The N-H methylsulfoxidation of sulfoximines using DMso as a methylsulfinyl source,induced by electrochemistry,has been developed.This method is the first example of an electrochemical reaction in which DMso serves as ...The N-H methylsulfoxidation of sulfoximines using DMso as a methylsulfinyl source,induced by electrochemistry,has been developed.This method is the first example of an electrochemical reaction in which DMso serves as a methylsulfinyl source.Unlike previous electrochemical reactions involving DMsO as a substrate,which exclusively proceed via radical mechanisms,this reaction follows an S-cation pathway.A wide range of N-methylsulfinyl sulfoximines were successfully obtained.展开更多
基金the Key Project of Provincial Natural Science Research Foundation of Anhui Universities,China(Nos.2022AH050406,2023AH050346)Anhui Province Research Funding for Outstanding Young Talents in Colleges and Universities,China(No.gxyq2022021)+3 种基金the Autonomous Project of Key Laboratory of Green and Precise Synthetic Chemistry and Applications,Ministry of Education(KLGPSCA202307,KLGPSCA202111)the Project of Graduate Innovation Fund(CX2024016)the Laboratory Open Project of Huaibei Normal University(Nos.2023syskf017,2023syskf027)the Industry-University-Research Horizontal Project(Nos.2023340603000039,22100370)forfinancial support.
文摘The N-H methylsulfoxidation of sulfoximines using DMso as a methylsulfinyl source,induced by electrochemistry,has been developed.This method is the first example of an electrochemical reaction in which DMso serves as a methylsulfinyl source.Unlike previous electrochemical reactions involving DMsO as a substrate,which exclusively proceed via radical mechanisms,this reaction follows an S-cation pathway.A wide range of N-methylsulfinyl sulfoximines were successfully obtained.
