This study selects geochemical data of basalts from different seamounts in the Mid-Pacific Mountains province and conducts analyses of major and trace elements as well as Sr-Nd-Pb isotopes to explore the tectonic evol...This study selects geochemical data of basalts from different seamounts in the Mid-Pacific Mountains province and conducts analyses of major and trace elements as well as Sr-Nd-Pb isotopes to explore the tectonic evolution,petrogenesis,and mantle-source magama characteristics of the Mid-Pacific Mountains.The basalts from the Mid-Pacific Mountains are predominantly alkali basalts,rich in alkalies,and changing in potassium.They exhibit geochemical features of ocean island basalts(OIB),with distinct fractionation between light and heavy rare-earth elements and a pronounced Ce negative anomaly(δ_(Ce)=0.16–1.10,average 0.84),along with enrichment in large ion lithophile elements(LILEs).The Mid-Pacific Mountains are intraplate ocean island basalts formed by mantle plume(hotspot)activity,originating mainly from an enriched mantle magma source region,and most of them have undergone low degree of partial melting and a certain degree of crystalline differentiation,with negligible contamination from oceanic crust materials.The Mid-Pacific Mountains exhibit ratios of^(87)Sr/^(86)Sr(i)(0.702733–0.704313,average 0.703452)and^(143)Nd/^(144)Nd(i)(0.512698–0.512996,average 0.512846)which are close to the HIMU mantle endmember,and ratios of 206Pb/204Pb(18.953–19.803),^(207)Pb/^(204)Pb(15.54–15.62)and^(208)Pb/^(204)Pb(38.813–39.514)which are close to the EMII mantle end-member.Combined with the isotopic geochemical characteristics in the West Pacific Seamounts province,the basalts from the Mid-Pacific Mountains were considered to represent a certain proportion of mixing mantle end-members between the HIMU and EMII,possibly formed by the mixing of the HIMU superplume in the South Pacific hotspot region with the EMII secondary mantle plume in the transition zone during their ascent.展开更多
Rare earth elements（REEs） and major elements of 25 cobalt-rich crusts obtained from different depths of Mid-Pacific M seamount were analyzed using inductively coupled plasma-atomic emission spectrometer and gravimet...Rare earth elements（REEs） and major elements of 25 cobalt-rich crusts obtained from different depths of Mid-Pacific M seamount were analyzed using inductively coupled plasma-atomic emission spectrometer and gravimetric method.The results showed that they were hydrogenous crusts with average ∑REE content of 2084.69 μg/g and the light REE（LREE）/heavy REE（HREE） ratio of 4.84.The shale-normalized REE patterns showed positive Ce anomalies.The total content of strictly trivalent REEs increased with water depth.The Ce content and LREE/HREE ratios in Fe-Mn crusts above 2000 m were lower than those below 2000 m.The change in REE with water depth could be explained by two processes：adsorptive scavenging by setting matters and behaviors of REE in seawater.However, the Ce abundance took no obvious correlation with water depth reflects the constant Ce flux.The Ce in crusts existed mainly as Ce（IV）, implying that the oxidative-enriching process was controlled by kinetic factors.展开更多
In the present paper, iodine （I）, iron （Fe）, manganese （Mn）, cobalt （Co）, phosphorus （P） and calcium （Ca） contents in three ferromanganese crusts from the Pacific Ocean are measured by spectrophotometric m...In the present paper, iodine （I）, iron （Fe）, manganese （Mn）, cobalt （Co）, phosphorus （P） and calcium （Ca） contents in three ferromanganese crusts from the Pacific Ocean are measured by spectrophotometric method and inductively coupled plasma atomic emission spectrometers （ICP-AES） to investigate the contents and distribution of iodine in ferromanganese crusts. The results show that iodine contents in three crusts vary between 27.1 and 836 mg/kg, with an average of 172 mg/kg, and the profile of iodine in the three crusts all exhibits a two-stage distribution zone： a young non-phosphatized zone and an old phosphatized zone that is rich in I, P and Ca. The iodine content ratios of old to young zone in MP5D44, CXD62-1 and CXD08-1 are 2.3, 3.4 and 13.7, respectively. The boundary depths of two-stage zone in MP5D44, CXD62-1 and CXD08-1 locate at 4.0 cm, 2.5 cm and 3.75 cm, respectively, and the time of iodine mutation in three crusts ranges from 17-37 Ma derived from 129I dating and Co empirical formula, which is consistent with the times of Cenozoic phosphatization events. The present study shows that the intensity of phosphatization is the main responsible for the distribution pattern of iodine in the crusts on the basis of the correlation analysis. Consequently, iodine is a sensitive indicator for phosphatization.展开更多
Systematic analyses were conducted including the petrographic features, major and trace elements, Sr and Nd isotopic compositions, and mineral structure and compositions of whole rocks. Mid-Pacific Mountain volcanic r...Systematic analyses were conducted including the petrographic features, major and trace elements, Sr and Nd isotopic compositions, and mineral structure and compositions of whole rocks. Mid-Pacific Mountain volcanic rocks are mainly phonotephrite with a porphyritic texture. Phenocrysts are mainly composed of Ca-rich plagioclase, clinopyroxene and nepheline.These volcanic rocks are significantly rich in large-ion lithophile and light rare earth elements, without obvious Eu anomalies(δEu=0.99–1.03), and with relatively enriched^(87) Sr/^(86) Sr(0.703829–0.704313) and^(143) Nd/^(144) Nd isotopic ratios(0.512857–0.512871), suggesting that they have similar but more enriched features than the OIB magmatic source. These volcanic rocks may originate from relatively deep magma source with the existence of spinel-garnet Iherzolites, and have undergone partial melting at a low degree of 1–3%. In addition, The residual Nb-Ta minerals(such as sphene, rutile, perovskite) may remain in the mantle source, and the magma components have undergone metasomatism by carbonate melt/fluid or alkali-rich fluid, causing high contents of incompatible elements and significant loss of Nb, Ta and Ti in these volcanic rocks. There are many similarities between the phonotephrites in the Mid-Pacific Mountain and the volcanic rocks in the Line Islands based on the tectonic settings and the geochemical characteristics. We thus speculate that Site 313 volcanic rocks in the Mid-Pacific Mountain is most likely to be a continuation of the Line Islands.展开更多
Growing evidence indicates that the Asian monsoon plays an important role in affecting the weather and climate outside of Asia. However, this active role of the monsoon has not been demonstrated as thoroughly as has t...Growing evidence indicates that the Asian monsoon plays an important role in affecting the weather and climate outside of Asia. However, this active role of the monsoon has not been demonstrated as thoroughly as has the variability of the monsoon caused by various impacting factors such as sea surface temperature and land surface. This study investigates the relationship between the Asian monsoon and the climate anomalies in the Asian-Pacific-American （APA） sector. A hypothesis is tested that the variability of the upper-tropospheric South Asian high （SAH）, which is closely associated with the overall heating of the large-scale Asian monsoon, is linked to changes in the subtropical western Pacific high （SWPH）, the midPacific trough, and the Mexican high. The changes in these circulation systems cause variability in surface temperature and precipitation in the APA region. A stronger SAH is accompanied by a stronger and more extensive SWPH. The enlargement of the SWPH weakens the mid-Pacific trough. As a result, the southern portion of the Mexican high becomes stronger. These changes are associated with changes in atmospheric teleconnections, precipitation, and surface temperature throughout the APA region. When the SAH is stronger, precipitation increases in southern Asia, decreases over the Pacific Ocean, and increases over the Central America. Precipitation also increases over Australia and central Africa and decreases in the Mediterranean region. While the signals in surface temperature are weak over the tropical land portion, they are apparent in the mid latitudes and over the eastern Pacific Ocean.展开更多
The Shatsky and Hess Rises,the Mid-Pacific Mountains and the Line Islands large igneous provinces(LIPs) present different challenges to conventional plume models.Resolving the genesis of these LIPs is important not on...The Shatsky and Hess Rises,the Mid-Pacific Mountains and the Line Islands large igneous provinces(LIPs) present different challenges to conventional plume models.Resolving the genesis of these LIPs is important not only for a more complete understanding of mantle plumes and plume-generated magmatism,but also for establishing the role of subducted LIP conjugates in the evolution of the Laramide orogeny and other circum-Pacific orogenic events,which are related to the development of large porphyry systems.Given past difficulties in developing consistent geodynamic models for these LIPs,it is useful to consider whether viable alternative geodynamic scenarios may be provided by recent concepts such as melt channel networks and channel-associated lineaments,along with the "two mode"model of melt generation,where a deeply-sourced channel network is superimposed on the plume,evolving and adapting over millions of years.A plume may also interact with transform faults in close proximity to a mid ocean ridge,with the resultant bathymetric character strongly affected by the relative age difference of lithosphere across the fault.Our results suggest that the new two-mode melt models resolve key persistent issues associated with the Shatsky Rise and other LIPs and provide evidence for the existence of a conduit system within plumes that feed deeply-sourced material to the plume head,with flow maintained over considerable distances.The conduit system eventually breaks down during plume-ridge separation and may do so prior to the plume head being freed from the triple junction or spreading ridge.There is evidence for not only plume head capture by a triple junction but also for substantial deformation of the plume stem as the distance between the stem and anchored plume head increases.The evidence suggests that young transforms can serve as pathways for plume material migration,at least in certain plume head-transform configurations.A fortuitous similarity between the path of the Shatsky and Sio plumes,with respect to young spreading ridges and transforms,helps to clarify previously problematic bathymetric features that were not readily ascribed to fixed plumes alone.The Line Island Chain,which has been the subject of a vast number of models,is related mainly to several plumes that passed beneath the same region of oceanic crust,a relatively rare event that has resulted in LIP formation rather than a regular seamount track.Our findings have important implications for the timing and mechanism for the Laramide Orogeny in North America,demonstrating that the Hess Rise conjugate may be much smaller than traditionally thought.The Mid Pacific Mountains conjugate may not exist at all,given large parts of these LIPs were formed at an ‘off-ridge’ site.This needs to be taken into account while considering the effects of conjugate collision on mineralization and orogenic events.展开更多
基金Supported by the National Natural Science Foundation of China(No.U2244222).
文摘This study selects geochemical data of basalts from different seamounts in the Mid-Pacific Mountains province and conducts analyses of major and trace elements as well as Sr-Nd-Pb isotopes to explore the tectonic evolution,petrogenesis,and mantle-source magama characteristics of the Mid-Pacific Mountains.The basalts from the Mid-Pacific Mountains are predominantly alkali basalts,rich in alkalies,and changing in potassium.They exhibit geochemical features of ocean island basalts(OIB),with distinct fractionation between light and heavy rare-earth elements and a pronounced Ce negative anomaly(δ_(Ce)=0.16–1.10,average 0.84),along with enrichment in large ion lithophile elements(LILEs).The Mid-Pacific Mountains are intraplate ocean island basalts formed by mantle plume(hotspot)activity,originating mainly from an enriched mantle magma source region,and most of them have undergone low degree of partial melting and a certain degree of crystalline differentiation,with negligible contamination from oceanic crust materials.The Mid-Pacific Mountains exhibit ratios of^(87)Sr/^(86)Sr(i)(0.702733–0.704313,average 0.703452)and^(143)Nd/^(144)Nd(i)(0.512698–0.512996,average 0.512846)which are close to the HIMU mantle endmember,and ratios of 206Pb/204Pb(18.953–19.803),^(207)Pb/^(204)Pb(15.54–15.62)and^(208)Pb/^(204)Pb(38.813–39.514)which are close to the EMII mantle end-member.Combined with the isotopic geochemical characteristics in the West Pacific Seamounts province,the basalts from the Mid-Pacific Mountains were considered to represent a certain proportion of mixing mantle end-members between the HIMU and EMII,possibly formed by the mixing of the HIMU superplume in the South Pacific hotspot region with the EMII secondary mantle plume in the transition zone during their ascent.
基金supported by the National Natural Science Foundation of China(40704029 40376016)+1 种基金China International Science and Technology Cooperation Project (2006DFB21620)the Young People Marine Science Foundation of State Oceanic Administration (2005304)
文摘Rare earth elements（REEs） and major elements of 25 cobalt-rich crusts obtained from different depths of Mid-Pacific M seamount were analyzed using inductively coupled plasma-atomic emission spectrometer and gravimetric method.The results showed that they were hydrogenous crusts with average ∑REE content of 2084.69 μg/g and the light REE（LREE）/heavy REE（HREE） ratio of 4.84.The shale-normalized REE patterns showed positive Ce anomalies.The total content of strictly trivalent REEs increased with water depth.The Ce content and LREE/HREE ratios in Fe-Mn crusts above 2000 m were lower than those below 2000 m.The change in REE with water depth could be explained by two processes：adsorptive scavenging by setting matters and behaviors of REE in seawater.However, the Ce abundance took no obvious correlation with water depth reflects the constant Ce flux.The Ce in crusts existed mainly as Ce（IV）, implying that the oxidative-enriching process was controlled by kinetic factors.
文摘In the present paper, iodine （I）, iron （Fe）, manganese （Mn）, cobalt （Co）, phosphorus （P） and calcium （Ca） contents in three ferromanganese crusts from the Pacific Ocean are measured by spectrophotometric method and inductively coupled plasma atomic emission spectrometers （ICP-AES） to investigate the contents and distribution of iodine in ferromanganese crusts. The results show that iodine contents in three crusts vary between 27.1 and 836 mg/kg, with an average of 172 mg/kg, and the profile of iodine in the three crusts all exhibits a two-stage distribution zone： a young non-phosphatized zone and an old phosphatized zone that is rich in I, P and Ca. The iodine content ratios of old to young zone in MP5D44, CXD62-1 and CXD08-1 are 2.3, 3.4 and 13.7, respectively. The boundary depths of two-stage zone in MP5D44, CXD62-1 and CXD08-1 locate at 4.0 cm, 2.5 cm and 3.75 cm, respectively, and the time of iodine mutation in three crusts ranges from 17-37 Ma derived from 129I dating and Co empirical formula, which is consistent with the times of Cenozoic phosphatization events. The present study shows that the intensity of phosphatization is the main responsible for the distribution pattern of iodine in the crusts on the basis of the correlation analysis. Consequently, iodine is a sensitive indicator for phosphatization.
基金supported by National Natural Science Foundation of China(Grant Nos.41476034,41272369,40802038,41320104006&41302102)
文摘Systematic analyses were conducted including the petrographic features, major and trace elements, Sr and Nd isotopic compositions, and mineral structure and compositions of whole rocks. Mid-Pacific Mountain volcanic rocks are mainly phonotephrite with a porphyritic texture. Phenocrysts are mainly composed of Ca-rich plagioclase, clinopyroxene and nepheline.These volcanic rocks are significantly rich in large-ion lithophile and light rare earth elements, without obvious Eu anomalies(δEu=0.99–1.03), and with relatively enriched^(87) Sr/^(86) Sr(0.703829–0.704313) and^(143) Nd/^(144) Nd isotopic ratios(0.512857–0.512871), suggesting that they have similar but more enriched features than the OIB magmatic source. These volcanic rocks may originate from relatively deep magma source with the existence of spinel-garnet Iherzolites, and have undergone partial melting at a low degree of 1–3%. In addition, The residual Nb-Ta minerals(such as sphene, rutile, perovskite) may remain in the mantle source, and the magma components have undergone metasomatism by carbonate melt/fluid or alkali-rich fluid, causing high contents of incompatible elements and significant loss of Nb, Ta and Ti in these volcanic rocks. There are many similarities between the phonotephrites in the Mid-Pacific Mountain and the volcanic rocks in the Line Islands based on the tectonic settings and the geochemical characteristics. We thus speculate that Site 313 volcanic rocks in the Mid-Pacific Mountain is most likely to be a continuation of the Line Islands.
文摘Growing evidence indicates that the Asian monsoon plays an important role in affecting the weather and climate outside of Asia. However, this active role of the monsoon has not been demonstrated as thoroughly as has the variability of the monsoon caused by various impacting factors such as sea surface temperature and land surface. This study investigates the relationship between the Asian monsoon and the climate anomalies in the Asian-Pacific-American （APA） sector. A hypothesis is tested that the variability of the upper-tropospheric South Asian high （SAH）, which is closely associated with the overall heating of the large-scale Asian monsoon, is linked to changes in the subtropical western Pacific high （SWPH）, the midPacific trough, and the Mexican high. The changes in these circulation systems cause variability in surface temperature and precipitation in the APA region. A stronger SAH is accompanied by a stronger and more extensive SWPH. The enlargement of the SWPH weakens the mid-Pacific trough. As a result, the southern portion of the Mexican high becomes stronger. These changes are associated with changes in atmospheric teleconnections, precipitation, and surface temperature throughout the APA region. When the SAH is stronger, precipitation increases in southern Asia, decreases over the Pacific Ocean, and increases over the Central America. Precipitation also increases over Australia and central Africa and decreases in the Mediterranean region. While the signals in surface temperature are weak over the tropical land portion, they are apparent in the mid latitudes and over the eastern Pacific Ocean.
基金The comments of two reviewers helped us to clarify and improve the final paper.John Cannon,Maria Seton and Simon Williams are thanked for assistance with GPlates during the studySabin Zahirovic was supported by the Australian Research Council(Grant IH130200012)Alfred P Sloan(Grants G-2017-9997 and G-2018-11296)through the Deep Carbon Observatory.
文摘The Shatsky and Hess Rises,the Mid-Pacific Mountains and the Line Islands large igneous provinces(LIPs) present different challenges to conventional plume models.Resolving the genesis of these LIPs is important not only for a more complete understanding of mantle plumes and plume-generated magmatism,but also for establishing the role of subducted LIP conjugates in the evolution of the Laramide orogeny and other circum-Pacific orogenic events,which are related to the development of large porphyry systems.Given past difficulties in developing consistent geodynamic models for these LIPs,it is useful to consider whether viable alternative geodynamic scenarios may be provided by recent concepts such as melt channel networks and channel-associated lineaments,along with the "two mode"model of melt generation,where a deeply-sourced channel network is superimposed on the plume,evolving and adapting over millions of years.A plume may also interact with transform faults in close proximity to a mid ocean ridge,with the resultant bathymetric character strongly affected by the relative age difference of lithosphere across the fault.Our results suggest that the new two-mode melt models resolve key persistent issues associated with the Shatsky Rise and other LIPs and provide evidence for the existence of a conduit system within plumes that feed deeply-sourced material to the plume head,with flow maintained over considerable distances.The conduit system eventually breaks down during plume-ridge separation and may do so prior to the plume head being freed from the triple junction or spreading ridge.There is evidence for not only plume head capture by a triple junction but also for substantial deformation of the plume stem as the distance between the stem and anchored plume head increases.The evidence suggests that young transforms can serve as pathways for plume material migration,at least in certain plume head-transform configurations.A fortuitous similarity between the path of the Shatsky and Sio plumes,with respect to young spreading ridges and transforms,helps to clarify previously problematic bathymetric features that were not readily ascribed to fixed plumes alone.The Line Island Chain,which has been the subject of a vast number of models,is related mainly to several plumes that passed beneath the same region of oceanic crust,a relatively rare event that has resulted in LIP formation rather than a regular seamount track.Our findings have important implications for the timing and mechanism for the Laramide Orogeny in North America,demonstrating that the Hess Rise conjugate may be much smaller than traditionally thought.The Mid Pacific Mountains conjugate may not exist at all,given large parts of these LIPs were formed at an ‘off-ridge’ site.This needs to be taken into account while considering the effects of conjugate collision on mineralization and orogenic events.
