Developing an efficient approach of transforming biomass waste to functional carbon-based electrode materials applied in supercapacitor offers an important and high value-added practical application due to the abundan...Developing an efficient approach of transforming biomass waste to functional carbon-based electrode materials applied in supercapacitor offers an important and high value-added practical application due to the abundance and considerable low price of biomass wastes.Herein,a hierarchical carbon functionalized with electrochemical-active oxygen-containing groups was fabricated by microwave treatment from the biomass waste of camellia oleifera.The obtained mesoporous carbon(MAC)owns nanosheet morphology,rich mesoporosity,large surface area(1726 m2/g)and very high oxygenic functionalities(16.2 wt%)with pseudocapacitive activity.Prepared electrode of supercapacitor and tested in 2.0 M H2 SO4,the MAC exhibits an obvious pseudocapacitive activity and achieved a superior supercapacitive performance to that of directly activated carbon(DAC-800)including high specific capacitance(367 F/g vs.298 F/g)and better rate performance(66%vs.44%).The symmetrical supercapacitor based on MAC shows a high capacity of275 F/g,large energy density of 9.55 Wh/kg(at power density of 478 W/kg)and excellent cycling stability with 99%capacitance retention after 10000 continuous charge-discharge,endowing the obtained MAC a promising functional material for electrochemical energy storage.展开更多
Based on Smith-Beljers theory and classical laminate theory, an explicit model is proposed for the ferromagnetic resonance （FMR） frequency shift of a stress-mediumed laminated magnetoelectric structure tuned by an e...Based on Smith-Beljers theory and classical laminate theory, an explicit model is proposed for the ferromagnetic resonance （FMR） frequency shift of a stress-mediumed laminated magnetoelectric structure tuned by an electric field. This model can effectively predict the experimental phenomenon that the FMR frequency increases under a parallel magnetic field and decreases under a perpendicular magnetic field when the electric field ranges from - 10 kV/m to 10 kV/m. Besides, this theory further shows that the FMR frequency increases monotonically as the angle between the direction of the external magnetic field and the outside normal direction of the laminated structure increases, and the frequency will increase as great as 7 GHz. In addition, when the angle reaches a certain critical value, the external electric field fails to tune the FMR frequency. When the angle is above the critical value, the increase of the electric field induces the FMR frequency to increase, and the opposite scenario happens when it is below the critical value. When the angle is 90~ （parallel magnetic field）, the FMR frequency is the most sensitive to the change of the electric field.展开更多
基金financially supported by the National Key Technology R&D Program of China(2017YFB0310704)the National Natural Science Foundation of China(21773112 and 21173119)the Fundamental Research Funds for the Central Universities
文摘Developing an efficient approach of transforming biomass waste to functional carbon-based electrode materials applied in supercapacitor offers an important and high value-added practical application due to the abundance and considerable low price of biomass wastes.Herein,a hierarchical carbon functionalized with electrochemical-active oxygen-containing groups was fabricated by microwave treatment from the biomass waste of camellia oleifera.The obtained mesoporous carbon(MAC)owns nanosheet morphology,rich mesoporosity,large surface area(1726 m2/g)and very high oxygenic functionalities(16.2 wt%)with pseudocapacitive activity.Prepared electrode of supercapacitor and tested in 2.0 M H2 SO4,the MAC exhibits an obvious pseudocapacitive activity and achieved a superior supercapacitive performance to that of directly activated carbon(DAC-800)including high specific capacitance(367 F/g vs.298 F/g)and better rate performance(66%vs.44%).The symmetrical supercapacitor based on MAC shows a high capacity of275 F/g,large energy density of 9.55 Wh/kg(at power density of 478 W/kg)and excellent cycling stability with 99%capacitance retention after 10000 continuous charge-discharge,endowing the obtained MAC a promising functional material for electrochemical energy storage.
基金Project supported by the National Natural Science Foundation of China(Grant Nos.10802082 and 11172285)the Natural Science Foundation of Zhejiang Province of China(Grant No.LR13A020002)the China Postdoctoral Science Foundation(Grant Nos.20100480089 and 201104727)
文摘Based on Smith-Beljers theory and classical laminate theory, an explicit model is proposed for the ferromagnetic resonance （FMR） frequency shift of a stress-mediumed laminated magnetoelectric structure tuned by an electric field. This model can effectively predict the experimental phenomenon that the FMR frequency increases under a parallel magnetic field and decreases under a perpendicular magnetic field when the electric field ranges from - 10 kV/m to 10 kV/m. Besides, this theory further shows that the FMR frequency increases monotonically as the angle between the direction of the external magnetic field and the outside normal direction of the laminated structure increases, and the frequency will increase as great as 7 GHz. In addition, when the angle reaches a certain critical value, the external electric field fails to tune the FMR frequency. When the angle is above the critical value, the increase of the electric field induces the FMR frequency to increase, and the opposite scenario happens when it is below the critical value. When the angle is 90~ （parallel magnetic field）, the FMR frequency is the most sensitive to the change of the electric field.
