Wing design is a critical factor in the aerodynamic performance of flapping-wing(FW)robots.Inspired by the natural wing structures of insects,bats,and birds,we explored how bio-mimetic wing vein morphologies,combined ...Wing design is a critical factor in the aerodynamic performance of flapping-wing(FW)robots.Inspired by the natural wing structures of insects,bats,and birds,we explored how bio-mimetic wing vein morphologies,combined with a bio-inspired double wing clap-and-fling mechanism,affect thrust generation.This study focused on increasing vertical force and payload capacity.Through systematic experimentation with various vein configurations and structural designs,we developed innovative wings optimized for thrust production.Comprehensive tests were conducted to measure aerodynamic forces,power consumption,and wing kinematics across a range of flapping frequencies.Additionally,wings with different aspect ratios,a key factor in wing design,were fabricated and extensively evaluated.The study also examined the role of bio-inspired vein layouts on wing flexibility,a critical component in improving flight efficiency.Our findings demonstrate that the newly developed wing design led to a 20%increase in thrust,achieving up to 30 g-force(gf).This research sheds light on the clap-and-fling effect and establishes a promising framework for bio-inspired wing design,offering significant improvements in both performance and payload capacity for FW robots.展开更多
Micro aerial vehicles(MAVs)have flexibility and maneuverability,which can offer vast potential for applications in both civilian and military domains.Compared to Fixed-wing/Rotor-wing MAVs,Flapping Wing Micro Robots(F...Micro aerial vehicles(MAVs)have flexibility and maneuverability,which can offer vast potential for applications in both civilian and military domains.Compared to Fixed-wing/Rotor-wing MAVs,Flapping Wing Micro Robots(FWMRs)have garnered widespread attention among scientists due to their superior miniaturized aerodynamic theory,reduced noise,and enhanced resistance to disturbances in complex and diverse environments.Flying insects,it not only has remarkable flapping flight ability(wings),but also takeoff and landing habitat ability(legs).If the various functions of flying insects can be imitated,efficient biomimetic FWMRs can be produced.This paper provides a review of the flight kinematics,aerodynamics,and wing structural parameters of insects.Then,the traditional wings and folding wings of insect-inspired FWMRs were compared.The research progress in takeoff and landing of FWMRs was also summarized,and the future developments and challenges for insect-inspired FWMRs were discussed.展开更多
Flapping-Wing Micro Air Vehicles(FMAVs)are compact and agile,capable of accessing narrow spaces that conventional vehicles struggle to reach,such as ruins,caves,or the interiors of complex structures,making them ideal...Flapping-Wing Micro Air Vehicles(FMAVs)are compact and agile,capable of accessing narrow spaces that conventional vehicles struggle to reach,such as ruins,caves,or the interiors of complex structures,making them ideal tools for reconnaissance and rescue missions.1 However,the operation of FMAVs relies on coordinating multiple forces with different scaling effects,posing challenges to miniaturization design.展开更多
This paper studies the trajectory tracking problem of flapping-wing micro aerial vehicles(FWMAVs)in the longitudinal plane.First of all,the kinematics and dynamics of the FWMAV are established,wherein the aerodynamic ...This paper studies the trajectory tracking problem of flapping-wing micro aerial vehicles(FWMAVs)in the longitudinal plane.First of all,the kinematics and dynamics of the FWMAV are established,wherein the aerodynamic force and torque generated by flapping wings and the tail wing are explicitly formulated with respect to the flapping frequency of the wings and the degree of tail wing inclination.To achieve autonomous tracking,an adaptive control scheme is proposed under the hierarchical framework.Specifically,a bounded position controller with hyperbolic tangent functions is designed to produce the desired aerodynamic force,and a pitch command is extracted from the designed position controller.Next,an adaptive attitude controller is designed to track the extracted pitch command,where a radial basis function neural network is introduced to approximate the unknown aerodynamic perturbation torque.Finally,the flapping frequency of the wings and the degree of tail wing inclination are calculated from the designed position and attitude controllers,respectively.In terms of Lyapunov's direct method,it is shown that the tracking errors are bounded and ultimately converge to a small neighborhood around the origin.Simulations are carried out to verify the effectiveness of the proposed control scheme.展开更多
Topology optimization is an effective method to obtain a lightweight structure that meets the requirements of structural strength.Whether the optimization results meet the actual needs mainly depends on the accuracy o...Topology optimization is an effective method to obtain a lightweight structure that meets the requirements of structural strength.Whether the optimization results meet the actual needs mainly depends on the accuracy of the material properties and the boundary conditions,especially for a tiny Flapping-wing Micro Aerial Vehicle(FMAV)transmission system manufactured by 3D printing.In this paper,experimental and numerical computation efforts were undertaken to gain a reliable topology optimization method for the bottom of the transmission system.First,the constitutive behavior of the ultraviolet(UV)curable resin used in fabrication was evaluated.Second,a numerical computation model describing further verified via experiments.Topology optimization modeling considering nonlinear factors,e.g.contact,friction and collision,was presented,and the optimization results were verified by both dynamic simulation and experiments.Finally,detailed discussions on different load cases and constraints were presented to clarify their effect on the optimization.Our methods and results presented in this paper may shed light on the lightweight design of a FMAV.展开更多
The problem of flapping motion control of Micro Air Vehicles (MAVs) with flapping wings was studied in this paper.Based upon the knowledge of skeletal and muscular components of hummingbird, a dynamic model for flappi...The problem of flapping motion control of Micro Air Vehicles (MAVs) with flapping wings was studied in this paper.Based upon the knowledge of skeletal and muscular components of hummingbird, a dynamic model for flapping wing wasdeveloped.A control scheme inspired by human memory and learning concept was constructed for wing motion control ofMAVs.The salient feature of the proposed control lies in its capabilities to improve the control performance by learning fromexperience and observation on its current and past behaviors, without the need for system dynamic information.Furthermore,the overall control scheme has a fairly simple structure and demands little online computations, making it attractive for real-timeimplementation on MAVs.Both theoretical analysis and computer simulation confirms its effectiveness.展开更多
Flapping-Wing Air Vehicles(FWAVs)have been developed to pursue the efficient,agile,and quiet flight of flying animals.However,unlike lightweight FWAVs capable of vertical takeoff,relatively heavy FWAVs face challenges...Flapping-Wing Air Vehicles(FWAVs)have been developed to pursue the efficient,agile,and quiet flight of flying animals.However,unlike lightweight FWAVs capable of vertical takeoff,relatively heavy FWAVs face challenges in self-takeoff,which refers to taking off without both external device and energy input.In this study,a cliff-drop method is implemented for an independent takeoff of a heavy FWAV,relying solely on gravity.In the takeoff process using the cliff-drop method,the FWAV moves on the ground to a cliff edge using a wheel-driving motor and then descends from the cliff to achieve the necessary speed for flight.To demonstrate the cliff-drop method,the KAIST Robotic Hawk(KRoHawk)with a mass of 740 g and a wingspan of 120 cm is developed.The takeoff tests demonstrate that the KRoHawk,significantly heavier than the vertical-takeoff capable FWAVs,can successfully take off using the gravity-assisted takeoff method.The scalability of cliff-drop method is analyzed through simulations.When drop constraints are absent,the wheel-driving motor mass fraction for cliff-drop method remains negligible even as the vehicle's weight increases.When drop constraints are set to 4 m,FWAVs heavier than KRoHawk,weighing up to 4.4 kg,can perform the cliff-drop takeoffs with a wheel-driving motor mass fraction of less than 8%.展开更多
Micro aerial platforms face significant challenges in achieving long controlled endurance as most of the energy is consumed to overcome the weight of the body.In this study,we present a controllable micro blimp that a...Micro aerial platforms face significant challenges in achieving long controlled endurance as most of the energy is consumed to overcome the weight of the body.In this study,we present a controllable micro blimp that addresses this issue through the use of a helium-filled balloon.The micro blimp has a long axis of 23 cm and is propelled by four insect-sized flapping-wing thrusters,each weighing 80 mg and with a wingspan of 3.5 cm.These distributed thrusters enable controlled motions and provide the micro blimp with an advantage in flight endurance compared to multirotors or flapping-wing micro aerial vehicles at the same size scale.To enhance the performance of the controlled flight,we propose a wireless control module that enables manipulation from a distance of up to 100 m.Additionally,a smartphone application is developed to send instructions to the circuit board,allowing the blimp to turn left and right,ascend and descend,and achieve a combination of these movements separately.Our findings demonstrate that this micro blimp is one of the smallest controlled self-powered micro blimps to date.展开更多
Micro/nanoplastics(M/NPs)have become pervasive environmental pollutants,posing significant risks to human health through various exposure routes,including ingestion,inhalation,and direct contact.This review systematic...Micro/nanoplastics(M/NPs)have become pervasive environmental pollutants,posing significant risks to human health through various exposure routes,including ingestion,inhalation,and direct contact.This review systematically examined the potential impacts of M/NPs on ocular health,focusing on exposure pathways,toxicological mechanisms,and resultant damage to the eye.Ocular exposure to M/NPs can occur via direct contact and oral ingestion,with the latter potentially leading to the penetration of particles through ocular biological barriers into ocular tissues.The review highlighted that M/NPs can induce adverse effects on the ocular surface,elevate intraocular pressure,and cause abnormalities in the vitreous and retina.Mechanistically,oxidative stress and inflammation are central to M/NP-induced ocular damage,with smaller particles often exhibiting greater toxicity.Overall,this review underscored the potential risks of M/NPs to ocular health and emphasized the need for further research to elucidate exposure mechanisms,toxicological pathways,and mitigation strategies.展开更多
Micro silicon(mSi)is a promising anode candidate for all-solid-state batteries due to its high specific capacity,low side reactions,and high tap density.However,silicon suffers from its poor electronic and ionic condu...Micro silicon(mSi)is a promising anode candidate for all-solid-state batteries due to its high specific capacity,low side reactions,and high tap density.However,silicon suffers from its poor electronic and ionic conductivity,which is particularly severe on a micro scale and in solid-state systems,leading to increased polarization and inferior electrochemical performance.Doping can broaden the transmission pathways and reduce the diffusion energy barrier for electrons and lithium ions.However,achieving effective,uniform doping in mSi is challenging due to its longer diffusion paths and higher energy barriers.Therefore,current doping research is primarily limited to nanosilicon.In this study,we successfully used a Joule-heating activated staged thermal treatment to achieve full-depth doping of germanium(Ge)in the mSi substrate.The Joule-heating process activated the mSi substrate,resulting in abundant vacancy defects that reduced the diffusion barrier of Ge into the silicon lattice and facilitated full-depth Ge doping.Surprisingly,the resulting Si-Ge anode exhibited significantly enhanced electrical conductivity(70 times).Meanwhile,the improved Li-ion conductivity in mSi and the reduced Young’s modulus enhance the electrode reaction kinetics and integrity after cycling.Ge-doped silicon anodes demonstrate excellent electrochemical performance when applied in sulfide solid-state half-cells and full-cells.This work provides substantial insights into the rational structural design of mSi alloyed anode materials,paving the way for the development of high-performance solid-state Li-ion batteries.展开更多
Extreme cold weather seriously harms human thermoregulatory system,necessitating high-performance insulating garments to maintain body temperature.However,as the core insulating layer,advanced fibrous materials always...Extreme cold weather seriously harms human thermoregulatory system,necessitating high-performance insulating garments to maintain body temperature.However,as the core insulating layer,advanced fibrous materials always struggle to balance mechanical properties and thermal insulation,resulting in their inability to meet the demands for both washing resistance and personal protection.Herein,inspired by the natural spring-like structures of cucumber tendrils,a superelastic and washable micro/nanofibrous sponge(MNFS)based on biomimetic helical fibers is directly prepared utilizing multiple-jet electrospinning technology for high-performance thermal insulation.By regulating the conductivity of polyvinylidene fluoride solution,multiple-jet ejection and multiple-stage whipping of jets are achieved,and further control of phase separation rates enables the rapid solidification of jets to form spring-like helical fibers,which are directly entangled to assemble MNFS.The resulting MNFS exhibits superelasticity that can withstand large tensile strain(200%),1000 cyclic tensile or compression deformations,and retain good resilience even in liquid nitrogen(-196℃).Furthermore,the MNFS shows efficient thermal insulation with low thermal conductivity(24.85 mW m^(-1)K^(-1)),close to the value of dry air,and remains structural stability even after cyclic washing.This work offers new possibilities for advanced fibrous sponges in transportation,environmental,and energy applications.展开更多
Strategically coupling nanoparticle hybrids and internal thermosensitive molecular switches establishes an innovative paradigm for constructing micro/nanoscale-reconfigurable robots,facilitating energyefficient CO_(2)...Strategically coupling nanoparticle hybrids and internal thermosensitive molecular switches establishes an innovative paradigm for constructing micro/nanoscale-reconfigurable robots,facilitating energyefficient CO_(2) management in life-support systems of confined space.Here,a micro/nano-reconfigurable robot is constructed from the CO_(2) molecular hunters,temperature-sensitive molecular switch,solar photothermal conversion,and magnetically-driven function engines.The molecular hunters within the molecular extension state can capture 6.19 mmol g^(−1) of CO_(2) to form carbamic acid and ammonium bicarbonate.Interestingly,the molecular switch of the robot activates a molecular curling state that facilitates CO_(2) release through nano-reconfiguration,which is mediated by the temperature-sensitive curling of Pluronic F127 molecular chains during the photothermal desorption.Nano-reconfiguration of robot alters the amino microenvironment,including increasing surface electrostatic potential of the amino group and decreasing overall lowest unoccupied molecular orbital energy level.This weakened the nucleophilic attack ability of the amino group toward the adsorption product derivatives,thereby inhibiting the side reactions that generate hard-to-decompose urea structures,achieving the lowest regeneration temperature of 55℃ reported to date.The engine of the robot possesses non-contact magnetically-driven micro-reconfiguration capability to achieve efficient photothermal regeneration while avoiding local overheating.Notably,the robot successfully prolonged the survival time of mice in the sealed container by up to 54.61%,effectively addressing the issue of carbon suffocation in confined spaces.This work significantly enhances life-support systems for deep-space exploration,while stimulating innovations in sustainable carbon management technologies for terrestrial extreme environments.展开更多
Mine filling materials urgently need to improve mechanical properties and achieve low-carbon transformation.This study explores the mechanism of the synergistic effect of optimizing aggregate fractal grading and intro...Mine filling materials urgently need to improve mechanical properties and achieve low-carbon transformation.This study explores the mechanism of the synergistic effect of optimizing aggregate fractal grading and introducing CO_(2)nanobubble technology to improve the performance of cement-fly ash-based backfill materials(CFB).The properties including fluidity,setting time,uniaxial compressive strength,elastic modulus,porosity,microstructure and CO_(2)storage performance were systematically studied through methods such as fluidity evaluation,time test,uniaxial compression test,mercury intrusion porosimetry(MIP),scanning electron microscopy-energy dispersive spectroscopy analysis(SEM-EDS),and thermogravimetric-differential thermogravimetric analysis(TG-DTG).The experimental results show that the density and strength of the material are significantly improved under the synergistic effect of fractal dimension and CO_(2)nanobubbles.When the fractal dimension reaches 2.65,the mass ratio of coarse and fine aggregates reaches the optimal balance,and the structural density is greatly improved at the same time.At this time,the uniaxial compressive strength and elastic modulus reach their peak values,with increases of up to 13.46%and 27.47%,respectively.CO_(2)nanobubbles enhance the material properties by promoting hydration reaction and carbonization.At the microscopic level,CO_(2)nanobubble water promotes the formation of C-S-H(hydrated calcium silicate),C-A-S-H(hydrated calcium aluminium silicate)gel and CaCO_(3),which is the main way to enhance the performance.Thermogravimetric studies have shown that when the fractal dimension is 2.65,the dehydration of hydration products and the decarbonization process of CaCO_(3)are most obvious,and CO_(2)nanobubble water promotes the carbonization reaction,making it surpass the natural state.The CO_(2)sequestration quality of cement-fly ash-based materials treated with CO_(2)nanobubble water at different fractal dimensions increased by 12.4wt%to 99.8wt%.The results not only provide scientific insights for the design and implementation of low-carbon filling materials,but also provide a solid theoretical basis for strengthening green mining practices and promoting sustainable resource utilization.展开更多
基金Nguyen Tat Thanh University,Ho Chi Minh City,Vietnam for supporting this study。
文摘Wing design is a critical factor in the aerodynamic performance of flapping-wing(FW)robots.Inspired by the natural wing structures of insects,bats,and birds,we explored how bio-mimetic wing vein morphologies,combined with a bio-inspired double wing clap-and-fling mechanism,affect thrust generation.This study focused on increasing vertical force and payload capacity.Through systematic experimentation with various vein configurations and structural designs,we developed innovative wings optimized for thrust production.Comprehensive tests were conducted to measure aerodynamic forces,power consumption,and wing kinematics across a range of flapping frequencies.Additionally,wings with different aspect ratios,a key factor in wing design,were fabricated and extensively evaluated.The study also examined the role of bio-inspired vein layouts on wing flexibility,a critical component in improving flight efficiency.Our findings demonstrate that the newly developed wing design led to a 20%increase in thrust,achieving up to 30 g-force(gf).This research sheds light on the clap-and-fling effect and establishes a promising framework for bio-inspired wing design,offering significant improvements in both performance and payload capacity for FW robots.
基金supported by the National Natural Science Foundation of China(grant numbers 52305321 and 62273246)The Natural Science Foundation of Jiangsu Province(BK20230496)+3 种基金China Postdoctoral Science Foundation Funded Project(2023M732536 and 2024T170630)Jiangsu Province Excellence Postdoctoral Program(2023ZB218)The National Key R&D Program of China(2022YFB4702202)The Jiangsu Provincial Key Technology R&D Program(BE2021009-02).
文摘Micro aerial vehicles(MAVs)have flexibility and maneuverability,which can offer vast potential for applications in both civilian and military domains.Compared to Fixed-wing/Rotor-wing MAVs,Flapping Wing Micro Robots(FWMRs)have garnered widespread attention among scientists due to their superior miniaturized aerodynamic theory,reduced noise,and enhanced resistance to disturbances in complex and diverse environments.Flying insects,it not only has remarkable flapping flight ability(wings),but also takeoff and landing habitat ability(legs).If the various functions of flying insects can be imitated,efficient biomimetic FWMRs can be produced.This paper provides a review of the flight kinematics,aerodynamics,and wing structural parameters of insects.Then,the traditional wings and folding wings of insect-inspired FWMRs were compared.The research progress in takeoff and landing of FWMRs was also summarized,and the future developments and challenges for insect-inspired FWMRs were discussed.
基金supported by the Scientific Research Innovation Capability Support Project for Young Faculty,China(No.ZYGXQNJSKYCXNLZCXM-D1)the National Natural Science Foundation of China(No.52272384).
文摘Flapping-Wing Micro Air Vehicles(FMAVs)are compact and agile,capable of accessing narrow spaces that conventional vehicles struggle to reach,such as ruins,caves,or the interiors of complex structures,making them ideal tools for reconnaissance and rescue missions.1 However,the operation of FMAVs relies on coordinating multiple forces with different scaling effects,posing challenges to miniaturization design.
基金supported in part by the National Natural Science Foundation of China(61933001,62061160371)Joint Funds of Equipment Pre-Research and Ministry of Education of China(6141A02033339)Beijing Top Discipline for Artificial Intelligent Science and Engineering,University of Science and Technology Beijing。
文摘This paper studies the trajectory tracking problem of flapping-wing micro aerial vehicles(FWMAVs)in the longitudinal plane.First of all,the kinematics and dynamics of the FWMAV are established,wherein the aerodynamic force and torque generated by flapping wings and the tail wing are explicitly formulated with respect to the flapping frequency of the wings and the degree of tail wing inclination.To achieve autonomous tracking,an adaptive control scheme is proposed under the hierarchical framework.Specifically,a bounded position controller with hyperbolic tangent functions is designed to produce the desired aerodynamic force,and a pitch command is extracted from the designed position controller.Next,an adaptive attitude controller is designed to track the extracted pitch command,where a radial basis function neural network is introduced to approximate the unknown aerodynamic perturbation torque.Finally,the flapping frequency of the wings and the degree of tail wing inclination are calculated from the designed position and attitude controllers,respectively.In terms of Lyapunov's direct method,it is shown that the tracking errors are bounded and ultimately converge to a small neighborhood around the origin.Simulations are carried out to verify the effectiveness of the proposed control scheme.
基金supported by the National Natural Science Foundation of China(No.11672022)。
文摘Topology optimization is an effective method to obtain a lightweight structure that meets the requirements of structural strength.Whether the optimization results meet the actual needs mainly depends on the accuracy of the material properties and the boundary conditions,especially for a tiny Flapping-wing Micro Aerial Vehicle(FMAV)transmission system manufactured by 3D printing.In this paper,experimental and numerical computation efforts were undertaken to gain a reliable topology optimization method for the bottom of the transmission system.First,the constitutive behavior of the ultraviolet(UV)curable resin used in fabrication was evaluated.Second,a numerical computation model describing further verified via experiments.Topology optimization modeling considering nonlinear factors,e.g.contact,friction and collision,was presented,and the optimization results were verified by both dynamic simulation and experiments.Finally,detailed discussions on different load cases and constraints were presented to clarify their effect on the optimization.Our methods and results presented in this paper may shed light on the lightweight design of a FMAV.
文摘The problem of flapping motion control of Micro Air Vehicles (MAVs) with flapping wings was studied in this paper.Based upon the knowledge of skeletal and muscular components of hummingbird, a dynamic model for flapping wing wasdeveloped.A control scheme inspired by human memory and learning concept was constructed for wing motion control ofMAVs.The salient feature of the proposed control lies in its capabilities to improve the control performance by learning fromexperience and observation on its current and past behaviors, without the need for system dynamic information.Furthermore,the overall control scheme has a fairly simple structure and demands little online computations, making it attractive for real-timeimplementation on MAVs.Both theoretical analysis and computer simulation confirms its effectiveness.
基金supported by Unmanned Vehicles Core Technology Research and Development Program through the National Research Foundation of Korea(NRF)Unmanned Vehicle Advanced Research Center(UVARC)funded by the Ministry of Science and ICT,the Republic of Korea(2020M3C1C1A01083415).
文摘Flapping-Wing Air Vehicles(FWAVs)have been developed to pursue the efficient,agile,and quiet flight of flying animals.However,unlike lightweight FWAVs capable of vertical takeoff,relatively heavy FWAVs face challenges in self-takeoff,which refers to taking off without both external device and energy input.In this study,a cliff-drop method is implemented for an independent takeoff of a heavy FWAV,relying solely on gravity.In the takeoff process using the cliff-drop method,the FWAV moves on the ground to a cliff edge using a wheel-driving motor and then descends from the cliff to achieve the necessary speed for flight.To demonstrate the cliff-drop method,the KAIST Robotic Hawk(KRoHawk)with a mass of 740 g and a wingspan of 120 cm is developed.The takeoff tests demonstrate that the KRoHawk,significantly heavier than the vertical-takeoff capable FWAVs,can successfully take off using the gravity-assisted takeoff method.The scalability of cliff-drop method is analyzed through simulations.When drop constraints are absent,the wheel-driving motor mass fraction for cliff-drop method remains negligible even as the vehicle's weight increases.When drop constraints are set to 4 m,FWAVs heavier than KRoHawk,weighing up to 4.4 kg,can perform the cliff-drop takeoffs with a wheel-driving motor mass fraction of less than 8%.
基金co-supported by the Beijing Natural Science Foundation,China(No.3232010)the National Natural Science Foundation of China(No.12002017)the Ministry of Education of the People’s Republic of China 111 Project(No.B08009).
文摘Micro aerial platforms face significant challenges in achieving long controlled endurance as most of the energy is consumed to overcome the weight of the body.In this study,we present a controllable micro blimp that addresses this issue through the use of a helium-filled balloon.The micro blimp has a long axis of 23 cm and is propelled by four insect-sized flapping-wing thrusters,each weighing 80 mg and with a wingspan of 3.5 cm.These distributed thrusters enable controlled motions and provide the micro blimp with an advantage in flight endurance compared to multirotors or flapping-wing micro aerial vehicles at the same size scale.To enhance the performance of the controlled flight,we propose a wireless control module that enables manipulation from a distance of up to 100 m.Additionally,a smartphone application is developed to send instructions to the circuit board,allowing the blimp to turn left and right,ascend and descend,and achieve a combination of these movements separately.Our findings demonstrate that this micro blimp is one of the smallest controlled self-powered micro blimps to date.
基金Supported by the Guangdong Provincial Natural Science Foundation(No.2114050001527).
文摘Micro/nanoplastics(M/NPs)have become pervasive environmental pollutants,posing significant risks to human health through various exposure routes,including ingestion,inhalation,and direct contact.This review systematically examined the potential impacts of M/NPs on ocular health,focusing on exposure pathways,toxicological mechanisms,and resultant damage to the eye.Ocular exposure to M/NPs can occur via direct contact and oral ingestion,with the latter potentially leading to the penetration of particles through ocular biological barriers into ocular tissues.The review highlighted that M/NPs can induce adverse effects on the ocular surface,elevate intraocular pressure,and cause abnormalities in the vitreous and retina.Mechanistically,oxidative stress and inflammation are central to M/NP-induced ocular damage,with smaller particles often exhibiting greater toxicity.Overall,this review underscored the potential risks of M/NPs to ocular health and emphasized the need for further research to elucidate exposure mechanisms,toxicological pathways,and mitigation strategies.
基金financially supported by the National Key Research and Development Program(2022YFE0127400)the National Natural Science Foundation of China(52172040,52202041,and U23B2077)+1 种基金Taishan Scholar Project of Shandong Province(tsqn202211086,ts202208832,tsqnz20221118)the Fundamental Research Funds for the Central Universities(23CX06055A).
文摘Micro silicon(mSi)is a promising anode candidate for all-solid-state batteries due to its high specific capacity,low side reactions,and high tap density.However,silicon suffers from its poor electronic and ionic conductivity,which is particularly severe on a micro scale and in solid-state systems,leading to increased polarization and inferior electrochemical performance.Doping can broaden the transmission pathways and reduce the diffusion energy barrier for electrons and lithium ions.However,achieving effective,uniform doping in mSi is challenging due to its longer diffusion paths and higher energy barriers.Therefore,current doping research is primarily limited to nanosilicon.In this study,we successfully used a Joule-heating activated staged thermal treatment to achieve full-depth doping of germanium(Ge)in the mSi substrate.The Joule-heating process activated the mSi substrate,resulting in abundant vacancy defects that reduced the diffusion barrier of Ge into the silicon lattice and facilitated full-depth Ge doping.Surprisingly,the resulting Si-Ge anode exhibited significantly enhanced electrical conductivity(70 times).Meanwhile,the improved Li-ion conductivity in mSi and the reduced Young’s modulus enhance the electrode reaction kinetics and integrity after cycling.Ge-doped silicon anodes demonstrate excellent electrochemical performance when applied in sulfide solid-state half-cells and full-cells.This work provides substantial insights into the rational structural design of mSi alloyed anode materials,paving the way for the development of high-performance solid-state Li-ion batteries.
基金supported by Young Elite Scientists Sponsorship Program by China Association for Science and Technology(No.2022QNRC001)the National Natural Science Foundation of China(No.52273053)the Chenguang Program of Shanghai Education Development Foundation and Shanghai Municipal Education Commission(No.21CGA41)。
文摘Extreme cold weather seriously harms human thermoregulatory system,necessitating high-performance insulating garments to maintain body temperature.However,as the core insulating layer,advanced fibrous materials always struggle to balance mechanical properties and thermal insulation,resulting in their inability to meet the demands for both washing resistance and personal protection.Herein,inspired by the natural spring-like structures of cucumber tendrils,a superelastic and washable micro/nanofibrous sponge(MNFS)based on biomimetic helical fibers is directly prepared utilizing multiple-jet electrospinning technology for high-performance thermal insulation.By regulating the conductivity of polyvinylidene fluoride solution,multiple-jet ejection and multiple-stage whipping of jets are achieved,and further control of phase separation rates enables the rapid solidification of jets to form spring-like helical fibers,which are directly entangled to assemble MNFS.The resulting MNFS exhibits superelasticity that can withstand large tensile strain(200%),1000 cyclic tensile or compression deformations,and retain good resilience even in liquid nitrogen(-196℃).Furthermore,the MNFS shows efficient thermal insulation with low thermal conductivity(24.85 mW m^(-1)K^(-1)),close to the value of dry air,and remains structural stability even after cyclic washing.This work offers new possibilities for advanced fibrous sponges in transportation,environmental,and energy applications.
基金supported by the National Natural Science Foundation of China(22168008,22378085)the Guangxi Natural Science Foundation(2024GXNSFDA010053)+1 种基金the Technology Development Project of Guangxi Bossco Environmental Protection Technology Co.,Ltd(202100039)Innovation Project of Guangxi Graduate Education(YCBZ2024065).
文摘Strategically coupling nanoparticle hybrids and internal thermosensitive molecular switches establishes an innovative paradigm for constructing micro/nanoscale-reconfigurable robots,facilitating energyefficient CO_(2) management in life-support systems of confined space.Here,a micro/nano-reconfigurable robot is constructed from the CO_(2) molecular hunters,temperature-sensitive molecular switch,solar photothermal conversion,and magnetically-driven function engines.The molecular hunters within the molecular extension state can capture 6.19 mmol g^(−1) of CO_(2) to form carbamic acid and ammonium bicarbonate.Interestingly,the molecular switch of the robot activates a molecular curling state that facilitates CO_(2) release through nano-reconfiguration,which is mediated by the temperature-sensitive curling of Pluronic F127 molecular chains during the photothermal desorption.Nano-reconfiguration of robot alters the amino microenvironment,including increasing surface electrostatic potential of the amino group and decreasing overall lowest unoccupied molecular orbital energy level.This weakened the nucleophilic attack ability of the amino group toward the adsorption product derivatives,thereby inhibiting the side reactions that generate hard-to-decompose urea structures,achieving the lowest regeneration temperature of 55℃ reported to date.The engine of the robot possesses non-contact magnetically-driven micro-reconfiguration capability to achieve efficient photothermal regeneration while avoiding local overheating.Notably,the robot successfully prolonged the survival time of mice in the sealed container by up to 54.61%,effectively addressing the issue of carbon suffocation in confined spaces.This work significantly enhances life-support systems for deep-space exploration,while stimulating innovations in sustainable carbon management technologies for terrestrial extreme environments.
基金financially supported by the China Scholarship Council(CSC)。
文摘Mine filling materials urgently need to improve mechanical properties and achieve low-carbon transformation.This study explores the mechanism of the synergistic effect of optimizing aggregate fractal grading and introducing CO_(2)nanobubble technology to improve the performance of cement-fly ash-based backfill materials(CFB).The properties including fluidity,setting time,uniaxial compressive strength,elastic modulus,porosity,microstructure and CO_(2)storage performance were systematically studied through methods such as fluidity evaluation,time test,uniaxial compression test,mercury intrusion porosimetry(MIP),scanning electron microscopy-energy dispersive spectroscopy analysis(SEM-EDS),and thermogravimetric-differential thermogravimetric analysis(TG-DTG).The experimental results show that the density and strength of the material are significantly improved under the synergistic effect of fractal dimension and CO_(2)nanobubbles.When the fractal dimension reaches 2.65,the mass ratio of coarse and fine aggregates reaches the optimal balance,and the structural density is greatly improved at the same time.At this time,the uniaxial compressive strength and elastic modulus reach their peak values,with increases of up to 13.46%and 27.47%,respectively.CO_(2)nanobubbles enhance the material properties by promoting hydration reaction and carbonization.At the microscopic level,CO_(2)nanobubble water promotes the formation of C-S-H(hydrated calcium silicate),C-A-S-H(hydrated calcium aluminium silicate)gel and CaCO_(3),which is the main way to enhance the performance.Thermogravimetric studies have shown that when the fractal dimension is 2.65,the dehydration of hydration products and the decarbonization process of CaCO_(3)are most obvious,and CO_(2)nanobubble water promotes the carbonization reaction,making it surpass the natural state.The CO_(2)sequestration quality of cement-fly ash-based materials treated with CO_(2)nanobubble water at different fractal dimensions increased by 12.4wt%to 99.8wt%.The results not only provide scientific insights for the design and implementation of low-carbon filling materials,but also provide a solid theoretical basis for strengthening green mining practices and promoting sustainable resource utilization.
