High-overload shocks are very likely to cause damage to the microstructure of MEMS devices, especially the continuous multiple high-overload shocks generated by the penetration of the multilayer target environment pos...High-overload shocks are very likely to cause damage to the microstructure of MEMS devices, especially the continuous multiple high-overload shocks generated by the penetration of the multilayer target environment pose more stringent challenges to its protective structure. In this study, the kinetic response model of the protective structure under single-pulse and continuous double-pulse impact is established,and a continuous double-pulse high overload impact test impact platform based on the sleeve-type bullet is constructed, and the protective performance of the multi-layer structure under multi-pulse is analyzed based on the acceleration decay ratio, and the results show that the protective performance of the structure has a positive correlation with its thickness, and it is not sensitive to the change of the load of the first impact;the first impact under double-pulse impact will cause damage to the microstructure through the superposition of the second impact. The first impact under double-pulse impact will cause an increase in the overload amplitude of the second impact through superposition;compared with the single-layer structure, the acceleration attenuation ratio of the double-layer structure can be increased by up to 26.13%, among which the epoxy-polyurethane combination has the best protection performance, with an acceleration attenuation ratio of up to 44.68%. This work provides a robust theoretical foundation and experimental basis for the reliable operation of MEMS devices, as well as for the design of protective structures in extreme environments.展开更多
Flow boiling in open microchannels offers highly efficient heat transfer performance and has attracted increasing attention in the fields of heat transfer and thermalmanagement of electronic devices in recent years.Ho...Flow boiling in open microchannels offers highly efficient heat transfer performance and has attracted increasing attention in the fields of heat transfer and thermalmanagement of electronic devices in recent years.However,the continuous rise in power density of electronic components imposesmore stringent requirements on the heat transfer capability of microchannel flow boiling.HFE-7100,a dielectric coolant with favorable thermophysical properties,has become a focal point of research for enhancing flow boiling performance in open microchannels.The flow boiling heat transfer performance ofHFE-7100 was investigated in this study by fabricating micro-nano composite structures on the bottom surface of open microchannels using laser ablation technology.Based on visualization results,a comparative analysis was conducted on the bubble dynamics and flow pattern characteristics of HFE-7100 flow boiling in micronano structured open microchannels(MNSOMC)and smooth-surface open microchannels(SSOMC),to elucidate the enhancement mechanism of micro-nano structures on flow boiling heat transfer in open microchannels.The results indicate that the surface structures and strong wettability of MNSOMC accelerated bubble nucleation and departure.Moreover,bubbles in the channel tended to coalesce along the flow direction,forming elongated slug bubbles with high aspect ratios,which enabled efficient thin film evaporation in conjunction with intense nucleate boiling,thereby significantly enhancing flow boiling heat transfer.Under the experimental conditions of this study,the maximum enhancements in the heat transfer coefficient(HTC)and critical heat flux(CHF)of HFE-7100 inMNSOMC were 33.4%and 133.1%,respectively,with the CHF reaching up to 1542.3 kW⋅m^(−2).Furthermore,due to the superior wettability and capillary wicking capability of the micro-nano composite structures,the significant enhancement in flow boiling heat transfer was achieved without incurring a noticeable pressure drop penalty.展开更多
A conventional solid-state process was used to synthesize the double perovskite materials HoRCoMnO_(6)(R=Ho,Gd,Eu,Nd).The structural properties of the compounds were investigated using X-ray powder diffraction(XRD).Th...A conventional solid-state process was used to synthesize the double perovskite materials HoRCoMnO_(6)(R=Ho,Gd,Eu,Nd).The structural properties of the compounds were investigated using X-ray powder diffraction(XRD).The results revealed that Ho_(2)CoMnO_(6) crystallizes in a monoclinic structure with the P2_(1)/n space group.In contrast,the other compounds HoRCoMnO_(6)(R=Gd,Eu,or Nd) exhibit an orthorhombic structure with the Pnma space group.As a result,the average crystallite size also changes as a function of rare-earth element doping.This investigation reveals that the magnetic properties of the compounds studied are significantly dependent on the doping elements.The Curie temperature T_C,for example,increases from 80 to 118℃ with the ionic radii of rare earths increasing.Furthermore,the study of the magnetocaloric effect(MCE) shows that the maximum of the entropy variation(-ΔS_(M)^(max)) increases from 4.97 to 6.06 J/(kg·K) under a magnetic field of 5 T with substitution by rare-earth ions.To examine the efficiency of MCE materials,the relative cooling power(RCP) was evaluated and is found to increase with increment of rare-earth radius till 406.69 J/kg for Nd.The mean entropy variation with tempe rature(TEC) was also studied.Due to their significant magnetocaloric performance,HoRCoMnO_(6)(noted as HRCMO) compounds(with R=Ho,Gd,Eu or Nd) could be good candidates for low-temperature magnetic cooling applications.展开更多
The application of single-phase face-centered cubic(FCC)medium entropy alloys(MEAs)in the engi-neering industry is often hindered by the challenge of insufficient strength.In this study,a novel non-equiatomic ratio Ni...The application of single-phase face-centered cubic(FCC)medium entropy alloys(MEAs)in the engi-neering industry is often hindered by the challenge of insufficient strength.In this study,a novel non-equiatomic ratio Ni_(40)Co_(30)Cr_(20)Al_(5)Ti_(5)MEA was successfully fabricated.Through the well-designed mechan-ical heat treatment processing,we introduced a heterogeneous grain structure comprising 67.4%fine grain and 32.6%coarse grain.Additionally,heterogeneous size L12 phases consisting of 18.7%submicron precip-itates and 11.7%nano-sized precipitates,were incorporated into the alloy.Tensile tests conducted at room temperature revealed that the double heterogeneous structure alloy demonstrated remarkable strength–ductility synergy.It exhibited a yield strength of 1200 MPa,an ultimate tensile strength of 1560 MPa and a total elongation of 33.6%.The exceptional strength of the alloy can be primarily attributed to heteroge-neous deformation induced strengthening,grain boundary strengthening and precipitation strengthening.The excellent ductility is mainly attributed to the high-density stacking faults and Lomer–Cottrell locks.This study not only contributes to the clarification of the strengthening and deformation mechanism of double heterogeneous structure alloys but also provides an effective strategy for the development of high-performance alloys with high strength and ductility.展开更多
Research efforts on electromagnetic interference(EMI)shielding materials have begun to converge on green and sustainable biomass materials.These materials offer numerous advantages such as being lightweight,porous,and...Research efforts on electromagnetic interference(EMI)shielding materials have begun to converge on green and sustainable biomass materials.These materials offer numerous advantages such as being lightweight,porous,and hierarchical.Due to their porous nature,interfacial compatibility,and electrical conductivity,biomass materials hold significant potential as EMI shielding materials.Despite concerted efforts on the EMI shielding of biomass materials have been reported,this research area is still relatively new compared to traditional EMI shielding materials.In particular,a more comprehensive study and summary of the factors influencing biomass EMI shielding materials including the pore structure adjustment,preparation process,and micro-control would be valuable.The preparation methods and characteristics of wood,bamboo,cellulose and lignin in EMI shielding field are critically discussed in this paper,and similar biomass EMI materials are summarized and analyzed.The composite methods and fillers of various biomass materials were reviewed.this paper also highlights the mechanism of EMI shielding as well as existing prospects and challenges for development trends in this field.展开更多
A comprehensive way to design a sub 50nm SADG MOSFET with the ability of being fabricated by improved CMOS technique is described.Under this way,the gate length and thickness of Si island of DG device show many diffe...A comprehensive way to design a sub 50nm SADG MOSFET with the ability of being fabricated by improved CMOS technique is described.Under this way,the gate length and thickness of Si island of DG device show many different scaling limits for various elements.Meanwhile,the spacer insulator shows a kind of width thickness on device drain current and circuit speed.A model about that effect is developed and offers design consideration for future.A new design of channel doping profile,called SCD,is also discussed here in detail.The DG device with SCD can achieve a good balance between the volume inversion operation mode and the control of V th .Finally,a guideline to make a SADG MOSFET is presented.展开更多
The employment of single atom catalysts(SACs)remarkably increases atomic utilization and catalytic efficiency in various electrochemical processes,especially when coupled with metal clusters/nanoparticles.However,the ...The employment of single atom catalysts(SACs)remarkably increases atomic utilization and catalytic efficiency in various electrochemical processes,especially when coupled with metal clusters/nanoparticles.However,the synergistic effects mainly focus on the energetics of key intermediates during the electrocatalysis,while the properties of electrode surface and electric-double-layer(EDL)structure are largely overlooked.Herein,we report the synthesis of Ru nanoparticles integrated with neighboring Ru single atoms on nitrogen doped carbon(Ru1,n/NC)as efficient catalysts toward hydrogen oxidation reaction(HOR)under alkaline electrolytes.Electrochemical data,in situ attenuated total reflectance surface-enhanced infrared absorption spectroscopy,and density functional theory calculations reveal that the positively charged Ru single atoms could lead to the dynamically regulated proportion of strongly hydrogen-bonded interfacial water structure with O-down conformation and optimized connectivity of the hydrogen-bond network in the EDL region,which contribute to the accelerated diffusion of hydroxide ions to the electrified interfaces.Consequently,the obtained Ru1,n/NC catalyst displays remarkable HOR performance with the mass activity of 1.15 mAμgPGM^(-1) under alkaline electrolyte.This work demonstrates the promise of single atoms for interfacial water environment adjustment and mass transfer process modulation,providing new insights into rational design of highly-effective SAC-based electrocatalysts.展开更多
One-dimensional semiconductor materials possess excellent photoelectric properties and potential for the construction of integrated nanodevices. Among them, Sn-doped CdS has different micro-nano structures, including ...One-dimensional semiconductor materials possess excellent photoelectric properties and potential for the construction of integrated nanodevices. Among them, Sn-doped CdS has different micro-nano structures, including nanoribbons,nanowires, comb-like structures, and superlattices, with rich optical microcavity modes, excellent optical properties, and a wide range of application fields. This article reviews the research progress of various micrometer structures of Sn-doped CdS, systematically elaborates the effects of different growth conditions on the preparation of Sn-doped CdS micro-nano structures, as well as the spectral characteristics of these structures and their potential applications in certain fields. With the continuous progress of nanotechnology, it is expected that Sn-doped CdS micro-nano structures will achieve more breakthroughs in the field of optoelectronics and form cross-integration with other fields, jointly promoting scientific, technological, and social development.展开更多
Using Fourier inversion transform, P.D.E. and Feynman-Kac formula, the closedform solution for price on European call option is given in a double exponential jump-diffusion model with two different market structure ri...Using Fourier inversion transform, P.D.E. and Feynman-Kac formula, the closedform solution for price on European call option is given in a double exponential jump-diffusion model with two different market structure risks that there exist CIR stochastic volatility of stock return and Vasicek or CIR stochastic interest rate in the market. In the end, the result of the model in the paper is compared with those in other models, including BS model with numerical experiment. These results show that the double exponential jump-diffusion model with CIR-market structure risks is suitable for modelling the real-market changes and very useful.展开更多
The welding heat source models and the plastic tension zone sizes of a typical weld joint involved in the double floor structure of high speed train under different welding parameters were calculated by a thermal-elas...The welding heat source models and the plastic tension zone sizes of a typical weld joint involved in the double floor structure of high speed train under different welding parameters were calculated by a thermal-elastic-plastic FEM analysis based on SYSWELD code.Then,the welding distortion of floor structure was predicted using a linear elastic FEM and shrinkage method based on Weld Planner software.The effects of welding sequence,clamping configuration and reverse deformation on welding distortion of floor structure were examined numerically.The results indicate that the established elastic FEM model for floor structure is reliable for predicting the distribution of welding distortion in view of the good agreement between the calculated results and the measured distortion for real double floor structure.Compared with the welding sequence,the clamping configuration and the reverse deformation have a significant influence on the welding distortion of floor structure.In the case of30 mm reverse deformation,the maximum deformation can be reduced about 70%in comparison to an actual welding process.展开更多
Co–Mo catalysts applied on the hydrodesulfurization（HDS） for FCC gasoline were prepared with Zn–Al layered double hydroxides（LDHs） to improve their performances,and the effects of pore structures and acidity on ...Co–Mo catalysts applied on the hydrodesulfurization（HDS） for FCC gasoline were prepared with Zn–Al layered double hydroxides（LDHs） to improve their performances,and the effects of pore structures and acidity on HDS performances were studied in detail. A series of Zn–Al/LDHs samples with different pore structures and acidities are synthesized on the bases of co-precipitation of OH-,CO2-,Al3＋,and Zn2＋. The neutralization p H is a main factor to affect the pore structures and acidity of Zn–Al/LDHs,and a series of Zn–Al/LDHs with different pore structures and acidities are obtained. Based on the representative samples with different specific surface areas（SBET） and acidities,three Co Mo/LDHs catalysts were prepared,and their HDS performances were compared with traditional Co Mo/Al2O3 catalysts. The results indicated that catalysts prepared with high SBETpossessed high HDS activity,and Br？nsted acid sites could reduce the thiol content in the product to some extent. All the three catalysts prepared with LDHs displayed little lower HDS activity but higher selectivity than Co Mo/Al2O3,and could restrain the reactions of re-combination between olefin and H2 S which could be due to the existence of Br？nsted acid sites.展开更多
In this paper, a new pressure reducing valve （PRV） with an orifice plate is proposed. The main objective is to explain the mechanisms of pressure reduction and energy conversion in the new PRV. A numerical simulatio...In this paper, a new pressure reducing valve （PRV） with an orifice plate is proposed. The main objective is to explain the mechanisms of pressure reduction and energy conversion in the new PRV. A numerical simulation method was used to investigate the PRV internal flow field and to analyze the throttling effects of the orifice plate and the transform of thermal parameters as outlet pressure, outlet temperature, velocity, and superheat. A structure improvement method for the valve body and orifice plate is put forward to reduce energy loss. The governing equations for internal flow numerical simulation are composed of the continuity, momentum, energy and k-e transport equations, based on isotropic eddy viscosity theory. Different valve plug displacement models were built to describe the double throttling process. Our analysis shows that the steam pressure drops twice and the degree of superheat increases. There are also lots of eddies which clog the flow channel and disturb the steam flow in the valve cavity after the valve plug and the outlet cavity. After modifying the structure, the numerical results show a better performance of steam flow.展开更多
A comprehensive protective structure with rigidity and flexibility was put forward and designed in view of the quality and safety problems for the double vertical explosive welding of large titanium/steel cladding pla...A comprehensive protective structure with rigidity and flexibility was put forward and designed in view of the quality and safety problems for the double vertical explosive welding of large titanium/steel cladding plate.The movement speed and displacement of the protective structure was calculated by establishing its physics model.The dynamics and stabilization properties were analyzed,and the protective structure parameters were optimized and devised.The comprehensive protective structure,which is composed of rigidity unit and flexibility wall,can bear the impact of detonation wave and the high-speed movement of the cladding plate.There are no damage and deformation in the protective structure and the cladding plate.The protective structure can be used many times.The bonding rate of the Ti/steel plate obtained was nearly 100%,and there is no deformation,surface cracks,and big wave and micro-defects.Therefore,the protective problems of the double vertical explosive welding can be solved effectively by the protective structure.展开更多
Monolithic catalysts for CO_(2) methanation have become an active research area for the industrial development of Power-to-Gas technology.In this study,we developed a facile and reproducible synthesis strategy for the...Monolithic catalysts for CO_(2) methanation have become an active research area for the industrial development of Power-to-Gas technology.In this study,we developed a facile and reproducible synthesis strategy for the preparation of structured NiFe catalysts on washcoated cordierite monoliths for CO_(2) methanation.The NiFe catalysts were derived from in-situ grown layered double hydroxides(LDHs)via urea hydrolysis.The influence of different washcoat materials,i.e.,alumina and silica colloidal suspensions on the formation of LDHs layer was investigated,together with the impact of total metal concentration.NiFe LDHs were precipitated on the exterior surface of cordierite washcoated with alumina,while it was found to deposit further inside the channel wall of monolith washcoated with silica due to different intrinsic properties of the colloidal solutions.On the other hand,the thickness of in-situ grown LDHs layers and the catalyst loading could be increased by high metal concentration.The best monolithic catalyst(COR-AluCC-0.5M)was robust,having a thin and well-adhered catalytic layer on the cordierite substrate.As a result,high methane yield was obtained from CO_(2) methanation at high flow rate on this structured NiFe catalysts.The monolithic catalysts appeared as promising structured catalysts for the development of industrial methanation reactor.展开更多
To further improve the removal ability of layered double hydroxide(LDH) for iodide(I^-) anions from wastewater, we prepared hierarchically porous Cu5Mg10Al5-LDH and used as a matrix for in suit growth of Cu/Cu2O on it...To further improve the removal ability of layered double hydroxide(LDH) for iodide(I^-) anions from wastewater, we prepared hierarchically porous Cu5Mg10Al5-LDH and used as a matrix for in suit growth of Cu/Cu2O on its surface, forming Cu/Cu2O-LDH, which was characterized and applied as an adsorbent.Results displayed high I^-saturation uptake capability(137.8 mg/g) of Cu/Cu2O-LDH compared with Cu5Mg10Al5-LDH(26.4 mg/g) even thermal activated LDH(76.1 mg/g).Thermodynamic analysis showed that the reaction between I^-anions and Cu/Cu2O-LDH is a spontaneous and exothermic.Uptake kinetics analysis exhibited that adsorption equilibrium can be reached after 265 min.Additionally, the adsorbent showed satisfactory selectivity in the presence of competitive anions(e.g., SO4^2-), and could achieve good adsorption performance in a wide pH range of 3–8.A cooperative adsorption mechanism was proposed on the basis of the following two aspects:(1) ion exchange between iodide and interlayer anions;(2) the adsorption performance of Cu, Cu(Ⅱ) and Cu2O for I^-.Meanwhile, the difference between the adsorption mechanism of Cu/Cu2O-LDH, Cu5Mg10Al5-LDH and Cu5Mg10Al5-CLDH adsorbents was also elaborated and verified.展开更多
A 1D supramolecular compound [dmbbbi]（1） and a 2D cobalt coordination polymer [Co（dmbbbi）（ox）] 2（2） [dmbbbi=1,1-（1,4-butanediyl）bis（5,6-dimethylbenzimidazole）,ox=oxalate],C48H52Co2N8O8,were obtained under ...A 1D supramolecular compound [dmbbbi]（1） and a 2D cobalt coordination polymer [Co（dmbbbi）（ox）] 2（2） [dmbbbi=1,1-（1,4-butanediyl）bis（5,6-dimethylbenzimidazole）,ox=oxalate],C48H52Co2N8O8,were obtained under hydrothermal conditions by tuning the molar ratio of the reactants.The crystal structure analysis reveals that in compound 1,the adjacent dmbbbi molecules connect with each other via hydrogen bonds to form a 1D supramolecular chain.In compound 2,two crystallographically independent Co2＋ ions show the same six-coordination mode.Each Co2＋ ion is coordinated by four oxygen atoms from two ox anions and two nitrogen atoms from two cis-dmbbbi ligands.The adjacent Co2＋ ions are bridged by ox anions to generate an infinite 1D zigzag chain,which is extended by pairs of dmbbbi ligands to form a 2D honeycomb-like（6,3） network.Moreover,the thermal stability and the electrochemical property of compound 2 were studied.展开更多
Reaction of HgCl2 and double betaine ligands in water at about 80 ℃ yielded two new Hg（Ⅱ） complexes,[Hg（L1）Cl2]·H2O 1 and [Hg2（L2）Cl4]·3HgCl2 2（L1 = 1,3-bis（pyridinio-4-carboxylato）-propane,L2 = 1...Reaction of HgCl2 and double betaine ligands in water at about 80 ℃ yielded two new Hg（Ⅱ） complexes,[Hg（L1）Cl2]·H2O 1 and [Hg2（L2）Cl4]·3HgCl2 2（L1 = 1,3-bis（pyridinio-4-carboxylato）-propane,L2 = 1,4-bis（pyridinio-4-carboxylato）-1,4-dimenthylbenzene）.Their struc-tures have been characterized by single-crystal X-ray diffraction techniques.The structure of 1 contains 1-D chains,in which the adjacent Hg（Ⅱ） atoms are bridged by L1 ligands in a syn-syn bis-monodentate mode.The chains are further connected through face-to-face π-π stacking interactions between pyridine rings to generate an infinite double-chain network.In 2,two Hg（Ⅱ） atoms are joined by L2 ligands in the same coordination mode as 1 to form an isolated dinuclear structure.The thermal stabilities of both complexes have also been investigated.展开更多
Both racemate and enantiomer of a novel double helix,binaphthylcyclooctaterthiophene(BN-COTh),which is a DNA-like molecule constructed by two single helices intertwined with each other via covalent bonds,have been syn...Both racemate and enantiomer of a novel double helix,binaphthylcyclooctaterthiophene(BN-COTh),which is a DNA-like molecule constructed by two single helices intertwined with each other via covalent bonds,have been synthesized with two building blocks,cycloocta-tetrathiophene(COTh) and cyclooctadinaphthyldithiophene(CONT) fused together via Negishi coupling reaction.Another homologue,dinaphthylcyclooctaterthiophene(DN-COTh) has been employed together as a model compound.Besides the synthetic work,BN-COTh and DN-COTh have been investigated by studying their crystal structures,spectroscopic behaviors,chiral resolution and chiral characteristics,including circular dichroism(CD) spectra and optical rotations.In addition,the novel crystal of enantiomer of(R,R,R)-BN-COTh has been explored.The enantiomer molecules packing along b-axis to form a larger and extended assembly packing due to intermolecular interactions between the enantiomer molecules and chloroform molecules in crystal.展开更多
The daily 1°× 1° data of the Aviation （AVN） model, the black body temperature （TBB） data of cloud top, and cloud images by geostationary meteorological satellite （GMS） are used to identify a dew-p...The daily 1°× 1° data of the Aviation （AVN） model, the black body temperature （TBB） data of cloud top, and cloud images by geostationary meteorological satellite （GMS） are used to identify a dew-point front near the periphery of the western Pacific subtropical high （WPSH）. The results clearly demonstrate the existence of the dew-point front, and its thermodynamic and dynamic structural characteristics are analyzed in detail. The dew-point front is a transitional belt between the moist southwest monsoon flow and the dry adiabatic sinking flow near the WPSH, manifested by a large horizontal moisture gradient in the mid-lower troposphere and conjugated with the mei-yu front to form a predominant double-front structure associated with intense rainfall in the mei-yu period. The mei-yu front is located between 30° and 35°N, vertically extends from the ground level to the upper level and shifts northward. The dew-point front is to the south of the mei-yu front and lies up against the periphery of the WPSH. Generally, it is located between 850 hPa and 500 hPa. On the dew-point front side, the southwesterly prevails at the lower level and the northeasterly at the upper level; this wind distribution is different from that on the mei-yu front side. Vertical ascending motion exists between the two fronts, and there are descending motions on the north side of the mei^yu front and on the south side of the dew-point front~ which form a secondary circulation. The dynamics of the double fronts also have some interesting features. At the lower level, positive vertical vorticity and obvious convergence between the two fronts are clearly identified. At the mid-lower level, negative local change of the divergence （corresponding to increasing convergence） is often embedded in the two fronts or against the mei-yu front. Most cloud clusters occur between the two fronts and propagate down stream in a wave-like manner.展开更多
In order to solve the problem of using new nozzle is proposed in fire rescue robot. middle or low water pressure to form fine water mist, a Existing water mist nozzles are basically used for high pressure and in large...In order to solve the problem of using new nozzle is proposed in fire rescue robot. middle or low water pressure to form fine water mist, a Existing water mist nozzles are basically used for high pressure and in large size, complex structure and poor low pressure atomization effect in comparison with requirement of snake-like fire rescue robots. On the basis of comprehensive typical spray noz- zles, a direct spiral double helix converging nozzle （DSDHCN） is proposed, which has the advanta- ges of small volume, light weight, simple structure, and convenient installation. To make the spray nozzle have good performance, and meet the requirements of more efficient fire extinguishing, a nu- merical study is carried out to analyze the internal and external full flow field of nozzle. A gas-liquid two-phase flow is applied to simulate the external full flow field of nozzle with VOF model in fluent software. The simulation results show the real situation of water flow out of the atomization nozzle and the water jet trajectory. Some simulations about middle or low water pressure direct spiral double he- lix converging optimized nozzle have been done in 30bar pressure. The simulation results show that the optimized nozzle structure not only makes the spray droplets have a good cone angle, but also have a sufficient axial velocity,which proves the structure rationality of the proposed optimized nozzle.展开更多
基金supported by Fund of the National Natural Science Foundation of China (Grant No. 52375553)。
文摘High-overload shocks are very likely to cause damage to the microstructure of MEMS devices, especially the continuous multiple high-overload shocks generated by the penetration of the multilayer target environment pose more stringent challenges to its protective structure. In this study, the kinetic response model of the protective structure under single-pulse and continuous double-pulse impact is established,and a continuous double-pulse high overload impact test impact platform based on the sleeve-type bullet is constructed, and the protective performance of the multi-layer structure under multi-pulse is analyzed based on the acceleration decay ratio, and the results show that the protective performance of the structure has a positive correlation with its thickness, and it is not sensitive to the change of the load of the first impact;the first impact under double-pulse impact will cause damage to the microstructure through the superposition of the second impact. The first impact under double-pulse impact will cause an increase in the overload amplitude of the second impact through superposition;compared with the single-layer structure, the acceleration attenuation ratio of the double-layer structure can be increased by up to 26.13%, among which the epoxy-polyurethane combination has the best protection performance, with an acceleration attenuation ratio of up to 44.68%. This work provides a robust theoretical foundation and experimental basis for the reliable operation of MEMS devices, as well as for the design of protective structures in extreme environments.
基金funded by the National Natural Science Foundation of China(Grant No.52276047)the Open Fund of NationalKey Laboratory of SpacecraftThermal Control(Grant No.NKLST-JJ-202401011)the Beijing Municipal Science&Technology Commission(Grant No.Z231100006123010).
文摘Flow boiling in open microchannels offers highly efficient heat transfer performance and has attracted increasing attention in the fields of heat transfer and thermalmanagement of electronic devices in recent years.However,the continuous rise in power density of electronic components imposesmore stringent requirements on the heat transfer capability of microchannel flow boiling.HFE-7100,a dielectric coolant with favorable thermophysical properties,has become a focal point of research for enhancing flow boiling performance in open microchannels.The flow boiling heat transfer performance ofHFE-7100 was investigated in this study by fabricating micro-nano composite structures on the bottom surface of open microchannels using laser ablation technology.Based on visualization results,a comparative analysis was conducted on the bubble dynamics and flow pattern characteristics of HFE-7100 flow boiling in micronano structured open microchannels(MNSOMC)and smooth-surface open microchannels(SSOMC),to elucidate the enhancement mechanism of micro-nano structures on flow boiling heat transfer in open microchannels.The results indicate that the surface structures and strong wettability of MNSOMC accelerated bubble nucleation and departure.Moreover,bubbles in the channel tended to coalesce along the flow direction,forming elongated slug bubbles with high aspect ratios,which enabled efficient thin film evaporation in conjunction with intense nucleate boiling,thereby significantly enhancing flow boiling heat transfer.Under the experimental conditions of this study,the maximum enhancements in the heat transfer coefficient(HTC)and critical heat flux(CHF)of HFE-7100 inMNSOMC were 33.4%and 133.1%,respectively,with the CHF reaching up to 1542.3 kW⋅m^(−2).Furthermore,due to the superior wettability and capillary wicking capability of the micro-nano composite structures,the significant enhancement in flow boiling heat transfer was achieved without incurring a noticeable pressure drop penalty.
文摘A conventional solid-state process was used to synthesize the double perovskite materials HoRCoMnO_(6)(R=Ho,Gd,Eu,Nd).The structural properties of the compounds were investigated using X-ray powder diffraction(XRD).The results revealed that Ho_(2)CoMnO_(6) crystallizes in a monoclinic structure with the P2_(1)/n space group.In contrast,the other compounds HoRCoMnO_(6)(R=Gd,Eu,or Nd) exhibit an orthorhombic structure with the Pnma space group.As a result,the average crystallite size also changes as a function of rare-earth element doping.This investigation reveals that the magnetic properties of the compounds studied are significantly dependent on the doping elements.The Curie temperature T_C,for example,increases from 80 to 118℃ with the ionic radii of rare earths increasing.Furthermore,the study of the magnetocaloric effect(MCE) shows that the maximum of the entropy variation(-ΔS_(M)^(max)) increases from 4.97 to 6.06 J/(kg·K) under a magnetic field of 5 T with substitution by rare-earth ions.To examine the efficiency of MCE materials,the relative cooling power(RCP) was evaluated and is found to increase with increment of rare-earth radius till 406.69 J/kg for Nd.The mean entropy variation with tempe rature(TEC) was also studied.Due to their significant magnetocaloric performance,HoRCoMnO_(6)(noted as HRCMO) compounds(with R=Ho,Gd,Eu or Nd) could be good candidates for low-temperature magnetic cooling applications.
基金supported by the National Key R&D Program of China(No.2022YFA1603800)the National Natural Science Foundation of China(No.12274362)the Central Guidance on Local Science and Technology Development Fund of Hebei Province(No.216Z1012G)。
文摘The application of single-phase face-centered cubic(FCC)medium entropy alloys(MEAs)in the engi-neering industry is often hindered by the challenge of insufficient strength.In this study,a novel non-equiatomic ratio Ni_(40)Co_(30)Cr_(20)Al_(5)Ti_(5)MEA was successfully fabricated.Through the well-designed mechan-ical heat treatment processing,we introduced a heterogeneous grain structure comprising 67.4%fine grain and 32.6%coarse grain.Additionally,heterogeneous size L12 phases consisting of 18.7%submicron precip-itates and 11.7%nano-sized precipitates,were incorporated into the alloy.Tensile tests conducted at room temperature revealed that the double heterogeneous structure alloy demonstrated remarkable strength–ductility synergy.It exhibited a yield strength of 1200 MPa,an ultimate tensile strength of 1560 MPa and a total elongation of 33.6%.The exceptional strength of the alloy can be primarily attributed to heteroge-neous deformation induced strengthening,grain boundary strengthening and precipitation strengthening.The excellent ductility is mainly attributed to the high-density stacking faults and Lomer–Cottrell locks.This study not only contributes to the clarification of the strengthening and deformation mechanism of double heterogeneous structure alloys but also provides an effective strategy for the development of high-performance alloys with high strength and ductility.
基金National Natural Science Foundation of China(32201491)Young Elite Scientists Sponsorship Program by CAST(2023QNRC001)The authors extend their appreciation to the Deanship of Scientific Research at Northern Border University,Arar,KSA for funding this research work through the project number“NBU-FPEJ-2024-1101-02”.
文摘Research efforts on electromagnetic interference(EMI)shielding materials have begun to converge on green and sustainable biomass materials.These materials offer numerous advantages such as being lightweight,porous,and hierarchical.Due to their porous nature,interfacial compatibility,and electrical conductivity,biomass materials hold significant potential as EMI shielding materials.Despite concerted efforts on the EMI shielding of biomass materials have been reported,this research area is still relatively new compared to traditional EMI shielding materials.In particular,a more comprehensive study and summary of the factors influencing biomass EMI shielding materials including the pore structure adjustment,preparation process,and micro-control would be valuable.The preparation methods and characteristics of wood,bamboo,cellulose and lignin in EMI shielding field are critically discussed in this paper,and similar biomass EMI materials are summarized and analyzed.The composite methods and fillers of various biomass materials were reviewed.this paper also highlights the mechanism of EMI shielding as well as existing prospects and challenges for development trends in this field.
文摘A comprehensive way to design a sub 50nm SADG MOSFET with the ability of being fabricated by improved CMOS technique is described.Under this way,the gate length and thickness of Si island of DG device show many different scaling limits for various elements.Meanwhile,the spacer insulator shows a kind of width thickness on device drain current and circuit speed.A model about that effect is developed and offers design consideration for future.A new design of channel doping profile,called SCD,is also discussed here in detail.The DG device with SCD can achieve a good balance between the volume inversion operation mode and the control of V th .Finally,a guideline to make a SADG MOSFET is presented.
文摘The employment of single atom catalysts(SACs)remarkably increases atomic utilization and catalytic efficiency in various electrochemical processes,especially when coupled with metal clusters/nanoparticles.However,the synergistic effects mainly focus on the energetics of key intermediates during the electrocatalysis,while the properties of electrode surface and electric-double-layer(EDL)structure are largely overlooked.Herein,we report the synthesis of Ru nanoparticles integrated with neighboring Ru single atoms on nitrogen doped carbon(Ru1,n/NC)as efficient catalysts toward hydrogen oxidation reaction(HOR)under alkaline electrolytes.Electrochemical data,in situ attenuated total reflectance surface-enhanced infrared absorption spectroscopy,and density functional theory calculations reveal that the positively charged Ru single atoms could lead to the dynamically regulated proportion of strongly hydrogen-bonded interfacial water structure with O-down conformation and optimized connectivity of the hydrogen-bond network in the EDL region,which contribute to the accelerated diffusion of hydroxide ions to the electrified interfaces.Consequently,the obtained Ru1,n/NC catalyst displays remarkable HOR performance with the mass activity of 1.15 mAμgPGM^(-1) under alkaline electrolyte.This work demonstrates the promise of single atoms for interfacial water environment adjustment and mass transfer process modulation,providing new insights into rational design of highly-effective SAC-based electrocatalysts.
基金supported by National Natural Science Foundation of China (52275551)Shanxi Scholarship Council of China (2021-117)。
文摘One-dimensional semiconductor materials possess excellent photoelectric properties and potential for the construction of integrated nanodevices. Among them, Sn-doped CdS has different micro-nano structures, including nanoribbons,nanowires, comb-like structures, and superlattices, with rich optical microcavity modes, excellent optical properties, and a wide range of application fields. This article reviews the research progress of various micrometer structures of Sn-doped CdS, systematically elaborates the effects of different growth conditions on the preparation of Sn-doped CdS micro-nano structures, as well as the spectral characteristics of these structures and their potential applications in certain fields. With the continuous progress of nanotechnology, it is expected that Sn-doped CdS micro-nano structures will achieve more breakthroughs in the field of optoelectronics and form cross-integration with other fields, jointly promoting scientific, technological, and social development.
基金Supported by the NNSF of China(40675023)the PHD Foundation of Guangxi Normal University.
文摘Using Fourier inversion transform, P.D.E. and Feynman-Kac formula, the closedform solution for price on European call option is given in a double exponential jump-diffusion model with two different market structure risks that there exist CIR stochastic volatility of stock return and Vasicek or CIR stochastic interest rate in the market. In the end, the result of the model in the paper is compared with those in other models, including BS model with numerical experiment. These results show that the double exponential jump-diffusion model with CIR-market structure risks is suitable for modelling the real-market changes and very useful.
基金financial support to this project from the Chinese CSR Qingdao Sifang Co.,Ltd
文摘The welding heat source models and the plastic tension zone sizes of a typical weld joint involved in the double floor structure of high speed train under different welding parameters were calculated by a thermal-elastic-plastic FEM analysis based on SYSWELD code.Then,the welding distortion of floor structure was predicted using a linear elastic FEM and shrinkage method based on Weld Planner software.The effects of welding sequence,clamping configuration and reverse deformation on welding distortion of floor structure were examined numerically.The results indicate that the established elastic FEM model for floor structure is reliable for predicting the distribution of welding distortion in view of the good agreement between the calculated results and the measured distortion for real double floor structure.Compared with the welding sequence,the clamping configuration and the reverse deformation have a significant influence on the welding distortion of floor structure.In the case of30 mm reverse deformation,the maximum deformation can be reduced about 70%in comparison to an actual welding process.
文摘Co–Mo catalysts applied on the hydrodesulfurization（HDS） for FCC gasoline were prepared with Zn–Al layered double hydroxides（LDHs） to improve their performances,and the effects of pore structures and acidity on HDS performances were studied in detail. A series of Zn–Al/LDHs samples with different pore structures and acidities are synthesized on the bases of co-precipitation of OH-,CO2-,Al3＋,and Zn2＋. The neutralization p H is a main factor to affect the pore structures and acidity of Zn–Al/LDHs,and a series of Zn–Al/LDHs with different pore structures and acidities are obtained. Based on the representative samples with different specific surface areas（SBET） and acidities,three Co Mo/LDHs catalysts were prepared,and their HDS performances were compared with traditional Co Mo/Al2O3 catalysts. The results indicated that catalysts prepared with high SBETpossessed high HDS activity,and Br？nsted acid sites could reduce the thiol content in the product to some extent. All the three catalysts prepared with LDHs displayed little lower HDS activity but higher selectivity than Co Mo/Al2O3,and could restrain the reactions of re-combination between olefin and H2 S which could be due to the existence of Br？nsted acid sites.
基金Project (No. 2012C11018-1) supported by the Science and Technology Department of Zhejiang Province,China
文摘In this paper, a new pressure reducing valve （PRV） with an orifice plate is proposed. The main objective is to explain the mechanisms of pressure reduction and energy conversion in the new PRV. A numerical simulation method was used to investigate the PRV internal flow field and to analyze the throttling effects of the orifice plate and the transform of thermal parameters as outlet pressure, outlet temperature, velocity, and superheat. A structure improvement method for the valve body and orifice plate is put forward to reduce energy loss. The governing equations for internal flow numerical simulation are composed of the continuity, momentum, energy and k-e transport equations, based on isotropic eddy viscosity theory. Different valve plug displacement models were built to describe the double throttling process. Our analysis shows that the steam pressure drops twice and the degree of superheat increases. There are also lots of eddies which clog the flow channel and disturb the steam flow in the valve cavity after the valve plug and the outlet cavity. After modifying the structure, the numerical results show a better performance of steam flow.
基金Project was supported by the National Natural Science Foundation of China(Grant No.51541112).
文摘A comprehensive protective structure with rigidity and flexibility was put forward and designed in view of the quality and safety problems for the double vertical explosive welding of large titanium/steel cladding plate.The movement speed and displacement of the protective structure was calculated by establishing its physics model.The dynamics and stabilization properties were analyzed,and the protective structure parameters were optimized and devised.The comprehensive protective structure,which is composed of rigidity unit and flexibility wall,can bear the impact of detonation wave and the high-speed movement of the cladding plate.There are no damage and deformation in the protective structure and the cladding plate.The protective structure can be used many times.The bonding rate of the Ti/steel plate obtained was nearly 100%,and there is no deformation,surface cracks,and big wave and micro-defects.Therefore,the protective problems of the double vertical explosive welding can be solved effectively by the protective structure.
文摘Monolithic catalysts for CO_(2) methanation have become an active research area for the industrial development of Power-to-Gas technology.In this study,we developed a facile and reproducible synthesis strategy for the preparation of structured NiFe catalysts on washcoated cordierite monoliths for CO_(2) methanation.The NiFe catalysts were derived from in-situ grown layered double hydroxides(LDHs)via urea hydrolysis.The influence of different washcoat materials,i.e.,alumina and silica colloidal suspensions on the formation of LDHs layer was investigated,together with the impact of total metal concentration.NiFe LDHs were precipitated on the exterior surface of cordierite washcoated with alumina,while it was found to deposit further inside the channel wall of monolith washcoated with silica due to different intrinsic properties of the colloidal solutions.On the other hand,the thickness of in-situ grown LDHs layers and the catalyst loading could be increased by high metal concentration.The best monolithic catalyst(COR-AluCC-0.5M)was robust,having a thin and well-adhered catalytic layer on the cordierite substrate.As a result,high methane yield was obtained from CO_(2) methanation at high flow rate on this structured NiFe catalysts.The monolithic catalysts appeared as promising structured catalysts for the development of industrial methanation reactor.
基金supported by the National Natural Science Foundation of China(Nos.11805101 and 11205089)the Jiangsu Engineering Technology Research Center of Environmental Cleaning Materials(No.KFK1504)the Environmental Protection Research Project of Jiangsu Province(No.JSZC-D2018-044).
文摘To further improve the removal ability of layered double hydroxide(LDH) for iodide(I^-) anions from wastewater, we prepared hierarchically porous Cu5Mg10Al5-LDH and used as a matrix for in suit growth of Cu/Cu2O on its surface, forming Cu/Cu2O-LDH, which was characterized and applied as an adsorbent.Results displayed high I^-saturation uptake capability(137.8 mg/g) of Cu/Cu2O-LDH compared with Cu5Mg10Al5-LDH(26.4 mg/g) even thermal activated LDH(76.1 mg/g).Thermodynamic analysis showed that the reaction between I^-anions and Cu/Cu2O-LDH is a spontaneous and exothermic.Uptake kinetics analysis exhibited that adsorption equilibrium can be reached after 265 min.Additionally, the adsorbent showed satisfactory selectivity in the presence of competitive anions(e.g., SO4^2-), and could achieve good adsorption performance in a wide pH range of 3–8.A cooperative adsorption mechanism was proposed on the basis of the following two aspects:(1) ion exchange between iodide and interlayer anions;(2) the adsorption performance of Cu, Cu(Ⅱ) and Cu2O for I^-.Meanwhile, the difference between the adsorption mechanism of Cu/Cu2O-LDH, Cu5Mg10Al5-LDH and Cu5Mg10Al5-CLDH adsorbents was also elaborated and verified.
基金Supported by the National Natural Science Foundation of China(No.21171025)the Natural Science Foundation of Liaoning Province,China(Nos.201102003 and 2009402007)
文摘A 1D supramolecular compound [dmbbbi]（1） and a 2D cobalt coordination polymer [Co（dmbbbi）（ox）] 2（2） [dmbbbi=1,1-（1,4-butanediyl）bis（5,6-dimethylbenzimidazole）,ox=oxalate],C48H52Co2N8O8,were obtained under hydrothermal conditions by tuning the molar ratio of the reactants.The crystal structure analysis reveals that in compound 1,the adjacent dmbbbi molecules connect with each other via hydrogen bonds to form a 1D supramolecular chain.In compound 2,two crystallographically independent Co2＋ ions show the same six-coordination mode.Each Co2＋ ion is coordinated by four oxygen atoms from two ox anions and two nitrogen atoms from two cis-dmbbbi ligands.The adjacent Co2＋ ions are bridged by ox anions to generate an infinite 1D zigzag chain,which is extended by pairs of dmbbbi ligands to form a 2D honeycomb-like（6,3） network.Moreover,the thermal stability and the electrochemical property of compound 2 were studied.
基金financially supported by the National Natural Science Foundation of China (20871115)Fujian Provincial Key Laboratory of Nanomaterials (NM10-06)
文摘Reaction of HgCl2 and double betaine ligands in water at about 80 ℃ yielded two new Hg（Ⅱ） complexes,[Hg（L1）Cl2]·H2O 1 and [Hg2（L2）Cl4]·3HgCl2 2（L1 = 1,3-bis（pyridinio-4-carboxylato）-propane,L2 = 1,4-bis（pyridinio-4-carboxylato）-1,4-dimenthylbenzene）.Their struc-tures have been characterized by single-crystal X-ray diffraction techniques.The structure of 1 contains 1-D chains,in which the adjacent Hg（Ⅱ） atoms are bridged by L1 ligands in a syn-syn bis-monodentate mode.The chains are further connected through face-to-face π-π stacking interactions between pyridine rings to generate an infinite double-chain network.In 2,two Hg（Ⅱ） atoms are joined by L2 ligands in the same coordination mode as 1 to form an isolated dinuclear structure.The thermal stabilities of both complexes have also been investigated.
基金supported by the National Natural Science Foundation of China(Nos.21672053 and 21672054)Innovation Scientists and Technicians Troop Construction Projects of Henan Province(C20150011)。
文摘Both racemate and enantiomer of a novel double helix,binaphthylcyclooctaterthiophene(BN-COTh),which is a DNA-like molecule constructed by two single helices intertwined with each other via covalent bonds,have been synthesized with two building blocks,cycloocta-tetrathiophene(COTh) and cyclooctadinaphthyldithiophene(CONT) fused together via Negishi coupling reaction.Another homologue,dinaphthylcyclooctaterthiophene(DN-COTh) has been employed together as a model compound.Besides the synthetic work,BN-COTh and DN-COTh have been investigated by studying their crystal structures,spectroscopic behaviors,chiral resolution and chiral characteristics,including circular dichroism(CD) spectra and optical rotations.In addition,the novel crystal of enantiomer of(R,R,R)-BN-COTh has been explored.The enantiomer molecules packing along b-axis to form a larger and extended assembly packing due to intermolecular interactions between the enantiomer molecules and chloroform molecules in crystal.
基金projects of the National Natural Science Foundation of China(Grant Nos.40405007 , 40505009)the National Key Basic Research and Development Project of China(Grant No.2004CB418302) projects of Chinese Academy of Sciences (Nos.KZCX3-SW-225 and 2005r-2-16)
文摘The daily 1°× 1° data of the Aviation （AVN） model, the black body temperature （TBB） data of cloud top, and cloud images by geostationary meteorological satellite （GMS） are used to identify a dew-point front near the periphery of the western Pacific subtropical high （WPSH）. The results clearly demonstrate the existence of the dew-point front, and its thermodynamic and dynamic structural characteristics are analyzed in detail. The dew-point front is a transitional belt between the moist southwest monsoon flow and the dry adiabatic sinking flow near the WPSH, manifested by a large horizontal moisture gradient in the mid-lower troposphere and conjugated with the mei-yu front to form a predominant double-front structure associated with intense rainfall in the mei-yu period. The mei-yu front is located between 30° and 35°N, vertically extends from the ground level to the upper level and shifts northward. The dew-point front is to the south of the mei-yu front and lies up against the periphery of the WPSH. Generally, it is located between 850 hPa and 500 hPa. On the dew-point front side, the southwesterly prevails at the lower level and the northeasterly at the upper level; this wind distribution is different from that on the mei-yu front side. Vertical ascending motion exists between the two fronts, and there are descending motions on the north side of the mei^yu front and on the south side of the dew-point front~ which form a secondary circulation. The dynamics of the double fronts also have some interesting features. At the lower level, positive vertical vorticity and obvious convergence between the two fronts are clearly identified. At the mid-lower level, negative local change of the divergence （corresponding to increasing convergence） is often embedded in the two fronts or against the mei-yu front. Most cloud clusters occur between the two fronts and propagate down stream in a wave-like manner.
基金Supported by the National Natural Science Foundation of China(No.61105086)Self-Planned Task(SKLRS-2010-MS-12)of State Key Laboratory of Robotics and System(HIT)Hubei Province Natural Science Foundation(No.2010CDB03405)
文摘In order to solve the problem of using new nozzle is proposed in fire rescue robot. middle or low water pressure to form fine water mist, a Existing water mist nozzles are basically used for high pressure and in large size, complex structure and poor low pressure atomization effect in comparison with requirement of snake-like fire rescue robots. On the basis of comprehensive typical spray noz- zles, a direct spiral double helix converging nozzle （DSDHCN） is proposed, which has the advanta- ges of small volume, light weight, simple structure, and convenient installation. To make the spray nozzle have good performance, and meet the requirements of more efficient fire extinguishing, a nu- merical study is carried out to analyze the internal and external full flow field of nozzle. A gas-liquid two-phase flow is applied to simulate the external full flow field of nozzle with VOF model in fluent software. The simulation results show the real situation of water flow out of the atomization nozzle and the water jet trajectory. Some simulations about middle or low water pressure direct spiral double he- lix converging optimized nozzle have been done in 30bar pressure. The simulation results show that the optimized nozzle structure not only makes the spray droplets have a good cone angle, but also have a sufficient axial velocity,which proves the structure rationality of the proposed optimized nozzle.
