用PIT(powder in tube)法在不同条件下制备MgB2样品,通过X射线衍射、扫描电子显微镜(SEM)对不同参数下制备样品的成分和微观结构进行了表征;利用Campbell法检测样品的bac-λ′关系,求得样品的超导临界转变电流密度Jc;由样品的Jc结合形...用PIT(powder in tube)法在不同条件下制备MgB2样品,通过X射线衍射、扫描电子显微镜(SEM)对不同参数下制备样品的成分和微观结构进行了表征;利用Campbell法检测样品的bac-λ′关系,求得样品的超导临界转变电流密度Jc;由样品的Jc结合形貌与相成分对比分析,结果表明:长时间烧结,晶粒较大,利于导电,但缺乏钉扎作用,在外磁场下超导电流减小。长时间烧结,晶界间氧化层增厚,超导电流密度减小。展开更多
The electron transport of linear atomic chain trodes was investigated by using the density Green's function method. We have calculated of MgB2 sandwiched between Au(100) elecfunctional theory with the non-equilibri...The electron transport of linear atomic chain trodes was investigated by using the density Green's function method. We have calculated of MgB2 sandwiched between Au(100) elecfunctional theory with the non-equilibrium the corresponding cohesion energy and conductance of junctions in different distance. It is found that, at the equilibrium position, the Au-B bond-length is 1.90 A, the B-Mg bond-length is 2.22 A, and the equilibrium conductance is 0.51G0 (Go=2e^2/h). The transport channel is almost formed by the π antibonding orbitals, which was made up of the Px and Py orbital electrons of B and Mg atoms. In the voltage range of -1.5 to 1.5 V, the junctions show the metallic behaviors. When the voltage is larger than 1.5 V, the current decreases gradually and then negative differential resistance appears almost symmetrically on both positive and negative bias.展开更多
基金National Natural Science Foundation of China(51772250)National Science Basic Research Plan in Shannxi Province of China(2017ZDJC-19)Xi’an Weiyang District Science and Technology Project(201816)
文摘用PIT(powder in tube)法在不同条件下制备MgB2样品,通过X射线衍射、扫描电子显微镜(SEM)对不同参数下制备样品的成分和微观结构进行了表征;利用Campbell法检测样品的bac-λ′关系,求得样品的超导临界转变电流密度Jc;由样品的Jc结合形貌与相成分对比分析,结果表明:长时间烧结,晶粒较大,利于导电,但缺乏钉扎作用,在外磁场下超导电流减小。长时间烧结,晶界间氧化层增厚,超导电流密度减小。
基金V. ACKNOWLEDGMENTS This work was supported by the National Natural Science Foundation of China (No.11174214 and No.11204192), the Research Project of Education Department in Sichuan Province (No.13ZB0207), and Scientific Research Project of Yibin University (No.2013YY05).
文摘The electron transport of linear atomic chain trodes was investigated by using the density Green's function method. We have calculated of MgB2 sandwiched between Au(100) elecfunctional theory with the non-equilibrium the corresponding cohesion energy and conductance of junctions in different distance. It is found that, at the equilibrium position, the Au-B bond-length is 1.90 A, the B-Mg bond-length is 2.22 A, and the equilibrium conductance is 0.51G0 (Go=2e^2/h). The transport channel is almost formed by the π antibonding orbitals, which was made up of the Px and Py orbital electrons of B and Mg atoms. In the voltage range of -1.5 to 1.5 V, the junctions show the metallic behaviors. When the voltage is larger than 1.5 V, the current decreases gradually and then negative differential resistance appears almost symmetrically on both positive and negative bias.