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Bimetallic ZnFe–NC prepared using microchannel reactor for oxygen reduction reaction and mechanism research
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作者 Pin Cui Ying Tang +6 位作者 Jie Yu Zhen Yang Shouhua Yang Boqin Li Gang Wang Huan Pang Feng Yu 《Chinese Chemical Letters》 2025年第9期608-612,共5页
An Fe-doped bimetallic ZnFe-MOF precursor was prepared using a microchannel reactor,and carbonization was conducted to synthesize a bimetallic catalyst(ZnFe-NC).The fundamental reason for the efficient activity of the... An Fe-doped bimetallic ZnFe-MOF precursor was prepared using a microchannel reactor,and carbonization was conducted to synthesize a bimetallic catalyst(ZnFe-NC).The fundamental reason for the efficient activity of the catalyst was determined through an in-depth analysis of its structural composition and close correlation with the oxygen reduction reaction(ORR).The ZnFe-NC catalyst maintains a stable truncated rhombohedral morphology and a rich microporous structure,exhibiting excellent ORR activity and long-term stability.The experimental results show that compared with the reversible hydrogen electrode,it has a high half-wave potential of 0.902 V(E_(1/2)),retains 94%of activity after 35,000 s of stability testing,and exhibits significant methanol tolerance in alkaline media.Density functional theory calculations confirm the synergistic effect between the Zn and Fe sites.Furthermore,the results indicate that the interaction between ZnFe-N_(6)coordination structures reduces the reaction energy barrier,thus enhancing intermediate adsorption during the ORR. 展开更多
关键词 Metal organic frameworks microchannel reactor ZnFe–NC ORR Reaction mechanism
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Enhanced oxygen reduction reaction performance of Co@N–C derived from metal-organic frameworks ZIF-67 via a continuous microchannel reactor 被引量:4
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作者 Chenxu Wang Huifang Yuan +10 位作者 Feng Yu Jie Zhang Yangyang Li Wentao Bao Zhimou Wang Ke Lu Jie Yu Ge Bai Gang Wang Banghua Peng Lili Zhang 《Chinese Chemical Letters》 SCIE CAS CSCD 2023年第1期503-507,共5页
Traditional methods of preparing metal-organic frameworks(MOFs)compounds have the disadvantages such as poor dispersion,inefficient and discontinuous process.In this work,microchannel reactor is used to prepare MOFs-d... Traditional methods of preparing metal-organic frameworks(MOFs)compounds have the disadvantages such as poor dispersion,inefficient and discontinuous process.In this work,microchannel reactor is used to prepare MOFs-derived zeolite-imidazole material via flash nanoprecipitation to form ZIF-67+PEI(FNP),which reduces the MOF synthesis time down to millisecond time interval while keeping the synthesized ZIF-67+PEI(FNP)highly dispersed.The Co@N–C(FNP)catalyst obtained by flash nanoprecipitation and carbonization has a higher Co content and thus more active sites for oxygen reduction reaction than the Co@N–C(DM)catalyst prepared by direct mixing method.Electrochemical tests show that the Co@N–C(FNP)catalyst prepared by this method has excellent oxygen reduction performance,good methanol resistance and high stability.The onset potential and half-wave potential of Co@N–C(FNP)are 0.92 VRHE and 0.83 VRHE,respectively,which are higher than that of Co@N–C(DM)(Eonset=0.90 VRHEand E1/2=0.83VRHE).Moreover,the Zn-air battery assembled with Co@N–C(FNP)as the cathode catalyst has high open circuit voltage,high power density and large specific capacity.The performance of these batteries has been comparable to that of Pt/C assembled batteries.Density functional theory(DFT)calculations confirm that the Co(220)crystal plane present in Co@N–C(FNP)have stronger adsorption energy than that of Co(111)crystal plane in Co@N–C(DM),leading to better electrocatalytic performance of the former. 展开更多
关键词 microchannel reactor Metal-organic frameworks ELECTROCATALYST Oxygen reduction reaction Zn-air batteries
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The effect of operating conditions on acylation of 2-methylnaphthalene in a microchannel reactor 被引量:3
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作者 Wenpeng Li Suohe Yang +2 位作者 Xiaoyan Guo Guangxiang He Haibo Jin 《Chinese Journal of Chemical Engineering》 SCIE EI CAS CSCD 2018年第6期1307-1311,共5页
Acylation of 2-methylnaphthalene(2-MN) is a very important reaction in organic synthesis,and the effiency of the continuous reactor is more than one of the batch reactor.Considering that the Friedel–Crafts acylation ... Acylation of 2-methylnaphthalene(2-MN) is a very important reaction in organic synthesis,and the effiency of the continuous reactor is more than one of the batch reactor.Considering that the Friedel–Crafts acylation is a rapid exothermic reaction,in this study,we perform the acylation of 2-MN in a stainless steel microchannel flow reactor,which is characterized by high mass and heat transfer rates.The effect of reactant ratio,mixing temperature,reaction temperature,and reaction time on product yield and selectivity were investigated.Under the optimal conditions,2-methyl-6-propionylnaphthalene(2,6-MPN) was obtained in 85.8% yield with 87.5% selectivity.Compared with the conventional batch system,the continuous flow microchannel reactor provides a more efficient method for the synthesis of 2,6-MPN. 展开更多
关键词 ACYLATION microchannel reactor 2-METHYLNAPHTHALENE 2-Methyl-6-propionylnaphthalene
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Microchannel reactors for Fischer-Tropsch synthesis:Experimental investigation and mathematical modeling 被引量:1
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作者 Huili Cao Run Xu +3 位作者 Xiaojin Tang Tao Yang Shuandi Hou Chaopeng Hou 《Chinese Journal of Chemical Engineering》 SCIE EI CAS CSCD 2023年第12期224-240,共17页
The Fischer-Tropsch synthesis is a significant technology for converting coal,natural gas,and biomass into synthetic fuels.In recent years,the use of microchannel reactors for the Fischer-Tropsch synthesis has attract... The Fischer-Tropsch synthesis is a significant technology for converting coal,natural gas,and biomass into synthetic fuels.In recent years,the use of microchannel reactors for the Fischer-Tropsch synthesis has attracted significant attention.Fischer-Tropsch synthesis experiments were carried out in a microchannel reactor and the influences of reaction conditions on the experimental results were investigated in this study.Based on the experimental data,a dynamic multi-component pseudo-homogeneous variable-volume flow model of microchannel reactors for the Fischer-Tropsch synthesis was built to determine the pressure-,velocity-,conversion-and(component-wise)concentration-distributions in reaction channels.The model takes into account the combined effects of gas volume expansion caused by the frictional pressure drop and gas volume contraction caused by reaction consumption.A novel effective method for calculating the pressure and superficial gas velocity values in microchannel reactors was proposed in the model.Besides that,two sets of experimental data were selected from references to evaluate the validity and accuracy of the model.The reaction performances in the microchannels were analyzed carefully based on the calculated results. 展开更多
关键词 Fischer-Tropsch synthesis microchannel reactors MODELING Variable-volume flow
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Modelling of Microchannel Reactors for Fischer-Tropsch Synthesis 被引量:1
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作者 Cao Huili Tang Xiaojin 《China Petroleum Processing & Petrochemical Technology》 SCIE CAS 2020年第2期93-101,共9页
The Fischer-Tropsch synthesis is an important step in coal liquefaction,natural gas liquefaction,and biomass liquefaction.In recent years,the use of microchannel reactors for Fischer-Tropsch synthesis has received wid... The Fischer-Tropsch synthesis is an important step in coal liquefaction,natural gas liquefaction,and biomass liquefaction.In recent years,the use of microchannel reactors for Fischer-Tropsch synthesis has received widespread attention.Since thermocouples and other sensors cannot be placed easily in a microchannel reactor,it is very vital to establish a model to provide calculated results highly compatible with the experimental data.This paper mainly introduces the establishment and solution of microchannel reactor models for Fischer-Tropsch synthesis.General mass transfer differential equations,heat transfer differential equations and related parameters(such as reaction rates,dispersion coefficient,and convective heat transfer coefficient)are listed.To solve the models,numerical solutions,such as the CFD simulation methods and the programming methods,are reviewed.It is recommended that a more accurate solution strategy is the combination of CFD simulation and programming methods. 展开更多
关键词 Fischer-Tropsch synthesis microchannel reactor MODELLING
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Microchannel Reactor for Methanol Autothermal Reforming 被引量:12
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作者 CHEN Guangwen, YUAN Quan, LI Shulian (Dalian Institute of Chemical Physics, The Chinese Academy of Sciences, Dalian 116023, Liaoning, China) 《催化学报》 SCIE CAS CSCD 北大核心 2002年第6期491-492,共2页
关键词 甲醇 自热重整 微反应器
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CFD and experimental investigations on the micromixing performance of single countercurrent-flow microchannel reactor 被引量:5
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作者 Kunpeng Cheng Chunyu Liu +1 位作者 Tianyu Guo Lixiong Wen 《Chinese Journal of Chemical Engineering》 SCIE EI CAS CSCD 2019年第5期1079-1088,共10页
Microchannel reactors are widely used in different fields due to their intensive micromixing and, thus, high masstransfer efficiency. In this work, a single countercurrent-flow microchannel reactor(S-CFMCR) at the siz... Microchannel reactors are widely used in different fields due to their intensive micromixing and, thus, high masstransfer efficiency. In this work, a single countercurrent-flow microchannel reactor(S-CFMCR) at the size of ~1 mm was developed by steel micro-capillary and laser drilling technology. Utilizing the Villermaux/Dushman parallel competing reaction, numerical and experimental studies were carried out to investigate the micromixing performance(expressed as the segregation index XS) of liquids inside S-CFMCR at the low flow velocity regime.The effects of various operating conditions and design parameters of S-CFMCR, e.g., inlet Reynolds number(Re),volumetric flow ratio(R), inlet diameter(d) and outlet length(L), on the quality of micromixing were studied qualitatively. It was found that the micromixing efficiency was enhanced with increasing Re, but weakened with the increase of R. Moreover, d and L also have a significant influence on micromixing. CFD results were in good agreement with experimental data. In addition, the visualization of velocity magnitude, turbulent kinetic energy and concentration distributions of various ions inside S-CFMCR was illustrated as well. Based on the incorporation model, the estimated minimum micromixing time tmof S-CFMCR is ~2 × 10-4s. 展开更多
关键词 SINGLE countercurrent-flow microchannel reactor MICROMIXING performance CFD Villermaux/Dushman reaction
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Novel Preparation of Magnetic Microcapsules by Using T-Shaped Microchannel Reactor
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作者 陈红苗 刘鹏 +1 位作者 钟毅 罗艳 《Journal of Donghua University(English Edition)》 EI CAS 2013年第1期63-67,共5页
Traditional preparation of magnetic microcapsules involves cumbersome processes and often results in irregular-shaped products. Due to the stable laminar flow of reaction solution and the moderate reaction conditions,... Traditional preparation of magnetic microcapsules involves cumbersome processes and often results in irregular-shaped products. Due to the stable laminar flow of reaction solution and the moderate reaction conditions, the T-shaped microchannel (T-MC) reactor is supposed to yield microcapsules with regular shape. In this paper, magnetic particles of ferroferric oxide modified by oleic acid (OA-Fe3O4) and dispersed in tetrachloroethylene were used as core material. Polymethyl methacrylate (PMMA) was used as shell material. Magnetic microcapsules were prepared by using a T-MC reactor. Factors that influenced the encapsulated reaction were investigated in details, which included the velocity ratio of aqueous phase to oil phase, the length and the inner diameter of the microchannel. The morphology, composition, and magnetic responsiveness of the magnetic microcapsules were analyzed and characterized by SEM, FTIR, XRD, TGA, and vibrating sample magnetometer (VSM). The results confirmed that magnetic microcapsules prepared by T-MC reactor were regular in shape. 展开更多
关键词 modified ferroferric oxide T-shaped microchannel (T-MC) reactor magnetic microcapsules morphology characterization
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Enhanced CO_(2) adsorption properties with bimetallic ZnCe-MOF prepared using a microchannel reactor
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作者 Pin Cui Ying Tang +4 位作者 Aixia Guo Chenxu Wang Minmin Liu Wencai Peng Feng Yu 《Frontiers of Chemical Science and Engineering》 2025年第2期93-102,共10页
The use of metal-organic frameworks (MOFs) as CO_(2)-gas-capture materials has attracted extensive research attention. In this study, two types of MOFs—Zn-MOF and ZnCe-MOF—were synthesized utilizing the microchannel... The use of metal-organic frameworks (MOFs) as CO_(2)-gas-capture materials has attracted extensive research attention. In this study, two types of MOFs—Zn-MOF and ZnCe-MOF—were synthesized utilizing the microchannel reaction method, with water being employed as the solvent. The specific surface area, pore size, and pore volume of Zn-MOF and ZnCe-MOF were 1566.4 and 15.6 m^(2)·g^(-1), 0.65 and 7.32 nm, as well as 1.65 and 0.03 cm^(3)·g^(-1), respectively. Furthermore, Ce doping not only increased the pore size of ZnCe-MOF but also its adsorption energy from −0.19 eV (Zn-MOF) to −0.53 eV (ZnCe-MOF). At 298 K, the adsorption capacities of Zn-MOF and ZnCe-MOF were 0.66 and 0.74 mmol·g^(-1), respectively. In addition, the CO_(2) adsorption behaviors of Zn-MOF and ZnCe-MOF were linear and logarithmic, respectively. Theoretical calculations show that the results of adsorption thermodynamic simulations were consistent with the experiments. Thus, the preparation of ZnCe-MOF materials using a microchannel reactor provides a new approach for the continuous preparation of MOFs. 展开更多
关键词 Metal-organic framework microchannel reactor reaction mechanism CO_(2)capture adsorption
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Different efficiency toward the biomimetic aerobic oxidation of benzyl alcohol in microchannel and bubble column reactors: Hydrodynamic characteristics and gas–liquid mass transfer 被引量:2
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作者 Qi Han Xin-Yuan Zhang +2 位作者 Hai-Bo Wu Xian-Tai Zhou Hong-Bing Ji 《Chinese Journal of Chemical Engineering》 SCIE EI CAS CSCD 2023年第3期84-92,共9页
The selective aerobic oxidation of benzyl alcohol to benzaldehyde has attracted considerable attention because benzaldehyde is a high value-added product. The rate of this typical gas–liquid reaction is significantly... The selective aerobic oxidation of benzyl alcohol to benzaldehyde has attracted considerable attention because benzaldehyde is a high value-added product. The rate of this typical gas–liquid reaction is significantly affected by mass transfer. In this study, CoTPP-mediated(CoTPP: cobalt(II) mesotetraphenylporphyrin) selective benzyl alcohol oxidation with oxygen was conducted in a membrane microchannel(MMC) reactor and a bubble column(BC) reactor, respectively. We observed that 83% benzyl alcohol was converted within 6.5 min in the MMC reactor, but only less than 10% benzyl alcohol was converted in the BC reactor. Hydrodynamic characteristics and gas–liquid mass transfer performances were compared for the MMC and BC reactors. The MMC reactor was assumed to be a plug flow reactor,and the dimensionless variance was 0.29. Compared to the BC reactor, the gas–liquid mass transfer was intensified significantly in MMC reactor. It could be ascribed to the high gas holdup(2.9 times higher than that of BC reactor), liquid film mass transfer coefficient(8.2 times higher than that of BC reactor), and mass transfer coefficient per unit interfacial area(3.8 times higher than that of BC reactor). Moreover,the Hatta number for the MMC reactor reached up to 0.61, which was about 15 times higher than that of the BC reactor. The computational fluid dynamics calculations for mass fractions in both liquid and gas phases were consistent with the experimental data. 展开更多
关键词 Membrane microchannel reactor Gas-liquid flow Mass transfer Benzyl alcohol Computational fluid dynamics(CFD) Bubble column reactor
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Multiphase surfactant-assisted reaction-separation system in a microchannel reactor
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作者 Saah ALJBOUR Tomohiko TAGAWA +1 位作者 Mohammad MATOUQ Hiroshi YAMADA 《Frontiers of Chemical Science and Engineering》 SCIE EI CSCD 2009年第1期33-38,共6页
The Lewis acid-catalyzed addition of tri-methylsilyl cyanide to p-chlorobenzaldehyde in a micro-channel reactor was investigated.The microchannel was integrated to promote both reaction and separation of the biphase s... The Lewis acid-catalyzed addition of tri-methylsilyl cyanide to p-chlorobenzaldehyde in a micro-channel reactor was investigated.The microchannel was integrated to promote both reaction and separation of the biphase system.FeF3 and Cu(triflate)2 were used as water-stable Lewis acid catalysts.Sodium dodecyl sulfate was incorporated in the organic-aqueous system to enhance the reactivity and to manipulate the multiphaseflow inside the microchannel.It was found that the dynamics and the kinetics of the multiphase reaction were affected by the new micellar system.Parallel multiphaseflow inside the microchannel was obtained,allowing for continuous and acceptable phase separation.Enhanced selectivity was achieved by operating at lower conversion values. 展开更多
关键词 Lewis acid catalysis multiphase reactions process intensification microchannel reactor green engi-neering
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Review of structural design, fabrication, and application of microchannel reactors 被引量:1
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作者 ZHOU Wei LIU YangXu +4 位作者 CHU XuYang YUAN Ding LIU RuiLiang Kwan San Hui Kwun Nam Hui 《Science Foundation in China》 CAS 2019年第2期66-80,共15页
Microchannel reactors usually have some microchannels with characteristic sizes(i.e., between 1 and 1000 μm). Small channel size and diversity are usually patterned in a microchannel reactor, and these features incre... Microchannel reactors usually have some microchannels with characteristic sizes(i.e., between 1 and 1000 μm). Small channel size and diversity are usually patterned in a microchannel reactor, and these features increase the surface area-to-volume ratio and driving force for heat and mass transport. Microchannel reactors are widely used in the petrochemistry, aerospace, electronics, information technology, and automotive industries, among others. According to the geometric shape of microchannels, a microchannel reactor can be classified as parallel, curved, micro-pin-fin array, bionic, or 3D network type. This review summarizes the fabrication methods of microchannel reactors, including traditional mechanical processing, chemical etching, electroforming injection molding technology, non-traditional machining, and sintering. It also presents the various applications of microchannel reactors in catalytic reactions, heat transfer, mixing, and other areas. Finally, this review describes the development and application prospects of microchannel reactors. 展开更多
关键词 microchannel reactor FABRICATION method GEOMETRIC shape CATALYTIC reaction Heat transfer MIXING
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微通道反应器中间二硝基苯的合成及反应动力学 被引量:1
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作者 季聪 詹乐武 +1 位作者 侯静 李斌栋 《火炸药学报》 北大核心 2025年第4期330-337,I0002,共9页
为了弥补间二硝基苯(m-DNB)在传统釜式生产工艺中生产能力小、生产过程稳定性差、生产效率低等缺陷,基于微通道反应器,以硝基苯(NB)为原料,二氯乙烷为溶剂,发烟硝酸与发烟硫酸的混合酸为硝化剂,合成了m-DNB;探究了混合酸摩尔比、硝酸与N... 为了弥补间二硝基苯(m-DNB)在传统釜式生产工艺中生产能力小、生产过程稳定性差、生产效率低等缺陷,基于微通道反应器,以硝基苯(NB)为原料,二氯乙烷为溶剂,发烟硝酸与发烟硫酸的混合酸为硝化剂,合成了m-DNB;探究了混合酸摩尔比、硝酸与NB摩尔比、反应温度、物料的总流速对硝化反应的影响,并对该反应的反应动力学进行了研究。结果表明,反应的最优条件为:物料的总流速60 mL/min、硝酸与硫酸摩尔比1∶4、NB与硝酸摩尔比1∶2、反应温度40℃;在此条件下,m-DNB收率高达93.60%;NB硝化反应的活化能为63.930 kJ/mol,指前因子为1.115×10^(9) L/(mol·s)。表明微通道反应器具有传热与传质效率高、反应进程可准确掌握、安全性高等优势。 展开更多
关键词 有机化学 间二硝基苯 m-DNB 微通道反应器 硝化工艺 反应动力学
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微通道连续流工艺在甲磺草胺中间体硝化反应中的应用 被引量:1
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作者 纪璐 李书龙 +5 位作者 安亭旺 郭帅 魏微 王珂 范娜 刘东 《农药》 北大核心 2025年第2期94-100,共7页
[目的]利用微通道反应器研究甲磺草胺中间体2-(2,4-二氯苯基)-4-二氟甲基-5-甲基-2,4-二氢-3H-1,2,4-三唑-3-酮(TZL)的硝化反应工艺。[方法]用二氯乙烷溶解原料TZL,与混酸在微反应器内进行连续硝化反应得到硝化产品。[结果]在n(TZL)∶n... [目的]利用微通道反应器研究甲磺草胺中间体2-(2,4-二氯苯基)-4-二氟甲基-5-甲基-2,4-二氢-3H-1,2,4-三唑-3-酮(TZL)的硝化反应工艺。[方法]用二氯乙烷溶解原料TZL,与混酸在微反应器内进行连续硝化反应得到硝化产品。[结果]在n(TZL)∶n(硝酸)∶n(108%硫酸)为1∶1.04∶8,进料温度为35℃,反应器温度为75℃的条件下,原料转化率达到100%,产品收率≥96%,与间歇工艺相比,反应时间由2 h降低至57 s。[结论]该工艺具有反应时间短、收率高、安全性和经济效益好等优势,可以实现工业化生产。 展开更多
关键词 甲磺草胺中间体 微通道反应器 硝化反应
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微通道反应器内间二甲苯连续氧化合成间苯二甲酸工艺研究
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作者 范雨 周维友 +1 位作者 何明阳 钱俊峰 《现代化工》 北大核心 2025年第2期146-150,共5页
以O_(2)为氧化剂、乙酸为溶剂、Co/Mn/Br为催化体系,研究了微通道反应器中液相连续流氧化间二甲苯合成间苯二甲酸工艺。考察了Co(Mn)摩尔分数、Co^(2+)与Mn^(2+)摩尔比、Br-摩尔分数、氧气摩尔分数、反应温度、反应压力、停留时间对反... 以O_(2)为氧化剂、乙酸为溶剂、Co/Mn/Br为催化体系,研究了微通道反应器中液相连续流氧化间二甲苯合成间苯二甲酸工艺。考察了Co(Mn)摩尔分数、Co^(2+)与Mn^(2+)摩尔比、Br-摩尔分数、氧气摩尔分数、反应温度、反应压力、停留时间对反应的影响。结果表明,在优化工艺条件下,间二甲苯的转化率和间苯二甲酸的收率均>99%。相比于间歇釜式反应工艺,该工艺操作简便、反应条件易控制、氧化效率和安全系数更高,为工业上合成间苯二甲酸提供了一种高效、绿色、经济的方法。 展开更多
关键词 间二甲苯 连续流 氧化 间苯二甲酸 微通道反应器
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微反应器中脂肪族C_(4)~C_(9)醛连续液相氧化反应研究 被引量:1
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作者 乔宾 宋万仓 +4 位作者 王本雷 曾贤君 王鹏飞 张利杰 李晨 《现代化工》 北大核心 2025年第2期199-204,共6页
在连续流微反应器中,以环烷酸锰为催化剂,在不同的原料浓度、反应温度、反应压力和氧气用量下,研究了正戊醛连续氧化制备正戊酸的反应工艺。为了进行比较,在鼓泡塔反应器中通过相同反应物浓度对正戊醛氧化进行了研究。结果表明,在其他... 在连续流微反应器中,以环烷酸锰为催化剂,在不同的原料浓度、反应温度、反应压力和氧气用量下,研究了正戊醛连续氧化制备正戊酸的反应工艺。为了进行比较,在鼓泡塔反应器中通过相同反应物浓度对正戊醛氧化进行了研究。结果表明,在其他实验条件相似的情况下,连续流微反应器中正戊醛质量分数为50%、n(O_(2))∶n(原料)=0.6∶1、停留时间为8 min、催化剂质量分数为10μg/g、温度为40℃、压力为0.6 MPa时,正戊酸的收率>95%,停留时间、反应温度和压力均明显降低。同时在微反应器中考察了不同底物醛的氧化效果,并用气相色谱-质谱联用表征不同底物醛氧化反应进程和产物组成。结果表明,温度是影响不同醛转化率的关键,低碳链的醛结构简单、反应活性好、收率最高。醛的碳链越长结构越复杂,需要进一步提高反应温度来提高醛的反应活性和产品收率。 展开更多
关键词 微通道 脂肪醛 连续 均相氧化 脂肪酸
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微通道反应器内甲苯的硝化反应及芳烃结构与硫酸脱水值关系研究
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作者 周锴 李子成 《现代化工》 北大核心 2025年第8期204-208,共5页
以硝酸-硫酸混酸作硝化剂,在体积为10 mL的微通道反应器内进行了甲苯的硝化反应,探究了停留时间、反应温度、硫酸脱水值对转化率、选择性的影响,以及不同芳烃完全转化所需的硫酸脱水值,并考察了硫酸循环利用的可行性。通过计算芳烃亲核... 以硝酸-硫酸混酸作硝化剂,在体积为10 mL的微通道反应器内进行了甲苯的硝化反应,探究了停留时间、反应温度、硫酸脱水值对转化率、选择性的影响,以及不同芳烃完全转化所需的硫酸脱水值,并考察了硫酸循环利用的可行性。通过计算芳烃亲核指数,确定其对硫酸脱水值的影响。反应产物的气相色谱分析表明,与常见反应器相比,微通道具有反应速度更快、温度可控、产物选择性提高等优点。 展开更多
关键词 微通道反应器 硝化 芳烃
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新型结构微通道反应器制备纳米硫酸钡
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作者 曾焕然 林笑 +1 位作者 张兴 喻发全 《化学与生物工程》 北大核心 2025年第10期22-27,共6页
设计了一种8字型管结构微通道反应器,以硫酸钠和氯化钡为原料制备了纳米硫酸钡,研究了反应器结构、体积流量、微通道长度、螺旋直径、微通道内径等因素对纳米硫酸钡的粒径和粒度分布的影响。结果表明,在相同的工艺条件下,采用8字型管反... 设计了一种8字型管结构微通道反应器,以硫酸钠和氯化钡为原料制备了纳米硫酸钡,研究了反应器结构、体积流量、微通道长度、螺旋直径、微通道内径等因素对纳米硫酸钡的粒径和粒度分布的影响。结果表明,在相同的工艺条件下,采用8字型管反应器制备的纳米硫酸钡的平均粒径仅为直管反应器的45%~70%,且粒度分布更窄;在体积流量为40mL·min^(-1)、微通道长度为1 000mm、螺旋直径为10mm、微通道内径为0.5mm的条件下,采用8字型管反应器制得的纳米硫酸钡的平均粒径为83nm、多分散系数(PDI)为0.06,为纳米硫酸钡的高通量制备提供了一种简单、可靠的方法。 展开更多
关键词 纳米硫酸钡 微通道反应器 8字型管 微观混合 弯曲通道
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微通道反应器在氟磺胺草醚硝化反应中的安全应用 被引量:2
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作者 包平 《价值工程》 2025年第5期105-108,共4页
以某公司氟磺胺草醚的硝化中间体为例,原生产硝化工艺为釜式间歇反应工艺,由于釜式硝化反应不易实现连续化,反应时间长,物料在线量大,生产过程强放热,反应热不易移出体系外,易造成超温反应,促进二硝基物、多硝基物等副产物的生成,釜内... 以某公司氟磺胺草醚的硝化中间体为例,原生产硝化工艺为釜式间歇反应工艺,由于釜式硝化反应不易实现连续化,反应时间长,物料在线量大,生产过程强放热,反应热不易移出体系外,易造成超温反应,促进二硝基物、多硝基物等副产物的生成,釜内压力升高,从而引发爆炸、火灾事故的发生。为了提高本质安全度水平,积极实施硝化新工艺改进,有效降低安全风险,对氟磺胺草醚采用微通道反应器连续硝化生产工艺,进一步提升工艺本质安全水平,管控源头风险。 展开更多
关键词 微通道反应器 氟磺胺草醚 硝化反应 安全应用
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微通道反应器中合成2,2,4-三甲基-1,3-戊二醇单异丁酸酯反应动力学研究
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作者 栗晓宁 李瑞端 冯浩 《辽宁化工》 2025年第1期79-81,共3页
2,2,4-三甲基-1,3-戊二醇单异丁酸酯是一种非水溶性、低冰点、高沸点的二元醇酯,因其稳定性好、聚结性能高、可降低成膜温度等优势,已作为一种新型的绿色成膜助剂广泛应用于建筑与装饰材料领域。本研究以异丁醛为原料,氢氧化钠、碳酸钠... 2,2,4-三甲基-1,3-戊二醇单异丁酸酯是一种非水溶性、低冰点、高沸点的二元醇酯,因其稳定性好、聚结性能高、可降低成膜温度等优势,已作为一种新型的绿色成膜助剂广泛应用于建筑与装饰材料领域。本研究以异丁醛为原料,氢氧化钠、碳酸钠混合碱溶液为催化剂,通过微通道反应器合成2,2,4-三甲基-1,3-戊二醇单异丁酸酯,对此工艺建立反应动力学方程,确定此反应为二级反应,指前因子为35.05 L·mol^(-1)·min^(-1),活化能为9.12 kJ·mol^(-1)。 展开更多
关键词 2 2 4-三甲基-1 3-戊二醇单异丁酸酯 羟醛缩合 微通道反应器 动力学
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