The handover speed is always vital for the further development of Wireless Local Area Network(WLAN),which is enjoying a fast growth.Based on the handover technology specified in IEEE 802.11 WLAN,Manageable Fast Handov...The handover speed is always vital for the further development of Wireless Local Area Network(WLAN),which is enjoying a fast growth.Based on the handover technology specified in IEEE 802.11 WLAN,Manageable Fast Handover(MFHO)mechanism is proposed to speed up handover at the Access Point(AP),meet handover demands of services with different Quality of Service(QoS),and ensure service continuity.Adopting a handover policy named'Make-before-break',this mechanism enables wireless APs to control and manage handover between two stations based on improving Inter-Access Point Protocol(IAPP).Tests have been carried out to compare functions and performance of MFHO and IAPP-based handover technology.The test results prove that MFHO provides a higher successful handover ratio and better handover performance than IAPP-based handover technology.展开更多
The letter proposes a three-layer manageable media distribution network system architecture called MSPnet, which is based on Session Initiation ProtocolIll and Peer to Peer （SIP P2P） technology. MSPnet performs appl...The letter proposes a three-layer manageable media distribution network system architecture called MSPnet, which is based on Session Initiation ProtocolIll and Peer to Peer （SIP P2P） technology. MSPnet performs application-level structured DHT routing and resource location among domains and unstructured ones in domain. Except for media distribution, it can be used to support a variety of P2P applications, including video broadcasting, video on demand, VoIP, etc. MSPnet is composed of three layers, namely, the signal control layer, the management layer, and the media transportation layer. The MSPnet prototype consists of the SIP server, the management server, the media server, and the node User Agent （UA）. Results from a prototype experiment in a large-scale Internet environment show that MSPnet is feasible, scalable and manageable.展开更多
Purpose-Interface management is the process of managing communications,responsibilities and coordination of project parties,phases or physical entities which are dependent on one another.Interface management is a cruc...Purpose-Interface management is the process of managing communications,responsibilities and coordination of project parties,phases or physical entities which are dependent on one another.Interface management is a crucial part of managing any construction project-but particularly important for high-speed railway projects that often have several contractual parties and stakeholders,very long project timelines and huge upfront cost overlays.This paper discusses how various project interfaces were managed during the design and construction of the civil engineering infrastructure for the High Speed Two(HS2)project in the United Kingdom.Design/methodology/approach-The paper uses the case study methodology.Key interfaces on the HS2 project are grouped into various categories and the paper discusses how they were managed within the Area North Integrated Project Team(IPT)of the HS2 project made up of contractor Balfour Beatty VINCI(BBV),the Mott MacDonald SYSTRA Design Joint Venture(DJV)and client HS2 Ltd.3 different case studies drawn from across the IPT are used,each of them highlighting different interfaces and how these interfaces were managed.Findings-The paper shows how innovative technical designs and modern methods of construction were used to address some of the unique and peculiar challenges of designing a brand-new railway in the United Kingdom.Addressing the contrasting and often competing requirements of different stakeholders,coupled with challenging physical constraints of the very limited land available for the project and the use of a rarely used Act of Parliament in the delivery of the project required different approach to interface management.Collaboration and proactive stakeholder engagement are necessary for successful interface management on megaprojects.The authors posit that adopting an integrated approach to engineering and construction management is an essential ingredient for the successful delivery of high-speed railway projects.Originality/value-With many high-speed railway projects around the world coming up in the next few years,understanding the context and challenges for each country will help engineering and design managers adopt appropriate approaches for their projects.The lessons learned on the HS2 project are also transferable to other mega infrastructure projects with complex project interfaces.展开更多
The spatial optimization of best management practices(BMPs) plays a critical role in precise watershed pollution control. However, the effectiveness of BMPs exhibits a complex nonlinear dependence on both configuratio...The spatial optimization of best management practices(BMPs) plays a critical role in precise watershed pollution control. However, the effectiveness of BMPs exhibits a complex nonlinear dependence on both configuration unit scale and rainfall intensity, often leading to widespread spatiotemporal mismatches during implementation. To fill this gap, this study proposes a new framework:(a) delineating configuration units based on the implementation scale differences between structural and nonstructural BMPs;(b) incorporating BMP reduction thresholds to enable dynamic adjustment of design scales according to inflow loads;and(c) developing a staged allocation strategy tailored to varying rainfall scenarios. The framework is exemplified by an agricultural catchment in the southeastern Liaohe watershed, China. The results showed that the framework could improve the assessment accuracy and cost-effectiveness of pollution control. Specifically, neglecting BMP reduction thresholds resulted in a 51.35% underestimation of treatment costs. Incorporating these thresholds and dynamically adjusting BMP design scales reduced treatment costs by 62.70%. Furthermore, the framework facilitated more precise localization of structural BMPs(1 km^(2)) and improved optimization efficiency by 95.91%. The proposed staged allocation strategy ensured water quality compliance under varying rainfall intensities. Structural BMPs primarily addressed pollution from light to moderate rainfall in the initial stage, while nonstructural BMPs targeted heavy rainfall pollution in the subsequent stage. The proposed framework may enhance the spatiotemporal adaptability of BMP configuration to respond to the threats posed by climate change and human activities. It can also be extended to other agriculture-dominated watersheds.展开更多
The proton exchange membrane fuel cell(PEMFC)and the hydrogen hybrid power system are studied by the fuzzy-PID(FPID)controlmethod and the fuzzy-PID controlmethod by Artificial Bee Colony algorithm(ABCFPID),respectivel...The proton exchange membrane fuel cell(PEMFC)and the hydrogen hybrid power system are studied by the fuzzy-PID(FPID)controlmethod and the fuzzy-PID controlmethod by Artificial Bee Colony algorithm(ABCFPID),respectively.The results reveal that compared with the FPID control method,the temperature overshoot of the PEMFC stack under the ABC-FPID control method is decreased by 0.6%.Moreover,the circulating water flow rate within the full operating envelope(about 3 min)is reduced by 19.46 L,which means the ABC-FPID control method is more effective in regulating the stack temperature.Then,the ABC-FPID control method is proposed to study the hydrogen hybrid power system,and the system output power matching,operating characteristic curve of the fuel cell,state of charge(SOC)of the lithium battery,system efficiency and hydrogen demand are obtained.The results indicate that the maximum system efficiency reaches 46.3%,the average system efficiency is 33.8%,and the average hydrogen demand is 0.192 kg/s.Overall,the ABC-FPID control method can efficiently ensure the stability of the fuel cell’s output power,and actively prompt the lithium battery to fulfill the function of“peak shaving and valley filling”under variable load power conditions.展开更多
Objective:To investigate the application effect of intelligent empowerment standardized airway management process in patients receiving mechanical ventilation.Methods:A retrospective analysis was conducted on the clin...Objective:To investigate the application effect of intelligent empowerment standardized airway management process in patients receiving mechanical ventilation.Methods:A retrospective analysis was conducted on the clinical data of 79 EICU inpatients who underwent tracheal intubation and mechanical ventilation treatment at our hospital from January 2023 to May 2025.The patients were divided into a control group(conventional airway management process,n=40)and a study group(intelligent empowerment standardized airway management process,n=39)based on the intervention protocols they received.Oral health scores,dental plaque index,oral odor,serum inflammatory markers[C-reactive protein(CRP),procalcitonin(PCT)],clinical pulmonary infection score(CPIS),as well as the incidence of ventilator-associated pneumonia(VAP),duration of mechanical ventilation,and length of stay in the EICU were assessed before and after treatment.Results:The baseline values of all indicators were consistent between the two groups before intervention(p>0.05).After corresponding interventions,both groups showed significant improvements in Beck oral health scores,dental plaque index,and oral odor,with more pronounced improvements observed in the study group(p<0.05).After the intervention,the research group showed a significant decrease in serum CRP and PCT levels,as well as CPIS scores(p<0.05).In contrast,the control group experienced an increase in these three indicators to a certain extent(p<0.05).Moreover,the incidence of ventilator-associated pneumonia(VAP),duration of mechanical ventilation,and length of stay in the EICU were all lower in the research group compared to the control group,while the nurse’s compliance rate with the protocol was higher in the research group(p<0.05).Conclusion:The standardized airway management protocol empowered by intelligent technology can significantly improve nursing compliance,benefit oral health status,reduce the risk of pulmonary infection and systemic inflammation levels,and promote rapid patient recovery,demonstrating considerable potential for widespread adoption.展开更多
Yam(Dioscorea opposita)is an important economic crop,and the development of its the cultivation tecchnology is of great significance for increasing yield,improving quality,and reducing the occurrence of pests and dise...Yam(Dioscorea opposita)is an important economic crop,and the development of its the cultivation tecchnology is of great significance for increasing yield,improving quality,and reducing the occurrence of pests and diseases.With the progression of agricultural technology and changes in market demands,the cultivation tecchnology of yam is constantly innovating and improving.This paper reviewed recent research advances in yam cultivation tecchnology,covering aspects such as soil improvement,variety selection,technological innovations,green pest control,and harvesting and storage.The goal is to provide references for the sustainable development of the yam industry.展开更多
[Objectives]To analyze the clinical characteristics,distribution of traditional Chinese medicine(TCM)syndrome types,spectrum of comorbidities,and complications among inpatients with gout.[Methods]Data from 592 gout pa...[Objectives]To analyze the clinical characteristics,distribution of traditional Chinese medicine(TCM)syndrome types,spectrum of comorbidities,and complications among inpatients with gout.[Methods]Data from 592 gout patients admitted in the Department of Rheumatology at Wuxi Traditional Chinese Medicine Hospital between January 2018 and December 2024 were retrospectively collected.The data collected encompassed patient gender,age,TCM syndrome types,underlying comorbidities,infection status,and major complications,including renal insufficiency,interstitial lung disease,and osteoporosis.Descriptive statistical analyses were subsequently performed.[Results]Among the 592 inpatients,80.75%were male and 19.25%were female.A total of 94.76%patients had at least one underlying condition,with hypertension(80.74%),cerebral infarction(29.59%),heart disease(24.24%),and diabetes(21.56%)being the most prevalent.The primary TCM syndrome types identified were damp-heat obstruction syndrome(63.51%)and phlegm-stasis obstruction syndrome(21.11%).During hospitalization,20.94%of patients experienced concurrent infections,predominantly pulmonary infections(38.10%).The principal complications observed included renal insufficiency(32.09%),interstitial lung disease(18.75%),and osteoporosis(9.29%).[Conclusions]Inpatients diagnosed with gout often present with complex conditions and a high burden of comorbidities,predominantly cardiovascular and cerebrovascular diseases,as well as metabolic disorders.Additionally,there is a high incidence of infections and renal insufficiency within this population.TCM syndrome types in these patients are primarily characterized by damp-heat obstruction.In clinical practice,a comprehensive management approach that incorporates multidisciplinary collaboration is recommended.Alongside the control of uric acid levels and joint inflammation,proactive screening and management of comorbidities and related complications are essential.展开更多
Invasive pests and pathogens cause immense damage globally,costing an estimated US$248 billion to the agricultural industry alone.Vehicles,such as farming and timber harvesting machinery and transportation trucks,can ...Invasive pests and pathogens cause immense damage globally,costing an estimated US$248 billion to the agricultural industry alone.Vehicles,such as farming and timber harvesting machinery and transportation trucks,can facilitate the rapid spread of biological invaders over distances far greater and more quickly than their natural dispersal ability.Understanding how frequent trips by these vehicles increase the spread of invasive agricultural and forestry pests can help inform effective biosecurity procedures before,during,or after an incursion.We used a case study of timber transport trucks in Aotearoa New Zealand to examine whether and how vehicles facilitate the spread of soil-borne pathogens between commercial forest plantations.Our results show that long-distance dispersal associated with truck movement facilitated the introduction of oomycete-like pathogens in 97% of forest sites within only one year,with pathogen loads within infected sites predicted at 84%of the sites’carrying capacity.Implementing preventative management strategies to reduce the transportation of infected soil by logging trucks,however,can reduce the spread by up to 50% after one year and reduce the pathogen load within infested sites by more than three times.Mitigating other human-assisted dispersal pathways can also help reduce spread.Reducing movement of forest visitors not involved in forestry activities,for instance,by closing forest sites to the public,can help to further reduce spread in addition to management related to harvesting activities.These results highlight the benefits of preventative management strategies in reducing the spread rate of novel soil pathogens through a high-intensity commercial forestry network but show that pest spread is still likely even with significant investment.展开更多
Cyprus has an extensive record in grape production and winemaking.Grapevine is essential for the economic and environmental sustainability of the agricultural sector,as it is in other Mediterranean regions.Intensive a...Cyprus has an extensive record in grape production and winemaking.Grapevine is essential for the economic and environmental sustainability of the agricultural sector,as it is in other Mediterranean regions.Intensive agriculture can overuse and exhaust natural resources,including soil and water.The current study evaluated how conservation strategies,including no tillage and semi-tillage(as a variation of strip tillage),affected grapevine growth and grape quality when compared to conventional tillage application.Two cultivars were used:Chardonnay and Maratheftiko(indigenous).Soil pH decreased,and EC increased after tillage applications,in both vineyards.Tillage lowered soil N levels through mineralization,but the vineyard with Maratheftiko cultivar had higher soil N and K levels than the vineyard with Chardonnay cultivar.No tillage reduced yield in Chardonnay;however,semi-tillage enhanced yield in Maratheftiko.There were no major changes in plant physiology,even though Maratheftiko had less variation in stomatal conductance values under the various tillage practices than Chardonnay.Tillage enhanced N and K content in Chardonnay vines during flowering,and increased N in Maratheftiko.Total phenols and antioxidant status of leaves varied,with tillage stimulating them,especially at the harvest stage.Furthermore,tillage raised grape juice total soluble solids,pH,and total phenols in both cultivars,while anthocyanins and tannins content were increased in Maratheftiko under no tillage.The results of this study may aid in the development of cultivation strategies to enable viticulture to address various environmental challenges due to climate change.展开更多
Heavy metal(HM)contamination severely impacts global agricultural production.HMs toxicity effectively damaged the physiological functions such as imbalanced redox homeostasis,altered antioxidant enzyme activity,damage...Heavy metal(HM)contamination severely impacts global agricultural production.HMs toxicity effectively damaged the physiological functions such as imbalanced redox homeostasis,altered antioxidant enzyme activity,damage root system architecture,hindered photosynthetic apparatus,cellular toxicity,restricted mineral accumulation,and changed the metabolite production.Using phytohormones may be a successful strategy for enhancing and stimulating plant tolerance to HMs toxicity without affecting the environment.Melatonin(MT),a novel plant growth regulator,and powerful antioxidant molecule,enhances plant resilience to HMs stress by enhancing seedling growth,protecting the photosynthetic system,increasing nutritional status,balanced redox homeostasis,and restricting HMs accumulation from root to shoot.In addition,MT enhances the activity of antioxidant enzymes and triggers the ascorbate-glutathione(AsA-GSH)cycle,which helps remove excessive ROS.MT improves RuBisCO activity to improve photosynthesis and reduce the breakdown of chlorophyll.To identify future research needs,it is crucial to understand the comprehensive and intricate regulatory mechanisms of exogenous and endogenous MT-mediated reduction of heavy metal toxicity in plants.Melatonin has several functions,and this review sheds light on those functions and the molecular processes by which it alleviates HMs toxicity.More research is needed to fully understand how melatonin affects plant tolerance to heavy metals stress.展开更多
Purpose-This study explores how managerial leadership and organizational innovation interact to enhance resilience and risk management in railway supply chains and how these capabilities contribute to sustained compet...Purpose-This study explores how managerial leadership and organizational innovation interact to enhance resilience and risk management in railway supply chains and how these capabilities contribute to sustained competitive advantage.It emphasizes the strategic importance of resilience in railway systems that face operational complexity,regulatory pressures and increasing exposure to systemic risks.Design/methodology/approach-A mixed-methods design was employed,integrating survey data from 186 railway organizations with six case studies involving railway operators,rolling stock manufacturers and supply chain partners across multiple regions.Constructs were measured using validated scales and hypothesized relationships were tested using Structural Equation Modeling(SEM).Case study interviews were analyzed thematically to provide contextual understanding of leadership practices and innovation strategies.Findings-The results confirm that transformational managerial leadership significantly predicts innovation adoption,which in turn strengthens resilience and risk management capabilities.Resilience emerged as a powerful driver of competitive advantage,reinforcing its role as a strategic capability rather than a reactive response to disruptions.Furthermore,innovation was shown to partially mediate the relationship between leadership and resilience,highlighting its function as the operational channel through which vision translates into capability.Originality/value-This study contributes to the literature by integrating the Resource-Based View(RBV)and Dynamic Capabilities(DC)framework into the context of railway supply chains.It is among the first to empirically validate the mediating role of innovation between leadership and resilience,offering both theoretical advancements and actionable strategies for building resilient and competitive railway systems.展开更多
Shandong Port Group(SPG),which was established in August 2019,regards standardization as the cornerstone of modern enterprise management,and vigorously implements the standardization innovation strategy.Its standardiz...Shandong Port Group(SPG),which was established in August 2019,regards standardization as the cornerstone of modern enterprise management,and vigorously implements the standardization innovation strategy.Its standardization work mainly focuses on the following four aspects.展开更多
Submission All manuscripts are submitted and reviewed via the journal's web-based manuscript submission system Editorial Manager:https://www.editorialmanager.com/lers/default.aspx.New authors should create an acco...Submission All manuscripts are submitted and reviewed via the journal's web-based manuscript submission system Editorial Manager:https://www.editorialmanager.com/lers/default.aspx.New authors should create an account prior to submitting a manuscript for consideration.If you have any questions about submitting,please contact the editorial office:lersurgery@srrsh.com.展开更多
With the intensification of population aging in China,the problem of cognitive impairment in the elderly has become increasingly prominent,attracting widespread attention from all sectors of society.Geriatric cognitiv...With the intensification of population aging in China,the problem of cognitive impairment in the elderly has become increasingly prominent,attracting widespread attention from all sectors of society.Geriatric cognitive impairment is characterized by chronicity,which not only seriously threatens the health of the elderly and reduces their quality of life,but also imposes a heavy burden on families and society due to its long course.Attaching importance to and strengthening the chronic disease management of elderly cognitive impairment has profound significance for delaying disease progression,improving patients’quality of life,and reducing the burden of family care.Therefore,this paper first comprehensively understands elderly cognitive impairment by briefly elaborating on its definition and characteristics;on this basis,it focuses on exploring effective strategies for the chronic disease management of elderly cognitive impairment,hoping to provide new ideas and methods for the management of this condition and offer useful references for relevant clinical research and practice.展开更多
Cellulose frameworks have emerged as promising materials for light management due to their exceptional light-scattering capabilities and sustainable nature.Conventional biomass-derived cellulose frameworks face a fund...Cellulose frameworks have emerged as promising materials for light management due to their exceptional light-scattering capabilities and sustainable nature.Conventional biomass-derived cellulose frameworks face a fundamental trade-off between haze and transparency,coupled with impractical thicknesses(≥1 mm).Inspired by squid’s skin-peeling mechanism,this work develops a peroxyformic acid(HCOOOH)-enabled precision peeling strategy to isolate intact 10-μm-thick bamboo green(BG)frameworks—100×thinner than wood-based counterparts while achieving an unprecedented optical performance(88%haze with 80%transparency).This performance surpasses delignified biomass(transparency<40%at 1 mm)and matches engineered cellulose composites,yet requires no energy-intensive nanofibrillation.The preserved native cellulose I crystalline structure(64.76%crystallinity)and wax-coated uniaxial fibril alignment(Hermans factor:0.23)contribute to high mechanical strength(903 MPa modulus)and broadband light scattering.As a light-management layer in polycrystalline silicon solar cells,the BG framework boosts photoelectric conversion efficiency by 0.41%absolute(18.74%→19.15%),outperforming synthetic anti-reflective coatings.The work establishes a scalable,waste-to-wealth route for optical-grade cellulose materials in next-generation optoelectronics.展开更多
Soil erosion is a fundamental physical process driving land degradation across various spatial and temporal scales.The Soil and Water Assessment Tool(SWAT)model is a robust tool for predicting soil erosion and evaluat...Soil erosion is a fundamental physical process driving land degradation across various spatial and temporal scales.The Soil and Water Assessment Tool(SWAT)model is a robust tool for predicting soil erosion and evaluating water and soil quality within watersheds.The latest version,SWAT+,introduces advanced encoding capabilities and improved performance,making it better suited for addressing complex watershed modeling challenges.This study implemented the SWAT+model to quantify soil erosion rates within the Chehelchay watershed in northern Iran.The foundational dataset comprises a 30-meter resolution Digital Elevation Model(DEM),land use classification,soil,and weather data.Model performance was evaluated using Nash-Sutcliffe Efficiency(NSE),coefficient of determination(R^(2)),root mean square error(RMSE),and percent bias(PBIAS).The SWAT+simulation revealed substantial spatial variation in erosion patterns across the watershed,with annual sediment yields in critical HRUs,reflecting diverse erosion intensities driven by variations in land use,soil characteristics,and slope.Among the Hydrological Response Units(HRUs),50 critical units,representing approximately 9%of the total watershed area,generate sediment yields exceeding 5 tons per hectare per year.The most severe erosion occurs predominantly in the central zone of the watershed.Downstream regions exhibit minimal soil loss due to gentle topography while upstream areas maintain soil stability through protective forest cover,resulting in negligible erosion rates.Best Management Practices(BMPs)were designed to safeguard water and soil resources at a watershed level.The study evaluated three strategic conservation interventions:alfalfa cultivation,agroforestry implementation,and garden development.When applied in combination,these measures achieved approximately 30%reduction in sediment yield at the HRU level.This integrated approach demonstrates the potential of combining multiple land management strategies to combat erosion effectively.展开更多
As urban landscapes evolve and vehicular volumes soar,traditional traffic monitoring systems struggle to scale,often failing under the complexities of dense,dynamic,and occluded environments.This paper introduces a no...As urban landscapes evolve and vehicular volumes soar,traditional traffic monitoring systems struggle to scale,often failing under the complexities of dense,dynamic,and occluded environments.This paper introduces a novel,unified deep learning framework for vehicle detection,tracking,counting,and classification in aerial imagery designed explicitly for modern smart city infrastructure demands.Our approach begins with adaptive histogram equalization to optimize aerial image clarity,followed by a cutting-edge scene parsing technique using Mask2Former,enabling robust segmentation even in visually congested settings.Vehicle detection leverages the latest YOLOv11 architecture,delivering superior accuracy in aerial contexts by addressing occlusion,scale variance,and fine-grained object differentiation.We incorporate the highly efficient ByteTrack algorithm for tracking,enabling seamless identity preservation across frames.Vehicle counting is achieved through an unsupervised DBSCAN-based method,ensuring adaptability to varying traffic densities.We further introduce a hybrid feature extraction module combining Convolutional Neural Networks(CNNs)with Zernike Moments,capturing both deep semantic and geometric signatures of vehicles.The final classification is powered by NASNet,a neural architecture search-optimized model,ensuring high accuracy across diverse vehicle types and orientations.Extensive evaluations of the VAID benchmark dataset demonstrate the system’s outstanding performance,achieving 96%detection,94%tracking,and 96.4%classification accuracy.On the UAVDT dataset,the system attains 95%detection,93%tracking,and 95%classification accuracy,confirming its robustness across diverse aerial traffic scenarios.These results establish new benchmarks in aerial traffic analysis and validate the framework’s scalability,making it a powerful and adaptable solution for next-generation intelligent transportation systems and urban surveillance.展开更多
The removal of trace plutonium(Pu)from uranium products and organic wastes during spent nuclear fuel reprocessing remains a critical challenge,resulting in excessive plutonium content in uranium products and waste org...The removal of trace plutonium(Pu)from uranium products and organic wastes during spent nuclear fuel reprocessing remains a critical challenge,resulting in excessive plutonium content in uranium products and waste organic liquid.Currently,most organic ligands with selective separation functions are lipophilic,while research on water-soluble,highly selective ligands is relatively scarce,and there are also few reports on the single crystal of these ligands coordinating with plutonium.Herein,a hydrophilic multiamide ligand,N,N,N′,N″,N″-hexaethyl-nitrilotriacetamide(NTAamideC2),was synthesized and evaluated for its Pu(Ⅳ)back-extraction efficiency under harsh conditions.Systematic experiments revealed that NTAamideC2 achieved>99%Pu(Ⅳ)back-extraction rate within 15 min across a wide nitric acid concentration range(0-5 M),even with elevated dibutyl phosphate(DBP≤20000 ppm).Remarkably,the separation factor(SFPu/U)reached 767 at 1.5 M HNO_(3),demonstrating exceptional selectivity over uranium(Ⅵ).Spectrophotometric titration and DFT calculations confirmed the formation of 1:1 and 1:2 Pu(Ⅳ)-NTAamideC2 complexes,with log β values of 7.42±0.01 and 13.23±0.02,respectively.Single-crystal X-ray diffraction analysis of{[Pu_(2)(H_(2)O)_(2)(NTAamideC2)_(4)](H_(2)O)_(2)(NO_(3))(ClO_(4))_(7)}revealed a nine-coordinated PuO_(7)N_(2)geometry,where two NTAamideC2 molecules bind via six O and two N atoms.Compared to conventional agents(AHA/HSC),NTAamideC2 exhibited superior acid tolerance and selectivity,aligning with the CHON principle for sustainable nuclear waste management.This work provides a robust strategy for Pu(Ⅳ)removal in uranium purification cycles and advances fundamental insights into Pu coordination chemistry,offering significant potential for industrial nuclear fuel reprocessing.展开更多
An effective lithium-ion battery thermal management system(BTMS) ensures the safety of electric vehicles(EVs) and energy storage systems. Immersion cooling is known for high efficiency and excellent temperature unifor...An effective lithium-ion battery thermal management system(BTMS) ensures the safety of electric vehicles(EVs) and energy storage systems. Immersion cooling is known for high efficiency and excellent temperature uniformity. To address the high energy consumption of secondary cooling loops in vehicles for cooling immersion oil, this paper proposes a method of immersion coupled cooling tubes. Battery heat is directly absorbed by the immersion liquid and rapidly dissipated via cooling water in the S-type cooling tube(SCT). This work investigated the effects of structural parameters, immersion fluid medium, and operating parameters on the cooling performance of the BTMS. The results showed that the fin height(h_(f)) has no significant effect on the cooling performance. Both Transformer Oil and HFE-7100 delivered outstanding thermal management, reaching a maximum of 36.73℃ and 41.39℃ while maintaining narrow temperature differences of only 3.70℃ and 2.09℃ apart, respectively. When the ambient temperature reached 40℃ and HFE-7100 was used as the immersion liquid, the maximum temperature difference remained consistently below 3℃. Subsequently, a sensitivity analysis was conducted on the respective influential parameters. It was found that inlet water temperature(T_(in)) and immersion fluids exert the most significant influence on the system performance. Finally, different immersion cooling schemes were compared, which demonstrated the advantages of the system proposed in this study under harsh condition, thereby supporting the application of different schemes under various scenarios. It can be directly integrated with the vehicle-mounted cooling circuit system, thereby reducing energy consumption and weight, and offering new insights for research on thermal management systems for EVs.展开更多
文摘The handover speed is always vital for the further development of Wireless Local Area Network(WLAN),which is enjoying a fast growth.Based on the handover technology specified in IEEE 802.11 WLAN,Manageable Fast Handover(MFHO)mechanism is proposed to speed up handover at the Access Point(AP),meet handover demands of services with different Quality of Service(QoS),and ensure service continuity.Adopting a handover policy named'Make-before-break',this mechanism enables wireless APs to control and manage handover between two stations based on improving Inter-Access Point Protocol(IAPP).Tests have been carried out to compare functions and performance of MFHO and IAPP-based handover technology.The test results prove that MFHO provides a higher successful handover ratio and better handover performance than IAPP-based handover technology.
基金Partially supported by National Advanced Technology Research Development Plan 863 Program (2005AA121130)Tsinghua University Media and Net-work Technology Ministry of Education-Microsoft Lab Fund, and CNGI 2006 Apoplectic Demonstration project.
文摘The letter proposes a three-layer manageable media distribution network system architecture called MSPnet, which is based on Session Initiation ProtocolIll and Peer to Peer （SIP P2P） technology. MSPnet performs application-level structured DHT routing and resource location among domains and unstructured ones in domain. Except for media distribution, it can be used to support a variety of P2P applications, including video broadcasting, video on demand, VoIP, etc. MSPnet is composed of three layers, namely, the signal control layer, the management layer, and the media transportation layer. The MSPnet prototype consists of the SIP server, the management server, the media server, and the node User Agent （UA）. Results from a prototype experiment in a large-scale Internet environment show that MSPnet is feasible, scalable and manageable.
文摘Purpose-Interface management is the process of managing communications,responsibilities and coordination of project parties,phases or physical entities which are dependent on one another.Interface management is a crucial part of managing any construction project-but particularly important for high-speed railway projects that often have several contractual parties and stakeholders,very long project timelines and huge upfront cost overlays.This paper discusses how various project interfaces were managed during the design and construction of the civil engineering infrastructure for the High Speed Two(HS2)project in the United Kingdom.Design/methodology/approach-The paper uses the case study methodology.Key interfaces on the HS2 project are grouped into various categories and the paper discusses how they were managed within the Area North Integrated Project Team(IPT)of the HS2 project made up of contractor Balfour Beatty VINCI(BBV),the Mott MacDonald SYSTRA Design Joint Venture(DJV)and client HS2 Ltd.3 different case studies drawn from across the IPT are used,each of them highlighting different interfaces and how these interfaces were managed.Findings-The paper shows how innovative technical designs and modern methods of construction were used to address some of the unique and peculiar challenges of designing a brand-new railway in the United Kingdom.Addressing the contrasting and often competing requirements of different stakeholders,coupled with challenging physical constraints of the very limited land available for the project and the use of a rarely used Act of Parliament in the delivery of the project required different approach to interface management.Collaboration and proactive stakeholder engagement are necessary for successful interface management on megaprojects.The authors posit that adopting an integrated approach to engineering and construction management is an essential ingredient for the successful delivery of high-speed railway projects.Originality/value-With many high-speed railway projects around the world coming up in the next few years,understanding the context and challenges for each country will help engineering and design managers adopt appropriate approaches for their projects.The lessons learned on the HS2 project are also transferable to other mega infrastructure projects with complex project interfaces.
基金supported by the Fund for Innovative Research Group of the National Natural Science Foundation of China (Grant No.52221003)。
文摘The spatial optimization of best management practices(BMPs) plays a critical role in precise watershed pollution control. However, the effectiveness of BMPs exhibits a complex nonlinear dependence on both configuration unit scale and rainfall intensity, often leading to widespread spatiotemporal mismatches during implementation. To fill this gap, this study proposes a new framework:(a) delineating configuration units based on the implementation scale differences between structural and nonstructural BMPs;(b) incorporating BMP reduction thresholds to enable dynamic adjustment of design scales according to inflow loads;and(c) developing a staged allocation strategy tailored to varying rainfall scenarios. The framework is exemplified by an agricultural catchment in the southeastern Liaohe watershed, China. The results showed that the framework could improve the assessment accuracy and cost-effectiveness of pollution control. Specifically, neglecting BMP reduction thresholds resulted in a 51.35% underestimation of treatment costs. Incorporating these thresholds and dynamically adjusting BMP design scales reduced treatment costs by 62.70%. Furthermore, the framework facilitated more precise localization of structural BMPs(1 km^(2)) and improved optimization efficiency by 95.91%. The proposed staged allocation strategy ensured water quality compliance under varying rainfall intensities. Structural BMPs primarily addressed pollution from light to moderate rainfall in the initial stage, while nonstructural BMPs targeted heavy rainfall pollution in the subsequent stage. The proposed framework may enhance the spatiotemporal adaptability of BMP configuration to respond to the threats posed by climate change and human activities. It can also be extended to other agriculture-dominated watersheds.
基金supported by the Natural Science Foundation of Jiangsu Province(BK20231445)Aeronautical Science Foundation of China(20230028052001).
文摘The proton exchange membrane fuel cell(PEMFC)and the hydrogen hybrid power system are studied by the fuzzy-PID(FPID)controlmethod and the fuzzy-PID controlmethod by Artificial Bee Colony algorithm(ABCFPID),respectively.The results reveal that compared with the FPID control method,the temperature overshoot of the PEMFC stack under the ABC-FPID control method is decreased by 0.6%.Moreover,the circulating water flow rate within the full operating envelope(about 3 min)is reduced by 19.46 L,which means the ABC-FPID control method is more effective in regulating the stack temperature.Then,the ABC-FPID control method is proposed to study the hydrogen hybrid power system,and the system output power matching,operating characteristic curve of the fuel cell,state of charge(SOC)of the lithium battery,system efficiency and hydrogen demand are obtained.The results indicate that the maximum system efficiency reaches 46.3%,the average system efficiency is 33.8%,and the average hydrogen demand is 0.192 kg/s.Overall,the ABC-FPID control method can efficiently ensure the stability of the fuel cell’s output power,and actively prompt the lithium battery to fulfill the function of“peak shaving and valley filling”under variable load power conditions.
文摘Objective:To investigate the application effect of intelligent empowerment standardized airway management process in patients receiving mechanical ventilation.Methods:A retrospective analysis was conducted on the clinical data of 79 EICU inpatients who underwent tracheal intubation and mechanical ventilation treatment at our hospital from January 2023 to May 2025.The patients were divided into a control group(conventional airway management process,n=40)and a study group(intelligent empowerment standardized airway management process,n=39)based on the intervention protocols they received.Oral health scores,dental plaque index,oral odor,serum inflammatory markers[C-reactive protein(CRP),procalcitonin(PCT)],clinical pulmonary infection score(CPIS),as well as the incidence of ventilator-associated pneumonia(VAP),duration of mechanical ventilation,and length of stay in the EICU were assessed before and after treatment.Results:The baseline values of all indicators were consistent between the two groups before intervention(p>0.05).After corresponding interventions,both groups showed significant improvements in Beck oral health scores,dental plaque index,and oral odor,with more pronounced improvements observed in the study group(p<0.05).After the intervention,the research group showed a significant decrease in serum CRP and PCT levels,as well as CPIS scores(p<0.05).In contrast,the control group experienced an increase in these three indicators to a certain extent(p<0.05).Moreover,the incidence of ventilator-associated pneumonia(VAP),duration of mechanical ventilation,and length of stay in the EICU were all lower in the research group compared to the control group,while the nurse’s compliance rate with the protocol was higher in the research group(p<0.05).Conclusion:The standardized airway management protocol empowered by intelligent technology can significantly improve nursing compliance,benefit oral health status,reduce the risk of pulmonary infection and systemic inflammation levels,and promote rapid patient recovery,demonstrating considerable potential for widespread adoption.
基金Supported by Shandong Provincial Key Research and Development Program(2023TZXD034)2024 National Undergraduate Innovation Training Program(202410061062).
文摘Yam(Dioscorea opposita)is an important economic crop,and the development of its the cultivation tecchnology is of great significance for increasing yield,improving quality,and reducing the occurrence of pests and diseases.With the progression of agricultural technology and changes in market demands,the cultivation tecchnology of yam is constantly innovating and improving.This paper reviewed recent research advances in yam cultivation tecchnology,covering aspects such as soil improvement,variety selection,technological innovations,green pest control,and harvesting and storage.The goal is to provide references for the sustainable development of the yam industry.
基金Supported by Wuxi Taihu Talent Program(202101)Project of Wu Jieping Medical Foundation(320.6750.2023-03-33).
文摘[Objectives]To analyze the clinical characteristics,distribution of traditional Chinese medicine(TCM)syndrome types,spectrum of comorbidities,and complications among inpatients with gout.[Methods]Data from 592 gout patients admitted in the Department of Rheumatology at Wuxi Traditional Chinese Medicine Hospital between January 2018 and December 2024 were retrospectively collected.The data collected encompassed patient gender,age,TCM syndrome types,underlying comorbidities,infection status,and major complications,including renal insufficiency,interstitial lung disease,and osteoporosis.Descriptive statistical analyses were subsequently performed.[Results]Among the 592 inpatients,80.75%were male and 19.25%were female.A total of 94.76%patients had at least one underlying condition,with hypertension(80.74%),cerebral infarction(29.59%),heart disease(24.24%),and diabetes(21.56%)being the most prevalent.The primary TCM syndrome types identified were damp-heat obstruction syndrome(63.51%)and phlegm-stasis obstruction syndrome(21.11%).During hospitalization,20.94%of patients experienced concurrent infections,predominantly pulmonary infections(38.10%).The principal complications observed included renal insufficiency(32.09%),interstitial lung disease(18.75%),and osteoporosis(9.29%).[Conclusions]Inpatients diagnosed with gout often present with complex conditions and a high burden of comorbidities,predominantly cardiovascular and cerebrovascular diseases,as well as metabolic disorders.Additionally,there is a high incidence of infections and renal insufficiency within this population.TCM syndrome types in these patients are primarily characterized by damp-heat obstruction.In clinical practice,a comprehensive management approach that incorporates multidisciplinary collaboration is recommended.Alongside the control of uric acid levels and joint inflammation,proactive screening and management of comorbidities and related complications are essential.
基金supported by the Forest Growers Levy Trust(QT-10353)the Ministry for Primary Industries and the Sustainable Food and Fibre Futures fund(SFFF22023)the Strategic Science Investment Fund(CO4X1703)for funding this research.
文摘Invasive pests and pathogens cause immense damage globally,costing an estimated US$248 billion to the agricultural industry alone.Vehicles,such as farming and timber harvesting machinery and transportation trucks,can facilitate the rapid spread of biological invaders over distances far greater and more quickly than their natural dispersal ability.Understanding how frequent trips by these vehicles increase the spread of invasive agricultural and forestry pests can help inform effective biosecurity procedures before,during,or after an incursion.We used a case study of timber transport trucks in Aotearoa New Zealand to examine whether and how vehicles facilitate the spread of soil-borne pathogens between commercial forest plantations.Our results show that long-distance dispersal associated with truck movement facilitated the introduction of oomycete-like pathogens in 97% of forest sites within only one year,with pathogen loads within infected sites predicted at 84%of the sites’carrying capacity.Implementing preventative management strategies to reduce the transportation of infected soil by logging trucks,however,can reduce the spread by up to 50% after one year and reduce the pathogen load within infested sites by more than three times.Mitigating other human-assisted dispersal pathways can also help reduce spread.Reducing movement of forest visitors not involved in forestry activities,for instance,by closing forest sites to the public,can help to further reduce spread in addition to management related to harvesting activities.These results highlight the benefits of preventative management strategies in reducing the spread rate of novel soil pathogens through a high-intensity commercial forestry network but show that pest spread is still likely even with significant investment.
基金financed by PRIMA(MiDiVine project),the European Union(ERA-NET Cofound FACCE SURPLUS Call of Horizon 2020-FACCE JPI,“VitiSmart”project)a programme supported by the European Union with co-funding by the Funding Agencies RIF-Cyprus。
文摘Cyprus has an extensive record in grape production and winemaking.Grapevine is essential for the economic and environmental sustainability of the agricultural sector,as it is in other Mediterranean regions.Intensive agriculture can overuse and exhaust natural resources,including soil and water.The current study evaluated how conservation strategies,including no tillage and semi-tillage(as a variation of strip tillage),affected grapevine growth and grape quality when compared to conventional tillage application.Two cultivars were used:Chardonnay and Maratheftiko(indigenous).Soil pH decreased,and EC increased after tillage applications,in both vineyards.Tillage lowered soil N levels through mineralization,but the vineyard with Maratheftiko cultivar had higher soil N and K levels than the vineyard with Chardonnay cultivar.No tillage reduced yield in Chardonnay;however,semi-tillage enhanced yield in Maratheftiko.There were no major changes in plant physiology,even though Maratheftiko had less variation in stomatal conductance values under the various tillage practices than Chardonnay.Tillage enhanced N and K content in Chardonnay vines during flowering,and increased N in Maratheftiko.Total phenols and antioxidant status of leaves varied,with tillage stimulating them,especially at the harvest stage.Furthermore,tillage raised grape juice total soluble solids,pH,and total phenols in both cultivars,while anthocyanins and tannins content were increased in Maratheftiko under no tillage.The results of this study may aid in the development of cultivation strategies to enable viticulture to address various environmental challenges due to climate change.
文摘Heavy metal(HM)contamination severely impacts global agricultural production.HMs toxicity effectively damaged the physiological functions such as imbalanced redox homeostasis,altered antioxidant enzyme activity,damage root system architecture,hindered photosynthetic apparatus,cellular toxicity,restricted mineral accumulation,and changed the metabolite production.Using phytohormones may be a successful strategy for enhancing and stimulating plant tolerance to HMs toxicity without affecting the environment.Melatonin(MT),a novel plant growth regulator,and powerful antioxidant molecule,enhances plant resilience to HMs stress by enhancing seedling growth,protecting the photosynthetic system,increasing nutritional status,balanced redox homeostasis,and restricting HMs accumulation from root to shoot.In addition,MT enhances the activity of antioxidant enzymes and triggers the ascorbate-glutathione(AsA-GSH)cycle,which helps remove excessive ROS.MT improves RuBisCO activity to improve photosynthesis and reduce the breakdown of chlorophyll.To identify future research needs,it is crucial to understand the comprehensive and intricate regulatory mechanisms of exogenous and endogenous MT-mediated reduction of heavy metal toxicity in plants.Melatonin has several functions,and this review sheds light on those functions and the molecular processes by which it alleviates HMs toxicity.More research is needed to fully understand how melatonin affects plant tolerance to heavy metals stress.
文摘Purpose-This study explores how managerial leadership and organizational innovation interact to enhance resilience and risk management in railway supply chains and how these capabilities contribute to sustained competitive advantage.It emphasizes the strategic importance of resilience in railway systems that face operational complexity,regulatory pressures and increasing exposure to systemic risks.Design/methodology/approach-A mixed-methods design was employed,integrating survey data from 186 railway organizations with six case studies involving railway operators,rolling stock manufacturers and supply chain partners across multiple regions.Constructs were measured using validated scales and hypothesized relationships were tested using Structural Equation Modeling(SEM).Case study interviews were analyzed thematically to provide contextual understanding of leadership practices and innovation strategies.Findings-The results confirm that transformational managerial leadership significantly predicts innovation adoption,which in turn strengthens resilience and risk management capabilities.Resilience emerged as a powerful driver of competitive advantage,reinforcing its role as a strategic capability rather than a reactive response to disruptions.Furthermore,innovation was shown to partially mediate the relationship between leadership and resilience,highlighting its function as the operational channel through which vision translates into capability.Originality/value-This study contributes to the literature by integrating the Resource-Based View(RBV)and Dynamic Capabilities(DC)framework into the context of railway supply chains.It is among the first to empirically validate the mediating role of innovation between leadership and resilience,offering both theoretical advancements and actionable strategies for building resilient and competitive railway systems.
文摘Shandong Port Group(SPG),which was established in August 2019,regards standardization as the cornerstone of modern enterprise management,and vigorously implements the standardization innovation strategy.Its standardization work mainly focuses on the following four aspects.
文摘Submission All manuscripts are submitted and reviewed via the journal's web-based manuscript submission system Editorial Manager:https://www.editorialmanager.com/lers/default.aspx.New authors should create an account prior to submitting a manuscript for consideration.If you have any questions about submitting,please contact the editorial office:lersurgery@srrsh.com.
文摘With the intensification of population aging in China,the problem of cognitive impairment in the elderly has become increasingly prominent,attracting widespread attention from all sectors of society.Geriatric cognitive impairment is characterized by chronicity,which not only seriously threatens the health of the elderly and reduces their quality of life,but also imposes a heavy burden on families and society due to its long course.Attaching importance to and strengthening the chronic disease management of elderly cognitive impairment has profound significance for delaying disease progression,improving patients’quality of life,and reducing the burden of family care.Therefore,this paper first comprehensively understands elderly cognitive impairment by briefly elaborating on its definition and characteristics;on this basis,it focuses on exploring effective strategies for the chronic disease management of elderly cognitive impairment,hoping to provide new ideas and methods for the management of this condition and offer useful references for relevant clinical research and practice.
基金supported by National Natural Science Foundation of China(32494793).
文摘Cellulose frameworks have emerged as promising materials for light management due to their exceptional light-scattering capabilities and sustainable nature.Conventional biomass-derived cellulose frameworks face a fundamental trade-off between haze and transparency,coupled with impractical thicknesses(≥1 mm).Inspired by squid’s skin-peeling mechanism,this work develops a peroxyformic acid(HCOOOH)-enabled precision peeling strategy to isolate intact 10-μm-thick bamboo green(BG)frameworks—100×thinner than wood-based counterparts while achieving an unprecedented optical performance(88%haze with 80%transparency).This performance surpasses delignified biomass(transparency<40%at 1 mm)and matches engineered cellulose composites,yet requires no energy-intensive nanofibrillation.The preserved native cellulose I crystalline structure(64.76%crystallinity)and wax-coated uniaxial fibril alignment(Hermans factor:0.23)contribute to high mechanical strength(903 MPa modulus)and broadband light scattering.As a light-management layer in polycrystalline silicon solar cells,the BG framework boosts photoelectric conversion efficiency by 0.41%absolute(18.74%→19.15%),outperforming synthetic anti-reflective coatings.The work establishes a scalable,waste-to-wealth route for optical-grade cellulose materials in next-generation optoelectronics.
文摘Soil erosion is a fundamental physical process driving land degradation across various spatial and temporal scales.The Soil and Water Assessment Tool(SWAT)model is a robust tool for predicting soil erosion and evaluating water and soil quality within watersheds.The latest version,SWAT+,introduces advanced encoding capabilities and improved performance,making it better suited for addressing complex watershed modeling challenges.This study implemented the SWAT+model to quantify soil erosion rates within the Chehelchay watershed in northern Iran.The foundational dataset comprises a 30-meter resolution Digital Elevation Model(DEM),land use classification,soil,and weather data.Model performance was evaluated using Nash-Sutcliffe Efficiency(NSE),coefficient of determination(R^(2)),root mean square error(RMSE),and percent bias(PBIAS).The SWAT+simulation revealed substantial spatial variation in erosion patterns across the watershed,with annual sediment yields in critical HRUs,reflecting diverse erosion intensities driven by variations in land use,soil characteristics,and slope.Among the Hydrological Response Units(HRUs),50 critical units,representing approximately 9%of the total watershed area,generate sediment yields exceeding 5 tons per hectare per year.The most severe erosion occurs predominantly in the central zone of the watershed.Downstream regions exhibit minimal soil loss due to gentle topography while upstream areas maintain soil stability through protective forest cover,resulting in negligible erosion rates.Best Management Practices(BMPs)were designed to safeguard water and soil resources at a watershed level.The study evaluated three strategic conservation interventions:alfalfa cultivation,agroforestry implementation,and garden development.When applied in combination,these measures achieved approximately 30%reduction in sediment yield at the HRU level.This integrated approach demonstrates the potential of combining multiple land management strategies to combat erosion effectively.
基金funded by the Open Access Initiative of the University of Bremen and the DFG via SuUB BremenThe authors extend their appreciation to the Deanship of Research and Graduate Studies at King Khalid University for funding this work through Large Group Project under grant number(RGP2/367/46)+1 种基金This research is supported and funded by Princess Nourah bint Abdulrahman University Researchers Supporting Project number(PNURSP2025R410)Princess Nourah bint Abdulrahman University,Riyadh,Saudi Arabia.
文摘As urban landscapes evolve and vehicular volumes soar,traditional traffic monitoring systems struggle to scale,often failing under the complexities of dense,dynamic,and occluded environments.This paper introduces a novel,unified deep learning framework for vehicle detection,tracking,counting,and classification in aerial imagery designed explicitly for modern smart city infrastructure demands.Our approach begins with adaptive histogram equalization to optimize aerial image clarity,followed by a cutting-edge scene parsing technique using Mask2Former,enabling robust segmentation even in visually congested settings.Vehicle detection leverages the latest YOLOv11 architecture,delivering superior accuracy in aerial contexts by addressing occlusion,scale variance,and fine-grained object differentiation.We incorporate the highly efficient ByteTrack algorithm for tracking,enabling seamless identity preservation across frames.Vehicle counting is achieved through an unsupervised DBSCAN-based method,ensuring adaptability to varying traffic densities.We further introduce a hybrid feature extraction module combining Convolutional Neural Networks(CNNs)with Zernike Moments,capturing both deep semantic and geometric signatures of vehicles.The final classification is powered by NASNet,a neural architecture search-optimized model,ensuring high accuracy across diverse vehicle types and orientations.Extensive evaluations of the VAID benchmark dataset demonstrate the system’s outstanding performance,achieving 96%detection,94%tracking,and 96.4%classification accuracy.On the UAVDT dataset,the system attains 95%detection,93%tracking,and 95%classification accuracy,confirming its robustness across diverse aerial traffic scenarios.These results establish new benchmarks in aerial traffic analysis and validate the framework’s scalability,making it a powerful and adaptable solution for next-generation intelligent transportation systems and urban surveillance.
基金supported by the China Institute of Atomic Energy。
文摘The removal of trace plutonium(Pu)from uranium products and organic wastes during spent nuclear fuel reprocessing remains a critical challenge,resulting in excessive plutonium content in uranium products and waste organic liquid.Currently,most organic ligands with selective separation functions are lipophilic,while research on water-soluble,highly selective ligands is relatively scarce,and there are also few reports on the single crystal of these ligands coordinating with plutonium.Herein,a hydrophilic multiamide ligand,N,N,N′,N″,N″-hexaethyl-nitrilotriacetamide(NTAamideC2),was synthesized and evaluated for its Pu(Ⅳ)back-extraction efficiency under harsh conditions.Systematic experiments revealed that NTAamideC2 achieved>99%Pu(Ⅳ)back-extraction rate within 15 min across a wide nitric acid concentration range(0-5 M),even with elevated dibutyl phosphate(DBP≤20000 ppm).Remarkably,the separation factor(SFPu/U)reached 767 at 1.5 M HNO_(3),demonstrating exceptional selectivity over uranium(Ⅵ).Spectrophotometric titration and DFT calculations confirmed the formation of 1:1 and 1:2 Pu(Ⅳ)-NTAamideC2 complexes,with log β values of 7.42±0.01 and 13.23±0.02,respectively.Single-crystal X-ray diffraction analysis of{[Pu_(2)(H_(2)O)_(2)(NTAamideC2)_(4)](H_(2)O)_(2)(NO_(3))(ClO_(4))_(7)}revealed a nine-coordinated PuO_(7)N_(2)geometry,where two NTAamideC2 molecules bind via six O and two N atoms.Compared to conventional agents(AHA/HSC),NTAamideC2 exhibited superior acid tolerance and selectivity,aligning with the CHON principle for sustainable nuclear waste management.This work provides a robust strategy for Pu(Ⅳ)removal in uranium purification cycles and advances fundamental insights into Pu coordination chemistry,offering significant potential for industrial nuclear fuel reprocessing.
基金supported by the Science and Technology Projects of Xizang Autonomous Region,China (Grant No.XZ202501ZY0080)。
文摘An effective lithium-ion battery thermal management system(BTMS) ensures the safety of electric vehicles(EVs) and energy storage systems. Immersion cooling is known for high efficiency and excellent temperature uniformity. To address the high energy consumption of secondary cooling loops in vehicles for cooling immersion oil, this paper proposes a method of immersion coupled cooling tubes. Battery heat is directly absorbed by the immersion liquid and rapidly dissipated via cooling water in the S-type cooling tube(SCT). This work investigated the effects of structural parameters, immersion fluid medium, and operating parameters on the cooling performance of the BTMS. The results showed that the fin height(h_(f)) has no significant effect on the cooling performance. Both Transformer Oil and HFE-7100 delivered outstanding thermal management, reaching a maximum of 36.73℃ and 41.39℃ while maintaining narrow temperature differences of only 3.70℃ and 2.09℃ apart, respectively. When the ambient temperature reached 40℃ and HFE-7100 was used as the immersion liquid, the maximum temperature difference remained consistently below 3℃. Subsequently, a sensitivity analysis was conducted on the respective influential parameters. It was found that inlet water temperature(T_(in)) and immersion fluids exert the most significant influence on the system performance. Finally, different immersion cooling schemes were compared, which demonstrated the advantages of the system proposed in this study under harsh condition, thereby supporting the application of different schemes under various scenarios. It can be directly integrated with the vehicle-mounted cooling circuit system, thereby reducing energy consumption and weight, and offering new insights for research on thermal management systems for EVs.
