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Comparative study on the electrochemical performance ofβ-manganese dioxide-3D graphene mixtures with(without)carbon nanotubes
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作者 Jiankai Liu Xiaoping Dong +3 位作者 Duolong Jin Qianran Pang Liying Yang Cuibiao Wang 《Materials Reports(Energy)》 2025年第2期103-111,I0003,共10页
Manganese dioxide is widely used as a cathode material in aqueous zinc-ion batteries,and the cathode material is a key factor limiting the performance of these batteries.In this study,β-manganese dioxide was used as ... Manganese dioxide is widely used as a cathode material in aqueous zinc-ion batteries,and the cathode material is a key factor limiting the performance of these batteries.In this study,β-manganese dioxide was used as the base material to synthesize two hybrid materials,i.e.manganese dioxide-3D graphene carbon nanotube hybrids(MnO_(2)@3D-GPE/CNT)and manganese dioxide-3D-graphene hybrids(MnO_(2)@3D-GPE),via intermittent highenergy vibration ball milling.Electrochemical tests revealed that the CNT-containing hybrid materials exhibited a higher specific capacity of 480 mAh g^(-1)and superior cycling stability,maintaining over 80%of its initial capacity after 1000 cycles at 500 mA g^(-1)with a Coulombic efficiency close to 100%.MnO_(2)@3D-GPE/CNT had a smaller particle size distribution and a larger specific surface area than MnO_(2)@3D-GPE,explaining its enhanced electrochemical performance.Additionally,MnO_(2)@3D-GPE/CNT exhibited lower electrode impedance,further supporting its efficacy as a cathode material. 展开更多
关键词 Aqueous zinc-ion batteries Carbon nanotubes Graphene hybrids microscopic morphology Electrochemical performance
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Macro-and micro-mechanical response and damage mechanism of sandstone under high-temperature conditions
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作者 Laiwei Wu Yanli Huang +5 位作者 Junmeng Li Guiyuan Wang Yingshun Li Xiaotong Li Junzhi Chen Chuning Ji 《International Journal of Mining Science and Technology》 2025年第2期265-274,共10页
The thermal effects of coal combustion considerably influence the physical and chemical properties,structural characteristics, and stability of rocks, posing a serious threat to the safety of coal mining operations. I... The thermal effects of coal combustion considerably influence the physical and chemical properties,structural characteristics, and stability of rocks, posing a serious threat to the safety of coal mining operations. In this study, the impacts of temperature on the physical and chemical characteristics(i.e., mineral phase, microstructure, and mechanical strength) of sandstone were investigated by employing experimental methods, including microstructural analysis, uniaxial acoustic emission(AE), and nuclear magnetic resonance(NMR). The results indicate that temperature alters the mineral phase and the pore characteristics, and these two factors jointly affect the mechanical properties of sandstone. The influence of temperature on the mechanical strength of sandstone is categorized into low-temperature strengthening and high-temperature damage, with a threshold temperature identified at 600 ℃. The lowtemperature strengthening effect encompasses both pore strengthening and mineral phase strengthening, while the high-temperature damage effect primarily results from pore damage. As the experimental temperature rises, both the number of AE events and the AE energy transition from a surge in the postpeak failure stage to a stepwise increase during the loading process. This transition implies that the failure mode of the sandstone sample evolves from brittle failure to tensile failure. 展开更多
关键词 Thermal effects Mineral phase Pore structure Acoustic emission energy microscopic morphology
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Morphology of Barium Hydrogen Phosphate Formation Induced by Phosphate-Mineralization Microbe
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作者 於孝牛 钱春香 WANG Xin 《Journal of Wuhan University of Technology(Materials Science)》 SCIE EI CAS 2016年第1期227-230,共4页
Phosphate-mineralization microbe was chosen to study the influences of bacterial mixture,filtrate,bacteria solution,bacterial body and bacterial secretion on barium hydrogen phosphate crystal formation.The chemical co... Phosphate-mineralization microbe was chosen to study the influences of bacterial mixture,filtrate,bacteria solution,bacterial body and bacterial secretion on barium hydrogen phosphate crystal formation.The chemical compositions and structures of samples were characterized with scanning electron microscopy(SEM),transmission electron microscopy(TEM),and X-ray diffraction techniques(XRD),revealing that the crystal morphology of barium hydrogen phosphate was dumbbell-shaped pattern,nanoparticles via aggregate clusters,irregular sphere with different sizes.The results indicated that bacterial body and bacterial secretion could induce the formation of irregular quadrilateral and spheres,respectively.But the effect of bacterial secretion was stronger than that of bacterial body when induced barium hydrogen phosphate crystal in bacteria solution.However,the crystals form could be affected only in bacterial mixture,but filtrate could induce the formation of nanoparticles.As a result,the bacteria and metabolites play an important role in the process of crystal nucleation,growth,and accumulation of barium hydrogen phosphate. 展开更多
关键词 phosphate-mineralization microbe barium hydrogen phosphate structure morphology scanning electron microscope
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Experimental study of Al agglomeration on solid propellant burning surface and condensed combustion products 被引量:3
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作者 Cheng-yin Tu Xiong Chen +2 位作者 Ying-kun Li Bei-chen Zhang Chang-sheng Zhou 《Defence Technology(防务技术)》 SCIE EI CAS CSCD 2023年第8期111-122,共12页
Aluminum(Al) particles are commonly added to energetic materials including propellants,explosives and pyrotechnics to increase the overall energy density of the composite,but aluminum agglomeration on the combustion s... Aluminum(Al) particles are commonly added to energetic materials including propellants,explosives and pyrotechnics to increase the overall energy density of the composite,but aluminum agglomeration on the combustion surface may lower the combustion efficiency of propellants,resulting in a loss in twophase flow.Therefore,it is necessary to understand the agglomeration mechanism of aluminum particles on the combustion surface.In this paper,a high-pressure sealed combustion chamber is constructed,and high-speed camera is used to capture the whole process of aluminum accumulation,aggregation and agglomeration on the combustion surface,and the secondary agglomeration process near the combustion surface.The microscopic morphology and chemical composition of the condensed combustion products(CCPs) are then studied by using scanning electron microscopy coupled with energy dispersive(SEM-EDS) method.Results show that there are three main types of condensed combustion products:small smoke oxide particles oxidized by aluminum vapor,usually less than 1 μm;typical agglomerates formed by the combustion of aluminum agglomerates;carbonized agglomerates that are widely distributed,usually formed by irregular movements of aluminum agglomerates.The particle size of condensed combustion products is measured by laser particle size meter.As the pressure increases from 0.5 MPa to 1.0 MPa in nitrogen,the mass average particle size of aluminum agglomerates decreases by 49.7%.As the ambient gas is changed from 0.5 MPa nitrogen to 0.5 MPa air,the mass average particle size of aluminum agglomerates decreases by 67.3%.Results show that as the ambient pressure increases,the higher oxygen content can improve combustion efficiency and reduce the average agglomeration size of aluminum particles. 展开更多
关键词 Solid propellant Al particles Condensed combustion products AGGLOMERATION microscopic morphology
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Petrophysical Texture Heterogeneity of Vesicles in Andesite Reservoir on Micro-Scales 被引量:1
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作者 Mutian Qin Shuyun Xie +4 位作者 Jianbo Zhang Tianfu Zhang Emmanuel John M.Carranza Hongjun Li Jiayi Ma 《Journal of Earth Science》 SCIE CAS CSCD 2021年第4期799-808,共10页
It is of great significance to study the spatial distribution patterns and petrophysical complexity of volcanic vesicles which determine whether the reservoir spaces of the volcanic rocks can accumulate oil and gas an... It is of great significance to study the spatial distribution patterns and petrophysical complexity of volcanic vesicles which determine whether the reservoir spaces of the volcanic rocks can accumulate oil and gas and enrich high yields or not.In this paper,the digital images of three different textures of vesicular andesite samples,including spherical vesicular andesite,shear deformation vesicular andesite,and secondary filling vesicular andesite,are obtained by microscopic morphology X-CT imaging technology.The spatial micro-vesicle heterogeneity of vesicular andesite samples with different textures is quantitatively analyzed by fractal and multifractal methods such as box-counting dimension and the moment method.It is found that the shear stress weakens the spatial homogeneity since vesicles rupture are accelerated,elongated directionally,and connected with one another under the strain;the secondary filling breaks the vesicles,which significantly enhances the spatial heterogeneity.In addition,shear stress and secondary filling increase the complexity of vesicle microstructures characterized by different fractal and multifractal parameters.These conclusions will provide important theoretical and practical insights into understanding the degassing of volcanic rocks and prediction of high-quality volcanic reservoirs. 展开更多
关键词 volcanic vesicles fractal and multifractal microscopic morphology HETEROGENEITY X-CT imaging
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Refining performance of Al–3Ti–0.2C–5Sr on A356 alloy and electron microanalysis of ternary Al–Ti–Sr phases 被引量:1
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作者 Hong-Liang Zhao Chuan-Bin Zhang +1 位作者 Ya Gao Qi-Yan Sun 《Rare Metals》 SCIE EI CAS CSCD 2017年第3期188-192,共5页
The effect of Al-3Ti-0.2C-5Sr (wt%) grain refiner on the refining performance and modification of A356 alloy was investigated using optical microscope (OM).The morphology and crystal structure of ternary Al-Ti-Sr ... The effect of Al-3Ti-0.2C-5Sr (wt%) grain refiner on the refining performance and modification of A356 alloy was investigated using optical microscope (OM).The morphology and crystal structure of ternary Al-Ti-Sr phases in Al-3Ti-0.2C-5Sr refiner were analyzed by scanning electron microscopy (SEM) and transmission electron microscopy (TEM).The results show that the ternary Al-Ti-Sr phases in Al-3Ti-0.2C-5Sr refiner can promote the grain refining efficiency of A356 alloy.The ternary Al-Ti-Sr phases co-exist in two morphologies,i.e.,blocky-like phase and surround-like phase,besides,which both have the same chemical composition of Al34Ti3Sr.The crystal structure of Al34TiaSr is face-centered cubic,and the lattice parameter is determined to be about 1.52 nm. 展开更多
关键词 Grain refiner Aluminum alloy AI-Ti-Srphase microscopic morphology Crystal structure
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Structural optimization and performance trade-off strategies for semi-crystalline sulfonated poly(arylene ether ketone) membranes in high-concentration direct methanol fuel cells
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作者 Di Liu Yunji Xie +3 位作者 Zhe Zhao Jinbao Li Jinhui Pang Zhenhua Jiang 《Journal of Energy Chemistry》 SCIE EI CAS CSCD 2023年第10期67-75,I0004,共10页
Direct methanol fuel cells(DMFCs) have attracted extensive attention as promising next-generation energy conversion devices. However, commercialized proton exchange membranes(PEMs) hardly fulfill the demand of methano... Direct methanol fuel cells(DMFCs) have attracted extensive attention as promising next-generation energy conversion devices. However, commercialized proton exchange membranes(PEMs) hardly fulfill the demand of methanol tolerance for DMFCs employing high-concentration methanol solutions.Herein, we report a series of semi-crystalline poly(arylene ether ketone) PEMs with ultra-densely sulfonic-acid-functionalized pendants linked by flexible alkyl chains, namely, SL-SPEK-x(where x represents the molar ratio of the novel monomer containing multiple phenyl side chain to the bisfluoride monomers). The delicate structural design rendered SL-SPEK-x membranes with high crystallinity and well-defined nanoscale phase separation between hydrophilic and hydrophobic phases. The reinforcement from poly(ether ketone) crystals enabled membranes with inhibited dimensional variation and methanol penetration. Furthermore, microphase separation significantly enhanced proton conductivity. The SL-SPEK-12.5 membrane achieved the optimum trade-off between proton conductivity(0.182 S cm^(-1), 80 ℃), water swelling(13.6%, 80 ℃), and methanol permeability(1.6 × 10^(-7)cm~2 s^(-1)). The DMFC assembled by the SL-SPEK-12.5 membrane operated smoothly with a 10 M methanol solution, outputting a maximum power density of 158.3 mW cm^(-2), nearly twice that of Nafion 117(94.2 mW cm^(-2)). Overall, the novel structural optimization strategy provides the possibility of PEMs surviving in high-concentration methanol solutions, thus facilitating the miniaturization and portability of DMFC devices. 展开更多
关键词 Semi-crystalline Ultra-densely sulfonated Flexible alkyl spacer microscopic morphology High-concentration direct methanol fuel cell
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Information integration research on cumulative effect of 'Siqi,Wuwei,and Guijing' in Traditional Chinese Medicine 被引量:3
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作者 Yang Xuming Qi Mingyuan +3 位作者 Li Qian Chen Li Yu Zhongyi Yang Lin 《Journal of Traditional Chinese Medicine》 SCIE CAS CSCD 2016年第4期538-546,共9页
OBJECTIVE:To study the morphological basis of the role of Siqi(cold as winter,cool as autumn,warm as spring,hot as summer),Wuwei(five flavors:sweet,pungent,salty,sour,and bitter),and Guijing(meridian tropism) through ... OBJECTIVE:To study the morphological basis of the role of Siqi(cold as winter,cool as autumn,warm as spring,hot as summer),Wuwei(five flavors:sweet,pungent,salty,sour,and bitter),and Guijing(meridian tropism) through the use of information integration.METHODS:A14C-2-deoxy-glucose autoradiography method was adopted to determine the overall impact of treatment with 39 herbs on functions of various tissues and organs.Data was measured at 4hs after a single dose and following the last treatment of repeated doses for a week.Least-squares estimation was used and fitted for each herb regression effect of organs and tissues after singleand repeated treatment.The slope of the regression line represented the cumulative trend of the effect of the herbs(β),and the standard deviation of the slope(Sβ) was compared with those of the untreated animals(t 'test).All significantly cumulative effect trends were applied with an artificial neural network,which integrated the relationship among Siqi,Wuwei,and Guijing with tissues and organs.RESULTS:There is a certain relationship among the Siqi,Wuwei,Guijing and the anatomy of organs and tissues,but the different scores indicate that influence of Siqi,Wuwei,Guijing to anatomy of organs and tissues was a nonlinear state.CONCLUSION:Results demonstrated that the effects of Siqi,Wuwei,and Guijing have a morphological basis,and each concept was associated with multiple anatomical structures. 展开更多
关键词 Four natures Five flavors Channel tropism Morphological and microscopic findings Least-squares estimation BP algorithm of artificial neural networks
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Exploration on using solid waste-derived sulphoaluminate composite as low-cost binder for high-impermeability stabilization of sandy soil
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作者 Shuang Zhang Jingwei Li +4 位作者 Wenbin Shi Fawei Lin Bigaliev Aitkhazha Bigalievich Eminov Ashraf Mamurovich Wenlong Wang 《Waste Disposal and Sustainable Energy》 2025年第3期481-493,共13页
Large-scale utilization of solid waste is the key challenge in building sustainable infrastructure.Given the high demand for sandy soil stabilizers in subgrades,dams and other infrastructure projects and the high perm... Large-scale utilization of solid waste is the key challenge in building sustainable infrastructure.Given the high demand for sandy soil stabilizers in subgrades,dams and other infrastructure projects and the high permeability of sandy soil,a sulphoaluminate composite cementitious material(SCCM)was developed by incorporating solid waste-derived sulphoaluminate cementitious material(SAC),desulfurized gypsum,ground granulated blast furnace slag(GGBS),and supplementary industrial byproducts,which can be used as high-permeability stabilizers for sandy soil.The economic and environmental assessment revealed that the carbon emission factor of the SCCM throughout their whole life cycle was 135.8 kg/t.The results revealed that the unconfined compressive strength(UCS)of stabilized sandy soil for 28 d was the highest among all the stabilized sandy soils,and the 28 d immersion stability rate was 72.5%.The 28 d permeability coefficient of sandy soil stabilized by SCCM decreased from 8.7×10^(−4)cm/s for natural sandy soil to 5.7×10^(−7)cm/s,which was 1–2 orders of magnitude lower than that of SAC and ordinary Portland cement(OPC)stabilized sandy soil.Both scanning electron microscopy(SEM)and X-ray diffraction(XRD)showed the co-existence of ettringite and hydrated calcium silicate gel,and their addition improved the properties of the stabilized sandy soil.The results of the low-field nuclear magnetic resonance(LF-NMR)test revealed that the porosity of the SCCM stabilized sandy soil was lower than that of the SAC stabilized sandy soil and OPC,resulting in a dense structure.This study provides an innovative solution for the utilization of bulk solid waste in stabilizing sandy soil in infrastructure projects. 展开更多
关键词 Solid waste utilization Unconfined compressive strength(UCS)Ettringite microscopic morphology Low-field nuclear magnetic resonance(LF-NMR)
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