The self-healing function is considered one of the effective ways to address structural damage and improve interfacial bonding in Energetic composite materials(ECMs).However,the currently prepared ECMs with self-heali...The self-healing function is considered one of the effective ways to address structural damage and improve interfacial bonding in Energetic composite materials(ECMs).However,the currently prepared ECMs with self-healing function have problems such as irregular particle shape and uneven distribution of components,which affect the efficient play of self-healing function.In this paper,HMX-based energetic microspheres with self-healing function were successfully prepared by microchannel technology,which showed excellent self-healing effect in both Polymer-bonded explosives(PBXs)and Composite solid propellants(CSPs).The experimental results show that the HMX-based energetic microspheres with different binder contents prepared by microchannel technology show regular shape,HMX crystal particles are uniformly wrapped by self-healing binder(GAPU).When the content of GAPU in HMX-based energetic microspheres is 10%,PBXs show excellent self-healing effect and mechanical safety is improved by 400%(raw HMX vs S4,5 J vs 25 J).As a high-energy component,the burning rate of CSPs is increased by 359.4%,the time(burning temperature>1700℃)is prolonged by 333.3%,and the maximum impulse force is increased by 107.3%(CSP-H vs CSP-S4,0.84 mm/s vs 3.87 mm/s,0.06 s vs 0.26 s,0.82 m N vs 1.70 m N).It also has excellent storage performance.The preparation of HMX-based energetic microspheres with self-healing function by microchannel technology provides a new strategy to improve the storage performance of ECMs and the combustion performance of CSPs.展开更多
基金support given by the Fundamental Research Program of Shanxi Province(Grant No.202203021212152)。
文摘The self-healing function is considered one of the effective ways to address structural damage and improve interfacial bonding in Energetic composite materials(ECMs).However,the currently prepared ECMs with self-healing function have problems such as irregular particle shape and uneven distribution of components,which affect the efficient play of self-healing function.In this paper,HMX-based energetic microspheres with self-healing function were successfully prepared by microchannel technology,which showed excellent self-healing effect in both Polymer-bonded explosives(PBXs)and Composite solid propellants(CSPs).The experimental results show that the HMX-based energetic microspheres with different binder contents prepared by microchannel technology show regular shape,HMX crystal particles are uniformly wrapped by self-healing binder(GAPU).When the content of GAPU in HMX-based energetic microspheres is 10%,PBXs show excellent self-healing effect and mechanical safety is improved by 400%(raw HMX vs S4,5 J vs 25 J).As a high-energy component,the burning rate of CSPs is increased by 359.4%,the time(burning temperature>1700℃)is prolonged by 333.3%,and the maximum impulse force is increased by 107.3%(CSP-H vs CSP-S4,0.84 mm/s vs 3.87 mm/s,0.06 s vs 0.26 s,0.82 m N vs 1.70 m N).It also has excellent storage performance.The preparation of HMX-based energetic microspheres with self-healing function by microchannel technology provides a new strategy to improve the storage performance of ECMs and the combustion performance of CSPs.
