The surge in environmental pollution in recent years driven by numerous pollutants has necessitated the search for efficient removal methods.Phytoremediation is an eco-friendly technique that provides multiple benefit...The surge in environmental pollution in recent years driven by numerous pollutants has necessitated the search for efficient removal methods.Phytoremediation is an eco-friendly technique that provides multiple benefits over conventional methods of removing contaminants.Despite the numerous benefits of this technique,it has certain limitations that can be addressed by incorporating nanoparticles to improve its effectiveness.This review paper aims to explore the impact of heavy metal pollution on plants and human health.It highlights the role and mechanism of nanoparticles in enhancing phytoremediation,their application in the detection of heavy metals,and the strategies for the safe disposal of phytoremediation biomass.Biosynthesized nanoparticles are eco-friendly and non-toxic,with applications in biomedical and environmental fields.Nanoparticles can be used in the form of nano biosensors like smartphone-operated wireless sensors made from Cinnamomum camphora,enabling efficient detection of heavy metal ions.According to the studies,nanoparticles remove 80%–97%of heavy metals by various methods like reduction,precipitation,adsorption,etc.The phytoremediation biomass disposal can be done by heat treatment,phytomining,and microbial treatment with some modifications to further enhance their results.Phytoremediation is an environmentally friendly technique but requires further research and integration with biomass energy production to overcome scalability challenges and ensure safe biomass disposal.展开更多
Heavy metal(HM)contamination severely impacts global agricultural production.HMs toxicity effectively damaged the physiological functions such as imbalanced redox homeostasis,altered antioxidant enzyme activity,damage...Heavy metal(HM)contamination severely impacts global agricultural production.HMs toxicity effectively damaged the physiological functions such as imbalanced redox homeostasis,altered antioxidant enzyme activity,damage root system architecture,hindered photosynthetic apparatus,cellular toxicity,restricted mineral accumulation,and changed the metabolite production.Using phytohormones may be a successful strategy for enhancing and stimulating plant tolerance to HMs toxicity without affecting the environment.Melatonin(MT),a novel plant growth regulator,and powerful antioxidant molecule,enhances plant resilience to HMs stress by enhancing seedling growth,protecting the photosynthetic system,increasing nutritional status,balanced redox homeostasis,and restricting HMs accumulation from root to shoot.In addition,MT enhances the activity of antioxidant enzymes and triggers the ascorbate-glutathione(AsA-GSH)cycle,which helps remove excessive ROS.MT improves RuBisCO activity to improve photosynthesis and reduce the breakdown of chlorophyll.To identify future research needs,it is crucial to understand the comprehensive and intricate regulatory mechanisms of exogenous and endogenous MT-mediated reduction of heavy metal toxicity in plants.Melatonin has several functions,and this review sheds light on those functions and the molecular processes by which it alleviates HMs toxicity.More research is needed to fully understand how melatonin affects plant tolerance to heavy metals stress.展开更多
Industrial waste salts are commonly used to make value-added snow-melting agents to ensure traffic safety in northern China during winter and spring after snowfall.However,heavy metals in industrial waste salts may po...Industrial waste salts are commonly used to make value-added snow-melting agents to ensure traffic safety in northern China during winter and spring after snowfall.However,heavy metals in industrial waste salts may pose certain environmental risks.Snow-melting agents and snow samples were collected and analyzed from highways,arterial roads,footbridges,and other locations in Beijing after the snowstorm in December 2023.It was found that the main component of snow-melting agents was sodium chloride with high concentrations of Cu,Mn,and Zn,which are not regulated in the current policies,despite the recent promotion of environmentally friendly snow-melting agents.The Pb,Zn and Cr contents of some snow samples exceeded the limitation value of surface water quality standards,potentially affecting the soil and water environment near roadsides,although the snow-melting agents comply with relevant standards,which indicates the policy gap in the management of recycled industrial salts.We reviewed and analyzed the relevant standards for snow-melting agents and industrial waste salts proposed nationally and internationally over the past 30 years.Through comparative analysis,we proposed relevant policy recommendations to the existing quality standards of snow-melting agents and the management regulations of industrial waste salts,and the formulation of corresponding usage strategies,aimed at reducing the potential environmental release of heavy metals from the use of snow-melting agents,thereby promoting more sustainable green urban development and environmentally sound waste management.展开更多
In 2021,approximately 537 million people suffered from diabetes mellitus(DM)globally,and this figure will increase to approximately 783 million within the next quarter-century.The increasing burden of DM is a pressing...In 2021,approximately 537 million people suffered from diabetes mellitus(DM)globally,and this figure will increase to approximately 783 million within the next quarter-century.The increasing burden of DM is a pressing global public health issue.Therefore,the early identification of high-risk groups and implementation of effective intervention measures is imperative.展开更多
Heavy metal pollution in coastal waters is on the rise,presenting serious threats to both ecosystems and human health.Coastal aquaculture zones,such as those in Quang Ninh province,are especially vulnerable due to the...Heavy metal pollution in coastal waters is on the rise,presenting serious threats to both ecosystems and human health.Coastal aquaculture zones,such as those in Quang Ninh province,are especially vulnerable due to the accumulation of heavy metals from multiple sources,including industrial wastewater,land runoff,and maritime activities.This study applies the Heavy Metal Pollution Index(HPI)to assess pollution levels based on the concentrations of nine heavy metals(Cr,Mn,Fe,Cu,Zn,As,Cd,Hg,Pb)found in seawater samples collected from coastal aquaculture areas in Quang Ninh.According to the HPI method,values exceeding 100 indicate polluted water,serving as a benchmark for evaluating heavy metal contamination in the region.A total of 25 seawater samples were collected and analyzed;of these,18 samples(72%)had HPI values above 100,signaling a concerning level of heavy metal pollution,while only 7 samples(28%)fell below the threshold,suggesting no significant contamination.These results underscore the urgent need for enhanced monitoring of water quality and stricter regulation of pollution sources to protect both environmental and public health.展开更多
The Sn−2Al filler metal was utilized to bond W90 tungsten heavy alloys by the ultrasonic-assisted coating technology in atmospheric environment at 250℃.The effects of ultrasonic power and ultrasonic time on microstru...The Sn−2Al filler metal was utilized to bond W90 tungsten heavy alloys by the ultrasonic-assisted coating technology in atmospheric environment at 250℃.The effects of ultrasonic power and ultrasonic time on microstructure and interfacial strength of Sn−2Al/W90 interface were investigated.The ultrasound improved the wettability of Sn−2Al filler metal on W90 surface.As the ultrasonic power increased and ultrasonic time increased,the size of Al phase in seam decreased.The maximum value of Sn−2Al/W90 interfacial strength reached 30.1 MPa.Based on the acoustic pressure simulation and bubble dynamics,the intensity of cavitation effect was proportional to ultrasonic power.The generated high temperature and high pressure by cavitation effect reached 83799.6 K and 1.26×10^(14) Pa,respectively.展开更多
Controlling heavy metal pollution in agricultural soil has been a significant challenge.These heavy metals seriously threaten the surrounding ecological environment and human health.The effective assessment and remedi...Controlling heavy metal pollution in agricultural soil has been a significant challenge.These heavy metals seriously threaten the surrounding ecological environment and human health.The effective assessment and remediation of heavy metals in agricultural soils are crucial.These two aspects support each other,forming a close and complete decisionmaking chain.Therefore,this review systematically summarizes the distribution characteristics of soil heavy metal pollution,the correlation between soil and crop heavy metal contents,the presence pattern and migration and transformation mode of heavy metals in the soil-crop system.The advantages and disadvantages of the risk evaluation tools and models of heavy metal pollution in farmland are further outlined,which provides important guidance for an in-depth understanding of the characteristics of heavymetal pollution in farmland soils and the assessment of the environmental risk.Soil remediation strategies involve multiple physical,chemical,biological and even combined technologies,and this paper compares the potential and effect of the above current remediation technologies in heavy metal polluted farmland soils.Finally,the main problems and possible research directions of future heavy metal risk assessment and remediation technologies in agricultural soils are prospected.This review provides new ideas for effective assessment and selection of remediation technologies based on the characterization of soil heavy metals.展开更多
Soil naturally contains various heavy metals,however,their concentrations have reached toxic levels due to excessive agrochemical use and industrial activities.Heavy metals are persistent and non-biodegradable,causing...Soil naturally contains various heavy metals,however,their concentrations have reached toxic levels due to excessive agrochemical use and industrial activities.Heavy metals are persistent and non-biodegradable,causing environmental disruption and posing significant health hazards.Microbial-mediated remediation is a promising strategy to prevent heavy metal leaching and mobilization,facilitating their extraction and detoxification.Nickel(Ni),being a prevalent heavy metal pollutant,requires specific attention in remediation efforts.Plants have evolved defense mechanisms to cope with environmental stresses,including heavy metal toxicity,but such stress significantly reduces crop productivity.Beneficial microorganisms play a crucial role in enhancing plant yield and mitigating abiotic stress.The impact of heavy metal abiotic stress on plants’growth and productivity requires thorough investigation.Bioremediation using Nickel nanoparticles(Ni NPs)offers an effective approach to mitigating environmental pollution.Microorganisms contribute to nanoparticle bioremediation by immobilizing metals or inducing the synthesis of remediating microbial enzymes.Understanding the interactions between microorganisms,contaminants,and nanoparticles(NPs)is essential for advancing bioremediation strategies.This review focuses on the role of Bacillus subtilis in the bioremediation of nickel nanoparticles to mitigate environmental pollution and associated health risks.Furthermore,sustainable approaches are necessary to minimize metal contamination in seeds.The current review discusses bacterial inoculation in enhancing heavy metal tolerance,plant signal transduction pathways,and the transition from molecular to genomic research in metal stress adaptation.Moreover,the inoculation of advantageous bacteria is crucial for preserving plants under severe mental stress.Different researchers develop a complex,vibrant relationship with plants through a series of events known as plant-microbe interactions.It increases metal stress resistance through the creation of phytohormones.In general,the defensive responses of plants to heavy metal stress,mediated by microbial inoculation require further in-depth research.Further studies should explore the detoxification mechanism of nickel through bioremediation to develop more effective and sustainable remediation strategies.展开更多
Agricultural soil is related to food security and human health,antibiotics and heavy metals(HMs),as two typical pollutants,possess a high coexistence rate in the environmental medium,which is extremely prone to induci...Agricultural soil is related to food security and human health,antibiotics and heavy metals(HMs),as two typical pollutants,possess a high coexistence rate in the environmental medium,which is extremely prone to inducing antibiotic-HMs combined pollution.Recently,frequent human activities have led to more prominent antibiotics-HMs combined contamination in agricultural soils,especially the production and spread of antibiotic resistance genes(ARGs),heavy metal resistance genes(MRGs),antibiotic resistant bacteria(ARB),and antibiotics-HMs complexes(AMCs),which seriously threaten soil ecology and human health.This review describes the main sources(Intrinsic and manmade sources),composite mechanisms(co-selective resistance,oxidative stress,and Joint toxicity mechanism),environmental fate and the potential risks(soil ecological and human health risks)of antibiotics and HMs in agricultural soils.Finally,the current effective source blocking,transmission control,and attenuation strategies are classified for discussion,such as the application of additives and barrier materials,as well as plant and animal remediation and bioremediation,etc.,pointing out that future research should focus on the whole chain process of“source-processterminal”,intending to provide a theoretical basis and decision-making reference for future research.展开更多
Abandoned mines,especially pyrite-rich ones,release acid mine drainage(AMD)with high acidity and excessive amounts of heavy metals,threatening regional ecosystems.Six samples of mine drainage,nine samples of surface w...Abandoned mines,especially pyrite-rich ones,release acid mine drainage(AMD)with high acidity and excessive amounts of heavy metals,threatening regional ecosystems.Six samples of mine drainage,nine samples of surface water,and twelve samples of sediment were analyzed in this case study of the Dashu pyrite mine in southwest China.A comprehensive analysis of the pollution levels,pollution sources,and potential hazards of eight metals(Ni,Cd,Cu,Zn,Fe,Al,Pb,and Mn)that exceeded regulatory standardswas conducted bymonitoring 24 conventional and characteristic indicators.Ultimately,this research evaluated the environmental hazards associated with abandonedmine water using the"pressure-response"model,thereby providing valuable insights for the effective protection of the environment in mining regions.The primary pollutants in mine water were determined to be SO_(4)^(2−),Fe,and Mn,with concentrations of 7700,1450,and 6.78mg/L,respectively.A clear"source-sink"dynamic was observed between themine water and the surrounding water system.surface water was primarily polluted by Ni and Mn,while water system sediments were primarily polluted by Cu and Hg.Ion ratio and Pearson correlation analyses indicated heavy metals in surface water and sediments originated from the same AMD source.The"pressureresponse"model was used to assess the environmental hazards of water from abandoned mines.Mines W1,W2,W5,and W6 were classified as high-risk,while W3 and W4 were medium-risk.This study offers a novel approach and valuable reference for identifying and classifying environmental risks in abandoned mines and targeting AMD treatment.展开更多
Coking industry is a potential source of heavy metals(HMs)pollution.However,its impacts to the groundwater of surrounding residential areas have not been well understood.This study investigated the pollution character...Coking industry is a potential source of heavy metals(HMs)pollution.However,its impacts to the groundwater of surrounding residential areas have not been well understood.This study investigated the pollution characteristics and health risks of HMs in groundwater nearby a typical coking plant.Nine HMs including Fe,Zn,Mo,As,Cu,Ni,Cr,Pb and Cd were analyzed.The average concentration of total HMswas higher in the nearby area(244.27μg/L)than that of remote area away the coking plant(89.15μg/L).The spatial distribution of pollution indices including heavy metal pollution index(HPI),Nemerow index(NI)and contamination degree(CD),all demonstrated higher values at the nearby residential areas,suggesting coking activity could significantly impact the HMs distribution characteristics.Four sources of HMs were identified by Positive Matrix Factorization(PMF)model,which indicated coal washing and coking emission were the dominant sources,accounted for 40.4%,and 31.0%,respectively.Oral ingestionwas found to be the dominant exposure pathway with higher exposure dose to children than adults.Hazard quotient(HQ)values were below 1.0,suggesting negligible non-carcinogenic health risks,while potential carcinogenic risks were from Pb and Ni with cancer risk(CR)values>10−6.Monte Carlo simulation matched well with the calculated results with HMs concentrations to be the most sensitive parameters.This study provides insights into understanding how the industrial coking activities can impact the HMs pollution characteristics in groundwater,thus facilitating the implement of HMs regulation in coking industries.展开更多
Two strains of Fe/Mn oxidizing bacteria tolerant to high concentrations of multiple heavy metal(loid)s and efficient decontamination for them were screened.The surface of the bio-Fe/Mn oxides produced by the oxidation...Two strains of Fe/Mn oxidizing bacteria tolerant to high concentrations of multiple heavy metal(loid)s and efficient decontamination for them were screened.The surface of the bio-Fe/Mn oxides produced by the oxidation of Fe(II)and Mn(II)by Pseudomonas taiwanensis(marked as P4)and Pseudomonas plecoglossicida(marked as G1)contains rich reactive oxygen functional groups,which play critical roles in the removal efficiency and immobilization of heavymetal(loid)s in co-contamination system.The isolated strains P4 and G1 can growwell in the following environments:pH 5-9,NaCl 0-4%,and temperature 20-30℃.The removal efficiencies of Fe,Pb,As,Zn,Cd,Cu,and Mn are effective after inoculation of the strains P4 and G1 in the simulated water system(the initial concentrations of heavy metal(loid)were 1 mg/L),approximately reaching 96%,92%,85%,67%,70%,54%and 15%,respectively.The exchangeable and carbonate bound As,Cd,Pb and Cu are more inclined to convert to the Fe-Mn oxide bound fractions in P4 and G1 treated soil,thereby reducing the phytoavailability and bioaccessible of heavy metal(loid)s.This research provides alternatives method to treat water and soil containing high concentrations of multi-heavy metal(loid)s.展开更多
Phosphorus(P)poses a global challenge to the environment and human health due to its natural association with heavy metals.Sustainable use of P is crucial to ensure food security for future generations.An analysis of ...Phosphorus(P)poses a global challenge to the environment and human health due to its natural association with heavy metals.Sustainable use of P is crucial to ensure food security for future generations.An analysis of the 150 phosphate fertilizers stored at the Institute for Crop and Soil Science in Germany has been conducted,supplemented by previously published data.The elements Cd,Bi,U,Cr,Zn,Tl,As,B,Sb,Ni,and Se are found in higher concentrations in sedimentary derived phosphates compared to igneous derived phosphates.Mineral fertilizers contain more than ten times the amount of U,Cd,B,and As compared to farmyard manure.Principal component analyses(PCA)indicate that U,Cd,Be,and Cr are primarily present in sedimentary derived phosphates and their concentrations are 2 to 10 times higher than those in igneous derived phosphates.Regarding heavy metal contamination,over 1000 potential combinations were identified;36% of these were significant but weak(>0.1).It is estimated that approximately 707 t of uranium enter farmland annually through the application of mineral phosphate fertilizers in European countries.This contribution addresses environmental issues related to the utilization of rock phosphate as well as alternative production methods for cleaner and safer phosphate fertilizers while presenting a roadmap with measures for mitigation.展开更多
Hydroxyapatite nanoparticles(HAP NPs)were synthesized by a one‐step hydrothermal method.The surface of HAP NPs was grafted-SH and-COOH chelating groups via in situ surface‐modification with iminodiacetic acid(IDA)an...Hydroxyapatite nanoparticles(HAP NPs)were synthesized by a one‐step hydrothermal method.The surface of HAP NPs was grafted-SH and-COOH chelating groups via in situ surface‐modification with iminodiacetic acid(IDA)and 3‐mercaptopropyl trimethoxysilane(MPS)to afford dual surface‐capped nano‐amendment HAPIDA/MPS.The structure of HAP‐IDA/MPS was characterized,and its adsorption performance for Hg^(2+),Cu^(2+),Zn^(2+),Ni^(2+),Co^(2+),and Cd^(2+)was evaluated.The total adsorption capacity of 0.10 g HAP‐IDA/MPS nano‐amendment for Hg^(2+),Cu^(2+),Zn^(2+),Ni^(2+),Co^(2+),and Cd^(2+)with an initial mass concentration of 20 mg·L^(-1) reached 13.7 mg·g^(-1),about 4.3 times as much as that of HAP.Notably,HAP‐IDA/MPS nano‐amendment displayed the highest immobilization rate for Hg^(2+),possibly because of its chemical reaction with-SH to form sulfide,possessing the lowest solubility product constant among a variety of metal sulfides.展开更多
The traditional techniques for treating wastewater contaminated by heavy metals mostly involve chemical precipitation,solvent extraction and adsorption,ion-exchange,chemical precipitation,and membrane separation.The m...The traditional techniques for treating wastewater contaminated by heavy metals mostly involve chemical precipitation,solvent extraction and adsorption,ion-exchange,chemical precipitation,and membrane separation.The main shortcomings of traditional procedures are low economic efficiency,lack of environmental friendliness,and poor selectivity.Cyclodextrins are artificial compounds that resemble cages.Through host-vip interaction,pollutants can be adsorbed by its stable inner hydrophobic chamber and exterior hydrophilic surface.It is not only inexpensive and environmentally friendly,but also quite selective.The synthesis and application of materials were reviewed,as well as the primary influencing factors,and the reaction principle of cyclodextrin adsorbent materials for better separation of heavy metal ions.And the future trend of discovery was described.展开更多
Industrial activities have contributed so much to the pollution of water bodies and these pollutions have adversely affected the aquatic ecosystem.This study aimed to investigate the ecological risk evaluation of heav...Industrial activities have contributed so much to the pollution of water bodies and these pollutions have adversely affected the aquatic ecosystem.This study aimed to investigate the ecological risk evaluation of heavy metal accumulation in Aba River bottom sediments:implications for soap and detergent industry wastewater management.Varian AA240 Atomic absorption spectrometer was used to analyse heavy metals.Individual and complex ecological indices were used to evaluate heavy metal contamination in bottom sediments.According to the results,the heavy metal properties of the wastewater indicated that Fe,Pb,Cd,Cr and Cu mean concentration values were higher than the World Health Organization(WHO)and the National Environmental Standards and Regulations Enforcement Agency(NESREA)permissible limits.Heavy metal properties of the surface water in Aba River(dry seasons)showed that Pb,Cd,Cu,Mn,Fe,and Cr,mean concentrations were above the NESREA,WHO and U.S.Environmental Protection Agency(USEPA)permissible limits.Heavy metal properties of the bottom sediments of Aba River(wet and dry season)showed that Pb,Cd,and Fe mean concentrations were significantly higher than the NESREA,WHO and USEPA permissible limits.The heavy metal contamination factor(CF)of sediments obtained from Aba River during the wet and dry season was low and the CFs of each of the assayed heavy metals were less than 1(CD<1).This also signifies the existence of a low contamination in the sediments of the course streams of Aba River during wet and dry season.The pollution load index(PLI)values of Aba River(sediment)indicated that there is no metal pollution at PLI<1 in the sampled sediments.The potential ecological risk index(RI)of Aba River was less than 150(RI<150)indicating a low ecological RI.Abatement of pollutants in the wastewater to permissible concentrations required for natural environment protection is needed.展开更多
Urban rivers are one of the main water sources for local residents.However,the rapid industrialization and urbanization caused serious heavy metals pollution in urban rivers,which posed harmful impact on human health ...Urban rivers are one of the main water sources for local residents.However,the rapid industrialization and urbanization caused serious heavy metals pollution in urban rivers,which posed harmful impact on human health and ecosystem.In this study,134 sediment samples were collected fromurban rivers in a typical Economic and Technological Development Zone(ETDZ)to evaluate the contamination status,ecological risk,biotoxicity,and potential source of 8 heavy metals including arsenic(As),cadmium(Cd),chromium(Cr),copper(Cu),mercury(Hg),nickel(Ni),plumbum(Pb),and zinc(Zn).Results showed that the average concentrations of all 8 metals exceeded their corresponding background values and followed the trend:Cr(248.67 mg/kg)>Pb(123.58 mg/kg)>Zn(67.06 mg/kg)>Ni(47.19 mg/kg)>Cu(27.40 mg/kg)>As(16.15 mg/kg)>Cd(0.62mg/kg)>Hg(0.21mg/kg).A high contamination and accumulation tendency of Cd and Cr were found in the sediments.Moreover,Cd and Hg were the main contributors of ecological risk,and posed moderate to high risk.In terms of biotoxicity,all the sediment samples were harmful to benthic organisms.Two possible pollution sources of heavy metals were identified:one is a combined source of industrial and traffic pollution dominated by Cr and Pd,the other is an industrial pollution source consisting of six heavy metals(Ni,Zn,Cd,Hg,As,and Cu).This study provides insights into heavy metals pollution management and risk control in the ETDZ and similar urban rivers worldwide due to intense industrialization.展开更多
Electroplating sludge(ES),a byproduct of the electroplating industry,is a significant environmental concern due to its high content of soluble heavy metals(HMs).The significance of spinel formation from ES lies in its...Electroplating sludge(ES),a byproduct of the electroplating industry,is a significant environmental concern due to its high content of soluble heavy metals(HMs).The significance of spinel formation from ES lies in its potential for HMs enrichment and environmental remediation,offering a sustainable solution for hazardous waste management.The article delves into themultifaceted recycling of HMs-rich spinel fromES,encompassing its synthesis,metal enrichment,and thermodynamic stability.The pyro-metallurgical and hydrometallurgical processes for spinel synthesis were discussed,with a focus on the critical role of thermodynamic data in predicting the stability and formation of spinel structures.The crystallographic and magnetic properties of spinels,with their applications in environmental remediation and energy storage are highlighted.The article provides a comprehensive reviewon the recycling of HMs-rich spinel fromES,offering a means to recycle HMs,mitigate ecological harm,and contribute to a circular economy through the recovery and application of valuable materials.The selective leaching of metals from ES also faces challenges,which was limited by the separation,purification steps and high energy consumption.This high energy consumption is a significant operational cost and also contributes to environmental concerns related to carbon emissions.It is essential to address the challenges through continued research and development,improved technologies,and supportive regulatory frameworks.展开更多
This study evaluates the impact of heavy metals(zinc,copper and cadmium)on the development and metabolic responses of the maize(Zea mays)variety“Torro Plus”.Seeds were cultivated on MS medium enriched with progressi...This study evaluates the impact of heavy metals(zinc,copper and cadmium)on the development and metabolic responses of the maize(Zea mays)variety“Torro Plus”.Seeds were cultivated on MS medium enriched with progressively higher concentrations of heavy metals(50,100 and 150μM),and plants were analyzed after 21 days.The results show a significant reduction in morphological parameters,notably an 87.28%decrease in the fresh weight of aerial parts and a 69.93%decrease in the fresh weight of roots under 150μM of Cd.Chlorophyll a,b and total content also decreased drastically,reaching a maximum reduction of 74.31%under Cd(150μM).In contrast,secondary metabolites such as proline and flavonoids increased,with a maximum proline accumulation of 0.71 mg/g under Cu(150μM)and a flavonoid concentration reaching 176.33 mg/g under Cu(100μM).These results show mechanisms of adaptation to stress,notably the accumulation of flavonoids and proline,while highlighting the increased toxicity of cadmium at high doses.These data are promising for applications in phytoremediation and sustainable agriculture.This study provides important data on the physiological and biochemical responses of plants to heavy metals and opens up prospects for phytoremediation applications.展开更多
The health effects of traffic-derived pollutants have gathered increasing concerns.Our objectives were to evaluate the associations of traffic-related heavy metal exposure with serum uric acid(SUA)and hyperuricemia an...The health effects of traffic-derived pollutants have gathered increasing concerns.Our objectives were to evaluate the associations of traffic-related heavy metal exposure with serum uric acid(SUA)and hyperuricemia and to explore the underlying mechanism.Traffic-related heavy metals(including zinc,iron,manganese,copper,lead,cadmium,antimony,and barium)and SUA were determined among 3909 community-based adults from the Wuhan-Zhuhai cohort.Various regression methods were applied to assess the association of heavy metals with SUA and hyperuricemia.Furthermore,mediation analyses were employed to evaluate the potential role of systemic inflammation in these associations.In single metal analyses,positive dose-response relationships between urinary zinc,iron,manganese,and antimony and SUA were observed.Furthermore,each 1-unit increase of ln-transformed urinary zinc levels was related to a 37.9%(OR=1.379,95%CI:1.148 to 1.657)increase in the hyperuricemia risk.In multiple metal analyses,both Bayesian kernel machine regression(BKMR)and weighted quantile sum regression(WQS)models showed positive associations of heavy metals mixture with SUA and hyperuricemia risk,and WQS analyses further revealed that zinc was the dominant metal(component weight:0.611 and 0.594,respectively).Additionally,plasma C-reactive protein(CRP)mediated 4.919%and 8.417%of the association of urinary zinc with SUA and hyperuricemia,respectively.In conclusion,exposure to several traffic-related heavy metals or traffic-related heavy metal mixtures were positively associated with SUA and hyperuricemia risk in the general Chinese population,in which zinc played a dominating role.Plasma CRP might partly mediate the association of urinary zinc with SUA and hyperuricemia risk.展开更多
文摘The surge in environmental pollution in recent years driven by numerous pollutants has necessitated the search for efficient removal methods.Phytoremediation is an eco-friendly technique that provides multiple benefits over conventional methods of removing contaminants.Despite the numerous benefits of this technique,it has certain limitations that can be addressed by incorporating nanoparticles to improve its effectiveness.This review paper aims to explore the impact of heavy metal pollution on plants and human health.It highlights the role and mechanism of nanoparticles in enhancing phytoremediation,their application in the detection of heavy metals,and the strategies for the safe disposal of phytoremediation biomass.Biosynthesized nanoparticles are eco-friendly and non-toxic,with applications in biomedical and environmental fields.Nanoparticles can be used in the form of nano biosensors like smartphone-operated wireless sensors made from Cinnamomum camphora,enabling efficient detection of heavy metal ions.According to the studies,nanoparticles remove 80%–97%of heavy metals by various methods like reduction,precipitation,adsorption,etc.The phytoremediation biomass disposal can be done by heat treatment,phytomining,and microbial treatment with some modifications to further enhance their results.Phytoremediation is an environmentally friendly technique but requires further research and integration with biomass energy production to overcome scalability challenges and ensure safe biomass disposal.
文摘Heavy metal(HM)contamination severely impacts global agricultural production.HMs toxicity effectively damaged the physiological functions such as imbalanced redox homeostasis,altered antioxidant enzyme activity,damage root system architecture,hindered photosynthetic apparatus,cellular toxicity,restricted mineral accumulation,and changed the metabolite production.Using phytohormones may be a successful strategy for enhancing and stimulating plant tolerance to HMs toxicity without affecting the environment.Melatonin(MT),a novel plant growth regulator,and powerful antioxidant molecule,enhances plant resilience to HMs stress by enhancing seedling growth,protecting the photosynthetic system,increasing nutritional status,balanced redox homeostasis,and restricting HMs accumulation from root to shoot.In addition,MT enhances the activity of antioxidant enzymes and triggers the ascorbate-glutathione(AsA-GSH)cycle,which helps remove excessive ROS.MT improves RuBisCO activity to improve photosynthesis and reduce the breakdown of chlorophyll.To identify future research needs,it is crucial to understand the comprehensive and intricate regulatory mechanisms of exogenous and endogenous MT-mediated reduction of heavy metal toxicity in plants.Melatonin has several functions,and this review sheds light on those functions and the molecular processes by which it alleviates HMs toxicity.More research is needed to fully understand how melatonin affects plant tolerance to heavy metals stress.
基金supported by the National Natural Science Foundation of China(No.22176200)the Industrial Innovation Entrepreneurial Team Project of Ordos 2021.
文摘Industrial waste salts are commonly used to make value-added snow-melting agents to ensure traffic safety in northern China during winter and spring after snowfall.However,heavy metals in industrial waste salts may pose certain environmental risks.Snow-melting agents and snow samples were collected and analyzed from highways,arterial roads,footbridges,and other locations in Beijing after the snowstorm in December 2023.It was found that the main component of snow-melting agents was sodium chloride with high concentrations of Cu,Mn,and Zn,which are not regulated in the current policies,despite the recent promotion of environmentally friendly snow-melting agents.The Pb,Zn and Cr contents of some snow samples exceeded the limitation value of surface water quality standards,potentially affecting the soil and water environment near roadsides,although the snow-melting agents comply with relevant standards,which indicates the policy gap in the management of recycled industrial salts.We reviewed and analyzed the relevant standards for snow-melting agents and industrial waste salts proposed nationally and internationally over the past 30 years.Through comparative analysis,we proposed relevant policy recommendations to the existing quality standards of snow-melting agents and the management regulations of industrial waste salts,and the formulation of corresponding usage strategies,aimed at reducing the potential environmental release of heavy metals from the use of snow-melting agents,thereby promoting more sustainable green urban development and environmentally sound waste management.
基金supported by the Research Funds of the Center for Big Data and Population Health of IHM(grant number JKS2022015)the Key Scientific Research Fund of the Anhui Provincial Education Department(grant number2023AH050610)the Anhui Natural Science Foundation(grant number 1808085QH252)。
文摘In 2021,approximately 537 million people suffered from diabetes mellitus(DM)globally,and this figure will increase to approximately 783 million within the next quarter-century.The increasing burden of DM is a pressing global public health issue.Therefore,the early identification of high-risk groups and implementation of effective intervention measures is imperative.
基金the outcome of project conducted at the Vietnam Academy of Science and Technology(VAST.07.05/24-25).
文摘Heavy metal pollution in coastal waters is on the rise,presenting serious threats to both ecosystems and human health.Coastal aquaculture zones,such as those in Quang Ninh province,are especially vulnerable due to the accumulation of heavy metals from multiple sources,including industrial wastewater,land runoff,and maritime activities.This study applies the Heavy Metal Pollution Index(HPI)to assess pollution levels based on the concentrations of nine heavy metals(Cr,Mn,Fe,Cu,Zn,As,Cd,Hg,Pb)found in seawater samples collected from coastal aquaculture areas in Quang Ninh.According to the HPI method,values exceeding 100 indicate polluted water,serving as a benchmark for evaluating heavy metal contamination in the region.A total of 25 seawater samples were collected and analyzed;of these,18 samples(72%)had HPI values above 100,signaling a concerning level of heavy metal pollution,while only 7 samples(28%)fell below the threshold,suggesting no significant contamination.These results underscore the urgent need for enhanced monitoring of water quality and stricter regulation of pollution sources to protect both environmental and public health.
基金supported by the National Natural Science Foundation of China(Nos.52105330,52175307)the Natural Science Foundation of Shandong Province,China(No.ZR2023JQ021)。
文摘The Sn−2Al filler metal was utilized to bond W90 tungsten heavy alloys by the ultrasonic-assisted coating technology in atmospheric environment at 250℃.The effects of ultrasonic power and ultrasonic time on microstructure and interfacial strength of Sn−2Al/W90 interface were investigated.The ultrasound improved the wettability of Sn−2Al filler metal on W90 surface.As the ultrasonic power increased and ultrasonic time increased,the size of Al phase in seam decreased.The maximum value of Sn−2Al/W90 interfacial strength reached 30.1 MPa.Based on the acoustic pressure simulation and bubble dynamics,the intensity of cavitation effect was proportional to ultrasonic power.The generated high temperature and high pressure by cavitation effect reached 83799.6 K and 1.26×10^(14) Pa,respectively.
基金supported by the National Natural Science Foundation of China(Nos.52100184,and U22A20617).
文摘Controlling heavy metal pollution in agricultural soil has been a significant challenge.These heavy metals seriously threaten the surrounding ecological environment and human health.The effective assessment and remediation of heavy metals in agricultural soils are crucial.These two aspects support each other,forming a close and complete decisionmaking chain.Therefore,this review systematically summarizes the distribution characteristics of soil heavy metal pollution,the correlation between soil and crop heavy metal contents,the presence pattern and migration and transformation mode of heavy metals in the soil-crop system.The advantages and disadvantages of the risk evaluation tools and models of heavy metal pollution in farmland are further outlined,which provides important guidance for an in-depth understanding of the characteristics of heavymetal pollution in farmland soils and the assessment of the environmental risk.Soil remediation strategies involve multiple physical,chemical,biological and even combined technologies,and this paper compares the potential and effect of the above current remediation technologies in heavy metal polluted farmland soils.Finally,the main problems and possible research directions of future heavy metal risk assessment and remediation technologies in agricultural soils are prospected.This review provides new ideas for effective assessment and selection of remediation technologies based on the characterization of soil heavy metals.
基金supported by the project of Sanya Yazhou Bay Science and Technology City,Grant No.SKJC-2023-02-004Education Department of Hainan Province,Grant No.Hnky2024ZD-27Key R&D Project of Hainan Province(Science and Technology Commissioner):405314040001.
文摘Soil naturally contains various heavy metals,however,their concentrations have reached toxic levels due to excessive agrochemical use and industrial activities.Heavy metals are persistent and non-biodegradable,causing environmental disruption and posing significant health hazards.Microbial-mediated remediation is a promising strategy to prevent heavy metal leaching and mobilization,facilitating their extraction and detoxification.Nickel(Ni),being a prevalent heavy metal pollutant,requires specific attention in remediation efforts.Plants have evolved defense mechanisms to cope with environmental stresses,including heavy metal toxicity,but such stress significantly reduces crop productivity.Beneficial microorganisms play a crucial role in enhancing plant yield and mitigating abiotic stress.The impact of heavy metal abiotic stress on plants’growth and productivity requires thorough investigation.Bioremediation using Nickel nanoparticles(Ni NPs)offers an effective approach to mitigating environmental pollution.Microorganisms contribute to nanoparticle bioremediation by immobilizing metals or inducing the synthesis of remediating microbial enzymes.Understanding the interactions between microorganisms,contaminants,and nanoparticles(NPs)is essential for advancing bioremediation strategies.This review focuses on the role of Bacillus subtilis in the bioremediation of nickel nanoparticles to mitigate environmental pollution and associated health risks.Furthermore,sustainable approaches are necessary to minimize metal contamination in seeds.The current review discusses bacterial inoculation in enhancing heavy metal tolerance,plant signal transduction pathways,and the transition from molecular to genomic research in metal stress adaptation.Moreover,the inoculation of advantageous bacteria is crucial for preserving plants under severe mental stress.Different researchers develop a complex,vibrant relationship with plants through a series of events known as plant-microbe interactions.It increases metal stress resistance through the creation of phytohormones.In general,the defensive responses of plants to heavy metal stress,mediated by microbial inoculation require further in-depth research.Further studies should explore the detoxification mechanism of nickel through bioremediation to develop more effective and sustainable remediation strategies.
基金supported by the National Natural Science Foundation of China(No.32171615)the National Key R&D Program of China(2019YFC1804102)。
文摘Agricultural soil is related to food security and human health,antibiotics and heavy metals(HMs),as two typical pollutants,possess a high coexistence rate in the environmental medium,which is extremely prone to inducing antibiotic-HMs combined pollution.Recently,frequent human activities have led to more prominent antibiotics-HMs combined contamination in agricultural soils,especially the production and spread of antibiotic resistance genes(ARGs),heavy metal resistance genes(MRGs),antibiotic resistant bacteria(ARB),and antibiotics-HMs complexes(AMCs),which seriously threaten soil ecology and human health.This review describes the main sources(Intrinsic and manmade sources),composite mechanisms(co-selective resistance,oxidative stress,and Joint toxicity mechanism),environmental fate and the potential risks(soil ecological and human health risks)of antibiotics and HMs in agricultural soils.Finally,the current effective source blocking,transmission control,and attenuation strategies are classified for discussion,such as the application of additives and barrier materials,as well as plant and animal remediation and bioremediation,etc.,pointing out that future research should focus on the whole chain process of“source-processterminal”,intending to provide a theoretical basis and decision-making reference for future research.
基金supported by the National Key Research and Development Program of China(No.2023YFC3710000)the National Natural Science Foundation of China(Nos.42277078 and 42307118).
文摘Abandoned mines,especially pyrite-rich ones,release acid mine drainage(AMD)with high acidity and excessive amounts of heavy metals,threatening regional ecosystems.Six samples of mine drainage,nine samples of surface water,and twelve samples of sediment were analyzed in this case study of the Dashu pyrite mine in southwest China.A comprehensive analysis of the pollution levels,pollution sources,and potential hazards of eight metals(Ni,Cd,Cu,Zn,Fe,Al,Pb,and Mn)that exceeded regulatory standardswas conducted bymonitoring 24 conventional and characteristic indicators.Ultimately,this research evaluated the environmental hazards associated with abandonedmine water using the"pressure-response"model,thereby providing valuable insights for the effective protection of the environment in mining regions.The primary pollutants in mine water were determined to be SO_(4)^(2−),Fe,and Mn,with concentrations of 7700,1450,and 6.78mg/L,respectively.A clear"source-sink"dynamic was observed between themine water and the surrounding water system.surface water was primarily polluted by Ni and Mn,while water system sediments were primarily polluted by Cu and Hg.Ion ratio and Pearson correlation analyses indicated heavy metals in surface water and sediments originated from the same AMD source.The"pressureresponse"model was used to assess the environmental hazards of water from abandoned mines.Mines W1,W2,W5,and W6 were classified as high-risk,while W3 and W4 were medium-risk.This study offers a novel approach and valuable reference for identifying and classifying environmental risks in abandoned mines and targeting AMD treatment.
基金supported by the National Key Research and Development Program of China(No.2019YFC1804501)the National Natural Science Foundation of China(Nos.42122056 and U1901210)+2 种基金Guangdong Basic and Applied Basic Research Foundation(No.2021B1515020063)the Key Research and Development Program of Guangdong Province(No.2021B1111380003)the Local Innovative and Research Teams Project of Guangdong Pearl River Talents Program(No.2017BT01Z032).
文摘Coking industry is a potential source of heavy metals(HMs)pollution.However,its impacts to the groundwater of surrounding residential areas have not been well understood.This study investigated the pollution characteristics and health risks of HMs in groundwater nearby a typical coking plant.Nine HMs including Fe,Zn,Mo,As,Cu,Ni,Cr,Pb and Cd were analyzed.The average concentration of total HMswas higher in the nearby area(244.27μg/L)than that of remote area away the coking plant(89.15μg/L).The spatial distribution of pollution indices including heavy metal pollution index(HPI),Nemerow index(NI)and contamination degree(CD),all demonstrated higher values at the nearby residential areas,suggesting coking activity could significantly impact the HMs distribution characteristics.Four sources of HMs were identified by Positive Matrix Factorization(PMF)model,which indicated coal washing and coking emission were the dominant sources,accounted for 40.4%,and 31.0%,respectively.Oral ingestionwas found to be the dominant exposure pathway with higher exposure dose to children than adults.Hazard quotient(HQ)values were below 1.0,suggesting negligible non-carcinogenic health risks,while potential carcinogenic risks were from Pb and Ni with cancer risk(CR)values>10−6.Monte Carlo simulation matched well with the calculated results with HMs concentrations to be the most sensitive parameters.This study provides insights into understanding how the industrial coking activities can impact the HMs pollution characteristics in groundwater,thus facilitating the implement of HMs regulation in coking industries.
基金supported d by the National Key Research and Development Program of China(No.2018YFC1802905).
文摘Two strains of Fe/Mn oxidizing bacteria tolerant to high concentrations of multiple heavy metal(loid)s and efficient decontamination for them were screened.The surface of the bio-Fe/Mn oxides produced by the oxidation of Fe(II)and Mn(II)by Pseudomonas taiwanensis(marked as P4)and Pseudomonas plecoglossicida(marked as G1)contains rich reactive oxygen functional groups,which play critical roles in the removal efficiency and immobilization of heavymetal(loid)s in co-contamination system.The isolated strains P4 and G1 can growwell in the following environments:pH 5-9,NaCl 0-4%,and temperature 20-30℃.The removal efficiencies of Fe,Pb,As,Zn,Cd,Cu,and Mn are effective after inoculation of the strains P4 and G1 in the simulated water system(the initial concentrations of heavy metal(loid)were 1 mg/L),approximately reaching 96%,92%,85%,67%,70%,54%and 15%,respectively.The exchangeable and carbonate bound As,Cd,Pb and Cu are more inclined to convert to the Fe-Mn oxide bound fractions in P4 and G1 treated soil,thereby reducing the phytoavailability and bioaccessible of heavy metal(loid)s.This research provides alternatives method to treat water and soil containing high concentrations of multi-heavy metal(loid)s.
基金funded by the Project of Yunnan Province’s Xingdian Talents Support Program(yfgrc202437)the Project of the International Cooperation Science Program of National Natural Science Foundation of China(42361144885).
文摘Phosphorus(P)poses a global challenge to the environment and human health due to its natural association with heavy metals.Sustainable use of P is crucial to ensure food security for future generations.An analysis of the 150 phosphate fertilizers stored at the Institute for Crop and Soil Science in Germany has been conducted,supplemented by previously published data.The elements Cd,Bi,U,Cr,Zn,Tl,As,B,Sb,Ni,and Se are found in higher concentrations in sedimentary derived phosphates compared to igneous derived phosphates.Mineral fertilizers contain more than ten times the amount of U,Cd,B,and As compared to farmyard manure.Principal component analyses(PCA)indicate that U,Cd,Be,and Cr are primarily present in sedimentary derived phosphates and their concentrations are 2 to 10 times higher than those in igneous derived phosphates.Regarding heavy metal contamination,over 1000 potential combinations were identified;36% of these were significant but weak(>0.1).It is estimated that approximately 707 t of uranium enter farmland annually through the application of mineral phosphate fertilizers in European countries.This contribution addresses environmental issues related to the utilization of rock phosphate as well as alternative production methods for cleaner and safer phosphate fertilizers while presenting a roadmap with measures for mitigation.
文摘Hydroxyapatite nanoparticles(HAP NPs)were synthesized by a one‐step hydrothermal method.The surface of HAP NPs was grafted-SH and-COOH chelating groups via in situ surface‐modification with iminodiacetic acid(IDA)and 3‐mercaptopropyl trimethoxysilane(MPS)to afford dual surface‐capped nano‐amendment HAPIDA/MPS.The structure of HAP‐IDA/MPS was characterized,and its adsorption performance for Hg^(2+),Cu^(2+),Zn^(2+),Ni^(2+),Co^(2+),and Cd^(2+)was evaluated.The total adsorption capacity of 0.10 g HAP‐IDA/MPS nano‐amendment for Hg^(2+),Cu^(2+),Zn^(2+),Ni^(2+),Co^(2+),and Cd^(2+)with an initial mass concentration of 20 mg·L^(-1) reached 13.7 mg·g^(-1),about 4.3 times as much as that of HAP.Notably,HAP‐IDA/MPS nano‐amendment displayed the highest immobilization rate for Hg^(2+),possibly because of its chemical reaction with-SH to form sulfide,possessing the lowest solubility product constant among a variety of metal sulfides.
基金National Natural Science Foundation of China(52074031)Key Research and Development Program of Shandong Province(ZR2021MB051,ZR2020ME256)。
文摘The traditional techniques for treating wastewater contaminated by heavy metals mostly involve chemical precipitation,solvent extraction and adsorption,ion-exchange,chemical precipitation,and membrane separation.The main shortcomings of traditional procedures are low economic efficiency,lack of environmental friendliness,and poor selectivity.Cyclodextrins are artificial compounds that resemble cages.Through host-vip interaction,pollutants can be adsorbed by its stable inner hydrophobic chamber and exterior hydrophilic surface.It is not only inexpensive and environmentally friendly,but also quite selective.The synthesis and application of materials were reviewed,as well as the primary influencing factors,and the reaction principle of cyclodextrin adsorbent materials for better separation of heavy metal ions.And the future trend of discovery was described.
文摘Industrial activities have contributed so much to the pollution of water bodies and these pollutions have adversely affected the aquatic ecosystem.This study aimed to investigate the ecological risk evaluation of heavy metal accumulation in Aba River bottom sediments:implications for soap and detergent industry wastewater management.Varian AA240 Atomic absorption spectrometer was used to analyse heavy metals.Individual and complex ecological indices were used to evaluate heavy metal contamination in bottom sediments.According to the results,the heavy metal properties of the wastewater indicated that Fe,Pb,Cd,Cr and Cu mean concentration values were higher than the World Health Organization(WHO)and the National Environmental Standards and Regulations Enforcement Agency(NESREA)permissible limits.Heavy metal properties of the surface water in Aba River(dry seasons)showed that Pb,Cd,Cu,Mn,Fe,and Cr,mean concentrations were above the NESREA,WHO and U.S.Environmental Protection Agency(USEPA)permissible limits.Heavy metal properties of the bottom sediments of Aba River(wet and dry season)showed that Pb,Cd,and Fe mean concentrations were significantly higher than the NESREA,WHO and USEPA permissible limits.The heavy metal contamination factor(CF)of sediments obtained from Aba River during the wet and dry season was low and the CFs of each of the assayed heavy metals were less than 1(CD<1).This also signifies the existence of a low contamination in the sediments of the course streams of Aba River during wet and dry season.The pollution load index(PLI)values of Aba River(sediment)indicated that there is no metal pollution at PLI<1 in the sampled sediments.The potential ecological risk index(RI)of Aba River was less than 150(RI<150)indicating a low ecological RI.Abatement of pollutants in the wastewater to permissible concentrations required for natural environment protection is needed.
基金supported by the National Key Research and Development Plan of China(No.2022YFE0197200)the National Natural Science Foundation of China(No.42277055).
文摘Urban rivers are one of the main water sources for local residents.However,the rapid industrialization and urbanization caused serious heavy metals pollution in urban rivers,which posed harmful impact on human health and ecosystem.In this study,134 sediment samples were collected fromurban rivers in a typical Economic and Technological Development Zone(ETDZ)to evaluate the contamination status,ecological risk,biotoxicity,and potential source of 8 heavy metals including arsenic(As),cadmium(Cd),chromium(Cr),copper(Cu),mercury(Hg),nickel(Ni),plumbum(Pb),and zinc(Zn).Results showed that the average concentrations of all 8 metals exceeded their corresponding background values and followed the trend:Cr(248.67 mg/kg)>Pb(123.58 mg/kg)>Zn(67.06 mg/kg)>Ni(47.19 mg/kg)>Cu(27.40 mg/kg)>As(16.15 mg/kg)>Cd(0.62mg/kg)>Hg(0.21mg/kg).A high contamination and accumulation tendency of Cd and Cr were found in the sediments.Moreover,Cd and Hg were the main contributors of ecological risk,and posed moderate to high risk.In terms of biotoxicity,all the sediment samples were harmful to benthic organisms.Two possible pollution sources of heavy metals were identified:one is a combined source of industrial and traffic pollution dominated by Cr and Pd,the other is an industrial pollution source consisting of six heavy metals(Ni,Zn,Cd,Hg,As,and Cu).This study provides insights into heavy metals pollution management and risk control in the ETDZ and similar urban rivers worldwide due to intense industrialization.
基金supported by the National Natural Science Foundation of China(Nos.52370158 and 22006053)Guangzhou Science and Technology Plan Project(No.2024A04J0821)Guangdong Provincial Education Science Planning Project(Higher Education Special Project)(No.2023GXJK108).
文摘Electroplating sludge(ES),a byproduct of the electroplating industry,is a significant environmental concern due to its high content of soluble heavy metals(HMs).The significance of spinel formation from ES lies in its potential for HMs enrichment and environmental remediation,offering a sustainable solution for hazardous waste management.The article delves into themultifaceted recycling of HMs-rich spinel fromES,encompassing its synthesis,metal enrichment,and thermodynamic stability.The pyro-metallurgical and hydrometallurgical processes for spinel synthesis were discussed,with a focus on the critical role of thermodynamic data in predicting the stability and formation of spinel structures.The crystallographic and magnetic properties of spinels,with their applications in environmental remediation and energy storage are highlighted.The article provides a comprehensive reviewon the recycling of HMs-rich spinel fromES,offering a means to recycle HMs,mitigate ecological harm,and contribute to a circular economy through the recovery and application of valuable materials.The selective leaching of metals from ES also faces challenges,which was limited by the separation,purification steps and high energy consumption.This high energy consumption is a significant operational cost and also contributes to environmental concerns related to carbon emissions.It is essential to address the challenges through continued research and development,improved technologies,and supportive regulatory frameworks.
文摘This study evaluates the impact of heavy metals(zinc,copper and cadmium)on the development and metabolic responses of the maize(Zea mays)variety“Torro Plus”.Seeds were cultivated on MS medium enriched with progressively higher concentrations of heavy metals(50,100 and 150μM),and plants were analyzed after 21 days.The results show a significant reduction in morphological parameters,notably an 87.28%decrease in the fresh weight of aerial parts and a 69.93%decrease in the fresh weight of roots under 150μM of Cd.Chlorophyll a,b and total content also decreased drastically,reaching a maximum reduction of 74.31%under Cd(150μM).In contrast,secondary metabolites such as proline and flavonoids increased,with a maximum proline accumulation of 0.71 mg/g under Cu(150μM)and a flavonoid concentration reaching 176.33 mg/g under Cu(100μM).These results show mechanisms of adaptation to stress,notably the accumulation of flavonoids and proline,while highlighting the increased toxicity of cadmium at high doses.These data are promising for applications in phytoremediation and sustainable agriculture.This study provides important data on the physiological and biochemical responses of plants to heavy metals and opens up prospects for phytoremediation applications.
基金supported by the Key Program of the National Natural Science Foundation of China(No.82241088).
文摘The health effects of traffic-derived pollutants have gathered increasing concerns.Our objectives were to evaluate the associations of traffic-related heavy metal exposure with serum uric acid(SUA)and hyperuricemia and to explore the underlying mechanism.Traffic-related heavy metals(including zinc,iron,manganese,copper,lead,cadmium,antimony,and barium)and SUA were determined among 3909 community-based adults from the Wuhan-Zhuhai cohort.Various regression methods were applied to assess the association of heavy metals with SUA and hyperuricemia.Furthermore,mediation analyses were employed to evaluate the potential role of systemic inflammation in these associations.In single metal analyses,positive dose-response relationships between urinary zinc,iron,manganese,and antimony and SUA were observed.Furthermore,each 1-unit increase of ln-transformed urinary zinc levels was related to a 37.9%(OR=1.379,95%CI:1.148 to 1.657)increase in the hyperuricemia risk.In multiple metal analyses,both Bayesian kernel machine regression(BKMR)and weighted quantile sum regression(WQS)models showed positive associations of heavy metals mixture with SUA and hyperuricemia risk,and WQS analyses further revealed that zinc was the dominant metal(component weight:0.611 and 0.594,respectively).Additionally,plasma C-reactive protein(CRP)mediated 4.919%and 8.417%of the association of urinary zinc with SUA and hyperuricemia,respectively.In conclusion,exposure to several traffic-related heavy metals or traffic-related heavy metal mixtures were positively associated with SUA and hyperuricemia risk in the general Chinese population,in which zinc played a dominating role.Plasma CRP might partly mediate the association of urinary zinc with SUA and hyperuricemia risk.
