The Carboniferous volcanic reservoir in the Chepaizi Uplift became an exploration hot target in recent years for its substantial amount of oils discovered. However, most of the Carboniferous heavy oils were biodegrade...The Carboniferous volcanic reservoir in the Chepaizi Uplift became an exploration hot target in recent years for its substantial amount of oils discovered. However, most of the Carboniferous heavy oils were biodegraded to PM7 or higher with orders of magnitude variation in oil viscosities. Two oil groups (I and II) exactly corresponding to the western and eastern Chepaizi Uplift were distinguished according to their source diagnose. Furthermore, three oil families (II1, II2 and II3), with the biodegradation level of PM7, PM8–8+, PM9+, respectively, were classified based on molecular compositions and parameter-stripping method of strongly bioresistant parameters. Allowing for this extremely high biodegradation case, more biodegradation refractory compound class were added to establish a refined Manco scale to quantitatively evaluate the biodegradation extent. Refined Manco number (RMN2) positively correlated with the oil density, NSO contents, and absolute concentrations of diasteranes and gammacerane, negatively correlated with the absolute concentrations of diahopane, summed tricyclic terpanes and pentacyclic terpanes. This refined scale showed higher resolution than the PM one to differentiate the biodegradation extent of Carboniferous heavy oils from the Chepaizi Uplift, especially those with same PM values but different oil viscosities.展开更多
【目的】车排子凸起中生界稠油资源丰富,但原油生物降解严重,制约了勘探进程。【方法】为明确车排子凸起东翼中生界原油的生物降解程度,对车排子凸起东翼侏罗纪和白垩纪储层样品抽提出的饱和烃和芳香烃进行了气相色谱—质谱(GC-MS)分析...【目的】车排子凸起中生界稠油资源丰富,但原油生物降解严重,制约了勘探进程。【方法】为明确车排子凸起东翼中生界原油的生物降解程度,对车排子凸起东翼侏罗纪和白垩纪储层样品抽提出的饱和烃和芳香烃进行了气相色谱—质谱(GC-MS)分析,采用分子地球化学指标,对其进行定性与定量评价。【结果】通过聚类分析,将原油分为Ⅰ、Ⅱ、Ⅲ、Ⅳ四类族群。PM(Peters and Moldowan)法分析结果表明Ⅰ_(1)类和Ⅱ_(1)类原油的生物降解程度达PM7,Ⅰ_(2)类和Ⅳ类原油的生物降解程度为PM8;Ⅱ_(2)类和Ⅲ_(1)类原油的生物降解程度为PM9,Ⅲ_(2)类原油生物降解程度为PM9+。基于优化的Manco法求得的MN_(1)值介于19693~215623,Ⅰ类原油的MN_(2)值介于769~919,Ⅱ类原油的MN_(2)值介于768~907,Ⅲ类原油的MN_(2)值介于906~954,Ⅳ类原油的MN_(2)值介于774~817。同一原油族群的Manco数与原油密度、黏度、非烃和沥青质含量均呈现良好的正相关性,与总烃呈现良好的负相关性。优化的Manco法成功厘定了生物降解程度在PM7-PM9+的储层样品,与PM等级评价具有一致性。【结论】与PM法相比,优化的Manco法对原油生物降解的识别分辨率更高。通过PM法定性评价和优化Manco法定量评价相结合,可以很好地揭示原油物性的变化,对稠油区的油气勘探有重要的指导作用。展开更多
基金This work was funded by the National Natural Science Foundation of China(Grant No.42072172,41772120)the Shandong Province Natural Science Fund for Distinguished Young Scholars(Grant No.JQ201311)+1 种基金the SDUST Research Fund(Grant No.2015TDJH101)Associated editor Jie Hao and seven anonymous reviewers were deeply acknowledged for their critical comments and helpful suggestions,which greatly improved the early version of this manuscript.
文摘The Carboniferous volcanic reservoir in the Chepaizi Uplift became an exploration hot target in recent years for its substantial amount of oils discovered. However, most of the Carboniferous heavy oils were biodegraded to PM7 or higher with orders of magnitude variation in oil viscosities. Two oil groups (I and II) exactly corresponding to the western and eastern Chepaizi Uplift were distinguished according to their source diagnose. Furthermore, three oil families (II1, II2 and II3), with the biodegradation level of PM7, PM8–8+, PM9+, respectively, were classified based on molecular compositions and parameter-stripping method of strongly bioresistant parameters. Allowing for this extremely high biodegradation case, more biodegradation refractory compound class were added to establish a refined Manco scale to quantitatively evaluate the biodegradation extent. Refined Manco number (RMN2) positively correlated with the oil density, NSO contents, and absolute concentrations of diasteranes and gammacerane, negatively correlated with the absolute concentrations of diahopane, summed tricyclic terpanes and pentacyclic terpanes. This refined scale showed higher resolution than the PM one to differentiate the biodegradation extent of Carboniferous heavy oils from the Chepaizi Uplift, especially those with same PM values but different oil viscosities.
文摘【目的】车排子凸起中生界稠油资源丰富,但原油生物降解严重,制约了勘探进程。【方法】为明确车排子凸起东翼中生界原油的生物降解程度,对车排子凸起东翼侏罗纪和白垩纪储层样品抽提出的饱和烃和芳香烃进行了气相色谱—质谱(GC-MS)分析,采用分子地球化学指标,对其进行定性与定量评价。【结果】通过聚类分析,将原油分为Ⅰ、Ⅱ、Ⅲ、Ⅳ四类族群。PM(Peters and Moldowan)法分析结果表明Ⅰ_(1)类和Ⅱ_(1)类原油的生物降解程度达PM7,Ⅰ_(2)类和Ⅳ类原油的生物降解程度为PM8;Ⅱ_(2)类和Ⅲ_(1)类原油的生物降解程度为PM9,Ⅲ_(2)类原油生物降解程度为PM9+。基于优化的Manco法求得的MN_(1)值介于19693~215623,Ⅰ类原油的MN_(2)值介于769~919,Ⅱ类原油的MN_(2)值介于768~907,Ⅲ类原油的MN_(2)值介于906~954,Ⅳ类原油的MN_(2)值介于774~817。同一原油族群的Manco数与原油密度、黏度、非烃和沥青质含量均呈现良好的正相关性,与总烃呈现良好的负相关性。优化的Manco法成功厘定了生物降解程度在PM7-PM9+的储层样品,与PM等级评价具有一致性。【结论】与PM法相比,优化的Manco法对原油生物降解的识别分辨率更高。通过PM法定性评价和优化Manco法定量评价相结合,可以很好地揭示原油物性的变化,对稠油区的油气勘探有重要的指导作用。
