(TOC),wide distribution and moderate organic thermal evolution degree,so it may be the next important field of shale gas exploration.In order to point out the target and direction of shale gas exploration and development in this region,this paper selects the Dalong Formation and Gufeng Formation shale in the Xuanjing area of Lower Yangtze as the research object to quantitatively describe the development characteristics of shale pores of different scales by means of scanning electron microscopy(SEM),high pressure mercury injection,CO_(2) and N_(2)adsorption.Then,the fractal dimension of sample pores is calculated by using the FHH(FrenkeleHalseyeHill)model.Finally,combined with TOC and mineral compositions,the relationship between pore structure and fractal dimension is discussed.And the following research results are obtained.First,dominant lithofacies of Dalong Formation are argillaceous-rich siliceous shale and argillaceous-rich/siliceous mixed shale,which has smaller specific surface area and pore volume,larger average pore diameter.The pore development is mainly controlled by clay mineral content.Dominant lithofacies of Gufeng Formation is siliceous shale,which has a larger specific surface area and pore volume,and smaller average pore diameter.The pore development is controlled by organic matter and brittle mineral content.Second,the influencing factors of fractal dimension can be attributed to the controlling factors of micropore development.The fractal dimension D_(1)of Dalong Formation ranges from 2.4515 to 2.5513(average 2.5227),and D_(2)ranges from 2.5817 to 2.6578(averagely 2.6246).The fractal dimension D_(1)of Gufeng Formation ranges from 2.5817 to 2.6578(averagely 2.6246),and D_(2)ranges from 2.7227 to 2.871(averagely 2.813).Gufeng Formation shale presents the characteristics of more complex pore structure.Third,the fractal dimension D_(1)is more sensitive to specific surface area,pore development and mineral composition,while D_(2)is more effective in characterizing the average pore diameter.In conclusion,Dalong Formation shalewith high D_(1)and D_(2)and Gufeng Formation shalewith low D_(1)and high D_(2)can be taken as the favorable exploration targets of Permianmarine shale gas in the LowerYangtze region,and the regional overpressure zones(belts)with weaker structural deformation in hydrocarbon rich sags will be the favorable shale gas exploration targets in this area.展开更多
基金Project supported by the National Natural Science Foundation of China(Key Program)“Lithospheric Structure and Fluid Circulation in the Ryukyu Trench Subduction Zone-Ocean Magnetotelluric and Seismic Data Constraints”(No.91958210)the Central Finance Secondary Project“Shale Gas Geological Survey in Jiangsu and Anhui Provinces”(No.:DD20190083).
文摘Shale of the MiddleeUpper Permian Dalong Formation and Gufeng Formation in the Lower Yangtze region is characterized by large thickness,high total organic carbon(TOC),wide distribution and moderate organic thermal evolution degree,so it may be the next important field of shale gas exploration.In order to point out the target and direction of shale gas exploration and development in this region,this paper selects the Dalong Formation and Gufeng Formation shale in the Xuanjing area of Lower Yangtze as the research object to quantitatively describe the development characteristics of shale pores of different scales by means of scanning electron microscopy(SEM),high pressure mercury injection,CO_(2) and N_(2)adsorption.Then,the fractal dimension of sample pores is calculated by using the FHH(FrenkeleHalseyeHill)model.Finally,combined with TOC and mineral compositions,the relationship between pore structure and fractal dimension is discussed.And the following research results are obtained.First,dominant lithofacies of Dalong Formation are argillaceous-rich siliceous shale and argillaceous-rich/siliceous mixed shale,which has smaller specific surface area and pore volume,larger average pore diameter.The pore development is mainly controlled by clay mineral content.Dominant lithofacies of Gufeng Formation is siliceous shale,which has a larger specific surface area and pore volume,and smaller average pore diameter.The pore development is controlled by organic matter and brittle mineral content.Second,the influencing factors of fractal dimension can be attributed to the controlling factors of micropore development.The fractal dimension D_(1)of Dalong Formation ranges from 2.4515 to 2.5513(average 2.5227),and D_(2)ranges from 2.5817 to 2.6578(averagely 2.6246).The fractal dimension D_(1)of Gufeng Formation ranges from 2.5817 to 2.6578(averagely 2.6246),and D_(2)ranges from 2.7227 to 2.871(averagely 2.813).Gufeng Formation shale presents the characteristics of more complex pore structure.Third,the fractal dimension D_(1)is more sensitive to specific surface area,pore development and mineral composition,while D_(2)is more effective in characterizing the average pore diameter.In conclusion,Dalong Formation shalewith high D_(1)and D_(2)and Gufeng Formation shalewith low D_(1)and high D_(2)can be taken as the favorable exploration targets of Permianmarine shale gas in the LowerYangtze region,and the regional overpressure zones(belts)with weaker structural deformation in hydrocarbon rich sags will be the favorable shale gas exploration targets in this area.