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The Market-Oriented Transfer of Rural Land
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作者 杨学成 曾启 《Social Sciences in China》 1996年第2期21-27,192,共8页
关键词 HIGH The market-oriented transfer of Rural Land
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Momentum transfer collision frequencies between electrons and neutrals of astrophysical interest
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作者 YuTian Cao Jun Cui +4 位作者 RuiQi Fu WenJun Liang XiaoShu Wu TieLong Zhang HaoYu Lu 《Earth and Planetary Physics》 2026年第1期82-91,共10页
Theoretical calculations serve as an effective method for determining plasma temperatures within planetary atmospheres.To simulate plasma temperature,a comprehensive implementation of the energy equation is used,which... Theoretical calculations serve as an effective method for determining plasma temperatures within planetary atmospheres.To simulate plasma temperature,a comprehensive implementation of the energy equation is used,which is governed by five terms:conductivity,heating,cooling,adiabatic expansion,and advection.The derivations mentioned are strongly dependent on the collision cross section between electrons and other particles(e.g.,neutrals,ions).It is notable that the momentum transfer cross sections between electrons and neutrals have been updated in recent decades.However,the widely used momentum average collision cross sections between electrons and neutrals,derived from the momentum transfer cross sections,are collected in studies dating back nearly half a century.Therefore,it becomes imperative to revise the momentum average collision cross sections relevant to astrophysical contexts,based on the latest studies.In this study,we summarize the momentum average collision cross sections of 13 species common in planetary atmospheres:H,H_(2),He,O,CH_(4),H_(2)O,CO,N_(2),O_(2),Ar,CO_(2),N_(2)O,and NO_(2).All results are derived from the latest studies concerning the electron-neutral collision cross section and are compared with previous studies.Furthermore,we present a comparison of the derived total electron-neutral collision frequency at Mars between this study and previous studies.Prominent differences in the total electron-neutral collision frequency between this and prior studies support the significance of updating the momentum average collision cross section between electrons and neutrals in studying the planetary atmospheres. 展开更多
关键词 momentum transfer collision planetary atmosphere electron-neutral collision frequency
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Pulsed Dynamic Water Electrolysis:Mass Transfer Enhancement,Microenvironment Regulation,and Hydrogen Production Optimization
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作者 Xuewei Zhang Wei Zhou +7 位作者 Xiaoxiao Meng Yuming Huang Yang Yu Haiqian Zhao Lijie Wang Fei Sun Jihui Gao Guangbo Zhao 《Nano-Micro Letters》 2026年第3期807-859,共53页
Pulsed dynamic electrolysis(PDE),driven by renewable energy,has emerged as an innovative electrocatalytic conversion method,demonstrating significant potential in addressing global energy challenges and promoting sust... Pulsed dynamic electrolysis(PDE),driven by renewable energy,has emerged as an innovative electrocatalytic conversion method,demonstrating significant potential in addressing global energy challenges and promoting sustainable development.Despite significant progress in various electrochemical systems,the regulatory mechanisms of PDE in energy and mass transfer and the lifespan extension of electrolysis systems,particularly in water electrolysis(WE)for hydrogen production,remain insufficiently explored.Therefore,there is an urgent need for a deeper understanding of the unique contributions of PDE in mass transfer enhancement,microenvironment regulation,and hydrogen production optimization,aiming to achieve low-energy consumption,high catalytic activity,and long-term stability in the generation of target products.Here,this review critically examines the microenvironmental effects of PDE on energy and mass transfer,the electrode degradation mechanisms in the lifespan extension of electrolysis systems,and the key factors in enhancing WE for hydrogen production,providing a comprehensive summary of current research progress.The review focuses on the complex regulatory mechanisms of frequency,duty cycle,amplitude,and other factors in hydrogen evolution reaction(HER)performance within PDE strategies,revealing the interrelationships among them.Finally,the potential future directions and challenges for transitioning from laboratory studies to industrial applications are proposed. 展开更多
关键词 Pulsed dynamic electrolysis Water electrolysis Energy and mass transfer MICROENVIRONMENT System stability
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Ultra-fast and high-responsivity self-powered vis-NIR photodetector via surface charge transfer doping in MoTe_(2)/ReS_(2)heterostructures
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作者 Haozhe Ruan Yongkang Liu +5 位作者 Jianyu Wang Linjiang Xie Yixuan Wang Mengting Dong Zhangting Wu Liang Zheng 《Journal of Semiconductors》 2026年第1期99-106,共8页
The development of optoelectronic technologies demands photodetectors with miniaturization,broadband operation,high sensitivity,and low power consumption.Although 2D van der Waals(vd W)heterostructures are promising c... The development of optoelectronic technologies demands photodetectors with miniaturization,broadband operation,high sensitivity,and low power consumption.Although 2D van der Waals(vd W)heterostructures are promising candidates due to their built-in electric fields,ultrafast photocarrier separation,and tunable bandgaps,defect states limit their performance.Therefore,the modulation of the optoelectronic properties in such heterostructures is imperative.Surface charge transfer doping(SCTD)has emerged as a promising strategy for non-destructive modulation of electronic and optoelectronic characteristics in two-dimensional materials.In this work,we demonstrate the construction of high-performance p-i-n vertical heterojunction photodetectors through SCTD of MoTe_(2)/ReS_(2)heterostructure using p-type F_(4)-TCNQ.Systematic characterization reveals that the interfacial doping process effectively amplifies the built-in electric field,enhancing photogenerated carrier separation efficiency.Compared to the pristine heterojunction device,the doped photodetector exhibits remarkable visible to nearinfrared(635-1064 nm)performance.Particularly under 1064 nm illumination at zero bias,the device achieves a responsivity of 2.86 A/W and specific detectivity of 1.41×10^(12)Jones.Notably,the external quantum efficiency reaches an exceptional value of 334%compared to the initial 11.5%,while maintaining ultrafast response characteristics with rise/fall times of 11.6/15.6μs.This work provides new insights into interface engineering through molecular doping for developing high-performance vd W optoelectronic devices. 展开更多
关键词 MoTe_(2)/ReS_(2)heterostructure broadband photodetector surface charge transfer doping P-I-N
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Chemical exchange saturation transfer MRI for neurodegenerative diseases:An update on clinical and preclinical studies
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作者 Ahelijiang Saiyisan Shihao Zeng +4 位作者 Huabin Zhang Ziyan Wang Jiawen Wang Pei Cai Jianpan Huang 《Neural Regeneration Research》 2026年第2期553-568,共16页
Chemical exchange saturation transfer magnetic resonance imaging is an advanced imaging technique that enables the detection of compounds at low concentrations with high sensitivity and spatial resolution and has been... Chemical exchange saturation transfer magnetic resonance imaging is an advanced imaging technique that enables the detection of compounds at low concentrations with high sensitivity and spatial resolution and has been extensively studied for diagnosing malignancy and stroke.In recent years,the emerging exploration of chemical exchange saturation transfer magnetic resonance imaging for detecting pathological changes in neurodegenerative diseases has opened up new possibilities for early detection and repetitive scans without ionizing radiation.This review serves as an overview of chemical exchange saturation transfer magnetic resonance imaging with detailed information on contrast mechanisms and processing methods and summarizes recent developments in both clinical and preclinical studies of chemical exchange saturation transfer magnetic resonance imaging for Alzheimer’s disease,Parkinson’s disease,multiple sclerosis,and Huntington’s disease.A comprehensive literature search was conducted using databases such as PubMed and Google Scholar,focusing on peer-reviewed articles from the past 15 years relevant to clinical and preclinical applications.The findings suggest that chemical exchange saturation transfer magnetic resonance imaging has the potential to detect molecular changes and altered metabolism,which may aid in early diagnosis and assessment of the severity of neurodegenerative diseases.Although promising results have been observed in selected clinical and preclinical trials,further validations are needed to evaluate their clinical value.When combined with other imaging modalities and advanced analytical methods,chemical exchange saturation transfer magnetic resonance imaging shows potential as an in vivo biomarker,enhancing the understanding of neuropathological mechanisms in neurodegenerative diseases. 展开更多
关键词 Alzheimer’s disease chemical exchange saturation transfer Huntington’s disease magnetic resonance imaging molecular imaging multiple sclerosis neurodegenerative disease Parkinson’s disease
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The Training Model and Development Route of Market-oriented Professional Farmers
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作者 李彬 《Agricultural Science & Technology》 CAS 2016年第3期747-750,共4页
To cultivate new professional farmers is a key way for rural labor development, resolving existing problems such as how to farming. It is notable that government and market take advantages in training of new professio... To cultivate new professional farmers is a key way for rural labor development, resolving existing problems such as how to farming. It is notable that government and market take advantages in training of new professional farmers. Therefore, it is necessary to guarantee government and market playing the roles. The research explored market-oriented farmer training model and the characteristics and investigated training routes for new professional farmers. 展开更多
关键词 New professional farmers market-oriented training model Development route
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Research on the effects of command-and-control and market-oriented policy tools on China's energy conservation and emissions reduction innovation 被引量:2
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作者 Qin Ye Shaoqing Dai Gang Zeng 《Chinese Journal of Population,Resources and Environment》 2018年第1期1-11,共11页
The impact of environmental regulation on technology innovation is a hot spot in current research where a large number of empirical studies are based on Porter Hypothesis(PH). However, there are still controversies in... The impact of environmental regulation on technology innovation is a hot spot in current research where a large number of empirical studies are based on Porter Hypothesis(PH). However, there are still controversies in academia about the establishment of "weak" and "narrow" versions of PH. Based on the panel data of application for patent of energy conservation and emission reduction(ECER) technology of Chinese city scale during 2008-2014, comprehensive energy price, pollutant emission, etc., mixed regression model and systematic generalized method of moments method were adopted, respectively,to study the impact of market-oriented and command-and-control policy tool on China's ECER technology innovation. The results show that the environmental regulation hindered the technological innovation in the immediate phase; however, it turned out to be positive in the first-lag phase. Hence, the establishment of "weak" PH is time-bounded. The command-and-control policy tool played a more positive role in promoting technological innovation in the first-lag phase than market-oriented policy tool. Therefore, "narrow" PH is not tenable. The reason is that the main participants of China's ECER technology innovation are state-owned companies and public institutions. Regionally speaking, the impact which command-and-control policy tool has on technological innovation at sight was nonsignificant in the eastern, the central, and the western regions of China whilst market-oriented policy tool had a negative effect. And market-oriented policy tool in the central region had strongest negative effect, which would diminish in the eastern region and become weakest in the western region. This was related to regional energy consumption level and the market economic vitality. 展开更多
关键词 Environmental regulation command-and-control policy tools market-oriented policy tools emissions reduction INNOVATION
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Market-oriented management method of coalmine accident hidden dangers
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作者 刘兆霞 李兴东 +1 位作者 路英 任大伟 《Journal of Coal Science & Engineering(China)》 2007年第3期355-358,共4页
By analyzing the problems which exist currently in the accident hidden dangers management of the coal mine, this paper proposed a new kind of management method--"simulating the market", in which an operation pattern... By analyzing the problems which exist currently in the accident hidden dangers management of the coal mine, this paper proposed a new kind of management method--"simulating the market", in which an operation pattern of simulating the market to transact hidden troubles was constructed. This method introduces "Market Mechanism" into safe management, and adopts measurable value to describe the hidden dangers such as" human behavior, technique, environment, equipments etc.". It regards the hidden dangers as "the goods produced by labor" which are found out by the safety managers and the security inspectors, then sells as "commodity". By the process of disposing, counterchecking, re-selling, and redisposing. It forms a set of market-oriented closed-form management pattern of coalmine accident hidden dangers. This kind of management method changes the past traditional methods in which the wageworkers treat safety management passively, but to encourage and restrict them to participate in the check-up and improvement of the hidden dangers. 展开更多
关键词 accident hidden dangers market-oriented market mechanism closed-form
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Dynamic Spatial Evolution of Market-oriented Supply Level of State-owned Land
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作者 Jiong WANG 《Asian Agricultural Research》 2014年第10期80-84,共5页
The purpose of this study is to analyze the characteristics of the spatial distribution and change trend of the marketing level of stateowned land supply so as to provide policy recommendations. Method of spatial auto... The purpose of this study is to analyze the characteristics of the spatial distribution and change trend of the marketing level of stateowned land supply so as to provide policy recommendations. Method of spatial autocorrelation analysis is employed. The results indicate that the spatial layout of the land supply marketing level is generally dispersed,but it does assemble in some specific area. The correlation between the marketing level of state-owned land supply and the economic development is not statistically significant. But their relations fluctuate obviously. The overall marketing level of state-owned land supply is increasing and spatially concentrated. The expansion rate of marketing has decreased first and then increased and stabilized now. The high-value cluster center of marketing level of state-owned land supply exists all over the country; however the existence probability of the cluster is bigger in undeveloped areas. It is concluded that spatial autocorrelation analysis is a good method to quantitatively analyze the spatial variation of marketing level of state-owned land supply in China. To grasp the spatial and temporal variations of the marketing level of state-owned land supply is also good to enhance running of the state-owned land market. 展开更多
关键词 LAND MANAGEMENT market-oriented supply EVOLUTION t
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World Market-oriented Shanghai Port Machinery Co.Ltd.
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《China's Foreign Trade》 1997年第1期26-26,共1页
Not long ago, the Shanghai Port Machinery Co. Ltd. won the bid during international tender for the cement construction equipment for dams and factory buildings of Phase Ⅱ of the Three Gorges Project, thanks to its ex... Not long ago, the Shanghai Port Machinery Co. Ltd. won the bid during international tender for the cement construction equipment for dams and factory buildings of Phase Ⅱ of the Three Gorges Project, thanks to its excellent product quality, advanced technology content and fine enterprise image, obtaining the contract to build the world’s largest, technically difficult overhead cranes, fully displaying its tremendous strength. 展开更多
关键词 World market-oriented Shanghai Port Machinery Co.Ltd CO VIEW HIGH
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Will Market-Oriented Reforms Propel Technology Progress?Empirical Evidence from China’s High-Tech Sectors
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作者 Dai Kuizao Liu Youjin 《China Economist》 2021年第4期85-100,共16页
This paper aims to explore the effects of market-oriented reforms on industrial technology progress.Based on a theoretical analysis,we performed an empirical study with a marketization index and panel data of high-tec... This paper aims to explore the effects of market-oriented reforms on industrial technology progress.Based on a theoretical analysis,we performed an empirical study with a marketization index and panel data of high-tech sectors in China.We found that market-oriented reforms had significantly propelled technology progress in China’s high-tech sectors,and the effects became more evident after China’s WTO entry.Market-oriented reforms induced technology progress by increasing capital allocation efficiency,R&D input,and technology diffusion.Among various aspects of market-oriented reforms,the institutional environment exerted the most significant effects,followed by the economy’s non-state sector,product market development,and factor market development;the government-market relationship index influenced technology’s progress the least.The effects are heterogeneous across sectors with different technology attributes and more significant for technology-intensive sectors.Our findings offer policy implications for China’s ongoing market-oriented reforms and policy design for technology progress in high-tech sectors. 展开更多
关键词 market-oriented reforms technology progress transmission mechanism high-tech sectors
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Perfecting the Market-Oriented Ecological Compensation Mechanism of Ethnic Minority Areas: A Case Study of Gannan Tibetan Autonomous Prefecture
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作者 HE Aihong WANG Yilong 《Journal of Landscape Research》 2017年第4期45-48,52,共5页
The construction of the market-oriented ecological compensation mechanism in China is complicated system engineering. China's ecological compensation funds are mainly derived from the public finance, lacking marke... The construction of the market-oriented ecological compensation mechanism in China is complicated system engineering. China's ecological compensation funds are mainly derived from the public finance, lacking market-oriented operation. That not only increases the financial burden of the government, but also leads to the incomprehensive compensation scope. Moreover, China's ecological compensation lacks market mechanism so that it is difficult to set compensation standards and calculate offsets. This paper takes Gannan Tibetan Autonomous Prefecture as an example to analyze the market-oriented ecological compensation system of ethnic minority areas from the perspective of market economy, so as to provide a theoretical basis and a reference point for the establishment of efficient and reasonable ecological compensation mechanism and policies in ethnic minority areas and provide environmental protection for the sustainable development of economy and society of ethnic minority areas. 展开更多
关键词 Ethnic Minority Areas market-oriented ecological compensation mechanism Gannan Tibetan Autonomous Prefecture
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Market-Oriented Interest Rates
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《ChinAfrica》 2012年第7期34-35,共2页
China's central bank cut interest rates for deposits and loans and adjusted their floating ranges on June 8.Yi Xianrong,a research fellow with the Institute of Finance and Bankingunder the Chinese Academy of Social S... China's central bank cut interest rates for deposits and loans and adjusted their floating ranges on June 8.Yi Xianrong,a research fellow with the Institute of Finance and Bankingunder the Chinese Academy of Social Sciences, shared his views on the impact of the cut with Shanghai Securities News. Edited excerpts follow: 展开更多
关键词 market-oriented Interest Rates CPI
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Market-Oriented Electricity Pricing Mechanism Should be Eagerly Set Up in China
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作者 Zeng Ming and Xu Zhiyong North China Electric Power University Ye Qing 《Electricity》 2008年第1期36-39,共4页
Electricity pricing is the core of the power institutional reform in China, which is related to not onlyinterests redistribution of all parties, but also health and security of the entire power industry. Only byaccele... Electricity pricing is the core of the power institutional reform in China, which is related to not onlyinterests redistribution of all parties, but also health and security of the entire power industry. Only byaccelerating the reform on pricing mechanism can sound development of the power industry be promoted. 展开更多
关键词 market-oriented Electricity Pricing Mechanism Should be Eagerly Set Up in China
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The role of mitochondria transfer in cancer biological behavior,the immune system and therapeutic resistance 被引量:1
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作者 Xintong Lyu Yangyang Yu +2 位作者 Yuanjun Jiang Zhiyuan Li Qiao Qiao 《Journal of Pharmaceutical Analysis》 2025年第3期511-522,共12页
Mitochondria play a crucial role as organelles,managing several physiological processes such as redox balance,cell metabolism,and energy synthesis.Initially,the assumption was that mitochondria primarily resided in th... Mitochondria play a crucial role as organelles,managing several physiological processes such as redox balance,cell metabolism,and energy synthesis.Initially,the assumption was that mitochondria primarily resided in the host cells and could exclusively transmit from oocytes to offspring by a mechanism known as vertical inheritance of mitochondria.Recent scholarly works,however,suggest that certain cell types transmit their mitochondria to other developmental cell types via a mechanism referred to as intercellular or horizontal mitochondrial transfer.This review details the process of which mitochondria are transferred across cells and explains the impact of mitochondrial transfer between cells on the efficacy and functionality of cancer cells in various cancer forms.Specifically,we review the role of mitochondria transfer in regulating cellular metabolism restoration,excess reactive oxygen species(ROS)generation,proliferation,invasion,metastasis,mitophagy activation,mitochondrial DNA(mtDNA)inheritance,immune system modulation and therapeutic resistance in cancer.Additionally,we highlight the possibility of using intercellular mitochondria transfer as a therapeutic approach to treat cancer and enhance the efficacy of cancer treatments. 展开更多
关键词 Mitochondria transfer Cancer biological behavior Immune system Therapeutic resistance
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Energy transfer enhanced photocatalytic hydrogen evolution in organic heterostructure nanoparticles via flash nanoprecipitation processing 被引量:1
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作者 Miaojie Yu Weiwei Zhang +4 位作者 Xueyan Liu Guohui Zhao Jun Du Yongzhen Wu Wei-Hong Zhu 《Green Energy & Environment》 2025年第2期390-398,共9页
Organic nanophotocatalysts are promising candidates for solar fuels production,but they still face the challenge of unfavorable geminate recombination due to the limited exciton diffusion lengths.Here,we introduce a b... Organic nanophotocatalysts are promising candidates for solar fuels production,but they still face the challenge of unfavorable geminate recombination due to the limited exciton diffusion lengths.Here,we introduce a binary nanophotocatalyst fabricated by blending two polymers,PS-PEG5(PS)and PBT-PEG5(PBT),with matched absorption and emission spectra,enabling a Forster resonance energy transfer(FRET)process for enhanced photocatalysis.These heterostructure nanophotocatalysts are processed using a facile and scalable flash nanoprecipitation(FNP)technique with precious kinetic control over binary nanoparticle formation.The resulting nanoparticles exhibit an exceptional photocatalytic hydrogen evolution rate up to 65 mmol g^(-1) h^(-1),2.5 times higher than that single component nanoparticles.Characterizations through fluorescence spectra and transient absorption spectra confirm the hetero-energy transfer within the binary nanoparticles,which prolongs the excited-state lifetime and extends the namely“effective exciton diffusion length”.Our finding opens new avenues for designing efficient organic photocatalysts by improving exciton migration. 展开更多
关键词 Polymer photocatalysts NANOPARTICLES Hydrogen evolution Forster resonance energy transfer
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Identification algorithm of low-count energy spectra under short-duration measurement based on heterogeneous sample transfer 被引量:1
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作者 Hao-Lin Liu Hai-Bo Ji +1 位作者 Jiang-Mei Zhang Jing Lu 《Nuclear Science and Techniques》 2025年第3期12-26,共15页
In scenarios such as vehicle radiation monitoring and unmanned aerial vehicle radiation detection,rapid measurements using a NaI(Tl)detector often result in low photon counts,weak characteristic peaks,and significant ... In scenarios such as vehicle radiation monitoring and unmanned aerial vehicle radiation detection,rapid measurements using a NaI(Tl)detector often result in low photon counts,weak characteristic peaks,and significant statistical fluctuations.These issues can lead to potential failures in peak-searching-based identification methods.To address the low precision associated with short-duration measurements of radionuclides,this paper proposes an identification algorithm that leverages heterogeneous spectral transfer to develop a low-count energy spectral identification model.Comparative experiments demonstrated that transferring samples from 26 classes of simulated heterogeneous gamma spectra aids in creating a reliable model for measured gamma spectra.With only 10%of target domain samples used for training,the accuracy on real low-count spectral samples was 95.56%.This performance shows a significant improvement over widely employed full-spectrum analysis methods trained on target domain samples.The proposed method also exhibits strong generalization capabilities,effectively mitigating overfitting issues in low-count energy spectral classification under short-duration measurements. 展开更多
关键词 Radionuclide identification Low-count Gamma energy spectral analysis HETEROGENEOUS transfer learning
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In situ growth of iron incorporated Ni_(3)S_(2)nanosheet on nickel foam in mediating electron transfer to peroxymonosulfate for pollutant abatement 被引量:1
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作者 Yunjin Yao Zhongming Tao +5 位作者 Hongwei Hu Lijie Zhang Ziwei Ma Yaoyao Wang Shiyang Lin Shaobin Wang 《Journal of Environmental Sciences》 2025年第4期704-718,共15页
Catalytic oxidation of organic pollutants is a well-known and effective technique for pollutant abatement.Unfortunately,this method is significantly hindered in practical applications by the lowefficiency and difficul... Catalytic oxidation of organic pollutants is a well-known and effective technique for pollutant abatement.Unfortunately,this method is significantly hindered in practical applications by the lowefficiency and difficult recovery of the catalysts in a powdery form.Herein,a three-dimensional(3D)framework of Fe-incorporated Ni_(3)S_(2)nanosheets in-situ grown on Ni foam(Fe-Ni_(3)S_(2)@NF)was fabricated by a facile two-step hydrothermal process and applied to trigger peroxymonosulfate(PMS)oxidation of organic compounds inwater.A homogeneous growth environment enabled the uniform and scalable growth of Fe-Ni_(3)S_(2)nanosheets on the Ni foam.Fe-Ni_(3)S_(2)@NF possessed outstanding activity and durability in activating PMS,as it effectively facilitated electron transfer from organic pollutants to PMS.Fe-Ni_(3)S_(2)@NF initially supplied electrons to PMS,causing the catalyst to undergo oxidation,and subsequently accepted electrons from organic compounds,returning to its initial state.The introduction of Fe into the Ni_(3)S_(2)lattice enhanced electrical conductivity,promoting mediated electron transfer between PMS and organic compounds.The 3D conductive Ni foam provided an ideal platform for the nucleation and growth of Fe-Ni_(3)S_(2),accelerating pollutant abatement due to its porous structure and high conductivity.Furthermore,its monolithic nature simplified the catalyst recycling process.A continuous flow packed-bed reactor by encapsulating Fe-Ni_(3)S_(2)@NF catalyst achieved complete pollutant abatement with continuous operation for 240 h,highlighting its immense potential for practical environmental remediation.This study presents a facile synthesis method for creating a novel type of monolithic catalyst with high activity and durability for decontamination through Fenton-like processes. 展开更多
关键词 Nickel foam Organic pollutants Persulfate activation Non-radical pathway Electron transfer
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MXene-induced electronic structure modulation of Fe-Al-LDH to boost the Fenton-like Reaction:Singlet oxygen evolution and electron-transfer mechanisms 被引量:1
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作者 Zhongzhu Yang Zeyan Zhou +2 位作者 Xiaofei Tan Guangming Zeng Chang Zhang 《Journal of Materials Science & Technology》 2025年第1期224-237,共14页
Layered double hydroxide(LDH)based heterogonous peroxymonosulfate(PMS)activation degradation of pollutants has attracted extensive attention.The challenge is to selectively regulate the traditional free radical domina... Layered double hydroxide(LDH)based heterogonous peroxymonosulfate(PMS)activation degradation of pollutants has attracted extensive attention.The challenge is to selectively regulate the traditional free radical dominant degradation pathway into a nonradical degradation pathway.Herein,an interface ar-chitecture of Ti_(3) C_(2) T_(x)-MXene(MXene)loading on the Fe-Al LDH scaffold was developed,which showed excellent stability and robust resistance against harsh conditions.Significantly,the rate constant for tetra-cycline hydrochloride(TC)degradation in the MXene-LDH/PMS process was 0.421 min^(-1),which was ten times faster than the rate constant for pure Fe-Al LDH(0.042 min^(-1)).Specifically,more reactive Fe with the closer d-band center to the Fermi level results in higher electron transfer efficiency.The occupa-tions of Fe-3d orbitals in Mxene/Fe-Al LDH are pushed above the Fermi level to generate,which results in higher PMS adsorption and inhibition of the release of oxygen-containing active species intermedi-ates,leading to the enhanced^(1)O_(2) generation.Additionally,the built-in electric field in the heterojunc-tion was driven by the charge redistribution between MXene and Fe-Al LDH,resulting in a mediated-electron transfer mechanism,differentiating it from the Fe-Al LDH/PMS system.It was fascinating that MXene/Fe-Al LDH achieved satisfactory treatment efficiency in continuous column reactor and real landfill leachate. 展开更多
关键词 Interface engineering Density functional theory Layered double hydroxides PEROXYMONOSULFATE Electron transfer
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