The complex[(CNC)^(Mes)Rh(PMe_(2)Ph)]PF6(1)has been found to be an effective catalyst for solventless formic acid(FA)dehydrogenation,affording exclusively H_(2)and CO_(2)as decomposition products.The effect of the add...The complex[(CNC)^(Mes)Rh(PMe_(2)Ph)]PF6(1)has been found to be an effective catalyst for solventless formic acid(FA)dehydrogenation,affording exclusively H_(2)and CO_(2)as decomposition products.The effect of the addition of a base as a co-catalyst was studied,and it was found that HCOONa was the most efficient additive in terms of catalyst efficiency with a catalyst loading of 0.016 mol%,reaching TOF_(max)values up to 5869 h^(−1).展开更多
基金PGC2018-099383-B-I00 and RTI2018-099136-A-I00 funded by MCIN/AEI/10.13039/501100011033by“ERDF A way of making Europe”,DGA/FSE(group E42_20R)CSIC project 202080I024 are gratefully acknowledged.The co-author V.P.thankfully acknowledges the resources from the supercomputers“Memento”and the technical expertise and assistance provided by the Institute for Biocomputation and Physics of Complex Systems(BIFI)–Universidad de Zaragoza.A.U.thankfully acknowledges the Spanish MECD for an FPU fellowship(FPU 2017/05417).
文摘The complex[(CNC)^(Mes)Rh(PMe_(2)Ph)]PF6(1)has been found to be an effective catalyst for solventless formic acid(FA)dehydrogenation,affording exclusively H_(2)and CO_(2)as decomposition products.The effect of the addition of a base as a co-catalyst was studied,and it was found that HCOONa was the most efficient additive in terms of catalyst efficiency with a catalyst loading of 0.016 mol%,reaching TOF_(max)values up to 5869 h^(−1).
