This paper describes the procedures for the facile synthesis of 9,9′-bis(methoxymethyl)fluorene using fluorene as starting material. By hydroxymethylation and etherification reaction, the fluorene can be converted to...This paper describes the procedures for the facile synthesis of 9,9′-bis(methoxymethyl)fluorene using fluorene as starting material. By hydroxymethylation and etherification reaction, the fluorene can be converted to desired products with high yield and purity. The optimum conditions of the synthetic procedures were determined. For hydroxymethylation, the reaction temperature was 13 ℃and the mole ratio of sodium methoxide to paraformaldehyde was 0.26; and for etherification, the reaction temperature was 40 ℃and the reaction time was 15 h. Under the optimum conditions, an overall yield of 580 0 and purity of 99.20 0 were obtained.展开更多
A mild and efficient method for the conversion of alcohols to their corresponding methoxymethyl ethers and acetates using benzyltriphenylphosphonium tribromide （BTPTB） as catalyst is described. All reactions were pe...A mild and efficient method for the conversion of alcohols to their corresponding methoxymethyl ethers and acetates using benzyltriphenylphosphonium tribromide （BTPTB） as catalyst is described. All reactions were performed under completely heterogeneous reaction conditions in good to high yields.展开更多
A mild, efficient and fast method for direct oxidation of trimethylsilyl, tetrahydropyranyl and methoxymethyl ethers to their corresponding carbonyl compounds using trinitratocerium（Ⅳ） bromate （TNCB） supported on...A mild, efficient and fast method for direct oxidation of trimethylsilyl, tetrahydropyranyl and methoxymethyl ethers to their corresponding carbonyl compounds using trinitratocerium（Ⅳ） bromate （TNCB） supported on NaHSO4.H2O under solvent-free conditions is reported.展开更多
文摘This paper describes the procedures for the facile synthesis of 9,9′-bis(methoxymethyl)fluorene using fluorene as starting material. By hydroxymethylation and etherification reaction, the fluorene can be converted to desired products with high yield and purity. The optimum conditions of the synthetic procedures were determined. For hydroxymethylation, the reaction temperature was 13 ℃and the mole ratio of sodium methoxide to paraformaldehyde was 0.26; and for etherification, the reaction temperature was 40 ℃and the reaction time was 15 h. Under the optimum conditions, an overall yield of 580 0 and purity of 99.20 0 were obtained.
文摘A mild and efficient method for the conversion of alcohols to their corresponding methoxymethyl ethers and acetates using benzyltriphenylphosphonium tribromide （BTPTB） as catalyst is described. All reactions were performed under completely heterogeneous reaction conditions in good to high yields.
文摘A mild, efficient and fast method for direct oxidation of trimethylsilyl, tetrahydropyranyl and methoxymethyl ethers to their corresponding carbonyl compounds using trinitratocerium（Ⅳ） bromate （TNCB） supported on NaHSO4.H2O under solvent-free conditions is reported.
