Supercapacitors are gaining popularity due to their high cycling stability,power density,and fast charge and discharge rates.Researchers are ex-ploring electrode materials,electrolytes,and separat-ors for cost-effecti...Supercapacitors are gaining popularity due to their high cycling stability,power density,and fast charge and discharge rates.Researchers are ex-ploring electrode materials,electrolytes,and separat-ors for cost-effective energy storage systems.Ad-vances in materials science have led to the develop-ment of hybrid nanomaterials,such as combining fil-amentous carbon forms with inorganic nanoparticles,to create new charge and energy transfer processes.Notable materials for electrochemical energy-stor-age applications include MXenes,2D transition met-al carbides,and nitrides,carbon black,carbon aerogels,activated carbon,carbon nanotubes,conducting polymers,carbon fibers,and nanofibers,and graphene,because of their thermal,electrical,and mechanical properties.Carbon materials mixed with conducting polymers,ceramics,metal oxides,transition metal oxides,metal hydroxides,transition metal sulfides,trans-ition metal dichalcogenide,metal sulfides,carbides,nitrides,and biomass materials have received widespread attention due to their remarkable performance,eco-friendliness,cost-effectiveness,and renewability.This article explores the development of carbon-based hybrid materials for future supercapacitors,including electric double-layer capacitors,pseudocapacitors,and hy-brid supercapacitors.It investigates the difficulties that influence structural design,manufacturing(electrospinning,hydro-thermal/solvothermal,template-assisted synthesis,electrodeposition,electrospray,3D printing)techniques and the latest car-bon-based hybrid materials research offer practical solutions for producing high-performance,next-generation supercapacitors.展开更多
Developing innovative catalysts continues to be a pivotal interest within the heterogeneous catalysis area.The carbonaceous material ND@G,featuring a sp^(2)/sp^(3)hybrid architecture,comprises a nanodiamond(ND)core st...Developing innovative catalysts continues to be a pivotal interest within the heterogeneous catalysis area.The carbonaceous material ND@G,featuring a sp^(2)/sp^(3)hybrid architecture,comprises a nanodiamond(ND)core structure encased within an ultrathin graphitic nanoshell(G),and has been widely exploited as a metal-free catalyst or a support for metal catalyst.Its unique curved zero-dimensional structure/surface and tunable defective surface characteristics endow it with outstanding performance in different heterogeneous catalytic systems.The present review summarized the construction of the diverse types of ND@G and a wide-ranging valorization of structure-activity relation with its catalytic mechanism in various reactions.The recent advancements in the impact of active sites’architecture and the interaction between metal and support(preventing the as-formed metal species migration and agglomeration based on ND@G)on the catalytic performance of supported metal catalysts are particularly highlighted.The current challenges and outlooks/opportunities confronted by ND@G materials in catalysis are prospected by virtue of its fundamental physicochemical characterizations and potential catalytic estimation.This in-depth analysis seeks to pave the way for effective utilizing the ND@G in catalytic processes.Based on our knowledge,we also identify the challenges along with this area and offer some perspectives on how to overcome them.展开更多
High-performance lithium-ion batteries and sodium-ion batteries have been developed utilizing a hybrid anode material composed of zinc sulfide/sulfurized polyacrylonitrile.The in situ-generated zinc sulfide nanopartic...High-performance lithium-ion batteries and sodium-ion batteries have been developed utilizing a hybrid anode material composed of zinc sulfide/sulfurized polyacrylonitrile.The in situ-generated zinc sulfide nanoparticles serve as catalytic agents,significantly enhancing conductivity,shortening diffusion paths,and accelerating reaction kinetics.Simultaneously,the sulfurized polyacrylonitrile fibers form a three-dimensional matrix that not only provides a continuous network for rapid electron transfer but also prevents zinc sulfide nanoparticle aggregation and mitigates volume changes during charge-discharge cycles.Moreover,the heterointerface structure at the junction of zinc sulfide nanoparticles and the sulfurized polyacrylonitrile matrix increases the availability of active sites and facilitates both ion adsorption and electron transfer.As an anode material for lithium-ion batteries,the zinc sulfide/sulfurized polyacrylonitrile hybrid demonstrates a high reversible capacity of 1178 mAh g^(-1)after 100 cycles at a current density of 0.2 A g^(-1),maintaining a capacity of 788 mAh g^(-1)after 200 cycles at 1 A g^(-1).It also exhibits excellent sodium storage capabilities,retaining a capacity of 625 mAh g^(-1)after 150 cycles at 0.2 A g^(-1).Furthermore,ex-situ X-ray photoelectron spectroscopy,X-ray diffraction,7Li solid-state magic angle spinning nuclear magnetic resonance,and in situ Raman are employed to investigate the reaction mechanisms of the zinc sulfide/sulfurized polyacrylonitrile hybrid anode,providing valuable insights that pave the way for the advancement of hybrid anode materials in lithium-ion batteries and sodium-ion batteries.展开更多
An inorganicDorganic hybrid crystalline material(SiMo_(12)O_(40))[Cu(2,2'-bipy)_(2)]_(2)·2H_(2)O(Complex 1,2,2'-bipy=2,2'-bipyridine)was synthesized for the first time by using 2,2'-bipy and trans...An inorganicDorganic hybrid crystalline material(SiMo_(12)O_(40))[Cu(2,2'-bipy)_(2)]_(2)·2H_(2)O(Complex 1,2,2'-bipy=2,2'-bipyridine)was synthesized for the first time by using 2,2'-bipy and transition metal copper to convert Waugh-type polyoxometalate[MnMo_(9)O_(3)_(2)]_(6-)into a Keggin polyoxometalate structure[SiMo_(12)O_(40)]^(4-)under hydrothermal conditions in glass vials.Single crystal tests and a series of characterizations were carried out on Complex 1.The structure of Complex 1 is composed of[SiMo_(12)O_(40)]^(4-)and[Cu^(Ⅱ)(2,2'-bipy)_(2)]^(2+).The five-coordinated Cu is connected to two 2,2'-bipy through CuDN bonds,forming an approximately square structure.Astonishingly,Complex 1 exhibited good photocatalytic performance for methylene blue degradation and electrocatalytic nitrite reduction properties simultaneously.展开更多
The conversion of solar energy to produce clean hydrogen fuel through water splitting is an emerging strategy for efficiently storing solar energy in the form of solar fuel.This aligns with the increasing global deman...The conversion of solar energy to produce clean hydrogen fuel through water splitting is an emerging strategy for efficiently storing solar energy in the form of solar fuel.This aligns with the increasing global demand for the development of an ideal energy alternative to fossil fuels that does not emit greenhouse gases.Electrochemical(EC) and photoelectrochemical(PEC) water splitting technologies have garnered significant attention worldwide for advanced hydrogen solar fuel production in recent decades.To achieve sustainable green H_(2) production,it is essential to create efficient catalyst materials that are low-cost and can replace expensive noble metal-based catalysts.These characteristics make them an ideal catalyst material for the process.Two-dimensional MXenes with M_(n+1)X_(n) structure have been identified as a promising option for EC and PEC water splitting due to their superior hydrophilicity,metal-like conductivity,large surface area,and adjustable surface chemistry.Here,we present a summary of recent advancements in the synthesis and performance enhancement methods for MXene hybrid materials in hydrogen production through EC and PEC water splitting.Furthermore,we examine the challenges and insights associated with the rational design of MXene-based hybrid materials to facilitate efficient water splitting for sustainable solar fuel production.展开更多
Metal-backboned polymers with anisotropy microstructures are promising for conductive,optoelectronic,and magnetic functional materials.However,the structure-property relationships governing the interplay between the c...Metal-backboned polymers with anisotropy microstructures are promising for conductive,optoelectronic,and magnetic functional materials.However,the structure-property relationships governing the interplay between the chemical structure and electromagnetic property of the metal-backboned polymer have been rarely investigated.Here we report a carbon/nickel hybrid from metal-backboned polymer to serve as electromagnetic wave-absorbing materials,which exhibit high microwave absorption capacity and tunable absorption band.The presence of nickel backbones promote the generation of heterogeneous interfaces with carbon during calcination,thereby enhancing the wave-absorbing capacity of the carbon/nickel hybrid.The C/Ni hybrids show a minimal reflection loss of-49.1 dB at 13.04 GHz,and its frequency of the absorption band can be adjusted by controlling the thickness of the absorption layer.展开更多
Poly (EA-MAn-APTES)/silica hybrid materials were successfully prepared fromEthyl acrylate (EA), maleic anhydride (MAn) and tetraethoxysilane (TEOS) in the presence of acoupling agent 3-aminopropyltriethoxysilane (APTE...Poly (EA-MAn-APTES)/silica hybrid materials were successfully prepared fromEthyl acrylate (EA), maleic anhydride (MAn) and tetraethoxysilane (TEOS) in the presence of acoupling agent 3-aminopropyltriethoxysilane (APTES),by free-radical solution polymerization and insitu sol-gel process. The mass fraction of TEOS varied from 0 to 25%. The hybrid materials werecharacterized by the methods of FT-IR spectra, solvent extraction, scanning electron microscope (SEM), transmission electron microscope (TEM), differential scanning calorimetry (DSC) andthermogravimetric analysis (TGA) measuring apparatus to get their structures, gel contents,morphologies, particle sizes and thermal performances. The results show that the covalent bonds arebetween organic and inorganic phases, gel contents in the hybrid materials are much higher, theSiO_2 phase is well dispersed in the polymer matrix, silicon dioxide exist at nanoscale in thecomposites and have excellent thermal stability.展开更多
The micro-dispersion structure of silica fillers exerts significant infiuences on the performance characteristics of rubber-based products. How to monitor this parameter is an important issue in the rubber industry, b...The micro-dispersion structure of silica fillers exerts significant infiuences on the performance characteristics of rubber-based products. How to monitor this parameter is an important issue in the rubber industry, but there is currently no suitable technical solution for numerical monitoring that can be applied in automatic production line. The labeling of silica in rubber is a challenge that bottlenecks the development of numerical quality monitoring technology. In this work, we employed the organometallic europium to modify silica endowing the fiuorescence properties for characterization. It provides more feasible solutions for visually studying the relationship between the submicroscopic structure and macroscopic properties of inorganic-filled polymers, and is the key foundation for achieving numerical monitoring of rubber filler qualities in industry.展开更多
Electrode materials that rely on conversion reactions for lithium-ion batteries(LIBs)possess high energy densities.However,a key issue in their design is bolstering their stability and minimizing volume variations dur...Electrode materials that rely on conversion reactions for lithium-ion batteries(LIBs)possess high energy densities.However,a key issue in their design is bolstering their stability and minimizing volume variations during lithiation and delithiation.Herein,an effect-ive strategy was devised to fulfill the fully reversible conversion reaction for lithium storage in CoMoO_(4) through the hybridization of Co-MoO_(3).CoMoO_(3)/CoMoO_(4) with a nanorod structure was synthesized via one-step annealing treatment after a solvothermal process.In such a structure,the CoMoO_(3)/CoMoO_(4) nanorod can considerably boost mechanical robustness and offer ample space to counteract volume fluctuations throughout successive cycles owing to the cooperative interaction between CoMoO_(3) and CoMoO_(4).CoMoO_(3)/CoMoO_(4) exhib-ited superior lithium-storage capacity(919.6 mAh/g at 0.1 A/g after 200 cycles)and cycling stability(683.4 mAh/g at 1 A/g after 600 cycles).CoMoO_(3)/CoMoO_(4) showed a high potential as an anode material for LIBs.展开更多
Hybrid materials with synergistic properties have been used for various applications.Herein,we report a green biosynthesis strategy for the fabrication of a novel Pd/bacteria@ZIF-8 composite,featuring a sandwiched str...Hybrid materials with synergistic properties have been used for various applications.Herein,we report a green biosynthesis strategy for the fabrication of a novel Pd/bacteria@ZIF-8 composite,featuring a sandwiched structure and size-selective capabilities.The Shewanella oneidensis(S.oneidensis)MR-1 was selected as the biological reductant to reduce Pd ions and synthesize Pd nanoparticles anchored on the surface of bacteria without the need for additional chemical reductants,bonding agents and toxic surfactants.This innovative sandwiched Pd/bacteria@ZIF-8 catalyst was further coated by the ZIF-8 to enhance its structural integrity.The as-prepared composite exhibits significant catalytic activity and excellent size-selective performance in the hydrogenation of olefins.This methodology opens up a horizon to designing size-selective catalysts through constructing the sandwiched structure.展开更多
Herein,a simple and effective outer-surface interactions assisted supramolecular hierarchical assembly has been first exploited to uniformly distribute tungstosilicic acid(TSA)inside the porous structure of cucurbit[1...Herein,a simple and effective outer-surface interactions assisted supramolecular hierarchical assembly has been first exploited to uniformly distribute tungstosilicic acid(TSA)inside the porous structure of cucurbit[10]uril-based single-layer 2D supramolecular-organic-frameworks(Q[10]-SOFs)in water.Importantly,the 2D Q[10]-SOFs can further serve as light harvesting antenna,achieving fast energy transfer to the embedded redox-active TSA upon photoexcitation,resulting in efficient visible light-driven selective oxidation of benzyl alcohols into the corresponding aldehydes in high yield at room temperature.Further studies revealed that the integrated of 2D Q[10]-SOFs and TSA played a key role in the catalytic process,due to the presence of a novel stepwise electron transfer route in the single-layer hybrid 2D structures.展开更多
The increasingly severe electromagnetic microwave pollution raises higher requirements for the development of efficient microwave absorption(MA)materials.Metal sulfides are regarded as potential robust MA materials be...The increasingly severe electromagnetic microwave pollution raises higher requirements for the development of efficient microwave absorption(MA)materials.Metal sulfides are regarded as potential robust MA materials because of their unique optical,thermal,electrical,and magnetic properties,as well as the controllable microstructures.However,due to the limited MA performances of unary metal sulfides,morphology regulations and foreign materials hybridizations are adopted as effective strategies to improve their MA performances.Recent years witnessed the fast research progresses on the metal sulfides based MA materials and thus,a systematic literature survey on the materials design,fabrication,characterizations,MA behaviors,and the mechanisms behind is,highly desirable to summarize the rapid progress of this hot research area so as to provide guidance for the future development trend.This review firstly reviewed the research background,research progress,and basic principles of MA materials.Subsequently,the present synthetic methods and performance improvement strategies of metal sulfides based MA materials are systematically introduced.Then,by comparing the MA properties of one-dimensional,two-dimensional,and three-dimensional metal sulfides based composites,the influence of dimensionality and morphology on the MA properties are analyzed.By summarizing the research process of metal sulfides/dielectrics composites,metal sulfides/magnets composites,and metal sulfides/dielectrics/magnets composites MA materials,the influence of foreign materials hybridizations on the loss mechanisms and impedance matching conditions of metal sulfides based composites are revealed.Finally,the challenges and development prospects of metal sulfides based MA materials are presented.This review would provide a comprehensive understanding and insightful guidance for the exploration and development of efficient MA materials with thin thickness,light weight,wide absorption bandwidth,and strong absorption intensity.展开更多
Nanocarbon materials play a critical role in the development of new or improved technologies and devices for sustainable production and use of renewable energy. This perspective paper defines some of the trends and ou...Nanocarbon materials play a critical role in the development of new or improved technologies and devices for sustainable production and use of renewable energy. This perspective paper defines some of the trends and outlooks in this exciting area, with the effort of evidencing some of the possibilities offered from the growing level of knowledge, as testified from the exponentially rising number of publications, and putting bases for a more rational design of these nanomaterials. The basic members of the new carbon family are fullerene, graphene, and carbon nanotube. Derived from them are carbon quantum dots, nanohorn, nanofiber, nano ribbon, nanocapsulate, nanocage and other nanomorphologies. Second generation nanocarbons are those which have been modified by surface functionalization or doping with heteroatoms to create specific tailored properties. The third generation of nanocarbons is the nanoarchitectured supramolecular hybrids or composites of the first and second genera- tion nanocarbons, or with organic or inorganic species. The advantages of the new carbon materials, relating to the field of sustainable energy, are discussed, evidencing the unique properties that they offer for developing next generation solar devices and energy storage solutions.展开更多
Naturally derived nanocellulose with unique physiochemical properties and giant potentials as renewable smart nanomaterials opens up endless novel advanced functional materials for multi-sensing applications.However,i...Naturally derived nanocellulose with unique physiochemical properties and giant potentials as renewable smart nanomaterials opens up endless novel advanced functional materials for multi-sensing applications.However,integrating inorganic functional two-dimensional carbon materials such as graphene has realized hybrid organic-inorganic nanocomposite materials with precisely tailored properties and multi-sensing abilities.Altogether,the affinity,stability,dispersibility,modification,and functionalization are some of the key merits permitting their synergistic interfacial interactions,which exhibited highly advanced multifunctional hybrid nanocomposites with desirable properties.Moreover,the high performance of such hybrids could be achievable through green and straightforward approaches.In this context,the review covered the most advanced nanocellulose-graphene hybrids,focusing on their synthetization,functionalization,fabrication,and multi-sensing applications.These hybrid films exhibited great potentials as a multifunctional sensing platform for numerous mechanical,environmental,and human bio-signals detections,mimicking,and in-situ monitoring.展开更多
Photoluminescent hybrid materials containing carboxymethyl cellulose and lanthanide ions（Eu3＋, Tb3＋）were prepared by a facile method under ambient conditions. Lanthanide ions were covalently grafted to the cellulo...Photoluminescent hybrid materials containing carboxymethyl cellulose and lanthanide ions（Eu3＋, Tb3＋）were prepared by a facile method under ambient conditions. Lanthanide ions were covalently grafted to the cellulose framework through coordination with the carboxylic groups of the cellulose. Hybrid materials were fabricated as hydrogel and aerogel. As shown by SEM and pore parameters, aerogel materials which were obtained by supercritical CO2 drying show hierarchical porous structure. The photoluminescence spectrum of the hybrid materials shows the characteristic red emission of Eu3＋ ion and green emission of Tb3＋. Further luminescent investigations reveal that these hybrid materials can detect Fe3＋ with relative selectivity and high sensitivity, which suggests that the hybrid materials could be a promising luminescent probe for selectively sensing Fe3＋ ion.展开更多
Hybrid materials of vanadium nitride and porous carbon nanoparticles(VN/PCNPs) were fabricated by a facile pyrolysis process of vanadium pentoxide(V_2O_5) xerogel and melamine at relatively low temperature of 800 ...Hybrid materials of vanadium nitride and porous carbon nanoparticles(VN/PCNPs) were fabricated by a facile pyrolysis process of vanadium pentoxide(V_2O_5) xerogel and melamine at relatively low temperature of 800 °C for supercapacitor application. The effects of the feed ratio of V_2O_5 to melamine(r), and nitrogen flow rate on the microstructure and electrochemical performance were also investigated. It was found that the size of the as-synthesized nanoparticles is about 20 nm. Both r value and N_2 flow rate have enormous impacts on morphology and microstructure of the nanoparticle, which correspondingly determined the electrochemical performance of the material. The VN/C hybrid nanoparticles exhibited high capacitive properties, and a maximum specific capacitance of 255.0 Fg^(-1) was achieved at a current density of 1.0 Ag^(-1) in 2 M KOH aqueous electrolyte and the potential range from 0 to -1.15 V. In addition,symmetrical supercapacitor fabricated with the as-synthesized VN/PCNPs presents a high specific capacitance of 43.5 F g^(-1) at 0.5 A g^(-1) based on the entire cell, and an energy density of 8.0 Wh kg^(-1) when the power density was 575 W kg^(-1). Even when the power density increased to 2831.5 W kg^(-1), the energy density still remained 6.1 Wh kg^(-1).展开更多
Mesoporous poly(styrene-co-maleic anhydride)/silica hybrid materials have been prepared. The synthesis was achieved by the HCl-catalyzed sol-gel reactions of tetraethyl orthosilicate (TEOS) and styrene-maleic anhydrid...Mesoporous poly(styrene-co-maleic anhydride)/silica hybrid materials have been prepared. The synthesis was achieved by the HCl-catalyzed sol-gel reactions of tetraethyl orthosilicate (TEOS) and styrene-maleic anhydride copolymer in the presence of 3-aminopropyl triethoxysilane (APTES) as a coupling agent and citric acid as a nonsurfactant template or pore-forming agent, followed by ethanol extraction. Characterization results from nitrogen sorption isotherms and powder X-ray diffraction indicate that polymer-modified mesoporous materials with large specific surface areas (e.g. 900 m(2)/g) and pore volumes (e.g. 0.6 cm(3)/g) could be prepared. As the citric acid concentration is increased, the specific surface areas, pore volumes and pore diameters of the hybrid materials increase.展开更多
The characteristic evaluation of aluminum oxide （A1203）/carbon nanotubes （CNTs） hybrid composites for micro-electrical discharge machining （EDM） was described. Alumina matrix composites reinforced with CNTs were...The characteristic evaluation of aluminum oxide （A1203）/carbon nanotubes （CNTs） hybrid composites for micro-electrical discharge machining （EDM） was described. Alumina matrix composites reinforced with CNTs were fabricated by a catalytic chemical vapor deposition method. A1203 composites with different CNT concentrations were synthesized. The electrical characteristic of A1203/CNTs composites was examined. These composites were machined by the EDM process according to the various EDM parameters, and the characteristics of machining were analyzed using field emission scanning electron microscope （FESEM）. The electrical conductivity has a increasing tendency as the CNTs content is increased and has a critical point at 5% A1203 （volume fraction）. In the machining accuracy, many tangles of CNT in A1203/CNTs composites cause violent spark. Thus, it causes the poor dimensional accuracy and circularity. The results show that conductivity of the materials and homogeneous distribution of CNTs in the matrix are important factors for micro-EDM of A1203/CNTs hybrid composites.展开更多
The unique luminescent performance of lanthanide complexes/clay minerals hybrid materials has been fascinating many researchers for recent decades.It not only retains the excellent luminescent characteristics of lanth...The unique luminescent performance of lanthanide complexes/clay minerals hybrid materials has been fascinating many researchers for recent decades.It not only retains the excellent luminescent characteristics of lanthanide complexes but also improves the poor stability of the complexes.In this article,we introduce the luminescence mechanism of lanthanide complexes and point out the necessity of their combination with clay minerals.After the analysis of the structure and interlayer environment differences of 1:1-type and 2:1-type clay minerals,the intercalation methods(covalent grafting and ion exchange)appropriate for different clay minerals are summarized with examples.Based on the luminescence characteristics of the hybrid materials,the applications of these materials as luminescent probes in recognition of specific metal cations and molecules,detection of pH value,and temperature are reviewed.Finally,the current problems in the preparation of lanthanide complexes/clay minerals hybrid luminescent materials and shortcomings that need improvement in their performance are analyzed,and the application prospect is forecast.展开更多
By employing a rational approach,we prepared a novel kind of luminescent europium-centered hybrid material named Eu(tta)_(3)NCP-TiO_(2).The resulting material was characterized by FT-IR spectra,SEM,X-ray diffraction,t...By employing a rational approach,we prepared a novel kind of luminescent europium-centered hybrid material named Eu(tta)_(3)NCP-TiO_(2).The resulting material was characterized by FT-IR spectra,SEM,X-ray diffraction,thermogravimetric analysis,and photoluminescence spectra.The hybrid material features the combined advantages of the europium complex and the titania host,exhibiting not only good thermostability,but also long luminescence lifetime.Owing to the excellent luminescence of this material,the application in detecting organic small molecule solvents and metal ions was explored systematically.Significantly,Eu(tta)_(3)NCP-TiO_(2) exhibits superior detection for nitrobenzene molecule and Cu^(2+) ion in DMF(N,N-dimethylformamide) medium.Furthermore,the limit of detection(LOD) of Eu(tta)_(3)NCP-TiO_(2) for nitrobenzene and Cu^(2+) ion can be counted as 5.593× 10^(-5) and 9.566 ×10^(-5) mol/L,respectively.The results demonstrate that Eu(tta)_(3)NCP-TiO_(2) can serve as an efficient fluorescence probe for the detection of sensing of nitrobenzene and Cu^(2+) ion.展开更多
文摘Supercapacitors are gaining popularity due to their high cycling stability,power density,and fast charge and discharge rates.Researchers are ex-ploring electrode materials,electrolytes,and separat-ors for cost-effective energy storage systems.Ad-vances in materials science have led to the develop-ment of hybrid nanomaterials,such as combining fil-amentous carbon forms with inorganic nanoparticles,to create new charge and energy transfer processes.Notable materials for electrochemical energy-stor-age applications include MXenes,2D transition met-al carbides,and nitrides,carbon black,carbon aerogels,activated carbon,carbon nanotubes,conducting polymers,carbon fibers,and nanofibers,and graphene,because of their thermal,electrical,and mechanical properties.Carbon materials mixed with conducting polymers,ceramics,metal oxides,transition metal oxides,metal hydroxides,transition metal sulfides,trans-ition metal dichalcogenide,metal sulfides,carbides,nitrides,and biomass materials have received widespread attention due to their remarkable performance,eco-friendliness,cost-effectiveness,and renewability.This article explores the development of carbon-based hybrid materials for future supercapacitors,including electric double-layer capacitors,pseudocapacitors,and hy-brid supercapacitors.It investigates the difficulties that influence structural design,manufacturing(electrospinning,hydro-thermal/solvothermal,template-assisted synthesis,electrodeposition,electrospray,3D printing)techniques and the latest car-bon-based hybrid materials research offer practical solutions for producing high-performance,next-generation supercapacitors.
基金financial support from the National Natural Science Foundation of China(22202217)the National Natural Science Foundation of Gansu(24JRRA046)+1 种基金the Department of Science&Technology of Shandong Province for their assistance(2023CXGC010607)the Joint Fund of Shandong Energy Institute and Enterprise(SEI U202308)。
文摘Developing innovative catalysts continues to be a pivotal interest within the heterogeneous catalysis area.The carbonaceous material ND@G,featuring a sp^(2)/sp^(3)hybrid architecture,comprises a nanodiamond(ND)core structure encased within an ultrathin graphitic nanoshell(G),and has been widely exploited as a metal-free catalyst or a support for metal catalyst.Its unique curved zero-dimensional structure/surface and tunable defective surface characteristics endow it with outstanding performance in different heterogeneous catalytic systems.The present review summarized the construction of the diverse types of ND@G and a wide-ranging valorization of structure-activity relation with its catalytic mechanism in various reactions.The recent advancements in the impact of active sites’architecture and the interaction between metal and support(preventing the as-formed metal species migration and agglomeration based on ND@G)on the catalytic performance of supported metal catalysts are particularly highlighted.The current challenges and outlooks/opportunities confronted by ND@G materials in catalysis are prospected by virtue of its fundamental physicochemical characterizations and potential catalytic estimation.This in-depth analysis seeks to pave the way for effective utilizing the ND@G in catalytic processes.Based on our knowledge,we also identify the challenges along with this area and offer some perspectives on how to overcome them.
基金supported by“regional innovation mega project”program through the Korea Innovation Foundation funded by Ministry of Science and ICT(Project Number:2023-DD-UP-0026)the Energy Technology Evaluation and Planning(KETEP)and the Ministry of Trade,Industry&Energy(MOTIE)(No.RS-2024-00509401,RS-2023-00217581)“Regional Innovation Strategy(RIS)”through the National Research Foundation of Korea(NRF)funded by the Ministry of Education(MOE)(2021RIS-001).
文摘High-performance lithium-ion batteries and sodium-ion batteries have been developed utilizing a hybrid anode material composed of zinc sulfide/sulfurized polyacrylonitrile.The in situ-generated zinc sulfide nanoparticles serve as catalytic agents,significantly enhancing conductivity,shortening diffusion paths,and accelerating reaction kinetics.Simultaneously,the sulfurized polyacrylonitrile fibers form a three-dimensional matrix that not only provides a continuous network for rapid electron transfer but also prevents zinc sulfide nanoparticle aggregation and mitigates volume changes during charge-discharge cycles.Moreover,the heterointerface structure at the junction of zinc sulfide nanoparticles and the sulfurized polyacrylonitrile matrix increases the availability of active sites and facilitates both ion adsorption and electron transfer.As an anode material for lithium-ion batteries,the zinc sulfide/sulfurized polyacrylonitrile hybrid demonstrates a high reversible capacity of 1178 mAh g^(-1)after 100 cycles at a current density of 0.2 A g^(-1),maintaining a capacity of 788 mAh g^(-1)after 200 cycles at 1 A g^(-1).It also exhibits excellent sodium storage capabilities,retaining a capacity of 625 mAh g^(-1)after 150 cycles at 0.2 A g^(-1).Furthermore,ex-situ X-ray photoelectron spectroscopy,X-ray diffraction,7Li solid-state magic angle spinning nuclear magnetic resonance,and in situ Raman are employed to investigate the reaction mechanisms of the zinc sulfide/sulfurized polyacrylonitrile hybrid anode,providing valuable insights that pave the way for the advancement of hybrid anode materials in lithium-ion batteries and sodium-ion batteries.
基金supported by the National Natural Science Foundation of China(Nos.21971221,21401162 and 22201244)Yangzhou University Interdisciplinary Research Foundation for Chemistry Discipline of Targeted Support(No.yzuxk202010)?Qing Lan Project?in Colleges and Universities of Jiangsu Province,the High-Level Entrepreneurial and Innovative Talents Program of Yangzhou University and the Lvyangjinfeng Talent Program of Yangzhou,and China Postdoctoral Science Foundation(No.2022M722688)。
文摘An inorganicDorganic hybrid crystalline material(SiMo_(12)O_(40))[Cu(2,2'-bipy)_(2)]_(2)·2H_(2)O(Complex 1,2,2'-bipy=2,2'-bipyridine)was synthesized for the first time by using 2,2'-bipy and transition metal copper to convert Waugh-type polyoxometalate[MnMo_(9)O_(3)_(2)]_(6-)into a Keggin polyoxometalate structure[SiMo_(12)O_(40)]^(4-)under hydrothermal conditions in glass vials.Single crystal tests and a series of characterizations were carried out on Complex 1.The structure of Complex 1 is composed of[SiMo_(12)O_(40)]^(4-)and[Cu^(Ⅱ)(2,2'-bipy)_(2)]^(2+).The five-coordinated Cu is connected to two 2,2'-bipy through CuDN bonds,forming an approximately square structure.Astonishingly,Complex 1 exhibited good photocatalytic performance for methylene blue degradation and electrocatalytic nitrite reduction properties simultaneously.
基金the result of a research project conducted with the funds of the Open R&D program of Korea Electric Power Corporation (R23XO04)supported by the Technology Innovation Program funded by the Ministry of Trade, Industry & Energy (MOTIE, Korea) (K_G012002238601)+2 种基金by “Regional Innovation Strategy (RIS)” through the National Research Foundation of Korea (NRF) funded by the Ministry of Education (MOE) (2021RIS-002)by the National Research Foundation of Korea (NRF) grant funded by the Korea government (MSIT) (No. 2021M3I3A1082880)by the Korea Institute of Energy Technology Evaluation and Planning (KETEP) and the Ministry of Trade, Industry & Energy (MOTIE) of the Republic of Korea (No. 20224000000320)。
文摘The conversion of solar energy to produce clean hydrogen fuel through water splitting is an emerging strategy for efficiently storing solar energy in the form of solar fuel.This aligns with the increasing global demand for the development of an ideal energy alternative to fossil fuels that does not emit greenhouse gases.Electrochemical(EC) and photoelectrochemical(PEC) water splitting technologies have garnered significant attention worldwide for advanced hydrogen solar fuel production in recent decades.To achieve sustainable green H_(2) production,it is essential to create efficient catalyst materials that are low-cost and can replace expensive noble metal-based catalysts.These characteristics make them an ideal catalyst material for the process.Two-dimensional MXenes with M_(n+1)X_(n) structure have been identified as a promising option for EC and PEC water splitting due to their superior hydrophilicity,metal-like conductivity,large surface area,and adjustable surface chemistry.Here,we present a summary of recent advancements in the synthesis and performance enhancement methods for MXene hybrid materials in hydrogen production through EC and PEC water splitting.Furthermore,we examine the challenges and insights associated with the rational design of MXene-based hybrid materials to facilitate efficient water splitting for sustainable solar fuel production.
基金This work was financially supported by MOST(Nos.2022YFA1203001 and 2022YFA1203002)NSFC(Nos.T2321003,22335003 and 22105045)STCSM(Nos.21511104900 and 20JC1414902).
文摘Metal-backboned polymers with anisotropy microstructures are promising for conductive,optoelectronic,and magnetic functional materials.However,the structure-property relationships governing the interplay between the chemical structure and electromagnetic property of the metal-backboned polymer have been rarely investigated.Here we report a carbon/nickel hybrid from metal-backboned polymer to serve as electromagnetic wave-absorbing materials,which exhibit high microwave absorption capacity and tunable absorption band.The presence of nickel backbones promote the generation of heterogeneous interfaces with carbon during calcination,thereby enhancing the wave-absorbing capacity of the carbon/nickel hybrid.The C/Ni hybrids show a minimal reflection loss of-49.1 dB at 13.04 GHz,and its frequency of the absorption band can be adjusted by controlling the thickness of the absorption layer.
文摘Poly (EA-MAn-APTES)/silica hybrid materials were successfully prepared fromEthyl acrylate (EA), maleic anhydride (MAn) and tetraethoxysilane (TEOS) in the presence of acoupling agent 3-aminopropyltriethoxysilane (APTES),by free-radical solution polymerization and insitu sol-gel process. The mass fraction of TEOS varied from 0 to 25%. The hybrid materials werecharacterized by the methods of FT-IR spectra, solvent extraction, scanning electron microscope (SEM), transmission electron microscope (TEM), differential scanning calorimetry (DSC) andthermogravimetric analysis (TGA) measuring apparatus to get their structures, gel contents,morphologies, particle sizes and thermal performances. The results show that the covalent bonds arebetween organic and inorganic phases, gel contents in the hybrid materials are much higher, theSiO_2 phase is well dispersed in the polymer matrix, silicon dioxide exist at nanoscale in thecomposites and have excellent thermal stability.
基金financially supported by the Yangzhou Key Research and Development Program: Industry Foresight and Key Core Technology (No. YZ2023019)Cooperation Project of Yangzhou City with Yangzhou University (No. YZ2023209)+2 种基金Jiangsu Provincial Six Talent Peaks Project (No. XCL-090)Priority Academic Program Development of Jiangsu Higher Education Institutions (PAPD)Yangzhou Bangjie New Materials Co., Ltd. for support。
文摘The micro-dispersion structure of silica fillers exerts significant infiuences on the performance characteristics of rubber-based products. How to monitor this parameter is an important issue in the rubber industry, but there is currently no suitable technical solution for numerical monitoring that can be applied in automatic production line. The labeling of silica in rubber is a challenge that bottlenecks the development of numerical quality monitoring technology. In this work, we employed the organometallic europium to modify silica endowing the fiuorescence properties for characterization. It provides more feasible solutions for visually studying the relationship between the submicroscopic structure and macroscopic properties of inorganic-filled polymers, and is the key foundation for achieving numerical monitoring of rubber filler qualities in industry.
基金supported by Jiangxi Provincial Natural Science Foundation,China(Nos.20242BAB25195 and 20224BAB211018)National Natural Science Foundation of China(No.12264029)+1 种基金the Scientific Research Foundation of Jiangxi Provincial Education Department,China(No.GJJ211944)the college Students’Innovation and Entrepreneurship Training program of Jiangxi Province,China.
文摘Electrode materials that rely on conversion reactions for lithium-ion batteries(LIBs)possess high energy densities.However,a key issue in their design is bolstering their stability and minimizing volume variations during lithiation and delithiation.Herein,an effect-ive strategy was devised to fulfill the fully reversible conversion reaction for lithium storage in CoMoO_(4) through the hybridization of Co-MoO_(3).CoMoO_(3)/CoMoO_(4) with a nanorod structure was synthesized via one-step annealing treatment after a solvothermal process.In such a structure,the CoMoO_(3)/CoMoO_(4) nanorod can considerably boost mechanical robustness and offer ample space to counteract volume fluctuations throughout successive cycles owing to the cooperative interaction between CoMoO_(3) and CoMoO_(4).CoMoO_(3)/CoMoO_(4) exhib-ited superior lithium-storage capacity(919.6 mAh/g at 0.1 A/g after 200 cycles)and cycling stability(683.4 mAh/g at 1 A/g after 600 cycles).CoMoO_(3)/CoMoO_(4) showed a high potential as an anode material for LIBs.
基金supported by the Young Talent Support Fund from Jiangsu University(No.5501310013)Jiangsu Provincial Founds for Young Scholars(Nos.BK20210782 and BK20210744)+2 种基金the Fellowship of China Postdoctoral Science Foundation(No.2022M720057)Wenzhou Science&Technology Program(No.ZG2021025)Guangdong Basic and Applied Basic Research Foundation(No.2022A1515111017).
文摘Hybrid materials with synergistic properties have been used for various applications.Herein,we report a green biosynthesis strategy for the fabrication of a novel Pd/bacteria@ZIF-8 composite,featuring a sandwiched structure and size-selective capabilities.The Shewanella oneidensis(S.oneidensis)MR-1 was selected as the biological reductant to reduce Pd ions and synthesize Pd nanoparticles anchored on the surface of bacteria without the need for additional chemical reductants,bonding agents and toxic surfactants.This innovative sandwiched Pd/bacteria@ZIF-8 catalyst was further coated by the ZIF-8 to enhance its structural integrity.The as-prepared composite exhibits significant catalytic activity and excellent size-selective performance in the hydrogenation of olefins.This methodology opens up a horizon to designing size-selective catalysts through constructing the sandwiched structure.
基金supported by the National Natural Science Foundation of China(No.22271090)。
文摘Herein,a simple and effective outer-surface interactions assisted supramolecular hierarchical assembly has been first exploited to uniformly distribute tungstosilicic acid(TSA)inside the porous structure of cucurbit[10]uril-based single-layer 2D supramolecular-organic-frameworks(Q[10]-SOFs)in water.Importantly,the 2D Q[10]-SOFs can further serve as light harvesting antenna,achieving fast energy transfer to the embedded redox-active TSA upon photoexcitation,resulting in efficient visible light-driven selective oxidation of benzyl alcohols into the corresponding aldehydes in high yield at room temperature.Further studies revealed that the integrated of 2D Q[10]-SOFs and TSA played a key role in the catalytic process,due to the presence of a novel stepwise electron transfer route in the single-layer hybrid 2D structures.
基金financially supported by the National Natural Science Foundation of China(Nos.51572157,21902085 and 51702188)Natural Science Foundation of Shandong Province(No.ZR2019QF012)+1 种基金Fundamental Research Funds for the Central Universities(Nos.2018JC036 and 2018JC046)Shandong Key Research and Development Program(No.2019JZZY010312)。
文摘The increasingly severe electromagnetic microwave pollution raises higher requirements for the development of efficient microwave absorption(MA)materials.Metal sulfides are regarded as potential robust MA materials because of their unique optical,thermal,electrical,and magnetic properties,as well as the controllable microstructures.However,due to the limited MA performances of unary metal sulfides,morphology regulations and foreign materials hybridizations are adopted as effective strategies to improve their MA performances.Recent years witnessed the fast research progresses on the metal sulfides based MA materials and thus,a systematic literature survey on the materials design,fabrication,characterizations,MA behaviors,and the mechanisms behind is,highly desirable to summarize the rapid progress of this hot research area so as to provide guidance for the future development trend.This review firstly reviewed the research background,research progress,and basic principles of MA materials.Subsequently,the present synthetic methods and performance improvement strategies of metal sulfides based MA materials are systematically introduced.Then,by comparing the MA properties of one-dimensional,two-dimensional,and three-dimensional metal sulfides based composites,the influence of dimensionality and morphology on the MA properties are analyzed.By summarizing the research process of metal sulfides/dielectrics composites,metal sulfides/magnets composites,and metal sulfides/dielectrics/magnets composites MA materials,the influence of foreign materials hybridizations on the loss mechanisms and impedance matching conditions of metal sulfides based composites are revealed.Finally,the challenges and development prospects of metal sulfides based MA materials are presented.This review would provide a comprehensive understanding and insightful guidance for the exploration and development of efficient MA materials with thin thickness,light weight,wide absorption bandwidth,and strong absorption intensity.
基金the financial support by MOST (2011CBA00504)NSFC (21133010, 50921004, 212111074) of China
文摘Nanocarbon materials play a critical role in the development of new or improved technologies and devices for sustainable production and use of renewable energy. This perspective paper defines some of the trends and outlooks in this exciting area, with the effort of evidencing some of the possibilities offered from the growing level of knowledge, as testified from the exponentially rising number of publications, and putting bases for a more rational design of these nanomaterials. The basic members of the new carbon family are fullerene, graphene, and carbon nanotube. Derived from them are carbon quantum dots, nanohorn, nanofiber, nano ribbon, nanocapsulate, nanocage and other nanomorphologies. Second generation nanocarbons are those which have been modified by surface functionalization or doping with heteroatoms to create specific tailored properties. The third generation of nanocarbons is the nanoarchitectured supramolecular hybrids or composites of the first and second genera- tion nanocarbons, or with organic or inorganic species. The advantages of the new carbon materials, relating to the field of sustainable energy, are discussed, evidencing the unique properties that they offer for developing next generation solar devices and energy storage solutions.
基金the National Key Research and Development Program of China(2017YFB1104300).
文摘Naturally derived nanocellulose with unique physiochemical properties and giant potentials as renewable smart nanomaterials opens up endless novel advanced functional materials for multi-sensing applications.However,integrating inorganic functional two-dimensional carbon materials such as graphene has realized hybrid organic-inorganic nanocomposite materials with precisely tailored properties and multi-sensing abilities.Altogether,the affinity,stability,dispersibility,modification,and functionalization are some of the key merits permitting their synergistic interfacial interactions,which exhibited highly advanced multifunctional hybrid nanocomposites with desirable properties.Moreover,the high performance of such hybrids could be achievable through green and straightforward approaches.In this context,the review covered the most advanced nanocellulose-graphene hybrids,focusing on their synthetization,functionalization,fabrication,and multi-sensing applications.These hybrid films exhibited great potentials as a multifunctional sensing platform for numerous mechanical,environmental,and human bio-signals detections,mimicking,and in-situ monitoring.
基金Project supported by the National Natural Science Foundation of China(21161023,21661034)
文摘Photoluminescent hybrid materials containing carboxymethyl cellulose and lanthanide ions（Eu3＋, Tb3＋）were prepared by a facile method under ambient conditions. Lanthanide ions were covalently grafted to the cellulose framework through coordination with the carboxylic groups of the cellulose. Hybrid materials were fabricated as hydrogel and aerogel. As shown by SEM and pore parameters, aerogel materials which were obtained by supercritical CO2 drying show hierarchical porous structure. The photoluminescence spectrum of the hybrid materials shows the characteristic red emission of Eu3＋ ion and green emission of Tb3＋. Further luminescent investigations reveal that these hybrid materials can detect Fe3＋ with relative selectivity and high sensitivity, which suggests that the hybrid materials could be a promising luminescent probe for selectively sensing Fe3＋ ion.
基金supported by the National Natural Science Foundation of China (51203071, 51363014 and 51463012)China Postdoctoral Science Foundation (2014M552509, 2015T81064)+2 种基金Natural Science Funds of the Gansu Province (2015GS05123)Program for Hongliu Distinguished Young Scholars in Lanzhou University of Technology (J201402)University Scientific Research Project of Gansu Province (2014B-025)
文摘Hybrid materials of vanadium nitride and porous carbon nanoparticles(VN/PCNPs) were fabricated by a facile pyrolysis process of vanadium pentoxide(V_2O_5) xerogel and melamine at relatively low temperature of 800 °C for supercapacitor application. The effects of the feed ratio of V_2O_5 to melamine(r), and nitrogen flow rate on the microstructure and electrochemical performance were also investigated. It was found that the size of the as-synthesized nanoparticles is about 20 nm. Both r value and N_2 flow rate have enormous impacts on morphology and microstructure of the nanoparticle, which correspondingly determined the electrochemical performance of the material. The VN/C hybrid nanoparticles exhibited high capacitive properties, and a maximum specific capacitance of 255.0 Fg^(-1) was achieved at a current density of 1.0 Ag^(-1) in 2 M KOH aqueous electrolyte and the potential range from 0 to -1.15 V. In addition,symmetrical supercapacitor fabricated with the as-synthesized VN/PCNPs presents a high specific capacitance of 43.5 F g^(-1) at 0.5 A g^(-1) based on the entire cell, and an energy density of 8.0 Wh kg^(-1) when the power density was 575 W kg^(-1). Even when the power density increased to 2831.5 W kg^(-1), the energy density still remained 6.1 Wh kg^(-1).
基金Project supported by the National Natural Science Foundation of China (No. 29874002) and the Outstanding Young Scientist Award from National Natural Science Foundation of China (No. 29825504)
文摘Mesoporous poly(styrene-co-maleic anhydride)/silica hybrid materials have been prepared. The synthesis was achieved by the HCl-catalyzed sol-gel reactions of tetraethyl orthosilicate (TEOS) and styrene-maleic anhydride copolymer in the presence of 3-aminopropyl triethoxysilane (APTES) as a coupling agent and citric acid as a nonsurfactant template or pore-forming agent, followed by ethanol extraction. Characterization results from nitrogen sorption isotherms and powder X-ray diffraction indicate that polymer-modified mesoporous materials with large specific surface areas (e.g. 900 m(2)/g) and pore volumes (e.g. 0.6 cm(3)/g) could be prepared. As the citric acid concentration is increased, the specific surface areas, pore volumes and pore diameters of the hybrid materials increase.
基金Project(2010-0008-277) supported by Program of Establishment of an Infrastructure for Public Usepartly by NCRC (National Core Research Center) through the National Research Foundation of Korea funded by the Ministry of Education
文摘The characteristic evaluation of aluminum oxide （A1203）/carbon nanotubes （CNTs） hybrid composites for micro-electrical discharge machining （EDM） was described. Alumina matrix composites reinforced with CNTs were fabricated by a catalytic chemical vapor deposition method. A1203 composites with different CNT concentrations were synthesized. The electrical characteristic of A1203/CNTs composites was examined. These composites were machined by the EDM process according to the various EDM parameters, and the characteristics of machining were analyzed using field emission scanning electron microscope （FESEM）. The electrical conductivity has a increasing tendency as the CNTs content is increased and has a critical point at 5% A1203 （volume fraction）. In the machining accuracy, many tangles of CNT in A1203/CNTs composites cause violent spark. Thus, it causes the poor dimensional accuracy and circularity. The results show that conductivity of the materials and homogeneous distribution of CNTs in the matrix are important factors for micro-EDM of A1203/CNTs hybrid composites.
基金Project supported by the National Natural Science Foundation of China(51872269,42072053)。
文摘The unique luminescent performance of lanthanide complexes/clay minerals hybrid materials has been fascinating many researchers for recent decades.It not only retains the excellent luminescent characteristics of lanthanide complexes but also improves the poor stability of the complexes.In this article,we introduce the luminescence mechanism of lanthanide complexes and point out the necessity of their combination with clay minerals.After the analysis of the structure and interlayer environment differences of 1:1-type and 2:1-type clay minerals,the intercalation methods(covalent grafting and ion exchange)appropriate for different clay minerals are summarized with examples.Based on the luminescence characteristics of the hybrid materials,the applications of these materials as luminescent probes in recognition of specific metal cations and molecules,detection of pH value,and temperature are reviewed.Finally,the current problems in the preparation of lanthanide complexes/clay minerals hybrid luminescent materials and shortcomings that need improvement in their performance are analyzed,and the application prospect is forecast.
基金Project supported by the National Natural Science Foundation of China(21473133,21173164)。
文摘By employing a rational approach,we prepared a novel kind of luminescent europium-centered hybrid material named Eu(tta)_(3)NCP-TiO_(2).The resulting material was characterized by FT-IR spectra,SEM,X-ray diffraction,thermogravimetric analysis,and photoluminescence spectra.The hybrid material features the combined advantages of the europium complex and the titania host,exhibiting not only good thermostability,but also long luminescence lifetime.Owing to the excellent luminescence of this material,the application in detecting organic small molecule solvents and metal ions was explored systematically.Significantly,Eu(tta)_(3)NCP-TiO_(2) exhibits superior detection for nitrobenzene molecule and Cu^(2+) ion in DMF(N,N-dimethylformamide) medium.Furthermore,the limit of detection(LOD) of Eu(tta)_(3)NCP-TiO_(2) for nitrobenzene and Cu^(2+) ion can be counted as 5.593× 10^(-5) and 9.566 ×10^(-5) mol/L,respectively.The results demonstrate that Eu(tta)_(3)NCP-TiO_(2) can serve as an efficient fluorescence probe for the detection of sensing of nitrobenzene and Cu^(2+) ion.
