Municipal sewage from an oxidation ditch was treated for reuse by nanofiltration（NF） in this study. The NF performance was optimized, and its fouling characteristics after different operational durations（i.e., 48 a...Municipal sewage from an oxidation ditch was treated for reuse by nanofiltration（NF） in this study. The NF performance was optimized, and its fouling characteristics after different operational durations（i.e., 48 and 169 hr） were analyzed to investigate the applicability of nanofiltration for water reuse. The optimum performance was achieved when transmembrane pressure = 12 bar, p H = 4 and flow rate = 8 L/min using a GE membrane. The permeate water quality could satisfy the requirements of water reclamation for different uses and local standards for water reuse in Beijing. Flux decline in the fouling experiments could be divided into a rapid flux decline and a quasi-steady state. The boundary flux theory was used to predict the evolution of permeate flux. The expected operational duration based on the 169-hr experiment was 392.6 hr which is 175% longer than that of the 48-hr one. High molecular weight（MW） protein-like substances were suggested to be the dominant foulants after an extended period based on the MW distribution and the fluorescence characteristics. The analyses of infrared spectra and extracellular polymeric substances revealed that the roles of both humic- and polysaccharide-like substances were diminished, while that of protein-like substances were strengthened in the contribution of membrane fouling with time prolonged. Inorganic salts were found to have marginally influence on membrane fouling. Additionally, alkali washing was more efficient at removing organic foulants in the long term, and a combination of water flushing and alkali washing was appropriate for NF fouling control in municipal sewage treatment.展开更多
As a major configuration of membrane elements,multi-channel porous inorganic membrane tubes were studied by means of theoretical analysis and simulation.Configuration optimization of a cylindrical 37-channel porous in...As a major configuration of membrane elements,multi-channel porous inorganic membrane tubes were studied by means of theoretical analysis and simulation.Configuration optimization of a cylindrical 37-channel porous inorganic membrane tube was studied by increasing membrane filtration area and increasing permeation efficiency of inner channels.An optimal ratio of the channel diameter to the inter-channel distance was proposed so as to increase the total membrane filtration area of the membrane tube.The three-dimensional computational fluid dynamics(CFD) simulation was conducted to study the cross-flow permeation flow of pure water in the 37-channel ceramic membrane tube.A model combining Navier–Stokes equation with Darcy's law and the porous jump boundary conditions was applied.The relationship between permeation efficiency and channel locations,and the method for increasing the permeation efficiency of inner channels were proposed.Some novel multichannel membrane configurations with more permeate side channels were put forward and evaluated.展开更多
When designing and building an optimal reverse osmosis (RO) desalination plant, it is important that engineers select effective membrane parameters for optimal application performance. The membrane selection can deter...When designing and building an optimal reverse osmosis (RO) desalination plant, it is important that engineers select effective membrane parameters for optimal application performance. The membrane selection can determine the success or failure of the entire desalination operation. The objective of this work is to review available membrane types and design parameters that can be selected for optimal application to yield the highest potential for plant operations. Factors such as osmotic pressure, water flux values, and membrane resistance will all be evaluated as functions of membrane parameters. The optimization of these parameters will be determined through the deployment of the solution-diffusion model devolved from the Maxwell Stephan Equation. When applying the solution-diffusion model to evaluate RO membranes, the Maxwell Stephan Equation provides mathematical analysis through which the steps for mass transfer through a RO membrane may be observed and calculated. A practical study of the use of the solution-diffusion model will be discussed. This study uses the diffusion-solution model to evaluate the effectiveness of a variety of Toray RO membranes. This practical application confirms two principal hypotheses when using the diffusion-solution model for membrane evaluation. First, there is an inverse relationship between membrane and water flux rate. Second, there is a proportional linear relationship between overall water flux rate and the applied pressure across a membrane.展开更多
基金supported by the Major Science & Technology Projects for Water Pollution Control and Management of China (Nos. 2012ZX07203-002 2015ZX07203-005)
文摘Municipal sewage from an oxidation ditch was treated for reuse by nanofiltration（NF） in this study. The NF performance was optimized, and its fouling characteristics after different operational durations（i.e., 48 and 169 hr） were analyzed to investigate the applicability of nanofiltration for water reuse. The optimum performance was achieved when transmembrane pressure = 12 bar, p H = 4 and flow rate = 8 L/min using a GE membrane. The permeate water quality could satisfy the requirements of water reclamation for different uses and local standards for water reuse in Beijing. Flux decline in the fouling experiments could be divided into a rapid flux decline and a quasi-steady state. The boundary flux theory was used to predict the evolution of permeate flux. The expected operational duration based on the 169-hr experiment was 392.6 hr which is 175% longer than that of the 48-hr one. High molecular weight（MW） protein-like substances were suggested to be the dominant foulants after an extended period based on the MW distribution and the fluorescence characteristics. The analyses of infrared spectra and extracellular polymeric substances revealed that the roles of both humic- and polysaccharide-like substances were diminished, while that of protein-like substances were strengthened in the contribution of membrane fouling with time prolonged. Inorganic salts were found to have marginally influence on membrane fouling. Additionally, alkali washing was more efficient at removing organic foulants in the long term, and a combination of water flushing and alkali washing was appropriate for NF fouling control in municipal sewage treatment.
基金Supported by the National Basic Research Program of China(2012CB224806)the National Natural Science Foundation of China(21490584,21476236)the National High Technology Research and Development Program of China(2012AA03A606)
文摘As a major configuration of membrane elements,multi-channel porous inorganic membrane tubes were studied by means of theoretical analysis and simulation.Configuration optimization of a cylindrical 37-channel porous inorganic membrane tube was studied by increasing membrane filtration area and increasing permeation efficiency of inner channels.An optimal ratio of the channel diameter to the inter-channel distance was proposed so as to increase the total membrane filtration area of the membrane tube.The three-dimensional computational fluid dynamics(CFD) simulation was conducted to study the cross-flow permeation flow of pure water in the 37-channel ceramic membrane tube.A model combining Navier–Stokes equation with Darcy's law and the porous jump boundary conditions was applied.The relationship between permeation efficiency and channel locations,and the method for increasing the permeation efficiency of inner channels were proposed.Some novel multichannel membrane configurations with more permeate side channels were put forward and evaluated.
文摘When designing and building an optimal reverse osmosis (RO) desalination plant, it is important that engineers select effective membrane parameters for optimal application performance. The membrane selection can determine the success or failure of the entire desalination operation. The objective of this work is to review available membrane types and design parameters that can be selected for optimal application to yield the highest potential for plant operations. Factors such as osmotic pressure, water flux values, and membrane resistance will all be evaluated as functions of membrane parameters. The optimization of these parameters will be determined through the deployment of the solution-diffusion model devolved from the Maxwell Stephan Equation. When applying the solution-diffusion model to evaluate RO membranes, the Maxwell Stephan Equation provides mathematical analysis through which the steps for mass transfer through a RO membrane may be observed and calculated. A practical study of the use of the solution-diffusion model will be discussed. This study uses the diffusion-solution model to evaluate the effectiveness of a variety of Toray RO membranes. This practical application confirms two principal hypotheses when using the diffusion-solution model for membrane evaluation. First, there is an inverse relationship between membrane and water flux rate. Second, there is a proportional linear relationship between overall water flux rate and the applied pressure across a membrane.
