The middle-lower Yangtze area underwent a series of complex tectonic evolution, such as Hercynian extensional rifting, Indosinian foreland basining, and Yanshanian transpression-transtension, resulting in a large dist...The middle-lower Yangtze area underwent a series of complex tectonic evolution, such as Hercynian extensional rifting, Indosinian foreland basining, and Yanshanian transpression-transtension, resulting in a large distinctive Cu-Fe-Au metallogenic belt. In the tectonic evolution, large-scale migration and convergence of fluids toward foreland basins induced during the collisional orogeny of the Yangtze and North China continental blocks were of vital importance for the formation of the metallogenic belt. Through geological surveys of the middle-lower Yangtze area, three lines of evidence of large-scale fluid migration are proposed: (1) The extensive dolomitic and silicic alteration penetrating Cambrian-Triassic strata generally occurs in a region sandwiched between the metallogenic belt along the Yangtze River and the Dabie orogenic belt, and in the alteration domain alternately strong and weak alteration zones extend in a NW direction and are controlled by the fault system of the Dabie orogenic belt; it might record the locus of the activities of long-distance migrating fluids. (2) The textures and structures of very thick Middle-Lower Triassic anhydrock sequences in restricted basins along the river reveal the important contribution of the convergence of regional hot brine in restricted basins and the chemical deposition or their formation. (3) Early-Middle Triassic syndepositional iron carbonate sequences and Fe-Cu-Pb-Zn massive sulfide deposits alternate with anhydrock sequences or are separated from the latter, but all of them occur in the same stratigraphic horizon and are intimately associated with each other, being the product of syndeposition of high-salinity hot brine. According to the geological surveys, combined with previous data, the authors propose a conceptual model of fluid migration-convergence and mineralization during the Dabie collisional orogeny.展开更多
This study presents LA–ICP–MS U–Pb dating and whole-rock geochemical analyses of the Late Triassic Gangshan harzburgite in the Qingyuan area,with the aim of elucidating its petrogenesis and further constraining the...This study presents LA–ICP–MS U–Pb dating and whole-rock geochemical analyses of the Late Triassic Gangshan harzburgite in the Qingyuan area,with the aim of elucidating its petrogenesis and further constraining the early Mesozoic tectonic evolution of the eastern segment of the northern margin of the North China Block(NCB).Zircons from the harzburgites exhibit typical oscillatory growth zoning or striped absorp-tion in cathodoluminescence images.U–Pb analyses of zircons yield ages ranging from 2525 Ma to 225 Ma,with two youngest ages(225±7 Ma)indicating that the harzburgites were formed during Late Triassic.Geochemical analyses of the Gangshan harzburgites show that the rocks have low concentrations of SiO_(2)(42.38%–42.85%)and Al_(2)O_(3)(3.31%–3.33%),along with high concentrations of MgO(41.32%–41.76%),Cr(4856×10^(-6)–5191×10^(-6))and Ni(1942×10^(-6)–2041×10^(-6)).They also display low REE abundances(∑REE=4.38×10^(-6)–4.69×10^(-6))and flat REE patterns with low(La/Yb)_(N) ratios(1.24–1.56)and slightly po-sitive Eu anomalies(δEu=1.13–1.16).These features suggest that the Gangshan harzburgites are cumulates of basaltic magma derived from the depleted lithospheric mantle.Combined with previous studies,these Late Triassic mafic–ultramafic rocks,together with coeval granitoids in adjacent regions,constitute a typical bimodal association,suggesting that they formed in a post-orogenic extensional environment after the final closure of the Paleo-Asian Ocean.展开更多
The Qinling orogenic belt in central China underwent long-term tectonic evolution during an amalgamation between the North China and South China cratons.However,intense compressional deformation and uplift erosion res...The Qinling orogenic belt in central China underwent long-term tectonic evolution during an amalgamation between the North China and South China cratons.However,intense compressional deformation and uplift erosion resulted in the transformation and disappearance of much geological record from the Qinling orogenic belt,and the tectonic evolution of this belt remains poorly constrained during the Triassic.Located in the northernmost margin of the South China Craton,the Sichuan Basin preserves the complete Triassic sedimentary succession,and can provide significant information for understanding the Triassic tectonic evolution of the Qinling orogenic belt.We present detrital zircon U-Pb dating,trace element and in situ Lu-Hf isotope data for the Middle Triassic Leikoupo Formation and the Late Triassic Xujiahe Formation samples from the eastern Sichuan Basin,South China.The detrital zircon U-Pb ages of the Leikoupo Formation show seven age clusters of 280-242,350-300,500-400,1000-800,2000-1750,2100-2000 and 2600-2400 Ma,while those of the Xujiahe Formation show five age clusters of 300-200,500-350,1050-950,2000-1750 and 2600-2400 Ma.Combined with published paleocurrent and paleogeographic data,the sediments of the Leikoupo Formation are interpreted to be sourced from the North China Craton,Yangtze Craton and North Qinling orogenic belt,and the potential main source regions of the Xujiahe Formation included the South and North Qinling orogenic belts.Provenance analysis indicates that the North Qinling orogenic belt was in inherited uplift and coeval denudation in the Middle Triassic.The proportion of the detritus formed in the South Qinling orogenic belt increases gradually from the Leikoupo to Xujiahe formations.This significant provenance change indicates that rapid tectonic uplift and extensive denudation of the South Qinling orogenic belt occurred in the early Late Triassic,which is related to the collision between the North China and South China cratons during the Triassic.展开更多
There is significant debate concerning the tectonic characteristics and evolutionary understanding of the South China Block(SCB)during the Early Mesozoic.One of the key points of contention is the tectonic-magmatic ac...There is significant debate concerning the tectonic characteristics and evolutionary understanding of the South China Block(SCB)during the Early Mesozoic.One of the key points of contention is the tectonic-magmatic activity during the Triassic and its dynamic mechanisms.However,research on the detailed chronology and tectonic settings of granite plutons in key regions remains insuffi-cient,limiting the understanding of the tectonic-magmatic dynamic mechanisms in the interior of SCB during the Triassic.In this contribution,we present whole-rock major and trace elemental data,Sr-Nd isotope data,LA-ICP-MS zircon U-Pb age dating,and Lu-Hf isotope data for granites of Dashenshan pluton in the Xiangzhong,northwest part of SCB.The results indicate that the Dashenshan granite has an emplacement age of 208.4-212.5 Ma,characterized by high SiO_(2),Na_(2)O,and K_(2)O contents and low MgO and CaO.The Dashenshan granite is enriched in light rare-earth elements with a significant negative Eu anomaly(averageδEu=0.42).It is also enriched in Rb,K,and Th and shows pronounced depletion in Nb,Ta,and Ti,classifying it as peraluminous calc-alkaline granite,specifically of the I-type.The zircon ε_(Hf(t)) values range from−8.39 to−4.4,with an average of−5.82,and the Sr-Nd isotopes are relatively enriched[ε_(Nd)(t)=−9.31 to−6.8].Combining these geochemical characteristics,it is revealed that the Dashenshan granite was derived from the partial melting of middle to upper crustal metamorphic basement materials under medium-to low-temperature conditions,with possible minor contributions from mantle-derived materials.Furthermore,it underwent fractional crystallization,including plagioclase differentiation.By integrating the geochemical features and spatial distribution of Triassic granites in SCB,this study suggests that the regional tectonic evolution of SCB during the Triassic was primarily controlled by the collision of the SCB with the Indochina Block and the North China Block.In Xiangzhong,the tectonic setting transitioned from syn-collisional compression to post-collisional extension during the Late Triassic.The Dashenshan pluton formed in a post-collisional extensional setting,resulting from the decompression melting of middle-to-upper crustal rocks.The upwelling of the asthenosphere and upward heat transfer likely played a significant role in the formation of the Dashenshan granitic magma.展开更多
The recent discovery of natural gas within the fifth member of the Xujiahe Formation(T_(3)x_(5))in the Dongfeng area within the Sichuan Basin highlights the significant exploration potential of this member.However,the...The recent discovery of natural gas within the fifth member of the Xujiahe Formation(T_(3)x_(5))in the Dongfeng area within the Sichuan Basin highlights the significant exploration potential of this member.However,the unconvincing previous understanding of the sedimentary microfacies,combined with a total lack of studies on the sand body architecture and reservoir distribution,hampers the further exploration of this member.Using core data,log curves,and seismic data,along with sedimentary microfacies analysis,this study investigated the interfaces between the sand bodies of various scales in the Dongfeng area.Furthermore,this study explored the morphological characteristics,types,and stacking patterns of these sand bodies and determined the distributions of sand bodies and reservoirs in the area.The results indicate that the first sand group of the T_(3)x_(5) member(T_(3)x^(1)_(5))exhibits delta-front deposits,including subaqueous distributary channels,sheet sands,and interdistributary bays.Seven levels of sand body interfaces are identified in the T_(3)x^(1)_(5) sand group.Among them,the interfaces of the first and second levels were identified only in cores,those of the third and fourth levels were recog-nizable from cores combined with log curves,while those of the fifth,sixth,and seventh levels were distinguishable using seismic data.Three superimposed subaqueous distributary channel complexes are found in the Dongfeng area.Among them,complex 1 in the northwest exhibits the strongest water body energy,while complex 2 in the south displays the weakest.Complex 2 was formed earlier than com-plexes 1 and 3.Also,complex 1 is further subdivided into three vertically stacked subaqueous distrib-utary channels.The subdivision of sedimentary microfacies in the T_(3)x_(5) member reveals nine lithofacies types.Among them,stacked pancake-shaped,carbonaceous debris-bearing,massive,and cross-bedded medium-grained sandstones are considered favorable lithofacies.These four lithofacies types exhibit high porosity,as well as low natural gamma-ray(GR)values,low-to-medium deep investigate double lateral resistivity(RD),and high interval transit time(AC)on the log curves.Additionally,the reservoir distribution in the Dongfeng area was delineated based on the characterization of the favorable lith-ofacies.This study serves as a guide for future exploration and evaluation of the T_(3)x_(5) member in the Dongfeng area while also augmenting the methodologies for describing tight sandstone reservoirs.展开更多
The Yangtze Plate(YP)and the North China Plate(NCP)are key components of the East Asian continent,and their collision significantly influences the tectonic evolution of the eastern Asian continental margin.As the Sout...The Yangtze Plate(YP)and the North China Plate(NCP)are key components of the East Asian continent,and their collision significantly influences the tectonic evolution of the eastern Asian continental margin.As the South Yellow Sea is located at the convergence of these plates,it becomes a pivotal area for understanding the tectonic evolution of East Asia.The characteristics and provenance of clastic rocks of the Middle Permian-the Early Triassic were analyzed and the strata in the Central Uplift including the Qinglong Formation(T_(1)q)and Talung Formation(P_(3)d),consisting of various mudstones and sandstones,were anatomized.Results show that quartz and feldspar are the main diagenetic minerals,while illite and chlorite show signs of secondary alterations.Geochemical imprints indicate a gradual shift in provenance from ancient sedimentary and mafic igneous rocks to intermediate igneous rocks.In the meantime,the tectonic background transformed from continent to continental island arc from the Middle Permian to the Early Triassic.Therefore,we inferred that a soft collision between the North China Plate and the Yangtze Plate likely occurred during the Late Permian,resulted in intensified collision between two plates in the Early Triassic,and shaped the South Yellow Sea.This study provided valuable information on the timing of plate collisions in the South Yellow Sea.展开更多
The lamina(combination)types,reservoir characteristics and shale oil occurrence states of organic-rich shale in the Triassic Yanchang Formation Chang 73 sub-member in the Ordos Basin were systematically investigated t...The lamina(combination)types,reservoir characteristics and shale oil occurrence states of organic-rich shale in the Triassic Yanchang Formation Chang 73 sub-member in the Ordos Basin were systematically investigated to reveal the main controlling factors of shale oil occurrence under different lamina combinations.The differential enrichment mechanisms and patterns of shale oil were discussed using the shale oil micro-migration characterization and evaluation methods from the perspectives of relay hydrocarbon supply,stepwise migration,and multi-stage differentiation.The results are obtained in five aspects.First,Chang 73 shale mainly develops five types of lamina combination,i.e.non-laminated shale,sandy laminated shale,tuffaceous laminated shale,mixed laminated shale,and organic-rich laminated shale.Second,shales with different lamina combinations are obviously different in the reservoir space.Specifically,shales with sandy laminae and tuffaceous laminae have a large number of intergranular pores,dissolution pores and hydrocarbon generation-induced fractures.The multi-scale pore and fracture system constitutes the main place for liquid hydrocarbon occurrence.Third,the occurrence and distribution of shale oil in shale with different lamina combinations are jointly controlled by organic matter abundance,reservoir property,thermal evolution degree,mineral composition and laminae scale.The micro-nano-scale pore-fracture networks within shales containing rigid laminae,particularly sandy and tuffaceous laminations,primarily contain free-state light hydrocarbon components.In contrast,adsorption-phase heavy hydrocarbon components predominantly occupy surfaces of organic matter assemblages,clay mineral matrices,and framework mineral particulates.Fourth,there is obvious shale oil micro-migration between shales with different lamina combinations in Chang 73.Generally,such micro-migration is stepwise in a sequence of organic-rich laminated shale→tuffaceous laminated shale→mixed laminated shale→sandy lamiated shale→non-laminated shale.Fifth,the relay hydrocarbon supply of organic matter under the control of the spatial superposition of shales with various laminae,the stepwise migration via multi-scale pore and fracture network,and the multi-differentiation in shales with different lamina combinations under the control of organic-inorganic interactions fundamentally decide the differences of shale oil components between shales with different lamina combinations.展开更多
Wells CXD1 and CX2 have uncovered high-concentration potassium-and lithium-containing brines and substantial layers of halite-type polyhalite potash deposits within the 4th and 5th members of the Triassic Jialingjiang...Wells CXD1 and CX2 have uncovered high-concentration potassium-and lithium-containing brines and substantial layers of halite-type polyhalite potash deposits within the 4th and 5th members of the Triassic Jialingjiang Formation and the 1st Member of Leikoupo Formation(Jia 4 Member,Jia 5 Member,and Lei 1 Member)in the Puguang area,Sichuan Basin.These discoveries mark significant breakthroughs in the exploration of deep marine potassium and lithium resources within the Sichuan Basin.Utilizing the concept of“gas-potassium-lithium integrated exploration”and incorporating drilling,logging,seismic,and geochemical data,we have investigated the geological and enrichment conditions,as well as the metallogenic model of potassium-rich and lithium-rich brines and halite-type polyhalite.First,the sedimentary systems of gypsum-dolomite flats,salt lakes and evaporated flats were developed in Jia 4 Member,Jia 5 Member,and the 1st member of Leikoupo Formation(Lei 1 Member)in northeastern Sichuan Basin,forming three large-scale salt-gathering and potassium formation centers in Puguang,Tongnanba and Yuanba,and developing reservoirs with potassium-rich and lithium-rich brines,which are favorable for the deposition of potassium and lithium resources in both solid or liquid phases.Second,the soluble halite-type polyhalite has a large thickness and wide distribution,and the reservoir brine has a high content of K+and Li+.A solid-liquid superimposed“three-story structure”(with the lower thin-layer of brine reservoir in lower part of Jia 4 Member and Jia 5 Member,middle layer of halite-type polyhalite potash depositS,upper layer of potassium-rich and lithium-rich brine reservoir in Lei 1 Member)is formed.Third,the ternary enrichment and mineralization patterns for potassium and lithium resources were determined.Vertical superposition of polyhalite and green bean rocks is the mineral material basis of potassium-lithium resources featuring“dual-source replenishment and proximal-source release”,with primary seawater and gypsum dehydration as the main sources of deep brines,while multi-stage tectonic modification is the key to the enrichment of halite-type polyhalite and potassiumlithium brines.Fourth,the ore-forming process has gone through four stages:salt-gathering and potassium-lithium accumulation period,initial water-rock reaction period,transformation and aggregation period,and enrichment and finalization period.During this process,the halite-type polyhalite layer in Jia 4 Member and Jia 5 Member is the main target for potassium solution mining,while the brine layer in Lei 1 Member is the focus of comprehensive potassium-lithium exploration and development.展开更多
Taking the second member of the Xujiahe Formation of the Upper Triassic in the Xinchang structural belt as an example,based on data such as logging,production,seismic interpretation and test,a systematic analysis was ...Taking the second member of the Xujiahe Formation of the Upper Triassic in the Xinchang structural belt as an example,based on data such as logging,production,seismic interpretation and test,a systematic analysis was conducted on the structural characteristics and evolution,reservoir diagenesis and densification processes,and types and stages of faults/fractures,and revealing the multi-stage and multi-factor dynamic coupled enrichment mechanisms of tight gas reservoirs.(1)In the early Yanshan period,the paleo-structural traps were formed with low-medium maturity hydrocarbons accumulating in structural highs driven by buoyancy since reservoirs were not fully densified in this stage,demonstrating paleo-structure control on traps and early hydrocarbon accumulation.(2)In the middle-late Yanshan period,the source rocks became mature to generate and expel a large quantity of hydrocarbons.Grain size and type of sandstone controlled the time of reservoir densification,which restricted the scale of hydrocarbon charging,allowing for only a small-scale migration through sand bodies near the fault/fracture or less-densified matrix reservoirs.(3)During the Himalayan period,the source rocks reached overmaturity,and the residual oil cracking gas was efficiently transported along the late-stage faults/fractures.Wells with high production capacity were mainly located in Type I and II fault/fracture zones comprising the late-stage north-south trending fourth-order faults and the late-stage fractures.The productivity of the wells was controlled by the transformation of the late-stage faults/fractures.(4)The Xinchang structural belt underwent three stages of tectonic evolution,two stages of reservoir formation,and three stages of fault/fractures development.Hydrocarbons mainly accumulated in the paleo-structure highs.After reservoir densification and late fault/fracture adjustment,a complex gas-water distribution pattern was formed.Thus,it is summarized as the model of“near-source and low-abundance hydrocarbon charging in the early stage,and differential enrichment of natural gas under the joint control of fault-fold-fracture complex,high-quality reservoirs and structural highs in the late stage”.Faults/fractures with well-coupled fault-fold-fracture-pore are favorable exploration targets with high exploration effectiveness.展开更多
Based on recent advancements in shale oil exploration within the Ordos Basin,this study presents a comprehensive investigation of the paleoenvironment,lithofacies assemblages and distribution,depositional mechanisms,a...Based on recent advancements in shale oil exploration within the Ordos Basin,this study presents a comprehensive investigation of the paleoenvironment,lithofacies assemblages and distribution,depositional mechanisms,and reservoir characteristics of shale oil of fine-grained sediment deposition in continental freshwater lacustrine basins,with a focus on the Chang 7_(3) sub-member of Triassic Yanchang Formation.The research integrates a variety of exploration data,including field outcrops,drilling,logging,core samples,geochemical analyses,and flume simulation.The study indicates that:(1)The paleoenvironment of the Chang 7_(3) deposition is characterized by a warm and humid climate,frequent monsoon events,and a large water depth of freshwater lacustrine basin.The paleogeomorphology exhibits an asymmetrical pattern,with steep slopes in the southwest and gentle slopes in the northeast,which can be subdivided into microgeomorphological units,including depressions and ridges in lakebed,as well as ancient channels.(2)The Chang 7_(3) sub-member is characterized by a diverse array of fine-grained sediments,including very fine sandstone,siltstone,mudstone and tuff.These sediments are primarily distributed in thin interbedded and laminated arrangements vertically.The overall grain size of the sandstone predominantly falls below 62.5μm,with individual layer thicknesses of 0.05–0.64 m.The deposits contain intact plant fragments and display various sedimentary structure,such as wavy bedding,inverse-to-normal grading sequence,and climbing ripple bedding,which indicating a depositional origin associated with density flows.(3)Flume simulation experiments have successfully replicated the transport processes and sedimentary characteristics associated with density flows.The initial phase is characterized by a density-velocity differential,resulting in a thicker,coarser sediment layer at the flow front,while the upper layers are thinner and finer in grain size.During the mid-phase,sliding water effects cause the fluid front to rise and facilitate rapid forward transport.This process generates multiple“new fronts”,enabling the long-distance transport of fine-grained sandstones,such as siltstone and argillaceous siltstone,into the center of the lake basin.(4)A sedimentary model primarily controlled by hyperpynal flows was established for the southwestern part of the basin,highlighting that the frequent occurrence of flood events and the steep slope topography in this area are primary controlling factors for the development of hyperpynal flows.(5)Sandstone and mudstone in the Chang 7_(3) sub-member exhibit micro-and nano-scale pore-throat systems,shale oil is present in various lithologies,while the content of movable oil varies considerably,with sandstone exhibiting the highest content of movable oil.(6)The fine-grained sediment complexes formed by multiple episodes of sandstones and mudstones associated with density flow in the Chang 7_(3) formation exhibit characteristics of“overall oil-bearing with differential storage capacity”.The combination of mudstone with low total organic carbon content(TOC)and siltstone is identified as the most favorable exploration target at present.展开更多
1.Objectives,A nearly E-W trending Early Mesozoic alkaline and mafic rock belt is exposed on the northern margin of the North China Craton(NCC),and geochemistry and isotope studies indicate that the magmas were origin...1.Objectives,A nearly E-W trending Early Mesozoic alkaline and mafic rock belt is exposed on the northern margin of the North China Craton(NCC),and geochemistry and isotope studies indicate that the magmas were originated from the depleted lithospheric mantle,implying the thinning and destruction of the lithosphere in the northern margin and eastern of the NCC(Zhang SH et al.,2012).The Alxa Block is located in the westernmost part of the NCC,which plays a significant part in understanding the tectonic evolution of the NCC.This paper mainly reports a firstly discovered 217 Ma gabbro from the Yabulai district in the western Alxa Block,where widely exposes Late Paleozoic intermediate-acid intrusive rocks and volcanic rocks(Liu Q et al.,2017).展开更多
The late Palaeozoic tectonic magmatism in the north-ern Qaidam tectonic belt(NQTB)related to the Palaeo-Tethys Ocean has become a critical issue.We performed a detailed geochronological and geochemical study of Lenghu...The late Palaeozoic tectonic magmatism in the north-ern Qaidam tectonic belt(NQTB)related to the Palaeo-Tethys Ocean has become a critical issue.We performed a detailed geochronological and geochemical study of Lenghu(LH)granitic rocks in the western NQTB.LA-ICP-MS U-Pb dating of zircons from LH granitic rocks yields emplacement ages of 253±4 Ma and 264±4 Ma,indicating a two-stage emplacement process.Geochemi-cal analyses show that the LH granitic rocks have low ACNK values and are enriched in LILEs(Rb,Th,Ba)and depleted in HFSEs(Sr,Nd,and Ta).The samples are enriched in LREEs(LREE/HREE=1.5-7.3).Values of(La/Yb)N range between 0.9 and 6.5,and all samples show negative Eu anomalies(δEu=0.2-0.6),with typical characteristics of island arc magmatism.The LH granitic rocks haveεHf(t)values of-3.7 to+8.0 and yield a TCDM age of 1.51-0.78 Ga.The data suggest that the LH granitic rocks were derived from partial melting of Proterozoic crust-related mafic to intermediate rocks with significant crust-mantle interac-tions.The results,combined with regional magmatic informa-tion,indicate that the Late Permian-early Triassic magmatism in western NQTB were controlled by subduction rollback-retraction of South Kunlun Oceanic plate under the Kun-lun-Qaidam Block.展开更多
The Tongling area is one of the 7 ore-cluster areas in the Middle-Lower Yangtze metallogenic belt, East China, and has tectonically undergone a long-term geologic history from the late Paleozoic continental rifting, t...The Tongling area is one of the 7 ore-cluster areas in the Middle-Lower Yangtze metallogenic belt, East China, and has tectonically undergone a long-term geologic history from the late Paleozoic continental rifting, through the Middle Triassic continent-continent collision to the Jurassic-Cretaceous intracontinental tectono-magmatic activation. The Carboniferous sedimentary-exhalative processes in the area produced widespread massive sulfides with ages of 303-321 Ma, which partly formed massive pyrite-Cu deposits, but mostly provided significant sulfur and metals to the skarn Cu mineralization associated with the Yanshanian felsic intrusions.To understand the Carboniferous submarine hydrothermal system, an area of about 1046 km^2 was chosen to carry out the geological fluid mapping. Associated with massive sulfide formation, footwall sequences 948 m to 1146 m thick, composed of the Lower Silurian-Upper Devonian sandstone, siltstone and thin-layered shale, were widely altered. This hydrothermal alteration is interpreted to reflect largescale hydrothermal fluid flow associated with the late Paleozoic crustal rifting and subsidence. Three hydrothermal alteration types, i.e., deep-level semiconformable siliclfication （S1）, fracture-controlled quartz-sericite-pyrite alteration （S2-3）, and upper-level sub-discordant quartz-sericite-chlorite alteration （D3）, were developed to form distinct zones in the mapped area. About 50-m thick semiconformable silicification zones are located at -1-km depth below massive sulfides and developed between an impermeable shale caprock （S1） and the underlying Ordovician unaltered limestone. Comparisons with modern geothermal systems suggest that the alteration zones record a sub-seafioor aquifer with the most productive hydrothermal fluid flow. Fracture-controlled quartz-sericite-pyrite alteration formed transgressive zones, which downward crosscut the semiconformable alteration zones, and upwards grade into sub-discordant alteration zones that enveloped no economic stringer- stockwork zones beneath massive sulfides. This transgressive zone likely marks an upfiow path of high- flux fluids from the hydrothermal aquifer. Lateral zonation of the sub-discordant alteration zones and their relationship to overlying massive sulfide lenses suggest lateral flows and diffusive discharging of the hydrothermal fluids in a permeable sandstone sequence. Three large-sized, 14 middle-small massive sulfide deposits, and 40 massive sulfide sites have been mapped in detail. They show regional strata- bound characters and two major styles, i.e., the layered sheet plus strata-bound stringer-style and the mound-style. Associated exhalite and chemical sedimentary rock suites include （1） anhydrite-barite, （2） jasper-chert, （3） Mg-rich mudstone-pyrite shale, （4） barite lens, （5） siderite-Fe-bearing dolomite, and （6） Mn-rich shale-mudstone, which usually comprise three sulfide-exhalite cyclic units in the area.The spatial distribution of these alteration zones （minerals） and associated massive sulfdes and exhalites, and regional variation in δ^34S of hydrothermal pyrite and in δ^18O-δ^34C of hanging wall carbonates, suggest three WNW-extending domains of fluid flow, controlled by the basement faults and syn-depositional faults. Each fluid domain appears to have at least two upflow zones, with estimated even spacing of about 5-8 km in the mapped area. The repeated appearance of sulfide-sulfate or sulfide-carbonate rhythmic units in the area suggests episodically venting of fluids through the upfiow conduits by breaking the overlying seals of the hydrothermal aquifer.展开更多
In the East Asian monsoon region, eolian deposits widely distributed in the middle-lower reaches of the Yantgze River are among the best materials available for studies on Quaternary climate change in the subtropical ...In the East Asian monsoon region, eolian deposits widely distributed in the middle-lower reaches of the Yantgze River are among the best materials available for studies on Quaternary climate change in the subtropical zone of Southern China. Typical eolian deposits in this region include upper Xiashu Loess （XL） and underlying Vermiculated Red Soil （VRS） layers. In this paper, chronological and paleoclimatic studies are conducted on an eolian deposit sequence near Jiujiang （J J） city in northern Jiangxi province. A magnetostratigraphic study, combined with optically stimulated luminescence （OSL） dating, is conducted on the JJ section and provides further evidence that eolian deposits in the middle-lower reaches of the Yangtze River have been formed since the late Early Pleistocene, and that the boundary age between the XL and VRS layers is about 300-400 kaBP. In grain-size records of the JJ section, the median grain-size and content of the 〉30μn size fraction increase sharply after 300-400 kaBP, representing an East Asian winter monsoon intensification event. Further pollen analysis reveals differing pollen assemblages before and after 300-400 kaBP： there is an evident increase in plants adapted to grow in a warm humid environment after 300-400 kaBP, implying an increase in precipitation caused by intensification of the East Asian summer monsoon. Global ice volume and uplift of the Tibet Plateau （TP） are regarded as crucial factors influencing variations of the East Asian monsoon on a long-term scale. The deep-sea JlSO record, which reflects variations in global ice volume, shows no obvious change after 300-400 kaBP. Moreover, the influence of global ice volume changes on the East Asian summer and winter monsoons is inverse; the global ice volume increase （decrease） implies a strengthened （weakened） winter monsoon and weakened （strengthened） summer monsoon. We therefore interpret the coupled intensifications of the East Asian summer and winter monsoons at about 300-400 kaBP to the uplift of the TP in the Middle Pleistocene. This climate event is also documented in eolian deposits from the southern margin of the Chinese Loess Plateau （CLP） and from the desert-loess transitional belt. However, it is not recorded in the loess-paleosol sequences from the central part of the CLP, thereby indicating differing climate responses to TP uplift in different regions, which requires further study.展开更多
The Tongshankou Cu-Mo deposit, located in southeast Hubei province, is a typical skarn–porphyry type ore deposit closely related to the Tongshankou granodiorite porphyry, characterized by a high Sr/Y ratio.Detailed i...The Tongshankou Cu-Mo deposit, located in southeast Hubei province, is a typical skarn–porphyry type ore deposit closely related to the Tongshankou granodiorite porphyry, characterized by a high Sr/Y ratio.Detailed in situ analyses of the trace elements and U–Pb and Lu–Hf isotopes in zircons from the Tongshankou granodiorite porphyry were performed.Scarcely any inherited zircons were observed, and the analyzed zircons yielded highly concordant results with a weighted mean 206Pb/238 U age of 143.5 ± 0.45 Ma（n=20, mean square weighted deviation was 0.75）, which was interpreted to represent the crystallization age of the Tongshankou granodiorite porphyry.The chondrite-normalized rare-earth element pattern was characterized by a slope that steeply rises from the light-group rare-earth elements（LREE） to the heavy-group rare-earth elements（HREE） with a positive Ce-anomaly and inconspicuous Eu-anomaly, which was coincident with the pattern of the zircons from the Chuquicamata West porphyry, Chile.The analyzed zircons also had relatively low 176Hf/177 Hf ratios of 0.282526–0.282604.Assuming t=143 Ma, the corresponding calculated initial Hf isotope compositions（εHf（t）） ranged from-5.6 to-2.9.The results of the in situ analysis of trace elements and U–Pb and Lu–Hf isotopes in zircons from the Tongshankou granodiorite porphyry suggest that a deep-seated process involving a thickened-crust/enriched-mantle interaction may play an important role in the generation of high Sr/Y-ratio magma and potentially in the generation of porphyry Cu-Mo systems.展开更多
The Nanling-Xuancheng ore region of Anhui Province is located in the Middle-Lower Yangtze River metallogenic belt.Insufficient exploration and research have been carried out in this newly defined ore district,although...The Nanling-Xuancheng ore region of Anhui Province is located in the Middle-Lower Yangtze River metallogenic belt.Insufficient exploration and research have been carried out in this newly defined ore district,although the Chating large porphyry Cu-Au deposit and a few middle-sized skarntype Cu polymetallic deposits have been discovered.In this study,we carried out high-resolution seismic reflection,magnetotelluric,gravity,and magnetic investigations,and constructed the 3 D geological structure of the uppermost crust in a depth range of 0-5 km using a comprehensive inversion of the new data constrained by previous deep-drilling data.We hence proposed some new insights to understand the mineralization processes of this district.A system of alternating ridges and valleys is suggested as the major structure pattern,composed of“two-layer structure”of the basins and“three-layer structure”of anticlines.Moreover,a conjugated fault system and its distribution features are revealed in our models,including the Jiangnan fault,Zhouwang fault,and Kunshan thrust nappe.The Jiangnan and Kunshan faults are suggested to have controlled the diagenesis and metallogenesis.Two deep concealed plutons located in Chating and Magushan are found,forming the Mesozoic diorite-felsic intrusions.These intrusions are believed to be the causes of hydrothermal deposits such as the Chating deposit and the Magushan deposit.展开更多
The Datuanshan deposit is one of the largest and most representative stratabound copper deposits in the Tongling area,the largest ore district in the Middle-Lower Yangtze River metallogenic belt.The location of the or...The Datuanshan deposit is one of the largest and most representative stratabound copper deposits in the Tongling area,the largest ore district in the Middle-Lower Yangtze River metallogenic belt.The location of the orebodies is controlled by the interlayer-slipping faults between the Triassic and Permian strata,and all the orebodies are distributed in stratiform shape around the Mesozoic quartz monzodiorite dikes.Based on field evidence and petrographic observations,four mineralization stages in the Datuanshan deposit have been identified：the skarn,early quartz-sulfide,late quartzsulfide and carbonate stages.Chalcopytite is the main copper mineral and mainly formed at the late quartz-sulfide stage.Fluid inclusions at different stages were studied for petrography,microthermometry,laser Raman spectrometry and stable isotopes.Four types of fluid inclusions,including three-phase fluid inclusions（type 1）,liquid-rich fluid inclusions（type 2）,vapour-rich fluid inclusions（type 3） and pure vapour fluid inclusions（type 4）,were observed.The minerals from the skarn,early and late quartz-sulfide stages contain all fluid inclusion types,but only type 2 fluid inclusions were observed at the carbonate stage.Petrographic observations suggest that most of the inclusions studied in this paper are likely primary.The coexistence of different types of fluid inclusions with contrasting homogenization characteristics（to the liquid and vapour phase,respectively） and similar homogenization temperatures（the modes are 440-480℃,380-400℃ and 280-320℃ for the skarn,early and late quartz-sulfide stages,respectively） in the first three stages,strongly suggests that three episodes of fluid boiling occurred during these stages,which is supported by the hydrogen isotope data.Laser Raman spectra identified CH_4 at the skarn and early quartz-sulfide stages.Combined with other geological features,the early ore-forming fluids were inferred to be under a relatively reduced environment.The CO_2 component has been identified at the late quartz-sulfide and carbonate stages,indicating that the late ore-forming fluids were under a relatively oxidized environment,probably as a result of inflow of and mixing with meteoric water.In addition,microthermometric results of fluid inclusions and H-O isotope data mdicate that the ore forming fluids were dominated by magmatic water in the early stages（skarn and early quartz-sulfide stages） and mixed with meteoric water in the late stages（late quartz-sulfide and carbonate stages）.The evidence listed above suggests that the chalcopyrite deposition in the Datuanshan deposit probably resulted from the combination of multiepisode fluid boiling and mixing of magmatic and meteoric water.展开更多
In order to examine the impacts of water-sediment regulation on regional carbon cycling,we collected water,particulate and sediment samples from the middle-lower Yellow River in late June and early July,2015 and analy...In order to examine the impacts of water-sediment regulation on regional carbon cycling,we collected water,particulate and sediment samples from the middle-lower Yellow River in late June and early July,2015 and analyzed their specific amino acids(AA),DOC,POC,and bacteria abundance.Summarized by 14 specific AA,the total hydrolysable AA(THAA),particulate AA(PAA),and sediment AA(SAA)varied in ranges of 2.29-9.05μmol L^-1,5.22-22.96μmol L^-1,and 81.7-137.19μg g^-1 dry weight.After the regulation,dissolved free AA(DFAA)decreased by 29%while DCAA increased by 72%.These variations suggested that DFAA were further degraded,while DCAA molecules were further activated.Meanwhile,PAA increased almost 4 times as many as those before regulation,and SAA increased as well.After regulation,the amounts of bioactive amino acids(Asp,Glu and Gly)increased in THAA but decreased in PAA,with little changes in SAA.The ratios of Asp/Gly in different phases increased after regulation,indicating the AA contributions were promoted by calcareous organisms rather than by siliceous organisms.Multiple correlation analysis showed that PAA was primary representatives of AA and organic carbon,followed by DCAA and POC.Moreover,bacterial reproduction played a key role in shaping the AA compositions and properties,followed by the redox condition and acid-base balance.The results of this study provided a clear evidence for the effects of water-sediment regulation on regional biogeochemistry of organic carbon in the middle-lower Yellow River.展开更多
The Middle-Lower Yangtze River Metallogenic Belt(MLYB)is known to contain abundant copper and iron porphyry-skarn deposits,with an increasing number of tungsten deposits and scheelite in Fe-Cu deposits being discovere...The Middle-Lower Yangtze River Metallogenic Belt(MLYB)is known to contain abundant copper and iron porphyry-skarn deposits,with an increasing number of tungsten deposits and scheelite in Fe-Cu deposits being discovered in the MLYB during recent decades.The ore genesis of the newly-discovered tungsten mineralization in the MLYB is poorly understood.We investigate four sets of scheelite samples from tungsten,iron and copper deposits,using CL imaging and LA-ICP-MS techniques to reveal internal zonation patterns and trace element compositions.The REE distribution patterns of four studied deposits show varying degrees of LREE enrichment with negative Eu anomalies.The oxygen fugacity of ore-forming fluid increased in Donggushan,while the oxygen fugacity of ore-forming fluid decreased in Ruanjiawan,Guilinzheng and Gaojiabang.The scheelites from the Donggushan,Ruanjiawan,Guilinzheng and Gaojiabang deposits show enrichment in LREEs and HFSE,with Nb/La ratios ranging from 1.217 to 52.455,indicating that the four tungsten deposits are enriched in the volatile fluorine.A plot of(La/Lu)N versus Mo/δEu can be used to distinguish quartz vein type,porphyry and skarn tungsten deposits.This study demonstrates that scheelite grains can be used to infer tungsten mineralization and are effective in identifying magmatic types of tungsten deposits in prospective mining sites.展开更多
Thallium has been used geochemical exploration of gold deposits. However, as an indicator element in searching for hydrothermal the T1 minerals and mineralization are rare in nature. Lorandite T1AsS2, a relatively un...Thallium has been used geochemical exploration of gold deposits. However, as an indicator element in searching for hydrothermal the T1 minerals and mineralization are rare in nature. Lorandite T1AsS2, a relatively uncommon mineral, has been dominantly discovered in some Carlin gold deposits, and minor Sb- Hg, U and Pb-Zn-Ag deposits.展开更多
文摘The middle-lower Yangtze area underwent a series of complex tectonic evolution, such as Hercynian extensional rifting, Indosinian foreland basining, and Yanshanian transpression-transtension, resulting in a large distinctive Cu-Fe-Au metallogenic belt. In the tectonic evolution, large-scale migration and convergence of fluids toward foreland basins induced during the collisional orogeny of the Yangtze and North China continental blocks were of vital importance for the formation of the metallogenic belt. Through geological surveys of the middle-lower Yangtze area, three lines of evidence of large-scale fluid migration are proposed: (1) The extensive dolomitic and silicic alteration penetrating Cambrian-Triassic strata generally occurs in a region sandwiched between the metallogenic belt along the Yangtze River and the Dabie orogenic belt, and in the alteration domain alternately strong and weak alteration zones extend in a NW direction and are controlled by the fault system of the Dabie orogenic belt; it might record the locus of the activities of long-distance migrating fluids. (2) The textures and structures of very thick Middle-Lower Triassic anhydrock sequences in restricted basins along the river reveal the important contribution of the convergence of regional hot brine in restricted basins and the chemical deposition or their formation. (3) Early-Middle Triassic syndepositional iron carbonate sequences and Fe-Cu-Pb-Zn massive sulfide deposits alternate with anhydrock sequences or are separated from the latter, but all of them occur in the same stratigraphic horizon and are intimately associated with each other, being the product of syndeposition of high-salinity hot brine. According to the geological surveys, combined with previous data, the authors propose a conceptual model of fluid migration-convergence and mineralization during the Dabie collisional orogeny.
基金Supported by projects of the National Natural Science Foundation of China(Nos.42372063,41722204).
文摘This study presents LA–ICP–MS U–Pb dating and whole-rock geochemical analyses of the Late Triassic Gangshan harzburgite in the Qingyuan area,with the aim of elucidating its petrogenesis and further constraining the early Mesozoic tectonic evolution of the eastern segment of the northern margin of the North China Block(NCB).Zircons from the harzburgites exhibit typical oscillatory growth zoning or striped absorp-tion in cathodoluminescence images.U–Pb analyses of zircons yield ages ranging from 2525 Ma to 225 Ma,with two youngest ages(225±7 Ma)indicating that the harzburgites were formed during Late Triassic.Geochemical analyses of the Gangshan harzburgites show that the rocks have low concentrations of SiO_(2)(42.38%–42.85%)and Al_(2)O_(3)(3.31%–3.33%),along with high concentrations of MgO(41.32%–41.76%),Cr(4856×10^(-6)–5191×10^(-6))and Ni(1942×10^(-6)–2041×10^(-6)).They also display low REE abundances(∑REE=4.38×10^(-6)–4.69×10^(-6))and flat REE patterns with low(La/Yb)_(N) ratios(1.24–1.56)and slightly po-sitive Eu anomalies(δEu=1.13–1.16).These features suggest that the Gangshan harzburgites are cumulates of basaltic magma derived from the depleted lithospheric mantle.Combined with previous studies,these Late Triassic mafic–ultramafic rocks,together with coeval granitoids in adjacent regions,constitute a typical bimodal association,suggesting that they formed in a post-orogenic extensional environment after the final closure of the Paleo-Asian Ocean.
基金supported by the National Key Research and Development Program of China(Grant No.2017YFC0602704)the National Natural Science Foundation of China(Grant No.U20B6001 and 91755211).
文摘The Qinling orogenic belt in central China underwent long-term tectonic evolution during an amalgamation between the North China and South China cratons.However,intense compressional deformation and uplift erosion resulted in the transformation and disappearance of much geological record from the Qinling orogenic belt,and the tectonic evolution of this belt remains poorly constrained during the Triassic.Located in the northernmost margin of the South China Craton,the Sichuan Basin preserves the complete Triassic sedimentary succession,and can provide significant information for understanding the Triassic tectonic evolution of the Qinling orogenic belt.We present detrital zircon U-Pb dating,trace element and in situ Lu-Hf isotope data for the Middle Triassic Leikoupo Formation and the Late Triassic Xujiahe Formation samples from the eastern Sichuan Basin,South China.The detrital zircon U-Pb ages of the Leikoupo Formation show seven age clusters of 280-242,350-300,500-400,1000-800,2000-1750,2100-2000 and 2600-2400 Ma,while those of the Xujiahe Formation show five age clusters of 300-200,500-350,1050-950,2000-1750 and 2600-2400 Ma.Combined with published paleocurrent and paleogeographic data,the sediments of the Leikoupo Formation are interpreted to be sourced from the North China Craton,Yangtze Craton and North Qinling orogenic belt,and the potential main source regions of the Xujiahe Formation included the South and North Qinling orogenic belts.Provenance analysis indicates that the North Qinling orogenic belt was in inherited uplift and coeval denudation in the Middle Triassic.The proportion of the detritus formed in the South Qinling orogenic belt increases gradually from the Leikoupo to Xujiahe formations.This significant provenance change indicates that rapid tectonic uplift and extensive denudation of the South Qinling orogenic belt occurred in the early Late Triassic,which is related to the collision between the North China and South China cratons during the Triassic.
基金supported financially by the Research Foundation of the Department of Natural Resources of Hunan Province(20230135DZ)the Provincial Natural Science Foundation of Hunan(2024JJ7080)+1 种基金the Scientific Research Fund of Hunan Provincial Education Department(23C0320)Hunan Provincial College Student Innovation and Entrepreneurship Training Project(S202311527014).
文摘There is significant debate concerning the tectonic characteristics and evolutionary understanding of the South China Block(SCB)during the Early Mesozoic.One of the key points of contention is the tectonic-magmatic activity during the Triassic and its dynamic mechanisms.However,research on the detailed chronology and tectonic settings of granite plutons in key regions remains insuffi-cient,limiting the understanding of the tectonic-magmatic dynamic mechanisms in the interior of SCB during the Triassic.In this contribution,we present whole-rock major and trace elemental data,Sr-Nd isotope data,LA-ICP-MS zircon U-Pb age dating,and Lu-Hf isotope data for granites of Dashenshan pluton in the Xiangzhong,northwest part of SCB.The results indicate that the Dashenshan granite has an emplacement age of 208.4-212.5 Ma,characterized by high SiO_(2),Na_(2)O,and K_(2)O contents and low MgO and CaO.The Dashenshan granite is enriched in light rare-earth elements with a significant negative Eu anomaly(averageδEu=0.42).It is also enriched in Rb,K,and Th and shows pronounced depletion in Nb,Ta,and Ti,classifying it as peraluminous calc-alkaline granite,specifically of the I-type.The zircon ε_(Hf(t)) values range from−8.39 to−4.4,with an average of−5.82,and the Sr-Nd isotopes are relatively enriched[ε_(Nd)(t)=−9.31 to−6.8].Combining these geochemical characteristics,it is revealed that the Dashenshan granite was derived from the partial melting of middle to upper crustal metamorphic basement materials under medium-to low-temperature conditions,with possible minor contributions from mantle-derived materials.Furthermore,it underwent fractional crystallization,including plagioclase differentiation.By integrating the geochemical features and spatial distribution of Triassic granites in SCB,this study suggests that the regional tectonic evolution of SCB during the Triassic was primarily controlled by the collision of the SCB with the Indochina Block and the North China Block.In Xiangzhong,the tectonic setting transitioned from syn-collisional compression to post-collisional extension during the Late Triassic.The Dashenshan pluton formed in a post-collisional extensional setting,resulting from the decompression melting of middle-to-upper crustal rocks.The upwelling of the asthenosphere and upward heat transfer likely played a significant role in the formation of the Dashenshan granitic magma.
基金funded by a SINOPEC project entitled Exploration Potential and Target Evaluation of Xujiahe Formation in the Northeastern Sichuan Basin(No.P23130).
文摘The recent discovery of natural gas within the fifth member of the Xujiahe Formation(T_(3)x_(5))in the Dongfeng area within the Sichuan Basin highlights the significant exploration potential of this member.However,the unconvincing previous understanding of the sedimentary microfacies,combined with a total lack of studies on the sand body architecture and reservoir distribution,hampers the further exploration of this member.Using core data,log curves,and seismic data,along with sedimentary microfacies analysis,this study investigated the interfaces between the sand bodies of various scales in the Dongfeng area.Furthermore,this study explored the morphological characteristics,types,and stacking patterns of these sand bodies and determined the distributions of sand bodies and reservoirs in the area.The results indicate that the first sand group of the T_(3)x_(5) member(T_(3)x^(1)_(5))exhibits delta-front deposits,including subaqueous distributary channels,sheet sands,and interdistributary bays.Seven levels of sand body interfaces are identified in the T_(3)x^(1)_(5) sand group.Among them,the interfaces of the first and second levels were identified only in cores,those of the third and fourth levels were recog-nizable from cores combined with log curves,while those of the fifth,sixth,and seventh levels were distinguishable using seismic data.Three superimposed subaqueous distributary channel complexes are found in the Dongfeng area.Among them,complex 1 in the northwest exhibits the strongest water body energy,while complex 2 in the south displays the weakest.Complex 2 was formed earlier than com-plexes 1 and 3.Also,complex 1 is further subdivided into three vertically stacked subaqueous distrib-utary channels.The subdivision of sedimentary microfacies in the T_(3)x_(5) member reveals nine lithofacies types.Among them,stacked pancake-shaped,carbonaceous debris-bearing,massive,and cross-bedded medium-grained sandstones are considered favorable lithofacies.These four lithofacies types exhibit high porosity,as well as low natural gamma-ray(GR)values,low-to-medium deep investigate double lateral resistivity(RD),and high interval transit time(AC)on the log curves.Additionally,the reservoir distribution in the Dongfeng area was delineated based on the characterization of the favorable lith-ofacies.This study serves as a guide for future exploration and evaluation of the T_(3)x_(5) member in the Dongfeng area while also augmenting the methodologies for describing tight sandstone reservoirs.
基金Supported by the National Natural Science Foundation of China(No.U 2344221)。
文摘The Yangtze Plate(YP)and the North China Plate(NCP)are key components of the East Asian continent,and their collision significantly influences the tectonic evolution of the eastern Asian continental margin.As the South Yellow Sea is located at the convergence of these plates,it becomes a pivotal area for understanding the tectonic evolution of East Asia.The characteristics and provenance of clastic rocks of the Middle Permian-the Early Triassic were analyzed and the strata in the Central Uplift including the Qinglong Formation(T_(1)q)and Talung Formation(P_(3)d),consisting of various mudstones and sandstones,were anatomized.Results show that quartz and feldspar are the main diagenetic minerals,while illite and chlorite show signs of secondary alterations.Geochemical imprints indicate a gradual shift in provenance from ancient sedimentary and mafic igneous rocks to intermediate igneous rocks.In the meantime,the tectonic background transformed from continent to continental island arc from the Middle Permian to the Early Triassic.Therefore,we inferred that a soft collision between the North China Plate and the Yangtze Plate likely occurred during the Late Permian,resulted in intensified collision between two plates in the Early Triassic,and shaped the South Yellow Sea.This study provided valuable information on the timing of plate collisions in the South Yellow Sea.
基金Supported by the National Natural Science Foundation of China(42302184)Innovation Group Project of Basic Research in Gansu Province,China(22JR5RA045)。
文摘The lamina(combination)types,reservoir characteristics and shale oil occurrence states of organic-rich shale in the Triassic Yanchang Formation Chang 73 sub-member in the Ordos Basin were systematically investigated to reveal the main controlling factors of shale oil occurrence under different lamina combinations.The differential enrichment mechanisms and patterns of shale oil were discussed using the shale oil micro-migration characterization and evaluation methods from the perspectives of relay hydrocarbon supply,stepwise migration,and multi-stage differentiation.The results are obtained in five aspects.First,Chang 73 shale mainly develops five types of lamina combination,i.e.non-laminated shale,sandy laminated shale,tuffaceous laminated shale,mixed laminated shale,and organic-rich laminated shale.Second,shales with different lamina combinations are obviously different in the reservoir space.Specifically,shales with sandy laminae and tuffaceous laminae have a large number of intergranular pores,dissolution pores and hydrocarbon generation-induced fractures.The multi-scale pore and fracture system constitutes the main place for liquid hydrocarbon occurrence.Third,the occurrence and distribution of shale oil in shale with different lamina combinations are jointly controlled by organic matter abundance,reservoir property,thermal evolution degree,mineral composition and laminae scale.The micro-nano-scale pore-fracture networks within shales containing rigid laminae,particularly sandy and tuffaceous laminations,primarily contain free-state light hydrocarbon components.In contrast,adsorption-phase heavy hydrocarbon components predominantly occupy surfaces of organic matter assemblages,clay mineral matrices,and framework mineral particulates.Fourth,there is obvious shale oil micro-migration between shales with different lamina combinations in Chang 73.Generally,such micro-migration is stepwise in a sequence of organic-rich laminated shale→tuffaceous laminated shale→mixed laminated shale→sandy lamiated shale→non-laminated shale.Fifth,the relay hydrocarbon supply of organic matter under the control of the spatial superposition of shales with various laminae,the stepwise migration via multi-scale pore and fracture network,and the multi-differentiation in shales with different lamina combinations under the control of organic-inorganic interactions fundamentally decide the differences of shale oil components between shales with different lamina combinations.
基金Supported by the National Research and Development Program(2017YFC0602804)Geological Bureau Program of Sichuan Province(SCDZ-KJXM202403).
文摘Wells CXD1 and CX2 have uncovered high-concentration potassium-and lithium-containing brines and substantial layers of halite-type polyhalite potash deposits within the 4th and 5th members of the Triassic Jialingjiang Formation and the 1st Member of Leikoupo Formation(Jia 4 Member,Jia 5 Member,and Lei 1 Member)in the Puguang area,Sichuan Basin.These discoveries mark significant breakthroughs in the exploration of deep marine potassium and lithium resources within the Sichuan Basin.Utilizing the concept of“gas-potassium-lithium integrated exploration”and incorporating drilling,logging,seismic,and geochemical data,we have investigated the geological and enrichment conditions,as well as the metallogenic model of potassium-rich and lithium-rich brines and halite-type polyhalite.First,the sedimentary systems of gypsum-dolomite flats,salt lakes and evaporated flats were developed in Jia 4 Member,Jia 5 Member,and the 1st member of Leikoupo Formation(Lei 1 Member)in northeastern Sichuan Basin,forming three large-scale salt-gathering and potassium formation centers in Puguang,Tongnanba and Yuanba,and developing reservoirs with potassium-rich and lithium-rich brines,which are favorable for the deposition of potassium and lithium resources in both solid or liquid phases.Second,the soluble halite-type polyhalite has a large thickness and wide distribution,and the reservoir brine has a high content of K+and Li+.A solid-liquid superimposed“three-story structure”(with the lower thin-layer of brine reservoir in lower part of Jia 4 Member and Jia 5 Member,middle layer of halite-type polyhalite potash depositS,upper layer of potassium-rich and lithium-rich brine reservoir in Lei 1 Member)is formed.Third,the ternary enrichment and mineralization patterns for potassium and lithium resources were determined.Vertical superposition of polyhalite and green bean rocks is the mineral material basis of potassium-lithium resources featuring“dual-source replenishment and proximal-source release”,with primary seawater and gypsum dehydration as the main sources of deep brines,while multi-stage tectonic modification is the key to the enrichment of halite-type polyhalite and potassiumlithium brines.Fourth,the ore-forming process has gone through four stages:salt-gathering and potassium-lithium accumulation period,initial water-rock reaction period,transformation and aggregation period,and enrichment and finalization period.During this process,the halite-type polyhalite layer in Jia 4 Member and Jia 5 Member is the main target for potassium solution mining,while the brine layer in Lei 1 Member is the focus of comprehensive potassium-lithium exploration and development.
基金Supported by the National Natural Science Foundation of China(42302141).
文摘Taking the second member of the Xujiahe Formation of the Upper Triassic in the Xinchang structural belt as an example,based on data such as logging,production,seismic interpretation and test,a systematic analysis was conducted on the structural characteristics and evolution,reservoir diagenesis and densification processes,and types and stages of faults/fractures,and revealing the multi-stage and multi-factor dynamic coupled enrichment mechanisms of tight gas reservoirs.(1)In the early Yanshan period,the paleo-structural traps were formed with low-medium maturity hydrocarbons accumulating in structural highs driven by buoyancy since reservoirs were not fully densified in this stage,demonstrating paleo-structure control on traps and early hydrocarbon accumulation.(2)In the middle-late Yanshan period,the source rocks became mature to generate and expel a large quantity of hydrocarbons.Grain size and type of sandstone controlled the time of reservoir densification,which restricted the scale of hydrocarbon charging,allowing for only a small-scale migration through sand bodies near the fault/fracture or less-densified matrix reservoirs.(3)During the Himalayan period,the source rocks reached overmaturity,and the residual oil cracking gas was efficiently transported along the late-stage faults/fractures.Wells with high production capacity were mainly located in Type I and II fault/fracture zones comprising the late-stage north-south trending fourth-order faults and the late-stage fractures.The productivity of the wells was controlled by the transformation of the late-stage faults/fractures.(4)The Xinchang structural belt underwent three stages of tectonic evolution,two stages of reservoir formation,and three stages of fault/fractures development.Hydrocarbons mainly accumulated in the paleo-structure highs.After reservoir densification and late fault/fracture adjustment,a complex gas-water distribution pattern was formed.Thus,it is summarized as the model of“near-source and low-abundance hydrocarbon charging in the early stage,and differential enrichment of natural gas under the joint control of fault-fold-fracture complex,high-quality reservoirs and structural highs in the late stage”.Faults/fractures with well-coupled fault-fold-fracture-pore are favorable exploration targets with high exploration effectiveness.
基金Supported by the CNPC Major Science and Technology Project(2021DJ1806).
文摘Based on recent advancements in shale oil exploration within the Ordos Basin,this study presents a comprehensive investigation of the paleoenvironment,lithofacies assemblages and distribution,depositional mechanisms,and reservoir characteristics of shale oil of fine-grained sediment deposition in continental freshwater lacustrine basins,with a focus on the Chang 7_(3) sub-member of Triassic Yanchang Formation.The research integrates a variety of exploration data,including field outcrops,drilling,logging,core samples,geochemical analyses,and flume simulation.The study indicates that:(1)The paleoenvironment of the Chang 7_(3) deposition is characterized by a warm and humid climate,frequent monsoon events,and a large water depth of freshwater lacustrine basin.The paleogeomorphology exhibits an asymmetrical pattern,with steep slopes in the southwest and gentle slopes in the northeast,which can be subdivided into microgeomorphological units,including depressions and ridges in lakebed,as well as ancient channels.(2)The Chang 7_(3) sub-member is characterized by a diverse array of fine-grained sediments,including very fine sandstone,siltstone,mudstone and tuff.These sediments are primarily distributed in thin interbedded and laminated arrangements vertically.The overall grain size of the sandstone predominantly falls below 62.5μm,with individual layer thicknesses of 0.05–0.64 m.The deposits contain intact plant fragments and display various sedimentary structure,such as wavy bedding,inverse-to-normal grading sequence,and climbing ripple bedding,which indicating a depositional origin associated with density flows.(3)Flume simulation experiments have successfully replicated the transport processes and sedimentary characteristics associated with density flows.The initial phase is characterized by a density-velocity differential,resulting in a thicker,coarser sediment layer at the flow front,while the upper layers are thinner and finer in grain size.During the mid-phase,sliding water effects cause the fluid front to rise and facilitate rapid forward transport.This process generates multiple“new fronts”,enabling the long-distance transport of fine-grained sandstones,such as siltstone and argillaceous siltstone,into the center of the lake basin.(4)A sedimentary model primarily controlled by hyperpynal flows was established for the southwestern part of the basin,highlighting that the frequent occurrence of flood events and the steep slope topography in this area are primary controlling factors for the development of hyperpynal flows.(5)Sandstone and mudstone in the Chang 7_(3) sub-member exhibit micro-and nano-scale pore-throat systems,shale oil is present in various lithologies,while the content of movable oil varies considerably,with sandstone exhibiting the highest content of movable oil.(6)The fine-grained sediment complexes formed by multiple episodes of sandstones and mudstones associated with density flow in the Chang 7_(3) formation exhibit characteristics of“overall oil-bearing with differential storage capacity”.The combination of mudstone with low total organic carbon content(TOC)and siltstone is identified as the most favorable exploration target at present.
基金supported by the National Key Research and Development Project of the Ministry of Science and Technology of China(Grant No.2017YFC0601301)the Basic Scientific Research Fund of the Institute of Geology,Chinese Academy of Geological Sciences(No.J2103)+1 种基金the National Natural Science Foundation of China(Grant No.41572190,41972224)the China Geological Survey(Grants No.DD2019004).
文摘1.Objectives,A nearly E-W trending Early Mesozoic alkaline and mafic rock belt is exposed on the northern margin of the North China Craton(NCC),and geochemistry and isotope studies indicate that the magmas were originated from the depleted lithospheric mantle,implying the thinning and destruction of the lithosphere in the northern margin and eastern of the NCC(Zhang SH et al.,2012).The Alxa Block is located in the westernmost part of the NCC,which plays a significant part in understanding the tectonic evolution of the NCC.This paper mainly reports a firstly discovered 217 Ma gabbro from the Yabulai district in the western Alxa Block,where widely exposes Late Paleozoic intermediate-acid intrusive rocks and volcanic rocks(Liu Q et al.,2017).
基金supported by the National Natural Science Foundation of China(No.41702204)the China Geology Survey(grant number DD20189614)the Basic Science Founda-tion of the Institute of Geomechanics(grant DZLXJK202004).
文摘The late Palaeozoic tectonic magmatism in the north-ern Qaidam tectonic belt(NQTB)related to the Palaeo-Tethys Ocean has become a critical issue.We performed a detailed geochronological and geochemical study of Lenghu(LH)granitic rocks in the western NQTB.LA-ICP-MS U-Pb dating of zircons from LH granitic rocks yields emplacement ages of 253±4 Ma and 264±4 Ma,indicating a two-stage emplacement process.Geochemi-cal analyses show that the LH granitic rocks have low ACNK values and are enriched in LILEs(Rb,Th,Ba)and depleted in HFSEs(Sr,Nd,and Ta).The samples are enriched in LREEs(LREE/HREE=1.5-7.3).Values of(La/Yb)N range between 0.9 and 6.5,and all samples show negative Eu anomalies(δEu=0.2-0.6),with typical characteristics of island arc magmatism.The LH granitic rocks haveεHf(t)values of-3.7 to+8.0 and yield a TCDM age of 1.51-0.78 Ga.The data suggest that the LH granitic rocks were derived from partial melting of Proterozoic crust-related mafic to intermediate rocks with significant crust-mantle interac-tions.The results,combined with regional magmatic informa-tion,indicate that the Late Permian-early Triassic magmatism in western NQTB were controlled by subduction rollback-retraction of South Kunlun Oceanic plate under the Kun-lun-Qaidam Block.
文摘The Tongling area is one of the 7 ore-cluster areas in the Middle-Lower Yangtze metallogenic belt, East China, and has tectonically undergone a long-term geologic history from the late Paleozoic continental rifting, through the Middle Triassic continent-continent collision to the Jurassic-Cretaceous intracontinental tectono-magmatic activation. The Carboniferous sedimentary-exhalative processes in the area produced widespread massive sulfides with ages of 303-321 Ma, which partly formed massive pyrite-Cu deposits, but mostly provided significant sulfur and metals to the skarn Cu mineralization associated with the Yanshanian felsic intrusions.To understand the Carboniferous submarine hydrothermal system, an area of about 1046 km^2 was chosen to carry out the geological fluid mapping. Associated with massive sulfide formation, footwall sequences 948 m to 1146 m thick, composed of the Lower Silurian-Upper Devonian sandstone, siltstone and thin-layered shale, were widely altered. This hydrothermal alteration is interpreted to reflect largescale hydrothermal fluid flow associated with the late Paleozoic crustal rifting and subsidence. Three hydrothermal alteration types, i.e., deep-level semiconformable siliclfication （S1）, fracture-controlled quartz-sericite-pyrite alteration （S2-3）, and upper-level sub-discordant quartz-sericite-chlorite alteration （D3）, were developed to form distinct zones in the mapped area. About 50-m thick semiconformable silicification zones are located at -1-km depth below massive sulfides and developed between an impermeable shale caprock （S1） and the underlying Ordovician unaltered limestone. Comparisons with modern geothermal systems suggest that the alteration zones record a sub-seafioor aquifer with the most productive hydrothermal fluid flow. Fracture-controlled quartz-sericite-pyrite alteration formed transgressive zones, which downward crosscut the semiconformable alteration zones, and upwards grade into sub-discordant alteration zones that enveloped no economic stringer- stockwork zones beneath massive sulfides. This transgressive zone likely marks an upfiow path of high- flux fluids from the hydrothermal aquifer. Lateral zonation of the sub-discordant alteration zones and their relationship to overlying massive sulfide lenses suggest lateral flows and diffusive discharging of the hydrothermal fluids in a permeable sandstone sequence. Three large-sized, 14 middle-small massive sulfide deposits, and 40 massive sulfide sites have been mapped in detail. They show regional strata- bound characters and two major styles, i.e., the layered sheet plus strata-bound stringer-style and the mound-style. Associated exhalite and chemical sedimentary rock suites include （1） anhydrite-barite, （2） jasper-chert, （3） Mg-rich mudstone-pyrite shale, （4） barite lens, （5） siderite-Fe-bearing dolomite, and （6） Mn-rich shale-mudstone, which usually comprise three sulfide-exhalite cyclic units in the area.The spatial distribution of these alteration zones （minerals） and associated massive sulfdes and exhalites, and regional variation in δ^34S of hydrothermal pyrite and in δ^18O-δ^34C of hanging wall carbonates, suggest three WNW-extending domains of fluid flow, controlled by the basement faults and syn-depositional faults. Each fluid domain appears to have at least two upflow zones, with estimated even spacing of about 5-8 km in the mapped area. The repeated appearance of sulfide-sulfate or sulfide-carbonate rhythmic units in the area suggests episodically venting of fluids through the upfiow conduits by breaking the overlying seals of the hydrothermal aquifer.
基金supported by the National Department Public Benefit Research Foundation of China(grant no. 201211077)the Mineral Resources Investigation and Appraisal Project of the Ministry of Land and Resources (grant no.12120114001501)the Fundamental Research Funds for the Central Universities(grant no. 53200859557)
文摘In the East Asian monsoon region, eolian deposits widely distributed in the middle-lower reaches of the Yantgze River are among the best materials available for studies on Quaternary climate change in the subtropical zone of Southern China. Typical eolian deposits in this region include upper Xiashu Loess （XL） and underlying Vermiculated Red Soil （VRS） layers. In this paper, chronological and paleoclimatic studies are conducted on an eolian deposit sequence near Jiujiang （J J） city in northern Jiangxi province. A magnetostratigraphic study, combined with optically stimulated luminescence （OSL） dating, is conducted on the JJ section and provides further evidence that eolian deposits in the middle-lower reaches of the Yangtze River have been formed since the late Early Pleistocene, and that the boundary age between the XL and VRS layers is about 300-400 kaBP. In grain-size records of the JJ section, the median grain-size and content of the 〉30μn size fraction increase sharply after 300-400 kaBP, representing an East Asian winter monsoon intensification event. Further pollen analysis reveals differing pollen assemblages before and after 300-400 kaBP： there is an evident increase in plants adapted to grow in a warm humid environment after 300-400 kaBP, implying an increase in precipitation caused by intensification of the East Asian summer monsoon. Global ice volume and uplift of the Tibet Plateau （TP） are regarded as crucial factors influencing variations of the East Asian monsoon on a long-term scale. The deep-sea JlSO record, which reflects variations in global ice volume, shows no obvious change after 300-400 kaBP. Moreover, the influence of global ice volume changes on the East Asian summer and winter monsoons is inverse; the global ice volume increase （decrease） implies a strengthened （weakened） winter monsoon and weakened （strengthened） summer monsoon. We therefore interpret the coupled intensifications of the East Asian summer and winter monsoons at about 300-400 kaBP to the uplift of the TP in the Middle Pleistocene. This climate event is also documented in eolian deposits from the southern margin of the Chinese Loess Plateau （CLP） and from the desert-loess transitional belt. However, it is not recorded in the loess-paleosol sequences from the central part of the CLP, thereby indicating differing climate responses to TP uplift in different regions, which requires further study.
基金supported by geological survey projects of the China Geological Survey (1212011120863, 12120114039401, 12120114005901 and 12120115029401)
文摘The Tongshankou Cu-Mo deposit, located in southeast Hubei province, is a typical skarn–porphyry type ore deposit closely related to the Tongshankou granodiorite porphyry, characterized by a high Sr/Y ratio.Detailed in situ analyses of the trace elements and U–Pb and Lu–Hf isotopes in zircons from the Tongshankou granodiorite porphyry were performed.Scarcely any inherited zircons were observed, and the analyzed zircons yielded highly concordant results with a weighted mean 206Pb/238 U age of 143.5 ± 0.45 Ma（n=20, mean square weighted deviation was 0.75）, which was interpreted to represent the crystallization age of the Tongshankou granodiorite porphyry.The chondrite-normalized rare-earth element pattern was characterized by a slope that steeply rises from the light-group rare-earth elements（LREE） to the heavy-group rare-earth elements（HREE） with a positive Ce-anomaly and inconspicuous Eu-anomaly, which was coincident with the pattern of the zircons from the Chuquicamata West porphyry, Chile.The analyzed zircons also had relatively low 176Hf/177 Hf ratios of 0.282526–0.282604.Assuming t=143 Ma, the corresponding calculated initial Hf isotope compositions（εHf（t）） ranged from-5.6 to-2.9.The results of the in situ analysis of trace elements and U–Pb and Lu–Hf isotopes in zircons from the Tongshankou granodiorite porphyry suggest that a deep-seated process involving a thickened-crust/enriched-mantle interaction may play an important role in the generation of high Sr/Y-ratio magma and potentially in the generation of porphyry Cu-Mo systems.
基金supported by the National Key R&D Program Project of China(No.2016YFC0600209)。
文摘The Nanling-Xuancheng ore region of Anhui Province is located in the Middle-Lower Yangtze River metallogenic belt.Insufficient exploration and research have been carried out in this newly defined ore district,although the Chating large porphyry Cu-Au deposit and a few middle-sized skarntype Cu polymetallic deposits have been discovered.In this study,we carried out high-resolution seismic reflection,magnetotelluric,gravity,and magnetic investigations,and constructed the 3 D geological structure of the uppermost crust in a depth range of 0-5 km using a comprehensive inversion of the new data constrained by previous deep-drilling data.We hence proposed some new insights to understand the mineralization processes of this district.A system of alternating ridges and valleys is suggested as the major structure pattern,composed of“two-layer structure”of the basins and“three-layer structure”of anticlines.Moreover,a conjugated fault system and its distribution features are revealed in our models,including the Jiangnan fault,Zhouwang fault,and Kunshan thrust nappe.The Jiangnan and Kunshan faults are suggested to have controlled the diagenesis and metallogenesis.Two deep concealed plutons located in Chating and Magushan are found,forming the Mesozoic diorite-felsic intrusions.These intrusions are believed to be the causes of hydrothermal deposits such as the Chating deposit and the Magushan deposit.
基金supported financially by the National Natural Science Foundation of China(grant 41302062)the Fundamental Research Funds for the Central Universities(grant 2652015053,2011YYL125)the China Geological Survey(grant 12120113069900)
文摘The Datuanshan deposit is one of the largest and most representative stratabound copper deposits in the Tongling area,the largest ore district in the Middle-Lower Yangtze River metallogenic belt.The location of the orebodies is controlled by the interlayer-slipping faults between the Triassic and Permian strata,and all the orebodies are distributed in stratiform shape around the Mesozoic quartz monzodiorite dikes.Based on field evidence and petrographic observations,four mineralization stages in the Datuanshan deposit have been identified：the skarn,early quartz-sulfide,late quartzsulfide and carbonate stages.Chalcopytite is the main copper mineral and mainly formed at the late quartz-sulfide stage.Fluid inclusions at different stages were studied for petrography,microthermometry,laser Raman spectrometry and stable isotopes.Four types of fluid inclusions,including three-phase fluid inclusions（type 1）,liquid-rich fluid inclusions（type 2）,vapour-rich fluid inclusions（type 3） and pure vapour fluid inclusions（type 4）,were observed.The minerals from the skarn,early and late quartz-sulfide stages contain all fluid inclusion types,but only type 2 fluid inclusions were observed at the carbonate stage.Petrographic observations suggest that most of the inclusions studied in this paper are likely primary.The coexistence of different types of fluid inclusions with contrasting homogenization characteristics（to the liquid and vapour phase,respectively） and similar homogenization temperatures（the modes are 440-480℃,380-400℃ and 280-320℃ for the skarn,early and late quartz-sulfide stages,respectively） in the first three stages,strongly suggests that three episodes of fluid boiling occurred during these stages,which is supported by the hydrogen isotope data.Laser Raman spectra identified CH_4 at the skarn and early quartz-sulfide stages.Combined with other geological features,the early ore-forming fluids were inferred to be under a relatively reduced environment.The CO_2 component has been identified at the late quartz-sulfide and carbonate stages,indicating that the late ore-forming fluids were under a relatively oxidized environment,probably as a result of inflow of and mixing with meteoric water.In addition,microthermometric results of fluid inclusions and H-O isotope data mdicate that the ore forming fluids were dominated by magmatic water in the early stages（skarn and early quartz-sulfide stages） and mixed with meteoric water in the late stages（late quartz-sulfide and carbonate stages）.The evidence listed above suggests that the chalcopyrite deposition in the Datuanshan deposit probably resulted from the combination of multiepisode fluid boiling and mixing of magmatic and meteoric water.
基金supported by the National Key Research and Development Program of China(No.2018YFC1407 601)the National Natural Science Foundation of China(No.41176064)
文摘In order to examine the impacts of water-sediment regulation on regional carbon cycling,we collected water,particulate and sediment samples from the middle-lower Yellow River in late June and early July,2015 and analyzed their specific amino acids(AA),DOC,POC,and bacteria abundance.Summarized by 14 specific AA,the total hydrolysable AA(THAA),particulate AA(PAA),and sediment AA(SAA)varied in ranges of 2.29-9.05μmol L^-1,5.22-22.96μmol L^-1,and 81.7-137.19μg g^-1 dry weight.After the regulation,dissolved free AA(DFAA)decreased by 29%while DCAA increased by 72%.These variations suggested that DFAA were further degraded,while DCAA molecules were further activated.Meanwhile,PAA increased almost 4 times as many as those before regulation,and SAA increased as well.After regulation,the amounts of bioactive amino acids(Asp,Glu and Gly)increased in THAA but decreased in PAA,with little changes in SAA.The ratios of Asp/Gly in different phases increased after regulation,indicating the AA contributions were promoted by calcareous organisms rather than by siliceous organisms.Multiple correlation analysis showed that PAA was primary representatives of AA and organic carbon,followed by DCAA and POC.Moreover,bacterial reproduction played a key role in shaping the AA compositions and properties,followed by the redox condition and acid-base balance.The results of this study provided a clear evidence for the effects of water-sediment regulation on regional biogeochemistry of organic carbon in the middle-lower Yellow River.
基金funded by grants from the National Key Research and Development Program(2016YFC0600206)the National Natural Science Foundation of China(41872081)+1 种基金the Doctoral initial funding project of Anhui Jianzhu University(2019QDZ33)the Anhui Province Science and Technology Plan Project for Housing Urban-rural Construction(2020-YF35)。
文摘The Middle-Lower Yangtze River Metallogenic Belt(MLYB)is known to contain abundant copper and iron porphyry-skarn deposits,with an increasing number of tungsten deposits and scheelite in Fe-Cu deposits being discovered in the MLYB during recent decades.The ore genesis of the newly-discovered tungsten mineralization in the MLYB is poorly understood.We investigate four sets of scheelite samples from tungsten,iron and copper deposits,using CL imaging and LA-ICP-MS techniques to reveal internal zonation patterns and trace element compositions.The REE distribution patterns of four studied deposits show varying degrees of LREE enrichment with negative Eu anomalies.The oxygen fugacity of ore-forming fluid increased in Donggushan,while the oxygen fugacity of ore-forming fluid decreased in Ruanjiawan,Guilinzheng and Gaojiabang.The scheelites from the Donggushan,Ruanjiawan,Guilinzheng and Gaojiabang deposits show enrichment in LREEs and HFSE,with Nb/La ratios ranging from 1.217 to 52.455,indicating that the four tungsten deposits are enriched in the volatile fluorine.A plot of(La/Lu)N versus Mo/δEu can be used to distinguish quartz vein type,porphyry and skarn tungsten deposits.This study demonstrates that scheelite grains can be used to infer tungsten mineralization and are effective in identifying magmatic types of tungsten deposits in prospective mining sites.
基金supported by the National Science Foundation of China(grants No.41372090 and 41573042)the National Special Research Programs for Non-Profit Trades (grant No.201311136)Basic Scientific Research Operation Cost of State-Leveled Public Welfare Scientific Research Courtyard(grant No.K1203)
文摘Thallium has been used geochemical exploration of gold deposits. However, as an indicator element in searching for hydrothermal the T1 minerals and mineralization are rare in nature. Lorandite T1AsS2, a relatively uncommon mineral, has been dominantly discovered in some Carlin gold deposits, and minor Sb- Hg, U and Pb-Zn-Ag deposits.
