The mechanical behaviors and damping capacities of the binary Mg−Ga alloys with the Ga content ranging from 1 to 5 wt.%were investigated by means of optical microscope(OM),scanning electron microscope(SEM),X-ray diffr...The mechanical behaviors and damping capacities of the binary Mg−Ga alloys with the Ga content ranging from 1 to 5 wt.%were investigated by means of optical microscope(OM),scanning electron microscope(SEM),X-ray diffraction(XRD),hardness test,tensile test and dynamic mechanical analyzer(DMA).The hardness(HV_(0.5))increases with the increase of Ga content,which can be described as HV_(0.5)=41.61+10.35c,and the solid solution strengthening effect∆σ_(s)of the alloy has a linear relationship with c^(n),where c is the molar fraction of solute atoms and n=1/2 or 2/3.Ga exhibits a stronger solid solution strengthening effect than Al,Zn or Sn due to the large atomic radius difference and the modulus mismatch between Ga and Mg atoms.The addition of Ga makes the Mg−Ga alloys have better damping capacity,and this phenomenon can be explained by the Granato−Lücke dislocation model.The lattice distortion and the modulus mismatch generated because of the addition of Ga increase the resistance to motion of the dislocation in the process of swinging or moving,and thus the better damping capacity is acquired.展开更多
采用失重法和开路电位、恒流放电等电化学测试方法评价了模拟深海环境下Mg-Ga-Hg合金出厂态和间歇工作过程中的电化学性能。结果表明,在4℃、4 cm/s下,Mg-Ga-Hg合金的开路电位低于-1.95 V且自放电速率较慢;在1~9 m A/cm^2下放电时,稳定...采用失重法和开路电位、恒流放电等电化学测试方法评价了模拟深海环境下Mg-Ga-Hg合金出厂态和间歇工作过程中的电化学性能。结果表明,在4℃、4 cm/s下,Mg-Ga-Hg合金的开路电位低于-1.95 V且自放电速率较慢;在1~9 m A/cm^2下放电时,稳定工作电位低于-1.90 V,电流效率维持在50%以上。此外,出厂态和间歇工作时的Mg-Ga-Hg合金均可快速启动,适合用作海水电池的负极材料,以满足深海观测仪器长期供电需求。展开更多
By observing the microstructure evolution of Mg-Ga alloy during tensile deformation, it is found that the prismatic slip and the pyramidal <c+a> slip occur during the tensile process at room temperature, which ...By observing the microstructure evolution of Mg-Ga alloy during tensile deformation, it is found that the prismatic slip and the pyramidal <c+a> slip occur during the tensile process at room temperature, which finally leads to the plenty of dislocation accumulation. After 8% tensile deformation,the {1012} extension twin is the main way to coordinate the strain in the c-axis direction for the alloy with the Ga content lower than 2 wt.%, but the pyramidal <c+a> slip is the main way to coordinate the strain along the c-axis direction for the alloy with the Ga content higher than 2 wt.%. The Ga addition can promote the activation of the non-basal slip, which is beneficial to the work-hardening of the alloy to achieve better plasticity. Dynamic precipitation can slightly reduce the increment of dislocations.The preparation method of high strain rate rolling(HSRR) is another important reason for the plasticity of magnesium alloy sheets, and it is an important embodiment of the application of the dislocation engineering concept in magnesium alloy. The non-basal dislocations derived from the HSRR deformation can provide the non-basal dislocation sources when magnesium alloy is deformed at room temperature,resulting in good ductility. This study can be used as a reference for preparing wrought magnesium alloy with high strength and high plasticity by Ga alloying and hot deformation.展开更多
In order to obtain the thermodynamic description of the Mg-Ga binary system,the thermodynamic assessment of the system was carried out using the CALPHAD method through Thermo-calc software package based on the evaluat...In order to obtain the thermodynamic description of the Mg-Ga binary system,the thermodynamic assessment of the system was carried out using the CALPHAD method through Thermo-calc software package based on the evaluation of all available experimental data from the published literature.The solution phases,including liquid,hcp(Mg) and orthorhombic(Ga),were described by the substitutional solution model,of which the excess Gibbs energies were expressed with the Redlich-Kister polynomial.Meanwhile,all intermetallic compounds,Mg5Ga2,Mg2Ga,MgGa,MgGa2 and Mg2Ga5,were modeled as stoichiometric compounds.A set of self-consistent thermodynamic parameters formulating the Gibbs energies of various phases in the Mg-Ga binary system were obtained finally.The much better agreement is achieved between the calculated results and the reported experimental data.展开更多
The microstructure and thermal characteristics of Mg-36%Ga,Mg-43%Ga,and Mg-45%Ga(wt%) alloys were investigated.The experimental results show that the microstructure of Mg-36%Ga alloy is mainly composed of primary a-Mg...The microstructure and thermal characteristics of Mg-36%Ga,Mg-43%Ga,and Mg-45%Ga(wt%) alloys were investigated.The experimental results show that the microstructure of Mg-36%Ga alloy is mainly composed of primary a-Mg phase and a-Mg+Mg_(5)Ga_(2) eutectic phase,the microstructure of Mg-43%Ga alloy is mainly composed of a-Mg+Mg_(5)Ga_(2) eutectic phase,and the microstructure of Mg-45%Ga alloy is mainly composed of primary Mg_(5)Ga_(2) phase and a-Mg+Mg_(5)Ga_(2) eutectic phase.The melting enthalpies of Mg-36%Ga,Mg-43%Ga,and Mg-45%Ga are 146.41,171.90,and 113.90 J/g,with the phase change temperature of 422.57,422.70,and 422.90 ℃,respectively.Mg-43%Ga alloy contains the highest melting enthalpy because of the highest content of a-Mg+Mg_(5)Ga_(2) eutectic phase.In addition,the thermal expansion of the three alloys increases with increasing temperature,while the thermal diffusivity and thermal conductivity decreases with increasing content of Ga.展开更多
Magnesium alloys can be developed as anode materials for seawater activated batteries. The electrochemical properties of AZ31, AP65 and Mg-3%Ga-2%Hg alloy anodes discharged in seawater were studied. The potentiodynami...Magnesium alloys can be developed as anode materials for seawater activated batteries. The electrochemical properties of AZ31, AP65 and Mg-3%Ga-2%Hg alloy anodes discharged in seawater were studied. The potentiodynamic polarization shows that the Mg-3%Ga-2%Hg alloy provides more negative corrosion potentials than AZ31 or AP65 alloy. The galvanostatic discharge results show that the Mg-3%Ga-2%Hg alloy exhibits good electrochemical properties as anodes in seawater. And the EIS studies reveal that the magnesium alloy anode/seawater interfacial process is determined by an activation controlled reaction. The Mg3Hg and Mg21Ga5Hg3 phases in Mg-3%Ga-2%Hg alloy improve its electrochemical properties better than the Mg17（Al,Zn）12 phase in AZ31 and Mg（Pb） solid solution phase in AP65 alloys.展开更多
基金supported by the National Natural Science Foundation of China(Nos.51571089, 51871093)the Natural Science Foundation of Hunan Province, China(No. 2019JJ40044)
文摘The mechanical behaviors and damping capacities of the binary Mg−Ga alloys with the Ga content ranging from 1 to 5 wt.%were investigated by means of optical microscope(OM),scanning electron microscope(SEM),X-ray diffraction(XRD),hardness test,tensile test and dynamic mechanical analyzer(DMA).The hardness(HV_(0.5))increases with the increase of Ga content,which can be described as HV_(0.5)=41.61+10.35c,and the solid solution strengthening effect∆σ_(s)of the alloy has a linear relationship with c^(n),where c is the molar fraction of solute atoms and n=1/2 or 2/3.Ga exhibits a stronger solid solution strengthening effect than Al,Zn or Sn due to the large atomic radius difference and the modulus mismatch between Ga and Mg atoms.The addition of Ga makes the Mg−Ga alloys have better damping capacity,and this phenomenon can be explained by the Granato−Lücke dislocation model.The lattice distortion and the modulus mismatch generated because of the addition of Ga increase the resistance to motion of the dislocation in the process of swinging or moving,and thus the better damping capacity is acquired.
基金financially supported by the National Natural Science Foundation of China (no. 51871093)the Natural Science Foundation of Hunan Province, China (no. 2019JJ40044)。
文摘By observing the microstructure evolution of Mg-Ga alloy during tensile deformation, it is found that the prismatic slip and the pyramidal <c+a> slip occur during the tensile process at room temperature, which finally leads to the plenty of dislocation accumulation. After 8% tensile deformation,the {1012} extension twin is the main way to coordinate the strain in the c-axis direction for the alloy with the Ga content lower than 2 wt.%, but the pyramidal <c+a> slip is the main way to coordinate the strain along the c-axis direction for the alloy with the Ga content higher than 2 wt.%. The Ga addition can promote the activation of the non-basal slip, which is beneficial to the work-hardening of the alloy to achieve better plasticity. Dynamic precipitation can slightly reduce the increment of dislocations.The preparation method of high strain rate rolling(HSRR) is another important reason for the plasticity of magnesium alloy sheets, and it is an important embodiment of the application of the dislocation engineering concept in magnesium alloy. The non-basal dislocations derived from the HSRR deformation can provide the non-basal dislocation sources when magnesium alloy is deformed at room temperature,resulting in good ductility. This study can be used as a reference for preparing wrought magnesium alloy with high strength and high plasticity by Ga alloying and hot deformation.
基金Project supported by Scientific Research Foundation for Advanced Talents in Central South University of Forestry and Technology,ChinaProject(50731002) supported by the National Natural Science Foundation of China
文摘In order to obtain the thermodynamic description of the Mg-Ga binary system,the thermodynamic assessment of the system was carried out using the CALPHAD method through Thermo-calc software package based on the evaluation of all available experimental data from the published literature.The solution phases,including liquid,hcp(Mg) and orthorhombic(Ga),were described by the substitutional solution model,of which the excess Gibbs energies were expressed with the Redlich-Kister polynomial.Meanwhile,all intermetallic compounds,Mg5Ga2,Mg2Ga,MgGa,MgGa2 and Mg2Ga5,were modeled as stoichiometric compounds.A set of self-consistent thermodynamic parameters formulating the Gibbs energies of various phases in the Mg-Ga binary system were obtained finally.The much better agreement is achieved between the calculated results and the reported experimental data.
基金Funded by the 2019 Scientific and Technological Innovation Major Project of Hubei Province(No.2019AAA031)。
文摘The microstructure and thermal characteristics of Mg-36%Ga,Mg-43%Ga,and Mg-45%Ga(wt%) alloys were investigated.The experimental results show that the microstructure of Mg-36%Ga alloy is mainly composed of primary a-Mg phase and a-Mg+Mg_(5)Ga_(2) eutectic phase,the microstructure of Mg-43%Ga alloy is mainly composed of a-Mg+Mg_(5)Ga_(2) eutectic phase,and the microstructure of Mg-45%Ga alloy is mainly composed of primary Mg_(5)Ga_(2) phase and a-Mg+Mg_(5)Ga_(2) eutectic phase.The melting enthalpies of Mg-36%Ga,Mg-43%Ga,and Mg-45%Ga are 146.41,171.90,and 113.90 J/g,with the phase change temperature of 422.57,422.70,and 422.90 ℃,respectively.Mg-43%Ga alloy contains the highest melting enthalpy because of the highest content of a-Mg+Mg_(5)Ga_(2) eutectic phase.In addition,the thermal expansion of the three alloys increases with increasing temperature,while the thermal diffusivity and thermal conductivity decreases with increasing content of Ga.
基金National Natural Science Foundation of China (51971014)Tianjin Municipal Natural Science Foundation (19JCQNJC02800)Beijing Municipal Natural Science Foundation (2182021)。
基金Project (2011BAE22B03) supported by National Key Technologies R&D Program of ChinaProject (2011DFA50906) supported by the International S&T Cooperation Program of China
文摘Magnesium alloys can be developed as anode materials for seawater activated batteries. The electrochemical properties of AZ31, AP65 and Mg-3%Ga-2%Hg alloy anodes discharged in seawater were studied. The potentiodynamic polarization shows that the Mg-3%Ga-2%Hg alloy provides more negative corrosion potentials than AZ31 or AP65 alloy. The galvanostatic discharge results show that the Mg-3%Ga-2%Hg alloy exhibits good electrochemical properties as anodes in seawater. And the EIS studies reveal that the magnesium alloy anode/seawater interfacial process is determined by an activation controlled reaction. The Mg3Hg and Mg21Ga5Hg3 phases in Mg-3%Ga-2%Hg alloy improve its electrochemical properties better than the Mg17（Al,Zn）12 phase in AZ31 and Mg（Pb） solid solution phase in AP65 alloys.
