Recent work has validated a new method for estimating the grain size of microgranular materials in the range of tens to hundreds of micrometers using laser-induced breakdown spectroscopy(LIBS).In this situation,a piec...Recent work has validated a new method for estimating the grain size of microgranular materials in the range of tens to hundreds of micrometers using laser-induced breakdown spectroscopy(LIBS).In this situation,a piecewise univariate model must be constructed to estimate grain size due to the complex dependence of the plasma formation environment on grain size.In the present work,we tentatively construct a unified calibration model suitable for LIBS-based estimation of those grain sizes.Specifically,two unified multivariate calibration models are constructed based on back-propagation neural network(BPNN)algorithms using feature selection strategies with and without considering prior information.By detailed analysis of the performances of the two multivariate models,it was found that a unified calibration model can be successfully constructed based on BPNN algorithms for estimating the grain size in the range of tens to hundreds of micrometers.It was also found that the model constructed with a priorguided feature selection strategy had better prediction performance.This study has practical significance in developing the technology for material analysis using LIBS,especially when the LIBS signal exhibits a complex dependence on the material parameter to be estimated.展开更多
Many igneous rocks distribute in Gejiu tin polymetallic ore-field at Yunnan province, rocks including basalt, gabbro, mafic microgranular enclaves, granites （porphyritic granite and equigranular granite） and akaline...Many igneous rocks distribute in Gejiu tin polymetallic ore-field at Yunnan province, rocks including basalt, gabbro, mafic microgranular enclaves, granites （porphyritic granite and equigranular granite） and akaline rocks. The ages of the granites and akaline rocks which are considered to have genetic connecting with the mineralization have been comfirmed, but the gabbro- mafic microgranular enclaves-granite assemblage＇s ages are still unknown. By means of LA-ICP-MS zircon U-Pb dating, the data of Shenxianshui equigranular granite, the mafic microgranular enclave in Jiasha area, the host rock of the mafic microgranular enclaves and the Jiasha gabbro are around ~80 Ma. Besides the above mentioned data, a group of new ages at ~30 Ma were discovered in this study, which is from gabbro and mafic microgranular enclaves. Based on the previous data and the new data gained this time, we suggest the major geochronology framework of the magmatism and mineralization events in Gejiu area is ~80 Ma, which is consistent with the Late Cretaceous magmatism and mineralization events in the whole southeast Yunnan and west Guangxi area and they were suggested to belong to the same geotectonic setting in late Yenshannian. And the new ages of the ~30 Ma obtained in this study is considered to represent a responding to the complicate tectonic evolution history of the Tibetan orogenic events in Cenozoic.展开更多
Plagioclase phenocrysts from mafic enclaves and plagioclase from its host granite possess a pat-tem of complex zonation. A plagioclase phenocryst can generally be divided into three parts : an oscillatory, locally pat...Plagioclase phenocrysts from mafic enclaves and plagioclase from its host granite possess a pat-tem of complex zonation. A plagioclase phenocryst can generally be divided into three parts : an oscillatory, locally patchy zoned core (An47-19), a ring with dusty, more calcic plagioclase (An64-20) and a normally zoned rim composed of sodic plagioclase (An22-3. 3). Majordiscontinuities in zoning coincide with resorption suffeces that are overgrown by the more calcic plagioclase. The cores of large plagioclase phenocrysts from mafic enclaves and host granite show similar zoning patterns and similar compositions, indicating their crystallization under the same conditions . Steep normal zoning of the rims of plagioclases both from host granite and mafic enclaves illustrates a drastic decrease in An content which is considered to have resulted from the continuous differentiation of hybrid magma and efficient heat loss because of the upward emplacement of the residual magma. Wide rims of plagioclases from the host granite against thc discrete rims of plagioclases from mafic enclaves indicate that differentiation and cooling lasted much longer in the host granite than in the mafic enclaves.展开更多
Better understanding of shoshonitic rocks is vital to unravel the formation process and spatial distribution of their associated ore deposits.Here,we conducted analyses on the shoshonitic granodiorite and its mafic mi...Better understanding of shoshonitic rocks is vital to unravel the formation process and spatial distribution of their associated ore deposits.Here,we conducted analyses on the shoshonitic granodiorite and its mafic microgranular enclaves(MMEs)from the Chadi Cu-Pb-Zn polymetallic deposit(South China),with the aim to investigate their petrogenesis and tectonic setting.Zircon U-Pb age of the MMEs(165.0±1.2 Ma)is coeval with that of the host granodiorite(164.8±0.63 Ma).The Chadi granitoids are enriched in large ion lithophile elements and light rare earth elements,but depleted in high-field-strength elements.The granodiorite displays low(^(87)Sr/^(86)Sr)_(i)(0.7069-0.7072),and negative ε_(Nd)(t)(−5.8 to−5.5)and zircon ε_(Hf)(t)(−3.6 to−0.4)values.These isotopic characteristics of the granodiorite and MMEs indicate the mixing of a mafic magma(formed from the subduction-related,metasomatically-enriched lithospheric mantle)and a felsic magma(formed from the partial melting of crustal materials),which is closely related to the Paleo-Pacific subduction.The Chadi granodioritic magma has likely low oxygen fugacity(<ΔFMQ+1),low whole-rock Sr/Y ratio(mostly<30),and low S(0.04±0.02 wt%)and Cl(0.23±0.04 wt%)contents,suggesting that the potential of forming large-scale Cu mineralization is low.展开更多
The mafic enclaves from Paleoproterozoic domain are considered to be the results of large-scale crust-mantle interaction and magma mixing. In this paper, petrography, mineralogy and geochemistry were jointly used to d...The mafic enclaves from Paleoproterozoic domain are considered to be the results of large-scale crust-mantle interaction and magma mixing. In this paper, petrography, mineralogy and geochemistry were jointly used to determine the origin of the mafic enclaves and their relationship with the host granitoids of the Kan granite-gneiss complex. This study also provides new information on crust-mantle interactions. The mafic enclaves of the Kan vary in shape and size and have intermediate chemical compositions. The diagrams used show a number of similarities in the major elements (and often in the trace elements) between the mafic enclaves and the host granitoids. Geochemical show that the Kan rock are metaluminous, enriched in silica, medium to high-K calc-alkaline I-type granite. The similarities reflect a mixing of basic and acid magma. Mafic enclaves have a typical magmatic structure, which is characterized by magma mixing. The genesis of these rocks is associated with the context of subduction. They result from the mixing of a mafic magma originating from the mantle and linked to subduction, and a granitic magma (type I granite) that arises from the partial melting of the crust.展开更多
基金supported in part by the National Key Research and Development Program of China(No.2017YFA0402300)National Natural Science Foundation of China(Nos.U2241288 and 11974359)Major Science and Technology Project of Gansu Province(No.22ZD6FA021-5)。
文摘Recent work has validated a new method for estimating the grain size of microgranular materials in the range of tens to hundreds of micrometers using laser-induced breakdown spectroscopy(LIBS).In this situation,a piecewise univariate model must be constructed to estimate grain size due to the complex dependence of the plasma formation environment on grain size.In the present work,we tentatively construct a unified calibration model suitable for LIBS-based estimation of those grain sizes.Specifically,two unified multivariate calibration models are constructed based on back-propagation neural network(BPNN)algorithms using feature selection strategies with and without considering prior information.By detailed analysis of the performances of the two multivariate models,it was found that a unified calibration model can be successfully constructed based on BPNN algorithms for estimating the grain size in the range of tens to hundreds of micrometers.It was also found that the model constructed with a priorguided feature selection strategy had better prediction performance.This study has practical significance in developing the technology for material analysis using LIBS,especially when the LIBS signal exhibits a complex dependence on the material parameter to be estimated.
基金supported by the National Science Foundation of China(40930419)Special Research Funding for the Public Benefits Sponsored by MLR (200911007–12)+2 种基金Research Program of Yunnan Tin Group (2010–04A)Geological Investigation Program by CGS (1212011120994)the Fundamental Research Funds for the Central Universities(2–9–2010–21)
文摘Many igneous rocks distribute in Gejiu tin polymetallic ore-field at Yunnan province, rocks including basalt, gabbro, mafic microgranular enclaves, granites （porphyritic granite and equigranular granite） and akaline rocks. The ages of the granites and akaline rocks which are considered to have genetic connecting with the mineralization have been comfirmed, but the gabbro- mafic microgranular enclaves-granite assemblage＇s ages are still unknown. By means of LA-ICP-MS zircon U-Pb dating, the data of Shenxianshui equigranular granite, the mafic microgranular enclave in Jiasha area, the host rock of the mafic microgranular enclaves and the Jiasha gabbro are around ~80 Ma. Besides the above mentioned data, a group of new ages at ~30 Ma were discovered in this study, which is from gabbro and mafic microgranular enclaves. Based on the previous data and the new data gained this time, we suggest the major geochronology framework of the magmatism and mineralization events in Gejiu area is ~80 Ma, which is consistent with the Late Cretaceous magmatism and mineralization events in the whole southeast Yunnan and west Guangxi area and they were suggested to belong to the same geotectonic setting in late Yenshannian. And the new ages of the ~30 Ma obtained in this study is considered to represent a responding to the complicate tectonic evolution history of the Tibetan orogenic events in Cenozoic.
文摘Plagioclase phenocrysts from mafic enclaves and plagioclase from its host granite possess a pat-tem of complex zonation. A plagioclase phenocryst can generally be divided into three parts : an oscillatory, locally patchy zoned core (An47-19), a ring with dusty, more calcic plagioclase (An64-20) and a normally zoned rim composed of sodic plagioclase (An22-3. 3). Majordiscontinuities in zoning coincide with resorption suffeces that are overgrown by the more calcic plagioclase. The cores of large plagioclase phenocrysts from mafic enclaves and host granite show similar zoning patterns and similar compositions, indicating their crystallization under the same conditions . Steep normal zoning of the rims of plagioclases both from host granite and mafic enclaves illustrates a drastic decrease in An content which is considered to have resulted from the continuous differentiation of hybrid magma and efficient heat loss because of the upward emplacement of the residual magma. Wide rims of plagioclases from the host granite against thc discrete rims of plagioclases from mafic enclaves indicate that differentiation and cooling lasted much longer in the host granite than in the mafic enclaves.
基金granted by the Basic Scientific Research Fund of Chinese Academy of Geological Sciences[Grant No.JKY202505,JYYWF20180601,KK2207]the National Natural Science Foundation of China(Grant No.41702083,41820104010)China Scholarship Council(Grant No.CSC 201908110163)。
文摘Better understanding of shoshonitic rocks is vital to unravel the formation process and spatial distribution of their associated ore deposits.Here,we conducted analyses on the shoshonitic granodiorite and its mafic microgranular enclaves(MMEs)from the Chadi Cu-Pb-Zn polymetallic deposit(South China),with the aim to investigate their petrogenesis and tectonic setting.Zircon U-Pb age of the MMEs(165.0±1.2 Ma)is coeval with that of the host granodiorite(164.8±0.63 Ma).The Chadi granitoids are enriched in large ion lithophile elements and light rare earth elements,but depleted in high-field-strength elements.The granodiorite displays low(^(87)Sr/^(86)Sr)_(i)(0.7069-0.7072),and negative ε_(Nd)(t)(−5.8 to−5.5)and zircon ε_(Hf)(t)(−3.6 to−0.4)values.These isotopic characteristics of the granodiorite and MMEs indicate the mixing of a mafic magma(formed from the subduction-related,metasomatically-enriched lithospheric mantle)and a felsic magma(formed from the partial melting of crustal materials),which is closely related to the Paleo-Pacific subduction.The Chadi granodioritic magma has likely low oxygen fugacity(<ΔFMQ+1),low whole-rock Sr/Y ratio(mostly<30),and low S(0.04±0.02 wt%)and Cl(0.23±0.04 wt%)contents,suggesting that the potential of forming large-scale Cu mineralization is low.
文摘The mafic enclaves from Paleoproterozoic domain are considered to be the results of large-scale crust-mantle interaction and magma mixing. In this paper, petrography, mineralogy and geochemistry were jointly used to determine the origin of the mafic enclaves and their relationship with the host granitoids of the Kan granite-gneiss complex. This study also provides new information on crust-mantle interactions. The mafic enclaves of the Kan vary in shape and size and have intermediate chemical compositions. The diagrams used show a number of similarities in the major elements (and often in the trace elements) between the mafic enclaves and the host granitoids. Geochemical show that the Kan rock are metaluminous, enriched in silica, medium to high-K calc-alkaline I-type granite. The similarities reflect a mixing of basic and acid magma. Mafic enclaves have a typical magmatic structure, which is characterized by magma mixing. The genesis of these rocks is associated with the context of subduction. They result from the mixing of a mafic magma originating from the mantle and linked to subduction, and a granitic magma (type I granite) that arises from the partial melting of the crust.
