Scientists and engineers are looking forward to new manufacturing technologies to realize the integrated fabrication of macro shape and microstructure for the components with a short production chain, which can also s...Scientists and engineers are looking forward to new manufacturing technologies to realize the integrated fabrication of macro shape and microstructure for the components with a short production chain, which can also save materials and reduce energy consumption. Additive manufacturing (AM) technology is a new fabrication pattern with a character of a lay-by-lay material deposition. The components are fabricated in a bottom-up way, from points, lines, to layers and volume, which provided a capability to solve the impossible integrated fabrication problem for micro- and macro-structure by using conventional manufacturing technologies. Thus, based on integrated fabrication of micro- and macro- structures, research team in Xi’an Jiaotong University has been focusing on technological innovations and applications of advanced additive manufacturing technologies. Novel additive manufacturing principles have been proposed and explored, by which new AM processes and equipment for met- als, composites, ceramics, and biomaterials have been developed to support the industrial applications. Additive manufacturing and cutting-edge applications of advanced composite structure, metamaterials, bio-implants, and monocrystal alloy components have been investigated to push the new development of integrated fabrication of micro- and macro- structures.展开更多
The mechanical behavior of cohesive soil is sensitized to drying-wetting cycles under confinements.However,the hydromechanical coupling effect has not been considered in current constitutive models.A macro-micro analy...The mechanical behavior of cohesive soil is sensitized to drying-wetting cycles under confinements.However,the hydromechanical coupling effect has not been considered in current constitutive models.A macro-micro analysis scheme is proposed in this paper to investigate the soil deformation behavior under the coupling of stress and drying-wetting cycles.A new device is developed based on CT(computerized tomography)workstation to apply certain normal and shear stresses on a soil specimen during drying-wetting cycles.A series of tests are conducted on a type of loess with various coupling of stress paths and drying-wetting cycles.At macroscopic level,stress sensor and laser sensor are used to acquire stress and strain,respectively.The shear and volumetric strain increase during the first few drying-wetting cycles and then become stable.The increase of the shear stress level or confining pressure would cause higher increase rate and the value of shear strain in the process of drying-wetting cycles.At microscopic level,the grayscale value(GSV)of CT scanning image is characterized as the proportion of soil particles to voids.A fabric state parameter is proposed to characterize soil microstructures under the influence of stress and drying-wetting cycle.Test results indicate that the macroand micro-responses show high consistence and relevance.The stress and drying-wetting cycles would both induce collapse of the soil microstructure,which dominants degradation of the soil mechanical properties.The evolution of the macro-mechanical property of soil exhibits a positive linear relationship with the micro-evolution of the fabric state parameter.展开更多
Mine filling materials urgently need to improve mechanical properties and achieve low-carbon transformation.This study explores the mechanism of the synergistic effect of optimizing aggregate fractal grading and intro...Mine filling materials urgently need to improve mechanical properties and achieve low-carbon transformation.This study explores the mechanism of the synergistic effect of optimizing aggregate fractal grading and introducing CO_(2)nanobubble technology to improve the performance of cement-fly ash-based backfill materials(CFB).The properties including fluidity,setting time,uniaxial compressive strength,elastic modulus,porosity,microstructure and CO_(2)storage performance were systematically studied through methods such as fluidity evaluation,time test,uniaxial compression test,mercury intrusion porosimetry(MIP),scanning electron microscopy-energy dispersive spectroscopy analysis(SEM-EDS),and thermogravimetric-differential thermogravimetric analysis(TG-DTG).The experimental results show that the density and strength of the material are significantly improved under the synergistic effect of fractal dimension and CO_(2)nanobubbles.When the fractal dimension reaches 2.65,the mass ratio of coarse and fine aggregates reaches the optimal balance,and the structural density is greatly improved at the same time.At this time,the uniaxial compressive strength and elastic modulus reach their peak values,with increases of up to 13.46%and 27.47%,respectively.CO_(2)nanobubbles enhance the material properties by promoting hydration reaction and carbonization.At the microscopic level,CO_(2)nanobubble water promotes the formation of C-S-H(hydrated calcium silicate),C-A-S-H(hydrated calcium aluminium silicate)gel and CaCO_(3),which is the main way to enhance the performance.Thermogravimetric studies have shown that when the fractal dimension is 2.65,the dehydration of hydration products and the decarbonization process of CaCO_(3)are most obvious,and CO_(2)nanobubble water promotes the carbonization reaction,making it surpass the natural state.The CO_(2)sequestration quality of cement-fly ash-based materials treated with CO_(2)nanobubble water at different fractal dimensions increased by 12.4wt%to 99.8wt%.The results not only provide scientific insights for the design and implementation of low-carbon filling materials,but also provide a solid theoretical basis for strengthening green mining practices and promoting sustainable resource utilization.展开更多
Micro/nanoplastics(M/NPs)have become pervasive environmental pollutants,posing significant risks to human health through various exposure routes,including ingestion,inhalation,and direct contact.This review systematic...Micro/nanoplastics(M/NPs)have become pervasive environmental pollutants,posing significant risks to human health through various exposure routes,including ingestion,inhalation,and direct contact.This review systematically examined the potential impacts of M/NPs on ocular health,focusing on exposure pathways,toxicological mechanisms,and resultant damage to the eye.Ocular exposure to M/NPs can occur via direct contact and oral ingestion,with the latter potentially leading to the penetration of particles through ocular biological barriers into ocular tissues.The review highlighted that M/NPs can induce adverse effects on the ocular surface,elevate intraocular pressure,and cause abnormalities in the vitreous and retina.Mechanistically,oxidative stress and inflammation are central to M/NP-induced ocular damage,with smaller particles often exhibiting greater toxicity.Overall,this review underscored the potential risks of M/NPs to ocular health and emphasized the need for further research to elucidate exposure mechanisms,toxicological pathways,and mitigation strategies.展开更多
Micro silicon(mSi)is a promising anode candidate for all-solid-state batteries due to its high specific capacity,low side reactions,and high tap density.However,silicon suffers from its poor electronic and ionic condu...Micro silicon(mSi)is a promising anode candidate for all-solid-state batteries due to its high specific capacity,low side reactions,and high tap density.However,silicon suffers from its poor electronic and ionic conductivity,which is particularly severe on a micro scale and in solid-state systems,leading to increased polarization and inferior electrochemical performance.Doping can broaden the transmission pathways and reduce the diffusion energy barrier for electrons and lithium ions.However,achieving effective,uniform doping in mSi is challenging due to its longer diffusion paths and higher energy barriers.Therefore,current doping research is primarily limited to nanosilicon.In this study,we successfully used a Joule-heating activated staged thermal treatment to achieve full-depth doping of germanium(Ge)in the mSi substrate.The Joule-heating process activated the mSi substrate,resulting in abundant vacancy defects that reduced the diffusion barrier of Ge into the silicon lattice and facilitated full-depth Ge doping.Surprisingly,the resulting Si-Ge anode exhibited significantly enhanced electrical conductivity(70 times).Meanwhile,the improved Li-ion conductivity in mSi and the reduced Young’s modulus enhance the electrode reaction kinetics and integrity after cycling.Ge-doped silicon anodes demonstrate excellent electrochemical performance when applied in sulfide solid-state half-cells and full-cells.This work provides substantial insights into the rational structural design of mSi alloyed anode materials,paving the way for the development of high-performance solid-state Li-ion batteries.展开更多
Extreme cold weather seriously harms human thermoregulatory system,necessitating high-performance insulating garments to maintain body temperature.However,as the core insulating layer,advanced fibrous materials always...Extreme cold weather seriously harms human thermoregulatory system,necessitating high-performance insulating garments to maintain body temperature.However,as the core insulating layer,advanced fibrous materials always struggle to balance mechanical properties and thermal insulation,resulting in their inability to meet the demands for both washing resistance and personal protection.Herein,inspired by the natural spring-like structures of cucumber tendrils,a superelastic and washable micro/nanofibrous sponge(MNFS)based on biomimetic helical fibers is directly prepared utilizing multiple-jet electrospinning technology for high-performance thermal insulation.By regulating the conductivity of polyvinylidene fluoride solution,multiple-jet ejection and multiple-stage whipping of jets are achieved,and further control of phase separation rates enables the rapid solidification of jets to form spring-like helical fibers,which are directly entangled to assemble MNFS.The resulting MNFS exhibits superelasticity that can withstand large tensile strain(200%),1000 cyclic tensile or compression deformations,and retain good resilience even in liquid nitrogen(-196℃).Furthermore,the MNFS shows efficient thermal insulation with low thermal conductivity(24.85 mW m^(-1)K^(-1)),close to the value of dry air,and remains structural stability even after cyclic washing.This work offers new possibilities for advanced fibrous sponges in transportation,environmental,and energy applications.展开更多
Strategically coupling nanoparticle hybrids and internal thermosensitive molecular switches establishes an innovative paradigm for constructing micro/nanoscale-reconfigurable robots,facilitating energyefficient CO_(2)...Strategically coupling nanoparticle hybrids and internal thermosensitive molecular switches establishes an innovative paradigm for constructing micro/nanoscale-reconfigurable robots,facilitating energyefficient CO_(2) management in life-support systems of confined space.Here,a micro/nano-reconfigurable robot is constructed from the CO_(2) molecular hunters,temperature-sensitive molecular switch,solar photothermal conversion,and magnetically-driven function engines.The molecular hunters within the molecular extension state can capture 6.19 mmol g^(−1) of CO_(2) to form carbamic acid and ammonium bicarbonate.Interestingly,the molecular switch of the robot activates a molecular curling state that facilitates CO_(2) release through nano-reconfiguration,which is mediated by the temperature-sensitive curling of Pluronic F127 molecular chains during the photothermal desorption.Nano-reconfiguration of robot alters the amino microenvironment,including increasing surface electrostatic potential of the amino group and decreasing overall lowest unoccupied molecular orbital energy level.This weakened the nucleophilic attack ability of the amino group toward the adsorption product derivatives,thereby inhibiting the side reactions that generate hard-to-decompose urea structures,achieving the lowest regeneration temperature of 55℃ reported to date.The engine of the robot possesses non-contact magnetically-driven micro-reconfiguration capability to achieve efficient photothermal regeneration while avoiding local overheating.Notably,the robot successfully prolonged the survival time of mice in the sealed container by up to 54.61%,effectively addressing the issue of carbon suffocation in confined spaces.This work significantly enhances life-support systems for deep-space exploration,while stimulating innovations in sustainable carbon management technologies for terrestrial extreme environments.展开更多
Modern power systems increasingly depend on interconnected microgrids to enhance reliability and renewable energy utilization.However,the high penetration of intermittent renewable sources often causes frequency devia...Modern power systems increasingly depend on interconnected microgrids to enhance reliability and renewable energy utilization.However,the high penetration of intermittent renewable sources often causes frequency deviations,voltage fluctuations,and poor reactive power coordination,posing serious challenges to grid stability.Conventional Interconnection FlowControllers(IFCs)primarily regulate active power flowand fail to effectively handle dynamic frequency variations or reactive power sharing in multi-microgrid networks.To overcome these limitations,this study proposes an enhanced Interconnection Flow Controller(e-IFC)that integrates frequency response balancing and an Interconnection Reactive Power Flow Controller(IRFC)within a unified adaptive control structure.The proposed e-IFC is implemented and analyzed in DIgSILENT PowerFactory to evaluate its performance under various grid disturbances,including frequency drops,load changes,and reactive power fluctuations.Simulation results reveal that the e-IFC achieves 27.4% higher active power sharing accuracy,19.6% lower reactive power deviation,and 18.2% improved frequency stability compared to the conventional IFC.The adaptive controller ensures seamless transitions between grid-connected and islanded modes and maintains stable operation even under communication delays and data noise.Overall,the proposed e-IFCsignificantly enhances active-reactive power coordination and dynamic stability in renewable-integrated multi-microgrid systems.Future research will focus on coupling the e-IFC with tertiary-level optimization frameworks and conducting hardware-in-the-loop validation to enable its application in large-scale smart microgrid environments.展开更多
This article presents a micro-macro unified model for predicting the deformation of metal matrix composites （MMCs）. A macro-scale model is developed to obtain the proper boundary conditions for the micro-scale model...This article presents a micro-macro unified model for predicting the deformation of metal matrix composites （MMCs）. A macro-scale model is developed to obtain the proper boundary conditions for the micro-scale model, which is used to assess the microstructural deformation of materials. The usage of the submodel technique in the analysis makes it possible to shed light on the stress and strain field at the microlevel. This is helpful to investigate the linkage between the microscopic and the macroscopic flow behavior of the composites. An iterative procedure is also proposed to find out the optimum parameters. The results show that the convergence can be attained after three iterations in computation. In order to demonstrate the reliability of mi- cro-macro unified model, results based on the continuum composite model are also investigated using the stress-strain relation of composite obtained from the iterations. By comparing the proposed unified model to the continuum composite model, it is clear that the former exhibits large plastic deformation in the case of little macroscopic deformation, and the stresses and strains obtained from the submodel are higher than those from the macroscopic deformation.展开更多
The experimental study on the macro and micro characteristics of the spray from a pressure swirl nozzle embraces the growth of surface unstable wave,disintegration process,spray angle,breakup length and so on.The e...The experimental study on the macro and micro characteristics of the spray from a pressure swirl nozzle embraces the growth of surface unstable wave,disintegration process,spray angle,breakup length and so on.The effects of injection pressure,nozzle geometry and liquid properties on these characteristics are also discussed.The results are helpful to understand the underlying physics of the pressure swirl nozzle and serve as the basis for the practical design,usage and improvement of the nozzle.展开更多
The load-bearing capacity of ductile composite structures comprised of periodic composites is studied by a combined micro/macromechanicai approach. Firstly, on the microscopic level, a representative volume element （...The load-bearing capacity of ductile composite structures comprised of periodic composites is studied by a combined micro/macromechanicai approach. Firstly, on the microscopic level, a representative volume element （RVE） is selected to reflect the microstructures of the composite materials and the constituents are assumed to be elastic perfectly-plastic. Based on the homogenization theory and the static limit theorem, an optimization formulation to directly calculate the macroscopic strength domain of the RVE is obtained. The finite element modeling of the static limit analysis is formulated as a nonlinear mathematical programming and solved by the sequential quadratic programming method, where the temperature parameter method is used to construct the self-stress field. Secondly, Hill＇s yield criterion is adopted to connect the micromechanicai and macromechanical analyses. And the limit loads of composite structures are worked out on the macroscopic scale. Finally, some examples and comparisons are shown.展开更多
When two contacting solid surfaces are tightly closed and invisible to the naked eye, the discontinuity is said to be microscopic regardless of whether its length is short or long. By this definition, it is not suffic...When two contacting solid surfaces are tightly closed and invisible to the naked eye, the discontinuity is said to be microscopic regardless of whether its length is short or long. By this definition, it is not sufficient to distinguish the difference between a micro- and macro-crack by using the length parameter. Microcracks in high strength metal alloys have been known to be sev- eral centimeters or longer. Considered in this work is a dual scale fatigue crack growth model where the main crack can be mi- cro or macro but there prevails an inherent microscopic tip region that is damaged depending on the irregularities of the micro- structure. This region is referred to as the ＂micro-tip＂ and can be simulated by a sharp wedge with different angles in addition to mixed boundary conditions. The combination is sufficient to model microscopic entities in the form of voids, inclusions, precipitations, interfaces, in addition to subgrain imperfections, or cluster of dislocations. This is accomplished by using the method of ＂singularity representation＂ such that closed form asymptotic solutions can be obtained for the development of fa- tigue crack growth rate relations with three parameters. They include： （1） the crack surface tightness o-＊ represented by Cro/Cr~ = 0.3-0.5 for short cracks in region I, and 0.1-0.2 for long cracks in region II, （2） the micro/macro material properties reflected by the shear modulus ratio/1＂ （=,L/micro/]-/macro varying between 2 and 5） and （3） the most sensitive parameter d＊ being the micro-tip characteristic length d＊ （=d/do） whose magnitude decreases in the direction of region I ---~II. The existing fatigue crack growth data for 2024-T3 and 7075-T6 aluminum sheets are used to reinterpret the two-parameter da/dN=C（AK）n relation where AK has now been re-derived for a microcrack with surfaces tightly in contact. The contact force will depend on the mean stress ~m or mean stress ratio R as the primary parameter and on the stress amplitude era as the secondary parameter.展开更多
This paper is based on three observations and independent thinking of the classroom teaching of the author’s colleagues.It attempts to examine how macro and micro contexts affect teaching and learning in the classroo...This paper is based on three observations and independent thinking of the classroom teaching of the author’s colleagues.It attempts to examine how macro and micro contexts affect teaching and learning in the classroom.The author focuses the discussion on three aspects:(i)the present EFL contextual setting in China;(ii)the influence of the evaluation system on both teachers and students;(iii)his own beliefs as a teacher.Finally,he comes to the implications that teachers should often reflect on their teaching by means of observing other teachers’teachings;In order to bring more effective teaching and learning to the class,Teachers should change their class from a teacher-centered one to a students-centered one.展开更多
A new unified macro- and micro-mechanics failure analysis method for composite structures was developed in order to take the effects of composite micro structure into consideration. In this method, the macro stress di...A new unified macro- and micro-mechanics failure analysis method for composite structures was developed in order to take the effects of composite micro structure into consideration. In this method, the macro stress distribution of composite structure was calculated by commercial finite element analysis software. According to the macro stress distribution, the damage point was searched and the micro-stress distribution was calculated by reformulated finite-volume direct averaging micromechanics （FVDAM）, which was a multi-scale finite element method for composite. The micro structure failure modes were estimated with the failure strength of constituents. A unidirectional composite plate with a circular hole in the center under two kinds of loads was analyzed with the traditional macro-mechanical failure analysis method and the unified macro- and micro-mechanics failure analysis method. The results obtained by the two methods are consistent, which show this new method＇s accuracy and efficiency.展开更多
An analysis of drill cores and well logs shows that the main micro-facies of the third member sand bodies of the Qingshankou Formation in Qian＇an are subaqueous distributary channel facies, sheet sand facies and suba...An analysis of drill cores and well logs shows that the main micro-facies of the third member sand bodies of the Qingshankou Formation in Qian＇an are subaqueous distributary channel facies, sheet sand facies and subaqueous fan facies （olistostrome）. Maps showing the distribution of these micro-facies together with inter-channel bay and prodelta mocro-facies are presented for different time-slices （lower, middle and upper parts of the Qingshankou Formation）. These maps reveal the instability and change of sediment transport in the Baokang sedimentary system during the depositional period. Sediment transport was from the west in the early stage, from the south in the middle stage and from the northwest in the late stage. Values of thickness, porosity and permeability of the sand bodies in the third member of the Qingshankou Formation show that they have low to medium porosity and low permeability, and are characterized by serious reservoir heterogeneity. The joints between micro-facies and subaqueous fan micro-facies are characterized by the highest heterogeneity, the sheet sand and distal sand bar subfacies come next, and the heterogeneity of the subaqueous distributary channel sand bodies is relatively weak.展开更多
文摘Scientists and engineers are looking forward to new manufacturing technologies to realize the integrated fabrication of macro shape and microstructure for the components with a short production chain, which can also save materials and reduce energy consumption. Additive manufacturing (AM) technology is a new fabrication pattern with a character of a lay-by-lay material deposition. The components are fabricated in a bottom-up way, from points, lines, to layers and volume, which provided a capability to solve the impossible integrated fabrication problem for micro- and macro-structure by using conventional manufacturing technologies. Thus, based on integrated fabrication of micro- and macro- structures, research team in Xi’an Jiaotong University has been focusing on technological innovations and applications of advanced additive manufacturing technologies. Novel additive manufacturing principles have been proposed and explored, by which new AM processes and equipment for met- als, composites, ceramics, and biomaterials have been developed to support the industrial applications. Additive manufacturing and cutting-edge applications of advanced composite structure, metamaterials, bio-implants, and monocrystal alloy components have been investigated to push the new development of integrated fabrication of micro- and macro- structures.
基金funded by National Key R&D Program of China(Grant No.2023YFC3007001)Beijing Natural Science Foundation(Grant No.8244053)China Postdoctoral Science Foundation(Grant No.2024M754065).
文摘The mechanical behavior of cohesive soil is sensitized to drying-wetting cycles under confinements.However,the hydromechanical coupling effect has not been considered in current constitutive models.A macro-micro analysis scheme is proposed in this paper to investigate the soil deformation behavior under the coupling of stress and drying-wetting cycles.A new device is developed based on CT(computerized tomography)workstation to apply certain normal and shear stresses on a soil specimen during drying-wetting cycles.A series of tests are conducted on a type of loess with various coupling of stress paths and drying-wetting cycles.At macroscopic level,stress sensor and laser sensor are used to acquire stress and strain,respectively.The shear and volumetric strain increase during the first few drying-wetting cycles and then become stable.The increase of the shear stress level or confining pressure would cause higher increase rate and the value of shear strain in the process of drying-wetting cycles.At microscopic level,the grayscale value(GSV)of CT scanning image is characterized as the proportion of soil particles to voids.A fabric state parameter is proposed to characterize soil microstructures under the influence of stress and drying-wetting cycle.Test results indicate that the macroand micro-responses show high consistence and relevance.The stress and drying-wetting cycles would both induce collapse of the soil microstructure,which dominants degradation of the soil mechanical properties.The evolution of the macro-mechanical property of soil exhibits a positive linear relationship with the micro-evolution of the fabric state parameter.
基金financially supported by the China Scholarship Council(CSC)。
文摘Mine filling materials urgently need to improve mechanical properties and achieve low-carbon transformation.This study explores the mechanism of the synergistic effect of optimizing aggregate fractal grading and introducing CO_(2)nanobubble technology to improve the performance of cement-fly ash-based backfill materials(CFB).The properties including fluidity,setting time,uniaxial compressive strength,elastic modulus,porosity,microstructure and CO_(2)storage performance were systematically studied through methods such as fluidity evaluation,time test,uniaxial compression test,mercury intrusion porosimetry(MIP),scanning electron microscopy-energy dispersive spectroscopy analysis(SEM-EDS),and thermogravimetric-differential thermogravimetric analysis(TG-DTG).The experimental results show that the density and strength of the material are significantly improved under the synergistic effect of fractal dimension and CO_(2)nanobubbles.When the fractal dimension reaches 2.65,the mass ratio of coarse and fine aggregates reaches the optimal balance,and the structural density is greatly improved at the same time.At this time,the uniaxial compressive strength and elastic modulus reach their peak values,with increases of up to 13.46%and 27.47%,respectively.CO_(2)nanobubbles enhance the material properties by promoting hydration reaction and carbonization.At the microscopic level,CO_(2)nanobubble water promotes the formation of C-S-H(hydrated calcium silicate),C-A-S-H(hydrated calcium aluminium silicate)gel and CaCO_(3),which is the main way to enhance the performance.Thermogravimetric studies have shown that when the fractal dimension is 2.65,the dehydration of hydration products and the decarbonization process of CaCO_(3)are most obvious,and CO_(2)nanobubble water promotes the carbonization reaction,making it surpass the natural state.The CO_(2)sequestration quality of cement-fly ash-based materials treated with CO_(2)nanobubble water at different fractal dimensions increased by 12.4wt%to 99.8wt%.The results not only provide scientific insights for the design and implementation of low-carbon filling materials,but also provide a solid theoretical basis for strengthening green mining practices and promoting sustainable resource utilization.
基金Supported by the Guangdong Provincial Natural Science Foundation(No.2114050001527).
文摘Micro/nanoplastics(M/NPs)have become pervasive environmental pollutants,posing significant risks to human health through various exposure routes,including ingestion,inhalation,and direct contact.This review systematically examined the potential impacts of M/NPs on ocular health,focusing on exposure pathways,toxicological mechanisms,and resultant damage to the eye.Ocular exposure to M/NPs can occur via direct contact and oral ingestion,with the latter potentially leading to the penetration of particles through ocular biological barriers into ocular tissues.The review highlighted that M/NPs can induce adverse effects on the ocular surface,elevate intraocular pressure,and cause abnormalities in the vitreous and retina.Mechanistically,oxidative stress and inflammation are central to M/NP-induced ocular damage,with smaller particles often exhibiting greater toxicity.Overall,this review underscored the potential risks of M/NPs to ocular health and emphasized the need for further research to elucidate exposure mechanisms,toxicological pathways,and mitigation strategies.
基金financially supported by the National Key Research and Development Program(2022YFE0127400)the National Natural Science Foundation of China(52172040,52202041,and U23B2077)+1 种基金Taishan Scholar Project of Shandong Province(tsqn202211086,ts202208832,tsqnz20221118)the Fundamental Research Funds for the Central Universities(23CX06055A).
文摘Micro silicon(mSi)is a promising anode candidate for all-solid-state batteries due to its high specific capacity,low side reactions,and high tap density.However,silicon suffers from its poor electronic and ionic conductivity,which is particularly severe on a micro scale and in solid-state systems,leading to increased polarization and inferior electrochemical performance.Doping can broaden the transmission pathways and reduce the diffusion energy barrier for electrons and lithium ions.However,achieving effective,uniform doping in mSi is challenging due to its longer diffusion paths and higher energy barriers.Therefore,current doping research is primarily limited to nanosilicon.In this study,we successfully used a Joule-heating activated staged thermal treatment to achieve full-depth doping of germanium(Ge)in the mSi substrate.The Joule-heating process activated the mSi substrate,resulting in abundant vacancy defects that reduced the diffusion barrier of Ge into the silicon lattice and facilitated full-depth Ge doping.Surprisingly,the resulting Si-Ge anode exhibited significantly enhanced electrical conductivity(70 times).Meanwhile,the improved Li-ion conductivity in mSi and the reduced Young’s modulus enhance the electrode reaction kinetics and integrity after cycling.Ge-doped silicon anodes demonstrate excellent electrochemical performance when applied in sulfide solid-state half-cells and full-cells.This work provides substantial insights into the rational structural design of mSi alloyed anode materials,paving the way for the development of high-performance solid-state Li-ion batteries.
基金supported by Young Elite Scientists Sponsorship Program by China Association for Science and Technology(No.2022QNRC001)the National Natural Science Foundation of China(No.52273053)the Chenguang Program of Shanghai Education Development Foundation and Shanghai Municipal Education Commission(No.21CGA41)。
文摘Extreme cold weather seriously harms human thermoregulatory system,necessitating high-performance insulating garments to maintain body temperature.However,as the core insulating layer,advanced fibrous materials always struggle to balance mechanical properties and thermal insulation,resulting in their inability to meet the demands for both washing resistance and personal protection.Herein,inspired by the natural spring-like structures of cucumber tendrils,a superelastic and washable micro/nanofibrous sponge(MNFS)based on biomimetic helical fibers is directly prepared utilizing multiple-jet electrospinning technology for high-performance thermal insulation.By regulating the conductivity of polyvinylidene fluoride solution,multiple-jet ejection and multiple-stage whipping of jets are achieved,and further control of phase separation rates enables the rapid solidification of jets to form spring-like helical fibers,which are directly entangled to assemble MNFS.The resulting MNFS exhibits superelasticity that can withstand large tensile strain(200%),1000 cyclic tensile or compression deformations,and retain good resilience even in liquid nitrogen(-196℃).Furthermore,the MNFS shows efficient thermal insulation with low thermal conductivity(24.85 mW m^(-1)K^(-1)),close to the value of dry air,and remains structural stability even after cyclic washing.This work offers new possibilities for advanced fibrous sponges in transportation,environmental,and energy applications.
基金supported by the National Natural Science Foundation of China(22168008,22378085)the Guangxi Natural Science Foundation(2024GXNSFDA010053)+1 种基金the Technology Development Project of Guangxi Bossco Environmental Protection Technology Co.,Ltd(202100039)Innovation Project of Guangxi Graduate Education(YCBZ2024065).
文摘Strategically coupling nanoparticle hybrids and internal thermosensitive molecular switches establishes an innovative paradigm for constructing micro/nanoscale-reconfigurable robots,facilitating energyefficient CO_(2) management in life-support systems of confined space.Here,a micro/nano-reconfigurable robot is constructed from the CO_(2) molecular hunters,temperature-sensitive molecular switch,solar photothermal conversion,and magnetically-driven function engines.The molecular hunters within the molecular extension state can capture 6.19 mmol g^(−1) of CO_(2) to form carbamic acid and ammonium bicarbonate.Interestingly,the molecular switch of the robot activates a molecular curling state that facilitates CO_(2) release through nano-reconfiguration,which is mediated by the temperature-sensitive curling of Pluronic F127 molecular chains during the photothermal desorption.Nano-reconfiguration of robot alters the amino microenvironment,including increasing surface electrostatic potential of the amino group and decreasing overall lowest unoccupied molecular orbital energy level.This weakened the nucleophilic attack ability of the amino group toward the adsorption product derivatives,thereby inhibiting the side reactions that generate hard-to-decompose urea structures,achieving the lowest regeneration temperature of 55℃ reported to date.The engine of the robot possesses non-contact magnetically-driven micro-reconfiguration capability to achieve efficient photothermal regeneration while avoiding local overheating.Notably,the robot successfully prolonged the survival time of mice in the sealed container by up to 54.61%,effectively addressing the issue of carbon suffocation in confined spaces.This work significantly enhances life-support systems for deep-space exploration,while stimulating innovations in sustainable carbon management technologies for terrestrial extreme environments.
基金the Deanship of Scientific Research at Northern Border University,Arar,Saudi Arabia,for funding this research work through the project number“NBU-FFR-2025-3623-11”.
文摘Modern power systems increasingly depend on interconnected microgrids to enhance reliability and renewable energy utilization.However,the high penetration of intermittent renewable sources often causes frequency deviations,voltage fluctuations,and poor reactive power coordination,posing serious challenges to grid stability.Conventional Interconnection FlowControllers(IFCs)primarily regulate active power flowand fail to effectively handle dynamic frequency variations or reactive power sharing in multi-microgrid networks.To overcome these limitations,this study proposes an enhanced Interconnection Flow Controller(e-IFC)that integrates frequency response balancing and an Interconnection Reactive Power Flow Controller(IRFC)within a unified adaptive control structure.The proposed e-IFC is implemented and analyzed in DIgSILENT PowerFactory to evaluate its performance under various grid disturbances,including frequency drops,load changes,and reactive power fluctuations.Simulation results reveal that the e-IFC achieves 27.4% higher active power sharing accuracy,19.6% lower reactive power deviation,and 18.2% improved frequency stability compared to the conventional IFC.The adaptive controller ensures seamless transitions between grid-connected and islanded modes and maintains stable operation even under communication delays and data noise.Overall,the proposed e-IFCsignificantly enhances active-reactive power coordination and dynamic stability in renewable-integrated multi-microgrid systems.Future research will focus on coupling the e-IFC with tertiary-level optimization frameworks and conducting hardware-in-the-loop validation to enable its application in large-scale smart microgrid environments.
基金Aeronautical Basic Science Foundation of China (03H53048)
文摘This article presents a micro-macro unified model for predicting the deformation of metal matrix composites （MMCs）. A macro-scale model is developed to obtain the proper boundary conditions for the micro-scale model, which is used to assess the microstructural deformation of materials. The usage of the submodel technique in the analysis makes it possible to shed light on the stress and strain field at the microlevel. This is helpful to investigate the linkage between the microscopic and the macroscopic flow behavior of the composites. An iterative procedure is also proposed to find out the optimum parameters. The results show that the convergence can be attained after three iterations in computation. In order to demonstrate the reliability of mi- cro-macro unified model, results based on the continuum composite model are also investigated using the stress-strain relation of composite obtained from the iterations. By comparing the proposed unified model to the continuum composite model, it is clear that the former exhibits large plastic deformation in the case of little macroscopic deformation, and the stresses and strains obtained from the submodel are higher than those from the macroscopic deformation.
文摘The experimental study on the macro and micro characteristics of the spray from a pressure swirl nozzle embraces the growth of surface unstable wave,disintegration process,spray angle,breakup length and so on.The effects of injection pressure,nozzle geometry and liquid properties on these characteristics are also discussed.The results are helpful to understand the underlying physics of the pressure swirl nozzle and serve as the basis for the practical design,usage and improvement of the nozzle.
基金supported by the National Natural Science Foundation of China (No.50809003)the National Foundation for Excellent Doctorial Dissertation of China (200025).
文摘The load-bearing capacity of ductile composite structures comprised of periodic composites is studied by a combined micro/macromechanicai approach. Firstly, on the microscopic level, a representative volume element （RVE） is selected to reflect the microstructures of the composite materials and the constituents are assumed to be elastic perfectly-plastic. Based on the homogenization theory and the static limit theorem, an optimization formulation to directly calculate the macroscopic strength domain of the RVE is obtained. The finite element modeling of the static limit analysis is formulated as a nonlinear mathematical programming and solved by the sequential quadratic programming method, where the temperature parameter method is used to construct the self-stress field. Secondly, Hill＇s yield criterion is adopted to connect the micromechanicai and macromechanical analyses. And the limit loads of composite structures are worked out on the macroscopic scale. Finally, some examples and comparisons are shown.
文摘When two contacting solid surfaces are tightly closed and invisible to the naked eye, the discontinuity is said to be microscopic regardless of whether its length is short or long. By this definition, it is not sufficient to distinguish the difference between a micro- and macro-crack by using the length parameter. Microcracks in high strength metal alloys have been known to be sev- eral centimeters or longer. Considered in this work is a dual scale fatigue crack growth model where the main crack can be mi- cro or macro but there prevails an inherent microscopic tip region that is damaged depending on the irregularities of the micro- structure. This region is referred to as the ＂micro-tip＂ and can be simulated by a sharp wedge with different angles in addition to mixed boundary conditions. The combination is sufficient to model microscopic entities in the form of voids, inclusions, precipitations, interfaces, in addition to subgrain imperfections, or cluster of dislocations. This is accomplished by using the method of ＂singularity representation＂ such that closed form asymptotic solutions can be obtained for the development of fa- tigue crack growth rate relations with three parameters. They include： （1） the crack surface tightness o-＊ represented by Cro/Cr~ = 0.3-0.5 for short cracks in region I, and 0.1-0.2 for long cracks in region II, （2） the micro/macro material properties reflected by the shear modulus ratio/1＂ （=,L/micro/]-/macro varying between 2 and 5） and （3） the most sensitive parameter d＊ being the micro-tip characteristic length d＊ （=d/do） whose magnitude decreases in the direction of region I ---~II. The existing fatigue crack growth data for 2024-T3 and 7075-T6 aluminum sheets are used to reinterpret the two-parameter da/dN=C（AK）n relation where AK has now been re-derived for a microcrack with surfaces tightly in contact. The contact force will depend on the mean stress ~m or mean stress ratio R as the primary parameter and on the stress amplitude era as the secondary parameter.
文摘This paper is based on three observations and independent thinking of the classroom teaching of the author’s colleagues.It attempts to examine how macro and micro contexts affect teaching and learning in the classroom.The author focuses the discussion on three aspects:(i)the present EFL contextual setting in China;(ii)the influence of the evaluation system on both teachers and students;(iii)his own beliefs as a teacher.Finally,he comes to the implications that teachers should often reflect on their teaching by means of observing other teachers’teachings;In order to bring more effective teaching and learning to the class,Teachers should change their class from a teacher-centered one to a students-centered one.
基金co-supported by National Basic Research Program of China, National Natural Science Foundation of China(No. 51075204)Aeronautical Science Foundation of China (No.2009ZB52028, No. 2012ZB52026)+1 种基金Research Fund for the Doctoral Program of Higher Education of China (No. 20070287039)NUAA Research Funding (No. NZ2012106)
文摘A new unified macro- and micro-mechanics failure analysis method for composite structures was developed in order to take the effects of composite micro structure into consideration. In this method, the macro stress distribution of composite structure was calculated by commercial finite element analysis software. According to the macro stress distribution, the damage point was searched and the micro-stress distribution was calculated by reformulated finite-volume direct averaging micromechanics （FVDAM）, which was a multi-scale finite element method for composite. The micro structure failure modes were estimated with the failure strength of constituents. A unidirectional composite plate with a circular hole in the center under two kinds of loads was analyzed with the traditional macro-mechanical failure analysis method and the unified macro- and micro-mechanics failure analysis method. The results obtained by the two methods are consistent, which show this new method＇s accuracy and efficiency.
文摘An analysis of drill cores and well logs shows that the main micro-facies of the third member sand bodies of the Qingshankou Formation in Qian＇an are subaqueous distributary channel facies, sheet sand facies and subaqueous fan facies （olistostrome）. Maps showing the distribution of these micro-facies together with inter-channel bay and prodelta mocro-facies are presented for different time-slices （lower, middle and upper parts of the Qingshankou Formation）. These maps reveal the instability and change of sediment transport in the Baokang sedimentary system during the depositional period. Sediment transport was from the west in the early stage, from the south in the middle stage and from the northwest in the late stage. Values of thickness, porosity and permeability of the sand bodies in the third member of the Qingshankou Formation show that they have low to medium porosity and low permeability, and are characterized by serious reservoir heterogeneity. The joints between micro-facies and subaqueous fan micro-facies are characterized by the highest heterogeneity, the sheet sand and distal sand bar subfacies come next, and the heterogeneity of the subaqueous distributary channel sand bodies is relatively weak.
