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Annealing-induced strengthening in hetero-structured Mg alloy laminates with gradient Al content
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作者 Xiang Chen Yuhao Liu +7 位作者 Qiuyue Shi Junlei Zhang Chao He Qi Zhao Shuo Wang Yifu Shen Shuping Tan Lifei Wang 《Journal of Magnesium and Alloys》 2025年第11期5369-5376,共8页
This study developed a five-layer Mg alloy laminate(pure Mg/AZ31/AZ91/AZ31/pure Mg)through an innovative synergistic strategy involving Al-element gradient design,extrusion,and short-term annealing.Microstructural cha... This study developed a five-layer Mg alloy laminate(pure Mg/AZ31/AZ91/AZ31/pure Mg)through an innovative synergistic strategy involving Al-element gradient design,extrusion,and short-term annealing.Microstructural characterization revealed hierarchical heterogeneities in grain size,texture intensity,dislocation density,and precipitated phases,accompanied by the formation of annealing twinning in pure Mg layer—a phenomenon rarely documented in Mg alloys.Mechanical tests demonstrated significant strengthening effects in all annealed samples,particularly in the 300℃/30 min annealed sample,which achieved the optimal comprehensive mechanical properties.The enhanced strength originated from the synergistic interaction among element-diffusion-induced solid solution strengthening,nanoscale β-Mg_(17)Al_(12) precipitation,and hetero-deformation-induced(HDI)strengthening.This approach breaks the strength-ductility trade-off induced by traditional annealing processes,offering a new paradigm for designing high-performance Mg alloy laminates. 展开更多
关键词 mg alloy laminates Annealing strengthening HETEROSTRUCTURES Mechanical properties Element diffusion
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微合金化元素La对经Al-5Ti-1B处理的Al-Mg合金凝固组织影响
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作者 李赐宇 张丽丽 +3 位作者 张悦 江鸿翔 赵九洲 何杰 《物理学报》 北大核心 2026年第1期420-427,共8页
实验研究了微合金化元素La对经Al-5Ti-1B细化处理的Al-Mg合金凝固组织的影响,发现添加微量的La可进一步细化Al-Mg合金凝固组织,降低a-Al的形核过冷度.建立了微合金化元素La在Al合金熔体和TiB_(2)界面处偏析行为模型,探明了微合金化元素L... 实验研究了微合金化元素La对经Al-5Ti-1B细化处理的Al-Mg合金凝固组织的影响,发现添加微量的La可进一步细化Al-Mg合金凝固组织,降低a-Al的形核过冷度.建立了微合金化元素La在Al合金熔体和TiB_(2)界面处偏析行为模型,探明了微合金化元素La增强TiB_(2)粒子对a-Al异质形核能力的作用机理,计算结果表明,微合金化元素La富集于Al熔体和TiB_(2)粒子间界面处,降低TiB_(2)和a-Al间的界面能和接触角,增强TiB_(2)对a-Al的形核能力,进一步细化基体晶粒组织. 展开更多
关键词 al-mg合金 晶粒细化 微合金化元素La al-5Ti-B
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Influence of interface shape on microstructure and mechanical properties of Mg/Al composite plates fabricated by hot-pressing
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作者 Shi-jun TAN Bo SONG +6 位作者 Hao-hua XU Ting-ting LIU Jia SHE Sheng-feng GUO Xian-hua CHEN Kai-hong ZHENG Fu-sheng PAN 《Transactions of Nonferrous Metals Society of China》 2026年第1期124-143,共20页
A new method was proposed for preparing AZ31/1060 composite plates with a corrugated interface,which involved cold-pressing a corrugated surface on the Al plate and then hot-pressing the assembled Mg/Al plate.The resu... A new method was proposed for preparing AZ31/1060 composite plates with a corrugated interface,which involved cold-pressing a corrugated surface on the Al plate and then hot-pressing the assembled Mg/Al plate.The results show that cold-pressing produces intense plastic deformation near the corrugated surface of the Al plate,which promotes dynamic recrystallization of the Al substrate near the interface during the subsequent hot-pressing.In addition,the initial corrugation on the surface of the Al plate also changes the local stress state near the interface during hot pressing,which has a large effect on the texture components of the substrates near the corrugated interface.The construction of the corrugated interface can greatly enhance the shear strength by 2−4 times due to the increased contact area and the strong“mechanical gearing”effect.Moreover,the mechanical properties are largely depended on the orientation relationship between corrugated direction and loading direction. 展开更多
关键词 mg/al composite plate interface shape MICROSTRUCTURE mechanical properties TEXTURE
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Effect of different artificial aging treatments on tensile creep behavior of extruded lean Mg−Al−Ca−Mn alloy
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作者 Ming-yu LI Zhi-ping GUAN +6 位作者 Jia-wang SONG Hong-jie JIA Pin-kui MA Gang WANG Wei YAN Ming-hui WANG Zhi-gang LI 《Transactions of Nonferrous Metals Society of China》 2026年第1期112-123,共12页
The effects of artificial aging(T6)on the creep resistance with tensile stresses in the range of 50−80 MPa at 175℃were investigated for an extruded Mg−1.22Al−0.31Ca−0.44Mn(wt.%)alloy.The Guinier-Preston(G.P.)zones pr... The effects of artificial aging(T6)on the creep resistance with tensile stresses in the range of 50−80 MPa at 175℃were investigated for an extruded Mg−1.22Al−0.31Ca−0.44Mn(wt.%)alloy.The Guinier-Preston(G.P.)zones primarily precipitate in the sample aged at 200℃for 1 h(T6-200℃/1h),while the Al_(2)Ca phases mainly precipitate in the sample aged at 275℃for 8 h(T6-275℃/8h).The T6-200℃/1h sample exhibits excellent creep resistance,with a steady-state creep rate one order of magnitude lower than that of the T6-275℃/8h sample.The abnormally high stress exponent(~8.2)observed in the T6-200℃/1h sample is associated with the power-law breakdown mechanism.TEM analysis illuminates that the creep mechanism for the T6-200℃/1h sample is cross-slip between basal and prismatic dislocations,while the T6-275℃/8h sample exhibits a mixed mechanism of dislocation cross-slip and climb.Compared with the Al_(2)Ca phase,the dense G.P.zones effectively impede dislocation climb and glide during the creep process,demonstrating superior creep resistance of the T6-200℃/1h sample. 展开更多
关键词 mgal−Ca−Mn alloy tensile creep artificial aging cross slip
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Precipitation behavior of S' phase in rapid cold punched Al−Cu−Mg alloy
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作者 Ze-yi HU Pu-yu LI +4 位作者 Cai-he FAN Shuai WU Yi-ling LU Yin-chun XIAO Ling OU 《Transactions of Nonferrous Metals Society of China》 2026年第1期68-79,共12页
The evolution of the S'precipitate in Al−Cu−Mg alloy was investigated using transmission electron microscopy(TEM),high-angle annular dark-field scanning transmission electron microscopy(HAADF−STEM),molecular dynam... The evolution of the S'precipitate in Al−Cu−Mg alloy was investigated using transmission electron microscopy(TEM),high-angle annular dark-field scanning transmission electron microscopy(HAADF−STEM),molecular dynamics(MD)simulations,and other analytical techniques.The precipitation behavior during different aging stages of the supersaturated solid solution formed after rapid cold punching was focused,which induces rapid dissolution of precipitates.The findings reveal that the precipitation sequence is significantly influenced by aging temperature.At higher aging temperatures,which mitigate lattice distortion in the matrix,the precipitation sequence follows the conventional path.Conversely,at lower aging temperatures,where lattice distortion persists,the sequence deviates,suppressing the formation of Guinier−Preston−Bagaryatsky(GPB)zones.MD simulations confirm that the variations in solute atom diffusion rates at different aging temperatures lead to the differences in the S'phase precipitation sequence. 展开更多
关键词 al−Cu−mg alloy aging treatment S'phase evolution rapid cold punching molecular dynamics simulations
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3D morphological characteristics of shrinkage porosities and their relationship with microstructures in Mg−12Al magnesium alloy
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作者 Chuang-ming LI Ang ZHANG +6 位作者 Yong-feng LI Heng-rui HU He LIU Yu-yang GAO Zhi-hua DONG Bin JIANG Fu-sheng PAN 《Transactions of Nonferrous Metals Society of China》 2026年第1期96-111,共16页
The dependence of shrinkage porosities on microstructure characteristics of Mg−12Al alloy was investigated.The distribution,morphology,size,and number density of shrinkage porosities were analyzed under different cool... The dependence of shrinkage porosities on microstructure characteristics of Mg−12Al alloy was investigated.The distribution,morphology,size,and number density of shrinkage porosities were analyzed under different cooling rates.The relationship between shrinkage porosities and microstructure characteristics was discussed in terms of temperature conditions,feeding channel characteristics,and feeding capacity.Further,the feeding behavior of the residual liquid phase in the solid skeleton was quantified by introducing permeability.Results show a strong correlation between the solid microstructure skeleton and shrinkage porosity characteristics.An increase in permeability corresponds to a declining number density of shrinkage porosities.This study aims to provide a more complete understanding how to reduce shrinkage porosities by controlling microstructure characteristics. 展开更多
关键词 mg−12al alloy shrinkage porosity SOLIDIFICATION microstructure characteristics morphological characteristics
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Comparative analysis of unipolar and bipolar plasma electrolytic oxidation coatings on Al−Mg laminated macro composites 被引量:1
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作者 Mohsen RASTEGARI Masoud ATAPOUR +2 位作者 Aboozar TAHERIZADEH Amin HAKIMIZAD Maryam RAHMATI 《Transactions of Nonferrous Metals Society of China》 2025年第5期1424-1439,共16页
Plasma electrolytic oxidation(PEO)coatings were prepared on Al−Mg laminated macro composites(LMCs)using both unipolar and bipolar waveforms in an appropriate electrolyte for both aluminum and magnesium alloys.The tech... Plasma electrolytic oxidation(PEO)coatings were prepared on Al−Mg laminated macro composites(LMCs)using both unipolar and bipolar waveforms in an appropriate electrolyte for both aluminum and magnesium alloys.The techniques of FESEM/EDS,grazing incident beam X-ray diffraction(GIXRD),and electrochemical methods of potentiodynamic polarization and electrochemical impedance spectroscopy(EIS)were used to characterize the coatings.The results revealed that the coatings produced using the bipolar waveform exhibited lower porosity and higher thickness than those produced using the unipolar one.The corrosion performance of the specimens’cut edge was investigated using EIS after 1,8,and 12 h of immersion in a 3.5 wt.%NaCl solution.It was observed that the coating produced using the bipolar waveform demonstrated the highest corrosion resistance after 12 h of immersion,with an estimated corrosion resistance of 5.64 kΩ·cm^(2),which was approximately 3 times higher than that of the unipolar coating.Notably,no signs of galvanic corrosion were observed in the LMCs,and only minor corrosion attacks were observed on the magnesium layer in some areas. 展开更多
关键词 almg laminated macro composite plasma electrolytic oxidation corrosion behavior pulsed waveform
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Effect of Addition of Er-TiB_(2)Dual-Phase Nanoparticles on Strength-Ductility of Al-Mn-Mg-Sc-Zr Alloy Prepared by Laser Powder Bed Fusion
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作者 Li Suli Zhang Yanze +5 位作者 Yang Mengjia Zhang Longbo Xie Qidong Yang Laixia MaoFeng Chen Zhen 《稀有金属材料与工程》 北大核心 2026年第1期9-17,共9页
A dual-phase synergistic enhancement method was adopted to strengthen the Al-Mn-Mg-Sc-Zr alloy fabricated by laser powder bed fusion(LPBF)by leveraging the unique advantages of Er and TiB_(2).Spherical powders of 0.5w... A dual-phase synergistic enhancement method was adopted to strengthen the Al-Mn-Mg-Sc-Zr alloy fabricated by laser powder bed fusion(LPBF)by leveraging the unique advantages of Er and TiB_(2).Spherical powders of 0.5wt%Er-1wt%TiB_(2)/Al-Mn-Mg-Sc-Zr nanocomposite were prepared using vacuum homogenization technique,and the density of samples prepared through the LPBF process reached 99.8%.The strengthening and toughening mechanisms of Er-TiB_(2)were investigated.The results show that Al_(3)Er diffraction peaks are detected by X-ray diffraction analysis,and texture strength decreases according to electron backscatter diffraction results.The added Er and TiB_(2)nano-reinforcing phases act as heterogeneous nucleation sites during the LPBF forming process,hindering grain growth and effectively refining the grains.After incorporating the Er-TiB_(2)dual-phase nano-reinforcing phases,the tensile strength and elongation at break of the LPBF-deposited samples reach 550 MPa and 18.7%,which are 13.4%and 26.4%higher than those of the matrix material,respectively. 展开更多
关键词 al-Mn-mg-Sc-Zr alloy laser powder bed fusion nano-reinforcing phase synergistic enhancement
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In-situ investigation of deformation behavior and fracture forms of Ti/Al/Mg/Al/Ti laminates 被引量:11
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作者 Hui-hui NIE Liu-wei ZHENG +3 位作者 Xiao-ping KANG Xin-wei HAO Xian-rong LI Wei LIANG 《Transactions of Nonferrous Metals Society of China》 SCIE EI CAS CSCD 2021年第6期1656-1664,共9页
In-situ bending and stretching were conducted on hot-rolled and annealed Ti/Al/Mg/Al/Ti laminates,with a focus on crack initiation and propagation of intermetallics and component layers,which helps to clarify their de... In-situ bending and stretching were conducted on hot-rolled and annealed Ti/Al/Mg/Al/Ti laminates,with a focus on crack initiation and propagation of intermetallics and component layers,which helps to clarify their deformation behavior and fracture forms.The results show that delamination is the early fracture form of laminate with or without intermetallics at Al/Mg interface,so Al/Mg interfacial bonding strength determines the mechanical properties of laminate.Various and irregular intermetallics cracks lead to Al/Mg interface delamination in annealed laminate and help to release stress.Necking and fracture of component layers are observed at the late deformation stage,and the sequence is Al,Mg and Ti layers,resulting from their strength.Angle between crack propagation direction and stretching direction of Mg layer both in rolled and annealed laminates is around 45°due to the effect of shear deformation,and crack convergence leads to final complete fracture of Mg layer. 展开更多
关键词 Ti/al/mg/al/Ti laminate in-situ test INTERMETalLICS crack initiation fracture form
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Enhanced strength-ductility synergy of Mg/Al laminate by coordinating the strain gradient of constituting layers
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作者 Lihua Qian Liang Chen +3 位作者 Jianwei Tang Yefei Li Cunsheng Zhang Xiangshan Kong 《Journal of Materials Science & Technology》 2025年第30期264-279,共16页
Mg/Al laminate with ZK60Mg and TiB2/6061Al as constitute layers was fabricated through the porthole die co-extrusion and hot rolling.The effects of rolling and roll temperatures on the microstructure,interfacial struc... Mg/Al laminate with ZK60Mg and TiB2/6061Al as constitute layers was fabricated through the porthole die co-extrusion and hot rolling.The effects of rolling and roll temperatures on the microstructure,interfacial structure,mechanical properties,and crack propagation paths were studied.The results show that the intermetallic compounds layer shows an intermittent form.The strong strain/dislocation hardening ability of Mg/Al laminate is attributed to the coupled effects of interlocking Al/βinterface,strain gradient,andβlayer with nanotwins and stacking faults.The complex dislocation structures such as network,loop,and array are found in the Al layer.Dislocation slip is the main deformation mode of the Al layer,while dislocation slip and dynamic recrystallization are the main deformation modes of the Mg layer.As roll temperature increases,prismatic〈a〉slip replaces the basal〈a〉slip as the most important slip mode.At a rolling temperature of 400℃ and a roll temperature of 150℃,an optimal synergy of mechanical properties is achieved,with ultimate tensile strength,shear strength,and elongation of 262.1 MPa,36.4 MPa,and 18.1%,respectively.As the rolling temperature increases,the fracture mode of Mg/Al laminate changes from discontinuous plastic shrinkage to transverse and longitudinal cracks.With increasing the roll temperature,the through cracks tend to form,indicating the plasticity and bonding quality of Mg/Al laminate are effectively enhanced. 展开更多
关键词 mg/al laminATE Interface Intermetallic compounds Strength-ductility
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Nanoscale analysis of interfacial structure and its effects on mechanical properties of Mg/Al laminate reinforced by TiB_(2) particles
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作者 Lihua Qian Liang Chen +3 位作者 Biaohua Que Kaiqiang Shen Guoqun Zhao Cunsheng Zhang 《Journal of Magnesium and Alloys》 2025年第3期1310-1324,共15页
Fabricating Mg/Al laminate is an effective strategy to circumvent the inherently low formability and poor corrosion resistance of Mg alloys.Here,Mg/Al laminate with good bonding quality and mechanical properties was s... Fabricating Mg/Al laminate is an effective strategy to circumvent the inherently low formability and poor corrosion resistance of Mg alloys.Here,Mg/Al laminate with good bonding quality and mechanical properties was successfully fabricated via porthole die co-extrusion process using ZK60 Mg and TiB_(2)/6061Al composite as constituted layers.Integrating the results from microstructural characterization and mechanical testing,the effects of extrusion temperature on microstructure,interfacial structure,element diffusion,and mechanical properties were investigated.The results show that Mg/Al laminate achieves a sound welding quality by mechanical bonding and diffusion bonding.The obvious intermetallic compounds(βandγ)layer forms at Mg/Al interface,and its thickness increases to 8.3μm as the extrusion temperature reaches 400℃.High extrusion temperature promotes the dynamic recrystallization and grain growth of Mg and Al layers,while the dislocation density decreases.β/γinterface shows a coherent feature,whileγ/Mg interface is semi-coherent with a locally ordered transition zone of 4.5 nm.The rich Mg and Cr layers are found at TiB_(2)/6061 interface,which is conducive to improving the bonding quality.When the extrusion temperature is 370℃,the thickness of diffusion layer is around 5.0μm,and the bonding strength reaches 18.68 MPa,resulting in the best comprehensive mechanical properties.This work provides a new direction for the development of Mg/Al laminate with excellent strength and ductility. 展开更多
关键词 mg/al EXTRUSION Microstructure Interface Dislocation density
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高Zn含量超高强Al-Zn-Mg-Cu合金强韧化研究现状及发展趋势 被引量:7
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作者 范才河 毛垚晶 +4 位作者 刘俊伟 吴琴 胡泽艺 李济 武帅 《中国有色金属学报》 北大核心 2025年第2期439-464,共26页
通过增加超高强Al-Zn-Mg-Cu合金中Zn的含量来提升合金的性能已成为超高强Al-Zn-Mg-Cu合金领域的研究热点。国内外学者对高Zn含量超高强Al-Zn-Mg-Cu合金的强韧化机制进行了广泛研究,并取得了多项科研成果,推动了这类合金的发展及其在多... 通过增加超高强Al-Zn-Mg-Cu合金中Zn的含量来提升合金的性能已成为超高强Al-Zn-Mg-Cu合金领域的研究热点。国内外学者对高Zn含量超高强Al-Zn-Mg-Cu合金的强韧化机制进行了广泛研究,并取得了多项科研成果,推动了这类合金的发展及其在多个领域的应用。本文综述了Al-Zn-Mg-Cu合金的强韧化机制和Zn含量的提升对于Al-Zn-Mg-Cu合金强韧化性能的影响,以及微合金化处理、热处理工艺、形变热处理和大塑性变形等强化手段。通过对比分析各种制备和强化方法对合金微观组织及性能的影响,详细阐述了高Zn含量超高强Al-Zn-Mg-Cu合金的强韧化机制及方法,展望了其研究方向和发展前景。旨在为高Zn含量Al-Zn-Mg-Cu合金的成分设计和制备提供指导,以进一步提升其综合性能。 展开更多
关键词 al-ZN-mg-CU合金 强韧化机制 高Zn含量 析出相 超高强铝合金
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除磷吸附剂-Mg/Al层状双金属氢氧化物水热制备的双响应面优化
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作者 万立国 左彦鑫 +2 位作者 赵茜 张丽君 肖本益 《应用化工》 北大核心 2025年第11期2809-2814,2824,共7页
随着水体磷污染问题日益严重,寻找高效且经济的除磷材料成为环境工程领域的重要研究方向。针对现有除磷材料存在的吸附容量有限、成本高昂等问题,以提高吸附容量和降低成本为目的,以除磷吸附容量和除磷药剂成本为响应值,采用Box-Behnke... 随着水体磷污染问题日益严重,寻找高效且经济的除磷材料成为环境工程领域的重要研究方向。针对现有除磷材料存在的吸附容量有限、成本高昂等问题,以提高吸附容量和降低成本为目的,以除磷吸附容量和除磷药剂成本为响应值,采用Box-Behnken双响应面法对Mg/Al层状双金属氢氧化物(Mg/Al LDH)的水热制备进行了优化。经过单因素及双响应面优化试验得到Mg/Al LDH的最佳水热制备条件为Mg/Al摩尔比1.52,水热pH 9.28,老化温度112.69℃,Mg/Al LDH实际磷吸附容量为47.13 mg/g,除磷药剂成本为0.059元/g。优化后的Mg/Al LDH在除磷方面具有较高的吸附性能和经济性,为污水中磷的去除提供了有效的技术支持和参考,同时为环境工程领域的材料开发和制备工艺优化提供了新的视角。 展开更多
关键词 mg/al LDH 双响应面 磷吸附容量 除磷药剂成本 水热制备
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退火温度对依据LSDR原理轧制的Mg/Al层合板界面结构的影响
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作者 冯光 郜豪杰 +1 位作者 刘洪涛 于百灵 《热加工工艺》 北大核心 2025年第12期34-38,共5页
基于点阵强变形轧制(lattice severe deformation rolling,LSDR)原理制备了Mg/Al层合板,研究了200~400℃退火温度下界面扩散层厚度、成分以及形态特征,并进行了拉伸试验。结果表明:随退火温度升高,扩散层厚度逐渐增大。当退火温度为300... 基于点阵强变形轧制(lattice severe deformation rolling,LSDR)原理制备了Mg/Al层合板,研究了200~400℃退火温度下界面扩散层厚度、成分以及形态特征,并进行了拉伸试验。结果表明:随退火温度升高,扩散层厚度逐渐增大。当退火温度为300℃时,界面由明显的两层组成,靠近镁合金一侧为Mg_(17)Al_(12)相,靠近铝合金一侧为Mg_(2)Al_(3)相,且随温度升高,Mg_(2)Al_(3)相比Mg_(17)Al_(12)相生长速度快;界面沿轧向(rolling direction,RD)和横向(transverse direction,TD)均连续分布。Mg/Al层合板沿RD和TD的抗拉强度以及伸长率随退火温度升高均呈先增大后减小规律,300℃退火时获得最优的力学性能,沿RD和TD抗拉强度最大值分别为242 MPa和247 MPa,同时伸长率超过14%,相较未经退火的板材有显著提高。研究结果为探究LSDR原理制备高质量Mg/Al层合板提供了试验参考。 展开更多
关键词 LSDR mg/al层合板 退火温度 界面 扩散层
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Mn元素对Al-Si-Cu-Mg合金富铁相形貌及力学性能的影响 被引量:1
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作者 李萌 相志磊 +2 位作者 李雷哲 谷欣硕 陈子勇 《铸造》 2025年第4期479-486,共8页
在Al9Si1Cu0.5Mg0.15Fe合金中添加不同含量的Mn元素,研究Mn元素添加量对合金中富铁相形貌、尺寸及合金性能的影响;同时从热力学角度探讨了添加不同含量Mn元素后合金中α-Fe相的形成温度与富铁相形貌之间的关系。结果表明:随着Mn元素含... 在Al9Si1Cu0.5Mg0.15Fe合金中添加不同含量的Mn元素,研究Mn元素添加量对合金中富铁相形貌、尺寸及合金性能的影响;同时从热力学角度探讨了添加不同含量Mn元素后合金中α-Fe相的形成温度与富铁相形貌之间的关系。结果表明:随着Mn元素含量的增加,富铁相形貌的演变顺序为:针状→汉字状、棒状→汉字状、粒状→树枝状、粒状→梅花状、树枝状。Mn的最佳添加量为0.4%,此时合金中α-Fe相的形成温度与α(Al)基体的结晶温度相近,富铁相以细小的汉字状均匀分布在合金中。经统计,富铁相的平均尺寸随Mn含量的增加先减小再增大,Mn添加量为0.4%时,富铁相的平均尺寸最小,面积分数相较于未添加Mn时增加的较少;合金中富铁相长径比为1的占比为40%,且长径比分布较为集中;合金塑性达到了7.99%,相较于未添加Mn元素的合金提高了104.9%。 展开更多
关键词 al-SI-CU-mg合金 富Fe相 演变顺序 显微组织 力学性能
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Al对镁空气电池用挤压态Mg-Al-Ca-Mn合金阳极腐蚀和放电性能的影响
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作者 邱玮 李玉林 +5 位作者 闫瑞 李雅文 陈维 甘浪 任延杰 陈荐 《材料研究学报》 北大核心 2025年第5期389-400,共12页
研究了Al含量对镁空气电池用Mg-Al-Ca-Mn合金挤压态阳极在3.5%NaCl电解液中腐蚀和电化学性能的影响。结果表明,AMX411合金阳极表现出优异的耐腐蚀性和放电性能。AMX411合金的72 h析氢测试结果表明,其最小的析氢量和质量损失分别为(2.25&... 研究了Al含量对镁空气电池用Mg-Al-Ca-Mn合金挤压态阳极在3.5%NaCl电解液中腐蚀和电化学性能的影响。结果表明,AMX411合金阳极表现出优异的耐腐蚀性和放电性能。AMX411合金的72 h析氢测试结果表明,其最小的析氢量和质量损失分别为(2.25±0.07)mL·cm^(-2)和(2.83±0.12)mg·cm_(-2);AMX411合金的腐蚀电位(φcorr)和腐蚀电流密度(Jcorr)分别为-1.267 V和(67.9±0.16)μA·cm^(-2),表明其具有较小的电化学活性和最佳的耐腐蚀性能。随着Al含量的提高含Al第二相的分布逐渐均匀,其在3.5%NaCl溶液中由区域性腐蚀转变为均匀腐蚀,表明耐蚀性提高了。Nyquist图中的高频容抗环最大表明其电荷转移电阻最大,可抑制腐蚀过程中的点蚀。同时,AMX411合金Bode图中的模峰值和相位角峰值最高,进一步表明其耐蚀性优异。同时,合金电极的4 h放电结果表明,在电流密度分别为5、10、20和30 mA·cm^(-2)条件下这种合金电极都保持着较负且稳定的电压,并且在放电电流密度分别为20和30 mA·cm^(-2)条件下其放电效率高达61.36%和65.35%,显著优于AMX111合金电极的41.83%和44.79%。在高电流密度条件下这种合金阳极的利用率较高。AMX411合金优异的性能源于其内部的Al第二相较小且均匀分布,降低了局部电势差和抑制了微电偶腐蚀效应。 展开更多
关键词 金属材料 mg-al-Ca-Mn合金 镁空气电池 腐蚀行为 电化学性能
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Sc、Zr对Al-7.5Zn-1.6Mg-1.5Cu合金微观组织与性能的影响
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作者 孙杰 张金恒 +3 位作者 任建琦 朱鹏程 程仁寨 房洪杰 《中国有色金属学报》 北大核心 2025年第10期3513-3526,共14页
Al-Zn-Mg-Cu合金因高强度、韧性及耐蚀性等特性,广泛用于航空航天与工业领域,提升其综合性能对拓展应用范围意义显著。本研究将微合金化元素Sc、Zr添加到Al-7.5Zn-1.6Mg-1.5Cu合金中,利用阳极覆膜、室温拉伸、断口扫描、透射电镜观察、... Al-Zn-Mg-Cu合金因高强度、韧性及耐蚀性等特性,广泛用于航空航天与工业领域,提升其综合性能对拓展应用范围意义显著。本研究将微合金化元素Sc、Zr添加到Al-7.5Zn-1.6Mg-1.5Cu合金中,利用阳极覆膜、室温拉伸、断口扫描、透射电镜观察、电化学测试、晶间腐蚀及剥落腐蚀等手段,分析了单独添加Sc元素或Zr元素以及Sc、Zr共同添加对合金微观组织、力学性能和耐腐蚀性能的影响。结果表明:添加Sc和Zr可以显著抑制合金再结晶,提升合金的抗拉强度和屈服强度。添加0.2%Sc的合金的抗拉强度和抑制再结晶效果明显低于添加0.2%Zr的合金,但其耐腐蚀能力更优。共同添加0.1%Sc和0.1%Zr的合金具有最高的抗拉强度和屈服强度,分别为590.02 MPa和544.86 MPa,与未添加Sc、Zr的合金相比分别提升17.7%和22.4%。共同添加0.1%Sc和0.1%Zr的合金腐蚀敏感性最低,腐蚀深度最浅,腐蚀电流密度和腐蚀速率最小,表明其耐腐蚀性能亦最佳。 展开更多
关键词 al-ZN-mg-CU合金 Sc+Zr 力学性能 耐腐蚀性能
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Y添加和热处理对Al-Mg-Si-Y合金组织与性能的影响
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作者 毕晓勤 张森 +3 位作者 郑泽远 齐玉蕾 付莹 徐琴 《金属热处理》 北大核心 2025年第2期148-154,共7页
制备了Al-0.6Mg-0.5Si-xY(x=0,0.1,0.2,0.3,0.4)合金,并进行T6热处理,研究了热处理后合金的组织演变、导电性和力学性能。结果表明,热处理后添加Y的合金晶界处形成了AlSiY相,晶内析出颗粒状和棒状的AlSiY相,基体弥散分布着白色颗粒状的M... 制备了Al-0.6Mg-0.5Si-xY(x=0,0.1,0.2,0.3,0.4)合金,并进行T6热处理,研究了热处理后合金的组织演变、导电性和力学性能。结果表明,热处理后添加Y的合金晶界处形成了AlSiY相,晶内析出颗粒状和棒状的AlSiY相,基体弥散分布着白色颗粒状的Mg2Si相。热处理后合金平均晶粒尺寸较铸态增大,且Y添加量越多,合金平均晶粒尺寸越小。热处理后合金导电率随Y添加量的增加先升高后降低,添加0.3%Y时,导电率最高为55.2%IACS,较铸态提高1.7%。热处理后合金晶粒增大使晶界减少,且固溶Si原子的析出降低固溶畸变,从而提高合金导电率。热处理态合金抗拉强度和硬度较铸态提高,且随Y添加量的增加先增加后降低,添加0.3%Y时,分别达最高值206.2 MPa和91.3 HV0.1,较铸态提高36.6%和40.5%。热处理态合金的伸长率较铸态有明显下降。热处理后,合金中大量的析出相提高了合金的强度和硬度,而晶界减少、析出相增多使热处理态合金伸长率较铸态降低。 展开更多
关键词 al-mg-SI合金 Y添加 热处理 微观组织 导电性能 力学性能
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均匀化处理对时效强化Al-Mg-Zn-Sc-Zr合金微观组织与性能的影响
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作者 李波 许龙 +1 位作者 杨涵 杜勇 《材料导报》 北大核心 2025年第16期219-224,共6页
利用差示扫描量热仪(DSC)、X射线衍射仪(XRD)、光学显微镜(OM)、扫描电子显微镜(SEM)、透射电子显微镜(TEM)、维氏显微硬度计和电导率仪等研究了均匀化处理对时效强化Al-Mg-Zn-Sc-Zr合金微观组织与性能的影响。实验结果表明:铸态Al-Mg-Z... 利用差示扫描量热仪(DSC)、X射线衍射仪(XRD)、光学显微镜(OM)、扫描电子显微镜(SEM)、透射电子显微镜(TEM)、维氏显微硬度计和电导率仪等研究了均匀化处理对时效强化Al-Mg-Zn-Sc-Zr合金微观组织与性能的影响。实验结果表明:铸态Al-Mg-Zn-Sc-Zr合金存在严重的枝晶偏析,大量非平衡第二相T-Mg_(32)(A1,Zn)_(49)相沿晶界呈连续网状分布;同时,α-Al基体上还存在少量的初生Al_(3)(Sc,Zr)粒子。DSC曲线显示,铸态Al-Mg-Zn-Sc-Zr合金在465℃处存在明显的吸热峰;因此,为避免出现过烧现象,该合金均匀化温度设置为460℃。随着均匀化时间从4 h延长到24 h,合金中非平衡第二相T-Mg_(32)(A1,Zn)_(49)相逐渐回溶到α-Al基体中,其体积分数从6.45%下降到0.55%;同时观察到合金中有大量弥散分布的二次Al_(3)(Sc,Zr)粒子析出。随着均匀化时间延长到32 h,合金出现过烧现象。合金的硬度与电导率随均匀化时间的延长均呈现出先上升后下降的趋势,在24 h时合金的硬度与电导率达到最大值(116.71HV、30.3%IACS)。结合微观组织表征和性能分析,确定了铸态Al-Mg-Zn-Sc-Zr合金最佳均匀化工艺为460℃/24 h。 展开更多
关键词 时效强化al-mg-Zn-Sc-Zr合金 均匀化处理 微观组织 al_(3)(Sc Zr)粒子
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