Exploiting high-performance electrolyte holds the key for realization practical application of rechargeable magnesium batteries(RMBs).Herein,a new non-nucleophilic mononuclear electrolyte was developed and its electro...Exploiting high-performance electrolyte holds the key for realization practical application of rechargeable magnesium batteries(RMBs).Herein,a new non-nucleophilic mononuclear electrolyte was developed and its electrochemical active species was identified as[Mg(DME)_(3)][GaCl_(4)]_(2) through single-crystal X-ray diffraction analysis.The as-synthesized Mg(GaCl_(4))_(2)-IL-DME electrolyte could achieve a high ionic conductivity(9.85 m S cm^(-1)),good anodic stability(2.9 V vs.Mg/Mg^(2+)),and highly reversible Mg plating/stripping.The remarkable electrochemical performance should be attributed to the in-situ formation of Mg^(2+)-conducting Ga_(5)Mg_(2)alloy layer at the Mg/electrolyte interface during electrochemical cycling,which not only efficiently protects the Mg anode from passivation,but also allows for rapid Mg-ion transport.Significantly,the Mg(GaCl_(4))_(2)-IL-DME electrolyte showed excellent compatibility with both conversion and intercalation cathodes.The Mg/S batteries with Mg(Ga Cl_(4))_(2)-IL-DME electrolyte and KB/S cathode showed a high specific capacity of 839 m Ah g^(-1)after 50 cycles at 0.1 C with the Coulombic efficiency of~100%.Moreover,the assembled Mg|Mo_6 S_8 batteries delivered a reversible discharge capacity of 85 m Ah g^(-1)after 120 cycles at 0.2 C.This work provides a universal electrolyte for the realization of high-performance and practical RMBs,especially Mg/S batteries.展开更多
The effects of Zn content on the microstxucture and the mechanical and corrosion properties of as-cast low-alloyed Mg-xZn~.2Ca alloys （x = 0.6wt%, 2.0wt%, 2.5wt%, hereafter denoted as 0.6Zn, 2.0Zn, and 2.5Zn alloys, ...The effects of Zn content on the microstxucture and the mechanical and corrosion properties of as-cast low-alloyed Mg-xZn~.2Ca alloys （x = 0.6wt%, 2.0wt%, 2.5wt%, hereafter denoted as 0.6Zn, 2.0Zn, and 2.5Zn alloys, respectively） axe investigated. The results show that the Zn content not only influences grain refinement but also induces different phase precipitation behaviors. The as-cast microstxucture of the 0.6Zn alloy is composed of ct-Mg, Mg2Ca, and Ca2Mg6Zn3 phases, whereas 2.0Zn and 2.5Zn alloys only contain ct-Mg and Ca2Mg6Zn3 phases, as revealed by X-ray diffraction （XRD） and txonsmission electron microscopy （TEM） analyses. Moreover, with in- creasing Zn content, both the ultimate tensile strength （UTS） and the elongation to fracture first increase and then decrease. Among the three investigated alloys, the largest UTS （178 MPa） and the highest elongation to fracture （6.5%） are obtained for the 2.0Zn alloy. In addition, the corrosion rate increases with increasing Zn content. This paper provides on updated investigation of the alloy composi- tion-microstxucture-property relationships of different Zn-containing Mg-Zn-Ca alloys.展开更多
The equilibrium of Mg-S in Ni melt was studied by the method of vapour equilibrium in a sealed chamber.At 1530℃ the equilibrium constant of the reaction MgS_(s)=Mg_(Ni)+S_(Ni)and the activity interaction coefficient ...The equilibrium of Mg-S in Ni melt was studied by the method of vapour equilibrium in a sealed chamber.At 1530℃ the equilibrium constant of the reaction MgS_(s)=Mg_(Ni)+S_(Ni)and the activity interaction coefficient were determined as K_(MgS)=6.76×10^(-5)and e_S^(Mg)=-9.1.展开更多
基金financially supported by National Natural Science Foundation of China(21773291,52303130,62205231,61904118,22002102)Natural Science Foundation of the Jiangsu Higher Education Institutions of China(19KJA210005)+1 种基金Postgraduate Research&Practice Innovation Program of Jiangsu Province(SJCX23_1710)Postgraduate Research&Practice Innovation Program of Suzhou University of Science and Technology(CLKYCX23_06)。
文摘Exploiting high-performance electrolyte holds the key for realization practical application of rechargeable magnesium batteries(RMBs).Herein,a new non-nucleophilic mononuclear electrolyte was developed and its electrochemical active species was identified as[Mg(DME)_(3)][GaCl_(4)]_(2) through single-crystal X-ray diffraction analysis.The as-synthesized Mg(GaCl_(4))_(2)-IL-DME electrolyte could achieve a high ionic conductivity(9.85 m S cm^(-1)),good anodic stability(2.9 V vs.Mg/Mg^(2+)),and highly reversible Mg plating/stripping.The remarkable electrochemical performance should be attributed to the in-situ formation of Mg^(2+)-conducting Ga_(5)Mg_(2)alloy layer at the Mg/electrolyte interface during electrochemical cycling,which not only efficiently protects the Mg anode from passivation,but also allows for rapid Mg-ion transport.Significantly,the Mg(GaCl_(4))_(2)-IL-DME electrolyte showed excellent compatibility with both conversion and intercalation cathodes.The Mg/S batteries with Mg(Ga Cl_(4))_(2)-IL-DME electrolyte and KB/S cathode showed a high specific capacity of 839 m Ah g^(-1)after 50 cycles at 0.1 C with the Coulombic efficiency of~100%.Moreover,the assembled Mg|Mo_6 S_8 batteries delivered a reversible discharge capacity of 85 m Ah g^(-1)after 120 cycles at 0.2 C.This work provides a universal electrolyte for the realization of high-performance and practical RMBs,especially Mg/S batteries.
基金supported by the National Natural Science Foundation of China(No.51671017)Fundamental Research Funds for the Central Universities(No.FRF-GF-17-B3)+1 种基金Beijing Laboratory of Metallic Materials and Processing for Modern Transportation,the Opening Research Fund of State Key Laboratory for Advanced Metals and Materials(Nos.2016Z-11,2017Z-08)State's Key Project of Research and Development Plan(No.2016YFB0300801)
文摘The effects of Zn content on the microstxucture and the mechanical and corrosion properties of as-cast low-alloyed Mg-xZn~.2Ca alloys （x = 0.6wt%, 2.0wt%, 2.5wt%, hereafter denoted as 0.6Zn, 2.0Zn, and 2.5Zn alloys, respectively） axe investigated. The results show that the Zn content not only influences grain refinement but also induces different phase precipitation behaviors. The as-cast microstxucture of the 0.6Zn alloy is composed of ct-Mg, Mg2Ca, and Ca2Mg6Zn3 phases, whereas 2.0Zn and 2.5Zn alloys only contain ct-Mg and Ca2Mg6Zn3 phases, as revealed by X-ray diffraction （XRD） and txonsmission electron microscopy （TEM） analyses. Moreover, with in- creasing Zn content, both the ultimate tensile strength （UTS） and the elongation to fracture first increase and then decrease. Among the three investigated alloys, the largest UTS （178 MPa） and the highest elongation to fracture （6.5%） are obtained for the 2.0Zn alloy. In addition, the corrosion rate increases with increasing Zn content. This paper provides on updated investigation of the alloy composi- tion-microstxucture-property relationships of different Zn-containing Mg-Zn-Ca alloys.
文摘The equilibrium of Mg-S in Ni melt was studied by the method of vapour equilibrium in a sealed chamber.At 1530℃ the equilibrium constant of the reaction MgS_(s)=Mg_(Ni)+S_(Ni)and the activity interaction coefficient were determined as K_(MgS)=6.76×10^(-5)and e_S^(Mg)=-9.1.
