Metal composites produced through the liquid metal dealloying(LMD)process feature an advanced matrix-matrix composite structure,where two metallic materials form a continuous,three-dimensional interconnected network.T...Metal composites produced through the liquid metal dealloying(LMD)process feature an advanced matrix-matrix composite structure,where two metallic materials form a continuous,three-dimensional interconnected network.This study investigates the effects of Ti Cu precursor compositions on dealloying behavior and microstructural evolution in liquid Mg,using Ti_(50)Cu_(50)and Ti_(30)Cu_(70)precursors.The initial microstructure of the precursor significantly influences dealloying kinetics and phase transitions.The single-phase Ti_(50)Cu_(50)precursor exhibits a faster initial dealloying rate due to its homogeneous structure,yet complete dealloying requires 90 min.In contrast,the dualphase Ti_(30)Cu_(70)precursor achieves complete dealloying in 30 min,demonstrating the impact of a higher Cu concentration on accelerating the process kinetics.Additionally,the study explores the coarsening behavior and hardness variations during the LMD process,along with the microstructural characteristics of Mg-Ti composites fabricated from these two precursors.The findings highlight the critical role of precursor composition in tailoring the microstructure and properties of Mg-Ti composites produced through the LMD process,demonstrating its potential for advanced composite material manufacturing.展开更多
An innovative physical simulation apparatus, including high speed camera, red thermal imaging system, and mechanical quantity sensor, was used to investigate the friction heat generation and atom diffusion behavior du...An innovative physical simulation apparatus, including high speed camera, red thermal imaging system, and mechanical quantity sensor, was used to investigate the friction heat generation and atom diffusion behavior during Mg-Ti friction welding process. The results show that the friction coefficient mainly experiences two steady stages. The first steady stage corresponds to the Coulomb friction with material abrasion. The second steady stage corresponds to the stick friction with fully plastic flow. Moreover, the increasing rates of axial displacement, temperature and friction coefficient are obviously enhanced with the increase of rotation speed and axial pressure. It can also be found that the there exists rapid diffusion phenomenon in the Mg-Ti friction welding system. The large deformation activated diffusion coefficient is about 105 higher than that activated by thermal.展开更多
A new kind of functionally graded materials (FGM) with density gradient has come to show great potentials as flier-plates for creating quasi-isotropic compression waves.In order to meet the demand of lower density in ...A new kind of functionally graded materials (FGM) with density gradient has come to show great potentials as flier-plates for creating quasi-isotropic compression waves.In order to meet the demand of lower density in the front face for such flier-plate,Mg with a low density of 1.74g/cm3 is selected to make a Mg-Ti FGM.Mg-Ti alloys with various weight ratios were sintered by spark plasma sintering (SPS) technique at relative low temperatures,and the processing of densification is mainly investigated.It is found that,up to 75wt%Ti,the Mg-Ti alloys can be fully densified at 560℃ due to the conglutination of Mg and the formation of a small amount of Mg-Ti solid solution.Finally,the Mg-Ti FGM with a density gradient from 1.74g/cm3 to 3.23g/cm3 is successfully fabricated.展开更多
The ultrafine pure Mg and Mg-Ti particles were prepared through a direct current （DC） arc plasma method. The X-ray diffraction （XRD）, transmission electron microscopy （TEM）, pressure-composition-temperature （PC...The ultrafine pure Mg and Mg-Ti particles were prepared through a direct current （DC） arc plasma method. The X-ray diffraction （XRD）, transmission electron microscopy （TEM）, pressure-composition-temperature （PCT） method and TG/DTA techniques were used to study the phase components, microstructure and hydrogen sorption properties of the powders before and after hydrogen absorption. It is revealed that most of the ultrafine Mg and Mg-Ti particles are hexagonal in shape with particle size in the range of 50-700 nm. According to the Van’t Hoff equation, the hydrogenation enthalpy of Mg-Ti powders is determined to be about -67 kJ/mol H2 based on the PCT curves of hydrogen absorption plateau pressures. This value is much higher than -78.6 kJ/mol H2 for pure Mg powders. TG/DTA analyses show that the onset dehydriding temperature of hydrogenated Mg-Ti powders is 386 °C, which is significantly lower than that of the hydrogenated Mg （423 °C）. The results prove that the addition of Ti into Mg through arc evaporation method can improve the thermodynamic properties of Mg for hydrogen storage.展开更多
基金supported by the National Research Foundation of Korea(NRF)grants funded by the Korea government(MSIT)(Nos.RS-2024–00351052 and RS-2024–00450561)。
文摘Metal composites produced through the liquid metal dealloying(LMD)process feature an advanced matrix-matrix composite structure,where two metallic materials form a continuous,three-dimensional interconnected network.This study investigates the effects of Ti Cu precursor compositions on dealloying behavior and microstructural evolution in liquid Mg,using Ti_(50)Cu_(50)and Ti_(30)Cu_(70)precursors.The initial microstructure of the precursor significantly influences dealloying kinetics and phase transitions.The single-phase Ti_(50)Cu_(50)precursor exhibits a faster initial dealloying rate due to its homogeneous structure,yet complete dealloying requires 90 min.In contrast,the dualphase Ti_(30)Cu_(70)precursor achieves complete dealloying in 30 min,demonstrating the impact of a higher Cu concentration on accelerating the process kinetics.Additionally,the study explores the coarsening behavior and hardness variations during the LMD process,along with the microstructural characteristics of Mg-Ti composites fabricated from these two precursors.The findings highlight the critical role of precursor composition in tailoring the microstructure and properties of Mg-Ti composites produced through the LMD process,demonstrating its potential for advanced composite material manufacturing.
基金Projects (51101126, 51071123) supported by the National Natural Science Foundation of ChinaProjects (20110491684, 2012T50817) supported by the China Postdoctoral Science FoundationProject (20110942K) supported by the Open Fund of State Key Laboratory of Powder Metallurgy of Central South University, China
文摘An innovative physical simulation apparatus, including high speed camera, red thermal imaging system, and mechanical quantity sensor, was used to investigate the friction heat generation and atom diffusion behavior during Mg-Ti friction welding process. The results show that the friction coefficient mainly experiences two steady stages. The first steady stage corresponds to the Coulomb friction with material abrasion. The second steady stage corresponds to the stick friction with fully plastic flow. Moreover, the increasing rates of axial displacement, temperature and friction coefficient are obviously enhanced with the increase of rotation speed and axial pressure. It can also be found that the there exists rapid diffusion phenomenon in the Mg-Ti friction welding system. The large deformation activated diffusion coefficient is about 105 higher than that activated by thermal.
文摘A new kind of functionally graded materials (FGM) with density gradient has come to show great potentials as flier-plates for creating quasi-isotropic compression waves.In order to meet the demand of lower density in the front face for such flier-plate,Mg with a low density of 1.74g/cm3 is selected to make a Mg-Ti FGM.Mg-Ti alloys with various weight ratios were sintered by spark plasma sintering (SPS) technique at relative low temperatures,and the processing of densification is mainly investigated.It is found that,up to 75wt%Ti,the Mg-Ti alloys can be fully densified at 560℃ due to the conglutination of Mg and the formation of a small amount of Mg-Ti solid solution.Finally,the Mg-Ti FGM with a density gradient from 1.74g/cm3 to 3.23g/cm3 is successfully fabricated.
基金Project (10JC1407700) supported by the Key Basic Project from Science and Technology Committee of Shanghai, ChinaProject(11ZR1417600) supported by Shanghai Nature Science Foundation from Science and Technology Committee of Shanghai, China+2 种基金Project(11PJ1406000) supported by ‘Pujiang’ project from the Science and Technology Committee of Shanghai, ChinaProject (12ZZ017)supported by Shanghai Education Commission, ChinaProject (20100073120007) supported by China Education Commission
文摘The ultrafine pure Mg and Mg-Ti particles were prepared through a direct current （DC） arc plasma method. The X-ray diffraction （XRD）, transmission electron microscopy （TEM）, pressure-composition-temperature （PCT） method and TG/DTA techniques were used to study the phase components, microstructure and hydrogen sorption properties of the powders before and after hydrogen absorption. It is revealed that most of the ultrafine Mg and Mg-Ti particles are hexagonal in shape with particle size in the range of 50-700 nm. According to the Van’t Hoff equation, the hydrogenation enthalpy of Mg-Ti powders is determined to be about -67 kJ/mol H2 based on the PCT curves of hydrogen absorption plateau pressures. This value is much higher than -78.6 kJ/mol H2 for pure Mg powders. TG/DTA analyses show that the onset dehydriding temperature of hydrogenated Mg-Ti powders is 386 °C, which is significantly lower than that of the hydrogenated Mg （423 °C）. The results prove that the addition of Ti into Mg through arc evaporation method can improve the thermodynamic properties of Mg for hydrogen storage.
基金Science Fund of Sichuan Province for Distinguished Young Scholars Sichuan Science(2023NSFSC1942)National Double First-Class Universities Construction Grant of Sichuan University(2020SCUNG201)。
