Shape memory polymers used in 4D printing only had one permanent shape after molding,which limited their applications in requiring multiple reconstructions and multifunctional shapes.Furthermore,the inherent stability...Shape memory polymers used in 4D printing only had one permanent shape after molding,which limited their applications in requiring multiple reconstructions and multifunctional shapes.Furthermore,the inherent stability of the triazine ring structure within cyanate ester(CE)crosslinked networks after molding posed significant challenges for both recycling,repairing,and degradation of resin.To address these obstacles,dynamic thiocyanate ester(TCE)bonds and photocurable group were incorporated into CE,obtaining the recyclable and 3D printable CE covalent adaptable networks(CANs),denoted as PTCE1.5.This material exhibits a Young's modulus of 810 MPa and a tensile strength of 50.8 MPa.Notably,damaged printed PTCE1.5 objects can be readily repaired through reprinting and interface rejoining by thermal treatment.Leveraging the solid-state plasticity,PTCE1.5 also demonstrated attractive shape memory ability and permanent shape reconfigurability,enabling its reconfigurable 4D printing.The printed PTCE1.5 hinges and a main body were assembled into a deployable and retractable satellite model,validating its potential application as a controllable component in the aerospace field.Moreover,printed PTCE1.5 can be fully degraded into thiol-modified intermediate products.Overall,this material not only enriches the application range of CE resin,but also provides a reliable approach to addressing environmental issue.展开更多
为了准确判断电池可用容量,采用长短期记忆神经网络对电池容量进行估算。首先分析电池各参数全生命周期变化曲线,计算其与电池容量之间的皮尔逊相关系数,选择电池电压、内阻、等压降时间等参数作为健康因子构建电池容量估计模型。使用...为了准确判断电池可用容量,采用长短期记忆神经网络对电池容量进行估算。首先分析电池各参数全生命周期变化曲线,计算其与电池容量之间的皮尔逊相关系数,选择电池电压、内阻、等压降时间等参数作为健康因子构建电池容量估计模型。使用美国先进寿命周期工程中心CALCE(Center for Advanced Life Cycle Engineering)电池数据集进行模型训练并估算电池容量,估计模型的平均百分误差为1.19%。分析估算误差产生的原因,通过电池初始容量参数修正和电池老化参数修正进行模型优化。优化结果表明,使用电池电压、内阻、恒流充电时间和4.0~3.4 V等压降时间构建模型估计误差在0.55%左右。展开更多
开展公路隧道结构状态精准预测是掌握隧道结构状态变化、识别潜在安全风险和保障安全运营的重要技术手段。针对隧道监控量测测点的空间分布与时序特性,提出了一种基于河马优化(Hippopotamus Optimization, HO)算法和卷积神经网络(Convol...开展公路隧道结构状态精准预测是掌握隧道结构状态变化、识别潜在安全风险和保障安全运营的重要技术手段。针对隧道监控量测测点的空间分布与时序特性,提出了一种基于河马优化(Hippopotamus Optimization, HO)算法和卷积神经网络(Convolutional Neural Network, CNN)的双向长短期记忆(Bidirectional Long Short Term Memory, BiLSTM)网络公路隧道结构状态预测方法。量化分析测点间关联性,结合温度特征构建模型输入矩阵;利用CNN挖掘各测点的空间关联性,采用BiLSTM提取时间序列特征,引入HO算法优化模型参数;将预测结果映射为隧道结构状态等级,展示隧道整体受力状态。结果表明,建立的HO-CNN-BiLSTM模型能够有效提取空间和温度特征,在预测精度和稳定性方面均优于对比模型,可实现隧道结构状态精确评估,为公路隧道的安全运营及分级管控措施制定提供技术支撑。展开更多
基金supported by the National Natural Science Foundation of China(Nos.52473080,52403167 and 52173079)the Fundamental Research Funds for the Central Universities(Nos.xtr052023001 and xzy012023037)+1 种基金the Postdoctoral Research Project of Shaanxi Province(No.2024BSHSDZZ054)the Shaanxi Laboratory of Advanced Materials(No.2024ZY-JCYJ-04-12).
文摘Shape memory polymers used in 4D printing only had one permanent shape after molding,which limited their applications in requiring multiple reconstructions and multifunctional shapes.Furthermore,the inherent stability of the triazine ring structure within cyanate ester(CE)crosslinked networks after molding posed significant challenges for both recycling,repairing,and degradation of resin.To address these obstacles,dynamic thiocyanate ester(TCE)bonds and photocurable group were incorporated into CE,obtaining the recyclable and 3D printable CE covalent adaptable networks(CANs),denoted as PTCE1.5.This material exhibits a Young's modulus of 810 MPa and a tensile strength of 50.8 MPa.Notably,damaged printed PTCE1.5 objects can be readily repaired through reprinting and interface rejoining by thermal treatment.Leveraging the solid-state plasticity,PTCE1.5 also demonstrated attractive shape memory ability and permanent shape reconfigurability,enabling its reconfigurable 4D printing.The printed PTCE1.5 hinges and a main body were assembled into a deployable and retractable satellite model,validating its potential application as a controllable component in the aerospace field.Moreover,printed PTCE1.5 can be fully degraded into thiol-modified intermediate products.Overall,this material not only enriches the application range of CE resin,but also provides a reliable approach to addressing environmental issue.
文摘针对不同磁密幅值、频率、谐波组合等复杂激励工况下磁致伸缩建模面临的精准性问题,该文利用空间注意力机制(spatial attention mechanism,SAM)对传统的卷积神经网络(convolutional neural network,CNN)进行改进,将SAM嵌套入CNN网络中,建立SAMCNN改进型网络。再结合双向长短期记忆(bidirectional long short-term memory,BiLSTM)网络,提出电工钢片SAMCNN-BiLSTM磁致伸缩模型。首先,利用灰狼优化算法(grey wolf optimization,GWO)寻优神经网络结构的参数,实现复杂工况下磁致伸缩效应的准确表征;然后,建立中低频范围单频与叠加谐波激励等复杂工况下的磁致伸缩应变数据库,开展数据预处理与特征分析;最后,对SAMCNN-BiLSTM模型开展对比验证。对比叠加3次谐波激励下的磁致伸缩应变频谱主要分量,SAMCNN-BiLSTM模型计算值最大相对误差为3.70%,其比Jiles-Atherton-Sablik(J-A-S)、二次畴转等模型能更精确地表征电工钢片的磁致伸缩效应。
文摘为了准确判断电池可用容量,采用长短期记忆神经网络对电池容量进行估算。首先分析电池各参数全生命周期变化曲线,计算其与电池容量之间的皮尔逊相关系数,选择电池电压、内阻、等压降时间等参数作为健康因子构建电池容量估计模型。使用美国先进寿命周期工程中心CALCE(Center for Advanced Life Cycle Engineering)电池数据集进行模型训练并估算电池容量,估计模型的平均百分误差为1.19%。分析估算误差产生的原因,通过电池初始容量参数修正和电池老化参数修正进行模型优化。优化结果表明,使用电池电压、内阻、恒流充电时间和4.0~3.4 V等压降时间构建模型估计误差在0.55%左右。
文摘开展公路隧道结构状态精准预测是掌握隧道结构状态变化、识别潜在安全风险和保障安全运营的重要技术手段。针对隧道监控量测测点的空间分布与时序特性,提出了一种基于河马优化(Hippopotamus Optimization, HO)算法和卷积神经网络(Convolutional Neural Network, CNN)的双向长短期记忆(Bidirectional Long Short Term Memory, BiLSTM)网络公路隧道结构状态预测方法。量化分析测点间关联性,结合温度特征构建模型输入矩阵;利用CNN挖掘各测点的空间关联性,采用BiLSTM提取时间序列特征,引入HO算法优化模型参数;将预测结果映射为隧道结构状态等级,展示隧道整体受力状态。结果表明,建立的HO-CNN-BiLSTM模型能够有效提取空间和温度特征,在预测精度和稳定性方面均优于对比模型,可实现隧道结构状态精确评估,为公路隧道的安全运营及分级管控措施制定提供技术支撑。
文摘目的探讨自回归移动平均模型-长短期记忆(autoregressive integrated moving average-long short-term memory,ARIMA-LSTM)组合模型在肾综合征出血热(hemorrhagic fever with renal syndrome,HFRS)不同流行模式发病率预测中应用的可行性。方法收集1961—2020年全国HFRS年发病率、2004年1月至2020年12月全国、黑龙江省、吉林省、辽宁省、陕西省、山东省、河北省、广东省HFRS逐月发病率数据;全国及黑龙江省作为冬峰较春峰高代表,吉林省、辽宁省作为春峰与冬峰相当代表,陕西省、山东省作为仅存在冬峰代表,河北省、广东省作为仅存在春峰代表。1961—2014年逐年发病率、2004年1月至2020年6月逐月发病率数据作为训练集,2015—2020年逐年发病率、2020年7-12月逐月发病率数据作为测试集。分别建立ARIMA模型、ARIMA-LSTM组合模型,采用平均绝对百分比误差下降率(decline rate of mean absolute percentage error,DR_(MAPE))、均方根误差下降率(decline rate of root mean squared error,DRRMSE)评价模型拟合及预测精度优化程度。结果全国逐年、全国及黑龙江省、吉林省、辽宁省、陕西省、山东省、河北省、广东省逐月HFRS发病率拟合最佳ARIMA模型分别为ARIMA(2,0,0)、ARIMA(3,1,0)(2,1,1)_(12)、ARIMA(2,0,1)(2,1,1)_(12)、ARIMA(3,0,0)(2,1,1)_(12)含常数项、ARIMA(2,1,1)(2,1,1)_(12)、ARIMA(1,0,3)(1,1,0)_(12)、ARIMA(0,1,3)(2,1,1)_(12)、ARIMA(1,1,3)(2,0,0)_(12)、ARIMA(3,1,1)(1,1,1)_(12)。全国逐年、全国及黑龙江省、吉林省、辽宁省、陕西省、山东省、河北省、广东省逐月数据建立ARIMA-LSTM组合模型较ARIMA模型拟合的DR_(MAPE)依次为-19.57%、-46.38%、-43.27%、-46.37%、-49.70%、-48.36%、-58.23%、-35.52%、-48.74%;DRRMSE依次为-11.21%、-36.17%、-64.89%、-55.68%、-54.81%、-31.76%、-39.69%、-55.64%、-30.06%。全国逐年、全国及黑龙江省、吉林省、辽宁省、陕西省、山东省、河北省、广东省逐月数据建立ARIMA-LSTM组合模型较ARIMA模型预测的DR_(MAPE)依次为-11.10%、-8.69%、-19.68%、-36.17%、-55.57%、-9.44%、-14.60%、-14.22%、-9.26%;DRRMSE依次为-14.43%、-7.42%、-12.66%、-13.83%、-36.56%、10.37%、81.14%、-19.68%、-1.18%。结论ARIMA-LSTM组合模型总体在各类HFRS数据中拟合及预测效果均优于ARIMA模型,LSTM适于我国HFRS预测模型优化,但陕西省和山东省不适于ARIMA-LSTM预测。
