The effects of different aging processes on the microstructure and mechanical properties of a novel Al-Cu-Li alloy have been investigated by X-ray diffraction, scanning electron microscopy and transmission electron mi...The effects of different aging processes on the microstructure and mechanical properties of a novel Al-Cu-Li alloy have been investigated by X-ray diffraction, scanning electron microscopy and transmission electron microscopy. It is found that the tensile properties of a novel Al-Cu-Li alloy are sensitive to aging processes, which correspond to different microstructures. σ（Al_5Cu_6Mg_2） and T_1（Al_2CuLi） phases are the major precipitates for the alloy in T6 aging condition（165 ℃/60 h）. After duplex aging condition（150 ℃/24 h ＋ 180 ℃/12 h）, σ, θ＇（Al_2Cu） and T_1 phases are detected. Only the T_1 phases can be found in the T8 state alloy（6% pre-strain＋135 ℃/60 h）. The failure modes of alloy in T6 and duplex aging conditions are dimple-intergranular fracture, while typical quasi-cleavage fracture in T8 condition.展开更多
The evolution of microstructure and mechanical properties of A356 aluminum alloy subjected to hot spinning process has been investigated. The results indicated that the deformation process homogenized microstructure a...The evolution of microstructure and mechanical properties of A356 aluminum alloy subjected to hot spinning process has been investigated. The results indicated that the deformation process homogenized microstructure and improved mechanical properties of the A356 aluminum alloy. During the hot spinning process, eutectic Si particles and Fe-rich phases were fragmented, and porosities were eliminated. In addition, recrystallization of Al matrix and precipitation of Al Si Ti phases occurred. The mechanical property testing results indicated that there was a significant increase of ductility and a decrease of average microhardness in deformed alloy over die-cast alloy. This is attributed to uniform distribution of finer spherical eutectic Si particles, the elimination of casting defects and to the recrystallized finer grain structure.展开更多
Since the launch of the economic reform and opening to the outside world, China has seen rapid growth in its export of mechanical and electrical products, with its export
In response to the new mechanism of direct vortex melting reduction of vanadium–titanium magnetite,the reaction control mechanism and the migration regularity of valuable components in the process of direct melting r...In response to the new mechanism of direct vortex melting reduction of vanadium–titanium magnetite,the reaction control mechanism and the migration regularity of valuable components in the process of direct melting reduction were investigated using kinetic empirical equation by fitting and combining with X-ray diffraction,X-ray fluorescence,scanning electron microscopy,energy-dispersive spectrometry,and optical microscopy.The results show that iron reduction is controlled by the mass transfer process of(FeOx)in the slag,while vanadium reduction is controlled by both the mass transfer of(VOx)in the slag and the mass transfer of[V]in the molten iron,and the slag–metal interfacial reaction is the only pathway for vanadium reduction.The reduction of iron and vanadium is an obvious first-order reaction,with activation energy of 101.6051 and 197.416 kJ mol^(−1),respectively.Increasing the vortex rate and reaction temperature is beneficial to improving the reaction rate and reduction efficiency.The mineral phase variation of iron and vanadium in the slag during the reduction process is Fe_(2)O_(3)→Fe_(3)O_(4)/FeV_(2)O_(4)→FeTiO_(3) and FeV_(2)O_(4)→MgV_(2)O_(5);titanium in slag is mainly in the form of Mg_(x)Ti_(3−x)O_(5)(0≤x≤1)and CaTiO_(3).As the reaction time went on,the molar ratio(nTi/nMg)in Mg_(x)Ti_(3−x)O_(5)(0≤x≤1)and the Ti2O_(3) content in the slag gradually went up,while the area proportion of Mg_(x)Ti_(3−x)O_(5)(0≤x≤1)went up and then down,and the porosity of the slag and the grain size of Mg_(x)Ti_(3−x)O_(5)(0≤x≤1)got smaller.展开更多
Three dimensional thermal-mechanical coupled elasto-plastic FEM has been used for simulation of round to oval single pass rolling. The analysis was conducted using MARC/AUTOFORCE1. 2 code. The material is assumed to b...Three dimensional thermal-mechanical coupled elasto-plastic FEM has been used for simulation of round to oval single pass rolling. The analysis was conducted using MARC/AUTOFORCE1. 2 code. The material is assumed to be elasto-plastic and it obey the Von Mises yield criterion and Prandtl- Reuss rule. Deformation of the workpiece is simulated in a step-by-step manner,updating the coordinates of material points and the property after each step, so that both nonsteady-state and stendy-state deformation can be simulated. The heat transfter between the workpiece, the rolls, and enviroment and the heat generation due to plastic work and friction force, are considered in the analys- is.Predicted the deformation shape of the workpiece, distributions of strains, stresses, strain rates and temperatures, roll-separating force and roll torque are presented.展开更多
The formation mechanisms and processes of geochemical anomalies used as proxies in surface geochemistry exploration （SGE） have not been well understood. Previous studies cannot realize 3D measurement of microseeping...The formation mechanisms and processes of geochemical anomalies used as proxies in surface geochemistry exploration （SGE） have not been well understood. Previous studies cannot realize 3D measurement of microseeping hydrocarbons from reservoirs to the surface, which made it difficult to understand the features and pathways of deep hydrocarbon microseepages. Understanding the processes of hydrocarbon microseepages will contribute to the acceptance and effectiveness of surface geochemistry. Based on a simplified geological model of hydrocarbon microseepages, including hydrocarbon reservoir, direct caprock, overlying strata and Quaternary sediments, this work established a 3D experimental system to simulate the mechanisms and processes of deep hydrocarbon microseepes extending to the surface. The dispersive halos of microseeping hydrocarbons in the subsurface were adequately described by using this 3D experimental system. Results indicate that different migration patterns of hydrocarbons above the point gas source within the simulated caprock and overlying strata can be reflected by the ratio of i-butane to n-butane （i-C4/n-C4）, which follow diffusion and infiltration （buoyancy） mechanisms. This is not the case for vertical measurement lines far from the point gas source. A vertical gas flow in the form of a plume was found during hydrocarbon microseepage. For sampling methods, the high-density grid sampling is favorable for delineating prospecting targets. Hydrocarbon infiltration or buoyancy flow occurs in the zones of infiltration clusters, coupling with a diffusion mechanism at the top of the water table and forming surface geochemical anomalies. These results are significant in understanding hydrocarbon microseepage and interpreting SGE data.展开更多
A successful mechanical property data-driven prediction model is the core of the optimal design of hot rolling process for hot-rolled strips. However, the original industrial data, usually unbalanced, are inevitably m...A successful mechanical property data-driven prediction model is the core of the optimal design of hot rolling process for hot-rolled strips. However, the original industrial data, usually unbalanced, are inevitably mixed with fluctuant and abnormal values. Models established on the basis of the data without data processing can cause misleading results, which cannot be used for the optimal design of hot rolling process. Thus, a method of industrial data processing of C-Mn steel was proposed based on the data analysis. The Bayesian neural network was employed to establish the reliable mechanical property prediction models for the optimal design of hot rolling process. By using the multi-objective optimization algorithm and considering the individual requirements of costumers and the constraints of the equipment, the optimal design of hot rolling process was successfully applied to the rolling process design for Q345B steel with 0.017% Nb and 0.046% Ti content removed. The optimal process design results were in good agreement with the industrial trials results, which verify the effectiveness of the optimal design of hot rolling process.展开更多
For Gu-Ag alloy, an important parameter called workability in the forming process of materials can be evaluated by processing maps yielded from the stress-strain data generated by hot compression tests at temperatures...For Gu-Ag alloy, an important parameter called workability in the forming process of materials can be evaluated by processing maps yielded from the stress-strain data generated by hot compression tests at temperatures of 700-850 °C and strain rates of 0.01-10 s-1. And at the true strain of 0.15, 0.35 and 0.55, respectively, the responses of strain-rate sensitivity, power dissipation efficiency and instability parameter to temperature and strain rate were studied. Instability maps and power dissipation maps were superimposed to form processing maps, which reveal the determinate regions where individual metallurgical processes occur and the limiting conditions of flow instability regions. Furthermore, the optimal processing parameters for bulk metal working are identified clearly by the processing maps.展开更多
For the lack of the present hot metal desulfurization processes in iron and steel industry, our group has proposed the in-situ mechanical stirring method for external desulfurization of molten iron and researched this...For the lack of the present hot metal desulfurization processes in iron and steel industry, our group has proposed the in-situ mechanical stirring method for external desulfurization of molten iron and researched this new method. This paper investigated this new in-situ mechanical stirring hot metal desulphurization process on desulphurization experiments of one-ton scale by using the new desulfurizer. The experimental results indicated that the desulfurization efficiency of in-situ mechanical stirring desulfurization process is 90% and the lowest sulfur content in the treated hot metal is 23ppm. By comparing with the methods of direct throwing desulfurizer and in-situ injecting desulfurization, in-situ mechanical stirring desulfurization process is the suitable desulfurizaton method.展开更多
Halogenated aromatic compounds have attracted increasing concerns due to their toxicity and persistency in the environment, and dehalogenation is one of the promising treatment and detoxification methods. Herein, we s...Halogenated aromatic compounds have attracted increasing concerns due to their toxicity and persistency in the environment, and dehalogenation is one of the promising treatment and detoxification methods. Herein, we systematically studied the debromination efficiency and mechanism of para-bromophenol（4-BP） by a recently developed UV/sulfite process. 4-BP underwent rapid degradation with the kinetics accelerated with the increasing sulfite concentration, pH（6.1–10） and temperature, whereas inhibited by dissolved oxygen and organic solvents. The apparent activation energy was estimated to be 27.8 kJ/mol. The degradation mechanism and pathways of 4-BP were explored by employing N2O and nitrate as the electron scavengers and liquid chromatography/mass spectrometry to identify the intermediates. 4-BP degradation proceeded via at least two pathways including direct photolysis and hydrated electron-induced debromination. The contributions of both pathways were distinguished by quantifying the quantum yields of 4-BP via direct photolysis and hydrated electron production in the system. 4-BP could be readily completely debrominated with all the substituted Br released as Br-, and the degradation pathways were also proposed. This study would shed new light on the efficient dehalogenation of brominated aromatics by using the UV/sulfite process.展开更多
Semisolid-rolling method was successfully developed to prepare the Ni-coated woven carbon fibers reinforced Al-matrix composite. Due to the appropriate matrix flowability and rolling pressure, the Al-matrix could infi...Semisolid-rolling method was successfully developed to prepare the Ni-coated woven carbon fibers reinforced Al-matrix composite. Due to the appropriate matrix flowability and rolling pressure, the Al-matrix could infiltrate into the woven fibers sufficiently and attach to the reinforcements closely forming a smooth interface. The rolling speed of 4 rad/min offered a subtle equilibrium between the heat transfer and the material deformation. The covering matrix should be controlled at semisolid state to provide a better infiltration behavior and a protective effect on the carbon fibers. With the addition of fibers, an improvement for more than 25% was obtained in the bending strength of the materials. Furthermore, the woven carbon fibers could strengthen the composite in multiple directions, rather than only along the fiber longitudinal directions. The annealing process promoted the Ni coating to react with and to diffuse into the matrix, resulted in an obvious increase of the bending strength.展开更多
AIM： The aim of the work is to study the pyrolysis characteristics of Radix Rhizoma Rhei, Cortex Moudan Radicis, and Radix Sanguisorbae in an inert atmosphere of argon （Ar）, and to investigate the mechanism of the ...AIM： The aim of the work is to study the pyrolysis characteristics of Radix Rhizoma Rhei, Cortex Moudan Radicis, and Radix Sanguisorbae in an inert atmosphere of argon （Ar）, and to investigate the mechanism of the carbonizing process of the three traditional Chinese herbs. METHODS： The pyrolysis characteristics of the crude materials and their extracts were studied by thermogravimetry-mass spectrometry （TG-MS） in a carrier gas of argon, coupled with Fourier transform infrared spectrometry （FTIR） and scanning electron microscopy （SEM） methods. Correlation of the pyrolysis behaviors with the carbonizing process by stir-frying of traditional Chinese medicines was made. RESULTS： Within the temperature range of 200-300 ℃, which is the testing range for the study of the carbonizing process of Chinese herbs, the temperatures indicated by the maximum weight loss rate peak of the above three extracts were taken as the upper-limit temperatures of the carbonizing process of the herbs, and which were 200, 240 and 247 ℃ for Radix Rhizoma Rhei, Cortex Moudan Radicis, and Radix Sanguisorbae, respectively. The ion monitoring signal peaks detected by the TG-MS method corresponded with reports that the level of chemical components of traditional Chinese medicinal materials would decrease after the carbonizing process. It was confirmed by Fourier transform infrared spectrometry （FTIR） and scanning electron microscopy （SEM） methods that better results of ＂medicinal property preservation＂ could be obtained by heating at 200 ℃ for Radix Rhizoma Rhei, at about 250 ℃ for Cortex Moudan Radicis, and Radix Sanguisorbae, as the relative intensity values of the common peaks were among the middle of their three carbonized samples by programmed heating. CONCLUSION： The upper-limit temperatures of the carbonizing process for Radix Rhizoma Rhei, Cortex Moudan Radicis and Radix Sanguisorbae were 200, 240 and 247 ℃ respectively. It is feasible to research the mechanism and technology of the carbonizing process of traditional Chinese medicinal materials using thermogravimetry, Fourier transform infrared spectrometry, and scanning electron microscopy methods.展开更多
This paper analyzes a problem processing mechanism in a new collaboration system between the main manufacturer and the supplier in the"main manufacturer-supplier"mode,which has been widely applied in the col...This paper analyzes a problem processing mechanism in a new collaboration system between the main manufacturer and the supplier in the"main manufacturer-supplier"mode,which has been widely applied in the collaborative development management of the complex product.This paper adopts the collaboration theory,the evolutionary game theory and numerical simulation to analyze the decision-making mechanism where one upstream supplier and one downstream manufacturer must process an unpredicted problem without any advance contract in common.Results show that both players'decision-makings are in some correlation with the initial state,income impact coefficients,and dealing cost.It is worth noting that only the initial state influences the final decision,while income impact coefficients and dealing cost just influence the decision process.This paper shows reasonable and practical suggestions for the manufacturer and supplier in a new collaboration system for the first time and is dedicated to the managerial implications on reducing risks of processing problems.展开更多
Traditional trade routes that penetrate the natural barrier of the Himalayas are critical for connecting major Chinese and South Asian markets.Research on these trade routes can contribute significantly to facilitatin...Traditional trade routes that penetrate the natural barrier of the Himalayas are critical for connecting major Chinese and South Asian markets.Research on these trade routes can contribute significantly to facilitating the construction of the South Asian Corridor and enhancing trans-Himalayan connectivity.Combining historical literature,field surveys,and geographic information system(GIS)techniques,this study examined the spatial distribution characteristics and evolution process of the routes,focusing on transverse valleys of the Himalayan arc.The key findings were as follows.First,there are 21 traditional trade routes traversing the Himalayan region:six Sino-Nepalese routes,four Sino-Bhutanese routes,and eleven Sino-Indian routes.Second,the evolution of traditional trade routes has entailed five distinct phases:an incipient period(pre-7th century),formation(7th century-842 AD),development(842-1959),decline(1959-1962)and recovery(1962-present).Third,the incipient and formative developmental phases were prompted by the spread of Buddhism and the exchange of goods.The stability of local governments in Tibet and Central China and favourable border trade policies along with Britain’s colonial expansion and commercial interests stimulated further development of traditional trade routes.However,India’s strategic miscalculation and“Forward Policy”instigated the decline phase,while the demands of regional cooperation and development are currently the key drivers of the restoration and construction phase.Finally,to shelve disputes,promote cooperation and development,and enhance political mutual trust,governments should recover and construct traditional trade routes by replanning and constructing border trade markets,expanding border trade,developing pilgrimage and tourism,and strengthening cross-border cooperative resear h under global climate change.展开更多
1 Introduction Physical and numerical models are constructed to investigate the evolution and mechanism of salt migration driven by tectonic processes.In recent years,we have designed and ran series of models to simul...1 Introduction Physical and numerical models are constructed to investigate the evolution and mechanism of salt migration driven by tectonic processes.In recent years,we have designed and ran series of models to simulate salt展开更多
Friction stir welding （FSW） and stationary shoulder friction stir welding （SSFSW） were carried out for the butt joining of dissimilar AA2024-T3 and AA7050-T7651 aluminium alloys with thicknesses of 2 mm. A compari...Friction stir welding （FSW） and stationary shoulder friction stir welding （SSFSW） were carried out for the butt joining of dissimilar AA2024-T3 and AA7050-T7651 aluminium alloys with thicknesses of 2 mm. A comparison between the two processes was performed by varying the welding speed while keeping the rotational speed constant, Through the analysis of the force and torque produced during welding and a simple analytical model, it was possible to show that in SSFSW there is more effective coupling with the tool and the heat produced is more efficiently distributed. This process decreases both the welding area and the diffusion at the interface of the two alloys compared with FSW. The minimum microhardness occurred at the advancing side （AS） at the interface between the thermo-mechanically affected zone （TMAZ） and the stir zone （SZ） in both processes, although the decrease was more gradual in SSFSW. This interface is also where all specimens failed for both welding technologies. An increase in tensile strength was measured in SSFSW compared with standard FSW. Furthermore, it was possible to establish the mechanical performance of the material in the fracture zone using digital image correlation.展开更多
The stretch formability of a low carbon steel processed by friction stir processing （FSP） was studied under biaxial loading condition applied by a miniaturized Erichsen test. One-pass FSP decreased the ferritic grai...The stretch formability of a low carbon steel processed by friction stir processing （FSP） was studied under biaxial loading condition applied by a miniaturized Erichsen test. One-pass FSP decreased the ferritic grain size in the processed zone from 25 μm to about 3 μm, which also caused a remarkable increase in strength values without considerable decrease in formability under uniaxial loading. A coarse-grained （CG） sample before FSP reflected a moderate formability with an Erichsen index （EI） of 2.73 mm. FSP slightly decreased the stretch formability of the sample to 2.66 ram. However, FSP increased the required punch load （FEI） due to the increased strength by grain refinement. FSP reduced considerably the roughness of the free surface of the biaxial stretched samples with reduced orange peel effect. The average roughness value （Ra） decreased from 2.90 in the CG sample down to about 0.65 μm in fine-grained （FG） sample after FSP. It can be concluded that the FG microstructure in low carbon steels sheets or plates used generally in shipbuilding provides a good balance between strength and formability.展开更多
This study sought to test the processing of three types of sentences in Chinese, as correct sentences, semantic violation sentences, and sentences containing semantic and syntactic violations, based on the following s...This study sought to test the processing of three types of sentences in Chinese, as correct sentences, semantic violation sentences, and sentences containing semantic and syntactic violations, based on the following sentence pattern： ＂subject （noun） ＋ yi/gang/zheng ＋ predicate （verb）＂. Event-related potentials on the scalp were recorded using 32-channel electroencephalography. Compared with correct sentences, target words elicited an early left anterior negativity （N400） and a later positivity （P600） over frontal, central and temporal sites in sentences involving semantic violations. In addition, when sentences contained both semantic and syntactic violations, the target words elicited a greater N400 and P600 distributed in posterior brain areas. These results indicate that Chinese sentence comprehension involves covert grammar processes.展开更多
Demand of improving the mechanical properties and productivity of automotive components while minimizing environmental impact makes the development of special steel combined with advance heat treatment and surface mod...Demand of improving the mechanical properties and productivity of automotive components while minimizing environmental impact makes the development of special steel combined with advance heat treatment and surface modification technologies become an important research area. Recently,to reduce CO_2 emissions by saving the manufacturing time,the following new special steel and advance heat treatment methods were developed: (1 ) An anti-coarsening extra-fine case hardening steel for automobile gear was developed,whose carburizing temperature can be improved for conventional 930 - 950℃to 1 050℃without coarsening,and the carburizing time can be reduced by maximum 75%. (2) Various microalloyed steels for fracture splitting connecting rod were developed.By using the above-mentioned steel combined with Thermo Mechanical Control Process(TMCP) method,the manufacturing time can be reduced by 30%-40%. (3) Vacuum carburizing and mild carburizing combined with induction quenching are being developed to replace the traditional gas carburizing,and the CO_2 emissions can be reduced by 20%-40%. (4) Intensive quenching is another new quenching technology which can be defined as cooling usually with pure water quenchant or low concentration water/salt solutions at a rate several times higher than the rate of ' normal' or conventional quenching,and the conventional effective case hardening depth can be reduce greatly and carburizing time can reduced. In addition,the high pressure gas quenching for reducing the quenching distortion and dual shot-peening for improving fatigue strength of gear will also be discussed. In a word,the present paper will focus on how to use the interaction among the development of special steel, advance heat treatment and surface modification to improve the strength of automotive components while reducing the manufacturing cost and impact to environment.展开更多
Background:To promote the quality evaluation,clarify the processing mechanism and distinguish origins of Corni Fructus(cornus)from different regions.Methods:This study developed a high performance liquid chromatograph...Background:To promote the quality evaluation,clarify the processing mechanism and distinguish origins of Corni Fructus(cornus)from different regions.Methods:This study developed a high performance liquid chromatography method for simultaneous determination of 5-hydroxymethylfurfural,2 phenolic acids and 4 iridoid glycosides and the reference fingerprint of cornus from different regions.In addition,the feedforward neural network model provided a pattern classification of sample regions.Results:The content of morroniside and loganin were the highest in all raw cornus samples ranging from 9.45μg/mg to 16.3μg/mg and 6.64μg/mg to 13.7μg/mg,respectively.The level of sweroside in raw cornus from Henan(0.83μg/mg^(-1).39μg/mg)and Zhejiang(0.64μg/mg^(-1).17μg/mg)were greater than other origins.After wine-processing,the glucose or fructose were dehydrated to increase the levels of 5-hydroxymethylfurfural.The C-4 position of-COOCH3 of hot-sensitive iridoid glycosides was hydrolyzed to generate-COOH as stable components.Polyphenol derivatives may be degraded to increase the content of phenolic acid.Subsequently,an excellent feedforward neural network model for identification of raw cornus and wine-prepared cornus was established which could distinguish the sample origins.Conclusion:This work provided a trustworthy method to evaluate the quality and distinguish the sources of cornus.Meanwhile,the clear processing mechanism provided a scientific foundation for controlling the cornus quality during wine-processing.展开更多
基金the National High Technology Research and Development Program of China (Grant No.2013AA032401)
文摘The effects of different aging processes on the microstructure and mechanical properties of a novel Al-Cu-Li alloy have been investigated by X-ray diffraction, scanning electron microscopy and transmission electron microscopy. It is found that the tensile properties of a novel Al-Cu-Li alloy are sensitive to aging processes, which correspond to different microstructures. σ（Al_5Cu_6Mg_2） and T_1（Al_2CuLi） phases are the major precipitates for the alloy in T6 aging condition（165 ℃/60 h）. After duplex aging condition（150 ℃/24 h ＋ 180 ℃/12 h）, σ, θ＇（Al_2Cu） and T_1 phases are detected. Only the T_1 phases can be found in the T8 state alloy（6% pre-strain＋135 ℃/60 h）. The failure modes of alloy in T6 and duplex aging conditions are dimple-intergranular fracture, while typical quasi-cleavage fracture in T8 condition.
基金supported by the National Key Research Project(No.2016YFB0300901)
文摘The evolution of microstructure and mechanical properties of A356 aluminum alloy subjected to hot spinning process has been investigated. The results indicated that the deformation process homogenized microstructure and improved mechanical properties of the A356 aluminum alloy. During the hot spinning process, eutectic Si particles and Fe-rich phases were fragmented, and porosities were eliminated. In addition, recrystallization of Al matrix and precipitation of Al Si Ti phases occurred. The mechanical property testing results indicated that there was a significant increase of ductility and a decrease of average microhardness in deformed alloy over die-cast alloy. This is attributed to uniform distribution of finer spherical eutectic Si particles, the elimination of casting defects and to the recrystallized finer grain structure.
文摘Since the launch of the economic reform and opening to the outside world, China has seen rapid growth in its export of mechanical and electrical products, with its export
基金supported by the National Natural Science Foundation of China(U1908225)the Fundamental Research Funds for Central Universities(N2225012 and N232405-06).
文摘In response to the new mechanism of direct vortex melting reduction of vanadium–titanium magnetite,the reaction control mechanism and the migration regularity of valuable components in the process of direct melting reduction were investigated using kinetic empirical equation by fitting and combining with X-ray diffraction,X-ray fluorescence,scanning electron microscopy,energy-dispersive spectrometry,and optical microscopy.The results show that iron reduction is controlled by the mass transfer process of(FeOx)in the slag,while vanadium reduction is controlled by both the mass transfer of(VOx)in the slag and the mass transfer of[V]in the molten iron,and the slag–metal interfacial reaction is the only pathway for vanadium reduction.The reduction of iron and vanadium is an obvious first-order reaction,with activation energy of 101.6051 and 197.416 kJ mol^(−1),respectively.Increasing the vortex rate and reaction temperature is beneficial to improving the reaction rate and reduction efficiency.The mineral phase variation of iron and vanadium in the slag during the reduction process is Fe_(2)O_(3)→Fe_(3)O_(4)/FeV_(2)O_(4)→FeTiO_(3) and FeV_(2)O_(4)→MgV_(2)O_(5);titanium in slag is mainly in the form of Mg_(x)Ti_(3−x)O_(5)(0≤x≤1)and CaTiO_(3).As the reaction time went on,the molar ratio(nTi/nMg)in Mg_(x)Ti_(3−x)O_(5)(0≤x≤1)and the Ti2O_(3) content in the slag gradually went up,while the area proportion of Mg_(x)Ti_(3−x)O_(5)(0≤x≤1)went up and then down,and the porosity of the slag and the grain size of Mg_(x)Ti_(3−x)O_(5)(0≤x≤1)got smaller.
文摘Three dimensional thermal-mechanical coupled elasto-plastic FEM has been used for simulation of round to oval single pass rolling. The analysis was conducted using MARC/AUTOFORCE1. 2 code. The material is assumed to be elasto-plastic and it obey the Von Mises yield criterion and Prandtl- Reuss rule. Deformation of the workpiece is simulated in a step-by-step manner,updating the coordinates of material points and the property after each step, so that both nonsteady-state and stendy-state deformation can be simulated. The heat transfter between the workpiece, the rolls, and enviroment and the heat generation due to plastic work and friction force, are considered in the analys- is.Predicted the deformation shape of the workpiece, distributions of strains, stresses, strain rates and temperatures, roll-separating force and roll torque are presented.
基金supported by the National Natural Science Foundation of China(grants No.41373121 and 41072099)the scientific and technological project of SINOPEC under Contract No.P05069Support by SINOPEC Key Laboratory of Petroleum Accumulation Mechanisms,China
文摘The formation mechanisms and processes of geochemical anomalies used as proxies in surface geochemistry exploration （SGE） have not been well understood. Previous studies cannot realize 3D measurement of microseeping hydrocarbons from reservoirs to the surface, which made it difficult to understand the features and pathways of deep hydrocarbon microseepages. Understanding the processes of hydrocarbon microseepages will contribute to the acceptance and effectiveness of surface geochemistry. Based on a simplified geological model of hydrocarbon microseepages, including hydrocarbon reservoir, direct caprock, overlying strata and Quaternary sediments, this work established a 3D experimental system to simulate the mechanisms and processes of deep hydrocarbon microseepes extending to the surface. The dispersive halos of microseeping hydrocarbons in the subsurface were adequately described by using this 3D experimental system. Results indicate that different migration patterns of hydrocarbons above the point gas source within the simulated caprock and overlying strata can be reflected by the ratio of i-butane to n-butane （i-C4/n-C4）, which follow diffusion and infiltration （buoyancy） mechanisms. This is not the case for vertical measurement lines far from the point gas source. A vertical gas flow in the form of a plume was found during hydrocarbon microseepage. For sampling methods, the high-density grid sampling is favorable for delineating prospecting targets. Hydrocarbon infiltration or buoyancy flow occurs in the zones of infiltration clusters, coupling with a diffusion mechanism at the top of the water table and forming surface geochemical anomalies. These results are significant in understanding hydrocarbon microseepage and interpreting SGE data.
文摘A successful mechanical property data-driven prediction model is the core of the optimal design of hot rolling process for hot-rolled strips. However, the original industrial data, usually unbalanced, are inevitably mixed with fluctuant and abnormal values. Models established on the basis of the data without data processing can cause misleading results, which cannot be used for the optimal design of hot rolling process. Thus, a method of industrial data processing of C-Mn steel was proposed based on the data analysis. The Bayesian neural network was employed to establish the reliable mechanical property prediction models for the optimal design of hot rolling process. By using the multi-objective optimization algorithm and considering the individual requirements of costumers and the constraints of the equipment, the optimal design of hot rolling process was successfully applied to the rolling process design for Q345B steel with 0.017% Nb and 0.046% Ti content removed. The optimal process design results were in good agreement with the industrial trials results, which verify the effectiveness of the optimal design of hot rolling process.
基金Project(CSTC2009BA4065) supported by the Chongqing Natural Science Foundation,China
文摘For Gu-Ag alloy, an important parameter called workability in the forming process of materials can be evaluated by processing maps yielded from the stress-strain data generated by hot compression tests at temperatures of 700-850 °C and strain rates of 0.01-10 s-1. And at the true strain of 0.15, 0.35 and 0.55, respectively, the responses of strain-rate sensitivity, power dissipation efficiency and instability parameter to temperature and strain rate were studied. Instability maps and power dissipation maps were superimposed to form processing maps, which reveal the determinate regions where individual metallurgical processes occur and the limiting conditions of flow instability regions. Furthermore, the optimal processing parameters for bulk metal working are identified clearly by the processing maps.
基金supported by the National Natural Science Foundation of China(No.50974035)National Natural Science Foundation of China(No.51074047)+2 种基金the doctoral fund of EDU gov(20090407)China Postdoctoral Science Foundation(20090451277)Key Scientific and Technological Program in Liaoning Province(200921007)
文摘For the lack of the present hot metal desulfurization processes in iron and steel industry, our group has proposed the in-situ mechanical stirring method for external desulfurization of molten iron and researched this new method. This paper investigated this new in-situ mechanical stirring hot metal desulphurization process on desulphurization experiments of one-ton scale by using the new desulfurizer. The experimental results indicated that the desulfurization efficiency of in-situ mechanical stirring desulfurization process is 90% and the lowest sulfur content in the treated hot metal is 23ppm. By comparing with the methods of direct throwing desulfurizer and in-situ injecting desulfurization, in-situ mechanical stirring desulfurization process is the suitable desulfurizaton method.
基金supported by the National Natural Science Foundation of China(No.21307057)the Natural Science Foundation of Jiangsu Province(No.BK20130577)+1 种基金the Specialized Research Fund for the Doctoral Program of Higher Education of China(SRFDP,No.20130091120014)the Fundamental Research Funds for the Central Universities(No.20620140128)
文摘Halogenated aromatic compounds have attracted increasing concerns due to their toxicity and persistency in the environment, and dehalogenation is one of the promising treatment and detoxification methods. Herein, we systematically studied the debromination efficiency and mechanism of para-bromophenol（4-BP） by a recently developed UV/sulfite process. 4-BP underwent rapid degradation with the kinetics accelerated with the increasing sulfite concentration, pH（6.1–10） and temperature, whereas inhibited by dissolved oxygen and organic solvents. The apparent activation energy was estimated to be 27.8 kJ/mol. The degradation mechanism and pathways of 4-BP were explored by employing N2O and nitrate as the electron scavengers and liquid chromatography/mass spectrometry to identify the intermediates. 4-BP degradation proceeded via at least two pathways including direct photolysis and hydrated electron-induced debromination. The contributions of both pathways were distinguished by quantifying the quantum yields of 4-BP via direct photolysis and hydrated electron production in the system. 4-BP could be readily completely debrominated with all the substituted Br released as Br-, and the degradation pathways were also proposed. This study would shed new light on the efficient dehalogenation of brominated aromatics by using the UV/sulfite process.
基金supported by the National Natural Science Foundation of China (Nos. 51271042 and 51501027)the Fundamental Research Funds for the Central Universities, the Key Laboratory of Basic Research Projects of Liaoning Province Department of Education (No. LZ2014007)+1 种基金the Natural Science Foundation of Liaoning Province (No. 2014028013)China Postdoctoral Science Foundation (No. 2015M570246)
文摘Semisolid-rolling method was successfully developed to prepare the Ni-coated woven carbon fibers reinforced Al-matrix composite. Due to the appropriate matrix flowability and rolling pressure, the Al-matrix could infiltrate into the woven fibers sufficiently and attach to the reinforcements closely forming a smooth interface. The rolling speed of 4 rad/min offered a subtle equilibrium between the heat transfer and the material deformation. The covering matrix should be controlled at semisolid state to provide a better infiltration behavior and a protective effect on the carbon fibers. With the addition of fibers, an improvement for more than 25% was obtained in the bending strength of the materials. Furthermore, the woven carbon fibers could strengthen the composite in multiple directions, rather than only along the fiber longitudinal directions. The annealing process promoted the Ni coating to react with and to diffuse into the matrix, resulted in an obvious increase of the bending strength.
文摘AIM： The aim of the work is to study the pyrolysis characteristics of Radix Rhizoma Rhei, Cortex Moudan Radicis, and Radix Sanguisorbae in an inert atmosphere of argon （Ar）, and to investigate the mechanism of the carbonizing process of the three traditional Chinese herbs. METHODS： The pyrolysis characteristics of the crude materials and their extracts were studied by thermogravimetry-mass spectrometry （TG-MS） in a carrier gas of argon, coupled with Fourier transform infrared spectrometry （FTIR） and scanning electron microscopy （SEM） methods. Correlation of the pyrolysis behaviors with the carbonizing process by stir-frying of traditional Chinese medicines was made. RESULTS： Within the temperature range of 200-300 ℃, which is the testing range for the study of the carbonizing process of Chinese herbs, the temperatures indicated by the maximum weight loss rate peak of the above three extracts were taken as the upper-limit temperatures of the carbonizing process of the herbs, and which were 200, 240 and 247 ℃ for Radix Rhizoma Rhei, Cortex Moudan Radicis, and Radix Sanguisorbae, respectively. The ion monitoring signal peaks detected by the TG-MS method corresponded with reports that the level of chemical components of traditional Chinese medicinal materials would decrease after the carbonizing process. It was confirmed by Fourier transform infrared spectrometry （FTIR） and scanning electron microscopy （SEM） methods that better results of ＂medicinal property preservation＂ could be obtained by heating at 200 ℃ for Radix Rhizoma Rhei, at about 250 ℃ for Cortex Moudan Radicis, and Radix Sanguisorbae, as the relative intensity values of the common peaks were among the middle of their three carbonized samples by programmed heating. CONCLUSION： The upper-limit temperatures of the carbonizing process for Radix Rhizoma Rhei, Cortex Moudan Radicis and Radix Sanguisorbae were 200, 240 and 247 ℃ respectively. It is feasible to research the mechanism and technology of the carbonizing process of traditional Chinese medicinal materials using thermogravimetry, Fourier transform infrared spectrometry, and scanning electron microscopy methods.
基金supported by the National Natural Science Foundation of China(7117111271502073)。
文摘This paper analyzes a problem processing mechanism in a new collaboration system between the main manufacturer and the supplier in the"main manufacturer-supplier"mode,which has been widely applied in the collaborative development management of the complex product.This paper adopts the collaboration theory,the evolutionary game theory and numerical simulation to analyze the decision-making mechanism where one upstream supplier and one downstream manufacturer must process an unpredicted problem without any advance contract in common.Results show that both players'decision-makings are in some correlation with the initial state,income impact coefficients,and dealing cost.It is worth noting that only the initial state influences the final decision,while income impact coefficients and dealing cost just influence the decision process.This paper shows reasonable and practical suggestions for the manufacturer and supplier in a new collaboration system for the first time and is dedicated to the managerial implications on reducing risks of processing problems.
基金The Second Tibetan Plateau Scientific Expedition and Research Program,No.2019QZKK0603Strategic Priority Research Program of Chinese Academy of Sciences,No.XDA20040201National Natural Science Foundation of China,No.41761144081。
文摘Traditional trade routes that penetrate the natural barrier of the Himalayas are critical for connecting major Chinese and South Asian markets.Research on these trade routes can contribute significantly to facilitating the construction of the South Asian Corridor and enhancing trans-Himalayan connectivity.Combining historical literature,field surveys,and geographic information system(GIS)techniques,this study examined the spatial distribution characteristics and evolution process of the routes,focusing on transverse valleys of the Himalayan arc.The key findings were as follows.First,there are 21 traditional trade routes traversing the Himalayan region:six Sino-Nepalese routes,four Sino-Bhutanese routes,and eleven Sino-Indian routes.Second,the evolution of traditional trade routes has entailed five distinct phases:an incipient period(pre-7th century),formation(7th century-842 AD),development(842-1959),decline(1959-1962)and recovery(1962-present).Third,the incipient and formative developmental phases were prompted by the spread of Buddhism and the exchange of goods.The stability of local governments in Tibet and Central China and favourable border trade policies along with Britain’s colonial expansion and commercial interests stimulated further development of traditional trade routes.However,India’s strategic miscalculation and“Forward Policy”instigated the decline phase,while the demands of regional cooperation and development are currently the key drivers of the restoration and construction phase.Finally,to shelve disputes,promote cooperation and development,and enhance political mutual trust,governments should recover and construct traditional trade routes by replanning and constructing border trade markets,expanding border trade,developing pilgrimage and tourism,and strengthening cross-border cooperative resear h under global climate change.
基金supported by China Geological Survey Bureau potash resources investigation and evaluation project (1212011085524)NSFC projects (40872134, 41272227 )
文摘1 Introduction Physical and numerical models are constructed to investigate the evolution and mechanism of salt migration driven by tectonic processes.In recent years,we have designed and ran series of models to simulate salt
文摘Friction stir welding （FSW） and stationary shoulder friction stir welding （SSFSW） were carried out for the butt joining of dissimilar AA2024-T3 and AA7050-T7651 aluminium alloys with thicknesses of 2 mm. A comparison between the two processes was performed by varying the welding speed while keeping the rotational speed constant, Through the analysis of the force and torque produced during welding and a simple analytical model, it was possible to show that in SSFSW there is more effective coupling with the tool and the heat produced is more efficiently distributed. This process decreases both the welding area and the diffusion at the interface of the two alloys compared with FSW. The minimum microhardness occurred at the advancing side （AS） at the interface between the thermo-mechanically affected zone （TMAZ） and the stir zone （SZ） in both processes, although the decrease was more gradual in SSFSW. This interface is also where all specimens failed for both welding technologies. An increase in tensile strength was measured in SSFSW compared with standard FSW. Furthermore, it was possible to establish the mechanical performance of the material in the fracture zone using digital image correlation.
基金supported by “The World Academy of Sciences,Italy(TWAS)” under the Visiting Researchers Program of TWASUNESCO Associateship Scheme(Ref.3240260896)
文摘The stretch formability of a low carbon steel processed by friction stir processing （FSP） was studied under biaxial loading condition applied by a miniaturized Erichsen test. One-pass FSP decreased the ferritic grain size in the processed zone from 25 μm to about 3 μm, which also caused a remarkable increase in strength values without considerable decrease in formability under uniaxial loading. A coarse-grained （CG） sample before FSP reflected a moderate formability with an Erichsen index （EI） of 2.73 mm. FSP slightly decreased the stretch formability of the sample to 2.66 ram. However, FSP increased the required punch load （FEI） due to the increased strength by grain refinement. FSP reduced considerably the roughness of the free surface of the biaxial stretched samples with reduced orange peel effect. The average roughness value （Ra） decreased from 2.90 in the CG sample down to about 0.65 μm in fine-grained （FG） sample after FSP. It can be concluded that the FG microstructure in low carbon steels sheets or plates used generally in shipbuilding provides a good balance between strength and formability.
基金the Foundation of National Social Sciences hosted by Professor Huanhai Fang, No. 03BYY013
文摘This study sought to test the processing of three types of sentences in Chinese, as correct sentences, semantic violation sentences, and sentences containing semantic and syntactic violations, based on the following sentence pattern： ＂subject （noun） ＋ yi/gang/zheng ＋ predicate （verb）＂. Event-related potentials on the scalp were recorded using 32-channel electroencephalography. Compared with correct sentences, target words elicited an early left anterior negativity （N400） and a later positivity （P600） over frontal, central and temporal sites in sentences involving semantic violations. In addition, when sentences contained both semantic and syntactic violations, the target words elicited a greater N400 and P600 distributed in posterior brain areas. These results indicate that Chinese sentence comprehension involves covert grammar processes.
文摘Demand of improving the mechanical properties and productivity of automotive components while minimizing environmental impact makes the development of special steel combined with advance heat treatment and surface modification technologies become an important research area. Recently,to reduce CO_2 emissions by saving the manufacturing time,the following new special steel and advance heat treatment methods were developed: (1 ) An anti-coarsening extra-fine case hardening steel for automobile gear was developed,whose carburizing temperature can be improved for conventional 930 - 950℃to 1 050℃without coarsening,and the carburizing time can be reduced by maximum 75%. (2) Various microalloyed steels for fracture splitting connecting rod were developed.By using the above-mentioned steel combined with Thermo Mechanical Control Process(TMCP) method,the manufacturing time can be reduced by 30%-40%. (3) Vacuum carburizing and mild carburizing combined with induction quenching are being developed to replace the traditional gas carburizing,and the CO_2 emissions can be reduced by 20%-40%. (4) Intensive quenching is another new quenching technology which can be defined as cooling usually with pure water quenchant or low concentration water/salt solutions at a rate several times higher than the rate of ' normal' or conventional quenching,and the conventional effective case hardening depth can be reduce greatly and carburizing time can reduced. In addition,the high pressure gas quenching for reducing the quenching distortion and dual shot-peening for improving fatigue strength of gear will also be discussed. In a word,the present paper will focus on how to use the interaction among the development of special steel, advance heat treatment and surface modification to improve the strength of automotive components while reducing the manufacturing cost and impact to environment.
基金supported by the Innovation Team and Talents Cultivation Program of National Administration of Traditional Chinese Medicine.(No.ZYYCXTD-D-202005)the Key Project at Central Government Level(No.2060302)+1 种基金the National Natural Science Foundation of China Grants(No.81872956)Tianjin Science and Technology Planning Project(No.19YFZCSY00170).
文摘Background:To promote the quality evaluation,clarify the processing mechanism and distinguish origins of Corni Fructus(cornus)from different regions.Methods:This study developed a high performance liquid chromatography method for simultaneous determination of 5-hydroxymethylfurfural,2 phenolic acids and 4 iridoid glycosides and the reference fingerprint of cornus from different regions.In addition,the feedforward neural network model provided a pattern classification of sample regions.Results:The content of morroniside and loganin were the highest in all raw cornus samples ranging from 9.45μg/mg to 16.3μg/mg and 6.64μg/mg to 13.7μg/mg,respectively.The level of sweroside in raw cornus from Henan(0.83μg/mg^(-1).39μg/mg)and Zhejiang(0.64μg/mg^(-1).17μg/mg)were greater than other origins.After wine-processing,the glucose or fructose were dehydrated to increase the levels of 5-hydroxymethylfurfural.The C-4 position of-COOCH3 of hot-sensitive iridoid glycosides was hydrolyzed to generate-COOH as stable components.Polyphenol derivatives may be degraded to increase the content of phenolic acid.Subsequently,an excellent feedforward neural network model for identification of raw cornus and wine-prepared cornus was established which could distinguish the sample origins.Conclusion:This work provided a trustworthy method to evaluate the quality and distinguish the sources of cornus.Meanwhile,the clear processing mechanism provided a scientific foundation for controlling the cornus quality during wine-processing.
